KR20210072270A - Solid aerosol spread agent composition and method for treating agricultural and livestock products using same - Google Patents
Solid aerosol spread agent composition and method for treating agricultural and livestock products using same Download PDFInfo
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- KR20210072270A KR20210072270A KR1020190162365A KR20190162365A KR20210072270A KR 20210072270 A KR20210072270 A KR 20210072270A KR 1020190162365 A KR1020190162365 A KR 1020190162365A KR 20190162365 A KR20190162365 A KR 20190162365A KR 20210072270 A KR20210072270 A KR 20210072270A
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- 239000000203 mixture Substances 0.000 title claims abstract description 52
- 244000144972 livestock Species 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims description 19
- 239000008275 solid aerosol Substances 0.000 title 1
- 239000003595 mist Substances 0.000 claims abstract description 70
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 27
- 239000007787 solid Substances 0.000 claims abstract description 19
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 150000007524 organic acids Chemical class 0.000 claims description 15
- 239000004202 carbamide Substances 0.000 claims description 14
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 13
- 150000003863 ammonium salts Chemical class 0.000 claims description 12
- 150000002772 monosaccharides Chemical class 0.000 claims description 12
- 238000005507 spraying Methods 0.000 claims description 12
- 239000004094 surface-active agent Substances 0.000 claims description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 10
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 6
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 6
- 239000001099 ammonium carbonate Substances 0.000 claims description 6
- -1 polyoxyethylenenonylphenyl Polymers 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- 235000012501 ammonium carbonate Nutrition 0.000 claims description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 4
- HNSDLXPSAYFUHK-UHFFFAOYSA-N 1,4-bis(2-ethylhexyl) sulfosuccinate Chemical group CCCCC(CC)COC(=O)CC(S(O)(=O)=O)C(=O)OCC(CC)CCCC HNSDLXPSAYFUHK-UHFFFAOYSA-N 0.000 claims description 3
- 235000019270 ammonium chloride Nutrition 0.000 claims description 3
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 3
- 235000015165 citric acid Nutrition 0.000 claims description 3
- 229960000878 docusate sodium Drugs 0.000 claims description 3
- 229960001031 glucose Drugs 0.000 claims description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 2
- LDMOEFOXLIZJOW-UHFFFAOYSA-N 1-dodecanesulfonic acid Chemical compound CCCCCCCCCCCCS(O)(=O)=O LDMOEFOXLIZJOW-UHFFFAOYSA-N 0.000 claims description 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 2
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 2
- GUBGYTABKSRVRQ-DCSYEGIMSA-N Beta-Lactose Chemical compound OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-DCSYEGIMSA-N 0.000 claims description 2
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 2
- 229930091371 Fructose Natural products 0.000 claims description 2
- 239000005715 Fructose Substances 0.000 claims description 2
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 2
- 229920001732 Lignosulfonate Polymers 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 2
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 2
- 229960004977 anhydrous lactose Drugs 0.000 claims description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 235000010216 calcium carbonate Nutrition 0.000 claims description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 2
- 239000001095 magnesium carbonate Substances 0.000 claims description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 2
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- 239000001630 malic acid Substances 0.000 claims description 2
- 235000011090 malic acid Nutrition 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 2
- 239000011736 potassium bicarbonate Substances 0.000 claims description 2
- 229910000028 potassium bicarbonate Inorganic materials 0.000 claims description 2
- 235000015497 potassium bicarbonate Nutrition 0.000 claims description 2
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims description 2
- 229940086066 potassium hydrogencarbonate Drugs 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- 235000017550 sodium carbonate Nutrition 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 238000009792 diffusion process Methods 0.000 abstract description 9
- 239000002994 raw material Substances 0.000 abstract description 5
- 230000000052 comparative effect Effects 0.000 description 17
- 239000000047 product Substances 0.000 description 10
- 239000002917 insecticide Substances 0.000 description 7
- 241000238631 Hexapoda Species 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000004009 herbicide Substances 0.000 description 6
- 241000607479 Yersinia pestis Species 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 4
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 4
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 4
- 239000000645 desinfectant Substances 0.000 description 4
- 239000000575 pesticide Substances 0.000 description 4
- 238000003892 spreading Methods 0.000 description 4
- 230000007480 spreading Effects 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000003337 fertilizer Substances 0.000 description 3
- 230000002401 inhibitory effect Effects 0.000 description 3
- 230000000749 insecticidal effect Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 240000007124 Brassica oleracea Species 0.000 description 2
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 2
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 2
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000003225 biodiesel Substances 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 230000002363 herbicidal effect Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000035899 viability Effects 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 1
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 241000500437 Plutella xylostella Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- YKBZOVFACRVRJN-UHFFFAOYSA-N dinotefuran Chemical compound [O-][N+](=O)\N=C(/NC)NCC1CCOC1 YKBZOVFACRVRJN-UHFFFAOYSA-N 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M11/00—Special adaptations or arrangements of combined liquid- and powder-spraying apparatus for purposes covered by this subclass
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/18—Vapour or smoke emitting compositions with delayed or sustained release
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Toxicology (AREA)
- Dentistry (AREA)
- Insects & Arthropods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
본 발명은 살충제, 살균제, 제초제 등을 가열 연무 방법으로 살포시 사용되는 고상의 연무확산제 조성물 및 이를 이용한 농축산물 처리방법에 관한 것이다.The present invention relates to a solid mist diffuser composition used when spraying pesticides, fungicides, herbicides, etc. by a heating mist method, and a method for treating agricultural and livestock products using the same.
종래 방역 및 농축산용 살충제, 살균제, 제초제 등의 처리제 살포방법에는 물 분무 방법, 가열 연무 방법 등이 보편적으로 사용된다.Conventional methods of spraying pesticides, sterilizers, herbicides, etc. for quarantine and livestock production, water spray method, heat mist method, etc. are commonly used.
