KR102297786B1 - 가소제 조성물, 및 이를 포함하는 염화비닐계 수지 조성물 - Google Patents
가소제 조성물, 및 이를 포함하는 염화비닐계 수지 조성물 Download PDFInfo
- Publication number
- KR102297786B1 KR102297786B1 KR1020180167915A KR20180167915A KR102297786B1 KR 102297786 B1 KR102297786 B1 KR 102297786B1 KR 1020180167915 A KR1020180167915 A KR 1020180167915A KR 20180167915 A KR20180167915 A KR 20180167915A KR 102297786 B1 KR102297786 B1 KR 102297786B1
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- KR
- South Korea
- Prior art keywords
- plasticizer
- vinyl chloride
- based resin
- resin composition
- ethylhexyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/014—Stabilisers against oxidation, heat, light or ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0016—Plasticisers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
가소제(중량비) | |
실시예 1 | DEHCH: DEHA (9:1) |
실시예 2 | DEHCH: DEHA (8:2) |
실시예 3 | DEHCH: DEHA (7:3) |
실시예 4 | DEHCH: DEHA (6:4) |
비교예 1 | DEHCH |
비교예 2 | DINP |
비교예 3 | DINP: DEHA (9:1) |
비교예 4 | DINP: DEHA (8:2) |
비교예 5 | DINP: DEHA (7:3) |
비교예 6 | DINP: DEHA (6:4) |
비교예 7 | DOTP |
비교예 8 | DOTP: DEHA (9:1) |
비교예 9 | DOTP: DEHA (8:2) |
비교예 10 | DOTP: DEHA (7:3) |
비교예 11 | DOTP: DEHA (6:4) |
가소제(중량비) | 가소제 이행성(%) | LTB(℃) | 헤이즈(%) | |
실시예 1 | DEHCH: DEHA (9:1) | 0.27 | -42.5 | 6.71 |
실시예 2 | DEHCH: DEHA (8:2) | 0.34 | -44.2 | 7.30 |
실시예 3 | DEHCH: DEHA (7:3) | 0.41 | -46.5 | 7.89 |
실시예 4 | DEHCH: DEHA (6:4) | 0.48 | -48.0 | 8.48 |
비교예 1 | DEHCH | 0.21 | -40.2 | 6.13 |
비교예 2 | DINP | 0.1 | -26.2 | 5.12 |
비교예 3 | DINP: DEHA (9:1) | 0.25 | -29.6 | 5.13 |
비교예 4 | DINP: DEHA (8:2) | 0.34 | -32.5 | 6.20 |
비교예 5 | DINP: DEHA (7:3) | 0.37 | -37.0 | 6.80 |
비교예 6 | DINP: DEHA (6:4) | 0.42 | -44.0 | 7.2 |
비교예 7 | DOTP | 1.42 | -38.5 | 8.90 |
비교예 8 | DOTP: DEHA (9:1) | 1.25 | -39.7 | 9.31 |
비교예 9 | DOTP: DEHA (8:2) | 1.19 | -43.8 | 9.62 |
비교예 10 | DOTP: DEHA (7:3) | 1.13 | -44.3 | 9.79 |
비교예 11 | DOTP: DEHA (6:4) | 1.00 | -48.1 | 10.2 |
Claims (10)
- 디(2-에틸헥실)사이클로헥산-1,4-디카르복실레이트 및 디(2-에틸헥실)아디페이트를 포함하는, 가소제 조성물.
- 제1항에 있어서,
디(2-에틸헥실)사이클로헥산-1,4-디카르복실레이트 및 디(2-에틸헥실)아디페이트의 중량비는 95:5 내지 50:50인, 가소제 조성물.
- 제2항에 있어서,
디(2-에틸헥실)사이클로헥산-1,4-디카르복실레이트 및 디(2-에틸헥실)아디페이트의 중량비는 90:10 내지 60:40인, 가소제 조성물.
- 염화비닐계 수지, 및
제1항 내지 제3항 중 어느 한 항의 가소제 조성물을 포함하는, 염화비닐계 수지 조성물.
- 제4항에 있어서,
상기 염화비닐계 수지 100 중량부에 대하여 상기 가소제 조성물을 30 내지 70 중량부로 포함하는, 염화비닐계 수지 조성물.
