KR20190110064A - 쉽게 박리가능한 폴리머층을 포함하는 전기 케이블 - Google Patents

쉽게 박리가능한 폴리머층을 포함하는 전기 케이블 Download PDF

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Publication number: KR20190110064A
Authority: KR; South Korea
Prior art keywords: layer; ethylene; semiconductive; polymer; semiconductive layer
Prior art date: 2018-03-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Ceased

Application number

KR1020190031295A

Other languages

English (en)

Korean (ko)

Inventor

크리스띠앙 코엘블랭

멜렉 모쟁

가브리엘레 페레고

Original Assignee

넥쌍

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2018-03-19

Filing date

2019-03-19

Publication date

2019-09-27

2019-03-19 Application filed by 넥쌍 filed Critical 넥쌍

2019-09-27 Publication of KR20190110064A publication Critical patent/KR20190110064A/ko

Status Ceased legal-status Critical Current

Links

229920000642 polymer Polymers 0.000 title claims description 33
229920000573 polyethylene Polymers 0.000 claims abstract description 56
239000011231 conductive filler Substances 0.000 claims abstract description 26
239000004020 conductor Substances 0.000 claims abstract description 22
238000010292 electrical insulation Methods 0.000 claims abstract description 16
239000000203 mixture Substances 0.000 claims description 86
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 59
239000005977 Ethylene Substances 0.000 claims description 59
229920001577 copolymer Polymers 0.000 claims description 51
238000000034 method Methods 0.000 claims description 26
239000004710 Non-polar ethylene copolymer Substances 0.000 claims description 14
229920001038 ethylene copolymer Polymers 0.000 claims description 13
239000004711 α-olefin Substances 0.000 claims description 12
229920001169 thermoplastic Polymers 0.000 claims description 7
239000004416 thermosoftening plastic Substances 0.000 claims description 7
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 5
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 5
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 5
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims description 4
229920001519 homopolymer Polymers 0.000 claims description 2
239000004065 semiconductor Substances 0.000 abstract description 4
239000008187 granular material Substances 0.000 description 15
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239000002184 metal Substances 0.000 description 11
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239000003963 antioxidant agent Substances 0.000 description 10
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239000007788 liquid Substances 0.000 description 8
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BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
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SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 4
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229910052802 copper Inorganic materials 0.000 description 3
239000010949 copper Substances 0.000 description 3
150000001993 dienes Chemical class 0.000 description 3
239000011780 sodium chloride Substances 0.000 description 3
ZNRLMGFXSPUZNR-UHFFFAOYSA-N 2,2,4-trimethyl-1h-quinoline Chemical compound C1=CC=C2C(C)=CC(C)(C)NC2=C1 ZNRLMGFXSPUZNR-UHFFFAOYSA-N 0.000 description 2
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
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239000003063 flame retardant Substances 0.000 description 2
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238000004519 manufacturing process Methods 0.000 description 2
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239000004701 medium-density polyethylene Substances 0.000 description 2
238000002844 melting Methods 0.000 description 2
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229910044991 metal oxide Inorganic materials 0.000 description 2
150000004706 metal oxides Chemical class 0.000 description 2
239000012764 mineral filler Substances 0.000 description 2
239000000178 monomer Substances 0.000 description 2
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229920006267 polyester film Polymers 0.000 description 2
238000000926 separation method Methods 0.000 description 2
230000008646 thermal stress Effects 0.000 description 2
DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 2
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OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
RGASRBUYZODJTG-UHFFFAOYSA-N 1,1-bis(2,4-ditert-butylphenyl)-2,2-bis(hydroxymethyl)propane-1,3-diol dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1)C(C)(C)C)C(C)(C)C RGASRBUYZODJTG-UHFFFAOYSA-N 0.000 description 1
YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
GAODDBNJCKQQDY-UHFFFAOYSA-N 2-methyl-4,6-bis(octylsulfanylmethyl)phenol Chemical compound CCCCCCCCSCC1=CC(C)=C(O)C(CSCCCCCCCC)=C1 GAODDBNJCKQQDY-UHFFFAOYSA-N 0.000 description 1
MQWCQFCZUNBTCM-UHFFFAOYSA-N 2-tert-butyl-6-(3-tert-butyl-2-hydroxy-5-methylphenyl)sulfanyl-4-methylphenol Chemical compound CC(C)(C)C1=CC(C)=CC(SC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O MQWCQFCZUNBTCM-UHFFFAOYSA-N 0.000 description 1
ODJQKYXPKWQWNK-UHFFFAOYSA-L 3-(2-carboxylatoethylsulfanyl)propanoate Chemical compound [O-]C(=O)CCSCCC([O-])=O ODJQKYXPKWQWNK-UHFFFAOYSA-L 0.000 description 1
BYMLDFIJRMZVOC-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid;methane Chemical compound C.CC(C)(C)C1=CC(CCC(O)=O)=CC(C(C)(C)C)=C1O BYMLDFIJRMZVOC-UHFFFAOYSA-N 0.000 description 1
GONPAIMDIMMKMK-UHFFFAOYSA-N 4-[3-carboxy-4-(3,5-ditert-butyl-4-hydroxyphenyl)butyl]sulfanyl-2-[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]butanoic acid Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CC(CCSCCC(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(O)=O)C(O)=O)=C1 GONPAIMDIMMKMK-UHFFFAOYSA-N 0.000 description 1
INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 1
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PUYNXCNOYUUUOO-UHFFFAOYSA-N C(CCCCCCCCCCC)SCCC(=O)OC1=CC(=C(C=C1C)OC(CCSCCCCCCCCCCCC)=O)C(C)(C)C Chemical compound C(CCCCCCCCCCC)SCCC(=O)OC1=CC(=C(C=C1C)OC(CCSCCCCCCCCCCCC)=O)C(C)(C)C PUYNXCNOYUUUOO-UHFFFAOYSA-N 0.000 description 1
229910000881 Cu alloy Inorganic materials 0.000 description 1
229920002943 EPDM rubber Polymers 0.000 description 1
OUBMGJOQLXMSNT-UHFFFAOYSA-N N-isopropyl-N'-phenyl-p-phenylenediamine Chemical compound C1=CC(NC(C)C)=CC=C1NC1=CC=CC=C1 OUBMGJOQLXMSNT-UHFFFAOYSA-N 0.000 description 1
239000006057 Non-nutritive feed additive Substances 0.000 description 1
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239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
239000000654 additive Substances 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
239000012965 benzophenone Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
238000004581 coalescence Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
239000007822 coupling agent Substances 0.000 description 1
239000003431 cross linking reagent Substances 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 description 1
238000009826 distribution Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
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150000002148 esters Chemical class 0.000 description 1
DKQVJMREABFYNT-UHFFFAOYSA-N ethene Chemical group C=C.C=C DKQVJMREABFYNT-UHFFFAOYSA-N 0.000 description 1
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125000001033 ether group Chemical group 0.000 description 1
229920002313 fluoropolymer Polymers 0.000 description 1
239000010439 graphite Substances 0.000 description 1
229910002804 graphite Inorganic materials 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
238000009413 insulation Methods 0.000 description 1
239000012212 insulator Substances 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
238000000691 measurement method Methods 0.000 description 1
239000012968 metallocene catalyst Substances 0.000 description 1
239000004200 microcrystalline wax Substances 0.000 description 1
235000019808 microcrystalline wax Nutrition 0.000 description 1
239000002480 mineral oil Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
GVKQRLXYDPFTKR-UHFFFAOYSA-N n-phenylaniline;styrene Chemical compound C=CC1=CC=CC=C1.C=1C=CC=CC=1NC1=CC=CC=C1 GVKQRLXYDPFTKR-UHFFFAOYSA-N 0.000 description 1
229920006113 non-polar polymer Polymers 0.000 description 1
SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920002959 polymer blend Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
239000003223 protective agent Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
239000000326 ultraviolet stabilizing agent Substances 0.000 description 1
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239000008096 xylene Substances 0.000 description 1