물 분무 방법은 처리제를 물로 희석한 희석액을 분무기로 분사하는 방법으로 가장 오랫동안 사용되었으나, 넓은 면적에 대한 살포 효율이 떨어지고 처리제 희석시 지나치게 많은 양의 물을 사용한다는 단점이 있다. The water spray method has been used for the longest time as a method of spraying a diluted solution obtained by diluting the treatment agent with water, but has a disadvantage in that the spraying efficiency over a large area is low and an excessive amount of water is used when diluting the treatment agent.
이에 최근에는 가열 연막기를 이용한 가열 연무 방법이 주로 사용되고 있다. For this reason, recently, a heated fogging method using a heated smoke machine is mainly used.
가열 연무 방법은 처리제의 희석 용제로 등유, 경유 등의 광물유를 사용하거나, 또는 물을 사용할 수 있다. In the heating mist method, mineral oil such as kerosene or light oil may be used as a diluent solvent for the treatment agent, or water may be used.
광물유를 사용하여 분무하는 경우 분사 입자가 0.1~10 ㎛ 정도로 작아, 먼곳까지 살포가 가능하고 좁은 틈새까지 용이하게 분포되는 장점이 있다. 그러나, 용제 특유의 불쾌한 냄새가 발생하고 환경을 오염시킨다는 단점이 있다. In the case of spraying using mineral oil, the spray particles are as small as 0.1 to 10 ㎛, so it can be sprayed far away and has the advantage of being easily distributed to narrow gaps. However, there is a disadvantage that an unpleasant odor peculiar to the solvent is generated and pollutes the environment.
최근에는 광물유 대신 바이오디젤을 사용하기도 하지만 이 경우에도 바이오디젤 특유의 콩기름 냄새로 인하여 사용이 기피되고 있는 실정이다(대한민국 등록특허 제0930653호, 제1085661호 및 제1869197호). Recently, biodiesel is used instead of mineral oil, but even in this case, the use of biodiesel is avoided due to the peculiar smell of soybean oil (Republic of Korea Patent Nos. 0930653, 1085661, and 1869197).
한편, 연무확산제와 같은 보조제를 사용하여 살포 효율을 높이는 기술도 알려져 있다. 그러나, 현재까지 알려진 연무확산제 대부분이 증량제로 물을 포함하는 액상 형태로서, 운반이나 보관 중에 누액으로 인한 환경 오염의 문제가 있다. 또한, 연무확산제를 이루는 구성 성분들이 인체나 가축에 해로워 살포시 인축에 닿지 않도록 주의해야 한다. On the other hand, a technique for increasing the spraying efficiency by using an auxiliary agent such as a mist spreading agent is also known. However, most of the mist diffusion agents known to date are in liquid form containing water as an extender, and there is a problem of environmental contamination due to leakage during transportation or storage. In addition, the components constituting the mist spreading agent are harmful to the human body or livestock, so care must be taken not to touch the livestock when spraying.
본 발명의 목적은 방역 및 농축산용 살충제, 살균제, 제초제 등을 첨가하여 분무 확산시키는 연무확산제로서 운반 및 보관이 용이한 고상으로 제조될 수 있으면서 인축 및 환경에 무해하여 친환경적인 연무확산제 조성물을 제공하고자 한다. An object of the present invention is to provide an eco-friendly mist spreader composition that is harmless to livestock and the environment while being produced in a solid state that is easy to transport and store as a mist spreader that sprays and diffuses pesticides, disinfectants, herbicides, etc. for quarantine and livestock production. would like to provide
상기 목적을 달성하기 위해, 본 발명은 우레아 20 내지 65 중량부; 유기산 10 내지 30 중량부; 탄산염 10 내지 30 중량부; 및 계면활성제 1 내지 10 중량부를 포함하는 고상 연무확산제 조성물을 제공한다.In order to achieve the above object, the present invention is urea 20 to 65 parts by weight; 10 to 30 parts by weight of an organic acid; 10 to 30 parts by weight of carbonate; and 1 to 10 parts by weight of a surfactant.
상기 다른 목적을 달성하기 위해, 본 발명은 상기 고상 연무확산제 조성물을 물과 혼합하여 농축산물에 분무하는 것을 포함하는 농축산물 처리방법을 제공한다.In order to achieve the above other object, the present invention provides a method for treating agricultural and livestock products comprising mixing the solid mist diffuser composition with water and spraying the agricultural and livestock products.
본 발명에 따른 고상 연무확산제 조성물은 인축 및 환경에 무해한 원료들로 이루어져 안전성이 우수하고 친환경적이다. 또한, 고상의 정제 타입으로 제조가능하므로 운반 및 보관이 용이할 뿐만 아니라, 종래 연무확산제에 비해 적은 양을 사용하여도 확산 효율 및 방제 효율이 우수하므로, 농축산물의 생장 및 보호에 도움이 된다. The solid fog diffuser composition according to the present invention is made of raw materials that are harmless to humans and the environment, so it has excellent safety and is environmentally friendly. In addition, since it can be manufactured as a solid tablet type, it is easy to transport and store, and since it has excellent diffusion efficiency and control efficiency even when using a small amount compared to the conventional fog diffuser, it is helpful for the growth and protection of agricultural and livestock products.
본 발명은 이하에 개시된 내용에 한정되는 것이 아니라, 발명의 요지가 변경되지 않는 한 다양한 형태로 변형될 수 있다. The present invention is not limited to the contents disclosed below, and may be modified in various forms as long as the gist of the present invention is not changed.
본 명세서에서 "포함"한다는 것은 특별한 기재가 없는 한 다른 구성요소를 더 포함할 수 있음을 의미한다. 또한, 본 명세서에 기재된 구성성분의 양, 반응 조건 등을 나타내는 모든 숫자 및 표현은 특별한 기재가 없는 한 모든 경우에 "약"이라는 용어로써 수식되는 것으로 이해하여야 한다.In the present specification, "comprising" means that other components may be further included unless otherwise specified. In addition, it should be understood that all numbers and expressions indicating amounts of components, reaction conditions, etc. described herein are modified by the term "about" in all cases unless otherwise specified.
