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KR102249988B1 - Ecofriendly Method for Removing Pollutant formed on Water Surface - Google Patents

Ecofriendly Method for Removing Pollutant formed on Water Surface Download PDF

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KR102249988B1
KR102249988B1 KR1020180096293A KR20180096293A KR102249988B1 KR 102249988 B1 KR102249988 B1 KR 102249988B1 KR 1020180096293 A KR1020180096293 A KR 1020180096293A KR 20180096293 A KR20180096293 A KR 20180096293A KR 102249988 B1 KR102249988 B1 KR 102249988B1
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water surface
oil
present
volatile
water
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KR20200020507A (en
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채금옥
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    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02BHYDRAULIC ENGINEERING
    • E02B15/00Cleaning or keeping clear the surface of open water; Apparatus therefor
    • E02B15/04Devices for cleaning or keeping clear the surface of open water from oil or like floating materials by separating or removing these materials
    • E02B15/042Devices for removing the oil by combustion with or without means for picking up the oil
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/14Treatment of water, waste water, or sewage by heating by distillation or evaporation using solar energy
    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02BHYDRAULIC ENGINEERING
    • E02B15/00Cleaning or keeping clear the surface of open water; Apparatus therefor
    • E02B15/04Devices for cleaning or keeping clear the surface of open water from oil or like floating materials by separating or removing these materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/20Controlling water pollution; Waste water treatment
    • Y02A20/204Keeping clear the surface of open water from oil spills
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/20Controlling water pollution; Waste water treatment
    • Y02A20/208Off-grid powered water treatment
    • Y02A20/212Solar-powered wastewater sewage treatment, e.g. spray evaporation

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Sustainable Energy (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Sustainable Development (AREA)
  • Mechanical Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Removal Of Floating Material (AREA)
  • Water Treatment By Sorption (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

오염 물질의 친환경적 제거 방법이 개시된다. 본 발명은, 휘발성 용액을 오염 물질이 형성되어 있는 수면에 공급하고, 휘발성 용액의 공급에 따라 수면에 형성되어 있는 오염 물질이 수면 상에서 확산되며, 수면 상에서 확산된 오염 물질의 성분이 태양열에 의해 대기 중으로 증발하는 과정을 통해 구현된다. 본 발명에 따르면, 해양에 유출된 기름 등과 같이 수면에 형성된 오염 물질을 친환경적으로 효과적으로 제거할 수 있게 된다. 본 발명에 따르면, 해양에 유출된 기름 등과 같이 수면에 형성된 오염 물질을 친환경적으로 효과적으로 제거할 수 있게 된다.An environmentally friendly method for removing contaminants is disclosed. In the present invention, a volatile solution is supplied to the water surface where pollutants are formed, and the pollutants formed on the water surface are diffused on the water surface according to the supply of the volatile solution. It is implemented through the process of evaporating into the medium. According to the present invention, it is possible to effectively remove contaminants formed on the surface of the water such as oil spilled into the ocean in an environmentally friendly manner. According to the present invention, it is possible to effectively remove contaminants formed on the surface of the water such as oil spilled into the ocean in an environmentally friendly manner.

Description

오염 물질의 친환경적 제거 방법{Ecofriendly Method for Removing Pollutant formed on Water Surface}Ecofriendly Method for Removing Pollutant formed on Water Surface}

본 발명은 오염 물질 제거 방법에 관한 것으로, 더욱 상세하게는 해양에 유출된 기름 등과 같이 수면에 형성된 오염 물질을 친환경적이면서도 효과적으로 제거할 수 있도록 하는 오염 물질의 친환경적 제거 방법에 관한 것이다.The present invention relates to a method for removing pollutants, and more particularly, to an environmentally friendly method for removing pollutants that enables environmentally and effective removal of pollutants formed on the surface of the water, such as oil spilled into the ocean.

해양에서의 선박 사고로 인해 기름이 유출된 경우에 유출된 기름으로 인해 기름띠가 해양에 형성되며, 이를 제거하기 위한 방제 작업이 다양한 광범위하게 이루어지게 된다.When oil is leaked due to a ship accident at sea, oil bands are formed in the sea due to the spilled oil, and various control works to remove them are carried out in a wide range.

