[go: up one dir, main page]

KR850007254A - 니트로메틸렌 유도체의 제조방법 - Google Patents

니트로메틸렌 유도체의 제조방법 Download PDF

Info

Publication number
KR850007254A
KR850007254A KR1019850002454A KR850002454A KR850007254A KR 850007254 A KR850007254 A KR 850007254A KR 1019850002454 A KR1019850002454 A KR 1019850002454A KR 850002454 A KR850002454 A KR 850002454A KR 850007254 A KR850007254 A KR 850007254A
Authority
KR
South Korea
Prior art keywords
group
formula
halogen atom
compound
lower alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
KR1019850002454A
Other languages
English (en)
Other versions
KR910004433B1 (ko
Inventor
고우조우 시오까와 (외 3)
Original Assignee
다데노 고자부로
니혼 도꾸슈 노야꾸 세이조 가부시기 가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP7296684A external-priority patent/JPS60218386A/ja
Priority claimed from JP59132943A external-priority patent/JPS6112682A/ja
Application filed by 다데노 고자부로, 니혼 도꾸슈 노야꾸 세이조 가부시기 가이샤 filed Critical 다데노 고자부로
Publication of KR850007254A publication Critical patent/KR850007254A/ko
Application granted granted Critical
Publication of KR910004433B1 publication Critical patent/KR910004433B1/ko
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/62—Oxygen or sulfur atoms
    • C07D213/70—Sulfur atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/36—Radicals substituted by singly-bound nitrogen atoms
    • C07D213/38—Radicals substituted by singly-bound nitrogen atoms having only hydrogen or hydrocarbon radicals attached to the substituent nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/61—Halogen atoms or nitro radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/62—Oxygen or sulfur atoms
    • C07D213/63—One oxygen atom
    • C07D213/64—One oxygen atom attached in position 2 or 6
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/79—Acids; Esters
    • C07D213/80—Acids; Esters in position 3
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/06—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pyridine Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

니트로메틸렌 유도체의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. 일반식(Ⅱ)의 화합물을 일반식(Ⅱ)의 화합물과 반응시킴을 특징으로 하여 일반식(Ⅰ)의 니트로 메틸렌 유도체 또는 그의 염을 제조하는 방법.
    상기식에서, R은 수소원자 또는 저급알킬 그룹이고; R′는 각각의 저급알킬그룹 또는 벤질그룹이거나, 두개의 R′그룹이 함께는 탄소수 2이상의 저급알킬랜그룹을 나타내며, 이들에 인접한 황 원자와 함께 환을 형성할 수도 있고; X는 할로겐원자, 저급알킬그룹, 저급알콕시그룹, 저급알킬티오그룹, 저급알킬설피닐그룹, 저급설포닐그룹, 저급알케닐그룹, 저급알키닐그룹, 아릴그룹, 할로겐원자에 의해 임의로 치환될 수 있는 아릴옥시그룹, 할로겐원자에 의해 임의로 치환될 수 있는 아릴티오그룹, 또는 아르알킬그룹이며; 1은 1,2,3 또는4이고; m은 2,3 또는 4이며; n은 0,1,2 또는 3이다.
  2. 제1항에 있어서, m이 2 또는 3인 일반식(Ⅰ)의 니트로메틸렌 유도체 또는 그의 염을 제조하는 방법.
  3. 일반식(Ⅳ)의 화합물을 일반식(Ⅴ)의 화합물과 반응시킴을 특징으로 하여 일반식(Ⅱ)의 화합물을 제조하는 방법.
    상기식에서, R은 수소원자 또는 저급알킬 그룹이고; X는 할로겐원자, 저급알킬그룹, 저급알콕시그룹, 저급알킬티오그룹, 저급알킬설피닐그룹, 저급알킬설포닐그룹, 저급알케닐그룹, 저급알키닐그룹, 아릴그룹, 할로겐원자에 의해 임의로 치환될 수 있는 아릴옥시그룹, 할로겐원자에 의해 임의로 치환될 수 있는 아릴티오그룹, 또는 아르알킬그룹이며; Y는 할로겐원자 또는 -OSO2R″그룹(여기에서 R″는 저급알킬 또는 아릴그룹이다)이고; 1은 1,2,3 또는 4이며; m은 2,3 또는 4이고; n은 0,1,2 또는 3이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019850002454A 1984-04-13 1985-04-12 니트로메틸렌 유도체의 제조방법 Expired KR910004433B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP59-72966 1984-04-13
JP7296684A JPS60218386A (ja) 1984-04-13 1984-04-13 ニトロメチレン誘導体、その製法及び殺虫剤
JP72966 1984-04-13
JP59132943A JPS6112682A (ja) 1984-06-29 1984-06-29 殺虫性ニトロメチレン誘導体
JP132943 1984-06-29

