KR200289407Y1 - Cloth coated with anion emission composite - Google Patents

Abstract

The present invention mixes the components such as tourmaline, chitosan, yew extract, elvan, etc. in a predetermined ratio and integrates them into a binder and a fixing agent, thereby releasing a large amount of anions and far infrared rays according to synergistic effects between the components, as well as antibacterial and deodorizing properties. In addition to the benefits, the present invention relates to a fabric coated with an anionic release composition that contributes to health promotion by coating the composition on the fabric.

The fabric coated with the present anion-releasing composition is 15 to 30% by weight of tourmaline, 2 to 5% by weight of fixing agent, 3 to 10% by weight of yew extract, and 100% by weight of binder based on the weight of the anion-emitting composition It is characterized by coating on.

Description

Cloth coated with anion emission composition

The present invention relates to a fabric coated with an anion-releasing composition that generates an anion effective for the human body, and more particularly, by mixing components such as tourmaline, chitosan, yew extract, elvan, etc. in a predetermined ratio and integrating them into a binder and a fixing agent. Not only beneficial to human body due to antibacterial and deodorizing effect as well as release of large amount of anion and far infrared rays according to synergistic effect between ingredients, and coating an anion emitting composition that contributes to health promotion by coating such composition on fabric will be.

Today, the area of use of cement or polymer plastics is expanding, and the environmental damage caused by the use of these materials is also increasing. For example, radon gas released from cement or environmental hormones contained in plastics are not only destructive but also harmful to human body. On the other hand, as the level of consciousness of the people increases, the interest in the health of the people is increasing day by day, and in order to meet these needs, various types of health supplements such as ocher room, ganbanseok far-infrared experience room, jade mat, ocher mat, charcoal mat, etc. They are being developed and most of them are used as a means for generating anions and far infrared rays.

Unlike cations, which release excess serotonin / histamine in the human body, harming health and lowering the oxygen absorption capacity of lungs, anions increase the ionization rate of minerals in the blood and alkalinize the blood. Purify and promote electrical metabolism in the cell membrane to stimulate metabolism and quickly discharge waste products in the body, while increasing the amount of r-globulin, an immune component in serum, to increase resistance and autonomic nervous system, blood and It is known to activate lymphatic fluid.

In order to achieve such an effect, anion generating device that purifies the air by generating anion electrically has been developed for automobiles, indoors or buildings. However, research has shown that the method of generating anions electrically increases the concentration of carbon monoxide in a confined space and that ozone generation adversely affects the bronchus of the human body. (Refer to Korea Ginseng and Tobacco Research Institute, May 25, 1998)

Natural sources of negative ions include waterfalls, pine forests, and near beaches where rocks hit rocks. Such sources are known to exist in the atmosphere, usually generating 3000-4000 anions.

On the other hand, far infrared rays resonate with water molecules that occupy more than 70% of the human body to activate the cells, help blood circulation, and supply the dissolved oxygen contained in the blood, which is beneficial to the human body by helping to recover from fatigue such as muscles. With the announcement, the public's interest in far-infrared is rising and its application to you is trying.

In addition, there are various germs living in the environment where people live, and it is natural to control such germs. In addition, many odors are generated by food, chemicals and body odors, and various deodorants are being developed to remove them.

The anion, far-infrared, antibacterial, and deodorizing functions which are beneficial to health as described above are made by independent devices or articles having respective functions. As such, devices or articles that provide negative ions, far infrared rays, antibacterial, and deodorizing functions are not good for the human body because they produce these functions mechanically or chemically, rather than naturally occurring. Will be taken.

On the other hand, modern people generally have more opportunities to work in narrow indoor spaces as their living environment is advanced or complex, and many people come into contact with harmful microorganisms such as bacteria and fungi due to lack of sunshine, and thus antibacterial or far-infrared rays for maintaining health. Development of release fabric products has been required.

In general, staphylococcus aureus and urea degrading bacteria, which are produced by nutrients such as sweat, fat, waste, and manure secreted by the human body, are not only harmful to the human body and the natural environment, such as causing skin diseases on sensitive areas of the skin, and contaminants. Involved in the decomposition process to generate ammonia gas and odor, the use of antimicrobial fabrics in reality is urgently needed. In particular, the removal of the odor generated in sportswear and sportswear after exercise is a situation that requires the antibacterial deodorization process for the skin protection.