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Classifications

- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/38—Insulated conductors or cables characterised by their form with arrangements for facilitating removal of insulation
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/14—Conductive material dispersed in non-conductive inorganic material
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B9/00—Power cables
- H01B9/02—Power cables with screens or conductive layers, e.g. for avoiding large potential gradients
- H01B9/027—Power cables with screens or conductive layers, e.g. for avoiding large potential gradients composed of semi-conducting layers
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes

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Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Dispersion Chemistry (AREA)
Inorganic Chemistry (AREA)
Physics & Mathematics (AREA)
Spectroscopy & Molecular Physics (AREA)
Organic Insulating Materials (AREA)
Compositions Of Macromolecular Compounds (AREA)
Conductive Materials (AREA)
Insulated Conductors (AREA)

KR1020190031295A 2018-03-19 2019-03-19 쉽게 박리가능한 폴리머층을 포함하는 전기 케이블 Ceased KR20190110064A (ko)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR1852334A FR3079067B1 (fr)	2018-03-19	2018-03-19	Cable electrique comprenant une couche polymerique facilement pelable
FR1852334		2018-03-19

Publications (1)

Publication Number	Publication Date
KR20190110064A true KR20190110064A (ko)	2019-09-27

Family

ID=62873451

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
KR1020190031295A Ceased KR20190110064A (ko)	2018-03-19	2019-03-19	쉽게 박리가능한 폴리머층을 포함하는 전기 케이블

Country Status (3)

Country	Link
EP (1)	EP3544025A1 (de)
KR (1)	KR20190110064A (de)
FR (1)	FR3079067B1 (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR3090985B1 (fr) *	2018-12-21	2020-12-18	Nexans	Câble comprenant une couche semi-conductrice facilement pelable

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* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6670554B1 (en) *	2002-10-07	2003-12-30	Union Carbide Chemicals & Plastics Technology Corporation	High-voltage direct current cable insulation
FR2950728B1 (fr) *	2009-09-30	2012-08-17	Nexans	Cable electrique a moyenne ou haute tension
BR112017012623B1 (pt) *	2014-12-17	2021-05-18	Prysmian S.P.A.	cabo de energia
EP3173442A1 (de) *	2015-11-27	2017-05-31	Borealis AG	Halbleitende polyethylenzusammensetzung
FR3045634B1 (fr)	2015-12-18	2020-01-31	Nexans	Composition polymere comprenant un liquide dielectrique presentant une polarite amelioree
FR3045635B1 (fr)	2015-12-18	2019-06-07	Nexans	Composition polymere presentant une resistance au blanchiment sous contrainte amelioree

2018
- 2018-03-19 FR FR1852334A patent/FR3079067B1/fr active Active
2019
- 2019-03-11 EP EP19161809.9A patent/EP3544025A1/de active Pending
- 2019-03-19 KR KR1020190031295A patent/KR20190110064A/ko not_active Ceased

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Publication number	Publication date
EP3544025A1 (de)	2019-09-25
FR3079067A1 (fr)	2019-09-20
FR3079067B1 (fr)	2020-03-20

Publication	Publication Date	Title
US20120227997A1 (en)	2012-09-13	Medium-or high-voltage electric cable
US8410789B2 (en)	2013-04-02	High voltage electric cable
EP2705079B1 (de)	2018-01-24	Polymerzusammensetzung für elektrische vorrichtungen
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WO2016005791A1 (en)	2016-01-14	Energy cable having a thermoplastic electrically insulating layer
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