- 제4항에 있어서,
ASTM D746 에 따라 측정한 LTB(Low Temperature Brittleness)가 -41℃ 이하인, 염화비닐계 수지 조성물.
- 제4항에 있어서,
ASTM D1003에 따라 측정한 헤이즈가 9% 이하인, 염화비닐계 수지 조성물.
- 제4항에 있어서,
안정제, 발포제, 충전제 및 이산화 티타늄(TiO2)으로 구성되는 군으로부터 선택되는 1종 이상을 더 포함하는, 염화비닐계 수지 조성물.
- 제4항의 염화비닐계 수지 조성물을 포함하는 성형품.
- 제9항에 있어서,
바닥재, 벽지, 타포린, 인조피혁, 장난감, 또는 자동차 하부 코팅재인, 성형품.
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020180167915A KR102297786B1 (ko) | 2018-12-21 | 2018-12-21 | 가소제 조성물, 및 이를 포함하는 염화비닐계 수지 조성물 |
EP19899075.6A EP3971236A4 (en) | 2018-12-21 | 2019-10-18 | PLASTICIZER COMPOSITION AND VINYL CHLORIDE-BASED RESIN COMPOSITION COMPRISING THEM |
PCT/KR2019/013763 WO2020130315A1 (ko) | 2018-12-21 | 2019-10-18 | 가소제 조성물, 및 이를 포함하는 염화비닐계 수지 조성물 |
CN201980078286.6A CN113166476A (zh) | 2018-12-21 | 2019-10-18 | 增塑剂组合物和包含其的基于氯乙烯的树脂组合物 |
JP2021535140A JP7209840B2 (ja) | 2018-12-21 | 2019-10-18 | 可塑剤組成物、およびこれを含む塩化ビニル系樹脂組成物 |
US17/295,906 US12104042B2 (en) | 2018-12-21 | 2019-10-18 | Plasticizer composition and vinyl chloride-based resin composition including the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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KR1020180167915A KR102297786B1 (ko) | 2018-12-21 | 2018-12-21 | 가소제 조성물, 및 이를 포함하는 염화비닐계 수지 조성물 |
Publications (2)
Publication Number | Publication Date |
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KR20200078222A KR20200078222A (ko) | 2020-07-01 |
KR102297786B1 true KR102297786B1 (ko) | 2021-09-02 |
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KR1020180167915A Active KR102297786B1 (ko) | 2018-12-21 | 2018-12-21 | 가소제 조성물, 및 이를 포함하는 염화비닐계 수지 조성물 |
Country Status (6)
Country | Link |
---|---|
US (1) | US12104042B2 (ko) |
EP (1) | EP3971236A4 (ko) |
JP (1) | JP7209840B2 (ko) |
KR (1) | KR102297786B1 (ko) |
CN (1) | CN113166476A (ko) |
WO (1) | WO2020130315A1 (ko) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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KR102648321B1 (ko) * | 2020-12-29 | 2024-03-14 | 한화솔루션 주식회사 | 수성 난연 접착제 조성물 및 그 제조방법 |
KR102742610B1 (ko) * | 2021-02-05 | 2024-12-12 | 한화솔루션 주식회사 | 가소제 조성물, 및 이를 포함하는 염화비닐계 수지 조성물 |
Family Cites Families (24)
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JPS6246527U (ko) | 1985-09-06 | 1987-03-20 | ||
JPS6246528U (ko) | 1985-09-09 | 1987-03-20 | ||
AU630884B2 (en) * | 1988-09-09 | 1992-11-12 | B.F. Goodrich Company, The | Polyvinyl chloride blends having improved physical properties |
JPH03128977A (ja) * | 1989-10-13 | 1991-05-31 | Inoue Mtp Co Ltd | 耐チッピング塗料 |
DE60230050D1 (de) * | 2001-09-25 | 2009-01-08 | Exxonmobil Chem Patents Inc | Weich-polyvinylchlorid |
KR100962985B1 (ko) | 2007-05-30 | 2010-06-10 | 주식회사 엘지화학 | 디옥틸테레프탈레이트를 포함하는 벽지용 염화비닐계 수지조성물 |