고상 연무확산제 조성물Solid mist diffuser composition
본 발명의 고상 연무확산제 조성물은 다음과 같은 친환경 구성성분들을 포함한다.The solid mist diffuser composition of the present invention includes the following eco-friendly components.
구체적으로, 본 발명의 연무확산제 조성물은 우레아 20 내지 65 중량부, 유기산 10 내지 30 중량부, 탄산염 10 내지 30 중량부 및 계면활성제 1 내지 10 중량부를 포함한다. 또한, 본 발명의 연무확산제 조성물은 암모늄염 및/또는 무수 단당류를 추가로 포함할 수 있다.Specifically, the mist diffuser composition of the present invention comprises 20 to 65 parts by weight of urea, 10 to 30 parts by weight of an organic acid, 10 to 30 parts by weight of carbonate, and 1 to 10 parts by weight of a surfactant. In addition, the mist diffuser composition of the present invention may further include an ammonium salt and/or anhydrous monosaccharides.
먼저, 우레아(urea)는 상기 연무확산제 조성물을 물 및 처리제(살충제, 살균제, 제초제 등)와 혼합하여 분사할 때, 분사 입자의 크기를 1 ㎛ 이하 또는 0.1 내지 1 ㎛로 작게 만들어, 넓은 면적에 고르게 살포될 수 있도록 함으로써 우수한 방제 효과를 제공한다.First, when urea is sprayed by mixing the mist diffuser composition with water and a treatment agent (insecticide, disinfectant, herbicide, etc.), the size of the sprayed particles is made small to 1 μm or less or 0.1 to 1 μm, and a large area It provides an excellent control effect by allowing it to be evenly sprayed on the
우레아는 일반적으로 암모니아 액체와 이산화탄소 액체로부터 대량 생산된다. 우레아는 질소 함량이 높고 땅에서 쉽게 암모니아로 전환되며, 비료로 이용될 만큼 값싸고 친환경적인 물질이다. 또한, 물에 잘 녹는 특성을 가지고 있다. Urea is generally produced in bulk from liquid ammonia and liquid carbon dioxide. Urea has a high nitrogen content, is easily converted to ammonia in the ground, and is inexpensive and environmentally friendly enough to be used as a fertilizer. In addition, it has the property of being easily soluble in water.
본 발명의 조성물은 이러한 우레아를 포함함으로써 넓은 면적에 고르게 살포되어 우수한 방제 효과를 가지면서도 환경을 오염시키지 않고, 나아가 비료로서의 부수적인 효과도 제공할 수 있다. The composition of the present invention is evenly distributed over a large area by including such urea, and does not pollute the environment while having an excellent control effect, and furthermore, it can provide an incidental effect as a fertilizer.
상기 연무확산제 조성물은 상기 우레아를 20 내지 65 중량부, 20 내지 62 중량부, 20 내지 60 중량부, 20 내지 55 중량부, 20 내지 50 중량부 또는 20 내지 47 중량부의 양으로 포함할 수 있다. 상기 범위 내일 때, 가열 연무 시 분무가 용이하고 확산 효율을 보다 향상시킬 수 있다. The mist diffuser composition may include the urea in an amount of 20 to 65 parts by weight, 20 to 62 parts by weight, 20 to 60 parts by weight, 20 to 55 parts by weight, 20 to 50 parts by weight, or 20 to 47 parts by weight. . When it is within the above range, it is easy to spray when heating mist and can further improve the diffusion efficiency.
또한, 본 발명의 연무확산제 조성물은 발포제로서 유기산 및 탄산염을 포함할 수 있다. In addition, the fog diffuser composition of the present invention may include an organic acid and carbonate as a foaming agent.
구체적으로, 상기 유기산은 사과산, 구연산, 주석산, 호박산, 말레산, 프탈산 및 에틸렌디아민테트라아세트산으로 이루어진 군으로부터 선택되는 1종 이상을 포함할 수 있고, 구체적으로 구연산을 포함할 수 있다. 상기 유기산은 발포제의 역할 외에, 병해충 억제 효과를 제공한다. 구체적으로, 상기 유기산은 상기 조성물이 병균이 생육하기 어려운 낮은 pH를 가질 수 있게 하여 해충 기피 및 억제 효과를 제공한다. Specifically, the organic acid may include at least one selected from the group consisting of malic acid, citric acid, tartaric acid, succinic acid, maleic acid, phthalic acid and ethylenediaminetetraacetic acid, and specifically citric acid. In addition to the role of the blowing agent, the organic acid provides an effect of inhibiting pests and diseases. Specifically, the organic acid provides a pest repelling and inhibitory effect by allowing the composition to have a low pH at which germs are difficult to grow.
상기 연무확산제 조성물은 상기 유기산을 10 내지 30 중량부, 10 내지 25 중량부, 10 내지 22 중량부, 15 내지 30 중량부, 15 내지 25 중량부 및 15 내지 22 중량부의 양으로 포함할 수 있다. The mist diffuser composition may include the organic acid in an amount of 10 to 30 parts by weight, 10 to 25 parts by weight, 10 to 22 parts by weight, 15 to 30 parts by weight, 15 to 25 parts by weight, and 15 to 22 parts by weight. .
상기 범위 내일 때, 수(水) 중 발포성(또는 용해도)이 우수하여 가열 연무를 용이하게 한다. 또한, 병해충 억제 효율을 유지할 수 있다. When it is within the above range, foamability (or solubility) in water is excellent to facilitate heating mist. In addition, it is possible to maintain the pest suppression efficiency.
