KR20070087701A - Silver nano cosmetics - Google Patents

Abstract

The present invention relates to a cosmetic oil paper (10) containing silver nano and the fragrance (40),

Generally, the cosmetic oil paper 10 used by women is used to wipe away and remove semi-fluid oil or fat sebum and secretions discharged through the pores of the face, and all women and men with high sebum secretion are also required. It is used as a portable item.

Cosmetic oil paper (10) used as a mandatory portable goods of women as described above was cut to a certain size and stored in a rectangular paper or plastic or plastic case was used to take out one sheet every time.

However, the conventional cosmetic oil paper used after being cut to a predetermined size and stored in a paper, plastic or vinyl case as described above is likely to be easily contaminated by the surrounding environment such as dust. Frequent cases of impurities on the surface of

In addition, in carrying a bag or the like, cosmetic oil papers stored in a case are spilled by collisions or interferences between other portable products, and the situation is frequently caused by contamination with peripheral equipments.

Accordingly, the present invention has been made to solve the above problems,

The present invention is the lifting or facial portion of women's cosmetics made of a variety of materials, such as paper, cotton, cotton, wool, silk, burlap and artificial fiber, plastic, synthetic resin, sponge, and latex as natural fibers The oil paper (10) is used for the removal of fat or sebum from the pores of the oil. Especially, the oil paper (10) is produced using silver nano (20) and the fragrance oil paper (10). Oil containing silver nano (20) and fragrance to deodorize, deteriorate, and smell of oil, to sterilize germs that grow inside and outside the oil paper (10), and to release healthy silver ions and far infrared rays It is related to the paper (10) and the silver nano (20) powder (Nano silver) or colloidal silver (Colloidal Silver) or silver nano silver solution (AG) in the preparation of the oil paper (10) by mixing the oil paper (10) The expiration date greatly Sterilize bacteria, pathogens, and microorganisms that cause deterioration, decay, and skin troubles, and release silver nano ions and far-infrared rays, which are good for the body, to protect the skin and health of oil paper users and to improve the health and health of the people. The purpose is to work.

Description

Oil Paper {Nano silver and perfume contain oil paper}

1 is a perspective view of an oil paper of the present invention.

Figure 2 is a block diagram of the production of oil paper of the present invention.

Figure 3 is another block diagram of the production of oil paper made of plastic or synthetic resin material of the present invention.

4 is a photograph taken at 60.000 times magnification of a cross section of silver nano of the present invention.

FIG. 5 is a photograph taken at 80.000 times magnification of the side surface of the silver nano of the present invention. FIG.

Figure 6 is a photograph taken at 50.000 times magnification of the surface of the silver nano of the present invention.

Figure 7 is a photograph of the antimicrobial activity of the strain into which the silver nano of the present invention.

8 is Staphylococcus aureus, pneumococci, bacteria in which the silver nano of the present invention is added.

MRSA (Methicillin-Resistant Staphylococcus Aureus) Bacteria Antimicrobial Test Picture.

9 is a diagram showing a three-dimensional structure diagram of the silver nano of the present invention.

* Explanation of symbols for the main parts of the drawings *

10: oil paper 20: silver nano

40: fragrance 60: melting

80: stirring 100: molding process

140: Weaving 160: Noodle-making process

180: spray process 190: deposition

200: container 220: drying process

240: cutting process 260: roller process

280: Latex 300: primary foaming process

320: 1st Oaks Mixer 340: 2nd Foaming Process

360: 2nd Oaks Mixer

The present invention, as described above, the lifting of women's cosmetics made of a variety of materials such as cotton, cotton, cotton, paper, wool, silk, burlap and artificial fibers of artificial fiber, synthetic resin, sponge, latex Oil paper (10) useful for the removal of fat and sebum discharged from the pores of the face or face.

Oil paper (10) is a product manufactured by using a 100% cotton or cloth abrasive fiber, which is a natural material, including artificial materials, so that there is no skin irritation.

The human skin acts as a secretion that strikes a protective film to protect itself.

The younger they are, the more active they wash their face, and even if they don't apply lotion or cream, their skin will protect themselves after washing, so as the skin ages, the skin's aging progresses as the skin ages. The face dries out as it exits.

Oil paper (10) has a sebum removal effect around the sebum or acne causing facial lumps, and is especially used by students who secrete a lot of secretions during oily skin or puberty.

People who have a lot of sebum or secretions should not touch their face as much as possible because various germs on their hands are transferred to the face by touching the face.

If you use oil paper but keep your hands clean, there is no big problem. Most of them touch oil paper with contaminated hands. Frequent cases of oil paper spilling and contamination of the surrounding equipment, making it unusable. In addition, the case of storing the opened oil paper has no antimicrobial activity, and the facial secretions adhered to by hands when the oil paper 10 is used. It is obvious that a large amount of bacteria are being fed to feed sebum, and when it is used continuously, it acts as a major cause of skin rashes and troubles such as skin sores and podrakji and blemishes.

In particular, we are surprised by the airwaves that large amounts of bacteria lie in the hands of about 20,000 birds / cm 2 to 100,000 animals / cm 3. Oil paper 10 that people often touch with contaminated hands can be said to be contaminated with many bacteria.

 The present invention relates to an oil paper (10) to be used to remove the sebum and to remove sebum, in particular, to improve the problems of the conventional oil paper, and in particular, the silver nano 20 and the fragrance agent 40 are added or coated. Regarding the functional oil paper (10) for the bacteria growth and deodorization effect and far-infrared radiation generated in the oil paper (10),

In the oil paper 10, the antimicrobial substances silver nano 20 and the fragrance agent 40 are put into the oil paper 10, even after opening the oil paper 10 for a long time to prevent deterioration and contamination and maintain moisture. Far infrared rays and silver can have the effect of radiating ions to protect the skin of people using oil paper (10) and to prevent infection.

  The present invention is a non-chemical agent and environmentally friendly silver nano (20) powder (Nano silver) or colloidal silver (Colloidal Silver), namely nano silver solution (Ag), and natural fragrance (40) oil paper (10) ) To produce a fragrance by blending in the manufacture of) and to prevent the growth of bacteria and fungi, viruses, or the production of sediment at the source, and relates to a functional oil paper (10) capable of safe and pleasant sebum removal.

