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KR19980052456A - Method for manufacturing cold-rolled wire rod with excellent spheroidizing heat treatment - Google Patents

Method for manufacturing cold-rolled wire rod with excellent spheroidizing heat treatment Download PDF

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KR19980052456A
KR19980052456A KR1019960071445A KR19960071445A KR19980052456A KR 19980052456 A KR19980052456 A KR 19980052456A KR 1019960071445 A KR1019960071445 A KR 1019960071445A KR 19960071445 A KR19960071445 A KR 19960071445A KR 19980052456 A KR19980052456 A KR 19980052456A
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heat treatment
cooling
wire rod
wire
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KR100268852B1 (en
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김종필
정두찬
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김종진
포항종합제철 주식회사
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • C21D1/32Soft annealing, e.g. spheroidising
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • C21D9/525Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length for wire, for rods
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/003Cementite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

본 발명은 신선 및 열처리공정을 거친후 냉간압조 또는 절삭가공 제품을 만드는 소재로 사용되는 열간압연한 5.5∼42㎜ Ψ 치수의 구상화 열처리성이 우수한 냉간압조용 선재의 제조 방법에 대한 것이다.The present invention relates to a method for producing a cold-rolled wire rod having excellent spherical heat treatment properties of hot rolled 5.5 to 42 mm Ψ dimensions used as a material for cold-rolling or cutting products after drawing and heat treatment.

본 발명의 구상화 열처리성이 우수한 냉간압조용 선재의 제조 방법은, 중량%로, C:0.25∼0.60%, Si:0.10∼0.35%, Mn:0.30∼2.0%, P:0.030% 이하, S:0.030% 이하, Cr:1.5% 이하, Mo:0.5% 이하, Cu:0.10% 이하, Al:0.005∼0.070%, 잔부 Fe 및 기타 불가피하게 함유되는 불순물로 이루어진 강을, 선재 압연전 가열로에서 1100∼1300℃로 가열하고, 선재압연중 소재 표면 온도를 950℃ 이상으로 유지하여 오스테나이트 입자를 ASTM No.8 이하로 최대한 조대화시키고, 선재 압연된 강을 냉각 개시 온도 880-1000℃로 선택하여 냉각시 630-1000℃ 온도 영역에서는 10-25℃/초의 냉각 속도로 냉각하고 630-500℃ 온도 영역에서는 5-15℃/초의 속도로 냉각하여 냉각된 선재의 페라이트 분율을 12% 이하로 제어하여 구상화 열처리후 구상화율이 88% 이상이며 구상화 세멘타이트 입자가 균일하게 분포하도록 한 것을 기술 요지로 한다.The manufacturing method of the cold-rolling wire rod excellent in the spheroidizing heat treatment property of this invention is C: 0.25-0.60%, Si: 0.10-0.35%, Mn: 0.30-2.0%, P: 0.030% or less, S: A steel consisting of 0.030% or less, Cr: 1.5% or less, Mo: 0.5% or less, Cu: 0.10% or less, Al: 0.005 to 0.070%, balance Fe, and other unavoidably contained impurities, is 1100 in a heating furnace before wire rolling. Heating to ~ 1300 ℃, maintaining the surface temperature of the material during the wire rolling to 950 ℃ or higher, coarsening the austenite particles to ASTM No.8 or lower, and selecting the wire-rolled steel at the cooling start temperature of 880-1000 ℃. During cooling, cooling is performed at a cooling rate of 10-25 ℃ / second in the temperature range of 630-1000 ℃ and at a rate of 5-15 ℃ / second in the temperature range of 630-500 ℃ to control the ferrite fraction of the cooled wire to 12% or less. After spheroidizing heat treatment, the spheroidization rate is over 88% and the spheroidized cementite particles are uniformly distributed. And as a base.

Description

구상화 열처리성이 우수한 냉간압조용 선재의 제조방법.Method for producing cold-rolled wire rod with excellent spheroidizing heat treatment property.