Known antibacterial and deodorant processing methods include applying inorganic compounds such as silver, copper, zinc, silver oxide, Acrylonitril-copper sulfide complex, zinc oxide, etc. to organic fabrics, or applying organic compounds such as quaternary ammonium. In addition, there is also a method of copolymerizing the low-molecules and polymers with quaternary ammonium, and the method to make the surface of the fabric react with the pyridium salt quaternary, ammonium salt, and simply dissolved chitosan in dilute organic acid in the form of chitosan There is a way to make it a sanitary product by padding the fabric product.

Bacteria and bactericidal action according to such metal ions or quaternary ammonium salts are caused by direct contact of microorganisms to the antimicrobial functional groups formed on the fabric surface, and microorganisms in which the cell walls are charged with anions are electrically connected to metal ions or cations of quaternary ammonium. Combined, the cellular function of the electron transport system is lowered, which causes the breathing to stop or the cell wall is destroyed and the cell fluid is leaked to die.

However, organic processing agents made of such antimicrobial compounds have a problem of not being organically in contact with the fabric, lack of washing durability, deterioration of touch and fluorescence loss or discoloration from anionic dyes when treated with fluorescent brighteners. There is a disadvantage.

In addition, some of them are exposed to ultraviolet rays for a long time, and a part of the polymer chain is cut, which causes yellowing of the hygiene product or loss of its function as a hygienic processing agent, and also acts on the human body to cause allergic skin diseases such as atopic dermatitis. There is a problem that can be denatured to harmful substances.

In addition, the antimicrobial deodorization processing of the fabric product using chitosan by another method must go through the process of dissolving chitosan by any method and processing on the fabric product. However, chitosan is not dissolved in water and dissolved in an organic acid solution, so in order to process the fabric product, it is necessary to treat it with a dilute acid solution. In addition, chitosan having a cation by combining an acid and a salt has a problem in that the antibacterial deodorization function is lost due to the conversion of ammonium ion to an amine group when treated with an alkaline solution such as NaOH.

In addition, minerals that have been added to synthetic fabrics for a long time include inorganic synthetic powders such as silver (Ag), calcium phosphate, zeolite, germanium, ganban stone, gemstones, tourmaline, carbon, etc. In addition to synthetic fabrics, research has been carried out for a long time to provide multifunctional functions such as antibacterial, deodorant, far infrared rays, electromagnetic wave blocking, ultraviolet ray blocking, adsorption, moisture absorption, and anion emission, but the characteristics (crystals) of minerals are diversified to obtain smooth radiation effect. There was no.

Accordingly, an object of the present invention is to devise to solve the above-mentioned drawbacks, by mixing the components such as tourmaline, chitosan, yew extract, elvan, etc. in a predetermined ratio by integrating them into a binder and a fixing agent by the synergistic effect between the components The present invention provides a fabric coated with an anion-releasing composition which contributes to health promotion by coating an anion-emitting composition having both deodorization and antimicrobial properties on the surface, as well as anion beneficial to the human body.

DETAILED DESCRIPTION A detailed description of embodiments of the present invention will be made with reference to the accompanying drawings, in which like numbers designate corresponding parts in the drawings.

1a and 1b are graphs showing the results of the far infrared emission test in the present state of the fabric coated with the composition of the present invention,

2a and 2b are graphs showing the results of the far-infrared emission test after 10 washes of the fabric coated with the composition of the present invention,

3a to 3d and 4a to 4d are photographs showing the antimicrobial test of the fabric coated with the composition of the present invention.

Fabric coated with an anion-releasing composition according to the present invention for achieving the above object is 15 to 30% by weight of tourmaline, 2 to 5% by weight of binder, 3 to 10% by weight of yew extract and residual weight of 100% by weight of liquid binder It is characterized in that the anion-emitting composition consisting of coated on the surface of the fabric.

Hereinafter, with reference to the accompanying drawings will be described in detail with respect to a preferred embodiment of the present invention. Before describing the composition of the present invention and a method for producing the same, the raw materials constituting the composition will be described in detail.