As described above, the present invention relates to an oil paper 10 containing silver nano 20 and a fragrance which greatly improves the decay, deterioration and deodorization problems of the conventional oil paper 10. Since it is simply added during the manufacture of oil paper (10) without washing, it contains powerful silver nano (20) material which is economical and sterilization and sustainability is unpredictable. Dosing consistently provides the following excellent benefits:

   Silver nano (20) is harmless to the human body and has a sterilizing power and antimicrobial detoxifying power tens of times stronger than chlorine series or acid.

If so, look at the characteristics of the oil paper (10) containing silver nano (20) and natural fragrance (40);

1: When silver is nano-ized, antibacterial, sterilization, deodorization, detoxification function is superior to any disinfectant, and oil paper (10) containing silver nano (20) generates healthy silver ions and far infrared rays when used, resulting in blood circulation and endocrine. It is very active and can have antiviral and antiallergic effects.

 2: It reacts sensitively according to the pollution level of the surrounding environment

It binds strongly to bacteria's bacterial membranes (SH, COOH, OH) and the like and destroys the bacterial cell membranes or disturbs the function of the cells and shows a continuous antiseptic action.

 Recent research has shown that 650 bacteria and viruses can be sterilized, and the proliferation suppression and antiseptic function is excellent against harmful bacteria, fungi, athlete's foot, and allergic bacteria, preventing secondary infections from other pathogens that are problematic. Silver catalyzes the conversion of oxygen into active oxygen, which prevents the growth of bacteria that propagate by bactericidal action.

  3: The silver nano 20 has an antistatic function and an electromagnetic wave blocking function to solve harmful electromagnetic waves, have excellent electrical conductivity, and suppress static electricity generation.

  4: The silver nano 20 is very easy to coat, mix, and feed with materials, and is very easy to fuse or blend with plastics, synthetic resin, rubber, and silicone.

  5: In addition, silver ions and far-infrared rays that are good for the body can be generated, which can have an effect on blood circulation and endocrine activity.

   6: It has a deodorizing effect and a fragrance diverging effect.

Oil paper (10) is the user's face secretion and sebum, dirt and dust foreign matters, the body of the oil paper (10) in the long-term use will give a very disgusting smell, the weight ratio of liquid or powder of natural fragrance raw materials during the manufacturing process In the amount of 0.01% to 10% by weight is always a gentle fragrance is emitted, the oil paper (10) has the effect of pleasing the sense of smell and increase the health.

The present invention has been made in order to solve the above-mentioned problems, as described above, natural fiber, cotton, cotton, paper, wool, silk, burlap and artificial fiber, plastic, synthetic resin, Oil paper (10) containing silver nano (20) and fragrance (40) in oil paper (10) used for absorbing sebum or secretions of women's makeup or men's makeup made of sponge, latex Regarding,

       The present invention is a silver nano-powder or silver (Ag) solution in the form of nano silver powder or silver (Ag) solution, which is a completely different technology from general silver powder or ions, to 0.01% to 20% by weight of silver nanoparticles per 100g of oil paper. 20) (Nano silver) It is formulated in a content ratio of 0.01 to 20 PPM standard, and the liquid or powder of natural and fragrance raw materials is added at 0.01% to 10% by weight, so that antibacterial function, sterilization function, deodorization effect, silver ion and far infrared ray The purpose is to produce an excellent oil paper 10 having a spinning function.

Oil paper (10) is different in size and shape depending on the type and the material is also natural, such as cotton, hemp, paper, wool, silk, artificial synthetic fibers, vinyl, latex, sponge, plastic material and The same material is made of various materials.

The present invention is a silver nano (20) and fragrance agent that can have antibacterial and deodorizing effect on the material of the oil paper (10) used to quickly absorb the sebum or facial secretions of men and sebum or facial secretions of women as described above Oil paper containing 10) and a method of manufacturing the same, which are natural fibers such as cotton, paper, cotton, wool, burlap, or artificial fibers such as plastics, synthetic resins, vinyl, and latex. As a main raw material of the sponge, additives such as pigments may be selectively mixed and mixed, or the silver nano 20 and the fragrance may be coated on the body of the oil paper 10.

The present invention relates to an oil paper (10) used for makeup or sebum removal or to absorb facial secretions, as described above, a silver nano (20) powder (Nano silver) which has a strong antibacterial and bactericidal effect on the oil paper (10). ) And colloidal silver (ie, silver solution (Ag) and the natural fragrance (40) to the input of the constituent material of the present invention to aid the understanding of the silver and silver nano (20) in detail As follows.

 Silver, the main component of silver nano (20), has been recognized as a precious metal of high value since ancient times, and has been the object of sampling. It is not only valued as a currency but also attracted attention as an important industrial material in modern industry. Production and proportion in many ways. Silver was mined early in Europe's Mediterranean coast, where silver was produced from the Incas and Aztecs before the Americas discovery, and later from Peru and Bolivia.

 Silver flowed into Europe, and the flow of silver went from 1520 to 1800.

It has grown steadily, but has declined since the discovery of large amounts of silver in the early 19th century. Currently, the world's major silver producers are Russia (13.8%), Canada (13.5%), Mexico (13%), Peru (13%), United States (11%), Australia (8%), Poland (6%). The country's silver reserves are 17 million tons, and its reserves are about 9.2 million tons. As of 2002, the amount of silver produced in our country is about 5,000 kg, which is 1.2% of the total domestic demand. It's a very small amount.

Characteristics of silver: The color of silver is gray in the case of elegant gray-white metal or powder, specific gravity is 10-12, Mohs hardness is 2.5-3, and melting (80) point is 960.5 ℃.

In particular, the melting point of silver (80) is very important for temperature compensation of high thermometers, which is the standard of scientific and industrial temperature, and silver is the best conductor of metal, and is used comprehensively for contacts and other electronics. Optically, the reflectance for visible light is 90%

It is one of the most excellent metals, such as platinum, and sterling silver does not produce rust even when left in the air or heated. However, the film of the camera should be especially careful because it reacts with sulfur and hydrogen sulfide to make silver emulsified silver.