Publications (2)

Publication Number Publication Date
KR850007254A true KR850007254A (ko) 1985-12-02
KR910004433B1 KR910004433B1 (ko) 1991-06-27

Family

ID=26414100

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019850002454A Expired KR910004433B1 (ko) 1984-04-13 1985-04-12 니트로메틸렌 유도체의 제조방법

Country Status (18)

Country Link
US (3) US4678795A (ko)
EP (1) EP0163855B1 (ko)
KR (1) KR910004433B1 (ko)
AR (1) AR241909A1 (ko)
AU (2) AU571961B2 (ko)
BR (1) BR8501739A (ko)
CA (1) CA1262725A (ko)
DE (1) DE3571131D1 (ko)
DK (2) DK169072B1 (ko)
ES (1) ES542202A0 (ko)
HU (1) HU196029B (ko)
IL (1) IL74864A (ko)
NZ (1) NZ211738A (ko)
OA (1) OA07991A (ko)
PH (1) PH22486A (ko)
PT (1) PT80231B (ko)
TR (1) TR22165A (ko)
ZW (1) ZW5085A1 (ko)

Families Citing this family (67)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0192060B1 (de) 1985-02-04 1991-09-18 Nihon Bayer Agrochem K.K. Heterocyclische Verbindungen
JPH072736B2 (ja) * 1985-08-27 1995-01-18 日本バイエルアグロケム株式会社 ニトロメチレン誘導体、その製法及び殺虫剤
US4731385A (en) * 1985-10-26 1988-03-15 Nihon Tokushu Noyaku Seizo K.K. Insecticidal and fungicidal composition for agricultural and horticultural use
DE3603100C2 (de) * 1986-02-01 1994-08-25 Bayer Ag Verfahren zur Herstellung von Nitromethylen-Derivaten
JPH0717621B2 (ja) 1986-03-07 1995-03-01 日本バイエルアグロケム株式会社 新規ヘテロ環式化合物
USRE39130E1 (en) * 1986-03-07 2006-06-13 Bayer Cropscience K.K. Heterocyclic compounds
JPH085859B2 (ja) * 1986-07-01 1996-01-24 日本バイエルアグロケム株式会社 新規アルキレンジアミン類
DE3630046A1 (de) * 1986-09-04 1988-03-17 Bayer Ag Verfahren zur herstellung von 5-chlormethylpyridinen
JPH07121909B2 (ja) * 1986-09-10 1995-12-25 日本バイエルアグロケム株式会社 新規複素環式化合物及び殺虫剤
DE3717837A1 (de) * 1987-05-27 1988-12-08 Bayer Ag Heterocyclisch substituierte 2-(1'-nitroalkyliden)-1,3-heterocyclen
EP0509559B1 (en) * 1987-08-01 2001-10-04 Takeda Chemical Industries, Ltd. Alpha-unsaturated amines, their production and use
DE3887800D1 (de) * 1987-08-04 1994-03-24 Ciba Geigy Substituierte Guanidine.
JP2583429B2 (ja) * 1987-11-06 1997-02-19 日本バイエルアグロケム株式会社 イミダゾリン類及び殺虫剤
JP2779403B2 (ja) * 1988-11-29 1998-07-23 日本バイエルアグロケム株式会社 殺虫性ニトロ化合物
DE58908969D1 (de) * 1988-12-16 1995-03-16 Bayer Ag Verfahren zur Herstellung von 2-Chlor-5-chlormethylpyridin.
EP0383091B1 (en) * 1989-02-13 1993-11-10 Nihon Bayer Agrochem K.K. Insecticidally active nitro compounds
US6232309B1 (en) 1989-03-09 2001-05-15 Nihon Bayer Agrochem K.K. Insecticidal heterocyclic compounds
JP2610988B2 (ja) * 1989-03-09 1997-05-14 日本バイエルアグロケム 株式会社 新規ヘテロ環式化合物及び殺虫剤
DE3912964A1 (de) * 1989-04-20 1990-10-25 Bayer Ag Verfahren zur herstellung von 2-chlor-5-chlormethyl-pyridin und neue zwischenprodukte
US5329011A (en) * 1989-04-20 1994-07-12 Bayer Aktiengesellschaft Process for the preparation of 2-chloro-5-chloromethyl-pyridine, and new intermediates
IL99445A (en) * 1990-09-18 1996-06-18 Ciba Geigy Ag Picoline oxides process for their preparation and insecticidal and acaricidal compositions containing them
