KR20020031750A - Ink-jet Printer Ink containing Natural Herb Oil - Google Patents
Ink-jet Printer Ink containing Natural Herb Oil Download PDFInfo
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- KR20020031750A KR20020031750A KR1020000062458A KR20000062458A KR20020031750A KR 20020031750 A KR20020031750 A KR 20020031750A KR 1020000062458 A KR1020000062458 A KR 1020000062458A KR 20000062458 A KR20000062458 A KR 20000062458A KR 20020031750 A KR20020031750 A KR 20020031750A
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- -1 polyoxyethylene Polymers 0.000 claims abstract description 13
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 4
- 239000002904 solvent Substances 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 15
- 239000003921 oil Substances 0.000 claims description 6
- 239000010516 ayurvedic herbal oil Substances 0.000 claims description 3
- 240000000073 Achillea millefolium Species 0.000 claims description 2
- 235000007754 Achillea millefolium Nutrition 0.000 claims description 2
- 240000008554 Aloysia triphylla Species 0.000 claims description 2
- 235000013668 Aloysia triphylla Nutrition 0.000 claims description 2
- 240000003538 Chamaemelum nobile Species 0.000 claims description 2
- 235000007866 Chamaemelum nobile Nutrition 0.000 claims description 2
- 240000004784 Cymbopogon citratus Species 0.000 claims description 2
- 235000017897 Cymbopogon citratus Nutrition 0.000 claims description 2
- 244000004281 Eucalyptus maculata Species 0.000 claims description 2
- 241000208152 Geranium Species 0.000 claims description 2
- 235000010650 Hyssopus officinalis Nutrition 0.000 claims description 2
- 235000010254 Jasminum officinale Nutrition 0.000 claims description 2
- 240000005385 Jasminum sambac Species 0.000 claims description 2
- 240000005183 Lantana involucrata Species 0.000 claims description 2
- 235000013628 Lantana involucrata Nutrition 0.000 claims description 2
- 244000178870 Lavandula angustifolia Species 0.000 claims description 2
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 2
- 235000007232 Matricaria chamomilla Nutrition 0.000 claims description 2
- 244000062730 Melissa officinalis Species 0.000 claims description 2
- 235000010654 Melissa officinalis Nutrition 0.000 claims description 2
- 235000006679 Mentha X verticillata Nutrition 0.000 claims description 2
- 235000002899 Mentha suaveolens Nutrition 0.000 claims description 2
- 235000001636 Mentha x rotundifolia Nutrition 0.000 claims description 2
- 235000006677 Monarda citriodora ssp. austromontana Nutrition 0.000 claims description 2
- 244000179970 Monarda didyma Species 0.000 claims description 2
- 235000010672 Monarda didyma Nutrition 0.000 claims description 2
- 235000010676 Ocimum basilicum Nutrition 0.000 claims description 2
- 240000007926 Ocimum gratissimum Species 0.000 claims description 2
- 240000007817 Olea europaea Species 0.000 claims description 2
- 235000011203 Origanum Nutrition 0.000 claims description 2
- 240000000783 Origanum majorana Species 0.000 claims description 2
- 244000178231 Rosmarinus officinalis Species 0.000 claims description 2
- 244000228451 Stevia rebaudiana Species 0.000 claims description 2
- 235000007303 Thymus vulgaris Nutrition 0.000 claims description 2
- 240000002657 Thymus vulgaris Species 0.000 claims description 2
- 150000005215 alkyl ethers Chemical class 0.000 claims description 2
- 239000001102 lavandula vera Substances 0.000 claims description 2
- 235000018219 lavender Nutrition 0.000 claims description 2
- HELXLJCILKEWJH-NCGAPWICSA-N rebaudioside A Chemical compound O([C@H]1[C@H](O)[C@@H](CO)O[C@H]([C@@H]1O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)O[C@]12C(=C)C[C@@]3(C1)CC[C@@H]1[C@@](C)(CCC[C@]1([C@@H]3CC2)C)C(=O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HELXLJCILKEWJH-NCGAPWICSA-N 0.000 claims description 2
- 235000002020 sage Nutrition 0.000 claims description 2
- 239000001585 thymus vulgaris Substances 0.000 claims description 2
- 240000006054 Agastache cana Species 0.000 claims 1
- 239000000976 ink Substances 0.000 description 30
- 239000003205 fragrance Substances 0.000 description 11
- 239000003094 microcapsule Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 4
- 230000035943 smell Effects 0.000 description 4
- 230000001133 acceleration Effects 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 3
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 1
- 240000001194 Heliotropium europaeum Species 0.000 description 1
- 240000001812 Hyssopus officinalis Species 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002996 emotional effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 230000008786 sensory perception of smell Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
본 발명은 잉크젯 프린터용 잉크 조성물 특히, 인쇄를 하면 인쇄물에서 향기가 나는 잉크젯(ink-jet) 프린터용 잉크 조성물에 관한 것이다.The present invention relates to an ink composition for an inkjet printer, and in particular, an ink composition for an ink-jet printer which, when printed, smells in a printed matter.