EP2231763B1 (en) * | 2007-12-21 | 2015-01-07 | ExxonMobil Chemical Patents Inc. | Co-plasticizer systems |
DE102008001655A1 (de) * | 2008-05-08 | 2009-11-12 | Kuraray Europe Gmbh | Weichmacherhaltige Folien aus Polyvinylacetal mit Cyclohexan-1,2-dicarbon-säureestern als Weichmacher |
US9534104B2 (en) * | 2013-01-28 | 2017-01-03 | Exxonmobil Chemical Patents Inc. | Plasticizer blends and use thereof |
EP2810982A1 (en) * | 2013-06-06 | 2014-12-10 | ExxonMobil Chemical Patents Inc. | Dialkyl esters of 1,4' cyclohexane di-carboxylic acid and their use as plasticisers |
JP6246528B2 (ja) | 2013-08-27 | 2017-12-13 | リケンテクノス株式会社 | 医療用放射線滅菌対応塩化ビニル樹脂組成物およびそれからなる医療用器具 |
JP6246527B2 (ja) | 2013-08-27 | 2017-12-13 | リケンテクノス株式会社 | 医療用塩化ビニル樹脂組成物及びそれからなる医療用器具 |
KR20160139001A (ko) * | 2014-03-27 | 2016-12-06 | 신닛폰 리카 가부시키가이샤 | 비프탈산계 에스테르를 함유하는 염화비닐계 수지용 가소제 및 해당 가소제를 함유하는 염화비닐계 수지 조성물 |
JP6318348B2 (ja) * | 2014-05-19 | 2018-05-09 | 平岡織染株式会社 | 軟質塩化ビニル樹脂製産業資材シート |
JP6318349B2 (ja) | 2014-05-26 | 2018-05-09 | 平岡織染株式会社 | 軟質塩化ビニル樹脂製産業資材シート |
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KR101889540B1 (ko) | 2014-10-22 | 2018-08-17 | 한화케미칼 주식회사 | 디(2-에틸헥실)사이클로헥산-1,4-디카르복실레이트 및 시트레이트계 화합물을 포함하는 가소제 조성물, 및 이를 포함하는 염화비닐 수지 조성물 |
JP6823247B2 (ja) * | 2015-06-30 | 2021-02-03 | 新日本理化株式会社 | エポキシシクロヘキサンジカルボン酸ジエステルを含有してなる自動車内装用塩化ビニル系樹脂組成物及び自動車内装材 |
JP2017115043A (ja) | 2015-12-25 | 2017-06-29 | 三菱ケミカル株式会社 | 軟質塩化ビニル樹脂組成物 |
CN109196034B (zh) | 2016-03-23 | 2021-06-08 | 巴斯夫欧洲公司 | 包含环烷基烷基二羧酸二酯作为增塑剂的聚合物组合物 |
ES2985420T3 (es) | 2016-04-22 | 2024-11-05 | Lg Chemical Ltd | Composición plastificante y método para producirla |
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BR112019007896B1 (pt) * | 2016-10-18 | 2022-11-08 | Interface Biologics, Inc | Composição misturada, artigo e seu método de produção |
-
2018
- 2018-12-21 KR KR1020180167915A patent/KR102297786B1/ko active Active
-
2019
- 2019-10-18 EP EP19899075.6A patent/EP3971236A4/en active Pending
- 2019-10-18 WO PCT/KR2019/013763 patent/WO2020130315A1/ko unknown
- 2019-10-18 US US17/295,906 patent/US12104042B2/en active Active
- 2019-10-18 JP JP2021535140A patent/JP7209840B2/ja active Active
- 2019-10-18 CN CN201980078286.6A patent/CN113166476A/zh active Pending
Also Published As
Publication number | Publication date |
---|---|
WO2020130315A1 (ko) | 2020-06-25 |
EP3971236A4 (en) | 2022-08-24 |
US20220010096A1 (en) | 2022-01-13 |
US12104042B2 (en) | 2024-10-01 |
CN113166476A (zh) | 2021-07-23 |
JP2022514853A (ja) | 2022-02-16 |
KR20200078222A (ko) | 2020-07-01 |
JP7209840B2 (ja) | 2023-01-20 |
EP3971236A1 (en) | 2022-03-23 |
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