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KR20130019603A - A green painting composite of structure for air purifying - Google Patents

A green painting composite of structure for air purifying Download PDF

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Publication number
KR20130019603A
KR20130019603A KR1020110081663A KR20110081663A KR20130019603A KR 20130019603 A KR20130019603 A KR 20130019603A KR 1020110081663 A KR1020110081663 A KR 1020110081663A KR 20110081663 A KR20110081663 A KR 20110081663A KR 20130019603 A KR20130019603 A KR 20130019603A
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composition
weight
coating composition
kaolin
coating
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KR101266838B1 (en
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백우현
오흥덕
최익현
조영동
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백우현
오흥덕
최익현
조영동
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/10Clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/04Macromolecular compounds
    • C04B16/06Macromolecular compounds fibrous
    • C04B16/0616Macromolecular compounds fibrous from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B16/0641Polyvinylalcohols; Polyvinylacetates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/34Natural resins, e.g. rosin
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04Homopolymers or copolymers of vinyl acetate

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Civil Engineering (AREA)
  • Paints Or Removers (AREA)

Abstract

본원은 환경 친화적으로 공기 질 개선효과를 갖는 건축물의 도장용 조성물에 관한 것으로, 친환경적인 원료의 소재로 황토와 고령토 원료를 30~40중량% 범위로 포함하되 황토와 고령토의 배합비율에 따라 구현되는 색상의 조도를 다르게 할 수 있고, E.V.A(Ethyl Vinyl Acetate)수지가 고착제 역활을 하도록 8~12중량% 범위로 사용되고, 지당(백색)과 알긴산, 곡사이드(엘루우)나 피톤치드를 첨가물로 이용하면서 황토지장수로 배합하여 제공되는 도장 조성물을 통하여 원하는 색상을 얻으며 E.V.A수지가 고착제 역활을 하면서 초산 수지의 발수 시 생겨나는 기포에 의해 단단한 결합력을 유지하는 건축물의 내부 도장용 조성물에 관한 것이다.
본원에서 제공되는 건축물의 내부 도장용 조성물은 도장용 조성물 중 황토와 고령토의 합량이 30~40중량%를 이루고, 초산 수지인 E.V.A수지가 8~12중량%로 함유되며, 지당(백색)이 0.5~5중량%, 알긴산이 0.1~0.2 중량%, 곡사이드(엘로우)가 0.01~0.05 중량%로 함유되고 잔량으로 황토지장수가 공정수로 추가되어 100중량%를 이루어서 제공된다.
The present invention relates to a composition for coating a building which is environmentally friendly and has the effect of improving air quality. The composition is made of environmentally friendly raw materials and includes 30 to 40 wt% of loess and kaolin as raw materials. It is used in the range of 8 ~ 12 wt% for EVA (Ethyl Vinyl Acetate) resin to serve as a fixing agent, and it is used by adding alginic acid, gin side (eluu) or phytoncide (peroxide) The present invention relates to a composition for internal coating of a building, which obtains a desired color through a coating composition provided by blending with a yellow mortar, and maintains a firm binding force by bubbles generated when the EVA resin acts as a fixing agent while water-
The composition for interior painting of a building provided in the present invention is characterized in that the total amount of the loess and kaolin in the coating composition is 30-40 wt%, the EVA resin as the acetic acid resin is 8-12 wt%, the peroxide (white) is 0.5 To 5% by weight of alginic acid, 0.1 to 0.2% by weight of alginic acid and 0.01 to 0.05% by weight of curdside (yellow), and the remaining amount of the yellowish ground water is added to the process water in an amount of 100% by weight.

Description

환경 친화적으로 공기 질 개선효과를 갖는 건축물의 도장용 조성물{A green painting composite of structure for air purifying}Technical Field [0001] The present invention relates to a composition for coating a building having an air-

본 발명은 환경 친화적으로 공기질 개선효과를 제공하는 건축물의 내부 도장용 조성물에 관한 것으로, 더욱 상세하게는 황토와 고령토를 다양한 조성비로 변환하며 도장물의 색상을 조절하도록 사용되는 것으로, 황토와 고령토의 혼합물량이 30~40중량% 범위를 이루고 초산 수지인 E.V.A수지를 8~12중량%로 사용하여 혼화제의 역활을 하게 하며, 지당(백색)과 알긴산 및 곡사이드(엘로우) 및 피톤치드가 첨가제로 함유되어 초산 수지의 발수 시 생겨나는 기포에 의해 사용재료의 결합력을 높여주는 건축물의 내부 도장용 조성물에 관한 것이다. More particularly, the present invention relates to a composition for interior painting of a building which provides environmentally friendly air quality improvement effect, and more particularly, to a composition for converting the yellow loess and kaolin into various composition ratios and controlling the color of the painted material. (White), alginic acid, gonads (yellow) and phytoncide are contained as additives, and the amount of EVA is in the range of 30 to 40 wt% and the amount of EVA resin is 8 to 12 wt% The present invention relates to a composition for internal coating of a building which increases the bonding force of a material to be used by bubbles generated by water repellency of acetic acid resin.