본 발명은 신선 및 열처리공정을 거진후 냉간압조 또는 절삭가공 제품을 만드는 소재로 사용되는 열간압연한 5.5∼42㎜ Ψ 치수의 구상화 열처리성이 우수한 냉간압조용 선재의 제조 방법에 대한 것이다.The present invention relates to a method for producing a cold rolled wire rod having excellent spheroidizing heat treatment property of hot rolled 5.5 to 42 mm Ψ dimension used as a material for making a cold press or a cut product after the drawing and heat treatment process.

선재의 열간압연 제조 공정은 도 1에 개략적으로 도시된 바와 같이, 가열로와, 선재 압연과정을 거친후, 권취기에서 선재의 냉각이 개시되어 선재를 냉각하는 과정을 통해 제조하는데, 그 제조 기술에 대해서는 종래 여러 방법이 알려져 있으며, 일반적으로 C:0.025-0.050%, Si:0.010-0.035%, Mn:0.30-2.0%를 포함하여, 이루어지는 열간압연한 강을 냉간압연하여 제조하였다.The hot rolling manufacturing process of the wire rod is manufactured through a process of heating the wire rod and the wire rod rolling process, and then cooling the wire rod in the winding machine to cool the wire rod, as shown in FIG. 1. Various methods are known in the related art, and are generally manufactured by cold rolling a hot rolled steel including C: 0.025-0.050%, Si: 0.010-0.035%, and Mn: 0.30-2.0%.

그러나, 일반적으로 5.5∼42 ㎜ Ψ 치수로 생산되는 열간압연한 실리콘 킬드강(C:0.025-0.050%, Si:0.010-0.035%, Mn:0.30-2.0%)은, 인성이 저하하고, 구상화 열처리성이 떨어지는 문제가 있는등, 종래 실리콘 킬드강의 선재 제조방법의 경우 열간압연후 코일상태의 선재 냉각시 소입 열처리성을 확보하기 위하여 즉, 최대한 조대한 조직 확보가 요구되므로 극서냉을 적용하며, 종래강에서 느린냉각 적용시 열간압연후 선재코일 냉각 과정에서 페라이트 핵생성과 성장이 용이하게 이루어지므로 페라이트 분율(점유비)이 높아져 구상화 열처리시 균일한 구상화 조직을 확보하기가 어렵다.However, in general, hot-rolled silicon-kilted steels (C: 0.025-0.050%, Si: 0.010-0.035%, Mn: 0.30-2.0%) produced in 5.5 to 42 mm Ψ dimensions have lowered toughness and spheroidized heat treatment. In the case of the conventional method of manufacturing the wire rod of silicon-kilted steel, such as poor properties, in order to ensure hardening heat treatment property when cooling the wire in the coil state after hot rolling, that is, it is required to secure the coarse structure as much as possible. In the case of slow cooling in the steel, ferrite nucleation and growth are facilitated in the process of cooling the wire coil after hot rolling, so that the ferrite fraction (occupancy ratio) increases, making it difficult to secure a uniform nodular structure during nodular heat treatment.

따라서, 본 발명은, 강의 제강 과정에서 적절한 강의 화학성분을 선택하고 빌레트(Billet)를 선재로 열간압연 및 냉각하는 과정에서 철강의 금속조직을 적절히 제어함으로써 구상화 열처리성이 우수한 열간압연한 냉간압조용 선재를 제조하는 방법을 제공하는데 그 목적이 있다.Accordingly, the present invention is suitable for hot rolling cold rolling with excellent spheroidizing heat treatment property by appropriately controlling the metal structure of the steel in the process of selecting an appropriate steel chemical composition in the steelmaking process of the steel and hot rolling and cooling the billet with wire. The purpose is to provide a method for manufacturing the wire rod.

