KR102862626B1 - Functional detergent composition having color retention functionality, anti-staining functionality and anti-color transfer functionality based on imidazole - Google Patents
Functional detergent composition having color retention functionality, anti-staining functionality and anti-color transfer functionality based on imidazoleInfo
- Publication number
- KR102862626B1 KR102862626B1 KR1020240181347A KR20240181347A KR102862626B1 KR 102862626 B1 KR102862626 B1 KR 102862626B1 KR 1020240181347 A KR1020240181347 A KR 1020240181347A KR 20240181347 A KR20240181347 A KR 20240181347A KR 102862626 B1 KR102862626 B1 KR 102862626B1
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- parts
- detergent composition
- functionality
- imidazole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
본 발명은 이미다졸기를 가지는 화합물을 포함하는 기능성 세제 조성물을 제공한다. 본 발명에 따른 기능성 세제 조성물은 컬러유지 기능성, 착색방지 기능성 및 이염방지 기능성을 가진다. 또한, 의류 손상방지, 섬유복원 기능성을 가진다.The present invention provides a functional detergent composition comprising a compound having an imidazole group. The functional detergent composition according to the present invention has color retention, anti-staining, and anti-color transfer functions. It also has clothing damage prevention and fiber restoration functions.
Description
본 발명은 이미다졸을 바탕으로 한 컬러유지 기능성, 착색방지 기능성 및 이염방지 기능성을 가지는 기능성 세제 조성물에 관한 것이다.The present invention relates to a functional detergent composition having color retention functionality, anti-staining functionality, and anti-color transfer functionality based on imidazole.
일반적으로 각종 의류에 묻은 얼룩이나 땀 기름때 등으로 오염된 세탁물을 세탁하기 위하여 세제를 사용하게 된다. 이와 같은 얼룩이나, 또는 땀 기름때 등과 같은 오염물질을 제거하기 위하여 세정력이 강한 세제들이 개발됨에 따라 세탁 후 탈색 현상이 빈번하게 발생하는 문제가 있었다.Detergents are typically used to wash clothing contaminated with stains, sweat, or grease. As detergents with strong cleaning power were developed to remove these stains and other contaminants, discoloration frequently occurred after washing.
또한, 세정력 향상이나 안정성 향상 등을 목적으로 하여, 촉감 향상제, 유연성 부여제, 모노에탄올아민, 디에탄올아민, 트리에탄올아민, N-메틸-디에탄올아민, N,N-디메틸모노에탄올아민 등의 알칸올아민 등의 알칼리 빌더, pH 조정제, 하이드로트로프제, 형광제, 효소, 이염(移染) 방지제, 상기 (D)성분에 해당하지 않는 재오염 방지제(예를 들면 폴리비닐피롤리돈, 카르복시메틸셀룰로오스 등), 진주제, 소일 릴리스제 등을 포함할 수 있다.In addition, for the purpose of improving cleaning power or stability, it may include a tactile improver, a flexibility imparting agent, an alkaline builder such as an alkanolamine such as monoethanolamine, diethanolamine, triethanolamine, N-methyl-diethanolamine, N,N-dimethylmonoethanolamine, a pH adjuster, a hydrotrope agent, a fluorescent agent, an enzyme, a dye transfer inhibitor, an anti-recontamination agent that does not correspond to the above (D) component (e.g., polyvinylpyrrolidone, carboxymethylcellulose, etc.), a pearlizing agent, a soil release agent, etc.
종래의 세제는 카복시메틸셀룰로오즈(CMC)와 폴리비닐피로리돈(PVP)를 주로 사용하여 재오염 부착 방지 기능과 동시에 이염 방지 기능을 부여하였다. 특히, 폴리비닐피로리돈(PVP)는 전 세계적으로 널리 사용되는 이염 방지 기능을 부여하는 물질로 저온보다는 고온에서 우수한 효과를 나타내는 것으로 알려져 있다. 이들의 이염 방지 메커니즘은 폴리머에 의해 염료와의 친화성을 높임으로써 염료가 다른 섬유에 염착되는 것보다 폴리머에 의해 싸여짐으로 인해서 염료를 섬유와 분리시키는 작용으로 이염을 방지하는 기능을 한다.Conventional detergents primarily use carboxymethylcellulose (CMC) and polyvinylpyrrolidone (PVP) to provide both anti-recontamination and anti-migration properties. In particular, polyvinylpyrrolidone (PVP) is a widely used anti-migration agent worldwide, known to be more effective at high temperatures than at low temperatures. Its anti-migration mechanism works by increasing affinity between the polymer and the dye, thereby preventing color transfer by encapsulating the dye within the polymer rather than allowing it to adhere to other fibers.
그러나, 국내의 세탁 조건은 대부분이 상온에서 세탁을 행하게 되어 여름철에는 섭씨 20 내지 25 ℃, 겨울철에는 실내 온도가 심지어 5 ℃ 정도의 찬물에서 세탁이 행하여지기도 한다. 때문에, 이러한 조건에서도 이염 방지 기능을 할 수 있는 성분이 요구된다.However, domestic laundry conditions generally require washing at room temperature. In summer, washing is performed in water at temperatures ranging from 20 to 25°C, and in winter, washing is performed in cold water at temperatures as low as 5°C. Therefore, ingredients that can prevent color transfer are required even under these conditions.
본 발명의 목적은 컬러유지 기능성, 착색방지 기능성 및 이염방지 기능성을 가지는 기능성 세제 조성물을 제공하는 것이다.The purpose of the present invention is to provide a functional detergent composition having color retention functionality, anti-staining functionality, and anti-color transfer functionality.
본 발명의 다른 목적은 의류 손상방지, 섬유복원, 컬러유지 기능성, 착색방지 기능성 및 이염방지 기능성을 가지는 기능성 세제 조성물을 제공하는 것이다.Another object of the present invention is to provide a functional detergent composition having clothing damage prevention, fiber restoration, color retention, stain prevention, and color transfer prevention functions.
본 발명의 과제는 이상에서 언급한 과제들로 제한되지 않으며, 언급되지 않은 또 다른 과제들은 아래의 기재로부터 당업자에게 명확하게 이해될 수 있을 것이다.The tasks of the present invention are not limited to the tasks mentioned above, and other tasks not mentioned will be clearly understood by those skilled in the art from the description below.
상기 목적을 달성하기 위하여 본 발명은In order to achieve the above purpose, the present invention
이미다졸기를 가지는 화합물을 포함하는 기능성 세제 조성물을 제공한다.A functional detergent composition comprising a compound having an imidazole group is provided.