새집 증후군(Sick House Syndrome) 이란 건물을 새로 지을 때 사용하는 건축자재나 벽지 등에서 나오는 유해물질로 인해 거주자들이 느끼는 건강상 문제 및 불쾌감을 이르는 용어로서, 새집 증후군을 야기하는 물질로 벤젠, 클로로폼, 스타이렌, 포름알데히드 등과 같은 VOCs(Volatile Organic Compounds)라 불리우는 휘발성 유기화합물이 있으며, 이들 물질에는 발암물질이 포함되어 있다. Sick House Syndrome is a term that causes residents to feel uneasiness and health problems due to toxic substances from building materials and wall paper used for building new buildings. Sick house syndrome is a substance causing sick house syndrome. Benzene, chloroform, There are volatile organic compounds called VOCs (Volatile Organic Compounds) such as styrene and formaldehyde, which contain carcinogens.

또 집을 지을 때 발생한 라돈, 석면, 일산화탄소, 이산화탄소, 질소산화물, 오존, 미세먼지, 부유세균과 같은 오염물질도 있을 수 있으며, 이 밖에 곰팡이, 바이러스 등과 같은 세균, 진드기, 등의 생물도 실내공기를 오염키는 요인이나, 이러한 오염물질이 건물 밖으로 배출되지 못하고 실내에 축적되면 각종 문제를 일으키게 된다. In addition, pollutants such as radon, asbestos, carbon monoxide, carbon dioxide, nitrogen oxides, ozone, fine dust, and floating bacteria may be present when building the house. In addition, bacteria such as fungi and viruses, ticks, It is a cause of pollution, but if these pollutants can not be discharged out of the building and accumulate in the room, they cause various problems.

최근 주거환경에 대한 인식이 웰-빙(well-being)을 추구하면서, 실내 공기 질에 대한 관리방안 및 유해오염물질에 대한 연구가 활발하게 진행되고 있으며, 건축 자재 자체에 유해 물질을 함유하지 않도록 제작하거나 표면에 도료의 코팅 등의 방법을 통해 상기 VOCs를 제거할 뿐만 아니라, 쾌적한 실내 환경을 만들어주며 탈취력 및 항균력까지 확보할 수 있는 다양한 방법이 제안되고 있다.In recent years, research on indoor air quality and harmful pollutants has been actively pursued while the awareness of the residential environment has pursued well-being. In order to prevent the harmful substances from being contained in the building material itself There have been proposed various methods of not only removing the VOCs through a method such as coating or painting a surface of a vehicle, making a comfortable indoor environment, and securing deodorizing power and antibacterial power.

대한민국 특허공개 제2005-0093048호 기술에서는 황토와 일라이트, 제올라이트, 규조토를 각각 1:1:1:1로 혼합하여 천연규산알루미늄 조성물을 만들고, 다른 하나의 조성물은 천연석고 60%~90%, 전기석 20%~5%, 음이온석 10%~1%, 참숯 5%~10% 광촉매 이산화티탄(TiO2)을 0.1%~5% 첨가하고 기능성 혼합물과 천연규산 알루미늄 조성물을 다시 1:1~2:1로 배합하여 혼합되는 실내 공기질을 개선하는 미장용 마감재 조성물을 제안하고 있다.In Korean Patent Laid-Open No. 2005-0093048, a natural aluminum silicate composition is prepared by mixing yellow earth, ilite, zeolite and diatomaceous earth in a ratio of 1: 1: 1: 1, tourmaline is added 20% to 5%, anionic seats 10-1%, the charcoal 5% to 10% the photocatalytic titanium dioxide (TiO 2) 0.1% ~ 5 % , and again, the functional mixture and natural aluminum silicate composition 1: 1-2. : 1 to improve the indoor air quality to be mixed.

또한, 대한민국 특허공개 제2006-0059110호 기술에서는 천연광물 분말 세라믹을 주 원료로 하여 냉 난방비 절감, 미세먼지 감소, 시멘트 독성 및 접합제의 독성중화 기능을 갖는 건축 마감재를 제공하기 위한 수단으로, 장석과 견운모(일라이트)를 325~400 메쉬로 고분채하여 항균제, 탈취제, 곰팡이제 등을 분말세라믹 과 액체형 천연 향을 수용성 에멀젼을 포함한 액상 바인더를 충분히 혼합하여, 건물의 벽체, 천정 및 바닥에 시공하여 신선한 공기를 공급하여 쾌적한 실내 환경을 제공할 수 있다고 언급하고 있다.Also, Korean Patent Laid-Open Publication No. 2006-0059110 discloses a means for providing a building finishing material having a natural mineral powder ceramic as a main raw material and having a function of reducing cooling and heating costs, reducing fine dust, And antimicrobial agent, deodorant, fungicide and so on are mixed with liquid binder containing water-soluble emulsion in the form of powder ceramics and liquid type natural fragrance to the wall, ceiling and floor of the building. And provide fresh air to provide a pleasant indoor environment.

그러나 아무리 이상적인 마감재 조성물을 제안한다 하더라도, 상기와 같이 고급 소재를 사용하는 경우 현실적으로 건설회사나 사용자가 구매 가능한 적절한 제품 단가로 공급할 수 없는 문제점을 가지며, 또한 고가의 제품이라고 하여 내구성을 갖고 장기간에 걸쳐 공기 질 개선효과를 제공하는 부분에서 미흡한 문제점이 발견된다.However, even if an ideal finishing material composition is proposed, there is a problem that a high-priced material can not be supplied to a construction company or a user at an appropriate product price that can be purchased. In addition, There is a problem in that the air quality improving effect is insufficient.

