KR20230171546A - Instant hair treatment using gold and silver compound complex - Google Patents
Instant hair treatment using gold and silver compound complex Download PDFInfo
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- KR20230171546A KR20230171546A KR1020220071831A KR20220071831A KR20230171546A KR 20230171546 A KR20230171546 A KR 20230171546A KR 1020220071831 A KR1020220071831 A KR 1020220071831A KR 20220071831 A KR20220071831 A KR 20220071831A KR 20230171546 A KR20230171546 A KR 20230171546A
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- hair dye
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- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 229910052737 gold Inorganic materials 0.000 title 1
- 239000010931 gold Substances 0.000 title 1
- 229940100890 silver compound Drugs 0.000 title 1
- 150000003379 silver compounds Chemical class 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 45
- 239000000118 hair dye Substances 0.000 claims abstract description 35
- YPNVIBVEFVRZPJ-UHFFFAOYSA-L silver sulfate Chemical compound [Ag+].[Ag+].[O-]S([O-])(=O)=O YPNVIBVEFVRZPJ-UHFFFAOYSA-L 0.000 claims abstract description 25
- 229910000367 silver sulfate Inorganic materials 0.000 claims abstract description 25
- 239000007864 aqueous solution Substances 0.000 claims abstract description 13
- 239000002253 acid Substances 0.000 claims abstract description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 10
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims description 10
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 5
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 5
- 239000010478 argan oil Substances 0.000 claims description 5
- 229960000541 cetyl alcohol Drugs 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 5
- 229940075529 glyceryl stearate Drugs 0.000 claims description 5
- 229920002545 silicone oil Polymers 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 229920002125 Sokalan® Polymers 0.000 claims description 4
- 229960001631 carbomer Drugs 0.000 claims description 4
- 239000001509 sodium citrate Substances 0.000 claims description 4
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 4
- 239000002562 thickening agent Substances 0.000 claims description 4
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- 235000015165 citric acid Nutrition 0.000 claims description 3
- 229920002674 hyaluronan Polymers 0.000 claims description 3
- 229960003160 hyaluronic acid Drugs 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 claims description 3
- 239000001433 sodium tartrate Substances 0.000 claims description 3
- 229960002167 sodium tartrate Drugs 0.000 claims description 3
- 235000011004 sodium tartrates Nutrition 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- 239000000230 xanthan gum Substances 0.000 claims description 3
- 235000010493 xanthan gum Nutrition 0.000 claims description 3
- 229920001285 xanthan gum Polymers 0.000 claims description 3
- 229940082509 xanthan gum Drugs 0.000 claims description 3
- 238000004043 dyeing Methods 0.000 abstract description 16
- 230000000694 effects Effects 0.000 abstract description 4
- 238000004904 shortening Methods 0.000 abstract description 3
- 229910052709 silver Inorganic materials 0.000 abstract description 2
- 239000004332 silver Substances 0.000 abstract description 2
- 210000003491 skin Anatomy 0.000 abstract 3
- 230000032683 aging Effects 0.000 abstract 1
- 230000001804 emulsifying effect Effects 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 239000010419 fine particle Substances 0.000 abstract 1
- 210000004927 skin cell Anatomy 0.000 abstract 1
- 230000036560 skin regeneration Effects 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 239000002699 waste material Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 10
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 4
- 239000004220 glutamic acid Substances 0.000 description 4
- 235000013922 glutamic acid Nutrition 0.000 description 4
- ZBKIUFWVEIBQRT-UHFFFAOYSA-N gold(1+) Chemical compound [Au+] ZBKIUFWVEIBQRT-UHFFFAOYSA-N 0.000 description 4
- 230000037308 hair color Effects 0.000 description 4
- 239000003638 chemical reducing agent Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000001024 permanent hair color Substances 0.000 description 2
- 239000001026 semi permanent hair color Substances 0.000 description 2
- 239000001027 temporary hair color Substances 0.000 description 2
- 229960004418 trolamine Drugs 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 description 1
- 230000003700 hair damage Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000344 non-irritating Toxicity 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/591—Mixtures of compounds not provided for by any of the codes A61K2800/592 - A61K2800/596
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
Description
본 발명은 염모제 조성물에 관한 것으로, 보다 상세하게는 순금 콜로이드와 황산은을 복합하여 사용하면 가시광선 하에서 모발의 염색시간을 단축시킴과 동시에 모발에 대한 염착력을 높일 수 있는 반영구적인 1제형 즉각적 염모제 조성물에 관한 것이다.The present invention relates to a hair dye composition, and more specifically, to a semi-permanent one-formulation instant hair dye composition that can shorten the dyeing time of hair under visible light and increase dyeing power to hair by using a combination of pure gold colloid and silver sulfate. It relates to composition.
