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KR850006687A - 폴리우레탄 조성물용 촉매 시스템 - Google Patents

폴리우레탄 조성물용 촉매 시스템 Download PDF

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Publication number
KR850006687A
KR850006687A KR1019850001482A KR850001482A KR850006687A KR 850006687 A KR850006687 A KR 850006687A KR 1019850001482 A KR1019850001482 A KR 1019850001482A KR 850001482 A KR850001482 A KR 850001482A KR 850006687 A KR850006687 A KR 850006687A
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composition
component
aliphatic
iii
polyol
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KR1019850001482A
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KR930004364B1 (ko
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치에 창 유진유
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존 제이 헤이간
아메리칸 사이아나밋드 캄파니
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Publication of KR930004364B1 publication Critical patent/KR930004364B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/06—Catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
    • C08G18/163—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C08G18/7628—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2120/00—Compositions for reaction injection moulding processes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

폴리우레탄 조성물용 촉매 시스템
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (18)

  1. 지방족 히드록실-함유 화합물과 차폐된 지방족 2차 또는 3차이소시아네이트기 함유 화합물 간의 반응을 촉매하며, 하기 (i), (ii) 및 (iii)으로 구성되는 촉매 조성물. (i) 1,8-디아자비시클로(5,4,0)-운데센-7 또는 그외염; (ii) 유기 주석 화합물; 및, 임의적으로 (iii) 유기 납 화합물[(i):(ii):(iii)의 중량비는 각각 약 0.5:1:0 내지 약 2:1:3이다.]
  2. 제1항에 있어서, 성분(i)이 페놀산염인 조성물.
  3. 제1항에 있어서, 성분(ii)가 디카르복실산디알킬주석인 조성물.
  4. 제1항에 있어서, 상기 디카르복실산디알킬주석이 다음과 같은 구조를 갖는 조성물.
    상기식에서, R은 C1-C8알킬이고, R'은 C1-C18알킬이다.
  5. 제4항에 있어서, 상기 디카르복실산디알킬주석이 디라우릴산 디메틸주석 및 디라우릴산디부틸주석으로 부터 선택되는 조성물.
  6. 제1항에 있어서, 성분(iii)이 나프텐산납인 조성물.
  7. 하기 (a),(b) 및 (c)로 구성되는 경화성 조성물, (a) 지방족 히드록실 함유 화합물; (b) 차폐된 지방족 2차 또는 3차 이소시아네이트기를 갖는 화합물; 및 (c) 하기 (i),(ii) 및 (iii)으로 구성되는, 촉매적 유효량의 촉매조성물. (i) 1,8-디아자비시클로(5,4,0)-운덴센-7 또는 그의 염; (ii) 유기 주석 화합물; 및, 임의적으로, (iii) 유기 납화합물, [(i):(ii):(iii)의 중량비는, 각각 약 0.5:1:0 내지 약 2:1:3이다.]
  8. 제7항에 있어서, 성분(a)가 중합체 폴리올로 구성되는 조성물.
  9. 제8항에 있어서, 성분(a)가 지방족 폴리올 또는 지방족폴리아민 폴리올과 결합된 중합체 폴리올로 구성되는 조성물.
  10. 제8항에 있어서, 성분(a)가 폴리에테르 폴리올로 구성되는 조성물.
  11. 제8항에 있어서, 성분(a)가 지방족 폴리올과 결합된 폴리에테르 폴리올로 구성되는 조성물.
  12. 제8항에 있어서, 성분(a)가 하기 구조를 갖는 조성물.
    상기식에서, R1과 R2는 각기 수소 또는 C1-C4알킬기이다.
  13. 제8항에 있어서, 성분(a)가 α,α',α'-테트라메틸-m-크실틸 디이소시아네이트인 조성물.
  14. 반응 혼합물 내에서 지방족 히드록실-함유 화합물과 차폐된 지방족 2차 및/또는 3차 이소시아네이트 화합물과의 반응에 대한 촉매 공정에 있어서, 제1항의 촉매 조성물 약 0.05-약 5중량%를 상기 반응 혼합물 내에 첨가하는 것으로 구성되는 방법.
  15. 제14항에 있어서, 상기 반응 혼합물이 하기 구조의 이소시아네이트 화합물로 구성되는 방법.
    상기식에서 R1과 R2는 각기 수소 또는 C1-C4알킬이다.
  16. 제15항에 있어서, 상기 이소시아네이트 화합물이 α,α,α',α'-테트라메틸-m-크실틸 디이소시아네이트인 방법.
  17. 제14항에 있어서, 상기 지방족 히드록실-함유화합물이 중합체폴리올 또는 폴리에테르 폴리올리거나, 또는 지방족 폴리올 또는 지방족 폴리아민 폴리올과의 결합상태의 것인 방법.
  18. 제14항에 있어서, 상기 촉매 조성물의 성분(i)은 1,8-디아자비시클로(5,4,0)-운데센-7이고; 성분(ii)는 디카르복실산 디알킬주석이며; 성분(iii)이 존재할 경우 이것은 나프텐산납인 방법.
    ※ 참고사항:최초출원 내용에 의하여 공개하는 것임.
KR1019850001482A 1984-03-09 1985-03-08 폴리우레탄 조성물용 촉매시스템 KR930004364B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US588015 1984-03-09
US588,015 1984-03-09
US06/588,015 US4547478A (en) 1984-03-09 1984-03-09 Catalyst systems for polyurethane compositions