도 1은 종래의 선재 열간압연 제조공정을 개략적으로 도시한 도면,1 is a view schematically showing a conventional wire rod hot rolling manufacturing process,

도 2는 본 발명에 따른 냉간압조용 선재의 제조 공정을 도시한 도면,2 is a view showing a manufacturing process of a cold-rolled wire rod according to the present invention,

도 3 (가), (나)는 열간압연한 선재 조직의 현미경 사진으로 (가)는 발명강, (나)는 비교강의 사진이며,3 (a) and (b) are micrographs of the hot rolled wire structure, (a) is the invention steel, (b) is a photograph of the comparative steel,

도 4 (가), (나)는 구상화 열처리후의 선재의 현미경 조직을 나타내는 사진으로 (가)는 발명강, (나)는 비교강의 사진이다.4 (a) and (b) are photographs showing the microscopic structure of the wire rod after spheroidization heat treatment, (a) is the invention steel, and (b) is a photograph of the comparative steel.

상기 목적을 달성하기 위하여 본 발명에서는, 중량 %로, C:0.25∼0.60%, Si:0.10∼0.35%, Mn:0.30∼2.0%, P:0.030% 이하, S:0.030% 이하, Cr:1.5% 이하, Mo:0.5% 이하, Cu:0.10% 이하, Al:0.005∼0.070%, 잔부 Fe 및 기타 불가피하게 함유되는 불순물로 이루어진 강을, 선재 압연전 가열로에서 1100∼1300℃로 가열하고, 선재압연중 소재 표면 온도를 950℃ 이상으로 유지하여 오스테나이트 입자를 ASTM No.8 이하로 최대한 조대화시키고, 선재 압연된 강을 냉각 개시 온도 880-1000℃로 선택하여 냉각시 630-1000℃ 온도 영역에서는 10-25℃/초의 냉각 속도로 냉각하고 630-500℃ 온도 영역에서는 5-15℃/초의 속도로 냉각하여 냉각된 선재의 페라이트 분율을 12% 이하로 제어하여 구상화 열처리후 구상화율이 88% 이상이며 구상화 세멘타이트 입자가 균일하게 분포하도록 한 것을 특징으로 하는 구상화 열처리성이 우수한 냉각 압조용 선재의 제조 방법을 제공한다.In order to achieve the above object, in the present invention, in weight%, C: 0.25 to 0.60%, Si: 0.10 to 0.35%, Mn: 0.30 to 2.0%, P: 0.030% or less, S: 0.030% or less, Cr: 1.5 Steel consisting of% or less, Mo: 0.5% or less, Cu: 0.10% or less, Al: 0.005 to 0.070%, balance Fe and other unavoidable impurities are heated to 1100 to 1300 ° C. in a heating furnace before wire rod rolling, Maintain the material surface temperature above 950 ℃ during wire rod rolling to make the austenitic particles as coarse as possible under ASTM No.8, and select the cold rolled steel as the cooling start temperature 880-1000 ℃ to cool 630-1000 ℃ In the region, cooling is carried out at a cooling rate of 10-25 ° C./sec and cooling at a rate of 5-15 ° C./sec in a temperature range of 630-500 ° C. to control the ferrite fraction of the cooled wire to 12% or less. % Or more and spheroidized heat treatment, characterized in that the spheroidized cementite particles are uniformly distributed Provided is a method for producing a cold-rolling wire rod having excellent properties.

이하에서는 양호한 실시예와 관련하여 본 발명을 상세하게 설명한다.Hereinafter, the present invention will be described in detail with reference to the preferred embodiments.

도 2에는 냉간압조용 선재의 신선, 열처리 가공 공정이 개략적으로 도시되고 있는데, 선재로 제조한후 저온 소둔하고, 이어서 산세 및 신선과정을 거쳐 구상화 소둔화고 재차 산세하며, 스킨패드(Skin Pass)밀을 통해 제조하는 과정으로 이루어지고 있다.Figure 2 is a schematic drawing of the cold-rolled wire rod, heat treatment process is shown, after the low temperature annealing after manufacturing the wire rod, followed by pickling and drawing process, spherical annealing and pickling again, skin pad (Skin Pass) It is made through the process of manufacturing through wheat.