DE4111215A1 (de) * 1991-04-06 1992-10-08 Bayer Ag Verfahren zur herstellung von 2-chlorpyridinen
JP3162450B2 (ja) 1991-04-27 2001-04-25 日本バイエルアグロケム株式会社 工芸素材類を害虫より保護するための害虫防除剤
US6936624B2 (en) 1991-04-27 2005-08-30 Nihon Bayer Agrochem K.K. Agents for preserving technical materials against insects
DE4137271A1 (de) * 1991-11-13 1993-05-19 Bayer Ag Verfahren zur herstellung von n-(2-chlor-pyridin-5-yl-methyl)-ethylendiamin
GB2263640A (en) * 1992-01-31 1993-08-04 Shell Int Research Method of combating aphids
DE4232561A1 (de) * 1992-09-29 1994-03-31 Bayer Ag Bekämpfung von Fischparasiten
DE4301110A1 (de) * 1993-01-18 1994-07-21 Bayer Ag Verfahren zur Herstellung von 2-Amino-5-aminomethyl-pyridin
DE4308152A1 (de) * 1993-03-15 1994-09-22 Bayer Ag Verfahren zur Herstellung von 2-Halogen-5-cyano-pyridinen
AU687383B2 (en) * 1993-06-02 1998-02-26 Bayer Corporation Combined use of chemicals and microbials in cockroach control
JP3363525B2 (ja) * 1993-06-08 2003-01-08 バイエルクロップサイエンス株式会社 殺虫方法
EP0652215A1 (en) * 1993-11-04 1995-05-10 Shell Internationale Researchmaatschappij B.V. Methylene-substituted heterocyclic compounds
DE4414569A1 (de) * 1994-04-27 1995-11-02 Bayer Ag Verwendung von substituierten Aminen zur Behandlung von Hirnleistungsstörungen
DE4417742A1 (de) 1994-05-20 1995-11-23 Bayer Ag Nicht-systemische Bekämpfung von Parasiten
DE4419814A1 (de) * 1994-06-07 1995-12-14 Bayer Ag Endoparasitizide
DE4426753A1 (de) * 1994-07-28 1996-02-01 Bayer Ag Mittel zur Bekämpfung von Pflanzenschädlingen
ATE203585T1 (de) * 1995-10-20 2001-08-15 Thomson Ind Inc Verfahren zur herstellung eines linearlagers
US6828275B2 (en) * 1998-06-23 2004-12-07 Bayer Aktiengesellschaft Synergistic insecticide mixtures
DE19548872A1 (de) 1995-12-27 1997-07-03 Bayer Ag Synergistische insektizide Mischungen
JP2000506846A (ja) 1996-03-04 2000-06-06 バイエル・アクチエンゲゼルシヤフト テトラヒドロピリミジン誘導体
DE19622355A1 (de) 1996-06-04 1997-12-11 Bayer Ag Formkörper die agrochemische Mittel freisetzen
DE19710613A1 (de) * 1997-03-14 1998-09-17 Bayer Ag Verfahren zur Herstellung von 5-Aminomethyl-2-chlorpyridinen
DE19807630A1 (de) 1998-02-23 1999-08-26 Bayer Ag Wasserhaltige Mittel zur Bekämpfung parasitierender Insekten und Milben an Menschen
DE19823396A1 (de) * 1998-05-26 1999-12-02 Bayer Ag Synergistische insektizide Mischungen
US6149913A (en) * 1998-11-16 2000-11-21 Rhone-Poulenc Ag Company, Inc. Compositions and methods for controlling insects
CO5210925A1 (es) 1998-11-17 2002-10-30 Novartis Ag Derivados de diamino nitroguanidina tetrasustituidos
DE19913174A1 (de) 1999-03-24 2000-09-28 Bayer Ag Synergistische insektizide Mischungen
US6156703A (en) * 1999-05-21 2000-12-05 Ijo Products, Llc Method of inhibiting fruit set on fruit producing plants using an aqueous emulsion of eicosenyl eicosenoate and docosenyl eicosenoate
DE19948129A1 (de) 1999-10-07 2001-04-12 Bayer Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