또한, 상기 이미다졸기를 가지는 화합물은 1-메틸이미다졸(1-Methylimidazole), 2-메틸이미다졸(2-Methylimidazole), 1-에틸-1H-이미다졸(1-Ethyl-1H-imidazole), 2-에틸이미다졸(2-Ethylimidazole), 1-부틸이미다졸(1-Butylimidazole) 및 에틸 1H-이미다졸-1-카르복실레이트(Ethyl 1H-imidazole-1-carboxylate)로 이루어지는 군으로부터 선택되는 1종 이상인 것을 특징으로 한다.In addition, the compound having the imidazole group is characterized in that it is at least one selected from the group consisting of 1-methylimidazole, 2-methylimidazole, 1-ethyl-1H-imidazole, 2-ethylimidazole, 1-butylimidazole, and ethyl 1H-imidazole-1-carboxylate.
또한, 상기 기능성 세제 조성물은 이미다졸기를 가지는 화합물, 황련뿌리추출물, 데실글루코사이드, 코코베타인, C12-14Sec-파레스-7, 티이에이-올리에이트, 셀룰라아제, 프로테아제, 만나아제, 아밀라아제, 글리세린, 1,3-부틸렌글리콜, 에탄올 및 정제수를 포함한다.In addition, the functional detergent composition includes a compound having an imidazole group, Coptis chinensis root extract, decyl glucoside, cocobetaine, C12-14Sec-pareth-7, TEA-oleate, cellulase, protease, mannanase, amylase, glycerin, 1,3-butylene glycol, ethanol, and purified water.
또한, 상기 기능성 세제 조성물은 이미다졸기를 가지는 화합물 1-5 중량부, 황련뿌리추출물 1-5 중량부, 데실글루코사이드 2-6 중량부, 코코베타인 2-6 중량부, C12-14Sec-파레스-7 1-5 중량부, 티이에이-올리에이트 1-5 중량부, 셀룰라아제 2-6 중량부, 프로테아제 2-6 중량부, 만나아제 2-6 중량부, 아밀라아제 2-6 중량부, 글리세린 1-5 중량부, 1,3-부틸렌글리콜 0.8-1.2 중량부, 에탄올 8-12 중량부 및 정제수 48-52 중량부를 포함한다.In addition, the functional detergent composition comprises 1-5 parts by weight of a compound having an imidazole group, 1-5 parts by weight of Coptis chinensis root extract, 2-6 parts by weight of decyl glucoside, 2-6 parts by weight of cocobetaine, 1-5 parts by weight of C12-14Sec-pareth-7, 1-5 parts by weight of TEA-oleate, 2-6 parts by weight of cellulase, 2-6 parts by weight of protease, 2-6 parts by weight of mannanase, 2-6 parts by weight of amylase, 1-5 parts by weight of glycerin, 0.8-1.2 parts by weight of 1,3-butylene glycol, 8-12 parts by weight of ethanol, and 48-52 parts by weight of purified water.
또한, 상기 이미다졸기를 가지는 화합물은 에틸 1H-이미다졸-1-카르복실레이트(Ethyl 1H-imidazole-1-carboxylate)인 것을 특징으로 한다.In addition, the compound having the above imidazole group is characterized as being ethyl 1H-imidazole-1-carboxylate.
또한, 상기 기능성 세제 조성물은 첨가제 1-5 중량부를 더 포함하고,In addition, the functional detergent composition further comprises 1-5 parts by weight of an additive,
상기 첨가제는 메틸메타크릴레이트 단량체 단위 23-27 중량부, 메타크릴산 단량체 단위 23-27 중량부, 1H,1H,2H,2H-퍼플루오로데실아크릴레이트(1H,1H,2H,2H-Perfluorodecyl acrylate) 단량체 단위 23-27 중량부 및 2-(1H-이미다졸-1-카르복사미도)에틸 메타크릴레이트(2-(1H-imidazole-1-carboxamido)ethyl methacrylate) 단량체 단위 23-27 중량부를 포함하는 아크릴계 공중합체인 것을 특징으로 한다.The above additive is characterized in that it is an acrylic copolymer containing 23-27 parts by weight of a methyl methacrylate monomer unit, 23-27 parts by weight of a methacrylic acid monomer unit, 23-27 parts by weight of a 1H,1H,2H,2H-perfluorodecyl acrylate monomer unit, and 23-27 parts by weight of a 2-(1H-imidazole-1-carboxamido)ethyl methacrylate monomer unit.
또한, 본 발명은In addition, the present invention
이미다졸기를 가지는 화합물 1-5 중량부, 첨가제 1-5 중량부, 황련뿌리추출물 1-5 중량부, 데실글루코사이드 2-6 중량부, 코코베타인 2-6 중량부, C12-14Sec-파레스-7 1-5 중량부, 티이에이-올리에이트 1-5 중량부, 셀룰라아제 2-6 중량부, 프로테아제 2-6 중량부, 만나아제 2-6 중량부, 아밀라아제 2-6 중량부, 글리세린 1-5 중량부, 1,3-부틸렌글리콜 0.8-1.2 중량부, 에탄올 8-12 중량부 및 정제수 48-52 중량부를 혼합하는 단계를 포함하고,A step of mixing 1-5 parts by weight of a compound having an imidazole group, 1-5 parts by weight of an additive, 1-5 parts by weight of a Coptis chinensis root extract, 2-6 parts by weight of decyl glucoside, 2-6 parts by weight of cocobetaine, 1-5 parts by weight of C12-14Sec-pareth-7, 1-5 parts by weight of TEA-oleate, 2-6 parts by weight of cellulase, 2-6 parts by weight of protease, 2-6 parts by weight of mannanase, 2-6 parts by weight of amylase, 1-5 parts by weight of glycerin, 0.8-1.2 parts by weight of 1,3-butylene glycol, 8-12 parts by weight of ethanol, and 48-52 parts by weight of purified water,
상기 이미다졸기를 가지는 화합물은 에틸 1H-이미다졸-1-카르복실레이트(Ethyl 1H-imidazole-1-carboxylate)이고,The compound having the above imidazole group is ethyl 1H-imidazole-1-carboxylate,
상기 첨가제는 메틸메타크릴레이트 단량체 단위 23-27 중량부, 메타크릴산 단량체 단위 23-27 중량부, 1H,1H,2H,2H-퍼플루오로데실아크릴레이트(1H,1H,2H,2H-Perfluorodecyl acrylate) 단량체 단위 23-27 중량부 및 2-(1H-이미다졸-1-카르복사미도)에틸 메타크릴레이트(2-(1H-imidazole-1-carboxamido)ethyl methacrylate) 단량체 단위 23-27 중량부를 포함하는 아크릴계 공중합체인 것을 특징으로 하는 기능성 세제 조성물의 제조방법을 제공한다.The above additive provides a method for producing a functional detergent composition, characterized in that it is an acrylic copolymer containing 23-27 parts by weight of a methyl methacrylate monomer unit, 23-27 parts by weight of a methacrylic acid monomer unit, 23-27 parts by weight of a 1H,1H,2H,2H-perfluorodecyl acrylate monomer unit, and 23-27 parts by weight of a 2-(1H-imidazole-1-carboxamido)ethyl methacrylate monomer unit.