우선, 본 발명에 있어서 첨가원소의 성분범위, 강의 가열온도 및 압연온도, 냉각조건에 있어서의 수치 한정 등의 한정 이유에 대하여 이하에서 설명한다.First, in the present invention, the reason for limitations such as the component range of the added element, the heating temperature and rolling temperature of the steel, and the numerical limitation in the cooling conditions will be described below.

열간압연 과정중 가열로에서 빌레트 가열온도를 1100∼1300℃로 제어하여 가열된 강의 오스테나이트 입자를 조대화시켜 최종 선재 냉각시 냉각조직의 입자 미세화 영향을 최소화 하였다.During the hot rolling process, by controlling the billet heating temperature to 1100 ~ 1300 ℃ in the furnace, the austenitic particles of the heated steel were coarsened to minimize the effect of particle refinement of the cooling structure during final wire cooling.

또한, 선재압연중 압연되는 소재의 온도는 950℃ 이상 유지하여 압연중 강빌레트(Billet)의 재결정과 오스테나이트 입자를 조대화시켜 선재 냉각시 선재의 냉각조직 입자를 미세화시키는 영향을 최소화시켰다.In addition, the temperature of the material to be rolled during the wire rod is maintained at 950 ℃ or more to minimize the recrystallization of the steel billet (Billet) and coarse austenite particles during the rolling to minimize the effect of refining the cooling structure particles of the wire rod during cooling of the wire rod.

압연후 선재 냉각시 냉각개시온도(권취온도)는 880℃∼1000℃ 범위로 유지하고, 선재 냉각시 퍼얼라이트 변태전 온도영역(630℃∼1000℃)은 15∼25℃/초의 냉각속도로 냉각하고, 퍼얼라이트의 온도 영역(630∼550℃)에서는 강의 변태 온도 구역은 5∼15℃/초의 냉각속도로 냉각하였는데, 이러한 냉각 속도의 수치 한정 이유는 다음과 같다.The cooling start temperature (winding temperature) during wire rod cooling after rolling is maintained in the range of 880 ℃ ~ 1000 ℃, and the temperature range (630 ℃ ~ 1000 ℃) before perlite transformation during wire rod cooling is cooled at 15 ~ 25 ℃ / sec. In the temperature range (630 to 550 ° C.) of the pearlite, the transformation temperature zone of the steel was cooled at a cooling rate of 5 to 15 ° C./sec.

선재 냉각 개시 온도를 880∼1000℃ 범위로 유지하여 고온에서 오스테나이트 입자의 성장을 용이하게 한다. 이는 오스테나이트 입자 조대화로 선재 냉각중 페라이트의 핵생성 자리수를 최소화시켜 주는 역할을 한다.The wire cooling start temperature is maintained in the range of 880 to 1000 캜 to facilitate the growth of austenite particles at high temperatures. This serves to minimize the nucleation sites of ferrite during wire rod cooling by coarsening austenite particles.

또한, 강의 퍼얼라이트 변태 온도 이상 온도 영역(630∼1000℃) 즉, 페라이트가 성장하는 온도영역에서는 15∼25℃/초의 냉각속도 범위로 급냉하고, 500℃∼630℃의 퍼얼라이트 변태온도 영역에서 구상화가 용이한 미세 퍼얼라이트 조직을 확보하기 위해서 5∼15℃/초의 냉각속도를 적용한다. 이 방법에 의하면, 궁극적으로 페라이트 분율을 최소화시키고 퍼얼라이트 분율의 최대화가 가능케하여 균일한 구상화 조직 즉, 구상화 입자의 균일한 분포를 가능하게 하여, 우수한 구상화 열처리 조직을 얻을 수 있다.In addition, in the temperature range where the ferrite is at or above the temperature range (630 to 1000 ° C.), that is, the temperature range where the ferrite grows, it is quenched at a cooling rate of 15 to 25 ° C./sec. A cooling rate of 5 to 15 ° C./sec is applied to secure a fine pearlite structure that is easily spheroidized. According to this method, it is possible to ultimately minimize the ferrite fraction and maximize the perlite fraction to enable a uniform spherical structure, that is, a uniform distribution of the spherical particles, thereby obtaining an excellent spheroidized heat treatment structure.

