KR20020048137A - Metallic inc composition, ball point pen tip using the same and aqueous ball point pen comprising the same - Google Patents
Metallic inc composition, ball point pen tip using the same and aqueous ball point pen comprising the same Download PDFInfo
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- KR20020048137A KR20020048137A KR1020000077442A KR20000077442A KR20020048137A KR 20020048137 A KR20020048137 A KR 20020048137A KR 1020000077442 A KR1020000077442 A KR 1020000077442A KR 20000077442 A KR20000077442 A KR 20000077442A KR 20020048137 A KR20020048137 A KR 20020048137A
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- ink composition
- same
- metallic
- tip
- ball point
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- 239000000203 mixture Substances 0.000 title claims abstract description 57
- 229910052751 metal Inorganic materials 0.000 claims abstract description 17
- 239000002184 metal Substances 0.000 claims abstract description 17
- 239000000843 powder Substances 0.000 claims abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000003086 colorant Substances 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 4
- 239000003349 gelling agent Substances 0.000 claims description 4
- 150000005846 sugar alcohols Polymers 0.000 claims description 4
- 229920001285 xanthan gum Polymers 0.000 claims description 4
- 229940082509 xanthan gum Drugs 0.000 claims description 4
- 235000010493 xanthan gum Nutrition 0.000 claims description 4
- 239000000230 xanthan gum Substances 0.000 claims description 4
- 239000003755 preservative agent Substances 0.000 claims description 3
- 239000004909 Moisturizer Substances 0.000 claims description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 2
- 235000010187 litholrubine BK Nutrition 0.000 claims description 2
- 230000001333 moisturizer Effects 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- -1 pH adjusters Substances 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 239000002932 luster Substances 0.000 abstract description 7
- 239000002245 particle Substances 0.000 description 9
- 239000000306 component Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 235000019239 indanthrene blue RS Nutrition 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- HCJLVWUMMKIQIM-UHFFFAOYSA-M sodium;2,3,4,5,6-pentachlorophenolate Chemical compound [Na+].[O-]C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl HCJLVWUMMKIQIM-UHFFFAOYSA-M 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
- C09D11/18—Writing inks specially adapted for ball-point writing instruments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
- B43K—IMPLEMENTS FOR WRITING OR DRAWING
- B43K7/00—Ball-point pens
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
- C09D11/17—Writing inks characterised by colouring agents
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
본 발명은 금속 광택을 가지는 잉크 조성물, 이를 사용하는 볼펜 팁 및 이를 포함하는 수성 볼펜에 관한 것으로, 보다 상세하게는, 금속분 또는 페이스트를 함유하는 금속성 잉크 조성물에 있어서, 상기 금속분 또는 페이스트의 평균 직경이 20 ㎛ 내지 100 ㎛인 것을 특징으로 하는 금속 광택을 가지는 잉크 조성물, 볼의 이동 간격이 20 내지 200 ㎛인 것을 특징으로 하는 상기 잉크 조성물을 사용하는 볼펜 팁 및 이를 포함하는 수성 볼펜에 관한 것이다.The present invention relates to an ink composition having a metallic luster, a ballpoint pen tip using the same, and an aqueous ballpoint pen including the same. More specifically, in a metallic ink composition containing a metal powder or a paste, the average diameter of the metal powder or the paste is It relates to an ink composition having a metallic luster, characterized in that 20 to 100 ㎛, ball point tip using the ink composition characterized in that the movement interval of the ball 20 to 200 ㎛ and an aqueous ball pen comprising the same.
본 발명의 잉크 조성물은 우수한 광택성을 가진다.The ink composition of the present invention has excellent glossiness.
Description
본 발명은 금속 광택을 가지는 잉크 조성물, 이를 사용하는 볼펜 팁 및 이를 포함하는 수성 볼펜에 관한 것이다. 보다 상세하게는, 카드나 포장지, 사진 등에 필기가 가능하며 광택성이 우수한 필기선으로 필기가 가능한 금속성 잉크 조성물, 이를 사용하는 볼펜 팁 및 이를 포함하는 수성 볼펜에 관한 것이다.The present invention relates to an ink composition having a metallic luster, a ballpoint pen tip using the same, and an aqueous ballpoint pen including the same. More specifically, the present invention relates to a metallic ink composition capable of writing on a card, a wrapping paper, a photograph, and the like, and capable of writing with a writing line having excellent gloss, a ballpoint tip using the same, and an aqueous ballpoint pen including the same.