염모제는 일시염모제, 반영구 염모제 또는 영구 염모제로 분류된다. 일시적으로 착색하는 일시염모제는 사용이 편리하지만, 염색 지속성이 낮다. 염색 지속성이 높은 반영구염모제 또는 영구염모제는 1제인 염모제와 2제인 산화제를 따로 보관하였다가 염색시에 1 및 2제를 혼합하여 사용하는 것이 보편화되어 있다. 그러나, 염모제의 안정성을 이유로 이 두 개의 성분을 따로 보관하고 염색시 혼합하여 사용해야 하는 번거로운 단점이 있다. 이를 해결하기 위하여 1제만으로 구성된 황산은(silver sulfate)과 구연산을 기본 조성물로 하는 염모제가 개발된 바 있는데, 이러한 염모제는 그 자체로만은 빛에 의한 감응도가 떨어져 약하게 염색이 되고, 모발 침투력이 약해 모발에 대한 염착력이 낮은 단점이 있다. Hair dyes are classified as temporary hair dyes, semi-permanent hair dyes, or permanent hair dyes. Temporary hair dyes that temporarily color hair are convenient to use, but have low dyeing durability. For semi-permanent hair dyes or permanent hair dyes with high dyeing sustainability, it is common to store the first hair dye and the second agent, the oxidizing agent, separately and then mix the first and second agents when dyeing. However, due to the stability of the hair dye, there is a cumbersome disadvantage in that these two ingredients must be stored separately and mixed when dyeing. In order to solve this problem, a hair dye was developed based on silver sulfate and citric acid, which consists of only one agent. These hair dyes by themselves have low sensitivity to light, dye the hair weakly, and have poor penetration into the hair. It has the disadvantage of low dyeing power to hair.
따라서 가시광선 하에서 연한 갈색에서부터 흑갈색까지 다양한 색을 나타내면서 빠르고 염착력이 우수한 반영구적인 즉각적 염모제의 개발이 필요한 실정이다.Therefore, there is a need to develop a semi-permanent instant hair dye that exhibits a variety of colors from light brown to dark brown under visible light and has fast and excellent dyeing ability.
본 발명에서는 가시광선 하에서 환원제 역할을 할 수 있는 순금 콜로이드 수용액에 황산은을 혼합되어진 순금 콜로이드와 황산은의 복합체가 연한 갈색에서부터 흑갈색까지 다양한 색의 은 입자로 변환되어 발색되는 시간을 단축시킴과 동시에 모발에 대한 염착력을 높일 수 있고, 자극이 없는 안전한 반영구적인 1제형 즉각적 염모제 조성물을 제공하고자 한다. In the present invention, a complex of pure gold colloid and silver sulfate mixed with a pure gold colloid aqueous solution that can act as a reducing agent under visible light is converted into silver particles of various colors from light brown to dark brown, thereby shortening the time for color development. The aim is to provide a safe, semi-permanent, one-component instant hair dye composition that can increase dyeing power to hair and is non-irritating.
본 발명에서는 가시광선 하에서 환원제 역할을 할 수 있는 순금 콜로이드 수용액에 황산은을 혼합하여 용해시킨 순금 콜로이드와 황산은의 복합체를 포함하는 것을 특징으로 하는 즉각적 염모제 조성물을 제공하여 모발의 염색 시간을 단축시킴과 동시에 모발에 대한 염착력을 높일 뿐 만 아니라, 모발 손상, 냄새 및 두피 자극이 없고, 값 비싼 원료인 황산은을 적게 사용하여 원가를 줄일 수 있는 반영구적인 1제형 즉각적 염모제의 제조방법을 제공함으로써 기존 제품의 문제점을 해결할 수 있다. The present invention provides an instant hair dye composition comprising a complex of pure gold colloid and silver sulfate dissolved by mixing silver sulfate in an aqueous solution of pure gold colloid that can act as a reducing agent under visible light, thereby shortening the hair dyeing time. At the same time, it provides a manufacturing method for a semi-permanent one-component instant hair dye that not only increases the dyeing power to the hair, but also has no hair damage, odor, or scalp irritation, and reduces costs by using less silver sulfate, an expensive raw material. Problems with existing products can be solved.