이하에서는 냉각 속도 설정 사유를 설명한다.The reason for setting the cooling rate will be described below.

냉각속도 설정 사유는 변태전 온도영역에서 25℃/초 이상으로 냉각시 후공정의 신선이 불가능한 베이나이트 또는 마르텐사이트 경조직이 발생하기 때문이며, 변태온도 영역에서 5℃/초 이하로 선재냉각시 퍼얼라이트 조직내 시멘타이트 두께가 과도하게 두꺼워져 구상화처리 시간 연장 및 구상화 입자 조대화를 초래하여 구상화 열처리성(조직)을 해치게 되며, 15℃/초 이상의 냉각 속도 이상에서는 앞에서 언급한 경조직이 발생하여 후 공정에서 신선가공이 불가능하게 되기 때문이다.The reason for setting the cooling rate is that the bainite or martensite hard structure, which cannot be drawn in the post-process, occurs when cooling to more than 25 ℃ / sec in the temperature range before transformation, and when the wire is cooled to 5 ℃ / sec or less in the transformation temperature range, The thickness of cementite in the tissue becomes excessively thick, which leads to prolongation of spheroidization treatment time and coarsening of the spheroidizing particles, thereby deteriorating the spheroidization heat treatment property (tissue). This is because fresh processing becomes impossible.

이하 실시예를 통하여 본 발명을 보다 구체적으로 설명한다.The present invention will be described in more detail with reference to the following Examples.

(실시예)(Example)

하기 표 1과 같은 조성을 갖는 발명강과 비교강을 단면부 치수가 160㎜ × 160㎜ 강편으로 제작한 후 표 2와 같은 조건으로 강을 가열후 선재압연을 실시하였다. 표 3에는 선재압연이 완료된 상태에서의 발명강과 비교강의 조직 및 기계적 성질을 나타내고 있는데, 도 3 (가), (나) 및 도 4 (가), (나)는 발명강과 비교강의 현미경 조직을 나타낸 사진이다. 이로부터 알 수 있는 바와 같이, 발명강에 의하면, 페라이트 분율이 낮아 구상화열처리성이 개선됨을 알 수 있으며, 기계적 성질도 향상됨을 알 수 있다.Inventive steel and comparative steel having a composition as shown in Table 1 below were made into 160 mm × 160 mm steel sections with cross-sectional dimensions, and then wires were rolled after heating the steel under the conditions shown in Table 2. Table 3 shows the structure and mechanical properties of the inventive steel and the comparative steel in the state that the wire rod is completed, Figure 3 (a), (b) and 4 (a), (b) shows the microscopic structure of the invention steel and the comparative steel It is a photograph. As can be seen from this, according to the invention steel, it can be seen that the ferrite fraction is low, and the spheroidization heat treatment property is improved, and the mechanical properties are also improved.

[표 1](%)Table 1 (%)

[표 2]TABLE 2

[표 3]TABLE 3

따라서, 상기 설명한 바와 같이, 본 발명의 구상화 열처리성이 우수한 냉각압조용 선재의 제조 방법에 의하면, 인성(냉간압조성)이 향상되며, 구상화 열처리성이 향상된 선재가 얻어지므로 제품의 품질의 향상을 도모할 수 있는 등 유용한 효과가 얻어진다.Therefore, as described above, according to the method for producing a cold-rolled wire rod having excellent spheroidizing heat treatment property of the present invention, the toughness (cold-pressure composition) is improved, and a wire rod having improved spheroidizing heat treatment property is obtained, thereby improving the product quality. Useful effects can be obtained.