본 발명에 따른 기능성 세제 조성물은 컬러유지 기능성, 착색방지 기능성 및 이염방지 기능성을 가진다. 또한, 의류 손상방지, 섬유복원 기능성을 가진다.The functional detergent composition according to the present invention has color retention, anti-staining, and anti-color transfer functions. It also has clothing damage prevention and fiber restoration functions.
이하에서는 다양한 실시예를 보다 상세하게 설명한다. 본 명세서에 기재된 실시예는 다양하게 변형될 수 있다. 특정한 실시예가 상세한 설명에서 자세하게 설명될 수 있다. 그러나 개시된 특정한 실시 예는 다양한 실시예를 쉽게 이해하도록 하기 위한 것일 뿐이다. 따라서 개시된 특정 실시예에 의해 기술적 사상이 제한되는 것은 아니며, 발명의 사상 및 기술 범위에 포함되는 모든 균등물 또는 대체물을 포함하는 것으로 이해되어야 한다.Below, various embodiments are described in more detail. The embodiments described herein are susceptible to various modifications. While specific embodiments may be described in detail in the detailed description, the disclosed specific embodiments are intended solely to facilitate understanding of various embodiments. Therefore, the disclosed specific embodiments are not intended to limit the technical scope of the invention, and should be understood to encompass all equivalents or alternatives falling within the spirit and technical scope of the invention.
1차, 2차, 제1, 제2 등과 같이 서수를 포함하는 용어는 다양한 구성요소들을 설명하는데 사용될 수 있지만, 이러한 구성요소들은 상술한 용어에 의해 한정되지는 않는다. 상술한 용어는 하나의 구성요소를 다른 구성요소로부터 구별하는 목적으로만 사용된다.Terms that include ordinal numbers, such as primary, secondary, first, second, etc., may be used to describe various components, but these components are not limited by the aforementioned terms. The aforementioned terms are used solely to distinguish one component from another.
본 명세서에서, '포함한다' 또는 '가지다' 등의 용어는 명세서상에 기재된 특징, 숫자, 단계, 동작, 구성요소, 부품 또는 이들을 조합한 것이 존재함을 지정하려는 것이지, 하나 또는 그 이상의 다른 특징들이나 숫자, 단계, 동작, 구성요소, 부품 또는 이들을 조합한 것들의 존재 또는 부가 가능성을 미리 배제하지 않는 것으로 이해되어야 한다. 어떤 구성요소가 다른 구성요소에 '연결되어' 있다거나 '접속되어' 있다고 언급된 때에는, 그 다른 구성요소에 직접적으로 연결되어 있거나 또는 접속되어 있을 수도 있지만, 중간에 다른 구성요소가 존재할 수도 있다고 이해되어야 할 것이다. 반면에, 어떤 구성요소가 다른 구성요소에 '직접 연결되어' 있다거나 '직접 접속되어' 있다고 언급된 때에는, 중간에 다른 구성요소가 존재하지 않는 것으로 이해되어야 할 것이다.In this specification, terms such as "include" or "have" are intended to specify the presence of a feature, number, step, operation, component, part, or combination thereof described in the specification, but should be understood as not excluding in advance the possibility of the presence or addition of one or more other features, numbers, steps, operations, components, parts, or combinations thereof. When a component is referred to as being "connected" or "connected" to another component, it should be understood that it may be directly connected or connected to the other component, but that other components may also exist in between. On the other hand, when a component is referred to as being "directly connected" or "directly connected" to another component, it should be understood that no other components exist in between.
그 밖에도, 본 발명을 설명함에 있어서, 관련된 공지 기능 혹은 구성에 대한 구체적인 설명이 본 발명의 요지를 불필요하게 흐릴 수 있다고 판단되는 경우, 그에 대한 상세한 설명은 축약하거나 생략한다.In addition, when describing the present invention, if it is determined that a detailed description of a related known function or configuration may unnecessarily obscure the gist of the present invention, the detailed description thereof is abbreviated or omitted.
본 발명은The present invention
이미다졸기를 가지는 화합물을 포함하는 기능성 세제 조성물을 제공한다.A functional detergent composition comprising a compound having an imidazole group is provided.
이하, 본 발명에 따른 기능성 세제 조성물에 대하여 상세히 설명한다.Hereinafter, the functional detergent composition according to the present invention will be described in detail.
상기 기능성 세제 조성물은 이미다졸기를 가지는 화합물을 포함하며, 이미다졸기를 가지는 화합물은 수용액에서 유리된 각종 활성 염료의 이온과 먼지, 진드기, 부유물 등을 흡착하여 옷감의 컬러 이동을 막아 상호 착색을 방지한다.The above functional detergent composition includes a compound having an imidazole group, and the compound having an imidazole group adsorbs ions of various active dyes released from an aqueous solution and dust, mites, floating substances, etc., thereby preventing color transfer of fabrics and preventing cross-coloring.
상기 이미다졸기를 가지는 화합물은 1-메틸이미다졸(1-Methylimidazole), 2-메틸이미다졸(2-Methylimidazole), 1-에틸-1H-이미다졸(1-Ethyl-1H-imidazole), 2-에틸이미다졸(2-Ethylimidazole), 1-부틸이미다졸(1-Butylimidazole) 및 에틸 1H-이미다졸-1-카르복실레이트(Ethyl 1H-imidazole-1-carboxylate) 등을 사용할 수 있고, 바람직하게는 에틸 1H-이미다졸-1-카르복실레이트(Ethyl 1H-imidazole-1-carboxylate)를 사용한다.Compounds having the above imidazole group include 1-methylimidazole, 2-methylimidazole, 1-ethyl-1H-imidazole, 2-ethylimidazole, 1-butylimidazole, and ethyl 1H-imidazole-1-carboxylate, and preferably ethyl 1H-imidazole-1-carboxylate.
