KR20060066150A - Composition for hair dye comprising main extract, lettuce leaves or lettuce extract and its manufacturing method - Google Patents

Abstract

The present invention relates to a hair dye composition comprising the extract from the leaves, berries, stems and roots of the natural mulberry tree as a main component and a method for preparing the same, more specifically, The present invention relates to a hair dye composition having a hot water extract and an alcohol extract or powder as a main component, and a method for preparing the same.

An object of the present invention is to solve the conventional problems as described above, the composition for hair dyes, the main component of the extract from the leaves, berries, stems and roots of the natural mulberry without the side effects, the upper leaf or lettuce extract and its composition To provide a manufacturing method.

Another object of the present invention is to provide an improved patent of the Applicant's prior registered patent No. 569788.

In order to realize the present invention, the composition for hair dyes comprising any one or more selected from the group consisting of lettuce, lettuce or lettuce hot water extract and alcohol extract and powder taken from the leaves, berries, stems and roots of natural mulberry It provides a preparation method thereof.

Heartache, upper lobe, epidermis, hair dye

Description

Composition for hair dye having main extract of lettuce, lettuce or lettuce extract and method for preparing the same {position for hairdye comprising mulberry, mulberry leaves or Mori Radicis Cortex}

The present invention relates to a hair dye composition comprising the extract from the leaves, berries, stems and roots of the natural mulberry tree as a main component and a method for preparing the same, more specifically, The present invention relates to a hair dye composition having a hot water extract and an alcohol extract or powder as a main component, and a method for preparing the same.

In general, hair dyes may be classified into permanent hair dyes, semi-permanent hair dyes, and temporary hair dyes according to differences in dyeing effects.

Permanent hair dye is a pigment-forming substance that can penetrate into the cortex or anhydrous layer inside the hair and cause chemical changes to form an insoluble pigment. A semi-permanent hair dye is a pigment that penetrates the hair or cuticle layer on the surface of the hair And the temporary hair dye is to physically adsorb the pigment only to the cuticle layer which is the surface of the hair.

Among these, permanent hair dyes can be divided into three types, namely, vegetable hair dyes, metallic hair dyes, and oxidized hair dyes. The hair dyes containing henna and chamomile are difficult to dye brightly due to their low dyeing effect, and the metal hair dyes lead oxidation It uses the principle of turning black when it is harmful to the human body, so it is rarely used at present. Finally, oxidative hair dyes have excellent dyeing effect and can be dyed in bright colors.

Oxidative hair dyes comprise the main components of the first and second agents, as shown in Tables 1 and 2 below.

Main ingredients of permanent hair dye (Part 1) division Characteristic Dye intermediates It is not a pigment itself, but a substance that turns into a pigment when oxidized, eg p-phenylenediamine, p-aminophenol, p-toluenediamine Dye modifier Substances that react with dye intermediates to vary color, eg resorcin, m-aminophenol, m-phenylenediamine Alkali It opens the cuticles and allows the pigmentation reaction to occur quickly. Ex) ammonia, monoethanolamine (MEA) Higher fatty acids Reacts with alkaline agents to form higher fatty acid salts. It facilitates the penetration of dye intermediates or dye modifiers and facilitates cleaning on trituration. Gelling agent When mixed with a second agent it forms a gel. Isocetyl alcohol solvent Helps dissolve dye intermediates, dye modifiers. Ex) isopropyl alcohol

Main ingredients of permanent hair dye (Part 2) division Characteristic Oxidant Destroys the melanin pigment in the hair, decolorizing the hair and at the same time reacting the dye intermediates and dye modifiers to make new pigments. pH regulator The pH is adjusted to around 4.0 to stabilize hydrogen peroxide.

However, the dye intermediates and dye modifiers of the diamine-based organic dyes of the main components as described above irritate the skin and bind to the skin cells to act as antigens, such as redness, rash, pruritus, heart margin, inflammation, blisters, etc. It is already known that people with sensitive skin may suffer from contact allergic dermatitis because it causes side effects, namely contact dermatitis. In addition, this irritation is likely to cause side effects when entering the eye.

