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KR102072163B1 - Manufacturing Method Of Antibacterial And Deodorization Natural Fabric Using Plazma - Google Patents

Manufacturing Method Of Antibacterial And Deodorization Natural Fabric Using Plazma Download PDF

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KR102072163B1
KR102072163B1 KR1020190043165A KR20190043165A KR102072163B1 KR 102072163 B1 KR102072163 B1 KR 102072163B1 KR 1020190043165 A KR1020190043165 A KR 1020190043165A KR 20190043165 A KR20190043165 A KR 20190043165A KR 102072163 B1 KR102072163 B1 KR 102072163B1
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natural fiber
plasma
lacquer
fiber
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박영희
서경덕
조배다
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박영희
서경덕
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
    • D06M10/025—Corona discharge or low temperature plasma
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/17—Natural resins, resinous alcohols, resinous acids, or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/13—Physical properties anti-allergenic or anti-bacterial

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

본 발명은 면, 견, 마, 및 양모 중 하나 이상을 포함하는 천연섬유를 가성소다액에 침지하는 방식으로 상기 천연섬유를 가성소다액으로 전처리하는 전처리단계(S1); 상기 천연섬유를 염료침투제와 가교제 중 하나와 증류수에 대한 천연 옻나무껍질 추출액의 농도가 10 중량% 또는 20 중량%인 50℃의 천연옻액에 병행으로 30분 동안 침지하여 처리하는 방식으로 병행처리하여 천연섬유에 대한 상기 천연옻액의 고착력을 향상시키는 병행처리단계(S2); 상기 천연섬유에 플라즈마를 조사하는 플라즈마 처리단계(S3); 플라즈마가 조사된 상기 천연섬유를 상기 천연옻액에 2분 동안 침지하는 침지단계(S4); 침지된 상기 천연섬유를 상기 천연옻액으로부터 건져 내어 탈수하는 탈수단계(S5); 및 탈수된 상기 천연섬유를 20℃ 온도와 70% 습도의 오븐에 넣어 건조하는 건조단계(S6)를 포함하고, 상기 염료침투제는 증류수에 대한 탄산칼륨의 농도가 2 중량%인 탄산칼륨액이며, 상기 가교제는 폴리우레탄 수지액 및 실리콘수지액 중 하나인 것을 특징으로 하는 플라즈마를 이용한 항균방취용 천연섬유의 제조방법에 관한 것이다.The present invention includes a pretreatment step (S1) of pretreating the natural fiber with caustic soda solution by dipping the natural fiber comprising at least one of cotton, silk, hemp, and wool into a caustic soda solution; The natural fibers were treated in parallel by immersing them in a natural lacquer at 50 ° C. having a concentration of 10% by weight or 20% by weight of one of the dye penetrant and the crosslinking agent and distilled water. Parallel treatment step (S2) to improve the adhesion of the natural lacquer to the fiber; Plasma treatment step (S3) for irradiating the plasma to the natural fiber; Immersion step of immersing the natural fiber plasma is irradiated in the natural lacquer for 2 minutes (S4); Dehydration step (S5) to dehydrate the natural fiber dipped from the natural lacquer; And a drying step (S6) of drying the dehydrated natural fibers in an oven at a temperature of 20 ° C. and 70% humidity, wherein the dye penetrant is potassium carbonate liquid having a concentration of potassium carbonate in distilled water of 2% by weight, The crosslinking agent relates to a method for producing natural fiber for antibacterial deodorization using plasma, characterized in that one of a polyurethane resin liquid and a silicone resin liquid.

Description

플라즈마를 이용한 항균방취용 천연섬유의 제조방법{Manufacturing Method Of Antibacterial And Deodorization Natural Fabric Using Plazma}Manufacturing Method Of Antibacterial And Deodorization Natural Fabric Using Plazma}

본 발명은 면, 견, 마, 및 양모 중 하나 이상을 포함하는 천연섬유를 가성소다액에 침지하는 방식으로 상기 천연섬유를 가성소다액으로 전처리하는 전처리단계(S1); 상기 천연섬유를 염료침투제와 가교제 중 하나와 증류수에 대한 천연 옻나무껍질 추출액의 농도가 10 중량% 또는 20 중량%인 50℃의 천연옻액에 병행으로 30분 동안 침지하여 처리하는 방식으로 병행처리하여 천연섬유에 대한 상기 천연옻액의 고착력을 향상시키는 병행처리단계(S2); 상기 천연섬유에 플라즈마를 조사하는 플라즈마 처리단계(S3); 플라즈마가 조사된 상기 천연섬유를 상기 천연옻액에 2분 동안 침지하는 침지단계(S4); 침지된 상기 천연섬유를 상기 천연옻액으로부터 건져 내어 탈수하는 탈수단계(S5); 및 탈수된 상기 천연섬유를 20℃ 온도와 70% 습도의 오븐에 넣어 건조하는 건조단계(S6)를 포함하고, 상기 염료침투제는 증류수에 대한 탄산칼륨의 농도가 2 중량%인 탄산칼륨액이며, 상기 가교제는 폴리우레탄 수지액 및 실리콘수지액 중 하나인 것을 특징으로 하는 플라즈마를 이용한 항균방취용 천연섬유의 제조방법에 관한 것이다.The present invention includes a pretreatment step (S1) of pretreating the natural fiber with caustic soda solution by dipping the natural fiber comprising at least one of cotton, silk, hemp, and wool into a caustic soda solution; The natural fibers were treated in parallel by immersing them in a natural lacquer at 50 ° C. having a concentration of 10% by weight or 20% by weight of one of the dye penetrant and the crosslinking agent and distilled water. Parallel treatment step (S2) to improve the adhesion of the natural lacquer to the fiber; Plasma treatment step (S3) for irradiating the plasma to the natural fiber; Immersion step of immersing the natural fiber plasma is irradiated in the natural lacquer for 2 minutes (S4); Dehydration step (S5) to dehydrate the natural fiber dipped from the natural lacquer; And a drying step (S6) of drying the dehydrated natural fibers in an oven at a temperature of 20 ° C. and 70% humidity, wherein the dye penetrant is potassium carbonate liquid having a concentration of potassium carbonate in distilled water of 2% by weight, The crosslinking agent relates to a method for producing natural fiber for antibacterial deodorization using plasma, characterized in that one of a polyurethane resin liquid and a silicone resin liquid.

이하, 첨부되는 도면과 함께 배경기술에 대해서 살펴보면 다음과 같다.Hereinafter, the background art together with the accompanying drawings will be described.

섬유 제품은, 사용시 또는 보관시 세균 번식이 종종 악취 등의 바람직하지 못한 결과를 가져오므로 항균방취 가공이 필요하다.Textile products require antibacterial and deodorant processing because bacterial propagation at use or storage often has undesirable consequences such as malodor.