상기 기능성 세제 조성물은 이미다졸기를 가지는 화합물, 황련뿌리추출물, 데실글루코사이드, 코코베타인, C12-14Sec-파레스-7, 티이에이-올리에이트, 셀룰라아제, 프로테아제, 만나아제, 아밀라아제, 글리세린, 1,3-부틸렌글리콜, 에탄올 및 정제수를 포함하는 것이 바람직하고, 이미다졸기를 가지는 화합물 1-5 중량부, 황련뿌리추출물 1-5 중량부, 데실글루코사이드 2-6 중량부, 코코베타인 2-6 중량부, C12-14Sec-파레스-7 1-5 중량부, 티이에이-올리에이트 1-5 중량부, 셀룰라아제 2-6 중량부, 프로테아제 2-6 중량부, 만나아제 2-6 중량부, 아밀라아제 2-6 중량부, 글리세린 1-5 중량부, 1,3-부틸렌글리콜 0.8-1.2 중량부, 에탄올 8-12 중량부 및 정제수 48-52 중량부를 포함하는 것이 더욱 바람직하다.The functional detergent composition preferably comprises a compound having an imidazole group, a Coptis chinensis root extract, decyl glucoside, cocobetaine, C12-14Sec-pareth-7, TEA-oleate, cellulase, protease, mannanase, amylase, glycerin, 1,3-butylene glycol, ethanol and purified water, and comprises 1-5 parts by weight of a compound having an imidazole group, 1-5 parts by weight of a Coptis chinensis root extract, 2-6 parts by weight of decyl glucoside, 2-6 parts by weight of cocobetaine, 1-5 parts by weight of C12-14Sec-pareth-7, 1-5 parts by weight of TEA-oleate, 2-6 parts by weight of cellulase, 2-6 parts by weight of protease, 2-6 parts by weight of mannanase, 2-6 parts by weight of amylase, 1-5 parts by weight of glycerin, and 1,3-butylene glycol. It is more preferable to include 0.8-1.2 parts by weight of ethanol, 8-12 parts by weight of purified water and 48-52 parts by weight of purified water.
상기 기능성 세제 조성물은 황련뿌리추출물을 포함하며, 황련뿌리추출물은 천연추출물로 피부 자극성을 줄여 유아용 세탁물에 사용 가능한 천연 세제로 사용가능하도록 도와주며, 세척력을 상승시키는 효과 및 세제의 보존기간을 증가시키는 안정성을 향상시키는 효과를 나타낸다.The above functional detergent composition includes a Coptis chinensis root extract, and the Coptis chinensis root extract is a natural extract that helps reduce skin irritation and can be used as a natural detergent for baby laundry, and exhibits an effect of increasing cleaning power and an effect of improving stability that increases the shelf life of the detergent.
상기 기능성 세제 조성물은 데실글루코사이드를 포함하며, 데실글루코사이드는 옥수수, 코코넛 및 팜커넬 오일에서 유래된 식물성 계면활성제 성분으로, 순하고 비이온성이며, 미생물에 의해 생분해되어 친환경적인 특징과 함께, 조밀한 거품을 형성하는 효과가 있다. The above functional detergent composition contains decyl glucoside, which is a plant-based surfactant derived from corn, coconut, and palm kernel oils. It is mild, nonionic, biodegradable by microorganisms, and has the effect of forming dense foam along with environmentally friendly characteristics.
상기 기능성 세제 조성물은 코코베타인을 포함하며, 코코베타인은 코코넛 오일을 합성해서 만든 식물성 계면활성제로, 거품을 형성하고, 피부 자극이 없는 순한 성질을 가지고 있으며, 다른 원료들과 결합하여도 점도가 떨어지지 않아 다양한 성분들과 조합이 용이할 뿐 아니라, 항균력 및 정전기 방지효과도 있다The above functional detergent composition contains cocobetaine, which is a plant-based surfactant synthesized from coconut oil. It forms foam and has mild properties that do not irritate the skin. Its viscosity does not decrease when combined with other raw materials, making it easy to combine with various ingredients. It also has antibacterial and antistatic effects.
상기 기능성 세제 조성물은 C12-14Sec-파레스-7을 포함하며, C12-14Sec-파레스-7는 에틸렌옥사이드가 평균 7몰인 C12-14 합성 2급지방알코올 혼합물의 폴리에틸렌글라이콜에터이다. The above functional detergent composition comprises C12-14Sec-pareth-7, which is a polyethylene glycol ether of a C12-14 synthetic secondary fatty alcohol mixture having an average of 7 moles of ethylene oxide.
상기 기능성 세제 조성물은 티이에이-올리에이트를 포함하며, 티이에이-올리에이트는 유화, 분산의 기능을 하며 거품의 발생이 적고 효소의 활성에 영향을 주지 않으며 강력한 계면활성을 나타내며 천연 성분이므로 독성이 없다. 특히 유성오염의 제거효과가 크며 표면장력의 저하능력이 크다.The above functional detergent composition contains TEA-oleate, which has emulsifying and dispersing functions, produces little foam, does not affect enzyme activity, exhibits strong surface activity, and is non-toxic as it is a natural ingredient. In particular, it is highly effective in removing oily contaminants and has a strong ability to reduce surface tension.
상기 기능성 세제 조성물은 셀룰라아제를 포함하며, 셀룰라아제는 셀룰로오스를 분해할 수 있는 능력 때문에 면 섬유의 유연제로서 사용될 수 있고, 면 섬유의 표면으로부터 돌출되어 서로 간에 자유롭게 미끄러지는 것을 방지하는, 이른바 피브릴이라고 하는 미세섬유 셀룰로오스를 우선적으로 가수분해시키고 제거하는 것으로 알려져 있다. 또한, 이러한 피브릴 분해의 부차 효과는 시각적 발색 효과를 강화시키는 것이다.The functional detergent composition comprises cellulase, which can be used as a softener for cotton fibers due to its ability to decompose cellulose. Cellulase is known to preferentially hydrolyze and remove microfibers of cellulose, called fibrils, that protrude from the surface of cotton fibers and prevent them from sliding freely against each other. Furthermore, a secondary effect of this fibril decomposition is to enhance the visual color development effect.
상기 기능성 세제 조성물은 프로테아제, 만나아제, 아밀라아제를 포함하며, 프로테아제, 만나아제, 아밀라아제는 단백질 제거를 돕고 지방분해에도 효과적이며, 전분 다당류의 촉매적 가수분해를 통해 전분-함유 오염물의 제거를 촉진시키는 기능을 가진다.The above functional detergent composition comprises protease, mannanase, and amylase, and the protease, mannanase, and amylase help remove proteins and are also effective in decomposing fat, and have the function of promoting the removal of starch-containing contaminants through catalytic hydrolysis of starch polysaccharides.
상기 기능성 세제 조성물은 글리세린을 포함하며, 글리세린은 함유된 하이드록실기가 세제의 점성을 상승시켜 세정효과를 높여주는 것으로, 적은 양으로도 오염제거능이 뛰어나고, 피부자극성이 적으며 생분해도를 더욱 향상시킬 수 있다.The above functional detergent composition contains glycerin, and the hydroxyl group contained in glycerin increases the viscosity of the detergent, thereby enhancing the cleaning effect. Therefore, even in a small amount, it has excellent contamination removal ability, causes less skin irritation, and can further enhance biodegradability.