Therefore, in order to improve such a problem, it is recommended to use only a person who is negatively tested by performing a skin patch test before using the hair dye.

      However, there is a problem that it is not only cumbersome to carry out such a test every time it is desired, but also the lung which consumes a lot of time to confirm the judgment result, and also has to be dyed very carefully so as not to get into the eyes.

On the other hand, the Applicant uses the extracts from the leaves, berries, stems and roots of the mulberry tree, which can be easily obtained in Korea, as the main component of the hair dye, and the serine component of the mulberry tree cells facilitates cell activation and blood circulation. It has been found that it can nourish the hair, which is obtained from natural substances and found to solve the problems of the side effects on the skin and problems of conventional oxidative hair dyes, and the composition for hair dyes comprising the heart, the upper leaf or the white skin and its For the mulberry herb plant, which has been applied for a manufacturing method and has been pre-registered as Patent No. 569788, and is an active ingredient of the hair dye of the present invention, US Patent 6,855,312 (B1) is disclosed as its prior art, and in the patent, the herb plant Is used for hair care, but it can be used to It is never disclosed how to obtain an extract and to prepare and use the powder form, moreover the patent relates to the composition for hair protection in particular, the scope of use is different from the hair dye of the present invention and no technical idea is disclosed in detail. There is no bar.

An object of the present invention is to solve the conventional problems as described above, the composition for hair dyes, the main component of the extract from the leaves, berries, stems and roots of the natural mulberry without the side effects, the upper leaf or lettuce extract and its composition To provide a manufacturing method.

Another object of the present invention is to provide an improved patent of the Applicant's prior registered patent No. 569788.

In order to realize the present invention, the composition for hair dyes comprising any one or more selected from the group consisting of lettuce, lettuce or lettuce hot water extract and alcohol extract and powder taken from the leaves, berries, stems and roots of natural mulberry It provides a preparation method thereof.

First, the present invention provides a raw material composition for hair dye comprising a hot water extract of lettuce, lettuce or lettuce skin and alcohol extract or powder collected from the leaves, berries, stems and roots of natural mulberry.

The alcohol extract means an extract obtained by using an alcohol that can be used for the hair dye, and in this case, the alcohol may be any one or more selected from the group consisting of ethyl alcohol, propyl alcohol, benzyl alcohol, and poly alcohol.

The lettuce, upper leaf or baekpipi refers to those taken from the fruit, leaves, and stem or root bark of mulberry trees, respectively.

Mulberry (Morus) is a generic term for a deciduous tree or shrub of the genus Nettle Mulberry and Mulberry, or one of them, M. alba . Mulberry has created a lot of varieties to a single species, three species of mulberry, mulberry mountains (M. bombycis), street trees (M. lhou) as progenitor. Cultivated varieties are often mixed with these three traits. Although it is difficult to distinguish, it is divided into mulberry, mountain mulberry, and road-tree.

The lettuce, lettuce or baekpipi can be used in the present invention is not limited to these varieties, it can be used that is collected from all common mulberry.

The above-mentioned lettuce, upper lobe or epidermis is mainly used in herbal medicine, and it is used not only for the treatment of cold, eye disease, hypertension, etc. Also used as.

      However, this has not been reported so far in the field of hair dyes.

In the present invention, the loser, upper leaf or lettuce leaves are used in the form of hot water extract and alcohol extract or dry powder, the hot water extract is most preferred in terms of hair dye effect.

In the present invention, the loser, the upper leaf or the baekpipi may also be used in powder form, which is to facilitate the dyeing, and to facilitate the transport of the final product produced, the level of mesh obtainable by a conventional powder machine Powdered, but the present invention is not limited thereto.

In the present invention, the hot water extract refers to a material obtained by heating 50 to 150 parts by weight of water with respect to 1 part by weight of washed core, upper leaf or lettuce, and wherein the heating temperature is preferably about 100 ° C. or more and the heating time is 10 hours. The above is good, but preferably heated at 100 ° C. for 10 to 15 hours.

In the present invention, the alcohol extract refers to a substance obtained by inserting 30-100 parts by weight of alcohol with respect to 1 part by weight of lettuce, lettuce or lettuce extract, wherein the extraction conditions are preferably extracted at 40-50 ° C. for 5-10 hours, but more preferably. Preferably it is extracted for 8 hours at 45 ℃.