     In addition, the mechanical properties change depending on the amount of impurities (O₂) contained in the silver, and the hardness of the high-purity silver obtained by thermal annealing is Brinell hardness HBS (10/500) 25-27, tensile strength 12-16kgf / mm2. The cast strength of the cast was up to about 29 kgf / mm 2, elongated 48 to 54%, and the recrystallization temperature was 150 ° C.

    In particular, in the case of pure silver, the processed hardened material is softened by recrystallization at normal room temperature and softened softly. The malleability and flexibility are abundant after gold, and the thin silver plate, which is thin silver plate, can be spread to a thickness of 0.2 μm.

     Silver's efficacy has been used as a tool to check the imbalance of the body that the person does not feel because the gloss or color changes depending on the condition of the body when worn on the body since ancient times. Fatigue or low rhythm) and Dongbobom said that it is effective in the prevention and treatment of mental disorders and gynecological diseases such as epilepsy and game, and it also acted as a herbal medicine powdered silver. The five chapters are comfortable, the mind and body are stable, and the main body writes that it prolongs morale by lightening the body and lengthening the body.

      Also, when the Black Plague prevailed in the Middle Ages, nobility of the black aristocrats and royals, who had many silverware and silver utensils, did not have black plague, which released silver to the extent that it was able to sterilize the Black Plague bacteria, making it relatively safe from infectious diseases. In the place where the royal family and the state guests were served, silver products were used habitually.

In order to help the understanding of the silver nano 20, the present invention will be described briefly with respect to the silver nano 20 (Nano silver) extraction method and features.

The atomic weight of silver is 107.87, and silver (Ag) has been known for a long time, regardless of east and west. Silver Nano 20 was first developed by a biotechnology company, a government subsidiary of our country, and was named Silver Nano 20 as a compound of the brand names Nano-technology and silver;

  Silver Nano (20) is a field of Nano-technology, which is an advanced antimicrobial agent that utilizes silver's strong antibacterial and sterilizing function and electromagnetic shielding mechanism. Silver nano (20) is unlike the traditional antibiotics, bacteria are not resistant to the silver nano (20) has been confirmed to kill almost all single cell germs on the ground in a short time.

 Currently, a variety of products based on silver nano (20) consisting of powder and solution have been invented and produced in real life. This technology, called silver nano (20), produces silver nano It is a small particle size of 1 million meters (1 billionth of a meter), or 0.000000001mm, and nanoparticles of 1 gram of silver can make 10 particles.

Therefore, silver nano (Ag) nano-nano-micronized in the form of ultra-fine particles (20) is a new concept produced by utilizing the excellent efficacy, such as antibacterial deodorizing power, extending the preservation time of food among the many properties of silver.

 Since ancient times, silver has been recognized as a disinfecting substance that not only prevents bacteria but also East and West. The extraction method of silver nano (20) which is currently used injects silver (Ag 99.9%) into distilled water and generates low current at low temperature. After electrolysis of the silver-containing compound, electrophoresis using the + and-poles of each molecule can be used to collect silver (Ag 99.9%) and other physical methods such as liquid reduction and grinding. In order to obtain a stable silver nano (20) (Nano silver) it is used a lot of the above electrolysis method.

Silver ions are also used in general sterilization concept machines and disinfectants, and all silver products currently used are silver obtained by decomposition, and the addition amount is very small. The sterilization power of silver varies depending on the product, but a maximum of 99% can be obtained.

 The silver nano 20 of the present invention has a particle diameter of 0.1 to 300 nm and has a particle size of 0.1 l to 50 μm of silver nano 20 coated on the oil paper, and acts directly on harmful bacteria. In addition, it dissolves cell membranes of harmful bacteria directly and sterilizes them by interfering with electron transfer system of harmful bacteria, so it has good and excellent antibacterial and bactericidal power (= 99.9%).

     The main antimicrobial mechanism of silver nano (20) is to dissolve harmful bacteria cell membranes and interact with enzymes in the cells to block the metabolic function of nutrients, ie, the influx and discharge of nutrients, and to stop the respiratory function and production of harmful bacteria. And destroys regenerating ability to kill harmful bacteria.

     In addition, the silver nano (20) to control the harmful bacteria by continually release the antimicrobial force from the fine particles, so the antimicrobial / antibacterial function of the excellent durability.

Therefore, silver nano (20) does not produce resistance and silver nano (20) is effective to perform a surface reaction and kill all the germs 99%, particularly effective in the general E. coli or food poisoning.

   In other words, the larger the surface area, the smaller the nanoparticles, the better the bactericidal and antimicrobial activity. Strongest

Up to MRSA (Methicillin-Resistant Staphylococcus Aureus) can be 99.9% antibacterial and bactericidal.

     Even if silver (Ag) is present in an ionic state or a metal state, it may be referred to as colloidal silver when it is present in a colloidal state by a solvent.

Silver nano (20) is the best antimicrobial activity is the silver nano (20) to maximize the surface area by minimizing particles.

 Unlike the general chemical antibacterial agent or chlorine disinfectant, silver nano (20) is an ultrafine particle of pure silver, and has excellent antibacterial / antibacterial ability (99.9%) even at high temperature.It is nontoxic and non-irritating to the human body. It has been reported that the silver nano 20 cannot be in contact with it for more than 5 minutes.

Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.

Figure 1 is a perspective view of the oil nano (10) and oil paper 10 containing the fragrance of the present invention when people use the compact, twin cake, foundation to remove the fluffing makeup or sebum or facial secretions The paper 10 is shown as a picture,

2 is a block diagram of a natural oil paper 10 containing silver nano 20 and fragrance of the present invention. It is deposited in a solution in which the silver nano 20 material and the fragrance agent 40 of 0.01% to 20% by weight of the fiber material are dissolved. The silver nano 20 particles have a particle size of 0.1 to 300 nm and the oil The silver nano-coated film is formed on the surface of the oil paper with a thickness of 0.0l to 50 μm of the silver nano 20 coated on the paper, and after wetting the nano silver solution and the fragrance 40 after drying, the weaving 140 is performed. Weaving (140), knitting, through a machine in the range of 0.1% to 20% by weight of silver nano yarns (threads) manufactured through the process and cutting process, or made of silver nanomaterials when weaving It is shown in the block diagram of sewing and manufacturing.