이에 본 발명자들은 본원에서 마련되는 건축물 내부 미장용 마감재 조성물로 제공되는 경우 수요자가 부담없이 구매할 수 있고 상대적으로 저가의 제품이면서 내구성을 갖고 장기간에 걸쳐 공기 질 개선효과를 제공하는 효과를 확인하여 본 발명을 완성하기에 이르렀다.Accordingly, the inventors of the present invention confirmed that the present invention provides an effect of improving air quality over a long period of time by providing a durable composition and a relatively low cost product, .

본원은 친환경적인 원료의 소재로 황토와 고령토 원료를 30~40중량% 범위로 포함하되 황토와 고령토의 배합비율에 따라 구현되는 색상의 조도를 다르게 할 수 있고, E.V.A(Ethyl Vinyl Acetate)수지가 고착제 역활을 하도록 8~12중량% 범위로 사용되고, 지당(백색)과 알긴산, 곡사이드(엘루우)나 피톤치드를 첨가물로 이용하면서 황토지장수로 배합하여 제공되는 도장 조성물을 통하여 원하는 색상을 얻으며 E.V.A수지가 고착제 역활을 하면서 초산 수지의 발수 시 생겨나는 기포에 의해 단단한 결합력을 유지하는 건축물의 내부 도장용 조성물을 제공하고자 하는 목적을 갖는다.The present invention relates to an environmentally friendly raw material, which comprises a mixture of loess and kaolin as a raw material in a range of 30 to 40% by weight, wherein the color of the hue is different according to the blending ratio of the loess and kaolin, and EVA (Ethyl Vinyl Acetate) (White), alginic acid (gum) and phytoncide as an additive, and a desired color is obtained through a coating composition provided as yellow clay. There is an object to provide a composition for internal coating of a building which maintains a firm bonding force due to bubbles generated by water repellency of acetic acid resin while acting as a fixing agent.

본원에서 제시되는 기술사상의 발명은 상기 목적을 달성하기 위한 수단으로서, 건축물의 내부 도장용 조성물 중 황토와 고령토의 합량이 30~40중량%를 이루고, 초산 수지인 E.V.A수지가 8~12중량%로 함유되며, 지당(백색)이 0.5~5중량%, 알긴산나트륨(Na-Alginate)이 0.1~0.2 중량%, 곡사이드(엘로우)가 0.01~0.05 중량%로 함유되고 잔량으로 황토지장수가 공정수로 추가되어 100중량%를 이루어서 제공되는 도장용 조성물을 이용하고자 하는 기술사상의 발명이다.As a means for achieving the above objects, the present invention provides a method for coating a building, the composition comprising 30 to 40% by weight of a mixture of loess and kaolin, 8 to 12% by weight of an EVA resin, By weight, and the content of peroxide (white) is 0.5 to 5% by weight, the content of sodium alginate is 0.1 to 0.2% by weight and the content of curdside (yellow) is 0.01 to 0.05% by weight, To 100% by weight based on the total weight of the composition.

상기의 도장용 조성물 100 kg을 기준으로 할 때 피톤치드가 10~30 gr이 추가되어 항균성을 높인 도장용 조성물로 제공될 수 있는 발명이다.It is an invention that can be provided as a coating composition in which phytonchide is added in an amount of 10 to 30 g based on 100 kg of the coating composition to increase antimicrobial activity.

본원의 도장용 조성물에서 주 원료로 사용되는 고령토는 석영조면암, 안산암, 화강암 등이 열수작용 또는 풍화작용에 의하여 분해되어 생성된 것으로, 화학식이 Al2O3, 2SiO2, 2H2O 로 표시되며, 이 kaolin 족에 속하는 광물로는 nacrite, dickite, kaolinite, halloysite 등이 있으며, 일반적으로 고령토는 kaolinite와 halloysite로 되어 있는 점토류에 속하는 광물로서 물리화학적으로는 카올린 광물 중에서 가장 활성이 큰 특징을 갖는바, 본원의 도장용 조성물에서 고령토는 점성기능을 갖고 결합력을 유지하도록 사용된다.The kaolin used as a main raw material in the coating composition of the present invention is produced by decomposing quartz surface rough rock, andesite, granite and the like by hydrothermal or weathering action. The formula is expressed as Al 2 O 3 , 2SiO 2 , 2H 2 O The kaolin group includes nacrite, dickite, kaolinite, and halloysite. In general, kaolinite is a mineral belonging to kaolinite and halloysite clay. Physicochemically it is the most active kaolin minerals In the coating composition of the present application, kaolin has a viscous function and is used to maintain the bonding force.