섬유 제품 중 화학섬유에 대해서는 항균방취성을 부여하는 방법이 개발되어 있다.A method for imparting antimicrobial deodorization to chemical fibers among textile products has been developed.

하지만, 천연섬유는 이미 섬유조직(fiber) 형태로 구성되어 있어서 화학섬유와 같이 섬유조직을 구성하기 전에 천연 항균방취제인 천연옻액을 천연섬유에 고착시키도록 전처리를 할 수가 없다. 따라서, 천연섬유는 원단으로 제작된 후에 이러한 원단에 대한 항균방취성의 물질을 부착시키도록 하는 후처리만이 가능하며 그에 따라 상기 원단을 세탁하는 경우에 상기 원단으로부터 상기 항균방취성의 물질이 분리되는 문제가 발생되고 그에 따라 세탁견뢰도가 떨어져 제품으로서의 효용가치가 떨어지는 문제점이 있다.However, the natural fiber is already composed of a fiber (fiber) form, it is not possible to pre-treat the natural lacquer, which is a natural antibacterial deodorant, to adhere to the natural fiber before forming the fiber structure, such as chemical fibers. Therefore, the natural fiber can only be post-processed to attach the antimicrobial deodorant material to the fabric after being made of a fabric, and thus the antimicrobial deodorant material is separated from the fabric when the fabric is washed. Is generated and thus the laundry fastness falls, there is a problem that the utility value as a product falls.

대한민국 특허공고번호 특1996-0009775호(1996.07.24.)Korean Patent Publication No. 1996-0009775 (1996.07.24.)

본 발명에 의한 플라즈마를 이용한 항균방취용 천연섬유의 제조방법은 다음 사항을 해결하고자 한다.Method for producing a natural fiber for antibacterial deodorization using the plasma according to the present invention is to solve the following.

본 발명의 목적은 천연섬유에 항균방취성의 천연옻액을 고착시키도록 전처리를 할 수 있게 하는 플라즈마를 이용한 항균방취용 천연섬유의 제조방법을 제공하는 것이다.It is an object of the present invention to provide a method for producing antimicrobial deodorant natural fiber using plasma which allows pretreatment to fix antimicrobial deodorant natural lacquer to natural fiber.

본 발명의 다른 목적은 천연섬유에 항균방취성의 천연옻액을 고착하고 고착 후에 천연섬유로부터 항균방취성의 물질이 분리되는 것이 방지되어 천연섬유를 원단으로 제작했을 때 원단의 세탁견뢰도가 향상되게 하는 플라즈마를 이용한 항균방취용 천연섬유의 제조방법을 제공하는 것이다.Another object of the present invention is to fix the antimicrobial deodorant natural lacquer to the natural fiber and prevent the separation of the antimicrobial deodorant material from the natural fiber after fixing the plasma to improve the laundry fastness of the fabric when fabricated as a natural fiber It provides a method for producing a natural fiber for antibacterial deodorization using.

본 발명에 의한 플라즈마를 이용한 항균방취용 천연섬유의 제조방법은 상기 과제를 해결하기 위해서Method of producing a natural fiber for antibacterial deodorization using the plasma according to the present invention to solve the above problems

면, 견, 마, 및 양모 중 하나 이상을 포함하는 천연섬유를 가성소다액에 침지하는 방식으로 상기 천연섬유를 가성소다액으로 전처리하는 전처리단계(S1); 상기 천연섬유를 염료침투제와 가교제 중 하나와 증류수에 대한 천연 옻나무껍질 추출액의 농도가 10 중량% 또는 20 중량%인 50℃의 천연옻액에 병행으로 30분 동안 침지하여 처리하는 방식으로 병행처리하여 천연섬유에 대한 상기 천연옻액의 고착력을 향상시키는 병행처리단계(S2); 상기 천연섬유에 플라즈마를 조사하는 플라즈마 처리단계(S3); 플라즈마가 조사된 상기 천연섬유를 상기 천연옻액에 2분 동안 침지하는 침지단계(S4); 침지된 상기 천연섬유를 상기 천연옻액으로부터 건져 내어 탈수하는 탈수단계(S5); 및 탈수된 상기 천연섬유를 20℃ 온도와 70% 습도의 오븐에 넣어 건조하는 건조단계(S6)를 포함하고, 상기 염료침투제는 증류수에 대한 탄산칼륨의 농도가 2 중량%인 탄산칼륨액이며, 상기 가교제는 폴리우레탄 수지액 및 실리콘수지액 중 하나인 것을 특징으로 한다.A pretreatment step (S1) of pretreating the natural fibers with caustic soda solution by dipping the natural fibers comprising at least one of cotton, silk, hemp, and wool into a caustic soda solution; The natural fibers were treated in parallel by immersing them in a natural lacquer at 50 ° C. having a concentration of 10% by weight or 20% by weight of one of the dye penetrant and the crosslinking agent and distilled water. Parallel treatment step (S2) to improve the adhesion of the natural lacquer to the fiber; Plasma treatment step (S3) for irradiating the plasma to the natural fiber; Immersion step of immersing the natural fiber plasma is irradiated in the natural lacquer for 2 minutes (S4); Dehydration step (S5) to dehydrate the natural fiber dipped from the natural lacquer; And a drying step (S6) of drying the dehydrated natural fibers in an oven at a temperature of 20 ° C. and 70% humidity, wherein the dye penetrant is potassium carbonate liquid having a concentration of potassium carbonate in distilled water of 2% by weight, The crosslinking agent is characterized in that one of the polyurethane resin solution and the silicone resin solution.

본 발명의 일실시예에서, 상기 병행처리단계(S2)는, 상기 천연섬유를 상기 탄산칼륨액 10 중량%와 상기 천연옻액 90 중량%의 혼합액에 침지하여 처리하는 것을 특징으로 한다.In one embodiment of the present invention, the parallel treatment step (S2), characterized in that the treatment by immersing the natural fiber in a mixed solution of 10% by weight of the potassium carbonate liquid and 90% by weight of the natural lacquer liquid.