Figure 3 is a block diagram of the production of oil paper (10) made of artificial nanofibers containing silver nano (20) and flavor of the present invention.

Artificial chemical fiber, synthetic resin, plastic, vinyl, non-woven fabric, spin lace, polyester,

The material of various oil paper 10 made of silicon, latex, sponge, rubber, microfiber, silver nano 20 material and fragrance agent 40 to the above artificial fiber or fabric which is a raw material of oil paper 10 0.1% to 20% by weight of the nanoparticles of the nanoparticles (20) is characterized by having a particle size of 0.1 to 300nm and the fragrance agent 40 of the present invention is 0.01% to 10% by weight in artificial fibers or fabrics Fragrance to give off fragrance, or when weaving silver nano 20, the silver nano yarn (thread) made of silver nano material is woven through a machine in the range of 0.01% to 20% by weight on artificial fibers or fabrics ( 140) It shows the process of manufacturing by knitting, sewing and sewing.

Next, a brief description of various preferred methods of preparing by adding the silver nano 20 and the fragrance 40 of the oil paper 10 of the present invention as follows.

1. Pre-treatment step,

Plastic, synthetic resin, latex, vinyl, nylon and polyester fibers, which are artificial chemical fibers incorporating and manufacturing silver nano (20) ash and fragrance (40) in powder type,

 In the polymerization of the fibers, silver nano 20 material and fragrance agent 40 are mixed to prepare antimicrobial oil paper fibers.

  2. Post-treatment method,

  As a method of imparting the silver nano 20 material to the fiber by the post-treatment method, ① ① silver nano 20 material and fragrance agent 40 are mixed and applied to the fiber by spraying ② silver like the dyeing process Process of dipping and immersing the oil paper 10 raw material in the liquid to which the nano (20) ash and the fragrance agent (40) are added. ③ Padding the liquid containing the silver nano (20) ash and the fragrance agent (40). By a pad method or a coating method.

Antimicrobial and deodorant processed textiles are generally processed to the final stages of post-dyeing processes.

  At this time, in order to improve the durability of the silver nano 20 material and the fragrance agent 40, the silver nano 20 material and the fragrance agent 40 component are fabricated through a synthetic resin capable of crosslinking the reactive resin and the fiber or forming a film. It is also possible to use a method of fixing to the surface.

 3. Reactive resin mediated method,

  This processing method is a silver nano (20) ash and a fragrance agent (40) on the surface of the fiber and then cross-links the components with the fiber and at the same time, the silver nano (20) ash and fragrance agent (40) ) Is a method of heat fixing.

 Aqueous solution of quaternary ammonium chitosan and a film-forming reactive resin is treated on a latex, nylon, or polyester fabric by spraying, padding, or coating, followed by heat treatment at a temperature of 130 ~ 180 ℃. Heat immobilize on.

 4. The method of immobilizing the antimicrobial agent on the fiber surface,

  This processing method is a method of adsorbing and immobilizing silver nano 20 ash and fragrance 40 on a fiber surface using a chemical reaction.

 5. Method of using organic silicon quaternary ammonium salt,

In this process, organic silicon-based quaternary ammonium salts are covalently bonded to hydroxyl groups and trimethoxyl groups on cotton fiber surfaces to fix silver nano (20) ashes and fragrances (40) on the fiber surface, and at the same time the surface of the organosilicon coating Coating method.

  For example, organic silicon-based quaternary ammonium salts are treated on the surface of cotton fibers by a deepening method or a padding method, followed by drying at 80-120 ° C. to remove water or methanol. By this operation, the silver nano 20 ash and the fragrance agent 40 are undispersed in water to decompose the trimethoxyl group to covalently bond the fiber surface, the silver nano 20 ash and the enzyme atom of the fragrance agent 40, The reactive resin of organosilicon is graft polymerized to form a very strong thin film and the antimicrobial agent is heat fixed.

  Antimicrobial agents used in the antibacterial and deodorized processed fibers, in addition to the silver nano 20 of the present invention, various types such as organometallic, guanycin, halo sialyl urea, phenol, fatty acid ester, natural (chitosan, hinokichiol, etc.) It is used for antimicrobial processed fiber.

The quaternary ammonium salt-based antimicrobial agent occupies an overwhelming position as an organic antimicrobial agent, and the use of the organosilicon quaternary ammonium salt is prominent.

  Brief description of the quaternary ammonium salt-based antimicrobial agent has a structure in which four hydrocarbons are bonded to a nitrogen atom in terms of chemical structure.

Of these, ospan (benzalkolium chloride), which is used as a disinfectant in water washing, is an organosilicon quaternary ammonium salt which is widely used for textiles, such as 3-trimethoxysilyl propyl and dimethyloctadecyl. And ammonium chloride.

  There are two antimicrobial mechanisms of quaternary ammonium salts, one of which is the physical destruction of the cell membrane. The cation of ammonium molecules binds to anion sites on the bacterial surface and physically destroys the cell membrane by hydrophobic interaction.

Another is the action of inhibiting metabolic function (growth) by quaternary ammonium salts strongly adsorbed to bacteria and inhibiting enzymes in cells due to the inhibition of bacterial metabolism.

 6. Fixed method by sputtering,

  Sputtering has been used to form thin films since Grove's discovery in 1852. Sputtering methods include direct current dipole sputtering, high frequency sputtering, macronet sputtering, and reactive sputtering.