JP5078211B2 (ja) 2000-01-19 2012-11-21 バイエル アクチェンゲゼルシャフト 複素環式化合物の製造方法
DE10024934A1 (de) * 2000-05-19 2001-11-22 Bayer Ag Wirkstoffkombinationen mit insektiziden akariziden Eigenschaften
US20020103233A1 (en) * 2000-11-30 2002-08-01 Arther Robert G. Compositions for enhanced acaricidal activity
DE10117676A1 (de) * 2001-04-09 2002-10-10 Bayer Ag Dermal applizierbare flüssige Formulierungen zur Bekämpfung von parasitierenden Insekten an Tieren
DE10154313A1 (de) 2001-11-05 2003-05-15 Bayer Cropscience Ag Halogen-nitro-butadiene
US8232261B2 (en) 2003-07-18 2012-07-31 Bayer Cropscience Lp Method of minimizing herbicidal injury
DE102004006075A1 (de) 2003-11-14 2005-06-16 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden Eigenschaften
JP2005272417A (ja) * 2004-03-26 2005-10-06 Kuraray Co Ltd ２−クロロ−４−アミノメチルピリジン類の製造方法
US20080090728A1 (en) * 2004-05-13 2008-04-17 Bayer Cropscience Ag Method for Improving Plant Growth
WO2006036387A2 (en) * 2004-08-25 2006-04-06 Bayer Cropscience Lp Method of controlling termites
DE102004054960A1 (de) * 2004-11-13 2006-05-18 Bayer Cropscience Ag Fliegen-Gelköder
US9919979B2 (en) 2005-01-21 2018-03-20 Bayer Cropscience Lp Fertilizer-compatible composition
CN102070607A (zh) * 2011-01-25 2011-05-25 南京农业大学 具有杀虫活性的吡啶氮氧化物类新烟碱化合物及其用途
AR109107A1 (es) 2016-07-29 2018-10-31 Bayer Cropscience Ag Compuestos halógeno(tio)acilo sustituidos
CN112010836B (zh) * 2020-09-07 2021-07-09 南通大学 含芳基联吡啶氧基结构的2-取代基咪唑烷衍生物及其制备方法和用途
CN111925365B (zh) * 2020-09-07 2022-07-29 南通大学 含取代1,3,5-噁二嗪单元的吡啶衍生物的制备方法与用途
CN111909145B (zh) * 2020-09-16 2022-07-22 南通大学 含吡啶联取代苯氧基单元的2-取代基-1,3-噻唑烷的制备与用途
CN113293046B (zh) * 2021-05-26 2021-11-30 安徽博洋润滑科技有限公司 一种低发尘润滑脂及其制备方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3252860A (en) * 1963-06-05 1966-05-24 Ciba Geigy Corp Antihypertensive n-picolyl-ethylene-diamine compositions
FR1511398A (fr) * 1966-02-16 1968-01-26 Takeda Chemical Industries Ltd Procédé de préparation de nouveaux dérivés de picoline
US4002765A (en) * 1974-09-27 1977-01-11 Shell Oil Company 2-(Nitromethylene)-1,3-diazacycloalkane insect control agents
US3971774A (en) * 1974-09-27 1976-07-27 Shell Oil Company 2-(Nitromethylene)-1,3-diazepines
DE2514402A1 (de) * 1975-04-02 1976-10-21 Hoechst Ag Insektizide mittel
US4136188A (en) * 1976-06-25 1979-01-23 Daiichi Seiyaku Co., Ltd. Treatment of diabetes with 2-substituted-1,3-diazacyclic compounds
GB2014147B (en) * 1978-02-14 1982-06-03 Shell Int Research Production of 1,3-diaza-heterocycles
DE3378046D1 (en) * 1982-07-16 1988-10-27 Upjohn Co (3-pyridinyl)heteroalkanols and alkanoic acids and esters
JPS60172976A (ja) * 1984-02-16 1985-09-06 Nippon Tokushu Noyaku Seizo Kk ニトロメチレン誘導体，その製法及び殺虫，殺ダニ，殺センチユウ剤
EP0192060B1 (de) * 1985-02-04 1991-09-18 Nihon Bayer Agrochem K.K. Heterocyclische Verbindungen
JPH072736B2 (ja) * 1985-08-27 1995-01-18 日本バイエルアグロケム株式会社 ニトロメチレン誘導体、その製法及び殺虫剤
US4918086A (en) * 1987-08-07 1990-04-17 Ciba-Geigy Corporation 1-nitro-2,2-diaminoethylene derivatives