1. Raw Material

(1) tourmaline

The tourmaline used in the present invention is commonly called tourmaline, and is used as a jewel as a hexagonal tablet having a hardness of 7.25 and a specific gravity of 3.05. Tourmaline has a refractive index of 1.62-1.64, birefringence of 0.018, and seven colors including green and blue. Among them, opaque tourmaline, which is of no value as a jewel, is mainly used for industrial purposes. Tourmaline is a polar crystal that permanently flows about 0.06A of microcurrent.

In addition, tourmaline has a piezoelectric property, and when a vertical pressure or shear stress is applied by a human hand or other tool, the surrounding water molecules are separated into hydrogen ions and hydroxyl ions. At this time, hydrogen ions are attracted to the cathode potential of the tourmaline, Emitted as air in the molecular state In addition, hydroxyl ions (OH-) are combined with the surrounding water molecules to form hydroxyl ions (H ₃ O ₂ ⁻ ), and these particles are measured as anions. In addition, since hydroxyl ions are surfactants, they have beneficial properties to remove static electricity by providing hydrophilicity.

In the method of the present invention, a tourmaline having a particle size of 100 μm or less is used. If the particle size is larger than this, the physical properties may be deteriorated.

(2) chitosan

Chitosan is the most representative of the natural antimicrobial that is almost harmless to the environment and harmless to the human body, characterized by antimicrobial, human compatibility and cationic properties. Fabrics treated with chitosan are widely known to exhibit complex functions such as antimicrobial, deodorant and moisturizing effects. Chitosan is a widely used material and a detailed description of its extraction method and effect will be omitted.

In the present invention, natural chitosan liquid is used to impart antimicrobial properties to the fabric. This prevents staphylococcus aureus, urea-degrading bacteria, and bacteria that cause skin diseases in sensitive areas of the body by breeding waste products such as sweat, fat, and manure secreted by the human body as nutrients. In addition, it maintains a suitable moisturizing effect, gives a comfortable fit and deodorant, activates cellular tissues and promotes metabolism by allowing far-infrared rays, which are well absorbed by the human body, to be absorbed and penetrated through the skin.

(3) yew tree extract

The part of the yew tree added to the present invention can be any part of the root, stem and leaf, and each of them can be washed and dried, then crushed to the size of sawdust and added directly, or extracted with a solvent, and the extract can be added. The solvent used in the extraction of the solvent is methanol, it is extracted for 1 to 10 hours at 30 to 70 ℃, the solvent is preferably used about 50 to 150L per kg solids. The content of yew or yew extract for producing taxol in high yield is preferably 0.5 to 100 g per 1 liter of culture medium based on solids.

Taxol (aka peclitaxel) is a substance found in the leaves, stems, and roots of Taxus cuspidata and Taxus brevifolia. , ME Wall, P. Coggon, and At McPhail, J. Am. Chem. Soc., 93,2325, 1971).

Taxol has been developed as a medicine because it shows excellent anticancer activity against various cancer cell lines, and has excellent performance as a therapeutic agent for leukemia, and it is also effective for uterine cancer, breast cancer, laryngeal cancer and incurable malaria. Has been proven. This substance is found to contain the most at about 0.041 to 0.02% in the stem bark of yeast.

(4) Elvan

Elvanite is a rock in the process of kaolinization due to the decomposition of feldspar contained in the quartz rock, and it is characterized by its porous structure, yellowish white color, and the shape of elvan, with white spots embedded therein. In addition, elvan is known to have about 20% water solubility, and is rich in Si (silic acid), Na (sodium), K (potassium), Ca (calcium), etc., and Mg (magnesium), Zn (zinc) and Cu (copper). It has been used for skin diseases as a Chinese medicine since ancient times.

Elvan absorbs moisture by adsorption, and removes various odors by deodorizing. It also promotes metabolism due to the minerals produced in elvan, giving a beneficial effect on the human body. In particular, elvan has excellent far-infrared radiation activity and is known to have excellent antibacterial and neutralizing properties because it is a porous inorganic substance.

(5) binder

The binder has a bonding function for bonding the components constituting the composition, acrylic resin series is suitable. The binder is used to make a liquid by mixing about 33% of the binder solids with about 67% of water.

(6) silicon

Silicone allows the components to be mixed well while maintaining proper elasticity and viscosity, and is usually used in liquid phase.