종래부터 금속성 잉크 조성물은 잘 알려져 있었지만 마킹용으로 섬유상 필기 선단을 갖는 필기구에 사용하는 경우에는 섬유상의 기공을 통과하여 종이 필기되기 위해 금속 성분의 평균 입경이 20 ㎛ 이하인 것이 필수 조건이었다.Conventionally, metallic ink compositions have been well known, but when used in writing instruments having a fibrous writing tip for marking, it is essential that the average particle diameter of the metal component is 20 µm or less in order to write the paper through the fibrous pores.
또한, 섬유상 필기 선단 대신에 플라스틱 유도심을 갖는 경우에도 유도심의 막힘을 방지하기 위하여 평균 입경이 20 ㎛이하일 필요가 있다.In addition, even in the case of having a plastic guide core instead of the fibrous writing tip, the average particle diameter needs to be 20 µm or less in order to prevent clogging of the guide core.
최근에 수성 볼펜에 금속성 잉크를 넣은 펜이 판매가 되고 있으나, 이 또한 금속 성분의 입경이 20 ㎛을 초과하지 못한다.Recently, pens containing metallic ink in aqueous ballpoint pens have been sold, but the particle diameter of the metal component does not exceed 20 µm.
이러한 20 ㎛ 이하의 입경을 가지는 금속 성분을 잉크 조성물에 사용한 경우에는 필기선에 광택성이 만족스럽지 못한 문제점이 있었다.When a metal component having a particle size of 20 µm or less is used in the ink composition, there is a problem in that glossiness is not satisfactory in writing lines.
따라서, 광택성이 우수한 금속성 잉크 조성물 및 이를 함유하는 볼펜이 요구되고 있는 실정이다.Therefore, there is a need for a metallic ink composition having excellent glossiness and a ballpoint pen containing the same.
본 발명은 상기 문제점을 해결하고자 안출된 것으로서, 본 발명자들은 우수한 필기선을 제공하기 위하여 금속성분의 평균 입자경을 20 내지 100 ㎛으로 하는 잉크 조성물을 사용하여 볼펜의 팁 선단을 통하여 필기가 가능하도록 예의 연구를 거듭한 결과, 볼펜의 팁 선단의 잉크유로 공간을 형성하는 볼의 이동 간격을 조정함으로써 이러한 잉크 조성물이 볼펜의 팁 선단을 통하여 부드럽게 유출가능하며 필기된 필기 선이 선명한 금속성 필기선을 가짐을 발견하고, 본 발명을 완성하기에 이르렀다.SUMMARY OF THE INVENTION The present invention has been made to solve the above problems, and the present inventors use the ink composition having an average particle diameter of 20 to 100 µm in order to provide excellent writing lines. As a result of research, it is possible to smoothly spill the ink composition through the tip end of the ballpoint pen by adjusting the moving distance of the balls forming the space with the ink oil at the tip end of the ballpoint pen, and the written writing line has a clear metallic writing line. It has been found and the present invention has been completed.
따라서, 본 발명은 광택성이 우수한 금속성 잉크 조성물을 제공함을 그 목적으로 한다.Therefore, an object of this invention is to provide the metallic ink composition excellent in glossiness.
또한, 본 발명은 상기 광택성이 우수한 금속성 잉크 조성물을 사용하는 볼펜 팁을 제공함을 그 목적으로 한다.In addition, an object of the present invention is to provide a ballpoint pen tip using the metallic ink composition excellent in the gloss.
또한, 본 발명은 상기 광택성이 우수한 금속성 잉크 조성물을 사용하는 볼펜 팁을 포함하는 수성 볼펜을 제공함을 그 목적으로 한다.In addition, an object of the present invention is to provide an aqueous ballpoint pen comprising a ballpoint pen tip using the metallic ink composition excellent in the gloss.
