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KR20060003784A - Preparation of New Silver Antibacterial Starch for Food Packaging Paper Coating - Google Patents

Preparation of New Silver Antibacterial Starch for Food Packaging Paper Coating Download PDF

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Publication number
KR20060003784A
KR20060003784A KR1020040053733A KR20040053733A KR20060003784A KR 20060003784 A KR20060003784 A KR 20060003784A KR 1020040053733 A KR1020040053733 A KR 1020040053733A KR 20040053733 A KR20040053733 A KR 20040053733A KR 20060003784 A KR20060003784 A KR 20060003784A
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silver
starch
solution
food packaging
antibacterial
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박근식
조동식
최문규
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박근식
조동식
최문규
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D103/00Coating compositions based on starch, amylose or amylopectin or on their derivatives or degradation products
    • C09D103/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/16Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
    • A61L2/23Solid substances, e.g. granules, powders, blocks, tablets
    • A61L2/238Metals or alloys, e.g. oligodynamic metals

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paper (AREA)

Abstract

본 발명은 식품포장지 코팅용 새로운 은항균전분 제조에 관한 것이다.The present invention relates to the production of new silver antibacterial starch for food packaging paper coating.

제1공정으로 새로은 은염을 제조한 은콜로이드용액을 전분을 제조할 때 사용되는 물에 100PPM을 합성시켜 제2공정으로 전분 250g을 상기 은용액 1,000g에 합성믹스하여 은항균 전분풀을 제조하여 식품 포장지 코팅용으로 사용하는 새로은 은항균 전분 제조에 관한 것이다.In the first step, the silver colloidal solution prepared with the new silver salt was synthesized with 100PPM in water used to prepare the starch. In the second step, 250g of starch was synthesized and mixed with 1,000g of the silver solution. The present invention relates to the production of new antibacterial starch for use in wrapping paper coating.

은항균제, 전분 Antibacterial, starch

Description

식품포장지 코팅용 새로운 은항균전분 제조 {We prlduce a silver antibiotic starch for coating with a food wrapper} Preparation of new silver antibacterial starch for coating food packaging {We prlduce a silver antibiotic starch for coating with a food wrapper}

본 발명은 식품포장지 코팅용 새로운 은항균전분 제조에 관한 것으로 현재 아이스크림, 식품, 통닭 등의 식품 포장지로 널리 사용되고 있는 식품포장지에 전분을 이용하여 한쪽면에 코팅하여 사용하고 있다.The present invention relates to the production of a new silver antibacterial starch for food packaging paper coating is currently used as a food wrapping paper such as ice cream, food, chicken, etc. by using starch coated on one side.

전분은 위생적이고 인체에 무해할 뿐 아니라 가격이 저렴하므로 식품 포장지 단면에 롤을 이용하여 코팅하면 광택이 나고 종이에 붙은 부유물질이 식품에 오염되지 않게 하기 위하여 널리 상요하고 있다. 화공약품인 P.V.A나 필림을 코팅하여 사용할 경우 환경공해를 야기시키고 P.V.A 역시 인체에 유해성이 있어 사용상 문제가 되고 있다.Starch is not only hygienic and harmless to the human body, but also low in price, so it is widely used to prevent gloss and suspended matter attached to paper from being coated with rolls on the cross section of food packaging. Coating with chemicals such as P.V.A or film causes environmental pollution, and P.V.A is also harmful to the human body, causing problems in use.

상기 전분은 이러한 문제점을 해결할 수 있으나 식품포장지로 사용할 경우 많은 세균들이 서식하고 곰팡이 등의 사각지대가 되고 있다.The starch can solve this problem, but when used as a food packaging paper, many bacteria inhabit and become a dead zone such as mold.

본 발명은 이러한 문제점을 해결하기 위하여 인체에 무취, 무독이고 항균성이 우수한 은항균제를 상기 전분을 제조할 때 물에 100ppm정도 은용액을 희석하여 전분을 끓여 항균효과를 얻을 수 있도록 한 것이 특징이다.The present invention is characterized in that the antibacterial agent odorless, non-toxic and excellent antimicrobial to the human body to prepare the starch by diluting the silver solution about 100ppm in water to obtain the antimicrobial effect.