구체적으로, 기름띠를 제거하기 위해 유처리제, 흡착제 등이 사용되는데 이는 전반적인 방제 비용을 현저히 상승시키는 문제가 있을 뿐만 아니라, 방제 과정에서 추가적인 환경 오염이 발생할 수 있다는 기술적 한계가 있다.Specifically, dispersants, adsorbents, etc. are used to remove the oil strip, which not only significantly increases the overall control cost, but also has a technical limitation that additional environmental pollution may occur during the control process.

따라서, 본 발명의 목적은, 해양에 유출된 기름 등과 같이 수면에 형성된 오염 물질을 친환경적이면서도 효과적으로 제거할 수 있도록 하는 오염 물질 제거 방법을 제공함에 있다.Accordingly, it is an object of the present invention to provide a method for removing pollutants that enables environmentally and effective removal of pollutants formed on the surface of the water, such as oil spilled into the ocean.

상기 목적을 달성하기 위한 본 발명에 따른 오염 물질 제거 방법은, (a) 휘발성 용액을 오염 물질이 형성되어 있는 수면에 공급하는 단계; 및 (b) 상기 휘발성 용액의 공급에 따라 수면에 형성되어 있는 상기 오염 물질이 수면 상에서 확산되는 단계; 및 (c) 수면 상에서 확산된 상기 오염 물질의 성분이 태양열에 의해 대기 중으로 증발하는 단계를 포함한다.A method for removing pollutants according to the present invention for achieving the above object comprises the steps of: (a) supplying a volatile solution to a water surface in which pollutants are formed; And (b) diffusing the pollutant formed on the water surface according to the supply of the volatile solution. And (c) evaporating the contaminant component diffused on the water surface into the atmosphere by solar heat.

바람직하게는, 상기 오염 물질은 수면에 형성된 기름띠인 것을 특징으로 한다.Preferably, the pollutant is characterized in that the oil band formed on the water surface.

본 발명에 따르면, 해양에 유출된 기름 등과 같이 수면에 형성된 오염 물질을 친환경적이면서도 효과적으로 제거할 수 있게 된다.According to the present invention, it is possible to environmentally and effectively remove pollutants formed on the water surface, such as oil spilled into the ocean.

도 1은 본 발명의 일 실시예에 따른 수면에 형성된 오염 물질 제거 방법의 실행 과정을 설명하는 절차 흐름도이다.1 is a flowchart illustrating an execution process of a method for removing pollutants formed on a water surface according to an embodiment of the present invention.

이하에서는 도면을 참조하여 본 발명을 보다 상세하게 설명한다. 도면들 중 동일한 구성요소들은 가능한 한 어느 곳에서든지 동일한 부호들로 나타내고 있음에 유의해야 한다. 또한 본 발명의 요지를 불필요하게 흐릴 수 있는 공지 기능 및 구성에 대한 상세한 설명은 생략한다.Hereinafter, the present invention will be described in more detail with reference to the drawings. It should be noted that the same components in the drawings are denoted by the same reference numerals wherever possible. In addition, detailed descriptions of known functions and configurations that may unnecessarily obscure the subject matter of the present invention will be omitted.

본 발명자는 아세톤(Acetone), 뷰틸아세테이트(Butyl acetate), 에탄올(Ethanol)을 혼합하여 제조되는 휘발성 용액을 기름띠 등과 같은 수면에 형성되어 있는 오염 물질에 스프레이 방식으로 분사한 후 태양광에 노출시킨 결과, 이후 시간 경과에 따라 오염 물질이 제거되는 현상을 발견하였다.The present inventors sprayed a volatile solution prepared by mixing acetone, butyl acetate, and ethanol on contaminants formed on the water surface such as oil strips by spraying and exposed to sunlight. As a result, it was found that contaminants were removed over time.

즉, 본 발명자는 휘발성 용액을 이용하여 수면에 형성되어 있는 기름띠 등의 오염 물질을 효과적으로 제거할 수 있다는 사실을 발견하였으며, 이와 같은 발견에 기초하여 본 발명에 따른 수면에 형성된 오염 물질 제거 방법을 제안하게 된 것이다.That is, the present inventors discovered that contaminants such as oil strips formed on the water surface can be effectively removed by using a volatile solution, and based on such findings, the method for removing contaminants formed on the water surface according to the present invention I came up with a proposal.

도 1은 본 발명의 일 실시예에 따른 오염 물질 제거 방법의 실행 과정을 설명하는 절차 흐름도이다. 이하에서는 도 1을 참조하여, 본 발명의 일 실시예에 따른 오염 물질 제거 방법의 실행 과정을 설명하기로 한다.1 is a flowchart illustrating an execution process of a pollutant removal method according to an embodiment of the present invention. Hereinafter, with reference to FIG. 1, an execution process of the pollutant removal method according to an embodiment of the present invention will be described.