(7) fixing agent

A fixing agent is a material for curing the present composition prepared by mixing the components in an appropriate ratio to have a predetermined hardness, and a thermosetting resin is used. Examples of the thermosetting resin include silicone series, acrylic series, and the like, and silicone series having excellent durability is preferable.

Now, the present composition consisting of the above components will be described in detail.

The composition is about 15 to 30% by weight of tourmaline solids, preferably 20 to 22% by weight, 3 to 8% by weight of silicone, 2 to 5% by weight of binder, 3 to 10% by weight of yew extract and 100% by weight of liquid binder It consists of mixing by reference residual weight%. The composition thus constructed is bound by a binder and hardened by a binder to solidify to a desired shape. The yew tree extract in the above composition functions to give more excellent anion radioactivity, in particular the yew tree extract not only generates anions as described above, but also has antibacterial properties, thereby neutralizing the binder having a cationic property. It will enhance the anion release performance.

In addition, when 3 ~ 10% by weight of the elvan rock powder is added during the preparation of the composition, far infrared rays are radiated in addition to the anion, which is more useful for health. In addition, when 5 to 10% by weight of liquid chitosan is mixed with the above components, the antibacterial, Deodorization performance can be given.

Here, tourmaline and elvan are used in powder form, chitosan, binder, and silicon are liquids in which solid content is dissolved in water, and yew tree extract is extracted by steaming bark or leaves with steam. In addition, the binder, silicone, and the fixing agent is a thermosetting resin, and when the composition is completed, it becomes a viscous material such as glue. It is hardened with and adheres.

The binder serves to combine the components to be mixed, preferably acrylic series is used, and the acrylic series in the present invention is mixed with the silicone series so as to give a softer feeling when coating on the fabric, such as the hardness of the thermal curing This will ease the hardness after curing. This silicone also acts as an adhesive. In addition, although the silicone series and the acrylic series may be used as the fixing agent, it is preferable to use the silicone series having excellent durability. That is, when the acrylic type is used as a fixing agent in the present composition coated on clothing, there is a possibility that blown into the water during washing, the silicone type is not blown with water is suitable.

Of the above components, tourmaline, yew tree extract generates anions, chitosan protects the skin with antibacterial and moisturizing functions, and elvan generates far infrared rays. It not only promotes metabolism by releasing far-infrared rays, but also improves health, and it is effective in combating harmful bacteria by moisturizing and antibacterial functions. Moreover, the yew extract blended in the present composition neutralizes the cationicity of the binder which is inevitably included in the preparation of the composition to combine the respective components and enhances the anionicity released from the tourmaline to function as a more beneficial composition. do.

The composition prepared as described above is a sticky mucus material, and when applied to clothing, exhibits an excellent effect. In more detail, the present composition is coated on a fabric by a conventional auto screen method or roller print method. At this time, the composition may be completely applied to the fabric, or may be coated with dots or stripes. Of course, in addition to the coating in a variety of shapes or thickness, preferably 40g ~ 70g per 1M ² fabric is good, when about 50g coating is most suitable for the human body because more than 1000 anions are generated. The composition coated on the fabric as described above is cured in the fabric through heat drying and firmly fixed. At this time, 120-140 degreeC is suitable as a drying temperature.

Now, the present invention will be described in detail with reference to the efficacy of the present invention.

Example 1.

The binder was prepared in the liquid phase by mixing 33% by weight of solid content to 67% by weight of water, and the silicone was prepared in the liquid phase by mixing 40% by weight of solid content with 60% by weight of water. Then, the composition was prepared by mixing 22% by weight of tourmaline solids, 5% by weight of silicone, 3% by weight of fixing agent, 7% by weight of yew extract, and 100% by weight with a liquid binder. The composition thus prepared is present in a sticky mucus state such as grass.

The composition prepared as described above was coated on the fabric by the auto screen method. At this time, the composition was coated to about 60g per fabric 1M ² . The composition-coated fabric was dried at about 130 ° C. for about 2 minutes to allow the mucus-like composition to harden and firmly adhere to the fabric.

An anion spinning test was performed on the fabric coated with the composition obtained by the above method, and the following results were obtained.

Table 1.