상기 탄산염은 탄산나트륨, 탄산칼슘, 탄산마그네슘, 탄산암모늄, 탄산수소나트륨, 탄산수소칼륨 및 탄산수소암모늄으로 이루어진 군으로부터 선택되는 1종 이상을 포함할 수 있고, 구체적으로 탄산수소나트륨을 포함할 수 있다.The carbonate may include at least one selected from the group consisting of sodium carbonate, calcium carbonate, magnesium carbonate, ammonium carbonate, sodium hydrogen carbonate, potassium hydrogen carbonate and ammonium hydrogen carbonate, and specifically may include sodium hydrogen carbonate. .
상기 연무확산제 조성물은 상기 탄산염을 10 내지 30 중량부, 10 내지 25 중량부, 15 내지 30 중량부 또는 15 내지 25 중량부의 양으로 포함할 수 있다. 상기 범위 내일 때, 수(水) 중 발포성이 우수하여 가열 연무를 용이하게 한다.The mist diffuser composition may include the carbonate in an amount of 10 to 30 parts by weight, 10 to 25 parts by weight, 15 to 30 parts by weight, or 15 to 25 parts by weight. When it is within the above range, it has excellent foamability in water to facilitate heating mist.
본 발명의 연무확산제 조성물은 계면활성제로서 디옥틸설포숙신산염, 나프탈렌설폰산염-포르말린 축합물, 폴리아크릴산염, 리그노설폰산염, 라우릴설폰산염, 폴리알킬나프탈렌설폰산염, 폴리옥시에틸렌노닐페닐 중합체, 폴리옥시에틸렌스티릴페닐 중합체 및 폴리옥시에틸렌-폴리옥시프로필렌으로 이루어진 군으로부터 선택되는 1종 이상을 포함할 수 있고, 구체적으로 디옥틸설포숙신산염을 포함할 수 있다.The mist diffuser composition of the present invention includes dioctylsulfosuccinate, naphthalenesulfonate-formalin condensate, polyacrylate, lignosulfonate, laurylsulfonate, polyalkylnaphthalenesulfonate, polyoxyethylenenonylphenyl as a surfactant. It may include at least one selected from the group consisting of a polymer, polyoxyethylene styrylphenyl polymer, and polyoxyethylene-polyoxypropylene, and specifically may include dioctylsulfosuccinate.
상기 연무확산제 조성물은 상기 계면활성제를 1 내지 10 중량부, 1 내지 8 중량부, 1 내지 5 중량부 또는 1 내지 3 중량부의 양으로 포함할 수 있다. 상기 범위 내일 때, 병해충 억제 효과를 저해하지 않으면서 조성물이 물과 잘 섞일 수 있도록 해준다. The mist diffuser composition may include the surfactant in an amount of 1 to 10 parts by weight, 1 to 8 parts by weight, 1 to 5 parts by weight, or 1 to 3 parts by weight. When within the above range, it allows the composition to be well mixed with water without compromising the effect of inhibiting pests and pests.
이외에도, 본 발명의 연무확산제 조성물은 암모늄염, 무수 단당류 등의 친환경 원료들을 추가로 포함할 수 있다.In addition, the mist diffuser composition of the present invention may further include eco-friendly raw materials such as ammonium salts and anhydrous monosaccharides.
상기 암모늄염 및/또는 무수 단당류는 상기 연무확산제 조성물을 물 및 처리제(살충제, 살균제, 제초제 등)와 혼합하여 분무할 때 처리제의 공기 중 체공 시간을 길게 하여 방제 효율을 보다 향상시킬 수 있다.The ammonium salt and/or anhydrous monosaccharide may increase the airborne time of the treatment agent when spraying by mixing the mist diffusion agent composition with water and a treatment agent (insecticide, disinfectant, herbicide, etc.) to further improve control efficiency.
상기 암모늄염은 탄산암모늄, 황산암모늄, 염화암모늄 및 질산암모늄으로 이루어진 군으로부터 선택되는 1종 이상일 수 있고, 구체적으로 염화암모늄일 수 있다. The ammonium salt may be at least one selected from the group consisting of ammonium carbonate, ammonium sulfate, ammonium chloride and ammonium nitrate, and specifically may be ammonium chloride.
상기 무수 단당류는 무수 포도당, 무수 젖당, 무수 과당 및 무수 만노스로 이루어진 군으로부터 선택되는 1종 이상을 포함할 수 있고, 구체적으로 무수 포도당을 포함할 수 있다.The anhydrous monosaccharide may include at least one selected from the group consisting of anhydrous glucose, anhydrous lactose, anhydrous fructose and anhydrous mannose, and specifically may include anhydrous glucose.
상기 연무확산제 조성물은 상기 암모늄염을 10 내지 30 중량부, 10 내지 20 중량부, 15 내지 30 중량부 또는 15 내지 20 중량부의 양으로 포함할 수 있다. The mist diffuser composition may include the ammonium salt in an amount of 10 to 30 parts by weight, 10 to 20 parts by weight, 15 to 30 parts by weight, or 15 to 20 parts by weight.
상기 연무확산제 조성물은 상기 무수 단당류를 10 내지 30 중량부, 10 내지 20 중량부, 15 내지 30 중량부 또는 15 내지 20 중량부의 양으로 포함할 수 있다.The mist diffuser composition may include the anhydrous monosaccharide in an amount of 10 to 30 parts by weight, 10 to 20 parts by weight, 15 to 30 parts by weight, or 15 to 20 parts by weight.
상기 암모늄염 및 무수 단당류가 상기 범위 내일 때, 처리제의 공기 중 체공 시간을 길게 하여 방제 효율을 보다 향상시킬 수 있다. When the ammonium salt and the anhydrous monosaccharide are within the above range, the airborne time of the treatment agent may be lengthened to further improve the control efficiency.