또한, 상기 기능성 세제 조성물은 첨가제 1-5 중량부를 더 포함하는 것이 더욱 바람직하다.In addition, it is more preferable that the functional detergent composition further includes 1 to 5 parts by weight of an additive.
상기 첨가제는 메틸메타크릴레이트 단량체 단위 23-27 중량부, 메타크릴산 단량체 단위 23-27 중량부, 1H,1H,2H,2H-퍼플루오로데실아크릴레이트(1H,1H,2H,2H-Perfluorodecyl acrylate) 단량체 단위 23-27 중량부 및 2-(1H-이미다졸-1-카르복사미도)에틸 메타크릴레이트(2-(1H-imidazole-1-carboxamido)ethyl methacrylate) 단량체 단위 23-27 중량부를 포함하는 아크릴계 공중합체이다.The above additive is an acrylic copolymer containing 23-27 parts by weight of a methyl methacrylate monomer unit, 23-27 parts by weight of a methacrylic acid monomer unit, 23-27 parts by weight of a 1H,1H,2H,2H-perfluorodecyl acrylate monomer unit, and 23-27 parts by weight of a 2-(1H-imidazole-1-carboxamido)ethyl methacrylate monomer unit.
상기 아크릴계 공중합체를 첨가제로 적용함으로써 더욱 우수한 세척력과 더불어 기능성을 확보할 수 있다.By applying the above acrylic copolymer as an additive, functionality can be secured along with superior cleaning power.
또한, 본 발명은In addition, the present invention
이미다졸기를 가지는 화합물 1-5 중량부, 첨가제 1-5 중량부, 황련뿌리추출물 1-5 중량부, 데실글루코사이드 2-6 중량부, 코코베타인 2-6 중량부, C12-14Sec-파레스-7 1-5 중량부, 티이에이-올리에이트 1-5 중량부, 셀룰라아제 2-6 중량부, 프로테아제 2-6 중량부, 만나아제 2-6 중량부, 아밀라아제 2-6 중량부, 글리세린 1-5 중량부, 1,3-부틸렌글리콜 0.8-1.2 중량부, 에탄올 8-12 중량부 및 정제수 48-52 중량부를 혼합하는 단계를 포함하고,A step of mixing 1-5 parts by weight of a compound having an imidazole group, 1-5 parts by weight of an additive, 1-5 parts by weight of a Coptis chinensis root extract, 2-6 parts by weight of decyl glucoside, 2-6 parts by weight of cocobetaine, 1-5 parts by weight of C12-14Sec-pareth-7, 1-5 parts by weight of TEA-oleate, 2-6 parts by weight of cellulase, 2-6 parts by weight of protease, 2-6 parts by weight of mannanase, 2-6 parts by weight of amylase, 1-5 parts by weight of glycerin, 0.8-1.2 parts by weight of 1,3-butylene glycol, 8-12 parts by weight of ethanol, and 48-52 parts by weight of purified water,
상기 이미다졸기를 가지는 화합물은 에틸 1H-이미다졸-1-카르복실레이트(Ethyl 1H-imidazole-1-carboxylate)이고,The compound having the above imidazole group is ethyl 1H-imidazole-1-carboxylate,
상기 첨가제는 메틸메타크릴레이트 단량체 단위 23-27 중량부, 메타크릴산 단량체 단위 23-27 중량부, 1H,1H,2H,2H-퍼플루오로데실아크릴레이트(1H,1H,2H,2H-Perfluorodecyl acrylate) 단량체 단위 23-27 중량부 및 2-(1H-이미다졸-1-카르복사미도)에틸 메타크릴레이트(2-(1H-imidazole-1-carboxamido)ethyl methacrylate) 단량체 단위 23-27 중량부를 포함하는 아크릴계 공중합체인 것을 특징으로 하는 기능성 세제 조성물의 제조방법을 제공한다.The above additive provides a method for producing a functional detergent composition, characterized in that it is an acrylic copolymer containing 23-27 parts by weight of a methyl methacrylate monomer unit, 23-27 parts by weight of a methacrylic acid monomer unit, 23-27 parts by weight of a 1H,1H,2H,2H-perfluorodecyl acrylate monomer unit, and 23-27 parts by weight of a 2-(1H-imidazole-1-carboxamido)ethyl methacrylate monomer unit.
본 발명에 따른 기능성 세제 조성물은 컬러유지 기능성, 착색방지 기능성 및 이염방지 기능성을 가진다. 또한, 의류 손상방지, 섬유복원 기능성을 가진다.The functional detergent composition according to the present invention has color retention, anti-staining, and anti-color transfer functions. It also has clothing damage prevention and fiber restoration functions.
이하, 본 발명을 하기의 실시예에 의해 보다 상세하게 설명한다.Hereinafter, the present invention will be described in more detail by the following examples.
단, 하기 실시예는 본 발명의 내용을 예시하는 것일 뿐 발명의 범위가 실시예 및 실험예에 의해 한정되는 것은 아니다.However, the following examples are only intended to illustrate the content of the present invention, and the scope of the invention is not limited by the examples and experimental examples.
<실시예 1> 기능성 세제 조성물의 제조-1<Example 1> Preparation of functional detergent composition-1
1-메틸이미다졸(1-Methylimidazole) 3 중량부, 황련뿌리추출물 3 중량부, 데실글루코사이드 4 중량부, 코코베타인 4 중량부, C12-14Sec-파레스-7 3 중량부, 티이에이-올리에이트 3 중량부, 셀룰라아제 4 중량부, 프로테아제 4 중량부, 만나아제 4 중량부, 아밀라아제 4 중량부, 글리세린 3 중량부, 1,3-부틸렌글리콜 1 중량부, 에탄올 10 중량부 및 정제수 50 중량부를 혼합하여 기능성 세제 조성물을 제조하였다.A functional detergent composition was prepared by mixing 3 parts by weight of 1-methylimidazole, 3 parts by weight of Coptis chinensis root extract, 4 parts by weight of decyl glucoside, 4 parts by weight of cocobetaine, 3 parts by weight of C12-14Sec-pareth-7, 3 parts by weight of TEA-oleate, 4 parts by weight of cellulase, 4 parts by weight of protease, 4 parts by weight of mannanase, 4 parts by weight of amylase, 3 parts by weight of glycerin, 1 part by weight of 1,3-butylene glycol, 10 parts by weight of ethanol, and 50 parts by weight of purified water.