Item Sample Name Anion (ION / cc) Anion fabric 724

The above test was conducted by Korea Far Infrared Application Evaluation Institute. The test was conducted under the condition of room temperature 23 ℃, humidity 46%, and anionic water 104 / cc using charge particle measuring device, according to KFIA-FI-1042 method. This is the result of measuring the anion emitted from the measuring object (anionic fabric) of 200 × 300 (mm) size and displaying the number of ions per unit volume. As shown in Table 1 above, it can be seen that more than 700 anions effective for the human body per unit volume are released.

Example 2.

The binder was prepared in the liquid phase by mixing 33% by weight of solid content to 67% by weight of water, and the silicone was prepared in the liquid phase by mixing 40% by weight of solid content with 60% by weight of water. Then, the composition was prepared by mixing 25% by weight of tourmaline solids, 3% by weight of ganbanite powder, 4% by weight of silicone, 2% by weight of fixing agent, 8% by weight of yew extract, and 100% by weight of the balance with a liquid binder. The composition thus prepared is present in a sticky mucus state such as grass.

The composition prepared as described above was coated on the fabric by the auto screen method. At this time, the composition was coated to about 70g per fabric 1M ² . The composition-coated fabric was dried at about 125 ° C. for about 3 minutes to allow the slime composition to harden and firmly adhere to the fabric. The fabric coated with the present composition gives many useful effects to the human body due to far-infrared rays generated from tourmaline, yeast tree extract, as well as far-infrared rays generated from elvan.

Figures 1a and 1b shows the results of the far infrared emission test in the present state of the fabric coated with the composition of the present invention obtained in Example 2, Figure 1a is a graph showing the far-infrared emissivity, Figure 1b is This graph shows far infrared radiation energy. In addition, Figure 2a and Figure 2b shows the results of the far infrared emission test after washing the fabric coated with the composition of the present invention 10 times, Figure 2a is a graph showing the far infrared emissivity, Figure 2b is a graph showing the far infrared radiation energy. This test was conducted at a measurement wavelength of 5 to 20 µm, a measurement temperature of 40 ° C, and a sample size of 30 x 30 mm. The graph is obtained by an infrared spectrophotometer, in which the line S represents the sample and the line T represents the blackbody compared to the sample. The results are shown in Table 2 below.

Table 2. Far Infrared Emission Test

Far Infrared Emissivity (wavelength 5 ~ 20㎛) Far Infrared Radiation Energy (W / ㎡ · ㎛, 40 ℃) Presentation 0.894 359.934 After washing 10 times 0.883 355.531

As can be seen from the above test results, the fabric coated with the present composition has almost no decrease in far-infrared emissivity and radiant energy even after washing several times (10 times) in the present state, so that even if it is applied to a garment, deterioration due to washing is hardly generated. Therefore, durability and homeostasis were found to be excellent.

Example 3.

The binder was prepared in the liquid phase by mixing 33% by weight of solid content to 67% by weight of water, and the silicone was prepared in the liquid phase by mixing 40% by weight of solid content with 60% by weight of water. Then, 30% by weight of tourmaline solids, 10% by weight of ganbanite powder, 7% by weight of silicone, 3% by weight of fixing agent, 5% by weight of yew extract, 8% by weight of liquid chitosan, and the rest by mixing 100% by weight with a liquid binder The composition was prepared. The composition thus prepared is present in a sticky mucus state such as grass.

The composition prepared as described above was coated on the fabric by the auto screen method. At this time, the composition was coated to about 50g per fabric 1M ² . The composition-coated fabric was dried at about 135 ° C. for about 2 minutes to allow the mucus-like composition to harden and firmly adhere to the fabric. The fabric coated with the present composition gives many useful effects to the human body due to far-infrared rays generated from tourmaline, yeast tree extract, as well as far-infrared rays generated from elvan. In addition, the antimicrobial effect of the chitosan is to increase the antimicrobial properties of the fabric. This antimicrobial test is shown in FIGS. 3A-4D.

3A to 3D and 4A to 4D show an antimicrobial test of the fabric coated with the present composition obtained in Example 3. FIG. 3a to 3d are tested using the test specimen 1 (Staphylococcus aureus ATCC 6538), in particular, Figures 3a and 3b shows the state after the initial test and culture carried out on the standard cloth, Figures 3c and 3d The test of the present state and the state after washing 10 times with a sample coated with the composition of the present invention as a sample. In addition, Figures 4a to 4d was tested using the test specimen 2 (Klebsiella pneumoniae ATCC 4352), in particular Figures 4a and 4b shows the state after the initial test and culture carried out on the standard cloth, Figure 4c and 4d is a test state of the present state and the state after washing 10 times with the fabric coated with the composition of the present invention as a sample.