먼저, 작업자는 휘발성 용액을 스프레이 장비 등의 분사 용기에 저장한다(S110). 본 발명을 실시함에 있어서는 전술한 S110 단계에서의 휘발성 용액은 아세톤, 뷰틸아세테이트, 에탄올을 0.5 내지 1.5 : 1.5 내지 2.5 : 4.5 내지 5.5의 중량비로 혼합하여 제조함이 바람직할 것이다.First, the operator stores the volatile solution in a spray container such as spray equipment (S110). In carrying out the present invention, the volatile solution in step S110 described above is preferably prepared by mixing acetone, butyl acetate, and ethanol in a weight ratio of 0.5 to 1.5: 1.5 to 2.5: 4.5 to 5.5.

그 다음, 작업자는 분사 장비를 이용하여 기름띠 등의 오염 물질이 형성된 수면에 휘발성 용액을 스프레이 방식으로 분사한다(S120).Then, the operator sprays a volatile solution onto the water surface where contaminants such as oil strips are formed using the spraying equipment in a spray method (S120).

이와 같이 스프레이 방식으로 분사된 휘발성 용액의 미세 입자들은 오염 물질이 형성된 수면으로 공급되며, 휘발성 용액의 미세 입자들은 기름띠 등의 오염 물질의 점성으로 인해 오염 물질에 흡착되게 된다.In this way, the fine particles of the volatile solution sprayed by the spray method are supplied to the water surface where the pollutant is formed, and the fine particles of the volatile solution are adsorbed to the pollutant due to the viscosity of the pollutant such as an oil strip.

한편, 오염 물질에 휘발성 용액의 입자들이 흡착됨에 따라 오염 물질의 점도는 낮아지고 유동성은 증가하게 되며, 그에 따라 기름띠가 수면상에서 보다 넓게 확산되는 확산 과정이 진행되게 된다(S130).Meanwhile, as the particles of the volatile solution are adsorbed to the pollutant, the viscosity of the pollutant decreases and the fluidity increases, and accordingly, a diffusion process in which the oil band diffuses more widely on the water surface proceeds (S130).

이와 같이 휘발성 용액의 입자들과 기름띠의 입자들은 상호 흡착된 상태에서 수면상에서 넓게 확산되게 되며, 그 결과 확산된 면적에 비례하여 태양광의 흡수량이 증가하게 된다.In this way, the particles of the volatile solution and the particles of the oil band are widely diffused on the surface of the water in a mutually adsorbed state, and as a result, the absorption amount of sunlight increases in proportion to the diffused area.

이처럼 태양광의 흡수량이 증가하게 됨에 따라, 휘발성 용액에 포함된 휘발성 물질들은 고유 물성인 끓는 점의 크기에 따라 아세톤, 에탄올, 뷰틸아세테이트의 순서로 대기 중으로 증발하게 된다(S140).As the absorption amount of sunlight increases, the volatile substances contained in the volatile solution evaporate into the atmosphere in the order of acetone, ethanol, and butyl acetate according to the size of the boiling point, which is an intrinsic physical property (S140).

한편, 이와 같은 휘발성 물질들의 순차적 증발 과정에서 휘발성 입자와 흡착되어 있는 일부 기름띠 입자의 대기중으로의 증발이 동시에 이루어지게 되며, 이와 같이 상호 다른 끓는 점을 갖는 복수의 휘발성 물질들의 순차적 증발 과정을 통해 기름띠 입자의 대기중으로의 증발양을 더욱 증대시킬 수 있게 된다.Meanwhile, in the process of sequential evaporation of volatile substances, evaporation of the volatile particles and some adsorbed oil band particles into the atmosphere simultaneously occurs, and through the sequential evaporation process of a plurality of volatile substances having different boiling points. It is possible to further increase the amount of evaporation of the oil band particles into the atmosphere.

상술한 바와 같은, 휘발성 물질들의 순차적 증발이 이루어진 다음에도 증발되지 않은 잔여 기름띠의 입자들은 여전히 수면상에서 넓게 확산된 상태를 유지하고 있으며, 이와 같은 기름띠의 입자들 또한 확산된 면적에 비례하여 태양광에 노출된 상태를 유지하게 된다.As described above, even after the sequential evaporation of volatile substances is performed, the remaining oil particles that have not evaporated remain widely diffused on the water surface, and the particles of such oil bands are also in proportion to the diffused area. It stays exposed to light.