상기 목적을 달성하기 위하여, 본 발명은In order to achieve the above object, the present invention
금속분 또는 페이스트를 함유하는 금속성 잉크 조성물에 있어서, 상기 금속분 또는 페이스트의 평균 직경이 20 ㎛ 내지 100 ㎛인 것을 특징으로 하는 금속 광택을 가지는 잉크 조성물을 제공한다.In a metallic ink composition containing a metal powder or a paste, the ink composition having a metallic luster is characterized in that the average diameter of the metal powder or paste is 20 µm to 100 µm.
또한, 본 발명은 볼의 이동 간격이 20 ㎛ 내지 200 ㎛인 것을 특징으로 하는 상기 잉크 조성물을 사용하는 볼펜 팁을 제공한다.In addition, the present invention provides a ballpoint pen tip using the ink composition, characterized in that the movement interval of the ball is 20 ㎛ to 200 ㎛.
또한, 본 발명은 상기 볼펜 팁을 포함하는 수성 볼펜을 제공한다.In addition, the present invention provides an aqueous ballpoint pen including the ballpoint pen tip.
이하 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.
본 발명은 선명한 금속성 광택을 갖는 잉크 조성물로서 수성 볼펜에 저장하여 필기시 볼펜의 선단을 통하여 유출이 원활하고 필기선의 광택이 우수하도록, 잉크 조성물 중에 평균 입경이 20 내지 100 ㎛인 금속분 또는 페이스트를 사용하고, 볼펜의 팁 선단의 잉크유로 공간을 형성하는 볼의 이동 간격을 20 내지 200 ㎛로 함으로써 이러한 잉크 조성물이 볼펜의 팁 선단을 통하여 부드럽게 유출 가능케 하였다.The present invention uses a metal powder or paste having an average particle diameter of 20 to 100 μm in the ink composition so that the ink composition has a vivid metallic luster and is stored in an aqueous ballpoint pen so that it can be easily spilled through the tip of the ballpoint pen and the gloss of writing lines is excellent. Then, the ink composition was allowed to flow out smoothly through the tip end of the ballpoint pen by setting the moving interval of the balls forming the space with the ink oil at the tip end of the ballpoint pen to 20 to 200 m.
즉, 본 발명의 잉크 조성물은 금속성 수성 볼펜용 잉크 조성물로서 필기감이 부드럽고 필기선의 금속 광택이 선명하며, 필기구로서 잉크의 끊어짐이나 필기시 종이에 잉크의 번짐이 없고 일반 수성 볼펜이 갖는 성질을 구비한다.That is, the ink composition of the present invention is an ink composition for a metallic aqueous ballpoint pen, which has a soft writing feeling and a sharp metallic luster of writing lines, and has a property that a general aqueous ballpoint pen does not have a bleeding of ink on paper or at the time of writing as a writing instrument. .
본 발명의 잉크 조성물은 평균 입경이 20 내지 100 ㎛인 금속분 또는 페이스트를 함유함을 특징으로 한다.The ink composition of the present invention is characterized by containing a metal powder or paste having an average particle diameter of 20 to 100 µm.
상기 금속분 또는 페이스트는 잉크 조성물 전체 중량에 대하여 1 내지 10 중량%의 양으로 함유되는 것이 바람직하며, 더욱 바람직하게는 1 내지 5 중량%의 양으로 함유된다.The metal powder or paste is preferably contained in an amount of 1 to 10% by weight based on the total weight of the ink composition, and more preferably in an amount of 1 to 5% by weight.
상기 입경 및 함량 범위에서 필기선의 금속성 및 광택성이 우수하게 나타난다.It is excellent in the metallicity and glossiness of the writing line in the particle size and content range.
본 발명의 잉크 조성물은 겔화제, 보습제, 착색제 및 기타 첨가제를 포함할 수 있다.The ink composition of the present invention may include a gelling agent, a humectant, a colorant and other additives.
상기 겔화제는 수성 잉크의 겔화성을 부여하기 위한 것으로, 잔탄검을 사용할 수 있으며, 이는 전체 잉크 조성물 중량에 대하여 0.5 내지 1.0 중량%의 양으로 포함되는 것이 바람직하다.The gelling agent is to impart gelation property of the aqueous ink, and xanthan gum may be used, which is preferably included in an amount of 0.5 to 1.0% by weight based on the total ink composition weight.