Publications (2)

Publication Number Publication Date
KR850006687A true KR850006687A (ko) 1985-10-16
KR930004364B1 KR930004364B1 (ko) 1993-05-26

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KR1019850001482A KR930004364B1 (ko) 1984-03-09 1985-03-08 폴리우레탄 조성물용 촉매시스템

Country Status (8)

Country Link
US (2) US4547478A (ko)
EP (1) EP0154180B1 (ko)
JP (1) JPS60190411A (ko)
KR (1) KR930004364B1 (ko)
AT (1) ATE88199T1 (ko)
CA (1) CA1262595A (ko)
DE (1) DE3587254T2 (ko)
ES (1) ES8606434A1 (ko)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3326566A1 (de) * 1983-07-22 1985-01-31 Bayer Ag, 5090 Leverkusen Reversibel blockierte katalysatoren enthaltende polyisocyanat-zubereitungen, ein verfahren zu ihrer herstellung, ihre verwendung zur herstellung von polyurethankunststoffen, sowie anlagerungsprodukte von sulfonylisocyanaten an katalysatoren mit zinn (ii)- bzw. zinn (iv)-carboxylat-struktur
US4601995A (en) * 1985-11-04 1986-07-22 Ashland Oil, Inc. Organo tin catalysts modified with bicyclic amide acetals
JPS62132913A (ja) * 1985-12-05 1987-06-16 Inoue Mtp Co Ltd 光で変色しない無色透明なウレタン樹脂の製造方法
US4663302A (en) * 1986-10-01 1987-05-05 Ashland Oil Bicyclic amide acetal modified catalysts for polyurethane polymer formation
JPS6416619A (en) * 1987-07-11 1989-01-20 Nippon Polyurethane Kogyo Kk Manufacture of polyurethane composite
US5536529A (en) * 1989-05-11 1996-07-16 Borden, Inc. Ultraviolet radiation-curable coatings for optical fibers and optical fibers coated therewith
US5352712A (en) * 1989-05-11 1994-10-04 Borden, Inc. Ultraviolet radiation-curable coatings for optical fibers
CA1321671C (en) * 1989-05-11 1993-08-24 Paul J. Shustack Ultraviolet radiation-curable coatings for optical fibers and optical fibers coated therewith
US5070110A (en) * 1989-08-25 1991-12-03 The Dow Chemical Company Blends of alkylene glycols and relatively high equivalent weight active hydrogen compounds containing multipurpose additives
US5057543A (en) * 1989-08-25 1991-10-15 The Dow Chemical Company Blends of alkylene glycols and relatively high equivalent weight active hydrogen compounds containing additives
US4981877A (en) * 1989-08-25 1991-01-01 The Dow Chemical Company Blends of alkylene glycols and relatively high equivalent weight active hydrogen compounds containing multipurpose additives
US5171818A (en) * 1990-03-23 1992-12-15 Bruce Wilson Sprayable aliphatic polyurea-polyurethane coating compositions and methods
US5212209A (en) * 1991-11-18 1993-05-18 The Dow Chemical Company Compatibilized internal mold release composition for preparations of foamed and fiber-reinforced polymeric articles
EP0672072B1 (en) * 1993-09-22 1998-08-05 Ashland Oil, Inc. Polyurethane reaction system having a blocked catalyst combination
US5502150A (en) * 1994-06-29 1996-03-26 Bayer Corporation Linear HDI urethane prepolymers for rim application