본 발명의 다른 실시예에서, 상기 병행처리단계(S2)는, 상기 천연섬유를 상기 천연옻액에 30분 동안 침지하는 단계(S2-1); 상기 단계(S2-1)를 거친 천연섬유를 상기 천연옻액으로부터 건져내어 20℃ 온도와 70% 습도로 건조하는 단계(S2-2); 상기 단계(S2-2)를 거친 천연섬유를 상기 폴리우레탄 수지액에 30분 동안 침지하는 단계(S2-3); 및 상기 단계(S2-3)를 거친 천연섬유를 상기 폴리우레탄 수지액으로부터 건져내어 20℃ 온도와 70% 습도로 건조하는 단계(S2-4)를 포함하는 것을 특징으로 한다.In another embodiment of the present invention, the parallel treatment step (S2), the step of immersing the natural fiber in the natural lacquer for 30 minutes (S2-1); Extracting the natural fiber from the step (S2-1) from the natural lacquer and drying it at 20 ° C. and 70% humidity (S2-2); Immersing the natural fiber passed through the step (S2-2) in the polyurethane resin solution for 30 minutes (S2-3); And it is characterized in that it comprises a step (S2-4) to dry the natural fiber passed through the step (S2-3) from the polyurethane resin liquid at 20 ℃ temperature and 70% humidity.

본 발명의 또 다른 실시예에서, 상기 병행처리단계(S2)는, 상기 천연섬유를 상기 천연옻액에 30분 동안 침지하는 단계(S2-1'); 단계(S2-1')를 거친 천연섬유를 상기 천연옻액으로부터 건져내어 20℃ 온도와 70% 습도로 건조하는 단계(S2-2'); 상기 단계(S2-2')를 거친 천연섬유를 상기 실리콘수지액에 30분 동안 침지하는 단계(S2-3'); 및 상기 단계(S2-3')를 거친 천연섬유를 상기 실리콘수지액으로부터 건져내어 20℃ 온도와 70% 습도로 건조하는 단계(S2-4')를 포함하는 것을 특징으로 한다.In another embodiment of the present invention, the parallel treatment step (S2), the step of immersing the natural fiber in the natural lacquer for 30 minutes (S2-1 '); Extracting the natural fiber from step S2-1 'from the natural lacquer and drying it at 20 ° C. and 70% humidity (S2-2'); Immersing the natural fiber passed through the step (S2-2 ') in the silicone resin solution for 30 minutes (S2-3'); And it is characterized in that it comprises a step (S2-4 ') of drying the natural fiber passed through the step (S2-3') from the silicone resin solution at 20 ℃ temperature and 70% humidity.

상기 전처리단계(S1)에서의 상기 전처리는, 상기 천연섬유를 온도가 20℃이고 가성소다의 농도가 15%인 가성소다액에 2분 동안 침지하는 방식으로 수행되는 것을 특징으로 한다.The pretreatment in the pretreatment step (S1) is characterized in that the natural fiber is carried out by dipping for 2 minutes in a caustic soda solution having a temperature of 20 ℃ and a concentration of caustic soda for 15 minutes.

상기 플라즈마 처리단계(S3)에서의 플라즈마 조사는 상기 천연섬유의 표면에 저온(30℃) 플라즈마로 조사하는 방식으로 이루어지는 것을 특징으로 한다.Plasma irradiation in the plasma processing step (S3) is characterized in that the surface of the natural fiber made of a method of irradiating with a low temperature (30 ℃) plasma.

상기 병행처리단계(S2)에서 증류수에 대한 천연 옻나무껍질 추출액의 농도가 10 중량%인 때에는 상기 천연섬유를 상기 천연섬유에 대하여 무게비로 150%인 천연옻액에 30분 동안 침지하여 처리하는 방식으로 병행처리하는 것을 특징으로 한다.When the concentration of natural lacquer bark extract to distilled water in the parallel treatment step (S2) is 10% by weight, the natural fiber is parallelly immersed in a natural lacquer solution having a weight ratio of 150% by weight to the natural fiber for 30 minutes. It is characterized by processing.

상기 병행처리단계(S2)에서 증류수에 대한 천연 옻나무껍질 추출액의 농도가 20 중량%인 때에는 상기 천연섬유를 상기 천연섬유에 대하여 무게비로 50%인 천연옻액에 30분 동안 침지하여 처리하는 방식으로 병행처리하는 것을 특징으로 한다.In the parallel treatment step (S2) when the concentration of the natural lacquer bark extract with respect to distilled water is 20% by weight in parallel to the process by immersing the natural fiber in a natural lacquer solution of 50% by weight relative to the natural fiber for 30 minutes. It is characterized by processing.

본 발명에 의한 플라즈마를 이용한 항균방취용 천연섬유의 제조방법은 상기 해결수단에 의해서 다음과 같은 효과를 발휘할 수 있다. The method for producing antimicrobial deodorant natural fiber using plasma according to the present invention can achieve the following effects by the above-mentioned solution.

첫째, 천연섬유에 항균방취성의 천연옻액을 고착시키도록 전처리를 할 수 있게 하는 플라즈마를 이용한 항균방취용 천연섬유의 제조방법을 제공하는 효과가 있다.First, there is an effect of providing a method for producing a natural fiber for antibacterial deodorization using a plasma that allows the pretreatment to fix the natural lacquer deodorant to the natural fiber.

둘째, 천연섬유에 항균방취성의 천연옻액을 고착하고 고착 후에 천연섬유로부터 항균방취성의 물질이 분리되는 것이 방지되어 천연섬유를 원단으로 제작했을 때 원단의 세탁견뢰도가 향상되게 하는 플라즈마를 이용한 항균방취용 천연섬유의 제조방법을 제공하는 효과가 있다.Second, antimicrobial deodorant using natural plasma to prevent the separation of the antimicrobial deodorant from the natural fiber after fixing the antimicrobial deodorant using a plasma to improve the laundry fastness of the fabric when the fabric is made of natural fibers It is effective to provide a method for producing natural fibers.

도 1은 본 발명의 플라즈마를 이용한 항균방취용 천연섬유의 제조방법을 단계별로 나타내는 플로우챠트이다.
도 2는 도 1의 플라즈마를 이용한 항균방취용 천연섬유의 제조방법을 구성하는 단계들 중 병행처리단계의 일실시예를 세분화하여 나타낸 플로우챠트이다.
도 3은 도 1의 플라즈마를 이용한 항균방취용 천연섬유의 제조방법을 구성하는 단계들 중 병행처리단계의 다른 실시예를 세분화하여 나타낸 플로우챠트이다.1 is a flow chart showing step by step a method for producing antimicrobial deodorizing natural fibers using the plasma of the present invention.
Figure 2 is a flow chart showing the embodiment of the parallel processing step of the steps of constituting the manufacturing method of the natural fiber for antibacterial deodorization using the plasma of FIG.
3 is a flowchart showing another embodiment of the parallel processing step of the steps constituting the manufacturing method of the antimicrobial deodorant natural fiber using the plasma of FIG.

이하, 첨부도면을 참고하여 본 발명에 대해 살펴보고, 바람직한 실시예를 참고하여 본 발명을 상세히 기술하면 다음과 같다.Hereinafter, the present invention will be described with reference to the accompanying drawings, and the present invention will be described in detail with reference to a preferred embodiment.