이에 본 발명은 "순금 콜로이드 수용액에 황산은(silver sulfate) 총 중량 대비 0.2~0.6 중량%을 첨가하여 40~70℃에서 용해시킨 순금 콜로이드와 황산은의 복합체를 포함하는 것을 특징으로 하는 즉각적 염모제 조성물과,Accordingly, the present invention is an instant hair dye composition comprising a complex of pure gold colloid and silver sulfate dissolved at 40 to 70 ° C by adding 0.2 to 0.6% by weight of silver sulfate relative to the total weight of silver sulfate in an aqueous solution of pure gold colloid. class,
상기 조성물에 총 중량 대비 산조절제로서 글루탐산, 주석산, 구연산, 락틱산 중 1종 이상을 0.1~0.9 중량% 추가하는 것을 특징으로 하는 즉각적 염모제 조성물과, An immediate hair dye composition characterized by adding 0.1 to 0.9% by weight of one or more of glutamic acid, tartaric acid, citric acid, and lactic acid as an acid regulator relative to the total weight of the composition,
상기 조성물에 안정제로서 주석산나트륨 또는 구연산나트륨을 0.1~1.9 중량%, 점증제로서 카보머 또는 잔탄검 0.3~1.5 중량%를 더 추가하는 것을 특징으로 하는 즉각적 염모제의 조성물과,A composition of instant hair dye, characterized in that 0.1 to 1.9% by weight of sodium tartrate or sodium citrate as a stabilizer and 0.3 to 1.5% by weight of carbomer or xanthan gum as a thickener are added to the composition,
또한, 상기 조성물에 제형제로서 하이루론산, 트리에탄올아민, 글리세릴스테아레이트, PEG, 아르간오일, 실리콘오일, 세틸알코올, 왁스, 부틸렌글리콜, 글리세린 중에서 1종 이상을 더 추가하는 것을 특징으로 하는 즉각적 염모제의 조성물"을 제공함으로서 상기의 목적을 해결할 수 있다.In addition, one or more of hyaluronic acid, triethanolamine, glyceryl stearate, PEG, argan oil, silicone oil, cetyl alcohol, wax, butylene glycol, and glycerin is added as a formulation to the composition. The above objective can be solved by providing a “hair dye composition.”
본 발명의 순금 콜로이드와 황산은의 복합체를 포함하는 즉각적 염모제 조성물은 가시광선 하에서 발색이 빠를 뿐 아니라, 모발에 깊숙이 침투하므로 모발에 대한 염착력을 높일 수 있고, 혼합된 황산은의 농도에 따라서 연한 갈색에서부터 흑갈색까지 반영구적인 다양한 색의 모발을 제공할 수 있는 효과가 있다.The instant hair dye composition containing a complex of pure gold colloid and silver sulfate of the present invention not only develops color quickly under visible light, but also penetrates deeply into the hair, thereby increasing the dyeing power to the hair, and depending on the concentration of mixed silver sulfate, it can increase the dyeing power of the hair. It has the effect of providing semi-permanent hair of various colors, from brown to dark brown.
본 명세서에 개시되어 있는 본 발명에 따른 반영구적인 1제형 즉각적 염모제의 조성물에 대해 설명한다. 하기 조성물에만 한정되는 것은 아니며, 필요에 따라 각 공정의 단계가 변형되거나 또는 선택적으로 혼용되어 수행될 수 있다. The composition of the semi-permanent one-part immediate hair dye according to the present invention disclosed herein will be described. It is not limited to the composition below, and the steps of each process may be modified or optionally mixed as needed.