Also Published As

Publication number Publication date
DK167885A (da) 1985-10-14
DK171643B1 (da) 1997-03-03
DE3571131D1 (en) 1989-07-27
EP0163855A1 (de) 1985-12-11
ZW5085A1 (en) 1985-09-18
PT80231B (pt) 1987-09-30
KR910004433B1 (ko) 1991-06-27
AR241909A1 (es) 1993-01-29
AU1018388A (en) 1988-04-28
AU571961B2 (en) 1988-04-28
TR22165A (tr) 1986-07-14
DK167885D0 (da) 1985-04-12
IL74864A (en) 1988-02-29
DK198891D0 (da) 1991-12-10
PT80231A (en) 1985-05-01
AU597772B2 (en) 1990-06-07
ES8603242A1 (es) 1985-12-16
US4812571A (en) 1989-03-14
ES542202A0 (es) 1985-12-16
CA1262725A (en) 1989-11-07
DK198891A (da) 1991-12-10
BR8501739A (pt) 1985-12-10
HUT37709A (en) 1986-02-28
HU196029B (en) 1988-09-28
PH22486A (en) 1988-09-12
US4678795A (en) 1987-07-07
OA07991A (fr) 1987-01-31
US4774247A (en) 1988-09-27
NZ211738A (en) 1987-08-31
EP0163855B1 (de) 1989-06-21
DK169072B1 (da) 1994-08-08
AU4109785A (en) 1985-10-17