상기 보습제로서는 일가알콜, 이가알콜, 다가 알콜 등이 사용될 수 있으며, 일가알콜의 예로는 에탄올, 이소프로필알콜 등의 물과 혼화하는 알콜을 들 수 있고, 이가 알콜로서는 에틸렌 글리콜, 디에틸렌글리콜, 트리에틸렌글리콜, 폴리에틸렌글리콜 등을 들 수 있고, 삼가 알콜 이상의 다가 알콜로서는 글리세린, 트리메틸올에탄, 트리메틸올프로판 등을 들 수 있으며, 기타 피롤리돈, N-메틸-2-피롤리돈 등을 사용할 수 있다. 이러한 보습제는 전체 잉크 조성물 중량의 10 내지 80 중량%의 양으로 사용될 수 있으며, 바람직하게는 10 내지 30 중량%의 양으로 사용된다.As the moisturizing agent, monohydric alcohol, dihydric alcohol, polyhydric alcohol and the like may be used. Examples of the monohydric alcohol include alcohols miscible with water such as ethanol and isopropyl alcohol, and the dihydric alcohol includes ethylene glycol, diethylene glycol, tri Ethylene glycol, polyethyleneglycol, etc. are mentioned, As polyhydric alcohol more than a trihydric alcohol, Glycerine, a trimethylol ethane, a trimethylol propane, etc. are mentioned, Other pyrrolidone, N-methyl- 2-pyrrolidone, etc. can be used. have. Such moisturizers may be used in amounts of 10 to 80% by weight of the total ink composition weight, preferably in amounts of 10 to 30% by weight.
상기 착색제는 금속성 잉크의 색상을 여러 가지로 나타내기 위한 것으로, 그 예로서, 무기안료로서 산화티탄, 카본 블랙 등이 있으며, 유기 안료로서 카민 6B, C.I. 안료 레드 112, C.I.안료 블루 15, C.I. 안료 그린 7 등을 들 수 있다. 이러한 착색제는 전체 잉크 조성물 중량의 1 내지 50 중량%의 양으로 사용될 수 있으며, 바람직한 사용량은 1 내지 10 중량%이다.The colorant is used to express various colors of the metallic ink, and examples thereof include titanium oxide and carbon black as inorganic pigments, and carmine 6B and C.I. Pigment Red 112, C.I. Pigment Blue 15, C.I. Pigment green 7; and the like. Such colorants can be used in amounts of 1 to 50% by weight of the total ink composition, with a preferred amount of 1 to 10% by weight.
기타 첨가제로서는, 수성 잉크 조성물에 사용가능한 비이온계 및 음이온계 계면활성제, 방부제로서 솔비탄산칼륨, 안식향산나트륨, 펜타클로로페놀나트륨 등을 사용할 수 있고, 방청제로서 벤조트리아졸, pH 조정제로서 수산화나트륨, 트리에탄올아민, 시트릭산 등을 사용할 수 있다.As other additives, nonionic and anionic surfactants usable in aqueous ink compositions, potassium sorbitan carbonate, sodium benzoate, sodium pentachlorophenol and the like as preservatives, benzotriazole as a rust inhibitor, sodium hydroxide as a pH adjuster, Triethanolamine, citric acid, etc. can be used.
또한, 상기 잉크 조성물을 사용하는 본 발명의 볼펜 팁은 볼펜의 팁 선단의 잉크유로 공간을 형성하는 볼의 이동간격이 20 내지 200 ㎛인 것을 특징으로 한다. 보다 바람직한 볼의 이동 간격은 40 내지 120 ㎛이다.In addition, the ballpoint tip of the present invention using the ink composition is characterized in that the movement interval of the ball to form a space with the ink flow at the tip end of the ballpoint pen is 20 to 200 ㎛. More preferably, the movement distance of the balls is 40 to 120 µm.