본 발명에서의 즉각적 염모제 조성물인 순금 콜로이드 수용액는 정제수 850g에 덱스트린 1g을 넣고 5분 동안 교반한 후에 염화금이 1 중량% 함유된 수용액 10g를 넣고 교반하면서 90~100℃까지 가열하여 혼합액 생성한 다음, 상기 생성된 혼합액을 90~100℃로 유지하면서 소듐카보네이트가 5 중량% 함유된 수용액 1g을 혼합한 후, 상기 혼합된 용액이 붉은색으로 될 때까지 교반하여 25~60nm 입자크기 100ppm 농도로 제조한다. The pure gold colloidal aqueous solution, which is an instant hair dye composition in the present invention, is prepared by adding 1 g of dextrin to 850 g of purified water and stirring for 5 minutes, then adding 10 g of an aqueous solution containing 1% by weight of gold chloride and heating to 90-100°C while stirring to produce a mixed solution. While maintaining the resulting mixed solution at 90-100°C, 1g of an aqueous solution containing 5% by weight of sodium carbonate is mixed, and the mixed solution is stirred until it turns red to prepare a particle size of 25-60nm and a concentration of 100ppm.
본 발명에서는 가시광선 하에서 환원제 역할을 하는 순금 콜로이드 수용액에 황산은을 혼합하여 용해시킨 순금 콜로이드와 황산은의 복합체를 포함하는 것을 특징으로 하는 즉각적 염모제 조성물을 제공한다.The present invention provides an instant hair dye composition comprising a complex of pure gold colloid and silver sulfate dissolved by mixing silver sulfate in an aqueous solution of pure gold colloid that acts as a reducing agent under visible light.
이에 본 발명은 "순금 콜로이드 수용액에 황산은(silver sulfate) 총 중량 대비 0.2~0.6 중량%을 첨가하여 40~70℃에서 용해시킨 순금 콜로이드와 황산은의 복합체를 포함하는 것을 특징으로 하는 즉각적 염모제 조성물과,Accordingly, the present invention is an instant hair dye composition comprising a complex of pure gold colloid and silver sulfate dissolved at 40 to 70 ° C by adding 0.2 to 0.6% by weight of silver sulfate relative to the total weight of silver sulfate in an aqueous solution of pure gold colloid. class,
상기 조성물에 총 중량 대비 산조절제로서 글루탐산, 주석산, 구연산, 락틱산 중 1종 이상을 0.1~0.9 중량% 추가하는 것을 특징으로 하는 즉각적 염모제 조성물과, An immediate hair dye composition characterized by adding 0.1 to 0.9% by weight of one or more of glutamic acid, tartaric acid, citric acid, and lactic acid as an acid regulator relative to the total weight of the composition,
상기 조성물에 안정제로서 주석산나트륨 또는 구연산나트륨을 0.1~1.9 중량%, 점증제로서 카보머 또는 잔탄검 0.3~1.5 중량%를 더 추가하는 것을 특징으로 하는 즉각적 염모제의 조성물과,A composition of instant hair dye, characterized in that 0.1 to 1.9% by weight of sodium tartrate or sodium citrate as a stabilizer and 0.3 to 1.5% by weight of carbomer or xanthan gum as a thickener are added to the composition,
또한, 상기 즉각적 염모제 조성물은 하이루론산, 트리에탄올아민, 글리세릴스테아레이트, PEG, 아르간오일, 실리콘오일, 세틸알코올, 왁스, 부틸렌글리콜, 글리세린 중에서 1종 이상을 더 추가하는 것을 특징으로 하는 즉각적 염모제의 조성물"을 제공함으로서 상기의 목적을 달성할 수 있다. In addition, the instant hair dye composition is an instant hair dye composition characterized in that one or more of hyaluronic acid, triethanolamine, glyceryl stearate, PEG, argan oil, silicone oil, cetyl alcohol, wax, butylene glycol, and glycerin is added. The above purpose can be achieved by providing a “composition of”.
<실시예 1><Example 1>
1. 순금 콜로이드 수용액 80㎖에 황산은 0.4g를 첨가하여 70℃에서 교반하면서 용해한다. 1. Add 0.4 g of silver sulfate to 80 ml of pure gold colloidal aqueous solution and dissolve while stirring at 70°C.
2. 상기 황산은이 녹아 있는 용액을 70℃로 유지하면서, 부틸렌글리콜 2g, 글리세린 4g을 첨가하고 호모믹서기를 교반한다. 2. While maintaining the solution containing the silver sulfate dissolved at 70°C, add 2 g of butylene glycol and 4 g of glycerin and stir with a homomixer.