In the present invention, the powder may be used in the form of dyed by a hot core, upper leaf or lettuce extract, which refers to a powder obtained by heating it while heating the lettuce, upper leaf or lettuce extract, wherein the dye is , Until the upper lobe, or the epidermis powder is dyed about 50% to 80%.

      The dyeing will be readily understood by those skilled in the art as it implies the meaning of adsorption.

     The degree of staining of the loser, upper lobe or epithelium powder is an effective range to show the hair dyeing effect, and the dyeing effect on the hair is less than the above range, or it takes a long time to make the required color. Even if the range is exceeded, the dyeing takes too much time, and economic problems occur, and the dyeing effect on the hair is too excessive, which may cause a problem of dyeing a subtle color.

The present invention further comprises a dye in addition to the raw material composition for the hair dye described above. Dyes are added to exhibit a variety of colors, and the type of dye may include all dyes that can be commonly used in the field of hair dyes. In addition, the amount of the dye may be adjusted according to the type of dye and the color of the hair to be represented, preferably 0.5 to 3% by weight, more preferably 1% by weight based on the total hair dye composition. If it is out of the above range, a problem arises that it is difficult to obtain desirable color and dyeing effects.

When used directly in the hair dye, it is used in combination with the hair dye composition and additives commonly used in the art.

The raw material composition for hair dye of the present invention thus obtained includes a novel substance which can be used as a hair dye as a natural substance, and also uses a substance used as a conventional medicine in terms of side effects, thereby minimizing side effects of chemicals added thereto. Not only are the side effects to the skin minimized, but also the irritation to the eyes is so small that it may have fewer side effects than those involving conventional chemical dyes. In addition, compared to conventional hair dyes containing other natural materials, the material can be easily obtained in Korea, and has an economically superior effect. Moreover, the use of baekbaekpi in the form of a powder has the advantage that it is easier to use and transport.

The present invention also provides a method for producing the raw material composition for the hair dye.

More specifically, preparing hot water extracts and alcohol extracts or powders of lettuce, lettuce or lettuce;

Preparation of a hair dye composition comprising all of the steps of preparing a raw material composition for hair dye by adding a dye to any one or more selected from the group consisting of hot water, lettuce or baekpipi hot water extract prepared in the step and alcohol extract or powder Provide a method.

At this time, the dye is added to indicate the color of the hair dye, and may include all conventional dyes used in the art. The amount added is preferably about 0.5 to 3% by weight based on the total hair dye composition, for example, 1% by weight.

Hereinafter, preferred embodiments of the present invention will be described in detail.

Example 1 manufacturing process of lettuce, lettuce or lettuce extract

Preparing a washed dry mulberry leaf or stem or root and purified water in a ratio of 1: 8 (first step);

Mixing the mulberry leaves or stems or roots with purified water in a ratio of 1: 8 and boiling for 3 hours (second step);

      The step of filtering the boiled mixture of the boiled mixture, and the step of receiving the extract, lettuce or lettuce extract (third step).

Example 2 Manufacturing Process of Hair Dye Composition as First Agent

Adding the obtained lettuce, lettuce or lettuce extract to the first agent (dye) of Tables 3, 4, 5, and 6 (first step);

Table 3 (Black)

     division     Classification      amount     unit      Main component      p-phenylenediamine      2.250       g      Main component      m-phenylenediamine      0.115       g      Main component      m-aminophenol      1.050       g      Main component        Resorcin      0.900       g   Metal Ion Blocker       IDT      0.100       g      Preservative       Methylparaben      0.050       g     Antioxidant   Cioglyclick acid      0.100       g        Mechanism   Sodium Laurin Sulfate Liquid      1.000       g        Mechanism  Cocamide Profile Betaine      1.000       g      Thickener Hydroxyethylcellulose      2.500       g       Alkali       Monoethanolamine      0.500       g        Solvent        Cereal Extract     90.435       g

(100 g total)