일 구체예에 따르면, 본 발명의 연무확산제 조성물은 상기 우레아를 20 내지 65 중량부, 상기 유기산을 15 내지 30 중량부, 상기 탄산염을 15 내지 30 중량부 및 상기 계면활성제를 1 내지 5 중량부로 포함할 수 있다.According to one embodiment, the mist diffuser composition of the present invention contains 20 to 65 parts by weight of the urea, 15 to 30 parts by weight of the organic acid, 15 to 30 parts by weight of the carbonate, and 1 to 5 parts by weight of the surfactant. may include
일 구체예에 따르면, 본 발명의 연무확산제 조성물은 상기 우레아를 20 내지 65 중량부, 상기 유기산을 15 내지 30 중량부, 상기 탄산염을 15 내지 30 중량부, 상기 계면활성제를 1 내지 5 중량부 및 상기 암모늄염을 10 내지 20 중량부의 양으로 포함할 수 있다. According to one embodiment, the mist diffuser composition of the present invention contains 20 to 65 parts by weight of the urea, 15 to 30 parts by weight of the organic acid, 15 to 30 parts by weight of the carbonate, and 1 to 5 parts by weight of the surfactant. and 10 to 20 parts by weight of the ammonium salt.
일 구체예에 따르면, 본 발명의 연무확산제 조성물은 상기 우레아를 20 내지 62 중량부, 상기 유기산을 15 내지 30 중량부, 상기 탄산염을 15 내지 30 중량부, 상기 계면활성제를 1 내지 5 중량부 및 상기 무수 단당류를 10 내지 20 중량부의 양으로 포함할 수 있다. According to one embodiment, the mist diffuser composition of the present invention contains 20 to 62 parts by weight of the urea, 15 to 30 parts by weight of the organic acid, 15 to 30 parts by weight of the carbonate, and 1 to 5 parts by weight of the surfactant. and 10 to 20 parts by weight of the anhydrous monosaccharide.
일 구체예에 따르면, 본 발명의 연무확산제 조성물은 상기 우레아를 20 내지 62 중량부, 상기 유기산을 15 내지 30 중량부, 상기 탄산염을 15 내지 30 중량부, 상기 계면활성제를 1 내지 5 중량부, 상기 암모늄염을 10 내지 20 중량부 및 상기 무수 단당류를 10 내지 20 중량부의 양으로 포함할 수 있다. According to one embodiment, the mist diffuser composition of the present invention contains 20 to 62 parts by weight of the urea, 15 to 30 parts by weight of the organic acid, 15 to 30 parts by weight of the carbonate, and 1 to 5 parts by weight of the surfactant. , 10 to 20 parts by weight of the ammonium salt and 10 to 20 parts by weight of the anhydrous monosaccharide may be included.
본 발명의 연무확산제 조성물은 정제 형태를 가질 수 있다. The mist diffuser composition of the present invention may have a tablet form.
상기 정제는 1 내지 5 cm, 1 내지 4 cm, 1 내지 3 cm, 1 내지 2 cm 또는 약 2 cm의 직경을 가질 수 있다. 또한, 상기 정제는 0.3 내지 2 cm, 0.5 내지 2 cm 또는 0.3 내지 1 cm의 두께를 가질 수 있다. 상기 정제는 1개당 5 내지 20 g, 5 내지 15 g, 8 내지 15 g 또는 약 10 g의 중량을 가질 수 있다. The tablet may have a diameter of 1 to 5 cm, 1 to 4 cm, 1 to 3 cm, 1 to 2 cm, or about 2 cm. In addition, the tablet may have a thickness of 0.3 to 2 cm, 0.5 to 2 cm, or 0.3 to 1 cm. The tablet may have a weight of 5 to 20 g, 5 to 15 g, 8 to 15 g, or about 10 g per tablet.
상기 정제는 앞서 설명한 연무확산제 조성물을 구성하는 성분들을 혼합한 다음 균일하게 분쇄하고, 타정하여 제조할 수 있다. 조성물의 분쇄 및 타정은 과립 및/또는 정제형의 비료나 약품 등을 제조하는 방법을 차용할 수 있다. The tablet may be prepared by mixing the components constituting the mist diffuser composition described above, then uniformly pulverizing and tabletting. Pulverization and tableting of the composition may employ a method of manufacturing granules and/or tablet-type fertilizers or drugs.
본 발명의 연무확산제 조성물은 정제 형태로 제조됨에 따라 종래 액상 형태의 연무확산제에 비해 부피가 크게 줄어 운반 및 보관이 용이하고 소량 포장이 가능하여, 물류 처리 비용을 대폭 절감시킬 수 있다. Since the fog diffuser composition of the present invention is manufactured in the form of a tablet, the volume is greatly reduced compared to the conventional liquid form of the fog diffuser, so that it is easy to transport and store, and a small amount of packaging is possible, thereby significantly reducing the cost of logistics processing.
농축산물 처리방법Agricultural products processing method
본 발명은 상기 고상 연무확산제 조성물을 물과 혼합하여 농축산물에 분무하는 것을 포함하는 농축산물 처리방법을 제공한다. The present invention provides a method for treating agricultural and livestock products comprising mixing the solid mist diffuser composition with water and spraying the mixture on the agricultural and agricultural products.
먼저, 본 발명의 농축산물 처리방법에 따르면, 상기 연무확산제 조성물을 물과 혼합한다. 이때, 살충제, 살균제, 제초제, 위생용 방역 약제 및 축사방역용 약제 등으로 이루어진 군으로부터 선택되는 1종 이상의 처리제를 추가로 혼합할 수 있다. 상기 처리제는 혼합물 전체 중량을 기준으로 3 중량% 이하, 0.1 내지 3 중량%, 0.5 내지 2 중량%, 0.5 내지 1 중량% 또는 약 1 중량%의 양으로 혼합할 수 있다.First, according to the agricultural and livestock treatment method of the present invention, the mist diffuser composition is mixed with water. At this time, one or more treatment agents selected from the group consisting of pesticides, disinfectants, herbicides, sanitary prevention agents, and livestock quarantine agents may be additionally mixed. The treating agent may be mixed in an amount of 3 wt% or less, 0.1 to 3 wt%, 0.5 to 2 wt%, 0.5 to 1 wt%, or about 1 wt% based on the total weight of the mixture.