또한 본원 도장용 조성물에서 주 원료로 사용되는 황토는 작은 방들을 촘촘하게 연결시킨 벌집 구조를 갖는 것으로 그 주성분은 규소, 알루미늄, 철, 마그네슘과 같은 무기질로서, 전체 성분의 절반 이상이 규소성분으로 이루어지고 규소는 산화 친화력이 높아 그 양이 많은 만큼 산소 흡착률이 높아지므로 황토의 복층 구조 속에는 항상 풍부한 산소가 저장되어 있으며, 고령토의 분자 구조는 단층 구조이지만 황토는 복층 구조이고, 복층 구조에서는 양쪽에 공극이 발생하므로 주변 입자와 결합 가능성이 증대되고 표면적이 일반 흙에 비해 7~10배정도 크기 때문에 흡착 능력이 뛰어나서 더 많은 원적외선을 흡수 및 저항할 수 있게 해주며, 황토의 작고 촘촘한 방에 보다 많은 원적외선을 흡수하고 저장할 수 있는 것은 황토의 표면적이 고령토의 표면적에 비해 약 7~10배에 달하기 때문이다.Also, the yellow loess used as a main raw material in the coating composition of the present invention has a honeycomb structure in which small rooms are closely connected, and its main component is an inorganic substance such as silicon, aluminum, iron, and magnesium, Since the oxygen has a high oxidation affinity with high oxidation affinity, silicon has a high oxygen absorption rate. Therefore, oxygen is always stored in the multi-layered structure of the loess, and the molecular structure of kaolin is a monolayer structure but the loess is a multi- The possibility of bonding with surrounding particles is increased and the surface area is 7 ~ 10 times larger than that of the general soil. Therefore, the adsorption ability is excellent, so that it can absorb and resist more far infrared rays, and more far infrared rays What can be absorbed and stored is that the surface area of the loess is the surface area of the kaolin Compared because the moon for about 7-10 times.

본원의 미장용 마감재 조성물에서 황토는 흡착기능성을 향상시켜 탈취와 습도조절 능력을 상승시키는 효과를 높이는 것으로 파악된다.It can be seen that the loess in the finishing coat composition of the present invention improves the adsorption function, thereby enhancing the effect of increasing deodorization and humidity control ability.

본원에서 미장용 마감재 조성물을 배합하는데 공정수로 사용되는 황토지장수는 양지 바른 들판이나 깊은 산등성이의 황토 땅속으로 60 이상 구덩이를 파면, 푸른 띠 같은 것이 가로로 연결되어 있는 것을 발견하게 되는바, 이 띠 밑의 흙을 파내어 숯으로 걸러낸 물과 황토를 알맞은 비율로 섞어 여러 번 휘저은 뒤에 24시간 이상 시간이 지나면 엷은 담황색 물이 위에 뜨는데, 이 윗물을 황토지장수로 이용할 수 있으며, 본원의 미장용 마감재 조성물에서 황토지장수는 실내의 유해 미세균을 흡수하여 해독작용을 갖게 된다.In the present invention, it is found that if the clay loam used as the process water for blending the finishing coat composition for finishing is broken into more than 60 pits in a loamy soil of a sunny field or deep ridges, a blue band is horizontally connected, After dipping the bottom soil and mixing it with the charcoal filtered water and the loess mixture at a suitable rate, after more than 24 hours of pouring, the pale yellowish water will float on top of it. This top can be used as the yellow clay loam. In the composition, the yellow clay is absorbed by harmful microorganisms in the room and has a detoxifying action.

상기의 주 원료 외에 본원에서 사용되는 E.V.A 초산 수지는 도장용 조성물에서 고화재 역할을 수행하게 되고, 지당은 광물의 조성을 갖고 도장용 조성물에서 안료기능을 수행하도록 제공 되며, 알긴산나트륨은 해초 중 갈조류인 곰피, 감태속, 대황속, 미역속, 다시마 등에 포함되어 있는 성분으로, 알긴산은 중합체 단 분자에 카르복실기(-COO-)를 갖고 있어서 수용액 중에서는 산의 성질을 나타내나 다시 알카리성 용액과 만나면 Na+ 이온과 결합하는 등의 양쪽성 성질을 나타내는바, 본원에서는 해초류를 건조, 분해하여 분말로 만든 다음 도장용 조성물에서 겔(gel)역할을 수행하도록 사용될 수 있으며, 곡사이드엘로우는 도장용 조성물에서 착색역할을 하도록 사용 되고, 피톤치드는 도장용 조성물에서 도장용 조성물이 건조 후 항균력을 유지하도록 사용될 수 있는 기술사상을 포함한다.In addition to the above-mentioned main raw materials, the EVA acetic acid resin used in the present invention plays a role of a fire in the coating composition, and has a mineral composition per side and is provided to perform a pigment function in a coating composition, and sodium alginate is a brown alga Alginic acid has a carboxyl group (-COO - ) in a polymer monomolecule and shows acidic properties in an aqueous solution. When it comes back to an alkaline solution, Na + ion And it can be used in the present invention to dry and decompose seaweed to make a powder and then to serve as a gel in a coating composition. In addition, the gauze side yellow can be used as a coloring agent in a coating composition , And phytoncide is used in the coating composition so as to maintain the antibacterial activity after the coating composition is dried Including the spirit can.