본 발명의 이점 및 특징, 그리고 그것들을 달성하는 방법은 첨부되는 도면과 함께 상세하게 후술되어 있는 실시예를 참조하면 명확해질 것이다. 그러나, 본 발명은 이하에서 개시되는 실시예에 한정되는 것이 아니라, 서로 다른 다양한 형태로 구현될 수 있으며, 단지 본 실시예는 본 발명의 개시가 완전하도록 하고, 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자에게 발명의 범주를 완전하게 알려주기 위해 제공되는 것이며, 본 발명은 청구항의 범주에 의해 정의될 뿐이다. 그리고, 명세서 전문에 걸쳐 동일 참조 부호는 동일 구성요소를 지칭한다.Advantages and features of the present invention, and methods for achieving them will be apparent with reference to the embodiments described below in detail with the accompanying drawings. However, the present invention is not limited to the embodiments disclosed below, but may be embodied in various different forms, and only the present embodiments make the disclosure of the present invention complete, and are common in the art to which the present invention pertains. It is provided to fully inform those skilled in the art of the scope of the invention, which is to be defined only by the scope of the claims. Like reference numerals refer to like elements throughout the specification.

본 발명은 플라즈마를 이용한 항균방취용 천연섬유의 제조방법에 관하여 개시된다.The present invention relates to a method for producing antimicrobial deodorant natural fiber using a plasma.

특히, 본 발명에서는 천연섬유에 항균방취성의 천연옻액을 고착시키도록 전처리를 할 수 있게 하고, 천연섬유에 항균방취성의 천연옻액을 고착하고 고착 후에 천연섬유로부터 항균방취성의 물질이 분리되는 것이 방지되어 천연섬유를 원단으로 제작했을 때 원단의 세탁견뢰도가 향상되게 하는 데에 효능이 나타나는 플라즈마를 이용한 항균방취용 천연섬유의 제조방법에 관한 것임을 주지한다.Particularly, in the present invention, pretreatment may be performed to fix the antimicrobial deodorant natural lacquer to the natural fiber, and the antimicrobial deodorant natural lacquer is fixed to the natural fiber and the antimicrobial deodorant substance is prevented from being separated from the natural fiber after fixing. Note that the present invention relates to a method for producing antibacterial and deodorant natural fibers using plasma, which is effective in improving washing fastness of fabrics when natural fibers are fabricated.

도 1은 본 발명의 플라즈마를 이용한 항균방취용 천연섬유의 제조방법을 단계별로 나타내는 플로우챠트이고, 도 2는 도 1의 플라즈마를 이용한 항균방취용 천연섬유의 제조방법을 구성하는 단계들 중 병행처리단계의 일실시예를 세분화하여 나타낸 플로우챠트이며, 도 3은 도 1의 플라즈마를 이용한 항균방취용 천연섬유의 제조방법을 구성하는 단계들 중 병행처리단계의 다른 실시예를 세분화하여 나타낸 플로우챠트이다.1 is a flowchart showing a method for producing antibacterial deodorant natural fiber using the plasma of the present invention step by step, Figure 2 is a parallel treatment of the steps constituting the manufacturing method of the antibacterial deodorant natural fiber using the plasma of FIG. One embodiment of the step is a flow chart shown in detail, Figure 3 is a flow chart showing the subdivision of another embodiment of the parallel processing step of constituting the manufacturing method of the antimicrobial deodorizing natural fiber using the plasma of FIG. .

도 1에 도시된 바와 같이, 본 발명의 플라즈마를 이용한 항균방취용 천연섬유의 제조방법은, 전처리단계(S1), 병행처리단계(S2), 플라즈마 처리단계(S3), 침지단계(S4), 탈수단계(S5), 및 건조단계(S6)를 포함한다.As shown in Figure 1, the manufacturing method of the antimicrobial deodorant natural fiber using the plasma of the present invention, pre-treatment step (S1), parallel processing step (S2), plasma treatment step (S3), immersion step (S4), Dehydration step (S5), and drying step (S6).

1. 전처리단계1. Pretreatment Step

상기 전처리단계(S1)에서는 면, 견, 마, 및 양모 중 하나 이상을 포함하는 천연섬유를 가성소다액에 침지하는 방식으로 상기 천연섬유를 가성소다액으로 전처리한다.In the pretreatment step (S1), the natural fiber is pretreated with caustic soda solution by dipping the natural fiber including at least one of cotton, silk, hemp, and wool into the caustic soda solution.

상기 전처리단계(S1)에서의 상기 전처리는, 상기 천연섬유를 온도가 20℃이고 가성소다의 농도가 15%인 가성소다액에 2분 동안 침지하는 방식으로 수행된다.The pretreatment in the pretreatment step (S1) is performed by immersing the natural fiber in a caustic soda solution having a temperature of 20 ° C. and a caustic soda concentration of 15% for 2 minutes.

2. 병행처리단계2. Parallel processing stage

이와 관련하여, 종래기술에 있어서, 천연섬유는 이미 섬유조직(fiber) 형태로 구성되어 있어서 화학섬유와 같이 섬유조직을 구성하기 전에 천연섬유에 항균방취성의 천연옻액을 고착시키도록 전처리를 할 수가 없고, 따라서 천연섬유는 원단으로 제작된 후에 이러한 원단에 대한 항균방취성의 물질을 부착시키도록 하는 후처리만이 가능하며 그에 따라 상기 원단을 세탁하는 경우에 상기 원단으로부터 상기 항균방취성의 물질이 분리되는 문제가 발생되고 그에 따라 세탁견뢰도가 떨어져 제품으로서의 효용가치가 떨어지는 문제점이 있었다.In this regard, in the prior art, the natural fibers are already formed in a fibrous form, and thus cannot be pretreated to fix the antimicrobial and deodorant natural lacquer to the natural fibers before forming the fibrous tissue such as chemical fibers. Therefore, the natural fiber can only be post-processed to attach the antimicrobial deodorant material to the fabric after being made into a fabric, and thus the antimicrobial deodorant substance is separated from the fabric when the fabric is washed. Was generated and thus the wash fastness was dropped there was a problem that the utility value as a product falls.