그에 따라, 기름띠 입자에 포함되어 있는 각종 석유 성분들은 고유 물성인 끓는 점의 크기에 따라 휘발유, 등유, 경유, 중유의 순서로 대기중으로 증발하게 된다(S150).Accordingly, various petroleum components contained in the oil band particles are evaporated into the atmosphere in the order of gasoline, kerosene, diesel, and heavy oil according to the size of the boiling point, which is an intrinsic physical property (S150).

이와 같이 기름띠 입자에 포함된 석유 성분들이 대기 중으로 순차적으로 증발하고 나면, 상대적으로 높은 끓는 점으로 인해 미처 증발하지 못한 잔사유 성분이 수면에 남게 되는데, 이와 같은 잔사유 성분(기름 찌꺼기)은 높은 밀도로 인해 점차적으로 수중으로 침전하게 되며, 수중으로 침전된 잔사유 성분은 수중에서의 조류의 영향으로 인해 희석되게 된다(S160).After the petroleum components contained in the oil band particles are sequentially evaporated into the atmosphere, residual oil components that have not yet evaporated due to the relatively high boiling point remain on the water surface. Due to the density, it is gradually precipitated into the water, and the residual oil component precipitated into the water is diluted due to the influence of algae in the water (S160).

이와 같이 본 발명에 의하면, 기름 오염 물질의 제거를 위해 휘발성 용액을 수면에 공급함으로써 휘발성 용액을 통해 기름띠를 수면상에서 확산시킨 후에, 휘발성 성분의 대기중으로의 증발 과정에서 휘발성 성분과 흡착된 일부 석유 성분이 함께 증발되게 되며, 이후 휘발성 성분의 증발이 완료된 이후에도 남아있는 기름띠의 석유 성분이 대기중으로 증발됨으로써, 수면에 형성되어 있는 기름띠의 효과적인 제거가 가능하게 된다.As described above, according to the present invention, a volatile solution is supplied to the water surface to remove oil contaminants, and after the oil band is diffused on the water surface through the volatile solution, some petroleum components adsorbed with volatile components in the evaporation process of the volatile components into the atmosphere The components are evaporated together, and after the evaporation of the volatile components is completed, the remaining petroleum components of the oil strip are evaporated into the atmosphere, thereby enabling effective removal of the oil strip formed on the water surface.

아울러, 본 발명에 의하면, 기름 오염 물질의 제거를 위해 공급한 휘발성 용액은 오염 물질의 제거 과정에서 대기 중으로 자연 증발됨으로써 기름 오염 물질 제거의 과정에서 추가적인 환경 피해가 발생하지 않게 된다.In addition, according to the present invention, the volatile solution supplied for the removal of oil pollutants is naturally evaporated into the atmosphere in the process of removing the pollutants, so that additional environmental damage does not occur in the process of removing the oil pollutants.

아울러, 본 발명에서는 전술한 S110 단계에서 휘발성 용액을 기름띠가 형성되어 있는 수면에 공급함에 있어서, 휘발성 용액을 필수적으로 스프레이 방식으로 공급할 필요성이 확인되었다.In addition, in the present invention, in supplying the volatile solution to the water surface in which the oil strip is formed in step S110, the necessity of supplying the volatile solution in a spray manner was confirmed.

구체적으로, 본원 발명자는 휘발성 용액을 수면에 공급함에 있어서, 스프레이 방식에 의하지 않고 휘발성 용액을 기름띠가 형성되어 있는 수면에 붓는 방식으로 공급한 바 있으나, 이러한 경우에는 기름띠 제거의 효과가 거의 발생하지 않았다.Specifically, in supplying the volatile solution to the water surface, the inventor of the present invention supplied the volatile solution by pouring the volatile solution onto the water surface where the oil strip is formed, but in this case, the effect of removing the oil strip is almost generated. Did not do it.