상기의 도장용 조성물에서 황토와 고령토의 배합비율에 따라 구현되는 색상의 조도를 다르게 조절할 수 있는바, 황토와 고령토가 2 : 5 배합비율로 조성되어 도장용 조성물 중량의 30~40중량% 범위를 이루도록 제공되는 A타입은 옅은 아이보리색상을 구현하도록 제공될 수 있고, 황토와 고령토가 3 : 4 배합비율로 조성되어 도장용 조성물 중량의 30~40중량% 범위를 이루도록 제공되는 B타입과, 황토와 고령토가 4 : 3 배합비율로 조성되어 도장용 조성물 중량의 30~40중량% 범위를 이루도록 제공되는 C타입과, 황토와 고령토가 5 : 2 배합비율로 조성되어 도장용 조성물 중량의 30~40중량% 범위를 이루도록 제공되는 D타입은 짙은 아이보리 색상을 구현하도록 제공될 수 있으며, 황토와 고령토가 1 : 6 배합비율로 조성되어 도장용 조성물 중량의 30~40중량% 범위를 이루도록 제공되는 E타입은 순백색을 원할 때 적용될 수 있는바, 따라서 수요자가 구현되기를 원하는 조도의 색상에 따라 A타입 ~ E타입 중에서 선택되는 조성을 붓이나 롤러로 도포되거나 또는 콤프레서에 의해 분무되는 방법으로 시공될 수 있다.The coating composition can control the illuminance of the hue according to the mixing ratio of the clay and the kaolin. The content of the clay is in the range of 2: 5, and the content of the clay is in the range of 30 to 40% Type A provided to achieve a light ivory color, B type having a ratio of 3: 4 of loess and kaolin to 30 to 40 wt% of the weight of the coating composition, A mixture of catechin and kaolin at a mixing ratio of 4: 3 to provide a range of 30 to 40 wt.% Of the coating composition, a mixture of catechin and kaolin at a ratio of 5: 2, % Can be provided to realize a deep ivory color, and the ratio of 1: 6 of the loess and kaolin is in the range of 30 to 40 weight% of the weight of the coating composition. The type E provided for the lock can be applied when pure white is desired, so that the composition selected from A type to E type is applied by a brush or a roller or sprayed by a compressor according to the color of the illumination desired by the consumer, .

본원의 도장용 조성물이 적용되는 범위는 실내 시멘트 벽면의 외측이나 석고보드면, 목재면, 금속면, 벽지면 등에 본원의 도장용 조성물 20kg 당 50~80 정도의 범위로 도포되는 방법으로 적용될 수 있다.The range of application of the coating composition of the present invention can be applied by a method such that the coating composition is applied to the outer side of the indoor cement wall surface, the gypsum board surface, the wood surface, the metal surface, the wallpaper surface, etc. in the range of about 50 to 80 per 20 kg of the coating composition of the present invention .

본 발명에 따른 조성물은 국내 토양에서 채취되는 황토 및 고령토를 주 성분으로 사용하고, 친환경적인 바인더로 인체에 무해한 E.V.A수지를 사용하며, 천연식물의 추출물인 일긴산 및 피톤치드를 사용하고, 국내 토양에서 채취되는 지당(백색)을 사용하여 도장용 조성물로 제공됨으로 환경오염 유발효과를 내는 원료를 사용하지 않고, 실내에서 장기간 동안 탈취, 항균, 소취 효과를 극대화시키는 도장용 조성물을 제공하는 효과를 갖는다.
The composition according to the present invention uses yellow loess and kaolin extracted from domestic soil as main components, EVA resin which is harmless to the human body as an environmentally friendly binder is used, and ilic acid and phytoncide which are extracts of natural plant are used, The present invention has the effect of providing a coating composition for maximizing deodorization, antibacterial and deodorizing effect in a room for a long period of time without using a raw material which is provided as a coating composition using a peroxide (white) collected.

이하 본원의 기술사상이 구현되는 실시양태를 하기에서 구체적인 실시예 형식으로 기재하고자 하는바, 본원에서 제시되는 실시예의 상한이나 하한을 나타내는 숫자는 본원의 목적을 달성하기 위한 다양한 시행오차법에 의한 실험결과로 출원인이 원하는 기대치를 달성하는 범위의 실시양태를 제시한 것이고, 본원의 기술사상을 모두 대변하는 것은 아니나 본원에서 제시되는 수치의 상한이나 하한을 벗어나는 경우 최상의 물성이 훼손되고 내구성이 떨어지는 문제점을 나타낼 수 있을 것이다.Hereinafter, embodiments in which the technical idea of the present invention is implemented will be described in the form of a specific embodiment, and numerals indicating the upper limit or the lower limit of the embodiments shown herein may be applied to various experiments As a result, it is an object of the present invention to provide a range of embodiments in which the applicant achieves the desired expectation and does not represent all of the technical ideas of the present invention. However, when the upper limit or the lower limit of the numerical value is exceeded, the best physical property is damaged and the durability is poor .

또한 본원의 목적을 달성하기 위한 수단으로 제시되는 도장용 조성물은 도장용 조성물 중 황토와 고령토의 합량이 30~40중량%를 이루고, 초산 수지인 E.V.A수지가 8~12중량%로 함유되며, 지당(백색)이 0.5~5중량%, 알긴산이 0.1~0.2 중량%, 곡사이드(엘로우)가 0.01~0.05 중량%로 함유되고 잔량으로 황토지장수가 공정수로 추가되어 100중량%를 이루어서 제공되는 도장용 조성물을 이용하고자 하는 기술사상의 발명인바, 각 조성물의 배합순서에 따라서도 다소 영향을 미칠 수 있을 것이나 본 발명의 기술사상에 따른 권리범위는 특허청구범위에 기재된 내용을 기준으로 균등론적으로 해석되어 적용되어야 할 것이다. In addition, the composition for painting which is presented as a means for achieving the object of the present invention is characterized in that the total amount of the loess and kaolin in the coating composition is 30-40 wt%, the EVA resin as acetic acid resin is 8-12 wt% (100% by weight) is added as a process water in an amount of 0.5 to 5% by weight, the alginic acid is contained in an amount of 0.1 to 0.2% by weight and the curd side (yellow) is contained in an amount of 0.01 to 0.05% The present invention may be somewhat influenced by the composition order of the respective compositions. However, the scope of rights according to the technical idea of the present invention is not limited to the description of the claims, .