이러한 종래기술의 문제점을 해결하기 위한 후처리 또는 후가공 기술에 있어서, 상기 병행처리단계(S2)에서는 상기 천연섬유를 염료침투제와 가교제 중 하나와 증류수에 대한 천연 옻나무껍질 추출액의 농도가 10 중량% 또는 20 중량%인 50℃의 천연옻액에 병행으로 30분 동안 침지하여 처리하는 방식으로 병행처리하여 천연섬유에 대한 상기 천연옻액의 고착력을 향상시킨다. 여기서, 상기 염료침투제는 증류수에 대한 탄산칼륨의 농도가 2 중량%(예, 증류수 200g에 탄산칼륨 4g)인 탄산칼륨액이며, 상기 가교제는 폴리우레탄 수지액 및 실리콘수지액 중 하나인 것이 바람직하다. 이 구성에 따르면, 상기 천연섬유에 대한 상기 천연옻액의 고착력이 더욱 향상된다.In the post-treatment or post-processing technology for solving the problems of the prior art, in the parallel processing step (S2) the concentration of the natural lacquer bark extract with respect to the natural fiber of one of the dye penetrant and the crosslinking agent and distilled water is 10% by weight or The treatment is performed by immersion for 30 minutes in parallel to a natural lacquer solution of 50 ℃ of 20% by weight to improve the adhesion of the natural lacquer to natural fibers. Here, the dye penetrant is a potassium carbonate liquid having a potassium carbonate concentration of 2% by weight (for example, 4 g of potassium carbonate in 200 g of distilled water), and the crosslinking agent is one of a polyurethane resin liquid and a silicone resin liquid. . According to this configuration, the adhesion of the natural lacquer to the natural fiber is further improved.

본 발명의 일실시예에서, 상기 병행처리단계(S2)는, 상기 천연섬유를 상기 탄산칼륨액 10 중량%와 상기 천연옻액 90 중량%의 혼합액에 침지하여 처리한다. 이러한 구성에 의하면, 상기 천연섬유에 대한 상기 천연옻액의 고착력이 향상된다.In one embodiment of the present invention, the parallel treatment step (S2), is treated by immersing the natural fiber in a mixed solution of 10% by weight of the potassium carbonate liquid and 90% by weight of the natural lacquer liquid. According to this structure, the sticking force of the said natural lacquer with respect to the said natural fiber improves.

본 발명의 다른 실시예에서, 상기 병행처리단계(S2)는, 상기 천연섬유를 상기 천연옻액에 30분 동안 침지하는 단계(S2-1); 상기 단계(S2-1)를 거친 천연섬유를 상기 천연옻액으로부터 건져내어 20℃ 온도와 70% 습도로 건조하는 단계(S2-2); 상기 단계(S2-2)를 거친 천연섬유를 상기 폴리우레탄 수지액에 30분 동안 침지하는 단계(S2-3); 및 상기 단계(S2-3)를 거친 천연섬유를 상기 폴리우레탄 수지액으로부터 건져내어 20℃ 온도와 70% 습도로 건조하는 단계(S2-4)를 포함한다. 이러한 구성에 의하면, 천연섬유를 상기 천연옻액에 침지한 후 및 천연섬유를 상기 폴리우레탄 수지액에 침지한 후 상기 천연섬유를 충분히 건조시킴으로써 상기 천연섬유로부터 습기가 완전히 제거되고 이와 동시에 상기 천연섬유에 대한 상기 천연옻액의 고착력이 향상된다.In another embodiment of the present invention, the parallel treatment step (S2), the step of immersing the natural fiber in the natural lacquer for 30 minutes (S2-1); Extracting the natural fiber from the step (S2-1) from the natural lacquer and drying it at 20 ° C. and 70% humidity (S2-2); Immersing the natural fiber passed through the step (S2-2) in the polyurethane resin solution for 30 minutes (S2-3); And the step (S2-3) comprises the step of taking out the natural fiber from the polyurethane resin liquid and drying at 20 ℃ temperature and 70% humidity (S2-4). According to this configuration, after the natural fibers are immersed in the natural lacquer and the natural fibers are immersed in the polyurethane resin solution, the natural fibers are sufficiently dried to completely remove moisture from the natural fibers and at the same time to the natural fibers. Adhesion of the natural lacquer to the water is improved.

본 발명의 또 다른 실시예에서, 상기 병행처리단계(S2)는, 상기 천연섬유를 상기 천연옻액에 30분 동안 침지하는 단계(S2-1'); 단계(S2-1')를 거친 천연섬유를 상기 천연옻액으로부터 건져내어 20℃ 온도와 70% 습도로 건조하는 단계(S2-2'); 상기 단계(S2-2')를 거친 천연섬유를 상기 실리콘수지액에 30분 동안 침지하는 단계(S2-3'); 및 상기 단계(S2-3')를 거친 천연섬유를 상기 실리콘수지액으로부터 건져내어 20℃ 온도와 70% 습도로 건조하는 단계(S2-4')를 포함한다. 이러한 구성에 의하면, 천연섬유를 상기 천연옻액에 침지한 후 및 천연섬유를 상기 실리콘수지액에 침지한 후 상기 천연섬유를 충분히 건조시킴으로써 상기 천연섬유로부터 습기가 완전히 제거되고 이와 동시에 상기 천연섬유에 대한 상기 천연옻액의 고착력이 향상된다.In another embodiment of the present invention, the parallel treatment step (S2), the step of immersing the natural fiber in the natural lacquer for 30 minutes (S2-1 '); Extracting the natural fiber from step S2-1 'from the natural lacquer and drying it at 20 ° C. and 70% humidity (S2-2'); Immersing the natural fiber passed through the step (S2-2 ') in the silicone resin solution for 30 minutes (S2-3'); And the step (S2-3 ') and the natural fiber is taken out from the silicone resin solution and the step of drying at 20 ℃ temperature and 70% humidity (S2-4'). According to this configuration, after the natural fibers are immersed in the natural lacquer and the natural fibers are immersed in the silicone resin solution, the natural fibers are sufficiently dried to completely remove moisture from the natural fibers and at the same time Adhesion of the natural lacquer liquid is improved.

상기 병행처리단계(S2)에서 증류수에 대한 천연 옻나무껍질 추출액의 농도가 10 중량%인 때에는 상기 천연섬유를 상기 천연섬유에 대하여 무게비로 150%인 천연옻액에 30분 동안 침지하여 처리하는 방식으로 병행처리한다. 이러한 구성에 의하면, 상기 천연섬유에 대해 고착되기 전에 부착되는 상기 천연옻액의 양이 사전에 설정된 수준으로 확보된다.When the concentration of natural lacquer bark extract to distilled water in the parallel treatment step (S2) is 10% by weight, the natural fiber is parallelly immersed in a natural lacquer solution having a weight ratio of 150% by weight to the natural fiber for 30 minutes. Process. According to this configuration, the amount of the natural lacquer adhered before being fixed to the natural fiber is ensured at a predetermined level.