<실시예 2> 기능성 세제 조성물의 제조-2<Example 2> Preparation of functional detergent composition-2
1-에틸-1H-이미다졸(1-Ethyl-1H-imidazole) 3 중량부, 황련뿌리추출물 3 중량부, 데실글루코사이드 4 중량부, 코코베타인 4 중량부, C12-14Sec-파레스-7 3 중량부, 티이에이-올리에이트 3 중량부, 셀룰라아제 4 중량부, 프로테아제 4 중량부, 만나아제 4 중량부, 아밀라아제 4 중량부, 글리세린 3 중량부, 1,3-부틸렌글리콜 1 중량부, 에탄올 10 중량부 및 정제수 50 중량부를 혼합하여 기능성 세제 조성물을 제조하였다.A functional detergent composition was prepared by mixing 3 parts by weight of 1-ethyl-1H-imidazole, 3 parts by weight of Coptis chinensis root extract, 4 parts by weight of decyl glucoside, 4 parts by weight of cocobetaine, 3 parts by weight of C12-14Sec-pareth-7, 3 parts by weight of TEA-oleate, 4 parts by weight of cellulase, 4 parts by weight of protease, 4 parts by weight of mannanase, 4 parts by weight of amylase, 3 parts by weight of glycerin, 1 part by weight of 1,3-butylene glycol, 10 parts by weight of ethanol, and 50 parts by weight of purified water.
<실시예 3> 기능성 세제 조성물의 제조-3<Example 3> Preparation of functional detergent composition-3
에틸 1H-이미다졸-1-카르복실레이트(Ethyl 1H-imidazole-1-carboxylate) 3 중량부, 황련뿌리추출물 3 중량부, 데실글루코사이드 4 중량부, 코코베타인 4 중량부, C12-14Sec-파레스-7 3 중량부, 티이에이-올리에이트 3 중량부, 셀룰라아제 4 중량부, 프로테아제 4 중량부, 만나아제 4 중량부, 아밀라아제 4 중량부, 글리세린 3 중량부, 1,3-부틸렌글리콜 1 중량부, 에탄올 10 중량부 및 정제수 50 중량부를 혼합하여 기능성 세제 조성물을 제조하였다.A functional detergent composition was prepared by mixing 3 parts by weight of ethyl 1H-imidazole-1-carboxylate, 3 parts by weight of Coptis chinensis root extract, 4 parts by weight of decyl glucoside, 4 parts by weight of cocobetaine, 3 parts by weight of C12-14Sec-pareth-7, 3 parts by weight of TEA-oleate, 4 parts by weight of cellulase, 4 parts by weight of protease, 4 parts by weight of mannanase, 4 parts by weight of amylase, 3 parts by weight of glycerin, 1 part by weight of 1,3-butylene glycol, 10 parts by weight of ethanol, and 50 parts by weight of purified water.
<실시예 4> 기능성 세제 조성물의 제조-4<Example 4> Preparation of functional detergent composition-4
상기 실시예 3에서 기능성 세제 조성물에 첨가제 3 중량부를 더 첨가한 것을 제외하고 상기 실시예 3과 동일하게 수행하여 기능성 세제 조성물을 제조하였다.A functional detergent composition was manufactured in the same manner as in Example 3, except that 3 parts by weight of an additive was added to the functional detergent composition.
상기 첨가제는 메틸메타크릴레이트 단량체 단위 25 중량부, 메타크릴산 단량체 단위 25 중량부, 1H,1H,2H,2H-퍼플루오로데실아크릴레이트(1H,1H,2H,2H-Perfluorodecyl acrylate) 단량체 단위 25 중량부 및 2-(1H-이미다졸-1-카르복사미도)에틸 메타크릴레이트(2-(1H-imidazole-1-carboxamido)ethyl methacrylate) 단량체 단위 25 중량부를 포함하는 아크릴계 공중합체를 사용하였다.The above additive used an acrylic copolymer containing 25 parts by weight of a methyl methacrylate monomer unit, 25 parts by weight of a methacrylic acid monomer unit, 25 parts by weight of a 1H,1H,2H,2H-perfluorodecyl acrylate monomer unit, and 25 parts by weight of a 2-(1H-imidazole-1-carboxamido)ethyl methacrylate monomer unit.
<비교예 1><Comparative Example 1>
황련뿌리추출물 3 중량부, 데실글루코사이드 4 중량부, 코코베타인 4 중량부, C12-14Sec-파레스-7 3 중량부, 티이에이-올리에이트 3 중량부, 셀룰라아제 4 중량부, 프로테아제 4 중량부, 만나아제 4 중량부, 아밀라아제 4 중량부, 글리세린 3 중량부, 1,3-부틸렌글리콜 1 중량부, 에탄올 10 중량부 및 정제수 53 중량부를 혼합하여 기능성 세제 조성물을 제조하였다.A functional detergent composition was prepared by mixing 3 parts by weight of Coptis chinensis root extract, 4 parts by weight of decyl glucoside, 4 parts by weight of cocobetaine, 3 parts by weight of C12-14Sec-pareth-7, 3 parts by weight of TEA-oleate, 4 parts by weight of cellulase, 4 parts by weight of protease, 4 parts by weight of mannanase, 4 parts by weight of amylase, 3 parts by weight of glycerin, 1 part by weight of 1,3-butylene glycol, 10 parts by weight of ethanol, and 53 parts by weight of purified water.
<실험예 1> 컬러유지 기능성 분석<Experimental Example 1> Color retention functionality analysis
본 발명에 따른 기능성 세제 조성물의 기능성을 확인하기 위하여, 아래와 같은 방법으로 시험을 수행하였다.In order to confirm the functionality of the functional detergent composition according to the present invention, a test was conducted using the following method.
상기 실시예 1-4 및 비교예 1에서 제조된 기능성 세제 조성물 100 ml를 30℃의 물 100 ml와 혼합하여 세제 용액을 제조하고, 세정되는 대상물을 세제 용액에 넣고, 30분 동안 기계 세탁을 수행하고, 탈수하고, 자연 건조한다. 본 발명에 따른 실시예 및 비교예에서 제조한 기능성 세제를 이용하지 않고 세정한 의류(대조군)와 비교하여, 그 결과를 하기 표 1에 나타내었다.A detergent solution was prepared by mixing 100 ml of the functional detergent compositions prepared in Examples 1-4 and Comparative Example 1 with 100 ml of water at 30°C, placing the object to be cleaned in the detergent solution, machine washing for 30 minutes, dehydrating, and air drying. The results are shown in Table 1 below, as compared to clothes cleaned without using the functional detergents prepared in the Examples and Comparative Examples according to the present invention (control group).
상기 표 1에 나타낸 바와 같이, 본 발명에 따른 기능성 세제 조성물을 적용하는 경우 우수한 컬러유지 기능성을 나타내는 것을 확인할 수 있었다.As shown in Table 1 above, it was confirmed that when the functional detergent composition according to the present invention was applied, excellent color retention functionality was exhibited.