잉크는 물과 색소(수용성 염료 또는 수불용성 안료)를 주성분으로 하여 보습제, 분산제 등의 첨가물로 이루어지는데 잉크에 향료를 혼합함으로써 카드나 광고지 등의 인쇄물에서 향기가 나게 하고자 하는 시도가 있어 왔다.Inks consist of additives such as moisturizers and dispersants with water and pigments (water-soluble dyes or water-insoluble pigments) as main ingredients, and there have been attempts to make fragrances in printed materials such as cards and advertisements by mixing flavors with ink.
향기나는 인쇄물을 제작하기 위하여 지금까지 시도된 종래기술을 살펴보면 다음과 같다.Looking at the prior art attempted to produce a fragrant print as follows.
한국 공개특허공보 95-8640에는 방향제 마이크로 캡슐을 함유하는 스크린 인쇄용 잉크 조성물에 관한 발명이 개시되어 있다. 그러나, 마이크로 캡슐의 존재로 인하여 잉크가 미세한 노즐을 통하여 분사되는 잉크젯 프린터에는 적합치 않다.Korean Laid-Open Patent Publication No. 95-8640 discloses an invention relating to an ink composition for screen printing containing a fragrance microcapsule. However, due to the presence of microcapsules, it is not suitable for ink jet printers in which ink is ejected through fine nozzles.
한국 공개특허공보 97-65665에는 합성향료를 1∼10중량% 함유하는 잉크 조성물에 관한 발명이 개시되어 있다. 그러나, 사용할 수 있는 향의 종류가 수용성인 합성향료에만 국한되어 다양한 향을 낼 수가 없는 단점이 있다.Korean Unexamined Patent Publication No. 97-65665 discloses an ink composition containing 1 to 10% by weight of synthetic perfume. However, the kind of fragrance that can be used is limited to synthetic fragrances that are water-soluble, and thus can not produce various fragrances.
일본 특개평5-185689에는 인쇄물에서 향기가 나게 하기 위하여 잉크 분사시 향료도 동시에 분사되도록 한 구성의 프린터가 개시되어 있다. 효과에 있어서는 본 발명과 동일하다고 할 수 있으나 향료가 잉크 조성물의 하나로서가 아니라 별도로 분사되는 점이 다르다.Japanese Patent Laid-Open No. Hei 5-185689 discloses a printer in which a fragrance is also sprayed at the same time when ink is sprayed in order to make a printed product smell. In effect, it can be said that it is the same as this invention, but the fragrance is sprayed separately instead of one of the ink compositions.
일본 특개평7-53904에는 서방성 향료를 함유하여 종래의 잉크보다 5∼10배 길게 향기가 지속되는 스크린 잉크 조성물에 관한 발명이 개시되어 있다. 그러나, 이는 유성이며 합성수지가 함유되어 있어 잉크젯 프린터에는 사용할 수 없다.Japanese Laid-Open Patent Publication No. Hei 7-53904 discloses a screen ink composition containing a sustained-release perfume and lasting for 5 to 10 times longer than a conventional ink. However, it is oily and contains synthetic resins and cannot be used in inkjet printers.