  In this process, polyester is washed with a taffeta cloth with a neutral detergent and dried, and then the sample is placed in a drum in the chamber of the Macnetron sputtering apparatus, and the pressure is first reduced to 1 × 10-3 Pa in the vacuum apparatus, followed by argon. While filling the gas, adjust the pressure to a predetermined pressure, and discharge the DC current at a voltage of 100 to 1000 V for 30 minutes to remove impurities adhering to the target (silver, copper, titanium) surface. Subsequently, it is preferable that the drum is sputtered for a predetermined time (12 to 20 seconds) while circulating the cooling water at 18 ° C by suppressing the temperature rise of the target by setting the rotational speed to 10 rpm.

Next, another preferred method of preparing by adding the silver nano 20 and the fragrance 40 of the oil paper 10 of the present invention will be described.

The silver nano 20 and the fragrance agent 40 are added to any one process selected from the process of woven fabric 160, a roller process 260, and a spray 180 process, which is a raw material of the oil paper 10.

 The manufacturing work of the oil paper 10 of the artificial textile chemical material is largely made of five processes: a noodle making process, a roller process 260 (the dipping process), a spraying process, a drying process, and a cutting process 240.

The noodle (공정) process is a process of making a fabric that is literally a body of oil paper 10 by squeezing out of artificial fiber-based chemical fiber yarn.

Artificial fiber means any fabric made without weaving or knitting, that is, without weaving (140)

The process of unplugging and re-weaving or scooping the fabric from short core oils requires a lot of effort.

Several methods have been invented.

① How to make from felt ② How to make from film ③ How to make fibers into felt state ④ How to make felt state sheet on rubber or plastic support ⑤ How to weld heat softened fiber ⑥ How to make fiber There are preferred methods of the present invention, such as those made by combining with a suitable solvent.

Therefore, the manufacture of artificial fibers consists of two parts: the web of fibers and the bonding. For 1 kg of fiber, a normal oil paper (10) can produce 30 to 40 meters, which is about 2 It is made of billion fiber of myriad thin fibers.

Therefore, making a web from fibers is more difficult than joining the fibers and there are two preferred methods for the webs: orienting the fibers and randomly arranging them (random web).

Orienting the fibers is the same as making ordinary fabrics. Cross-aligned webs are created to compensate for this, because the well-arranged, parallel fibers are weak in the transverse direction. Is one web placed on the other as close to the right angle as possible, which is much slower to manufacture than a parallel array web.

The random web is made of a special machine that combines a feeder called Lando Feeder, Lando Weber (trade name of US Collator), and a web-making device, which blows the fibers onto the screen and presses the random web.

The fibers in the form of webs are bonded to each other, and examples of the binder include polyvinyl acetate, rubber, sponge, latex, urea formaldehyde, polyvinyl chloride dispersion, water-soluble carboxymethyl cellulose, and the like.

 In addition to the methods described above, there is also a method in which thermoplastic fibers are mixed with other fibers to be melted (60) with a solvent or heat to bond the fibers. Artificial chemical fibers are more elastic than natural fibers, and have resilience, tensile strength, shrinkage and abrasion resistance. Because of its large size, it is mainly used for rayon, synthetic resin, latex, nonwoven fabric, polyester, and nylon.

The most common uses are apparel wicks, and other materials such as bed sheets, towels, blankets, iron pallets, carpets, napkins, shoe insoles and upholstery. In the case of oil paper 10, the yarn It's blown by the wind, captured on the screen, and sorted by clicking on the random web.

 The fibers in the web form are bonded to each other and the binder (Binder), which is a binder, is sprayed onto the chemical fibers so that the bonds are maintained without being scattered.

The fabric for the oil paper 10 manufactured through the noodle making process 160 is introduced into the pigment and the film-forming crosslinking agent through the roller process 260. The roller process is also referred to as a dipping process.

The fabric for the oil paper 10 manufactured through the noodle making process 160 is pressed while passing through the first roller, and then colored through the container 200 containing the pigment and the film-forming crosslinking agent. At the same time, the film-forming crosslinking agent is combined to form a strong tissue fabric.

The fabric contained in the pigment 200 containing the pigment and the film-forming crosslinking agent and then released again is compressed through the roller, which is the secondary roller process, and the fabric is thick due to the secondary roller process 260. Can be kept flat and constant and can be said to be a process for increasing the flatness of the fabric.

Next, the spray process 180 refers to the oil paper 10 by uniformly applying the film-forming crosslinking agent to the pigment-coated oil paper 10 through the mechanical sprayer once again through the roller process 260. The process of increasing the strength and after the spray 180 process is completed through the cutting process 240 in accordance with the specifications of the oil paper 10 of the present invention to complete the product.

After the spray 180 process, the functional oil paper 10 containing the silver nano 20 and the fragrance 40 of the present invention is finally completed through the drying process 220.

Drying is a natural drying and artificial drying (220) method, the natural drying is to dry in the shade, artificial drying is to dry by forced air through hot air or warm air.

In the manufacturing process of the oil paper 10, the addition of the silver nano 20 material and the fragrance agent 40 of the present invention may be performed in any of the preferred processes of the noodle making process 160, the roller process 260, and the spray 180 process. Is committed.

Preferred addition ratio is 500g / kg pigment, crosslinking agent 200g, / kg, adhesive 100g, / kg, other additive 200g / kg, silver nano (20) material and fragrance (40) additives and oil paper (10) 0.01% to 20% by weight of silver nano (20) of the combined weight percent of the fabric is composed of a proportion of 0.01% to 10% by weight of the fragrance (40) for the oil paper (10) while passing through the container (200) The fabric is doped.

At this time, the silver nano 20 material and the fragrance agent 40 are also bonded together with the pigment and the film-forming crosslinking agent. In order to give the color of the oil paper 10, the pigment is added to the surface of the oil paper at 0.1% to 5% by weight. It is also preferable that 0.1% to 5% by weight of the curing agent or flocculant is added in order to promote flocculation of the oil paper 10.

The doped fabric from the container 200 is adhered evenly and strongly spreading in the fabric as it passes through the roller again, and in the spray 180 process, the film-forming crosslinker, the liquid adhesive, the silver nano 20 material, and the fragrance ( 40) are sprayed together by stirring (80).

