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KR840001232A - Electroplating method - Google Patents

Electroplating method Download PDF

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Publication number
KR840001232A
KR840001232A KR1019820003772A KR820003772A KR840001232A KR 840001232 A KR840001232 A KR 840001232A KR 1019820003772 A KR1019820003772 A KR 1019820003772A KR 820003772 A KR820003772 A KR 820003772A KR 840001232 A KR840001232 A KR 840001232A
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KR
South Korea
Prior art keywords
zinc
nickel
anode
bath
cathode
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KR1019820003772A
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Korean (ko)
Inventor
마크 매킨티어 죤
Original Assignee
리차드 고든 워터맨
더 다우 케미칼 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by 리차드 고든 워터맨, 더 다우 케미칼 캄파니 filed Critical 리차드 고든 워터맨
Publication of KR840001232A publication Critical patent/KR840001232A/en

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/56Electroplating: Baths therefor from solutions of alloys

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

내용 없음No content

Description

전기 도금 방법Electroplating method

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (16)

니켈과 아연이온을 포함한 조 내에서 전기 전도성 기판에 니켈-아연 합금 코팅물을 전기도금하고, 코팅물로 부터 거의 모든 아연을 제거시킴으로서 코팅된 금속부품을 제조하는 방법에 있어서, 니켈 양극 세트의 투영된 표며적에 대한 아연양극세트의 기판을 향해 투영된 전체 표면적의 비가 약 2 : 1인, 니켈양극세트와 아연양극세트로부터 니켈과 아연이온을 조에 공급하고, 각 양극세트에 있어서, 대략 같은 전류밀도로 개개의 양극을 조작함으로서 니켈 0.75내지 1.25몰 농도와 아연 0.75내지 1.25몰 농도로 조의 농도를 유지시키며, 60내지 70중량%아연과 30내지 40중량%의 니켈로 이루어진 코팅물을 5내지 100마이크론의 두께로 코팅될 수 있는 충분한 전류밀도에서 몇시간동안 기판에 전기도금시킴을 특징으로 하는 코팅된 금속부품의 제작방법.A method of manufacturing a coated metal part by electroplating a nickel-zinc alloy coating on an electrically conductive substrate in a bath containing nickel and zinc ions and removing almost all zinc from the coating, the projection of the nickel anode set. The nickel and zinc ions were supplied to the bath from the nickel anode set and the zinc anode set having a ratio of the total surface area projected toward the substrate of the zinc anode set to the substrate on the basis of the set of targets. By operating the individual anodes, the bath is maintained at a concentration of 0.75 to 1.25 moles of nickel and 0.75 to 1.25 moles of zinc, and a coating of 60 to 70% by weight zinc and 30 to 40% by weight of nickel is coated in a range of 5 to 100 microns. A method of manufacturing a coated metal part, comprising electroplating the substrate for several hours at a sufficient current density that can be coated to a thickness of. 제1항에 있어서, 조 내의 아연이온 농도와 니켈이온 농도의 비가 2 : 1내지 1 : 2인 방법.The method according to claim 1, wherein the ratio of zinc ion concentration to nickel ion concentration in the bath is from 2: 1 to 1: 2. 제2항에 있어서, 조 내의 니켈이온농도와 아연이온 농도의 비가 약 1 : 1인 방법.The method of claim 2 wherein the ratio of nickel ion concentration to zinc ion concentration in the bath is about 1: 1. 제1항, 2항 또는 3항에 있어서, 각 양극의 전류밀도가 0.1내지 2amp/cm2(0.0155내지 0.31cmamp/cm2)인 방법.Claim 1 wherein, in the 2 or 3 wherein the current density of each of the positive electrode from 0.1 to 2 amp/cm 2 (0.0155 to 0.31cmamp / cm 2) methods. 제4항에 있어서, 전류밀도가 약 0.5amp/in2(0.0775amp/cm2)인 방법.The method of claim 4, wherein the current density is about 0.5 amp / in 2 (0.0775 amp / cm 2 ). 제1항 내지 5항중의 어느 하나에 있어서, 니켈-아연 합금 코팅물의 두께가 5내지 100마이크론인 방법.The method according to any one of claims 1 to 5, wherein the nickel-zinc alloy coating has a thickness of 5 to 100 microns. 