일본 특개평7-3075에는 광고지 등의 인쇄물에 방향성분의 마이크로 캡슐을 합성수지로 종이표면에 약하게 접착시켜 손으로 만지면 향기가 나게 되는 잉크 조성물에 관한 발명이 개시되어 있다.Japanese Patent Laid-Open No. Hei 7-3075 discloses an ink composition in which a microcapsule of an aromatic component is applied to a printed matter such as an advertisement paper by weakly adhering it to a paper surface with a synthetic resin, and the fragrance is touched by hand.
미합중국 특허3,888,689에는 향료의 마이크로 캡슐을 함유하는 수성잉크 및 향료의 마이크로 캡슐 제조방법이 개시되어 있다. 한국 공개특허공보 95-8640와 마찬가지로 마이크로 캡슐의 존재로 인하여 잉크젯 프린터에는 사용할 수 없다.US Pat. No. 3,888,689 discloses a process for preparing microcapsules of aqueous inks and flavorings containing microcapsules of flavoring. Similar to Korea Patent Application Publication No. 95-8640, due to the presence of the microcapsule, the inkjet printer cannot be used.
이상 살펴본 바와 같이, 종래기술에서는 인쇄물에서 향기가 나게 하기 위하여 주로 향료를 담은 마이크로 캡슐을 잉크에 섞거나 수용성기를 도입한 합성향료에 의하고 있다. 이는 천연향이 대부분 유성(비극성)이어서 용매인 물과 혼합되지 않을 뿐만 아니라 혼합하기 위하여 통상의 계면활성제를 사용하는 경우에는 잉크의 저장 안정성, 인쇄품질 등이 손상되는 폐단이 있기 때문이다.As described above, in the prior art, the microcapsules containing fragrance are mainly mixed with ink or introduced with a synthetic fragrance to introduce a water-soluble group in order to make the printed product smell. This is because the natural flavor is mostly oily (non-polar), so that it is not mixed with water, which is a solvent, and when a conventional surfactant is used for mixing, there is a disadvantage that damages storage stability, print quality, and the like of the ink.
본 발명의 목적은 잉크의 저장 안정성 및 인쇄품질 등이 손상시키지 않으면서 천연 허브오일을 함유하는 잉크젯 프린터용 잉크 조성물을 제공하는 것이다.It is an object of the present invention to provide an ink composition for an inkjet printer containing natural herbal oils without impairing the storage stability and print quality of the ink.
용매인 물 100중량부를 기준으로 HLB(hydrophilic lipophilic balance)값이 8∼15인 비이온계 계면활성제 0.1∼3.0중량부와 유성의 천연 허브오일 0.1∼3.0중량부를 함유하는 잉크젯 프린터용 잉크 조성물.An ink composition for an inkjet printer containing 0.1 to 3.0 parts by weight of a nonionic surfactant having a hydrophilic lipophilic balance (HLB) value of 8 to 15 and 0.1 to 3.0 parts by weight of an oily natural herbal oil based on 100 parts by weight of water as a solvent.
상기 HLB값이 8∼15인 비이온계 계면활성제로는 하기 [화학식 1]의 폴리옥시에틸렌 알킬 페놀 에테르(polyoxyethylene alkyl phenol ether)를 사용한다.As the nonionic surfactant having an HLB value of 8 to 15, polyoxyethylene alkyl phenol ether of the following [Formula 1] is used.
여기에서, Ph는 페닐기이고, x는 5∼12의 정수이고, n은 4∼12의 정수이다.Ph is a phenyl group, x is an integer of 5-12, n is an integer of 4-12.
상기 [화학식 1]의 폴리옥시에틸렌 알킬 페놀 에테르 대신 페닐기가 없는 하기 [화학식 2]의 폴리옥시에틸렌 알킬 에테르(polyoxyethylene alkyl ether)를 사용할 수도 있다.Instead of the polyoxyethylene alkyl phenol ether of [Formula 1], a polyoxyethylene alkyl ether of [Formula 2] without a phenyl group may be used.
여기에서, x는 10∼17의 정수이고, n은 3∼10의 정수이다.Here, x is an integer of 10-17, n is an integer of 3-10.