그 이유는 스프레이 방식을 통해 미세 입자의 형태로 대기를 통해 공급된 휘발성 용액은 휘발성 용액 입자가 수면 위에 안착됨으로써 수면 위에 형성되어 있는 기름띠 입자의 석유 성분과 높은 결합 확률을 갖게 되지만, 수면에 붓는 방식으로 공급된 휘발성 용액은 수면에 형성되어 있는 기름 성분과 결합을 형성할 기회를 갖지 못하고 대부분 수중으로 침전되기 때문인 것으로 이해된다.The reason is that the volatile solution supplied through the atmosphere in the form of fine particles through the spray method has a high probability of binding with the petroleum component of the oil band particles formed on the water surface as the volatile solution particles settle on the water surface. It is understood that this is because the volatile solution supplied by the method does not have the opportunity to form bonds with the oil components formed on the water surface and is mostly precipitated into the water.

본 발명에서 사용한 용어는 단지 특정한 실시 예를 설명하기 위해 사용된 것으로 본 발명을 한정하려는 의도가 아니다. 단수의 표현은 문맥상 명백하게 다르게 뜻하지 않는 한, 복수의 표현을 포함한다. 본 출원에서, "포함하다" 또는 "가지다" 등의 용어는 명세서상에 기재된 특징, 숫자, 단계, 동작, 구성요소, 부품 또는 이들을 조합한 것이 존재함을 지정하려는 것이지, 하나 또는 그 이상의 다른 특징들이나 숫자, 단계, 동작, 구성요소, 부품 또는 이들을 조합한 것들의 존재 또는 부가 가능성을 미리 배제하지 않는 것으로 이해되어야 한다.The terms used in the present invention are only used to describe specific embodiments and are not intended to limit the present invention. Singular expressions include plural expressions unless the context clearly indicates otherwise. In the present application, terms such as "comprise" or "have" are intended to designate the presence of features, numbers, steps, actions, components, parts, or combinations thereof described in the specification, but one or more other features. It is to be understood that the presence or addition of elements or numbers, steps, actions, components, parts, or combinations thereof does not preclude in advance.

이상에서는 본 발명의 바람직한 실시예 및 응용예에 대하여 도시하고 설명하였지만, 본 발명은 상술한 특정의 실시예 및 응용예에 한정되지 아니하며, 청구범위에서 청구하는 본 발명의 요지를 벗어남이 없이 당해 발명이 속하는 기술분야에서 통상의 지식을 가진 자에 의해 다양한 변형실시가 가능한 것은 물론이고, 이러한 변형실시들은 본 발명의 기술적 사상이나 전망으로부터 개별적으로 이해되어져서는 안될 것이다.In the above, preferred embodiments and applications of the present invention have been illustrated and described, but the present invention is not limited to the specific embodiments and application examples described above, and the present invention is not departing from the gist of the present invention claimed in the claims. Various modifications may be possible by those of ordinary skill in the art to which they belong, and these modifications should not be individually understood from the technical spirit or prospect of the present invention.

Claims (2)

(a) 서로 다른 끓는 점을 갖는 복수의 휘발성 물질이 혼합된 휘발성 용액을 오염 물질이 형성되어 있는 수면에 공급하는 단계;
(b) 상기 휘발성 용액에 의해 상기 오염 물질의 유동성이 증가됨으로써, 수면에 형성되어 있는 상기 오염 물질이 수면 상에서 확산되는 단계; 및
(c) 수면 상에서 확산된 상기 오염 물질의 성분이 태양열에 의해 대기 중으로 증발하는 단계
를 포함하며,
상기 (c) 단계는,
상기 서로 다른 끓는 점을 갖는 복수의 휘발성 물질이 태양열에 의해 대기 중으로 순차적으로 증발됨에 따라, 순차적으로 증발되는 휘발성 입자가 흡착되어 있는 오염 물질의 성분이 대기 중으로 순차적으로 증발하는 단계를 포함하는 것인 오염 물질 제거 방법.
(a) supplying a volatile solution in which a plurality of volatile substances having different boiling points are mixed to a water surface in which pollutants are formed;
(b) increasing the fluidity of the pollutant by the volatile solution, so that the pollutant formed on the water surface is diffused on the water surface; And
(c) evaporating the contaminant components diffused on the water surface into the atmosphere by solar heat.
Including,
The step (c),
As the plurality of volatile substances having different boiling points are sequentially evaporated into the atmosphere by solar heat, components of the pollutants in which the volatile particles evaporated sequentially are adsorbed are sequentially evaporated into the atmosphere. How to remove contaminants.
제1항에 있어서,
상기 오염 물질은 수면에 형성된 기름띠인 것인 오염 물질 제거 방법.
The method of claim 1,
The pollutant removal method is that the pollutant is an oil band formed on the surface of the water.
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