Claims (1)

중량 %로, C:0.25∼0.60%, Si:0.10∼0.35%, Mn:0.30∼2.0%, P:0.030% 이하, S:0.030% 이하, Cr:1.5% 이하, Mo:0.5% 이하, Cu:0.10% 이하, Al:0.005∼0.070%, 잔부 Fe 및 기타 불가피하게 함유되는 불순물로 이루어진 강을, 선재 압연전 가열로에서 1100∼1300℃로 가열하고, 선재압연중 소재 표면 온도를 950℃ 이상으로 유지하여 오스테나이트 입자를 ASTM No.8 이하로 최대한 조대화시키고, 선재 압연된 강을 냉각 개시 온도 880-1000℃로 선택하여 냉각시 630-1000℃ 온도 영역에서는 10-25℃/초의 냉각 속도로 냉각하고 630-500℃ 온도 영역에서는 5-15℃/초의 속도로 냉각하여 냉각된 선재의 페라이트 분율을 12% 이하로 제어하여 구상화 열처리후 구상화율이 88% 이상이며 구상화 세멘타이트 입자가 균일하게 분포하도록 한 것을 특징으로 하는 구상화 열처리성이 우수한 냉간 압조용 선재의 제조 방법.By weight%, C: 0.25 to 0.60%, Si: 0.10 to 0.35%, Mn: 0.30 to 2.0%, P: 0.030% or less, S: 0.030% or less, Cr: 1.5% or less, Mo: 0.5% or less, Cu : 0.10% or less, Al: 0.005 to 0.070%, remainder Fe and other unavoidable impurity steels are heated to 1100 to 1300 ° C in a heating furnace before wire rolling, and the material surface temperature during wire rolling is 950 ° C or more. Austenitic particles are coarsened to ASTM No. 8 or less as much as possible, and the wire-rolled steel is selected at a cooling start temperature of 880-1000 ° C., and a cooling rate of 10-25 ° C./sec in the 630-1000 ° C. temperature range during cooling is maintained. The ferrite fraction of the cooled wire rod is controlled to 12% or less by cooling at a rate of 5-15 ℃ / sec in the temperature range of 630-500 ℃, and the spheroidization rate is 88% or more after spheroidization heat treatment, and the spheroidized cementite particles are uniformly A method for producing a cold-rolled wire rod having excellent spheroidization heat treatment properties, characterized in that it is distributed.
KR1019960071445A 1996-12-24 1996-12-24 Method for manufacturing cold-rolled wire rod with excellent spheroidizing heat treatment Expired - Fee Related KR100268852B1 (en)

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KR100469671B1 (en) * 2002-07-11 2005-02-02 삼화강봉주식회사 Quenched and tempered steel wire with superior characteristics of cold forging
KR100530065B1 (en) * 2001-12-13 2005-11-22 주식회사 포스코 A method for manufacturing steel wire rod for cold forging featuring short-time spheroidized annealing
KR100588758B1 (en) * 2004-02-23 2006-06-14 현대자동차주식회사 Automobile kickdown drum material and manufacturing method thereof
KR100627454B1 (en) * 1999-12-27 2006-09-22 주식회사 포스코 Manufacturing method of medium carbon steel wire with excellent spheroidizing heat treatment

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KR100415664B1 (en) * 1999-12-09 2004-01-31 주식회사 포스코 A method for manufacturing wire rod for bolt with superior spheroidizing heat treatment property
KR101277977B1 (en) 2009-10-07 2013-06-27 주식회사 포스코 Free-cutting steel wire rod and method for manufacturing the same

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JPS61153230A (en) * 1984-12-26 1986-07-11 Kawasaki Steel Corp Production of low-alloy steel wire rod which permits quick spheroidization

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KR100627454B1 (en) * 1999-12-27 2006-09-22 주식회사 포스코 Manufacturing method of medium carbon steel wire with excellent spheroidizing heat treatment
KR100530065B1 (en) * 2001-12-13 2005-11-22 주식회사 포스코 A method for manufacturing steel wire rod for cold forging featuring short-time spheroidized annealing
KR100469671B1 (en) * 2002-07-11 2005-02-02 삼화강봉주식회사 Quenched and tempered steel wire with superior characteristics of cold forging
KR100588758B1 (en) * 2004-02-23 2006-06-14 현대자동차주식회사 Automobile kickdown drum material and manufacturing method thereof

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