US5965685A (en) * 1998-01-14 1999-10-12 Reichhold Chemicals, Inc. Rapid curing aliphatic hot melt adhesive
US20020068808A1 (en) * 2000-10-13 2002-06-06 Hiroyuki Kometani Catalyst for production of a two component polyurethane sealant
US20030212236A1 (en) * 2001-05-01 2003-11-13 Luigi Pellacani Process for producing polyurethane elastomer
US20030044690A1 (en) * 2001-06-27 2003-03-06 Imation Corp. Holographic photopolymer data recording media, method of manufacture and method of holographically reading, recording and storing data
US6743552B2 (en) * 2001-08-07 2004-06-01 Inphase Technologies, Inc. Process and composition for rapid mass production of holographic recording article
CA2489547C (en) * 2002-06-21 2011-08-02 Recticel Micro-cellular or non-cellular light-stable polyurethane material and method for the production thereof
US8258198B2 (en) * 2004-05-28 2012-09-04 Air Products And Chemicals, Inc. Fast demold/extended cream time polyurethane formulations
US20060160977A1 (en) * 2005-01-14 2006-07-20 Jung-Shun Ou Prescription for preparation of non-yellowing polyurethane foam
US20060266472A1 (en) * 2005-05-06 2006-11-30 Kipp Michael D Vacuum bagging methods and systems
WO2007130372A2 (en) * 2006-05-01 2007-11-15 American Consulting Technology & Research Method for extending the useful life of mold type tooling
US20080105997A1 (en) * 2006-10-17 2008-05-08 Ridges Michael D Method for enhancing the sealing potential of formable, disposable tooling materials
US20080106007A1 (en) * 2006-10-17 2008-05-08 Kipp Michael D Resin infusion process utilizing a reusable vacuum bag
US20080131716A1 (en) * 2006-12-04 2008-06-05 American Consulting Technology & Research, Inc. Shrinkable film barrier for mandrel tooling members
EP2335138A4 (en) 2008-08-15 2012-12-19 Qualcomm Inc ENHANCED MULTIPOINT DETECTION

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL6610758A (ko) * 1965-08-09 1967-02-10
DE1720633A1 (de) * 1967-03-15 1971-07-01 Bayer Ag Verfahren zur Herstellung von Polyurethanen
LU74540A1 (ko) * 1976-03-12 1977-09-27
US4078257A (en) * 1976-08-23 1978-03-07 Hewlett-Packard Company Calculator apparatus with electronically alterable key symbols
DE2737671A1 (de) * 1977-08-20 1979-02-22 Bayer Ag Verfahren zur herstellung von schaumstoff-formkoerpern
US4293658A (en) * 1980-05-12 1981-10-06 Abbott Laboratories Process for rigid foams of improved friability

Also Published As

Publication number Publication date
EP0154180B1 (en) 1993-04-14
JPH0562610B2 (ko) 1993-09-08
KR930004364B1 (ko) 1993-05-26
US4547478A (en) 1985-10-15
EP0154180A3 (en) 1986-10-01
ES541095A0 (es) 1986-04-16
US4598103A (en) 1986-07-01
EP0154180A2 (en) 1985-09-11
ATE88199T1 (de) 1993-04-15
ES8606434A1 (es) 1986-04-16
CA1262595A (en) 1989-10-31
DE3587254T2 (de) 1993-11-25
DE3587254D1 (de) 1993-05-19
JPS60190411A (ja) 1985-09-27

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