상기 연무확산제 조성물과 물의 중량비는 1:5 내지 6, 1:5.5 내지 6, 또는 1:5.7 내지 6일 수 있다. The weight ratio of the mist diffuser composition and water may be 1:5 to 6, 1:5.5 to 6, or 1:5.7 to 6.
상기 연무확산제 조성물과 처리제의 중량비는 1:0.01 내지 1.5, 1:0.01 내지 1, 1:0.1 내지 1.5, 또는 1:0.1 내지 1.0일 수 있다. The weight ratio of the mist diffuser composition and the treatment agent may be 1:0.01 to 1.5, 1:0.01 to 1, 1:0.1 to 1.5, or 1:0.1 to 1.0.
상기 함량 범위 내일 때, 연무확산제를 소량 사용하여도 탁월한 확산 효과를 제공할 수 있을 뿐만 아니라 방제 효율도 향상시킬 수 있다. When within the above content range, it is possible to provide an excellent diffusion effect even when using a small amount of a mist diffusion agent, as well as improve control efficiency.
상술한 바와 같이, 본 발명의 고상 연무확산제 조성물은 인축 및 환경에 무해한 원료들로 이루어져 안전성이 우수하고 친환경적이다. 또한, 고상의 정제 타입으로 제조 가능하므로 운반 및 보관이 용이할 뿐만 아니라, 종래 연무확산제에 비해 적은 양을 사용하여도 확산 효율 및 방제 효율이 우수하므로, 농축산물의 생장 및 보호에 도움이 된다. As described above, the solid mist diffuser composition of the present invention is made of raw materials that are harmless to livestock and the environment, so it has excellent safety and is environmentally friendly. In addition, since it can be manufactured as a solid tablet type, it is easy to transport and store, and it has excellent diffusion efficiency and control efficiency even when using a small amount compared to the conventional fog diffuser, so it is helpful for the growth and protection of agricultural and livestock products.
상기 내용을 하기 실시예에 의하여 더욱 상세하게 설명한다. 단, 하기 실시예는 본 발명을 예시하기 위한 것일 뿐, 실시예의 범위가 이들만으로 한정되는 것은 아니다.The above will be described in more detail with reference to the following examples. However, the following examples are only for illustrating the present invention, and the scope of the examples is not limited thereto.
실시예 1.Example 1.
우레아 50 중량부, 유기산으로서 구연산(무수) 22 중량부, 탄산염으로서 탄산수소나트륨 25 중량부 및 계면활성제로서 나프탈렌설폰산염-포르말린 축합물 3 중량부를 가정용 믹서에 넣고 고르게 분쇄 및 혼합하였다. 그 다음, 타정기를 이용하여 중량 10 g, 직경 2 cm 및 두께 0.5 cm의 정제 형태의 연무확산제를 제조하였다. 50 parts by weight of urea, 22 parts by weight of citric acid (anhydrous) as an organic acid, 25 parts by weight of sodium hydrogencarbonate as carbonate and 3 parts by weight of a naphthalenesulfonate-formalin condensate as a surfactant were placed in a household mixer, and evenly ground and mixed. Then, using a tableting machine, a mist diffusion agent in the form of a tablet having a weight of 10 g, a diameter of 2 cm, and a thickness of 0.5 cm was prepared.
실시예 2 내지 8 및 비교예 1.Examples 2 to 8 and Comparative Example 1.
하기 표 1에 기재된 바와 같이 원료의 종류 및/또는 함량을 변화시키는 것을 제외하고는, 실시예 1과 동일한 방법으로 정제 타입의 연무확산제를 제조하였다.As shown in Table 1 below, except for changing the type and/or content of the raw material, a tablet-type mist diffusing agent was prepared in the same manner as in Example 1.
비교예 2. Comparative Example 2.
시판되는 안개왕®을 구입하여 사용하였다. A commercially available Mist King ® was purchased and used.
[평가예][Evaluation example]
상기 실시예 1 내지 8 및 비교예 1의 정제형 연무확산제 및 비교예 2의 시판품 각각에 대하여 하기와 같이 평가하였다. The tablet-type mist diffuser of Examples 1 to 8 and Comparative Example 1 and the commercially available products of Comparative Example 2 were evaluated as follows.
평가예 1. 물리안정성 평가Evaluation Example 1. Physical stability evaluation
투명한 용기에 실시예 및 비교예의 연무확산제 또는 안개왕®을 넣고 물을 혼합하여 희석하였다. 이때, 연무확산제와 물을 1:5의 중량비로 혼합하였다. 그 다음, 용기의 뚜껑을 닫고 그늘진 실내 및 직사광선에 노출된 옥외에서 일주일간 보관하고, 일주일 후 혼합액에 대하여 성상 변화가 일어났는지를 육안으로 확인하였다. Mist spreader or Mist King ® of Examples and Comparative Examples was added to a transparent container and diluted with water. At this time, the mist diffusing agent and water were mixed in a weight ratio of 1:5. Then, the lid of the container was closed and stored in a shaded room and outdoors exposed to direct sunlight for a week, and it was visually confirmed whether a change in the properties of the mixed solution occurred after a week.
그 결과, 실시예 및 비교예 모두 물에 잘 유화되었으며 일주일이 경과한 후에도 석출, 색상 변화, 층분리 등의 성상 변화가 관찰되지 않았다. As a result, both Examples and Comparative Examples were well emulsified in water, and no change in properties such as precipitation, color change, or layer separation was observed even after a week had elapsed.
평가예 2. 연무 분사량 평가Evaluation Example 2. Evaluating the amount of mist spraying
비교예 1의 정제 및 비교예 2의 시판품을 각각 물과 1:4의 중량비로 혼합하여 희석하였다. 그 다음, 실시예 1~8의 연무확산제를 비교예보다 30% 적게 사용하여 물과 혼합하였다(실시예 1~8의 연무확산제:물의 중량비=1:5.7).The tablets of Comparative Example 1 and the commercial products of Comparative Example 2 were diluted by mixing with water in a weight ratio of 1:4, respectively. Then, 30% less of the mist diffusing agent of Examples 1 to 8 than that of Comparative Example was used and mixed with water (weight ratio of the mist spreading agent of Examples 1 to 8: water=1:5.7).