<실험예 2> 이염방지 기능성 분석<Experimental Example 2> Analysis of anti-infection functionality
본 발명에 따른 기능성 세제 조성물의 기능성을 확인하기 위하여, 아래와 같은 방법으로 시험을 수행하였다.In order to confirm the functionality of the functional detergent composition according to the present invention, a test was conducted using the following method.
터고터미터(Terg-O-Tometer)에 염료(산성, 직접, 반응성)의 종류에 따라 염색된 10.0 × 10.0 cm2 크기의 천(오염포) 5장, 및 염색되지 않은 같은 크기의 백색 면포 1장을 버켓(bucket)에 넣고, 상기 실시예 1-4 및 비교예 1에서 제조된 기능성 세제 조성물을 각각 2.0 g/L를 넣고 물의 온도는 30℃ 이며, 경도는 110 ppm으로 맞추고 세탁 시간을 30분으로 하여 세탁을 하였다.Five pieces of cloth (contaminated cloth) of 10.0 × 10.0 cm 2 in size dyed according to the type of dye (acid, direct, reactive) and one piece of undyed white cotton cloth of the same size were placed in a bucket in a Terg-O-Tometer, and 2.0 g/L of the functional detergent compositions manufactured in Examples 1-4 and Comparative Example 1 were added thereto, and the water temperature was set to 30°C, the hardness to 110 ppm, and the washing time was set to 30 minutes.
세탁이 끝난 후 각각의 버켓(Bucket)에 있는 천을 20℃, 110 ppm으로 하여 3 분간 헹굼을 실시한 다음, 염색된 천과 백색 면포를 분리하여 물을 짠 다음, 자연 건조한 후, 백색 포의 L, a, b값을 측정하여 세탁 전에 측정된 L, a, b 값과 함께 하기 수학식 1에 의하여 색차(ΔE 값)를 구하였으며, 그 결과를 하기 표 2에 나타내었다.After washing, the fabrics in each bucket were rinsed for 3 minutes at 20℃ and 110 ppm, the dyed fabric and white cotton cloth were separated, the water was squeezed out, and after natural drying, the L, a, and b values of the white cloth were measured, and the color difference (ΔE value) was calculated using the following mathematical formula 1 together with the L, a, and b values measured before washing, and the results are shown in Table 2 below.
<수학식 1><Mathematical Formula 1>
(상기 수학식 1에서, L은 표면 반사율이고, a는 redness/greenness이고, b는 yellowness/blueness이고, w는 세탁 후의 천이고, o는 세탁 전의 천을 나타내고, ΔE는 색차를 나타내며, 세탁하기 전의 백색 면포와 세탁 후의 백색 면포간의 색 차이를 나타내는 값 을 나타낸다.)(In the above mathematical expression 1, L is surface reflectance, a is redness/greenness, b is yellowness/blueness, w is the cloth after washing, o is the cloth before washing, and ΔE is the color difference, which is a value representing the color difference between the white cotton cloth before washing and the white cotton cloth after washing.)
이 ΔE값이 큰 값일수록 이염이 많이 발생하였으며, 적은 값일수록 이염 방지 효과가 있는 것으로 판단하였다.The larger the ΔE value, the more otitis media occurred, and the smaller the value, the better the anti-otitis media effect was determined.
상기 표 2에 나타낸 바와 같이, 본 발명에 따른 기능성 세제 조성물을 적용하는 경우 우수한 이염방지 기능성을 나타내는 것을 확인할 수 있었다.As shown in Table 2 above, it was confirmed that when the functional detergent composition according to the present invention was applied, excellent anti-dyeing functionality was exhibited.
<실험예 3> 의류손상방지 기능성 분석<Experimental Example 3> Analysis of clothing damage prevention functionality
본 발명에 따른 기능성 세제 조성물의 기능성을 확인하기 위하여, KSK 0600, 0601에 의거하여 의류 수축율 시험을 수행하였으며, 그 결과를 하기 표 3에 나타내었다.In order to confirm the functionality of the functional detergent composition according to the present invention, a clothing shrinkage test was performed according to KSK 0600, 0601, and the results are shown in Table 3 below.
상기 표 3에 나타낸 바와 같이, 본 발명에 따른 기능성 세제 조성물을 적용하는 경우 우수한 의류손상방지 기능성을 나타내는 것을 확인할 수 있었다.As shown in Table 3 above, it was confirmed that when the functional detergent composition according to the present invention was applied, excellent clothing damage prevention functionality was exhibited.
Claims (6)
상기 이미다졸기를 가지는 화합물은 1-메틸이미다졸(1-Methylimidazole), 2-메틸이미다졸(2-Methylimidazole), 1-에틸-1H-이미다졸(1-Ethyl-1H-imidazole), 2-에틸이미다졸(2-Ethylimidazole), 1-부틸이미다졸(1-Butylimidazole) 및 에틸 1H-이미다졸-1-카르복실레이트(Ethyl 1H-imidazole-1-carboxylate)로 이루어지는 군으로부터 선택되는 1종 이상인 것을 특징으로 하는 기능성 세제 조성물.In the first paragraph,
A functional detergent composition characterized in that the compound having the above imidazole group is at least one selected from the group consisting of 1-methylimidazole, 2-methylimidazole, 1-ethyl-1H-imidazole, 2-ethylimidazole, 1-butylimidazole, and ethyl 1H-imidazole-1-carboxylate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020240181347A KR102862626B1 (en) | 2024-12-09 | 2024-12-09 | Functional detergent composition having color retention functionality, anti-staining functionality and anti-color transfer functionality based on imidazole |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020240181347A KR102862626B1 (en) | 2024-12-09 | 2024-12-09 | Functional detergent composition having color retention functionality, anti-staining functionality and anti-color transfer functionality based on imidazole |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR102862626B1 true KR102862626B1 (en) | 2025-09-19 |
Family
ID=97173776
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020240181347A Active KR102862626B1 (en) | 2024-12-09 | 2024-12-09 | Functional detergent composition having color retention functionality, anti-staining functionality and anti-color transfer functionality based on imidazole |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR102862626B1 (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4971299B2 (en) * | 2005-03-22 | 2012-07-11 | ビーエーエスエフ ソシエタス・ヨーロピア | Use of cationic polycondensation products as additives to fix colorants to detergent products and laundry post-treatment agents and / or to prevent migration of colorants |
| KR101358405B1 (en) | 2013-08-21 | 2014-02-11 | (주)파라스 | Functional detergent composition |
| US20150135445A1 (en) * | 2011-10-11 | 2015-05-21 | The Sweet Living Group, LLC | Fabric having ultraviolet radiation protection |
| US20230109638A1 (en) * | 2020-02-28 | 2023-04-06 | Basf Se | Automatic dishwashing composition comprising at least one imidazole-based compound |
| KR20230160348A (en) * | 2021-03-22 | 2023-11-23 | 시므라이즈 아게 | liquid detergent composition |