Table 4 (Dark Brown)

     division     Classification      amount     unit      Main component      p-phenylenediamine      1.650       g      Main component      m-phenylenediamine      0.050       g      Main component      m-aminophenol      0.750       g      Main component        Resorcin      0.750       g   Metal Ion Blocker       IDT      0.100       g      Preservative       Methylparaben      0.050       g     Antioxidant   Cioglyclick acid      0.100       g        Mechanism   Sodium Laurin Sulfate Liquid      1.000       g        Mechanism  Cocamide Profile Betaine      1.000       g      Thickener Hydroxyethylcellulose      2.500       g       Alkali       Monoethanolamine      0.600       g        Solvent        Cereal Extract     91.450       g

(100 g total)

Table 5 (Brown)

     division     Classification      amount     unit      Main component      p-phenylenediamine      1.300       g      Main component      m-phenylenediamine      0.800       g      Main component      m-aminophenol      0.155       g      Main component        Resorcin      0.500       g   Metal Ion Blocker       IDT      0.100       g      Preservative       Methylparaben      0.050       g     Antioxidant   Cioglyclick acid      0.100       g        Mechanism   Sodium Laurin Sulfate Liquid      1.000       g        Mechanism  Cocamide Profile Betaine      1.000       g      Thickener Hydroxyethylcellulose      2.500       g       Alkali       Monoethanolamine      0.700       g        Solvent        Cereal Extract     90.400       g

(100 g total)

Table 6 (Light Brown)

     division     Classification      amount     unit      Main component      p-phenylenediamine      0.750       g      Main component      m-phenylenediamine      0.060       g      Main component      m-aminophenol      0.100       g      Main component        Resorcin      0.600       g   Metal Ion Blocker       IDT      0.100       g      Preservative       Methylparaben      0.050       g     Antioxidant   Cioglyclick acid      0.100       g        Mechanism   Sodium Laurin Sulfate Liquid      1.000       g        Mechanism  Cocamide Profile Betaine      1.000       g      Thickener Hydroxyethylcellulose      2.500       g       Alkali       Monoethanolamine      0.800       g        Solvent        Cereal Extract     92.940       g

(100 g total)

     After mixing the oil phase and the water raw material of the first step into the production tank and mixing at a homogeneous and waste mixer (HM: 2000 RPM for 3 minutes, PD: 150 RPM maintained stirring) and mixing (second step) ;

     Cooling (vacuum cooling, nitrogen substitution, PD450RPM) to 45 ° C. while mixing the mixture of the second step with the wastes mixer (third step);

     Mixing the monoethanolamine which is an alkaline agent and a conditioning agent to the mixture of the third step, cooling to 25 ° C. (vacuum defoaming, nitrogen substitution, HM: continued for 3 minutes at 2500 RPM, and kept stirring at PD: 150 RPM) (4) Step);

     Transfer and ripening step (fifth step) of nitrogen-substituted color cream in the mixture of the third step to filter and store the nitrogen in the storage tank.

Example 3 Oxidizer Production Process

     Adding the obtained lettuce, lettuce or lettuce extract to a second agent (oxidant) of Table 7 and mixing them (first step);

TABLE 7

    division            Name      amount      unit    Main component            Hydrogen peroxide       8.000         g    Stabilizer            IDT       0.200         g    Mechanism       Stearmonium chloride       0.100         g    Mechanism            Mineral oil       0.500         g    Mechanism            Cetyl alcohol       1.000         g    Mechanism              lanolin       0.500         g    Stabilizer               Phosphoric acid       0.030         g    Buffer            Titanium Pyrophosphate       0.070         g    Solvent             Lettuce extract      89.600         g

                                                               (100 g total)

      After mixing the oil phase and the water raw material of the first step into the production tank and mixing at a homogeneous and waste mixer (HM: 2000 RPM for 3 minutes, PD: 150 RPM maintained stirring) and mixing (second step) ;

      Cooling the mixture of the second step and the raw material of Table 8 to 45 ° C. while stirring with a wastes mixer (PD: 150 RPM) (third step);

TABLE 8

    division            Name    Main component            Hydrogen peroxide    Stabilizer               Phosphoric acid    Buffer          Titanium Pyrophosphate

       Aging the mixture of the third step (second agent, oxidant) in a storage tank by aging for 24 hours (fourth step);

       Filling the container of the fourth step into a PE container (step 5);

       Packing and shipping the finished product after the fifth step (sixth step).