이의 구체적인 적용양태는 아래의 실시예 형태로 적용되었는바, 본원의 제조실시예에서 사용된 황토지장수는 출원인의 선출원 10-2010-0014609 호에 출원된 황토지장수 제조방법에 개시된 기술을 통하여 얻은 황토지장수가 이용되었다.The specific application mode of the present invention is applied in the form of the following embodiments, and thus the yellow clay gangs used in the manufacturing examples of the present application are the same as those of the yellow clay gangs obtained through the technique disclosed in the method of manufacturing yellow clay gangue filed in the applicant's application No. 10-2010-0014609 Was used.

1. 건축내부 도장용 조성물 제조실시예(A 타입)1. Construction Example of Compositions for Interior Painting (Type A)

40 mesh 범위의 체로 걸러진 고령토 5.0 kg과 40 mesh 범위의 체로 걸러진 황토 2.0 kg과, E.V.A수지 1.8 kg, 지당(백색) 500 gr, 알긴산 30 gr에 황토지장수 약 11.5l를 혼합하여 A 타입의 건축물의 내부 미장용 마감재 조성물 약 20 kg을 얻고 도장하기전 피톤치드 2gr을 교반하여 에어컴프레서로 분무 시공하여 짙은 아이보리 컬러의 벽면체를 형성하였다.2.0 kg of loess filtered sieves ranging from 5.0 kg to 40 mesh sieved in the range of 40 mesh, 1.8 kg of EVA resin, 500 gr of peroxide (white), 30 g of alginic acid and about 11.5 l of yellow clay Approximately 20 kg of the interior finishing composition was obtained, and 2 gr of phononchid was stirred and sprayed into an air compressor to form a thick ivory color wall body.

2. 건축내부 도장용 조성물 제조실시예(B 타입)2. Example of composition for interior paint coating (B type)

40 mesh 범위의 체로 걸러진 고령토 4.0kg과 40 mesh 범위의 체로 걸러진 황토 3.0kg과, E.V.A수지 1.8kg, 지당(백색) 300 gr, 알긴산 30 gr, 곡사이드(옐로우) 3 gr을 넣고 황토지장수 약 11.5l를 혼합하여 B 타입의 건축물의 내부 미장용 마감재 조성물 약 20kg을 얻고 도장하기전 피톤치드 2gr을 교반하여 에어컴프레서로 분무 시공하여 아이보리 컬러의 벽면체를 형성하였다.4.0 kg of kaolin sieved in the range of 40 mesh and 3.0 kg of yellow loess sieved in the range of 40 mesh, 1.8 kg of EVA resin, 300 gr of white perge (white), 30 gr of alginic acid and 3 gr of gonad (yellow) l were mixed to obtain about 20 kg of a finishing composition for interior finishing of a type B building. Before coating, 2 gr of phononchid was stirred and sprayed to an air compressor to form an ivory color wall body.

3. 건축내부 도장용 조성물 제조실시예(C 타입)3. Construction Example of Compositions for Interior Painting Construction (Type C)

40 mesh 범위의 체로 걸러진 고령토 3.0 kg와 40 mesh 범위의 체로 걸러진 황토 4.0 kg과, E.V.A수지 1.8 kg, 알긴산 30 gr에 곡사이드(옐로우)5 gr을 넣고 황토지장수 약 11.5l를 혼합하여 C 타입의 건축물의 내부 미장용 마감재 조성물 약 20kg을 얻고 도장하기전 피톤치드 2gr을 교반하여 에어컴프레서로 분무 시공하여 아이보리 컬러의 벽면체를 형성하였다.4.0 kg of yellow algae sieved in a range of 3.0 kg and 40 mesh kaolin sieved with a mesh size of 40 mesh, 1.8 kg of EVA resin and 5 gr of gauze (yellow) in 30 g of alginic acid were mixed with about 11.5 L of yellow clay, Approximately 20 kg of the finishing composition for interior finishing of the building was obtained and 2 gr of phononchid was stirred and sprayed to an air compressor to form an ivory color wall body before coating.

4. 건축내부 도장용 조성물 제조실시예(D 타입)4. Construction Example of Compositions for Interior Painting Construction (Type D)

40 mesh 범위의 체로 걸러진 고령토 2.0kg과 40 mesh 범위의 체로 걸러진 황토 5.0 kg과, E.V.A수지 1.8 kg, 알긴산 30 gr에 곡사이드(옐로우) 10 gr을 넣고 황토지장수 약 11.5l를 혼합하여 D 타입의 건축물의 내부 미장용 마감재 조성물 약 20 kg을 얻고 도장하기 전 피톤치드 2gr을 교반하여 에어컴프레서로 분무 시공하여 옅은 아이보리 컬러의 벽면체를 형성하였다.2.0 kg of kaolin sieved in the range of 40 mesh and 5.0 kg of loess filtered sieves in the range of 40 mesh, 1.8 kg of EVA resin and 10 gr of gonads (yellow) in 30 g of alginic acid were mixed and about 11.5 L of yellow clay was mixed to obtain D type Approximately 20 kg of finishing composition for interior finishing of buildings was obtained, and 2 gr of phononchid was stirred and sprayed into an air compressor to form a pale ivory color wall body before coating.