유성의 천연 허브오일로는 이를테면, 라벤더, 레몬 그라스, 레몬 밤, 레몬 버베나, 로즈마리, 람스 이어, 마조람, 민트, 바질, 베르가못, 세이지, 스테비아, 얄로우, 오레가노, 올리브, 유칼립투스, 쟈스민, 제라늄, 캐모마일, 타임, 헬리오트러프, 휀넬, 휘버휴, 히솝에서 1 또는 2 이상 선택한다.Oily natural herbal oils include lavender, lemongrass, lemon balm, lemon verbena, rosemary, ram's ear, marjoram, mint, basil, bergamot, sage, stevia, yarrow, oregano, olive, eucalyptus, jasmine, geranium, Choose from 1 or 2 of Chamomile, Thyme, Heliotrope, Chanel, Huber Hue, and Hyssop.
상기 본 발명의 잉크젯 프린터용 잉크 조성물은 다음 실시예에 기재된 방법에 의하여 제조될 수 있다.The ink composition for an inkjet printer of the present invention can be prepared by the method described in the following examples.
<실시예 1><Example 1>
비이온 계면활성제로 폴리옥시에틸렌 노닐 페놀 에테르(polyoxyethylene nonyl phenol ether) 0.5g과 라벤더 오일 0.3g을 증류수 100㎖에 넣고 고속분산기로 약 2,000rpm으로 2시간 동안 교반하여 에멀젼을 형성시킨 후, 증류수 대신 사용하여 잉크젯 프린터용 잉크를 제조하였다.0.5 g of polyoxyethylene nonyl phenol ether and 0.3 g of lavender oil were added to 100 ml of distilled water as a nonionic surfactant, and the mixture was stirred at about 2,000 rpm for 2 hours using a high speed disperser to form an emulsion. To prepare an ink for an inkjet printer.
상기 방법에 의하여 제조된 잉크는 원심분리기를 사용하여 10,000g(g: 중력가속도)에서 10분간 원심분리하여도 층분리가 생기지 않았고, 엡손용 카트리지에 주입하여 인쇄한 결과, 노즐이 막히는 현상없이 인쇄가 가능하였다.The ink prepared by the above method did not produce a layer separation even after centrifugation at 10,000 g (g: gravity acceleration) for 10 minutes using a centrifugal separator. The ink was injected into the Epson cartridge and printed, resulting in no clogging of the nozzle. Was possible.
그리고, 인쇄물을 노출시킨 경우에는 일주일 이상, 카드처럼 봉투에 담아놓음ㅁ 경우에는 한달 이상 인쇄물에서 향기를 맡을 수 있었다.And, if the printed matter was exposed for more than a week, such as a card in an envelope, in the case of a month or more could smell the printed matter.
<실시예 2><Example 2>
휴렛 팩커드사의 잉크젯 프린터용 잉크(HP51636, black) 100㎖에 비이온 계면활성제로 폴리옥시에틸렌 라우릴 에테르(polyoxyethylene lauryl ether) 0.5g과 라벤더 오일 0.5g을 넣고 고속분산기로서 약 2,000rpm으로 2시간동안 교반하였다.To 100 ml of Hewlett Packard's inkjet printer ink (HP51636, black), 0.5 g of polyoxyethylene lauryl ether and 0.5 g of lavender oil were added as a nonionic surfactant for about 2 hours at 2,000 rpm as a high-speed disperser. Stirred.
상기 방법에 의하여 허브오일과 계면활성제가 첨가된 잉크는 10,000g(g: 중력가속도)에서 10분간 원심분리하여도 층분리가 생기지 않았고, 다시 카트리지에 충전하여 인쇄한 결과, 노즐이 막히는 현상없이 인쇄가 가능하였다.The ink to which the herbal oil and the surfactant were added was not separated by centrifugation for 10 minutes at 10,000 g (g: gravitational acceleration) by the above method. Was possible.
그리고, 인쇄물을 대기중에 노출시킨 경우에는 일주일 이상, 카드처럼 밀봉된 상태에서는 한달 이상 인쇄물에서 향기를 맡을 수 있었다.In addition, when the printed matter was exposed to the atmosphere, the printed matter could be smelled for more than a week when sealed like a card.