비교예 및 실시예의 희석액을 각각 가열식 휴대용 연무기에 넣고 분사하여 연무 분사량과 분사된 연무의 질적인 특성을 육안으로 관찰하였다.The diluents of Comparative Examples and Examples were respectively put in a heated portable mister and sprayed, and the amount of mist sprayed and the qualitative characteristics of the sprayed mist were visually observed.
그 결과, 실시예 및 비교예 모두 연무 발생량 및 직진 확산성이 우수하였다.또한, 연무 분사구로부터 2 m 떨어진 거리에서 분사된 연막 내에 포함된 유효 미세입자의 크기와 양을 달관으로 관찰한 결과 모두 양호한 것으로 확인되었다.As a result, both the Examples and Comparative Examples were excellent in the amount of mist generated and the spreadability in a straight line. In addition, the size and amount of effective fine particles included in the smoke film sprayed at a distance of 2 m from the mist injection port were observed with a lunar view. was confirmed to be
평가예 3. 살충력 평가Evaluation Example 3. Insecticide evaluation
실시예 및 비교예의 연무확산제에 대하여 다음과 같이 실험하여 살충력을 평가하였다.The insecticidal power was evaluated by experimenting as follows for the mist spreading agent of Examples and Comparative Examples.
살충제로는 네오니코티노이드 계열의 디노테퓨란 유제를 사용하였다.As an insecticide, a neonicotinoid-based dinotefuran emulsion was used.
먼저, 실시예 1~8 및 비교예 1의 연무확산제에 대하여, 연무확산제:물:살충제를 1:6:0.06의 중량비로 혼합하여 희석액을 제조하였다. 비교예 2의 시판품 안개왕®에 대하여, 안개왕®:물:살충제 = 1.5:6:0.06의 중량비로 혼합하여 희석액을 제조하였다. First, with respect to the haze diffuser of Examples 1 to 8 and Comparative Example 1, the haze diffuser:water:insecticide was mixed in a weight ratio of 1:6:0.06 to prepare a diluted solution. With respect to the commercial product Mist King ® of Comparative Example 2, Mist King ® : Water: Insecticide = 1.5:6: A diluted solution was prepared by mixing in a weight ratio of 0.06.
배추 좀나방은 2000년에 경주 인근에서 채집 후 사육실에서 누대 사육한 개체를 사용하였다. 양배추(daiya사)의 잎을 직경 5.8 ㎝의 절편으로 만든 후, 양배추 잎을 여과지가 깔린 패트리디쉬(직경 8.8 ㎝)에 놓고 배추 좀나방 3령충을 10마리씩 3회 반복하여 접종하였다. 상기 패트리디쉬를 휴대용 연무기의 분사구에서 약 5 m 떨어진 거리에 설치하고, 10초씩 3회 연무 처리하였다. 그 다음, 이를 광조건 16:8시간, 25±1℃, 및 상대습도 50~60% 조건하에서 보관하면서, 연무 처리후 24시간 경과 및 48시간 경과후 배추 좀나방의 생충수를 조사하였다.Cabbage moths were collected in the vicinity of Gyeongju in 2000 and then bred continuously in a breeding room. After cutting the leaves of cabbage (Daiya) into slices with a diameter of 5.8 cm, the cabbage leaves were placed on a Petri dish (diameter 8.8 cm) lined with filter paper and inoculated with 10 Chinese cabbage moth 3 times repeated 3 times. The Petri dish was installed at a distance of about 5 m from the injection port of the portable atomizer, and mist treatment was performed 3 times for 10 seconds each. Then, while it was stored under light conditions of 16:8 hours, 25±1° C., and 50-60% relative humidity, the number of live insects of Chinese cabbage moth was investigated 24 hours and 48 hours after misting treatment.
생충률은 하기 수학식 1과 같이 연무 처리전 배추좀나방의 밀도(생존 개체수)에 대한 연무 처리후 밀도로 계산하였다. 연무 처리를 하지 않은 무처리 군의 생충률은 100% 이었다. The live insect rate was calculated as the density after the misting treatment with respect to the density (surviving population) of the Chinese cabbage moth before the misting treatment as shown in Equation 1 below. The viability rate of the untreated group was 100%.
방제가는 하기 수학식 2와 같이 무처리(연무 처리 안함) 시의 배추 좀나방의 생충률에서 연무 처리후의 생충률을 제외하였다. 이때, 연무 처리후의 생충률은 평균값을 사용하였다(참고 문헌: A method of computing the effectiveness of an insecticide. J. Econ. Entomol. 18:265~267. Abbott, 1925). 결과값을 하기 표 2 및 3에 나타내었다.As for the control value, as shown in Equation 2 below, the live insect rate after mist treatment was excluded from the live insect rate of Chinese cabbage moth during untreated (no fogging treatment). At this time, an average value was used for the survival rate after mist treatment (Reference: A method of computing the effectiveness of an insecticide. J. Econ. Entomol. 18:265-267. Abbott, 1925). The results are shown in Tables 2 and 3 below.