본 발명의 잉크 조성물은, 실온에서 서서히 교반 하에 물에 크산탄 검 등의 겔화제를 서서히 가하고 완전히 분산시킨 후, 다가알콜 등의 수성 매체 성분 및 글리콜 에테르 등의 침투 건조제, 착색제 및 기타 첨가제를 가하고, 이들을 용해 또는 균일하게 분산시키고, 금속성 성분은 물과 별도로 분산시킨 상태에서 상기 분산액에 첨가하여 균일하게 분산함으로써, 제조될 수 있다.In the ink composition of the present invention, a gelling agent such as xanthan gum is gradually added to water and gradually dispersed in water under gentle stirring at room temperature, and then, an aqueous medium component such as polyhydric alcohol, a penetration drying agent such as glycol ether, a coloring agent and other additives are added thereto. They can be prepared by dissolving or uniformly dispersing the same, and adding the metallic component to the dispersion in a state where it is dispersed separately from water to disperse uniformly.
또한, 본 발명의 잉크 조성물은 플라스틱 튜브에 넣어서 잉크 조성물의 뒷면에 구리스를 넣어서 보존 안정성 및 충격안정성을 우수하게 할 수 있다.In addition, the ink composition of the present invention can be put in a plastic tube to put grease on the back of the ink composition to excellent storage stability and impact stability.
이하, 본 발명을 하기 실시예 및 비교예에 의거하여 본 발명을 보다 구체적으로 설명하나, 이는 본 발명을 예시하기 위한 것일 뿐 본 발명이 이에 제한되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to the following Examples and Comparative Examples, which are intended to illustrate the present invention, but the present invention is not limited thereto.
[실시예 1]Example 1
물 59 중량%에 실온에서 서서히 교반시키면서 잔탄검 (KELCO사 제품 상품명 Keltrol 또는 Kelzan) 0.5 중량%를 서서히 가하고 완전히 분산시킨 후 글리세린 30중량%, C.I. 안료 블루 60 5 중량% 및 방부제 (PLOCEL XL-2) 0.5 중량%를 가하고 용해 또는 동일하게 분산시켰다. 금속분 (ECKART-WERKE사제 METALLUX) 5 중량%를 물과 별도로 분산시킨 상태에서 상기 분산액에 첨가하여 균일하게 분산하여 잉크 조성물을 제조하였다.0.5 wt% of xanthan gum (Kelco trade name Keltrol or Kelzan) was slowly added to 59 wt% of water at room temperature with 30 wt% of glycerin, C.I. 5 wt% Pigment Blue 60 and 0.5 wt% preservative (PLOCEL XL-2) were added and dissolved or dispersed equally. 5 wt% of metal powder (METALLUX, manufactured by ECKART-WERKE) was added to the dispersion in a state where it was dispersed separately from water to uniformly disperse the ink composition.
상기 잉크 조성물을 일반시중에서 구입가능한 동아연필제의 수성 볼펜인 3-제로펜 또는 젤티니펜에 넣어 견본 펜을 제작하였다.A sample pen was prepared by putting the ink composition into 3-zero pen or geltin pen, which is an aqueous ball pen made of commercially available Dong-A pencil.
[실시예 2]Example 2
금속분으로서 ECKART-WERKE사제 METALLUX 대신 日本板硝子(주) 제품 그라스플레이트 (상품명: 크리스탈스타)을 사용한 것 이외에는, 실시예 1과 동일한 방법으로 청색조의 금속성 잉크를 제조하였다.A blue-colored metallic ink was prepared in the same manner as in Example 1 except that a glass plate (trade name: Crystal Star) manufactured by Nippon Co., Ltd. was used instead of METALLUX manufactured by ECKART-WERKE.
[실시예 3]Example 3
금속분으로서 ECKART-WERKE사제 METALLUX 대신 ZEON KASE (주)제 상품명 AL COMPOUND를 사용한 것을 제외하고는, 실시예 1과 동일한 방법으로 청색조의 금속성 잉크를 제조하였다.A blue-colored metallic ink was prepared in the same manner as in Example 1, except that ZEON KASE Co., Ltd. brand name AL COMPOUND was used instead of METALLUX manufactured by ECKART-WERKE.
[실시예 4]Example 4
안료로서 C.I.안료 블루 60 대신에 C.I 안료 레드 209를 사용한 것을 제외하고는, 실시예 1과 동일한 방법으로 빨강색조의 금속성 잉크를 제조하였다.A reddish metallic ink was prepared in the same manner as in Example 1 except that C.I Pigment Red 209 was used instead of C.I. Pigment Blue 60 as a pigment.