At this time, the addition ratio of the pigment 500g / kg, the film forming cross-linking agent 200g, / kg, the adhesive 100g, / kg, other additives 200g / kg of the same ratio and the silver nano (20) material and the fragrance (40) and the additives 0.01% to 20% by weight of the silver nano (20) in the weight percent ratio of the oil paper (10) combined with the fragrance (40) in a ratio of 0.01% to 10% by weight and the size of the silver nano (20) fine particles is 0.1 To have a particle diameter of 300 nm.

   Figure 4 is another block diagram of the production of silver nano 20 and the oil paper 10 containing the fragrance of the present invention, the process of manufacturing the oil paper 10 of the sponge, latex, material according to an embodiment of the present invention As the flow chart shown,

Referring to the oil paper 10 produced by foam molding 100 using a sponge or latex as a main material is as follows.

The latex storage tank primary foamer 300 and the OAKES MIXER 320 and the secondary foamer 340 and the Oaks mixer 360 which store the latex 280 and other additives, which are the main materials of the sponge, as a whole. The molding machine is connected in series with the corresponding pipe.

In the latex storage tank, a stirring 80 mixing a latex 280 with 0.01 to 20% by weight of the silver nano 20 of the present invention, 0.01 to 10% by weight of a fragrance agent 40 and a pigment or other additives (80) Means are provided, and a metering transfer device, such as a mono pump, for example, for discharging the stirred 80 mixed latex mixture at an appropriate rate.

In the latex storage tank, a liquid latex (280) mixture of 0.01 to 20% by weight of silver nano (20), 0.01 to 10% by weight of fragrance (40), and an additive and agitation (80) is connected to the pipe by the metering device. Through the primary foamer.

The conveyed latex (2800 mixture is foamed into the primary Oaks mixer 320 as air is injected through the primary foamer to form a foamy primary foam, where the amount of air injected through the primary foamer is the overall process 80% of the amount of air used is preferred.

Bubble-shaped primary foam formed in the primary foamer is transferred to the secondary foaming process 300 through a corresponding pipe connected to the primary Oaks mixer 320, the air is injected through the secondary foamer secondary The Oaks mixer 360 is formed of a secondary foam 340 sieve.

Here, the amount of air injected through the secondary foam 340 is preferably 20% of the total air usage.

The secondary foam formed through the secondary foamer is moved to the molding machine 100 through a corresponding pipe connected to the secondary oak-ser mixer, molded in the mold (100) and thereby the oil paper of latex 280 or sponge material ( 10) to be prepared.

That is, the latex 280 or sponge oil paper 10 of the present invention, as described above, the primary foamer 300 and the primary oak mixer 320, the secondary foaming process 340 and the secondary oak mixer ( 360 is placed in series, and the latex 280 mixture is sequentially foamed on a secondary basis, while the stored latex 280 mixture is sequentially transferred along the corresponding pipe through a metering feeder formed in the storage tank. According to this circulation process is repeated a number of times until the desired structure and density of the cell is obtained, and during the final foaming, the coagulant or hardener is added while foaming without injecting air, and the opening and closing operation of the valve device The final foam is transferred to a molding machine 100, and molding 100 is completed after drying.

Oil paper 10 of the present invention is a combination of silver nano 20 and the fragrance agent 40 is a cell structure of various sizes and densities, including antiseptic function, fragrance divergence function, electromagnetic wave blocking, humidity control function It can help prevent skin problems, rashes and eczema in women and men.

 5 is another manufacturing block diagram of an oil paper 10 made of silver nano 20 and flavor-containing plastic or synthetic resin material according to the present invention.

After removing foreign substances of plastic or synthetic resin, it is put into the container 200 and melted by melting 60. Then, paint, crosslinking agent, curing agent and other additives are added to the material, and silver nano (20) is added to the material. 0.01 to 20% by weight of the ash and 0.01 to 10% by weight of the fragrance (40) was added. At this time, the silver nano (20) ash and the fragrance (40) were also bonded together with the pigment and the film-forming crosslinking agent. In order to promote the color of the pigment, 0.1% to 5% by weight of the oil paper is added to the surface, and in order to promote coagulation of the curing of the oil paper 10, 0.1 to 5% by weight of the curing agent or flocculant is added to the stirring ( 80) After inserting into the roller and going through the pressing process, and then inserted into the case of the oil paper after the cutting process, after inspection and packaging and completing the step is shown in the block diagram.

  Looking at the manufacturing method of the preferred oil paper 10 made of a plastic or a synthetic resin material according to the present invention for achieving this object,

1, injection molding

 It is suitable for mass production of complex shaped products by injection molding of the molding material by heating melting 60, injection filling into a cavity of a pre-closed mold, and then solidifying or curing to form a molded article. It is a large field.

 As the molding materials used for injection molding, thermoplastic resins are applied to almost all molding materials such as main or thermosetting resins, rubber and foam molding materials, and various processing machines and mold structures have been developed in consideration of the types of molding materials and the shape of molded articles.

The figure shows an example of the molding of thermoplastic resin, shows the state that the mold is closed and the injection is completed, and the mold is opened after the molding material is solidified and the mold is released. The mold is usually cooled through water so that the molded part is automatically extracted.

 Molding is carried out as follows: ① body, ② injection, ③ holding pressure (this series of processes to prevent backflow of the material filled in the cavity and extract it by cooling is repeated as one cycle). The in-line screw injection molding machine (100) is a standard type, and the screw retreats by gasification of the molding material, and when the injection is performed, the screw moves forward to extrude the molding material, and the molding machine of this type is also used for molding the thermosetting resin. .

Compared with the thermoplastic resin, when the mold is heated to cure the resin, the temperature of the heating cylinder is lowered to prevent the resin from solidifying, and thus, the heating method of the cylinder and the shape of the screw are somewhat different.