Similar Documents

Publication Publication Date Title
KR850007254A (ko) 니트로메틸렌 유도체의 제조방법
KR860001793A (ko) 벤즈 이미다졸 유도체의 제조방법
KR850006404A (ko) 니트로 메틸렌 유도체의 제조방법
ES8105694A1 (es) Procedimiento para la produccion de propenilaminas
KR840004406A (ko) 히단토인의 제조방법
KR870003998A (ko) 퀴나졸린 유도체류의 제조방법
KR860009023A (ko) 치환된 실릴기를 갖는 신규 에테르 화합물의 제조방법
KR830005162A (ko) 색소형성 퀴나졸린
KR880002823A (ko) 약제학적 화합물
KR880012590A (ko) 신규 함질소 화합물
KR830005110A (ko) 플루오렌 유도체의 제조방법
KR840006233A (ko) 티오펜 유도체의 제조방법
KR860002482A (ko) 디페닐 에테르 이민 유도체 제조방법
KR830004210A (ko) 2-아미노-3-벤조일-페닐아세트아미드 및 환상 동족체
KR850002460A (ko) 카르바메이트 화합물의 제조방법
KR850006934A (ko) 3-페닐-2-프로펜아민 유도체의 제법
KR860007232A (ko) 벤조일 우레아의 제조방법
KR850004470A (ko) 유기 화합물의 제조방법
KR840004103A (ko) 디아졸릴 알칸올의 제조방법
KR850002979A (ko) 1,2,3-트리티안화합물의 신규 제조방법
KR840002821A (ko) N-(2,3-에폭시프로필렌)-n-아르알킬술폰아미드 유도체의 제조방법
KR860002486A (ko) 티아진포스폰산 유도체의 제조방법
KR850007247A (ko) 바이페닐릴설포닐 우레아의 제조방법
KR860008154A (ko) 진디기 구제작용을 가진 티아디아졸류의 제조방법
KR840004105A (ko) N,n- 치환된 아졸 카복스 아미드 유도체의 제조방법

Legal Events

Date Code Title Description
PA0109 Patent application

Patent event code: PA01091R01D

Comment text: Patent Application

Patent event date: 19850412

PG1501 Laying open of application
A201 Request for examination
PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 19890706

Comment text: Request for Examination of Application

Patent event code: PA02011R01I

Patent event date: 19850412

Comment text: Patent Application

G160 Decision to publish patent application
PG1605 Publication of application before grant of patent

Comment text: Decision on Publication of Application

Patent event code: PG16051S01I

Patent event date: 19910601

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

Patent event code: PE07011S01D

Comment text: Decision to Grant Registration

Patent event date: 19910924

GRNT Written decision to grant
PR0701 Registration of establishment

Comment text: Registration of Establishment

Patent event date: 19911202

Patent event code: PR07011E01D

PR1002 Payment of registration fee

Payment date: 19911202

End annual number: 3

Start annual number: 1

PR1001 Payment of annual fee

Payment date: 19940526

Start annual number: 4

End annual number: 4

PR1001 Payment of annual fee

Payment date: 19950526

Start annual number: 5

End annual number: 5

PR1001 Payment of annual fee

Payment date: 19960605

Start annual number: 6

End annual number: 6

PR1001 Payment of annual fee

Payment date: 19970605

Start annual number: 7

End annual number: 7

PR1001 Payment of annual fee

Payment date: 19980609

Start annual number: 8

End annual number: 8

PR1001 Payment of annual fee

Payment date: 19990526

Start annual number: 9

End annual number: 9

PR1001 Payment of annual fee

Payment date: 20000526

Start annual number: 10

End annual number: 10

PR1001 Payment of annual fee

Payment date: 20010525

Start annual number: 11

End annual number: 11

PR1001 Payment of annual fee

Payment date: 20020528

Start annual number: 12

End annual number: 12

PR1001 Payment of annual fee

Payment date: 20030526

Start annual number: 13

End annual number: 13

FPAY Annual fee payment

Payment date: 20040607

Year of fee payment: 14

PR1001 Payment of annual fee

Payment date: 20040607

Start annual number: 14

End annual number: 14

EXPY Expiration of term
PC1801 Expiration of term