3. 상기 혼합액에 70℃로 유지하면서, 글리세릴스테아레이트 2g, 실리콘오일 4g, 아르간오일 1g, 세틸알코올 4.5g, 왁스 1g 첨가하고 호모믹서기를 교반한 후에 실온으로 냉각하여 즉각적 염모제의 조성물을 제조하였다. 3. While maintaining the temperature at 70°C, add 2g of glyceryl stearate, 4g of silicone oil, 1g of argan oil, 4.5g of cetyl alcohol, and 1g of wax, stir in a homomixer, and cool to room temperature to prepare an instant hair dye composition. did.
<실시예 2><Example 2>
1. 순금 콜로이드 수용액 80㎖에 글루탐산 0.5g과 황산은 0.4g를 첨가하여 70℃에서 교반하면서 용해한다. 1. Add 0.5 g of glutamic acid and 0.4 g of silver sulfate to 80 ml of pure gold colloidal aqueous solution and dissolve while stirring at 70°C.
2. 상기 황산은이 녹아 있는 용액을 70℃로 유지하면서, 부틸렌글리콜 2g, 글리세린 4g을 첨가하고 호모믹서기를 교반한다. 2. While maintaining the solution containing the silver sulfate dissolved at 70°C, add 2 g of butylene glycol and 4 g of glycerin and stir with a homomixer.
3. 상기 혼합액에 70℃로 유지하면서, 글리세릴스테아레이트 2g, 실리콘오일 4g, 아르간오일 1g, 세틸알코올 4.5g, 왁스 1g 첨가하고 호모믹서기를 교반한 후에 실온으로 냉각하여 즉각적 염모제의 조성물을 제조하였다.3. While maintaining the temperature at 70°C, add 2g of glyceryl stearate, 4g of silicone oil, 1g of argan oil, 4.5g of cetyl alcohol, and 1g of wax, stir in a homomixer, and cool to room temperature to prepare an instant hair dye composition. did.
<실시예 3><Example 3>
1. 순금 콜로이드 수용액 80㎖에 글루탐산 0.5g과 황산은 0.4g를 첨가하여 70℃에서 교반하면서 용해한다.1. Add 0.5 g of glutamic acid and 0.4 g of silver sulfate to 80 ml of pure gold colloidal aqueous solution and dissolve while stirring at 70°C.
2. 상기 황산은이 녹아 있는 용액을 70℃로 유지하면서, 구연산나트륨을 0.8 중량% 첨가하고 10분간 호모믹서기를 교반한다. 2. While maintaining the solution containing the silver sulfate dissolved at 70°C, add 0.8% by weight of sodium citrate and stir with a homomixer for 10 minutes.
3. 상기 혼합액에 70℃로 유지하면서 점증제로서 카보머 1.2 중량%를 첨가하고 호모믹서기를 10분간 교반한 후에 실온으로 냉각하여 즉각적 염모제의 조성물을 제조하였다. 3. While maintaining the temperature at 70°C, 1.2% by weight of carbomer was added as a thickener to the mixture, stirred in a homomixer for 10 minutes, and then cooled to room temperature to prepare an instant hair dye composition.
상기 실시예들에 따라서 제조된 염모제 조성물들은 크림 형태이며 모발에 바른 후에 자연광에 노출 1분 후 모발의 색상이 변하기 시작하여 10분 후에는 자연스러운 흑갈색으로 변색되었다. The hair dye compositions prepared according to the above examples were in a cream form, and after being applied to the hair, the color of the hair began to change 1 minute after exposure to natural light, and after 10 minutes, the hair color changed to a natural dark brown color.
하기 표 1에서는 실시예에서 얻은 염모제 조성물들의 발색 10분 후 모발색 및 세탁견뢰도를 비교하여 나타내었다. Table 1 below shows a comparison of hair color and washing fastness of the hair dye compositions obtained in Examples 10 minutes after color development.
상기 표 1에 나타낸 바와 같이, 세탁 견뢰도(염착력)가 우수하고 모발의 색상도 10분 안에 흑갈색으로 얻어졌다. 따라서 본 발명의 조성물은 가시광선 하에서 발색이 빠를 뿐 아니라, 모발에 깊숙이 침투하므로 모발에 대한 염착력을 높일 수 있는 효과가 있음을 보여준다. As shown in Table 1, washing fastness (dyeing power) was excellent and the hair color was obtained as dark brown within 10 minutes. Therefore, the composition of the present invention not only has rapid color development under visible light, but also penetrates deeply into the hair, showing that it has the effect of increasing dyeing power to the hair.