Next, as a method of determining the injection molding conditions;

1, extrusion

 The silver nano 20 and the fragrance agent 40 are introduced into a thermoplastic material on the surface of various thin base materials such as paper, cloth, cellophane, plastic, film, metal film, etc., and are heated by melting 60 for heat using an extruder. After making it into a state, it is the process method of extruding to thin film form at the time of T, and simultaneously crimping continuously. The combination of the properties of the substrate and the characteristics of the extruded and compressed thermoplastics (water resistance, moisture resistance, chemical resistance, flexibility, toughness, breathability, heat seal synthesis, etc.) creates a packaging volume layer material adapted to a variety of applications, but is currently in use. The mainstream ones are low density polyethylene, polypropylene, vinylene chloride resin and the like.

2. Compression-molding

 In the most common molding method of the thermosetting resin, the molding material in which the silver nano 20 and the fragrance agent 40 are added is put into a recess (called a cavity) of a heated mold and press-molded by a compression molding machine (press). (100).

 The molding material is heated in the cavity and once flowed, spreads to every corner of the cavity and causes a simultaneous chemical reaction to cure.The mold is opened after a suitable time (called curing time), and the finish is removed after flash removal, etc. To get the product. If the molding process is largely divided into molding process and finishing process. The molding 100 process is performed as follows: ① Molding material processing Weighing (sometimes, the turret machine is used to process the turret) ② Inserting the material into the cavity (previously preheated)

 ③ Pressurization operation ④ Curing process ⑤ Molded product removal Mold cleaning.

Finishing process includes ① flash removal ② gloss, etc. For large products or thick ones, high-frequency preheating is usually performed for efficiency and quality improvement, and the curing time is appropriate to obtain the optimum degree of curing depending on the molding temperature or the thickness of the molded part. You have to decide. In the case of thermoplastic products, compression molding is performed in the case of molding thick products or producing a small film. In this case, the trick is to remove the molded article by cooling the mold after heating and pressing the molding material. In general, the compression molding is characterized by less molding of the dielectric material or molecules compared to injection molding or transfer molding, so that a molded article having less internal stress can be easily obtained.

 3, extrusion-blow molding

 Thermoplastic is inserted into one or two or more molds of flies, continuously extruded into a tube from an extruder, by heating the plastic material into which the nano (20) and the fragrance (40) are injected (60). Blowing air into the fly hand in the rear mandrel to expand, the fly hand is in close contact with the mold inner wall to make the oil paper (10) is the most popular blow molding method.

 4, blow molding

 It is a method of softening by heating in a split mold to inflate the flyson or sheet into which the thermoplastic plastic, silver nano 20 and fragrance agent 40 are injected, by using pneumatic pressure, etc. Called molding or blow molding 100.

Normally, the molten thermoplastic molding material for heating (60) is extruded or preformed into a tube according to the injection method, or a sheet or a sheet of two pieces of sheets, which are pre-molded into a blowing mold, and then softened by heating and air therein. Blowing to form a hollow product.

There are various types of blow molding depending on the Paris shaping state molding method and the like, such as injection blow molding, extrusion blow molding, sheet blow method (sheet flyson method), direct blow molding, and injection blow molding.

5, casting

 A liquid retaining resin solution or a compounded rubber latex liquid and a silver nano 20 and a fragrance agent 40 are introduced into an open type or cotton, and the molding method is solidified by drying or polymerization under normal pressure. In thermally curable plastics it is used as a monomer to prepolymer or polymer solution in the initial condensate or in free polymer thermoplastics.

 6, vacuum forming

 After heating and softening the thermoplastic plastic sheet into which the silver nano 20 and the fragrance agent 40 were injected, the soft plastic sheet was placed on the mold, and the gap between the tongue and the sheet was vacuumed, and the sheet was brought into close contact with the surface of the mold and cooled. After fixing the phenomenon of the molded article, on the contrary, air is sucked out and the molded article is taken out. If a female is used, it is called a straight forming, and if a male is used, it is called a draping forming.

1 is a perspective view of an oil paper of the present invention.

Figure 2 is a block diagram of the production of oil paper of the present invention.

Figure 3 is another block diagram of the production of oil paper made of plastic or synthetic resin material of the present invention.

4 is a photograph taken at 60.000 times magnification of a cross section of silver nano of the present invention.

FIG. 5 is a photograph taken at 80.000 times magnification of the side surface of the silver nano of the present invention. FIG.

Figure 6 is a photograph taken at 50.000 times magnification of the surface of the silver nano of the present invention.

Figure 7 is a photograph of the antimicrobial activity of the strain into which the silver nano of the present invention.

8 is Staphylococcus aureus, pneumococci, bacteria in which the silver nano of the present invention is added.

MRSA (Methicillin-Resistant Staphylococcus Aureus) Bacteria Antimicrobial Test Picture.

9 is a diagram showing a three-dimensional structure diagram of the silver nano of the present invention.

In the above, the configuration of the oil paper 10 of the present invention has been described. For the anti-sterilization of the oil paper 10 of the present invention, silver nano (20) material is extremely preferable, and the amount of blending is based on the material of the oil paper (10). Preference is given to 0.01 to 20% by weight, respectively.

 At 0.01% by weight or less, there is no effect of disinfection and deterioration. At 20% by weight or more, it is difficult to manufacture the oil paper 10 of the present invention because the price increase and viscosity are too high because the silver nano 20 is expensive. Because.

 In addition, the fragrance 40 of the natural fragrance of the present application can not expect the aroma function when used in less than 0.01% by weight, and more than 10% by weight of the fragrance can be sensed olfactory discomfort and dizziness.

  As described above, the present invention comprises 0.01 to 20% by weight of silver nano 20 solution or powder in oil paper 10 made of artificial chemical fiber or natural fiber fabric and fibers, and the silver nano ( 20) The particle size is characterized by having a particle size of 0.1 to 300nm, prepared by adding the fragrance agent 40 at 0.01 to 10% by weight to sterilize the bacteria remaining in the oil paper (10) and good for the body Functional oil paper (10) containing silver nano (20) and fragrance bases to emit silver ions, far infrared rays and fragrances to enhance the safety and effectiveness of oil paper (10) and oil paper (10) The purpose of the present invention is to protect the face and skin by using a healthy and clean oil paper (10) by blocking the infection and bacterial breeding of the user's hand or human secretions and the manufacturing method of the oil paper is a conventional oil paper manufacturing method The weight ratio is according to the weight ratio, which can vary sufficiently.