현재까지 은콜로이드용액은 전기분해로 나노와 같이 작은 입자를 물에 용출시켜 은콜로이드용액을 제조하는 기술과 은염을 이용하여 은콜로이드용액을 제조하는 기술 등이 보현화되어 있으나 이들의 은염이나 은콜로이등 용액은 햇볕이나 하로겐 화합물 등과 결합하면 흑변되거나 황변 되는 것이 은 염의 고유의 성질이다.Until now, silver colloidal solution has been developed by electrolysis to produce silver colloidal solution by dissolving small particles like nanoparticles in water and silver colloidal solution using silver salt. It is the inherent property of silver salts that the back solution turns black or yellow when combined with sunlight or halogen compounds.

본 발명은 이러한 은염의 성질을 완전히 배제한 새로은 은염을 제조하기 위하여 은괴를 소립하여 용해조에 넣고 질산을 첨가시켜 은을 용해한 후 탄산칼슘용액(PH9.5)을 첨가시켜 중성으로 만들면서 빙초산을 첨가시키면서 PH5정도가 되게 하면 작은 입자의 은염이 제조된다.In the present invention, in order to prepare a new silver salt that completely excludes the properties of the silver salt, the silver ingot is put in a dissolution tank, and nitric acid is added to dissolve silver, and then calcium carbonate solution (PH9.5) is added to make neutral, while adding glacial acetic acid. When the pH is about 5, silver particles of small particles are produced.

상기 은염 100g을 물 1,000g에 합성하여 황산제1철을 첨가시켜 교반하여 가성소오다로 PH를 조정하여 1시간 정도 방치하면 침전물이 생긴다.100 g of the silver salt was synthesized in 1,000 g of water, ferrous sulfate was added thereto, stirred, and the pH was adjusted with caustic soda and left for about 1 hour to form a precipitate.

상기 침전물은 투명액체의 콜로이드가 만들어진다. 이때 은콜로이드의 은고형분을 측정하면 약10,000PPM의 은이 함유되어 있는 것이 확인되고 있다.The precipitate is made of a colloid of transparent liquid. At this time, when the silver solid content of silver colloid is measured, it is confirmed that silver of about 10,000PPM is contained.

상기 은염을 전분을 제조하는 물에 약 100PPM정도 은이 함유되면 전분을 넣고 전분풀을 끓여 식품포장지 코팅제로 사용할 경우 항균성이 99.9% 항균되는 것이다. 이때 새로운 은염은 황변이 되지 않고 은항균전분이 코팅된 포장지에는 황변이나 흑변이 일어나지 않고 깨끗한 식품포장지가 제조되고 은이 함유된 전분풀 역시 황변이나 흑변이 되지 않는 것이 확인되고 있다.When the silver salt contains about 100PPM silver in the water to prepare the starch, when the starch is added and the starch pool is used as a food packaging coating agent, the antimicrobial activity is 99.9% antibacterial. At this time, the new silver salt does not become yellowed, silver antibacterial starch coated paper is not produced yellowing or black stools, clean food packaging is produced, it is confirmed that the starch pool containing silver does not become yellow or black stools.

상기와 같이 본 발명의 기술핵심은 새로운 은염제조시 은을 유기산에 용해하여 탄산칼슘으로 중화하여 다시 빙초산으로 PH5로 한 후 상기 은염을 물에 용해한 후 은이 철분 등과 결합할 경우 검은 앙금 등을 유발시킨다. 이때 황산 제1철의 량 은 상기 은용액의 0.1%를 초과하지 않도록 한 것이 특징이다. 이것은 은용액이 일반 수돗물이나 지하수에 함유된 철분 등과 결합할 때 흑변되는 현상을 막기 위하여 1차로 철염을 이용한 것이 특징이다.As described above, the technical core of the present invention dissolves silver in an organic acid and neutralizes it with calcium carbonate when preparing a new silver salt, and then converts it to PH5 with glacial acetic acid, and then, when silver is dissolved in water and silver is combined with iron, it causes black sediment. . At this time, the amount of ferrous sulfate is characterized in that it does not exceed 0.1% of the silver solution. It is characterized by the primary use of iron salts to prevent blackening when silver solutions combine with iron in groundwater or groundwater.