본 발명의 개념에 따른 실시 예들은 다양한 변경들을 가할 수 있고 여러 가지 형태들을 가질 수 있으므로, 발명자는 그 자신의 발명을 가장 최선의 방법으로 설명하기 위해 용어의 개념을 적절하게 정의할 수 있다는 점에 입각하여, 본 발명의 기술적 사상에 부합하는 의미와 개념으로 해석되어야 한다. 따라서 본 발명의 명세서에 기재된 실시예는 본 발명의 가장 바람직한 실시 예에 불과할 뿐이고, 본 발명의 출원 시점에 있어서 이를 대체할 수 있는 다양한 균등물과 변형예가 가능함을 이해하여야 할 것이다. Since the embodiments according to the concept of the present invention can make various changes and have various forms, the inventor can appropriately define the concept of the term to explain the invention in the best way. Based on this, it should be interpreted with meaning and concept consistent with the technical idea of the present invention. Therefore, it should be understood that the embodiments described in the specification of the present invention are only the most preferred embodiments of the present invention, and that various equivalents and modifications are possible to replace them at the time of filing the application for the present invention.
Claims (4)
An instant hair dye composition comprising a complex of pure gold colloid and silver sulfate dissolved at 40 to 70°C by adding 0.2 to 0.6% by weight of silver sulfate relative to the total weight of the pure gold colloid aqueous solution.
상기 조성물에 총 중량 대비 산조절제로서 히알루론산, 주석산, 구연산, 락틱산 중 1종 이상을 0.1~0.9 중량%를 추가한 것을 특징으로 하는 즉각적 염모제 조성물.
According to paragraph 1 above,
An instant hair dye composition, characterized in that 0.1 to 0.9% by weight of one or more of hyaluronic acid, tartaric acid, citric acid, and lactic acid is added as an acid regulator based on the total weight of the composition.
상기 조성물에 안정제로서 주석산나트륨 또는 구연산나트륨을 0.1~1.9 중량%, 점증제로서 카보머 또는 잔탄검 0.3~1.5 중량%를 추가한 것을 특징으로 하는 즉각적 염모제 조성물.
According to clause 1 or 2 above,
An instant hair dye composition, characterized in that 0.1 to 1.9% by weight of sodium tartrate or sodium citrate as a stabilizer and 0.3 to 1.5% by weight of carbomer or xanthan gum as a thickener are added to the composition.
상기 조성물은 글리세릴스테아레이트, PEG, 아르간오일, 실리콘오일, 세틸알코올, 왁스, 부틸렌글리콜, 글리세린 중에서 1종 이상을 더 추가한 것을 특징으로 하는 즉각적 염모제 조성물.
According to paragraph 1, 2 or 3 above,
The composition is an instant hair dye composition characterized by adding one or more of glyceryl stearate, PEG, argan oil, silicone oil, cetyl alcohol, wax, butylene glycol, and glycerin.
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| KR101103567B1 (en) | 2011-02-23 | 2012-01-06 | 이용권 | Hair dye composition |
| JP2013180981A (en) * | 2012-03-01 | 2013-09-12 | Masato Kurimura | Hair dyeing method and pretreatment agent for hair dyeing |
| KR101438370B1 (en) | 2007-11-28 | 2014-09-05 | (주)아모레퍼시픽 | Composition for the oxidative dyeing of hair |
| KR101534864B1 (en) | 2009-06-30 | 2015-07-08 | 현대자동차주식회사 | Manufacturing method of cylinder liners for vehicles |
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| KR101438370B1 (en) | 2007-11-28 | 2014-09-05 | (주)아모레퍼시픽 | Composition for the oxidative dyeing of hair |
| KR101534864B1 (en) | 2009-06-30 | 2015-07-08 | 현대자동차주식회사 | Manufacturing method of cylinder liners for vehicles |
| KR101103567B1 (en) | 2011-02-23 | 2012-01-06 | 이용권 | Hair dye composition |
| JP2013180981A (en) * | 2012-03-01 | 2013-09-12 | Masato Kurimura | Hair dyeing method and pretreatment agent for hair dyeing |
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