상기 병행처리단계(S2)에서 증류수에 대한 천연 옻나무껍질 추출액의 농도가 20 중량%인 때에는 상기 천연섬유를 상기 천연섬유에 대하여 무게비로 50%인 천연옻액에 30분 동안 침지하여 처리하는 방식으로 병행처리한다. 이러한 구성에 의하면, 상기 천연섬유에 대해 고착되기 전에 부착되는 상기 천연옻액의 양이 사전에 설정된 수준으로 확보된다.In the parallel treatment step (S2) when the concentration of the natural lacquer bark extract with respect to distilled water is 20% by weight in parallel to the process by immersing the natural fiber in a natural lacquer solution of 50% by weight relative to the natural fiber for 30 minutes. Process. According to this configuration, the amount of the natural lacquer adhered before being fixed to the natural fiber is ensured at a predetermined level.

3. 플라즈마 처리단계3. Plasma Treatment Step

상기 플라즈마 처리단계(S3)에서는 상기 천연섬유에 플라즈마를 조사한다.In the plasma processing step (S3), the plasma is irradiated to the natural fiber.

상기 플라즈마 처리단계(S3)에서의 플라즈마 조사는 상기 천연섬유의 표면에 저온(30℃) 플라즈마로 조사하는 방식으로 이루어진다. Plasma irradiation in the plasma processing step (S3) is made by irradiating the surface of the natural fiber with a low temperature (30 ℃) plasma.

상기 구성에 따르면, 천연섬유에 대한 플라즈마 조사 시에는 상기 천연섬유 표면의 친수성기가 증대되거나 또는 천연섬유 표면의 셀룰로우즈 분자가 원자핵과 전자로 분리되어 활성화된다.According to the above configuration, during plasma irradiation of the natural fiber, the hydrophilic group on the surface of the natural fiber is increased or the cellulose molecules on the surface of the natural fiber are separated and activated by atomic nuclei and electrons.

4. 침지단계4. Immersion stage

상기 침지단계(S4)에서는 플라즈마가 조사된 상기 천연섬유를 상기 천연옻액에 2분 동안 침지한다.In the immersion step (S4), the natural fiber irradiated with plasma is immersed in the natural lacquer for 2 minutes.

상기 구성에 따르면, 상기 플라즈마 처리단계(S3)에서 상기 천연섬유 표면이 원자핵과 전자로 분리되어 활성화되어 상기 천연옻액과 결합하려는 힘이 증가하므로 상기 천연옻액이 상기 천연섬유 표면에 부착되어 고착되는 것이 가능하다.According to the configuration, in the plasma processing step (S3) the surface of the natural fiber is separated by the atomic nucleus and electrons are activated to increase the strength to combine with the natural lacquer is that the natural lacquer is attached to the surface of the natural fiber is fixed It is possible.

5. 탈수단계5. Dehydration Step

상기 탈수단계(S5)에서는 침지된 상기 천연섬유를 상기 천연옻액으로부터 건져 내어 탈수한다. 이러한 탈수는 시판되는 탈수기를 이용하여 수행된다.In the dehydration step (S5), the dipped natural fiber is drained from the natural lacquer and dehydrated. This dehydration is carried out using a commercially available dehydrator.

상기 구성에 의하면, 상기 천연섬유에 대한 탈수가 이루어진다.According to the said structure, the dehydration is performed with respect to the said natural fiber.

6. 건조단계6. Drying Step

상기 건조단계(S6)에서는 탈수된 상기 천연섬유를 20℃ 온도와 70% 습도의 오븐에 넣어 건조한다.In the drying step (S6) and put the dehydrated natural fibers in an oven at 20 ℃ temperature and 70% humidity.

상기 구성에 따르면, 탈수된 상기 천연섬유를 20℃ 온도와 70% 습도의 오븐에 넣어 건조하므로 천연섬유가 완전히 건조되는 것이 가능하다.According to the above configuration, the dehydrated natural fibers are put in an oven at 20 ° C. and 70% humidity, and thus the natural fibers can be completely dried.

이하에서는 본 발명의 실시예 1을 구성하고 실험을 통해 플라즈마를 이용한 항균방취용 천연섬유의 제조방법의 효과에 대해서 면밀하게 파악하고자 한다.Hereinafter, to configure the first embodiment of the present invention and through the experiment to examine the effect of the method of producing a natural fiber for antibacterial deodorization in detail.

면으로 구성되는 천연섬유를 가성소다액에 침지하는 방식으로 상기 천연섬유를 가성소다액으로 전처리하는 전처리단계(S1); 상기 천연섬유를 염료침투제와 가교제 중 하나와 증류수에 대한 천연 옻나무껍질 추출액의 농도가 10 중량% 인 50℃의 천연옻액에 병행으로 30분 동안 침지하여 처리하는 방식으로 병행처리하여 천연섬유에 대한 상기 천연옻액의 고착력을 향상시키는 병행처리단계(S2); 상기 천연섬유에 저온(30℃) 플라즈마를 조사하는 플라즈마 처리단계(S3); 플라즈마가 조사된 상기 천연섬유를 상기 천연옻액에 2분 동안 침지하는 천연옻액에의 침지단계(S4); 침지된 상기 천연섬유를 상기 천연옻액으로부터 건져 내어 탈수하는 탈수단계(S5); 및 탈수된 상기 천연섬유를 20℃ 온도와 70% 습도의 오븐에 넣어 건조하는 건조단계(S6)를 포함하고, 상기 염료침투제는 증류수에 대한 탄산칼륨의 농도가 2 중량%인 탄산칼륨액이며, 상기 가교제는 실리콘수지액인 본 발명의 플라즈마를 이용한 항균방취용 천연섬유의 제조방법에 의해 제조된 항균방취용 천연섬유인 면에 비이온계면활성제(TWEEN 80)를 접종균액에 0.05% 첨가하되 Staphylococcus aureus ATCC 6538을 균주로 사용하고, 세탁조건으로는 KS K ISO 6330 : 2012, 8B, 세탁온도(27±3)℃에서 세탁하며 수평망건조한 것을 실험예 1로 하였다.A pretreatment step (S1) of pretreating the natural fiber with caustic soda solution by dipping the natural fiber composed of cotton in a caustic soda solution; The natural fiber was treated in parallel by immersion for 30 minutes in a natural lacquer at 50 ° C. in which the concentration of the natural lacquer bark extract with respect to one of the dye penetrant and the crosslinking agent and distilled water was treated for 30 minutes. Parallel treatment step (S2) to improve the adhesion of the natural lacquer; Plasma processing step (S3) of irradiating the low-temperature (30 ℃) plasma to the natural fiber; Immersing the natural fiber irradiated with plasma in the natural lacquer for 2 minutes in a natural lacquer (S4); Dehydration step (S5) to dehydrate the natural fiber dipped from the natural lacquer; And a drying step (S6) of drying the dehydrated natural fibers in an oven at a temperature of 20 ° C. and 70% humidity, wherein the dye penetrant is potassium carbonate liquid having a concentration of potassium carbonate in distilled water of 2% by weight, The cross-linking agent is added to 0.05% non-ionic surfactant (TWEEN 80) in the inoculation bacteria solution to the cotton that is the antimicrobial deodorant natural fiber prepared by the method of manufacturing the antimicrobial deodorant natural fiber using the plasma of the present invention is a silicone resin Staphylococcus Aureus ATCC 6538 was used as a strain, and the washing conditions were KS K ISO 6330: 2012, 8B, washing at a washing temperature (27 ± 3) ℃ and horizontal network drying was Experimental Example 1.