-
2024
- 2024-12-09 KR KR1020240181347A patent/KR102862626B1/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4971299B2 (en) * | 2005-03-22 | 2012-07-11 | ビーエーエスエフ ソシエタス・ヨーロピア | Use of cationic polycondensation products as additives to fix colorants to detergent products and laundry post-treatment agents and / or to prevent migration of colorants |
| US20150135445A1 (en) * | 2011-10-11 | 2015-05-21 | The Sweet Living Group, LLC | Fabric having ultraviolet radiation protection |
| KR101358405B1 (en) | 2013-08-21 | 2014-02-11 | (주)파라스 | Functional detergent composition |
| US20230109638A1 (en) * | 2020-02-28 | 2023-04-06 | Basf Se | Automatic dishwashing composition comprising at least one imidazole-based compound |
| KR20230160348A (en) * | 2021-03-22 | 2023-11-23 | 시므라이즈 아게 | liquid detergent composition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0272574B1 (en) | Mixtures of liquid non-ionic surfactants | |
| DE69630577T2 (en) | Prewash stain remover composition with surfactant based on siloxane | |
| KR101128856B1 (en) | Environment-friendly solvent for water-cleaning and dry-cleaning, and composition for cleaning containing the same solvent | |
| CN111057624A (en) | Sterilization, color protection and color cross-linking prevention concentrated laundry detergent and preparation method thereof | |
| CN113388458A (en) | Special acidic laundry detergent for underwear | |
| JP2012533638A (en) | Liquid cleaning or cleaning agent containing a graying inhibiting polymer | |
| CN107129882B (en) | Transparent laundry detergent composition with washing and softening effects and preparation method thereof | |
| KR102862626B1 (en) | Functional detergent composition having color retention functionality, anti-staining functionality and anti-color transfer functionality based on imidazole | |
| JP4429000B2 (en) | Liquid detergent composition for clothing | |
| JP2011137111A (en) | Liquid detergent composition for clothing | |
| EP2414496B1 (en) | Fluid bleaching agent composition | |
| JP4727281B2 (en) | Liquid detergent composition for clothing | |
| JP4166564B2 (en) | Fashionable cleaning composition | |
| KR100952440B1 (en) | Liquid detergent composition for natural dyed clothing | |
| EP2404988B1 (en) | Laundry pre-spotting composition | |
| CN107922886B (en) | Liquid detergent composition for clothes | |
| KR102375505B1 (en) | liquid detergent composition | |
| KR102920440B1 (en) | Detergent composition for wet cleaning | |
| EP2812421A1 (en) | Washing or cleaning agent with cellulose or a cellulose derivative | |
| KR102802865B1 (en) | Detergent composition for wet cleaning | |
| JP2000096086A (en) | Liquid detergent composition | |
| KR970002048B1 (en) | Liquid neutral detergent composition with minimal damage to clothing and skin | |
| EP3450532B1 (en) | Use of an amodimethicone/organosilicon-containing copolymer, detergent, use of the detergent and washing method | |
| JP2019182970A (en) | Liquid detergent for fiber product | |
| CN121064924A (en) | Washing and nursing composition capable of improving wearing comfort of fabric |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0109 | Patent application |
St.27 status event code: A-0-1-A10-A12-nap-PA0109 |
|
| PA0201 | Request for examination |
St.27 status event code: A-1-2-D10-D11-exm-PA0201 |
|
| PA0302 | Request for accelerated examination |
St.27 status event code: A-1-2-D10-D17-exm-PA0302 St.27 status event code: A-1-2-D10-D16-exm-PA0302 |
|
| D13-X000 | Search requested |
St.27 status event code: A-1-2-D10-D13-srh-X000 |
|
| D14-X000 | Search report completed |
St.27 status event code: A-1-2-D10-D14-srh-X000 |
|
| PE0902 | Notice of grounds for rejection |
St.27 status event code: A-1-2-D10-D21-exm-PE0902 |
|
| E13-X000 | Pre-grant limitation requested |
St.27 status event code: A-2-3-E10-E13-lim-X000 |
|
| P11-X000 | Amendment of application requested |
St.27 status event code: A-2-2-P10-P11-nap-X000 |
|
| P13-X000 | Application amended |
St.27 status event code: A-2-2-P10-P13-nap-X000 |
|
| PE0701 | Decision of registration |
St.27 status event code: A-1-2-D10-D22-exm-PE0701 |
|
| F11 | Ip right granted following substantive examination |
Free format text: ST27 STATUS EVENT CODE: A-2-4-F10-F11-EXM-PR0701 (AS PROVIDED BY THE NATIONAL OFFICE) |
|
| PR0701 | Registration of establishment |
St.27 status event code: A-2-4-F10-F11-exm-PR0701 |
|
| PR1002 | Payment of registration fee |
St.27 status event code: A-2-2-U10-U11-oth-PR1002 Fee payment year number: 1 |
|
| U11 | Full renewal or maintenance fee paid |
Free format text: ST27 STATUS EVENT CODE: A-2-2-U10-U11-OTH-PR1002 (AS PROVIDED BY THE NATIONAL OFFICE) Year of fee payment: 1 |
|
| P14 | Amendment of ip right document requested |
Free format text: ST27 STATUS EVENT CODE: A-5-5-P10-P14-NAP-X000 (AS PROVIDED BY THE NATIONAL OFFICE) |
|
| P14-X000 | Amendment of ip right document requested |
St.27 status event code: A-5-5-P10-P14-nap-X000 |
|
| P16 | Ip right document amended |
Free format text: ST27 STATUS EVENT CODE: A-5-5-P10-P16-NAP-X000 (AS PROVIDED BY THE NATIONAL OFFICE) |
|
| P16-X000 | Ip right document amended |
St.27 status event code: A-5-5-P10-P16-nap-X000 |
|
| PG1601 | Publication of registration |
St.27 status event code: A-4-4-Q10-Q13-nap-PG1601 |
|
| Q13 | Ip right document published |
Free format text: ST27 STATUS EVENT CODE: A-4-4-Q10-Q13-NAP-PG1601 (AS PROVIDED BY THE NATIONAL OFFICE) |
|
| Q16 | A copy of ip right certificate issued |
Free format text: ST27 STATUS EVENT CODE: A-4-4-Q10-Q16-NAP-X000 (AS PROVIDED BY THE NATIONAL OFFICE) |
|
| Q16-X000 | A copy of ip right certificate issued |
St.27 status event code: A-4-4-Q10-Q16-nap-X000 |