상기와 같이 용해된 은용액을 여과시에 여과시키면 투명액체의 은콜로이드용액이 제조된다.When the silver solution dissolved as mentioned above is filtered at the time of filtration, the silver colloidal solution of a transparent liquid is manufactured.

상기 은용액의 은함유량을 한국화학시험연구원에 은함유량 측정결과 은이 10,000PPM 함유된 것이 확인되고 있다.The silver content of the silver solution was measured by the Korea Chemical Testing and Research Institute that the silver content was confirmed to contain 10,000 PPM silver.

상기 은용액을 전분을 이용하여 풀을 끓일 때 사용되는 물에 100PPM정도 희석하여 전분풀을 제조했을 때 대장균, 포도상구균이 99.9% 항균되는 것이 확인되고 있다.It is confirmed that E. coli, Staphylococcus aureus is 99.9% antibacterial when the silver solution is diluted to about 100PPM in water used to boil the pool using starch.

본 발명은 기존 전분풀을 새로운 은용액을 제조하여 색상이 변하지 않는 은항균 전분을 제조한 것이 특징이다.The present invention is characterized by the production of silver antibacterial starch that does not change color by producing a new silver solution of the existing starch pool.

상기와 같이 본 발명은 기존 전분풀을 이용하여 식품 포장지에 코팅하였을 때 많은 세균이 서식하는 것을 제거하기 위하여 새로운 은염을 제조하여 은항균전분을 제조하는 것이 특징이다.As described above, the present invention is characterized in that silver antibacterial starch is prepared by preparing a new silver salt in order to remove a large number of bacteria inhabit when coated on food packaging paper using the existing starch pool.

상기와 같이 본 발명은 식품포장지 코팅용 새로운 은항균 전분 제조 관한 것으로 새로운 은항균제를 제조하기 위하여 은을 소립하여 용해조에 열을 80도로 유지시키면서 질산을 첨가시켜 은을 용해한 후 탄산칼슘을 물에 용되게 한 후 상기 은용액에 빙초산을 첨가시켜 PH5가 되게 하면 작은 연갈색의 입자가 만들어진다.As described above, the present invention relates to the production of new silver antibacterial starch for coating food packaging paper. In order to prepare a new silver antibacterial agent, silver is dissolved by adding nitric acid while maintaining silver at 80 degrees in a dissolution tank to dissolve silver and then dissolving silver carbonate in water. After the glacial acetic acid is added to the silver solution to make PH5, small light brown particles are formed.

상기 연갈색의 은염 100g을 물 1,000g에 용해한 후 황산제1철(40%)을 상기 은용액에 0.1% 첨가시켜 반응시키면서 PH를 조절하기 위하여 가성소오다용액을 첨가하고 교반시켜 1시간정도 햇볕에 방치하면 많은 침전물이 생긴다.After dissolving 100 g of the light brown silver salt in 1,000 g of water, ferrous sulfate (40%) was added to the silver solution by adding 0.1% of the caustic soda solution to adjust the pH, followed by stirring for 1 hour in the sun. If left unattended, a lot of sediment is formed.

상기 침전물을 여과하면 투명액체의 은항균콜로이드용액이 제조된다.Filtration of the precipitate produces a silver antibacterial colloidal solution of a clear liquid.

상기 은용액을 전분풀을 끓일 때 사용되는 물에 100PPM 은이 함유되게 한 후 전분을 넣고 풀을 끓이면 항균성이 우수한 전분을 제조하여 식품포장지 코팅용으로 사용하는 것이다.When the silver solution is used to boil the starch paste, 100PPM silver is contained, and then starch is added to boil the paste to prepare starch having excellent antimicrobial properties and to use it for food packaging coating.