<실시예 3><Example 3>
휴렛 팩커드사의 잉크젯 프린터용 잉크(C1823A, colour)에서 뽑아낸 잉크( magenta, yellow, cyan) 100㎖에 각각 비이온 계면활성제로 폴리옥시에틸렌 올레일 에테르(polyoxyethylene oleyl ether) 0.5g과 라벤더 오일 0.5g을 넣고 고속 분산기로서 약 2,000rpm으로 2시간동안 교반하였다.In 100 ml of ink (magenta, yellow, cyan) extracted from Hewlett Packard's inkjet printer ink (C1823A, colour), 0.5 g of polyoxyethylene oleyl ether and 0.5 g of lavender oil were used as nonionic surfactants, respectively. Was added and stirred at about 2,000 rpm for 2 hours as a high speed disperser.
상기 방법에 의하여 허브오일과 계면활성제가 첨가된 잉크는 10,000g(g: 중력가속도)에서 10분간 원심분리하여도 층분리가 생기지 않았고, 다시 카트리지에 충전하여 인쇄한 결과, 노즐이 막히는 현상없이 인쇄가 가능하였다.The ink to which the herbal oil and the surfactant were added was not separated by centrifugation for 10 minutes at 10,000 g (g: gravitational acceleration) by the above method. Was possible.
그리고, 인쇄물을 대기중에 노출시킨 경우에는 일주일 이상, 카드처럼 밀봉된 상태에서는 한달 이상 인쇄물에서 향기를 맡을 수 있었다.In addition, when the printed matter was exposed to the atmosphere, the printed matter could be smelled for more than a week when sealed like a card.
본 발명에 의하면 저장 안정성이 손상되지 않으며 향기가 오랫동안 지속되는 잉크젯 프린터용 잉크가 제공된다.According to the present invention, there is provided an ink for an ink jet printer in which the storage stability is not impaired and the fragrance lasts for a long time.
또한, 향기나는 카드나 인사장 등의 인쇄물을 제작할 수 있어 인쇄물에 단순한 정보전달 기능 외에 후각에 의한 감성전달 기능이 추가될 수 있다.In addition, it is possible to produce a printed card, such as a fragrant card or greeting card, so that in addition to the simple information transfer function can be added to the emotional transfer function by the sense of smell.
Claims (4)
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| Application Number | Priority Date | Filing Date | Title |
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| KR1020000062458A KR20020031750A (en) | 2000-10-24 | 2000-10-24 | Ink-jet Printer Ink containing Natural Herb Oil |
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| KR1020000062458A KR20020031750A (en) | 2000-10-24 | 2000-10-24 | Ink-jet Printer Ink containing Natural Herb Oil |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| KR20020093703A (en) * | 2002-11-06 | 2002-12-16 | 이성진 | Manufacturing method of soybean oil ink with natural fragrance and fragrance emitting emotional print using the same |
| KR20040034925A (en) * | 2002-10-17 | 2004-04-29 | 동아연필 주식회사 | Ink Composite for Writing board |
| KR100798404B1 (en) * | 2007-06-25 | 2008-01-28 | 세창화학 주식회사 | Water-soluble antibacterial ink composition and hygiene material using the same |
| KR100798405B1 (en) * | 2007-06-25 | 2008-01-28 | 세창화학 주식회사 | Method for preparing water-soluble antimicrobial ink composition and method for preparing sanitary article material using the same |
| KR102324915B1 (en) * | 2021-06-22 | 2021-11-12 | 주식회사 한국펄프 | Natural ingredient paper sheet for pets and manufacturing method thereof |
| CN116554733A (en) * | 2023-06-08 | 2023-08-08 | 昆山合美标识设计制作有限公司 | Fragrant advertisement jet printing ink and preparation method and application thereof |
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| KR102324915B1 (en) * | 2021-06-22 | 2021-11-12 | 주식회사 한국펄프 | Natural ingredient paper sheet for pets and manufacturing method thereof |
| CN116554733A (en) * | 2023-06-08 | 2023-08-08 | 昆山合美标识设计制作有限公司 | Fragrant advertisement jet printing ink and preparation method and application thereof |
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