5. 건축내부 미장용 마감재의 제조실시예(E 타입)5. Manufacturing Example of Interior Finishing Material for Interior Finishes (Type E)

40 mesh 범위의 체로 걸러진 고령토 6.0 kg과 40 mesh 범위의 체로 걸러진 황토 1.0 kg과, E.V.A수지 1.8kg, 지당(백색) 1.0kg, 알긴산 30 gr에 황토지장수 약 11.5l를 혼합하여 E 타입의 건축물의 내부 미장용 마감재 조성물 약 20 kg을 얻고 도장하기 전 피톤치드 2gr을 교반하여 에어컴프레서로 분무 시공하여 순백색 컬러의 벽면체를 형성하였다.1.0 kg of EVA resin, 1.0 kg of EVA resin, 1.0 kg of peroxide (white), and about 11.5 l of alum germicide were mixed with about 11.5 l of alum germicide. Approximately 20 kg of the finishing composition for internal plaster was obtained and 2 gr of phononchid was stirred and sprayed into an air compressor before coating to form a pure white color wall body.

6. 탈취율 시험 실시 예6. Deodorization rate test Example

제조실시예 A타입을 통하여 얻은 도장용 조성물을 이용하여 가로 30 ㎝ * 세로 30 ㎝ * 두께 2.5 ㎝의 돌판 샘플에 본원의 제조실시예 A타입을 통하여 얻은 도장용 조성물을 균일하게 도포하고 물성 실험을 실시하였는바, 탈취율 시험은 KCL-FIR1004 (가스검지관에 의한 탈취율의 간이 측정방법)에 따라 실시한 결과는 표 1과 같다. Manufacturing Example A coating composition obtained through Type A was used to uniformly coat a coating composition obtained through Manufacturing Type A of the present application on a sample of a stone plate having a width of 30 cm, a length of 30 cm and a thickness of 2.5 cm, As a result, the deodorization rate test was carried out in accordance with KCL-FIR1004 (simple measurement method of deodorization ratio by gas detection tube).

표 1. 결과 시간에 따른 가스농도 및 탈취율 변화Table 1. Changes in gas concentration and deodorization rate with time


시험항목

Test Items
탈취시험(HCHO)Deodorization test (HCHO)
경과시간
(분)
Elapsed time
(minute)
Blank 농도(ppm)Blank Concentration (ppm) 시료농도
(ppm)
Sample concentration
(ppm)
탈취율
(%)
Deodorization rate
(%)


시험결과


Test result
00 8181 8181 --
3030 7878 77 91.091.0 6060 7575 44 94.794.7 9090 7272 33 95.895.8 120120 7070 22 97.197.1 180180 6969 N.DN.D. N.DN.D. 시험방법Test Methods KCL-FIR 1085KCL-FIR 1085

(비고)N.D : 검출되지 않거나 최소 검출 한계 농도 (1ppm) 미만의 농도.
(Remarks) ND: Concentration not detected or less than the minimum detection limit concentration (1ppm).

7. 항 곰팡이 성능 시험 실시예7. Antifungal Performance Test Examples

상기의 탈취율 실험과 같은 방법으로 마련된 돌판 샘플에 대한 항 곰팡이 성능을 평가하기 위하여 ASTM-G21에 의하여 시험한 결과는 표 2와 같다.Table 2 shows the results of the test according to ASTM-G21 in order to evaluate the antifungal performance of the stone plate samples prepared in the same manner as the deodorization test.

표 2 도장용 마감재에 대한 항곰팡이 성능 시험결과Table 2 Antifungal Performance Test Results for Coating Finishes

시험항목Test Items 배양시험의 기간Period of culture test 항곰팡이
시험
Antifungal
exam
1주후One week 2주후after 2 weeks 3주후Three weeks 4주후Four weeks
00 00 00 00

* 1) 시험방법 : ASTM-G21* 1) Test method: ASTM-G21

2)곰팡이균주 (혼합균주)  2) Fungal strains (mixed strains)

Aspergillus niger ATCC 9642Aspergillus niger ATCC 9642

Penicillium Ponophilum ATCC 11797Penicillium Ponophilum ATCC 11797

Chaetomium globosum ATCC 6205Chaetomium globosum ATCC 6205

Gliosiadium uirens ATCC 9645Gliosiadium uirens ATCC 9645

Aureobasidium pullulans ATCC 15233
Aureobasidium pullulans ATCC 15233

8. 항균시험 실시예8. Example of antibacterial test

상기의 탈취율 실험과 같은 방법으로 마련된 돌판 샘플에 대한 항균성능을 평가하기 위하여 KCL-FIR 1003에 따라 실시한 결과는 표 3과 같다.Table 3 shows the results of KCL-FIR 1003 in order to evaluate the antimicrobial performance of the stone plate samples prepared in the same manner as the deodorization experiment described above.

표 3. 항균시험 결과Table 3. Results of Antimicrobial Test

측정항목Metrics 측정치Measure 검사방법       method of inspection 벤젠benzene 불검출Non-detection


GC-MS 분석법



GC-MS method
톨루엔toluene 94.13/94.13 / 에틸벤젠Ethylbenzene 불검출Non-detection m.p-자일렌m.p-xylene 10.67/10.67 / o-자일렌o-xylene 불검출Non-detection 1,4-디클로로벤젠1,4-dichlorobenzene 불검출Non-detection 스틴렌Stinren 10.88/10.88 /