상기 내용을 보다 실시예에서 상세하게 설명하면 다음과 같다.The above content will be described in detail in the following Examples.

[실시예 1]Example 1

제1공정 first process

은 100g을 소립한 후 용해조에 넣고 용해조의 열을 80도를 유지시켜 질산 150g을 첨가하여 은을 용해한 후 상기 은용액에 탄산칼슘용액(PH9.5)을 서서히 첨가시키면서 PH가 7.5가 되게 중성의 은입자를 만든후 다시 빙초산을 첨가시켜 열을 주면서 PH5정도의 은입자를 제조한 후 상기 은염 100g을 물 1,000g에 용해한 후 황산제1철(40%)을 상기 용액에 0.1% 용해하여 1시간 정도 햇볕에 방치하면 흑갈색의 침전물의 작은 입자가 생긴다.After 100 g of silver was sintered, the solution was placed in a dissolution tank. The heat of the dissolution tank was maintained at 80 degrees, and 150 g of nitric acid was added to dissolve the silver. The solution was neutrally added with a calcium carbonate solution (PH9.5) to a pH of 7.5. After the silver particles were made, silver glacial acetic acid was added again to prepare a silver particle having a pH of about 5 by heating. Then, 100 g of the silver salt was dissolved in 1,000 g of water, and ferrous sulfate (40%) was dissolved in the solution for 1 hour. If left in the sun, small particles of dark brown precipitates are formed.

상기 용액을 여과하면 투명액체의 은콜로이드를 제조한다. 이때 상기 은콜로이드의 은고형분은 10,000PPM이 함유된 것이 확인된다.Filtration of the solution produces a silver colloid of transparent liquid. At this time, the silver solid of the silver colloid is confirmed to contain 10,000PPM.

상기 은콜로이드 용액 1,000g을 정량한다.1,000 g of the silver colloidal solution is quantified.

제2공정 2nd process

물 1,000g을 정량한 후 제1공정의 은용액 10g을 첨가시켜 은용액 100PPM이 함유되게 한 은용액 1,000g을 정량한다.After 1,000g of water was quantified, 10g of silver solution of the first step was added to quantify 1,000g of silver solution containing 100PPM of silver solution.

제3공정 3rd process

전분 250g을 정량한 다음 제2공정의 은용액 1,000g에 합성 분산시켜 90도 열을 유지하면서 은항균 전분풀을 제조한다.250g of starch is quantified, and then synthesized and dispersed in 1,000g of silver solution of the second step to prepare silver antibacterial starch pool while maintaining 90 ° heat.

상기와 같이 항변되지 않는 은용액을 제조하여 항균 전분을 제조하여 식품 포장지에 코팅했을 때 균이 서식하지 않는 깨끗한 무균포장지를 제조할 수 있는 은항균전분을 제조한 것이다.It is to prepare a silver antibacterial starch that can produce a clean sterile packaging paper that does not inhabit when the antimicrobial starch is prepared by preparing a silver solution that does not change as described above and coated on food packaging.

상기와 같이 은항균제에 사용된 은은 이 지구상에서 가장 안전된 항균금속으로 높이 평가하고 있고 은에 접촉되어 6분간 살아남는 병균이나 바이러스가 이 지구상에 없다는 것이 확인되고 있다. 또한 은은 인체에 아무런 해를 주지 않고 모든 병균을 살균하는 무기 항균제로 높이 평가하고 있다.As mentioned above, silver used in silver antibacterial agent is highly regarded as the safest antibacterial metal on this earth, and it is confirmed that there are no germs or viruses on this earth that survive for 6 minutes after contact with silver. Silver is also highly regarded as an inorganic antibacterial agent that kills all germs without harming the human body.

상기 은항균 전분을 이용하여 식품포장지에 코팅된 포장지를 한국원사시험연구원에 항균시험결과는 다음표와 같다.The antimicrobial test results of the wrapping paper coated on the food packaging paper using the silver antibacterial starch at the Korea Yarn Testing Institute are as follows.