      In hair dyeing using the raw material composition for hair dye of the present invention in Examples 2 and 3 above, a diamine organic dye, a surfactant, a perfume, ammonia water, hydrogen peroxide, ammonium thioglycolate, fatty acid alcohol and the like The hair dye composition of the present invention is added to the hair dye excipient.

     In the term, diamine-based organic dyes include P-phenylenediamine, M-phenylenediamine, O-phenylenediamine, P-nitro-O-phenylenediamine, N-phenyl-P-phenylenediamine, and 4-sulfuric acid. Methoxy-m-phenylenediamine, toluene sulfate 2,5-diamine and the like.

     In one example, a hydrogen peroxide solution, water, N-phenyl-p-phenyleneamine, potassium alum, alcohol, and the like are added to an effective amount of the hair dye composition.

     At this time, the effective amount of the raw material composition for hair dye composition of the present invention is preferably 10 to 40 parts by weight with respect to 100 parts by weight of the total hair dye, but if the amount is less than 10 parts by weight, the hair dye effect is lowered. There is no need to add more.

Hereinafter, specific examples of the present invention will be described in detail with reference to experimental examples and preparation examples, but the scope of the present invention is not limited thereto.

A dye was mixed with the hot water extract and the alcohol extract or powder of the lettuce, lettuce or baekpipi prepared in Example 1 to prepare a raw material composition for hair dyes.

TABLE 9

Mixing ratio of raw material composition for hair dye of the present invention (unit: parts by weight)

White skin dyes powder Hot Water Extract Alcohol extract Composition 2 0 0 0 One Composition 3 0 0 0 One Composition 4 100 0 0 One Composition 5 0 0 0 One Composition 6 10 30 10 One Composition 7 20 10 10 One Composition 8 20 10 10 One

Experimental Example 1: Skin irritation test of the raw material composition for hair dye of the present invention

The skin stimulation test using the test method of the Korea Food and Drug Administration Notice No. 1999-61 was commissioned by the Korea Chemical Testing Institute, a national accredited testing institution, for the hair dye composition of the present invention prepared in Examples 2 and 3. As shown in Fig. 7, it was confirmed to be a non-irritating substance on the skin.

TABLE 10

Skin irritation test result

Test Items Result Test Methods Skin irritation test One Korea Food & Drug Administration Notice 1999-61 Note: The skin application of the composition for hair dyes in New Zealand White rabbits has a primary stimulation index of 0.50. The skin irritation of this test substance is considered to be non-irritant.

Experimental Example 2: Heavy metal elution test of the raw material composition for the hair dye of the present invention

The heavy metal dissolution test was carried out using the test method of ICP analysis of the hair dye composition of the present invention prepared in Examples 2 and 3 by the Korea Testing and Research Institute, a national accredited testing laboratory, as shown in Table 8 below. This was not detected at all.

TABLE 8

Heavy Metal Dissolution Test Results

Test Items unit Result Test Methods Pb mg / kg Not detected ICP Analysis CD mg / kg Not detected ICP Analysis Mn mg / kg Not detected ICP Analysis Hg mg / kg Not detected ICP Analysis As mg / kg Not detected ICP Analysis

Preparation Example 1: Preparation of a hair dye using the raw material composition for hair dye of the present invention

Hair dyes 1 to 8 were prepared by mixing each of the raw materials for hair dye compositions 1 to 8 prepared in Examples 2 and 3 to the compositions shown in Table 9 below.

TABLE 9

ingredient weight% Remarks Raw material composition for hair dye of the present invention 89% ICID Hydrogen peroxide solution 2% ICID N-phenyl-p-phenylenediamine 2% ICID Potassium alum 2% ICID Alcohol 5% ICID

Experimental Example 3: Investigation of the Dyeing, Hair Conditioning Effect and Color Fastness of the Hair Dye of the Present Invention

The dyeing properties, hair conditioning effects, and fastnesses of the hair dyes 1 to 8 prepared in Preparation Example 1 were measured.