The present invention described above is not limited to the above-described exemplary embodiment and some accompanying drawings, and various substitutions, modifications, and changes can be made without departing from the technical spirit of the present invention. It will be apparent to those of ordinary skill in Esau.

Example 1

Applicant will test this

1.The oil paper (10) of the natural cotton material which the second year high school girl uses five times a day for 15 days now,

1. With oil paper (10) of the natural hemp material which a male high school student uses three times a day for one month,

An oil paper (10) made of chemical fiber material used by women in their 20s and 3 times a day for 1 month,

3. Forty full-time housewives who are over 40 sebum injectors purchased the remaining oil paper 10 of chemical material in use for 5 days a day for 20 days, and carried out a bacteriological test at a chemical laboratory to show the following results. And women who were participants.

Example 2

In order to test this, 10PPM pure silver colloid obtained by decomposing the silver rod into D / C current by purchasing a silver nanogenerator that generates silver ions stably with high purity in order to test the above various oil papers (10) Make a solution (Silver Colloidal Solution), and add 10% by weight of the aroma fragrance powder purchased from Samhwa Co., Ltd. to 10PPM, and add 10L of silver nano solution water to the sterilized tank. The various oil papers 10 were deposited at room temperature of 20 ° C. for 30 minutes to deposit silver ions, and then dried in a drier for 60 minutes, and before and after the silver solution treatment, Staphylococcus aureus, pneumococci, bacteria, MRSA (methicillin The average values obtained by measuring the number of resistant Staphylococcus aureus are briefly shown in the analysis table below. It gained a faint feeling of natural aromas drifting from the paper (10) confirmed that the industry can be fully applied to cosmetic and accomplished the present invention.

In the above, the embodiments or preferred embodiments of the present invention are easily described.

Those skilled in the art to which the present invention pertains will understand that the spirit and scope of the present invention described in the claims below can be variously modified or modified within the scope of the present invention.

The present invention has been made to solve the above-mentioned conventional problems, as described above, natural fibers (cotton, cotton, paper, wool, silk, burlap and artificial fibers, plastic, synthetic resin) , Vinyl, sponge, latex (280) as a material of the oil paper (10) used to modify the lifting or sebum or secretion of women's makeup made of various materials,

As described above, since the oil paper 10 of the present invention has an excellent effect for protecting the skin of a man or a make-up man and sterilization and storage of the contents, it contains silver nano 20 having excellent humidity control ability. It is a useful invention having a very excellent effect compared to the oil paper (10).

As described above, the present invention, as described above, the present invention is a silver nano (20) (Nano silver) powder or silver (Ag) solution having a number of the advantages in the body of the oil paper (10) 0.01% to 20 % By weight or PPM by weight of 100 g of oil paper (Nano silver) in the content ratio of 0.01 to 20 PPM standard range, and the liquid or powder of the fragrance raw material in a ratio of 0.01% to 10% by weight As it is manufactured, oil paper (10) that is easy to produce decay, alteration, degeneration, and bacteria, pathogens and microorganisms can be used cleanly and sanitarily until the end of its life, which has the effect of contributing to the protection of important face and skin of the human body. It is a useful invention that can be.

Those skilled in the art to which the present invention pertains will understand that the present invention can be variously modified or modified without departing from the scope and spirit of the present invention described in the claims below. .

The table below shows one example of a diagram in which Staphylococcus aureus, pneumococci, bacteria, and MRSA (Methicillin-resistant Staphylococcus aureus) were injected with silver nano (160) at 5% and killed after 30 minutes. It can be seen that nano has excellent bactericidal power.

test subject unit Number of strains  5% nano addition (after 30 minutes) Staphylococcus aureus CFU / mL 3.4 X 10 ³ 0 Pneumonia group CFU / mL 3.1 X 10 ³ 0 MRSA (Methicillin Resistant Staphylococcus Aureus) CFU / mL 1.3 X 10 ² 0 bacteria CFU / mL 3.4 X 10 ² 0

  (This test report is the analysis data of Korea Testing Institute)

Claims (9)

In the fabric of natural fiber or artificial fiber and oil paper used to remove sebum, fat or human secretions formed of any one of paper, synthetic resin and plastic, Oil paper, characterized in that it is formulated or coated on the surface of the oil paper by adding a silver nano solution or powder in 0.01 to 20% by weight of the fragrance liquid or powder in a weight ratio of 0.01 to 10% by weight. The method according to claim 1, Silver nano-containing oil paper, characterized in that the particle size of the silver nano (20) particles injected into the surface of the oil paper has a particle diameter of 0.1 to 300nm. The method according to claim 1, Oil paper, characterized in that the silver nano-coated film is formed on the surface of the oil paper to a thickness of 0.0l ~ 50㎛ thickness of the silver nano (20) coated on the oil paper. When weaving oil paper 10, silver nano yarn (thread) made of silver nano material Oil paper characterized by being woven or woven by blending silver nanomaterials with 0.01 to 20% by weight in the total weight of cloth or fiber, which is the material of oil paper. The method according to any one of claims 1 to 5, Oil paper characterized in that the silver nano (20) (Nano silver) solution or powder is formulated or coated on the surface of the oil paper in a weight ratio in the range of 0.01 to 20 PPM silver silver (20) (Nano silver) per 100 g of oil paper.  Oil paper, characterized in that the pigment is added to the surface of the oil paper in 0.1% to 5% by weight to give the color of the oil paper (10). The method of claim 6, Oil paper, characterized in that 0.1% to 5% by weight of the curing agent or flocculant is added to promote the aggregation of the oil paper (10). The method according to any one of claims 1 to 7, The antimicrobial material is an oil paper, characterized in that the nano silver colloidal solution (Silver Colloidal Solution). Oil paper, characterized in that it is molded (100) through a foaming process through a foaming machine after stirring silver nano (20), fragrance material, pigment and flocculant to artificial latex or sponge raw material of artificial fiber.

Images