Figure 112004510257615-PAT00001
Figure 112004510257615-PAT00001

상기와 같이 본 발명의 은항균 전분을 식품포장지에 항균검사 결과는 99.9% 항균성이 있는 것이 확인되고 있다.As mentioned above, the antimicrobial test result of the silver antibacterial starch of this invention to food packaging paper has confirmed that it is 99.9% antimicrobial.

상기와 같이 본 발명은 식품 포장지에 전분으로 코팅했을 때 세균이 서식하고 곰팡이 등이 서식하여 비위생적인 것을 깨끗하고 위생적인 무균 식품 포장지를 제공받을 수 있는 은항균 전분을 제조한 것이 특징이다.As described above, the present invention is characterized in that the antibacterial starch, which can be provided with clean and hygienic sterile food packaging, in which bacteria inhabit and mold and the like inhabit when the food packaging is coated with starch.

Claims (1)

식품포장지 코팅용 새로운 은항균 전분 제조함에 있어In the production of new silver antibacterial starch for coating food packaging 제1공정으로 은100g을 소립하여 용해조에 넣고 80도 열을 유지시키면서 질산 150g을 첨가하여 은을 용해한 후 탄산칼슘용액(PH9.5)을 첨가시키면서 은용액을 중화시켜 중성으로 하면서 빙초산을 첨가시켜 PH5의 은염을 제조한다. 이때 은염의 입자는 갈색으로 되어 있다.In the first step, 100 g of silver is granulated, and 150 g of nitric acid is added while keeping the heat at 80 degrees to dissolve the silver, while neutralizing the silver solution by adding calcium carbonate solution (PH9.5), adding glacial acetic acid. Prepare a silver salt of PH5. The particle | grains of silver salt are brown at this time. 상기 은염 100g을 물1,000g에 용해하여 황산1철(40%)을 상기 용액에 0.1% 첨가하여 교반시키면서 가성소오다 용액으로 PH를 중성으로 조절하여 햇볕에 1시간 방치하면 흑갈색의 작은 입자들이 형성된다.100 g of the silver salt was dissolved in 1,000 g of water, ferrous sulfate (40%) was added to the solution by 0.1%, and the pH was adjusted to neutral with caustic soda solution and left in the sun for 1 hour to form dark brown small particles. do. 상기 은용액을 여과하면 투명액체의 은코로이드용액이 된다. 이때 은콜로이드용액의 은함유량은 10,000PPM이 된다.Filtration of the silver solution leads to a transparent liquid silver colloidal solution. At this time, the silver content of the silver colloidal solution is 10,000 PPM. 상기 은콜로이드용액 1,000g을 정량하고1,000 g of the silver colloidal solution was quantified and 제2공정으로(전분 풀제조) 물1,000g에 제1공정의 은용액 10g을 용해하면 100PPM의 은콜로이드용액이 된다.In the second step (starch paste production), when 10 g of the silver solution of the first step is dissolved in 1,000 g of water, a silver colloidal solution of 100 PPM is obtained. 상기 용액 1,000g에 전분 250g을 합성믹스하여 90도 열을 유지시켜 끓이면 은항균전분이 제조된다. 상기 전분을 식품 포장지에 코팅하는 은항균 전분.Synthetic mix 250 g of starch to 1,000 g of the solution to maintain a 90 ° heat to boil silver antibacterial starch is prepared. Silver antibacterial starch coating the starch on food packaging.
KR1020040053733A 2004-07-07 2004-07-07 Preparation of New Silver Antibacterial Starch for Food Packaging Paper Coating Ceased KR20060003784A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI849038B (en) * 2019-01-18 2024-07-21 南韓商Lg新能源股份有限公司 Battery management apparatus and method and battery pack

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI849038B (en) * 2019-01-18 2024-07-21 南韓商Lg新能源股份有限公司 Battery management apparatus and method and battery pack

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