이에 대해 항균처리되지 않은 면 섬유를 비교예 1로 하고, On the other hand, the non-antibacterial cotton fiber as Comparative Example 1,

일반적인 섬유용도의 고유점도 0.65인 폴리에스터 칩 99중량%와 3.8중량%의 은과 35중량%의 지르코늄이 함유된 평균입경 0.4㎛의 무기세라믹 1중량%를 혼합기에 넣고 혼합한 후 트윈스크류 혼련기로 용융혼련하여 마스타 배치 칩을 제조한다. 이렇게 제조한 마스타 배치 칩을 160℃에서 4시간 감압 건조하여 칩표면의 수분을 제거한 후 일반 폴리에스터 칩과 혼합비율 1 : 9로 혼합하여 용융시키고 3000rpm의 속도로 방사하여 부분연신사를 제조하고, 이 부분연신사를 히터롤라 온도 90℃ 조건으로 1.80배 연신하고 125℃온도로 열처리하여 최종 섬유에 무기 세라믹이 0.5중량% 함유된 75d/36f의 폴리에스터 섬유를 제조한 것을 비교예 2로 하였으며,99 wt% polyester chip with intrinsic viscosity of 0.65, 3.8 wt% of silver, and 1 wt% of inorganic ceramic with an average particle diameter of 0.4 μm containing 35 wt% of zirconium were mixed in a mixer, followed by a twin screw kneader. Melt kneading to prepare a master batch chip. The master batch chip thus prepared was dried under reduced pressure at 160 ° C. for 4 hours to remove moisture from the surface of the chip, mixed with a general polyester chip in a mixing ratio of 1: 9, melted and spun at a speed of 3000 rpm to prepare partially drawn yarn. This partially drawn yarn was drawn 1.80 times under a heater roller temperature of 90 ° C. and heat-treated at 125 ° C. to prepare 75d / 36f polyester fiber containing 0.5 wt% of inorganic ceramic in the final fiber, as Comparative Example 2,

0.3중량%의 은과 1.1중량%의 지르코늄이 함유된 무기 세라믹을 투입한 것을 제외하고는 비교예 2과 동일한 방법으로 폴리에스터 섬유를 제조한 것을 비교예 3으로 하였다.Comparative Example 3 was prepared in the same manner as in Comparative Example 2 except that an inorganic ceramic containing 0.3 wt% silver and 1.1 wt% zirconium was added thereto.

이들 실험예 1, 비교예 1 내지 3에 대해 성능시험을 행하여 그 결과를 아래의 표 1에 나타내었다.. Performance test was carried out for these Experimental Examples 1 and Comparative Examples 1 to 3 and the results are shown in Table 1 below.

구분division 항균도Antimicrobial activity 세탁전Before washing 세탁후(20회)
After washing (20 times)
실험예 1Experimental Example 1 99.9
99.9
99.9
99.9
비교예 1Comparative Example 1 46.5
46.5
43.7
43.7
비교예 2Comparative Example 2 56.7
56.7
45.1
45.1
비교예 3Comparative Example 3 49.6
49.6
48.9
48.9

상기 표 1을 참조하면, 항균도는 실험예 1이 비교예 1 내지 3에 비하여 세탁 전후 모두 현저히 더 높아 항균성이 우수한 것으로 나타났다.Referring to Table 1, the antimicrobial degree was shown that Experimental Example 1 is significantly higher both before and after washing than Comparative Examples 1 to 3 excellent antibacterial.

S1 : 전처리단계
S2 : 병행처리단계
S2-1, S2-1' : 침지하는 단계
S2-2, S2-2' : 건조하는 단계
S2-3, S2-3' : 침지하는 단계
S2-4, S2-4' : 건조하는 단계
S3 : 플라즈마 처리단계
S4 : 천연옻액에의 침지단계
S5 : 탈수단계
S6 : 건조단계S1: pretreatment step
S2: Parallel Processing Step
S2-1, S2-1 ': immersion step
S2-2, S2-2 ': drying step
S2-3, S2-3 ': immersion step
S2-4, S2-4 ': drying step
S3: plasma treatment step
S4: Dipping step in natural lacquer
S5: Dehydration Step
S6: Drying Step

Claims (8)