As can be seen in these figures, the bacteria rapidly proliferated after culture in the standard cloth, but it can be seen that the test bacteria were almost sterile in this sample. The test results are shown in Table 3 below.

Table 3. Antimicrobial Test

Average number of bacteria Test establishment 1) Test specimen 1 2) Test specimen 2 1) Test specimen 1 2) Test specimen 2 Initial number of bacteria ("0" time) 2.3 × 10 ⁴ 2.0 × 10 ⁴ 113 times increase (more than 31.6 times) 170x increase (more than 31.6x) After standard culture 2.6 × 10 ⁶ 3.4 × 10 ⁶ Test Sample Bacteriostatic rate (%) 1) Test specimen 1 2) Test specimen 2 Presentation 99.9 or more 99.9 or more After washing 10 times 99.9 or more 99.9 or more Nonionic surfactant Use 0.05% nonionic surfactant (TWEEN 80) for inoculation Use of standard cloth KS K 0905 Dyeing fastness

As can be seen from the above anion and far infrared emission test and antimicrobial test, the present invention promotes blood circulation due to the anion and far infrared emission, which facilitates metabolism, removes sweat odor and sterilizes bacteria due to antibacterial and deodorant effect. It is very hygienic.

When the garment made of the present composition is coated with a fabric, and wear, the body having a cationic is more than 40% of the cation is converted to an anion, the body becomes close to the anion or becomes anionic. The degree of difference may vary depending on the person, but the test is applied to a human body having 900 cations per unit area and 50 anions, and the number of cations decreases to about 400 and the number of anions increases to about 300. And it was found.

The embodiments disclosed herein are only presented by selecting the most preferred examples to help those skilled in the art from the various possible examples, the technical spirit of the present invention is not necessarily limited or limited only by this embodiment, the present invention Various changes and modifications are possible within the scope without departing from the spirit of the invention, as well as other equivalent embodiments.

As described above, the present invention is effective to release anion and far infrared rays effective to the human body, as well as antibacterial and deodorant effect, which improves the fit and promotes health. In particular, the present invention is not only environmentally friendly using natural materials tourmaline, yew tree extract, elvan, and chitosan, but also has a beneficial effect on health as compared to a product that artificially emits anions and far infrared rays.

In addition, in the case of the existing product produced by providing anion radiation, antibacterial or deodorant and far infrared radiation alone, the present invention has the advantage that the cost reduction and synergistic effect can be obtained by giving multifunctionality. This composition has many advantages such as antibacterial, deodorizing function, which is most important in hygiene and health products, as well as anion radiation and far-infrared radiation, which are useful for human body. It is expected to be applied to various kinds of jewelry, home appliances and furniture.

Claims (7)

Anion-releasing composition characterized by coating an anion-emitting composition consisting of 15 to 30% by weight of tourmaline, 2 to 5% by weight of binder, 3 to 10% by weight of yew tree extract, and 100% by weight of residual liquid binder. Coated fabric. The method of claim 1, wherein the anion-emitting composition is a fabric coated with an anion-emitting composition, characterized in that the addition of 3 to 10% by weight of elvan powder to emit far infrared rays during manufacture. According to claim 1 or 2, wherein the anion release composition is coated with an anion release composition characterized in that 5 to 10% by weight of liquid chitosan, which exhibits antimicrobial and moisturizing properties during manufacture. According to claim 3, The binder is a thermosetting acrylic series is used, 3 to 8% by weight of the thermosetting silicone to function as an adhesive and to relieve the hardness of the acrylic binder when thermal curing is further added Fabric coated with anion release composition. 2. The fabric of claim 1, wherein the fixing agent of the anion-releasing composition is a silicone-based and / or an acrylic-based. The method of claim 1, wherein the yew tree extract is coated with an anionic release composition, characterized in that it contains a taxol component extracted from the bark or leaves of the anti-cancer component. The method of claim 6, wherein the anion release composition is a fabric coated with an anion release composition, characterized in that 40g ~ 70g is coated per 1M ^{2 of} the fabric.