As a comparative example, in the case of the hair dye, a hair dye (trade name: Mugen's Moving Hair Color) sold by Mugens Co., Ltd. was purchased and used as a commercially available hair dye. Ten hair dyes purchased as described above were used, and compared to the use of 10 people for each of the products of the present invention, dyeing, hair conditioning effect and dyeing fastness were compared.

The comparison of the dyeability is based on the color difference, and the comparison of the hair conditioning effect and the color fastness is performed by the 5-point scale (5 = the best effect; 4 = the effect is very good; 3 = the effect is moderate; 2 = the effect is slightly good; 1 = ineffective) and scored 10 sensory evaluation specialists and averaged the scores.

1) dyeability

In the case of the hair dye, the hair dyes 1 to 8 prepared in Preparation Examples 1 to 3 were mixed with water and applied to the black hair and the white hair, and after 1 hour, washed with running water using a commercial shampoo, and dried with a hair dryer. . Thereafter, the color difference (ΔE) between the dyed hair and the untreated hair was measured using a spectrophotometer. The larger or darker the color difference, the better the dyeing property of the hair dye.

2) hair conditioning effect

In the case of the hair dye, the hair dyes 1 to 8 prepared in Preparation Example 1 were mixed with water and applied to black hair and white hair, and after 1 hour, washed with running water using a commercially available shampoo, and dried with a hair dryer. Thereafter, the hand hair of the dyed hair was compared with the texture of the hair by combing 20 times to evaluate the incidence of static electricity.

3) color fastness

In the case of the hair dye, the hair dyes 1 to 8 prepared in Preparation Example 1 were mixed with water and applied to black hair and white hair, and after 1 hour, washed with running water using a commercially available shampoo, and dried with a hair dryer. Thereafter, the dyed hair was immersed in an acidic solution similar to the sweat component, and after a predetermined time, the degree of discoloration was observed.

The results are shown in Table 10 below.

TABLE 10

Comparison of dyeing, hair conditioning effect and dyeing fastness of hair dye

Evaluation item Hair dye 1 Hair dyes 2 Hair dye 3 Hair dyes 4 Hair dye 5 Hair dye 6 Hair dye 7 Hair-dye 8 Comparative example Dyeing (ΔE) 70 58 59 60 67 69 71 75 41 Hair conditioning effect 4.6 4.5 4.6 4.7 4.6 4.6 4.7 4.8 2.1 Dyeing fastness 4.6 4.6 4.7 4.7 4.5 4.8 4.7 4.9 2.0

The raw material composition for hair dyes of the present invention as described above is a natural dye that is harmless to the human body, which is also used as a conventional medicine as a dye, and not only reduces the side effects of the chemical substance, but also has excellent dyeing, hair conditioning effect, and color fastness. At the same time, there is an excellent effect of eliminating side effects such as skin irritation caused by a conventional chemical dye.

Claims (8)