[비교예 1]Comparative Example 1
금속분으로서 ECKART-WERKE사제 METALLUX 대신ECKART-WERKE사제 STAPA HYDROLAC을 이용한 것을 제외하고는, 실시예 1과 동일한 방법으로 금속성 잉크를제조하였다.A metallic ink was prepared in the same manner as in Example 1, except that STAPA HYDROLAC manufactured by ECKART-WERKE was used instead of METALLUX manufactured by ECKART-WERKE.
[비교예 2]Comparative Example 2
금속분으로서 ECKART-WERKE사제 METALLUX 대신 SHOWA ALUMINUM POWDER (주) 제 Leafing Type #200 Series를 사용한 것을 제외하고는, 실시예 1과 동일한 방법으로 금속성 잉크를 제조하였다.Metallic ink was prepared in the same manner as in Example 1, except that Leafing Type # 200 Series manufactured by SHOWA ALUMINUM POWDER Co., Ltd. was used instead of METALLUX manufactured by ECKART-WERKE.
실시예 1-4의 금속성 잉크 조성물은 선명한 금속성을 나타내고 있었으나, 비교예 1 및 2의 조성물은 금속성분이 떨어지는 것이 육안으로 확실히 판단되었다.Although the metallic ink composition of Example 1-4 showed clear metallicity, it was judged visually that the composition of Comparative Examples 1 and 2 was inferior in metal component.
이상에서와 같이, 본 발명의 잉크 조성물은 평균 입경이 20 내지 100 ㎛인 금속분을 사용하고 이 잉크 조성물을 저장한 수성 볼펜의 팁을 금속 성분이 충분히 유출가능하도록 볼의 이동 간격을 20 내지 200 ㎛로 함에 의하여, 필기 선에 금속 광택이 우수한 효과를 보인다.As described above, the ink composition of the present invention uses a metal powder having an average particle diameter of 20 to 100 µm, and moves the ball 20 to 200 µm so that the tip of the aqueous ballpoint pen storing the ink composition can sufficiently flow out of the metal component. By this, the metallic luster on the writing line shows an excellent effect.
Claims (8)
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59172565A (en) * | 1983-03-18 | 1984-09-29 | Sakura Color Prod Corp | Ink composition |
| JPS61123684A (en) * | 1985-10-08 | 1986-06-11 | Sakura Color Prod Corp | Double coloring ink composition |
| JPH08209053A (en) * | 1994-05-27 | 1996-08-13 | Pentel Kk | Water-based metallic luster color ink |
| WO2000001778A1 (en) * | 1998-07-03 | 2000-01-13 | Sakura Color Products Corporation | Double-color ink and writing utensil containing the same |
| KR100309197B1 (en) * | 1993-01-29 | 2001-12-28 | 아사베 히로시 | Water-based Metal Inks for Ballpoint Pens |
| KR100364178B1 (en) * | 1996-12-12 | 2003-01-24 | 미츠비시엔피츠가부시키가이샤 | Water-base ballpoint ink having metallic glossy color |
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2000
- 2000-12-16 KR KR1020000077442A patent/KR20020048137A/en not_active Application Discontinuation
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59172565A (en) * | 1983-03-18 | 1984-09-29 | Sakura Color Prod Corp | Ink composition |
| JPS61123684A (en) * | 1985-10-08 | 1986-06-11 | Sakura Color Prod Corp | Double coloring ink composition |
| KR100309197B1 (en) * | 1993-01-29 | 2001-12-28 | 아사베 히로시 | Water-based Metal Inks for Ballpoint Pens |
| JPH08209053A (en) * | 1994-05-27 | 1996-08-13 | Pentel Kk | Water-based metallic luster color ink |
| KR100364178B1 (en) * | 1996-12-12 | 2003-01-24 | 미츠비시엔피츠가부시키가이샤 | Water-base ballpoint ink having metallic glossy color |
| WO2000001778A1 (en) * | 1998-07-03 | 2000-01-13 | Sakura Color Products Corporation | Double-color ink and writing utensil containing the same |
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