[수학식 1][Equation 1]
생충률(%) = (연무 처리후 밀도 / 연무 처리전 밀도) x 100Viability (%) = (density after mist treatment / density before mist treatment) x 100
[수학식 2][Equation 2]
방제가(%) = (무처리 생충률 - 연무 처리후 생충률) / 무처리 생충률 x 100Control value (%) = (Non-treated live insect rate - After mist treatment) / Untreated live insect rate x 100
상기 표 2 및 3의 결과를 보면, 실시예 1~8의 연무확산제를 사용한 경우 대부분이 24시간 경과후 및 48시간 경과후 90% 이상의 방제가를 나타낸 반면, 비교예 1은 이에 미치지 못하는 방제가를 나타내어 살충 효과가 훨씬 저조하다는 것을 알 수 있다. 특히, 실시예 3 및 4의 경우에는 비교예 2보다 30%나 적은 양을 사용하였음에도 비교예 2보다 월등히 우수한 살충 효과를 나타냈다.Looking at the results of Tables 2 and 3, when the mist diffusing agent of Examples 1 to 8 was used, most showed a control value of 90% or more after 24 hours and 48 hours, whereas Comparative Example 1 did not achieve this. It can be seen that the insecticidal effect is much lower. In particular, in the case of Examples 3 and 4, although 30% less than Comparative Example 2 was used, the insecticidal effect was significantly superior to that of Comparative Example 2.
Claims (11)
유기산 10 내지 30 중량부;
탄산염 10 내지 30 중량부; 및
계면활성제 1 내지 10 중량부를 포함하는, 고상 연무확산제 조성물.20 to 65 parts by weight of urea;
10 to 30 parts by weight of an organic acid;
10 to 30 parts by weight of carbonate; and
A solid mist diffuser composition comprising 1 to 10 parts by weight of a surfactant.
상기 유기산이 사과산, 구연산, 주석산, 호박산, 말레산, 프탈산 및 에틸렌디아민테트라아세트산으로 이루어진 군으로부터 선택되는 1종 이상을 포함하는, 고상 연무확산제 조성물.According to claim 1,
The organic acid comprises at least one selected from the group consisting of malic acid, citric acid, tartaric acid, succinic acid, maleic acid, phthalic acid and ethylenediaminetetraacetic acid.
상기 탄산염이 탄산나트륨, 탄산칼슘, 탄산마그네슘, 탄산암모늄, 탄산수소나트륨, 탄산수소칼륨 및 탄산수소암모늄으로 이루어진 군으로부터 선택되는 1종 이상을 포함하는, 고상 연무확산제 조성물.The method of claim 1,
The carbonate is sodium carbonate, calcium carbonate, magnesium carbonate, ammonium carbonate, sodium hydrogen carbonate, potassium hydrogen carbonate and ammonium hydrogen carbonate composition comprising at least one selected from the group consisting of, the solid mist diffuser composition.
상기 계면활성제가 디옥틸설포숙신산염, 나프탈렌설폰산염-포르말린 축합물, 폴리아크릴산염, 리그노설폰산염, 라우릴설폰산염, 폴리알킬나프탈렌설폰산염, 폴리옥시에틸렌노닐페닐 중합체, 폴리옥시에틸렌스티릴페닐 중합체 및 폴리옥시에틸렌-폴리옥시프로필렌으로 이루어진 군으로부터 선택되는 1종 이상을 포함하는, 고상 연무확산제 조성물.The method of claim 1 .
The surfactant is dioctylsulfosuccinate, naphthalenesulfonate-formalin condensate, polyacrylate, lignosulfonate, laurylsulfonate, polyalkylnaphthalenesulfonate, polyoxyethylenenonylphenyl polymer, polyoxyethylenestyryl A solid mist diffuser composition comprising at least one selected from the group consisting of phenyl polymers and polyoxyethylene-polyoxypropylene.
상기 연무확산제 조성물이 10 내지 30 중량부의 암모늄염을 추가로 포함하는, 고상 연무확산제 조성물.According to claim 1,
The mist diffuser composition further comprises 10 to 30 parts by weight of an ammonium salt, a solid fog diffuser composition.
상기 암모늄염이 탄산암모늄, 황산암모늄, 염화암모늄 및 질산암모늄으로 이루어진 군으로부터 선택되는 1종 이상을 포함하는, 고상 연무확산제 조성물.6. The method of claim 5,
The ammonium salt comprises at least one selected from the group consisting of ammonium carbonate, ammonium sulfate, ammonium chloride and ammonium nitrate, a solid mist diffuser composition.
상기 연무확산제 조성물이 10 내지 30 중량부의 무수 단당류를 추가로 포함하는, 고상 연무확산제 조성물.According to claim 1,
The mist diffuser composition further comprises 10 to 30 parts by weight of anhydrous monosaccharides.
상기 무수 단당류가 무수 포도당, 무수 젖당, 무수 과당 및 무수 만노스로 이루어진 군으로부터 선택되는 1종 이상을 포함하는, 고상 연무확산제 조성물.8. The method of claim 7,
The anhydrous monosaccharide comprises at least one selected from the group consisting of anhydrous glucose, anhydrous lactose, anhydrous fructose and anhydrous mannose.
상기 연무확산제 조성물이 정제 형태를 갖고,
상기 정제가 1 내지 5 cm의 직경 및 0.3 내지 2 cm의 두께를 갖는, 고상 연무확산제 조성물.According to claim 1,
The mist diffusing agent composition has a tablet form,
Wherein the tablet has a diameter of 1 to 5 cm and a thickness of 0.3 to 2 cm.
상기 연무확산제 조성물이 암모늄염 및 무수 단당류를 추가로 포함하고,
상기 우레아를 20 내지 62 중량부, 상기 유기산을 15 내지 30 중량부, 상기 탄산염을 15 내지 30 중량부, 상기 계면활성제를 1 내지 5 중량부, 상기 암모늄염을 10 내지 20 중량부 및 상기 무수 단당류를 10 내지 20 중량부의 양으로 포함하는, 고상 연무확산제 조성물.According to claim 1,
The mist diffuser composition further comprises an ammonium salt and anhydrous monosaccharide,
20 to 62 parts by weight of the urea, 15 to 30 parts by weight of the organic acid, 15 to 30 parts by weight of the carbonate, 1 to 5 parts by weight of the surfactant, 10 to 20 parts by weight of the ammonium salt, and the anhydrous monosaccharide A solid mist diffuser composition comprising an amount of 10 to 20 parts by weight.
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