Adding to the first agent (dye) a mixture of lettuce, lettuce or lettuce extract taken from natural mulberry leaves, berries, stems and roots (first step);      A step (second step) of stirring the oil and water raw materials in the first step into the production tank and maintaining the mixture at a homo and waste mixer while maintaining the temperature at 80 ° C .;      Cooling and mixing the mixture of the second stage to 45 ° C. while stirring with the wastes mixer (third stage);      Adding a monoethanolamine as an alkaline agent and a conditioning agent to the mixture of the third step and then cooling and mixing the mixture to 25 ° C. (fourth step);      A transfer and ripening step (5th step) of nitrogen-substituting the color cream to the mixture of the third step and filtration and storing the resultant by nitrogen pressure in a storage tank;       Filling the container made of the fourth step into a PE container (step 5);      A method for preparing a hair dye composition comprising a lettuce, lettuce or lettuce extract as a main component, characterized in that it comprises the step of packaging and shipping the finished product after the fifth step (sixth step). The method according to claim 1, further comprising: adding a mixture of lettuce, lettuce or lettuce extract from natural mulberry leaves, berries, stems and roots to a second agent (oxidant) and mixing them (first step);      Mixing the oil phase and the water phase raw material of the first step into a homogeneous and wastes mixer (continuous for 3 minutes at HM: 2000RPM and maintaining stirring at PD: 150RPM) while maintaining the temperature at 80 ° C. (second step);      Cooling the mixture of the second step and raw materials such as hydrogen peroxide, phosphoric acid and titanium pyrophosphate to 45 ° C. while stirring with a waste mixer (third step);      Filtering the mixture of the third step (second agent, oxidant) in a storage tank and aging for 24 hours (fourth step);      Filling the raw material composition passed through the fourth step into a container made of PE (fifth step);     A method for preparing a hair dye composition comprising a lettuce, lettuce or lettuce extract as a main component, characterized in that it comprises the step of packaging and shipping the finished product after the fifth step (sixth step).      The method according to claim 1 or 2, further comprising the steps of preparing the washed dry mulberry leaves or stems or roots and purified water in a ratio of 1: 8 (first step); Mixing the mulberry leaves or stems or roots with purified water in a ratio of 1: 8 and boiling for 3 hours (second step);      Method of producing a composition for hair dyes, the main ingredient, characterized in that it comprises the step (step 3) of receiving the lettuce, lettuce or lettuce extract from the boiled mixture of the boiled mixture.      The first hair dye of claim 1, when black, is 2.250 g of p-phenylenediamine, 0.115 g of m-phenylenediamine, 1.050 g of m-aminophenone, 0.900 g of sorbitol, 0.100 g of methyl, based on 100 g of total weight. Heartache consisting of 0.050 g of paraben, 0.100 g of thioglycolic acid, 1.000 g of sodium lauric sulfate solution, 1.000 g of cocamide propyl betaine, 2.500 g of hydroxyethoxycellulose, 0.500 g of monoethanolamine, and 90.435 g of lettuce extract Composition for hair dyes containing, as the main ingredient, the extract of lettuce or lettuce.       The second agent of claim 2, the oxidizing agent based on a total weight of 100g, hydrogen peroxide 8.000g, eddiey 0.200g, sterimonium chloride 0.100g, mineral oil 0.500g, cetyl alcohol 1.000g, lanolin 0.500g, phosphoric acid 0.030g, pyrophosphate tart A hair dye composition comprising, as a main component, a lettuce, lettuce or lettuce extract consisting of 89.600 g of lettuce extract, 0.070 g of cerium.        The hair dye according to claim 4, wherein the hair dye is 1.650g p-phenylenediamine, 0.050g m-phenylenediamine, 0.750g m-aminophenone, 0.750g resorcin 0.700g, i. Heartache consisting of 0.050 g of methyl paraben, 0.100 g of thioglycolic acid, 1.000 g of sodium lauric sulfate solution, 1.000 g of cocamide propyl betaine, 2.500 g of hydroxyethoxycellulose, 0.600 g of monoethanolamine, and 91.450 g of lettuce extract Now, the composition for hair dyes mainly comprising the extract of lettuce or lettuce.         The hair dye according to claim 4, wherein the hair dye is brown based on 100 g of total weight, p-phenylenediamine 1.300 g, m-phenylenediamine 0.800 g, m-aminophenone 0.155 g, resorcin 0.500 g, editiei 0.100 g, methyl Heartache consisting of 0.050 g of paraben, 0.100 g of thioglycolic acid, 1.000 g of sodium lauric sulfate solution, 1.000 g of cocamide propyl betaine, 2.500 g of hydroxyethoxycellulose, and 0.700 g of monoethanolamine. Composition for hair dyes containing, as the main ingredient, the extract of lettuce or lettuce.          The hair dye according to claim 4, wherein the hair dye is 0.750g p-phenylenediamine, 0.060g m-phenylenediamine, 0.100g m-aminophenone, 0.600g resorcin, 0.100g, Heartache consisting of 0.050 g of methyl paraben, 0.100 g of thioglycolic acid, 1.000 g of sodium lauric sulfate solution, 1.000 g of cocamide propyl betaine, 2.500 g of hydroxyethoxycellulose, and 0.800 g of monoethanolamine. Now, the composition for hair dyes mainly comprising the extract of lettuce or lettuce.