제6항에 있어서, 니켈-아연 코팅물의 두께가 30내지 50마이크론인 방법.The method of claim 6, wherein the nickel-zinc coating has a thickness of 30 to 50 microns. 제1항 내지 7항중의 어느 하나에 있어서, 코팅물이 약 66중량%의 아연과 약 34중량%의 니켈을 함유함을 특징으로 하는 방법.8. The method of any one of claims 1 to 7, wherein the coating contains about 66% zinc and about 34% nickel. 제1항 내지 8항중 어느 하나에 있어서, 조의 온도가 10내지 60℃이고, dH가 2내지 5인 방법.The process according to any one of claims 1 to 8, wherein the bath temperature is 10 to 60 ° C and dH is 2 to 5. 제1항, 2항 또는 3항에 있어서, 조 내의 니켈농도와 아연농도를 약 1몰 농도로 유지하는 방법.The method of claim 1, 2 or 3, wherein the nickel and zinc concentrations in the bath are maintained at about 1 molar concentration. 제1항 내지 10항중 어느 하나에 있어서, 알칼리 용액으로 코팅된 기판을 처리함으로서 아연을 제거시키는 방법.The method according to claim 1, wherein the zinc is removed by treating the substrate coated with an alkaline solution. 제1항 내지 11항중의 어느 하나에 있어서, 니켈양극 세트중의 니켈 양극의 수가 아연양극세트중의 아연 양극수의 1/2인 방법.The method according to any one of claims 1 to 11, wherein the number of nickel anodes in the nickel anode set is 1/2 of the number of zinc anodes in the zinc anode set. 제1항 내지 12항중의 어느 한 방법으로 제조한 물품.An article made by the method of claim 1. 음극, 근본적으로 니켈로 이루어진 첫번째 양극세트 및 음극과 대하는 첫번째 양극세트의 표면적보다 약 2배 정도 큰 음극과 대하는 표면적을 갖는 근본적으로 아연으로 이루어진 2번째 양극세트로 된 2개의 양극세트, 각 양극이 각각 다른 양극의 전류밀도와 대략 같은 전류밀도를 갖도록 하는 수준으로 각 양극세트내의 각 양극에 전류를 공급하는 장치, 10내지 60℃의 온도로 조를 유지시키는 장치 및 2내지 5의 pH로 조를 조절하는 장치로 이루어진 코팅된 금속부품 제작용 전기도금장치.Two anode sets consisting of a cathode, essentially a first set of nickel, and a second set of anodes essentially of zinc with a surface area that is approximately two times larger than the surface of the first set of anodes. A device for supplying current to each anode in each set of anodes at a level such that the current density is approximately equal to that of the other anodes, a device for maintaining the bath at a temperature of 10 to 60 ° C, and a tank at a pH of 2 to 5 Electroplating apparatus for manufacturing coated metal parts consisting of adjusting devices. 음극으로 제13항의 물품을 사용함을 특징으로 하는 양극, 음극 및 양극과 음극사이에 위치한 분리기 요소로 이루어진 염소와 가성화물 제조용 전해조.An electrolytic cell for producing chlorine and caustic, comprising an anode, a cathode and a separator element positioned between the anode and the cathode, characterized by using the article of claim 13 as a cathode. 음극으로 제13항의 물품을 사용함을 특징으로 하는 양극, 음극 및 양극과 음극사이에 위치한 분리기 요소로 이루어진 물의 전해용 전해조.An electrolytic cell for electrolysis of water, comprising an anode, a cathode, and a separator element located between the anode and the cathode, characterized by using the article of claim 13 as a cathode. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019820003772A 1981-05-26 1982-08-23 Electroplating method KR840001232A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US26685481A 1981-05-26 1981-05-26
US266,854 1988-11-03

Publications (1)

Publication Number Publication Date
KR840001232A true KR840001232A (en) 1984-03-28

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KR1019820003772A KR840001232A (en) 1981-05-26 1982-08-23 Electroplating method

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Patent event code: PA01091R01D

Comment text: Patent Application

Patent event date: 19820823

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Patent event date: 19840131

Patent event code: PE09021S01D

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