상기의 제조실시예 B, C, D, E 타입을 통하여 얻은 도장용 조성물을 이용하여 상기와 같은 방법으로 가로 30 ㎝ * 세로 30 ㎝ * 두께 2.5 ㎝의 돌판 샘플을 만들어 상기의 탈취율 시험, 항 곰팡이 실험, 항균실험 실시결과에서도 상기와 동일/유사한 범위의 실험결과를 얻을 수 있음으로부터 본원의 기술구성으로 제공되는 건축물 내부 도장용 조성물이 저가의 비용으로 수요자가 부담없이 구매할 수 있고 상대적으로 저가의 제품임에도 장기간에 걸쳐 공기 질 개선효과를 제공하는 효과를 확인하여 본 발명을 완성하기에 이르렀다. Using the coating composition obtained in the above Production Examples B, C, D, and E, a stone plate sample having a size of 30 cm in length, 30 cm in length and 2.5 cm in thickness was prepared in the same manner as above, As a result of the experiment and the result of the antibacterial test, the same or similar experimental results as above can be obtained. Therefore, the composition for interior painting provided with the technical composition of the present invention can be easily purchased by the consumer at low cost, And the effect of improving the air quality over a long period of time has been confirmed. Thus, the present invention has been completed.

Claims (7)

건축물의 내부 도장용 조성물에 있어서,
도장용 조성물 중 황토와 고령토의 합량이 30~40중량%를 이루고, 초산 수지인 E.V.A수지가 8~12중량%로 함유되며, 지당(백색)이 0.5~5중량%, 알긴산이 0.1~0.2 중량%, 곡사이드(엘로우)가 0.01~0.05 중량%로 함유되고 잔량으로 황토지장수가 공정수로 추가되어 100중량%를 이루어서 제공되는 것을 특징으로 하는 건축물의 내부 도장용 조성물.
A composition for internal coating of a building,
(White) is 0.5 to 5% by weight, alginic acid is 0.1 to 0.2% by weight (weight), and the amount of the alginic acid is 0.1 to 5% by weight By weight, and 0.01% by weight to 0.05% by weight, and the remaining amount is added as process water to 100% by weight of the composition.
제1항에 있어서,
상기의 도장용 조성물 100 kg을 기준으로 할 때 피톤치드가 10~30 gr이 추가되어 제공되는 것을 특징으로 하는 건축물의 내부 도장용 조성물.
The method according to claim 1,
Wherein the phytoncide is added in an amount of 10 to 30 g based on 100 kg of the composition for coating.
제1항에 있어서,
상기의 도장용 조성물 중 황토와 고령토의 배합비가 2 : 5 비율로 배합되어 도장용 조성물 중량의 30~40중량% 범위를 이루도록 제공되는 것을 특징으로 하는 건축물의 내부 도장용 조성물.
The method according to claim 1,
Wherein the coating composition is blended in a ratio of 2: 5 of the mixture of the yellow clay and the kaolin, so as to be in the range of 30 to 40 wt% of the weight of the coating composition.
제1항에 있어서,
상기의 도장용 조성물 중 황토와 고령토의 배합비가 3 : 4 비율로 배합되어 도장용 조성물 중량의 30~40중량% 범위를 이루도록 제공되는 것을 특징으로 하는 건축물의 내부 도장용 조성물.
The method according to claim 1,
Wherein the coating composition is blended in a ratio of 3: 4 of a mixture of yellow clay and kaolin in a proportion of 30 to 40% by weight based on the weight of the coating composition.
제1항에 있어서,
상기의 도장용 조성물 중 황토와 고령토의 배합비가 4 : 3 비율로 배합되어 도장용 조성물 중량의 30~40중량% 범위를 이루도록 제공되는 것을 특징으로 하는 건축물의 내부 도장용 조성물.
The method according to claim 1,
Wherein the coating composition is blended in a ratio of 4: 3 of a mixture of yellow clay and kaolin in a proportion of 30 to 40% by weight based on the weight of the coating composition.
제1항에 있어서,
상기의 도장용 조성물 중 황토와 고령토의 배합비가 5 : 2 비율로 배합되어 도장용 조성물 중량의 30~40중량% 범위를 이루도록 제공되는 것을 특징으로 하는 건축물의 내부 도장용 조성물.
The method according to claim 1,
Wherein the coating composition is blended at a ratio of 5: 2 of a mixture of yellow clay and kaolin in the range of 30 to 40 weight% of the weight of the coating composition.
제1항에 있어서,
상기의 도장용 조성물 중 황토와 고령토의 배합비가 1 : 6 비율로 배합되어 도장용 조성물 중량의 30~40중량% 범위를 이루도록 제공되는 것을 특징으로 하는 건축물의 내부 도장용 조성물.
The method according to claim 1,
Wherein the coating composition is blended at a ratio of 1: 6 of a mixture of yellow clay and kaolin in the range of 30 to 40 weight% of the weight of the coating composition.
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KR20210057970A (en) 2019-11-13 2021-05-24 주식회사 엠씨엠글로벌 The manufacturing method of paints eco-friendly using natural material
KR102239423B1 (en) 2020-12-01 2021-04-13 주식회사 에이스인더스트리 Functional paint compositions for eco-friendly construction finishing comprising the plant extract and eco-friendly construction finishing method using the same
KR102423141B1 (en) 2021-09-29 2022-07-20 주식회사 에이스 인더스트리 Functional paint composition for non-flammable and anti-bacterial eco-friendly building finishes and construction method of eco-friendly building finishes using the same
KR102502103B1 (en) 2022-08-25 2023-02-24 장성일 Inorganic paint for final finishing material with natural texture

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