면, 견, 마, 및 양모 중 하나 이상을 포함하는 천연섬유를 가성소다액에 침지하는 방식으로 상기 천연섬유를 가성소다액으로 전처리하는 전처리단계(S1);
상기 천연섬유를 염료침투제와 가교제 중 하나와 증류수에 대한 천연 옻나무껍질 추출액의 농도가 10 중량% 또는 20 중량%인 50℃의 천연옻액에 병행으로 30분 동안 침지하여 처리하는 방식으로 병행처리하여 천연섬유에 대한 상기 천연옻액의 고착력을 향상시키는 병행처리단계(S2);
상기 천연섬유에 플라즈마를 조사하는 플라즈마 처리단계(S3);
플라즈마가 조사된 상기 천연섬유를 상기 천연옻액에 2분 동안 침지하는 천연옻액에의 침지단계(S4);
침지된 상기 천연섬유를 상기 천연옻액으로부터 건져 내어 탈수하는 탈수단계(S5); 및
탈수된 상기 천연섬유를 20℃ 온도와 70% 습도의 오븐에 넣어 건조하는 건조단계(S6)를 포함하고,
상기 염료침투제는 증류수에 대한 탄산칼륨의 농도가 2 중량%인 탄산칼륨액이며,
상기 가교제는 폴리우레탄 수지액 및 실리콘수지액 중 하나인 것을 특징으로 하는 플라즈마를 이용한 항균방취용 천연섬유의 제조방법.A pretreatment step (S1) of pretreating the natural fiber with caustic soda solution by dipping the natural fiber including at least one of cotton, silk, hemp, and wool into a caustic soda solution;
The natural fibers were treated in parallel by immersing them in a natural lacquer at 50 ° C. having a concentration of 10% by weight or 20% by weight of one of the dye penetrant and the crosslinking agent and distilled water for 30 minutes. Parallel treatment step (S2) to improve the adhesion of the natural lacquer to the fiber;
Plasma treatment step (S3) for irradiating the plasma to the natural fiber;
Immersing the natural fiber irradiated with plasma in the natural lacquer for 2 minutes in a natural lacquer (S4);
A dehydration step (S5) of dehydrating the natural fiber dipped from the natural lacquer; And
It includes a drying step (S6) to put the dehydrated natural fiber in an oven at 20 ℃ temperature and 70% humidity,
The dye penetrant is a potassium carbonate liquid having a concentration of 2% by weight of potassium carbonate relative to distilled water,
The cross-linking agent is a method for producing natural fiber for antibacterial deodorization using plasma, characterized in that one of the polyurethane resin solution and the silicone resin solution. 제1항에 있어서,
상기 병행처리단계(S2)는
상기 천연섬유를 상기 탄산칼륨액 10 중량%와 상기 천연옻액 90 중량%의 혼합액에 침지하여 처리하는 것을 특징으로 하는 플라즈마를 이용한 항균방취용 천연섬유의 제조방법.The method of claim 1,
The parallel processing step (S2) is
Method of producing a natural fiber for antibacterial deodorization using plasma, characterized in that the natural fiber is immersed in a mixed solution of 10% by weight of the potassium carbonate liquid and 90% by weight of the natural lacquer liquid. 제1항에 있어서,
상기 병행처리단계(S2)는,
상기 천연섬유를 상기 천연옻액에 30분 동안 침지하는 단계(S2-1);
상기 단계(S2-1)를 거친 천연섬유를 상기 천연옻액으로부터 건져내어 20℃ 온도와 70% 습도로 건조하는 단계(S2-2);
상기 단계(S2-2)를 거친 천연섬유를 상기 폴리우레탄 수지액에 30분 동안 침지하는 단계(S2-3); 및
상기 단계(S2-3)를 거친 천연섬유를 상기 폴리우레탄 수지액으로부터 건져내어 20℃ 온도와 70% 습도로 건조하는 단계(S2-4)를 포함하는 것을 특징으로 하는 플라즈마를 이용한 항균방취용 천연섬유의 제조방법.The method of claim 1,
The parallel processing step (S2),
Immersing the natural fiber in the natural lacquer for 30 minutes (S2-1);
Extracting the natural fiber from the step (S2-1) from the natural lacquer and drying it at 20 ° C. and 70% humidity (S2-2);
Immersing the natural fiber having passed through the step (S2-2) in the polyurethane resin solution for 30 minutes (S2-3); And
Natural fiber for the antimicrobial deodorant using a plasma, comprising the step (S2-3) to remove the natural fiber passed through the step (S2-3) from the polyurethane resin solution and dried at 20 ℃ temperature and 70% humidity (S2-4) Method of making fibers. 제1항에 있어서,
상기 병행처리단계(S2)는,
상기 천연섬유를 상기 천연옻액에 30분 동안 침지하는 단계(S2-1');
단계(S2-1')를 거친 천연섬유를 상기 천연옻액으로부터 건져내어 20℃ 온도와 70% 습도로 건조하는 단계(S2-2');
상기 단계(S2-2')를 거친 천연섬유를 상기 실리콘수지액에 30분 동안 침지하는 단계(S2-3'); 및
상기 단계(S2-3')를 거친 천연섬유를 상기 실리콘수지액으로부터 건져내어 20℃ 온도와 70% 습도로 건조하는 단계(S2-4')를 포함하는 것을 특징으로 하는 플라즈마를 이용한 항균방취용 천연섬유의 제조방법.The method of claim 1,
The parallel processing step (S2),
Immersing the natural fiber in the natural lacquer for 30 minutes (S2-1 ′);
Extracting the natural fiber from step S2-1 'from the natural lacquer and drying it at 20 ° C. and 70% humidity (S2-2');
Immersing the natural fiber passed through the step (S2-2 ') in the silicone resin solution for 30 minutes (S2-3'); And
Antimicrobial deodorization using plasma, comprising the step (S2-3 ') to remove the natural fiber from the silicone resin solution and dried at 20 ℃ temperature and 70% humidity (S2-4') Method of making natural fibers. 제1항에 있어서,
상기 전처리단계(S1)에서의 상기 전처리는, 상기 천연섬유를 온도가 20℃이고 가성소다의 농도가 15%인 가성소다액에 2분 동안 침지하는 방식으로 수행되는 것을 특징으로 하는 플라즈마를 이용한 항균방취용 천연섬유의 제조방법.The method of claim 1,
The pretreatment in the pretreatment step (S1), the antibacterial using plasma, characterized in that the natural fiber is immersed in a caustic soda solution having a temperature of 20 ℃ and a concentration of caustic soda for 15 minutes for 2 minutes Method of manufacturing natural fiber for deodorization. 제1항에 있어서,
상기 플라즈마 처리단계(S3)에서의 플라즈마 조사는 상기 천연섬유의 표면에 저온(30℃) 플라즈마로 조사하는 방식으로 이루어지는 것을 특징으로 하는 플라즈마를 이용한 항균방취용 천연섬유의 제조방법.The method of claim 1,
Plasma irradiation in the plasma processing step (S3) is a method of producing antimicrobial deodorant natural fiber using a plasma, characterized in that the surface of the natural fiber made of a method of irradiating with a low temperature (30 ℃) plasma. 제1항에 있어서,
상기 병행처리단계(S2)에서 증류수에 대한 천연 옻나무껍질 추출액의 농도가 10 중량%인 때에는 상기 천연섬유를 상기 천연섬유에 대하여 무게비로 150%인 천연옻액에 30분 동안 침지하여 처리하는 방식으로 병행처리하는 것을 특징으로 하는 플라즈마를 이용한 항균방취용 천연섬유의 제조방법.The method of claim 1,
When the concentration of natural lacquer bark extract in distilled water is 10% by weight in the parallel treatment step (S2), the natural fibers are immersed in a natural lacquer solution having a weight ratio of 150% by weight relative to the natural fibers for 30 minutes. Method for producing a natural fiber for antibacterial deodorization using a plasma characterized in that the treatment. 제1항에 있어서,
상기 병행처리단계(S2)에서 증류수에 대한 천연 옻나무껍질 추출액의 농도가 20 중량%인 때에는 상기 천연섬유를 상기 천연섬유에 대하여 무게비로 50%인 천연옻액에 30분 동안 침지하여 처리하는 방식으로 병행처리하는 것을 특징으로 하는 플라즈마를 이용한 항균방취용 천연섬유의 제조방법.
The method of claim 1,
In the parallel treatment step (S2) when the concentration of the natural lacquer bark extract with respect to distilled water is 20% by weight in parallel to the process by immersing the natural fiber in a natural lacquer solution of 50% by weight relative to the natural fiber for 30 minutes. Method for producing a natural fiber for antibacterial deodorization using a plasma characterized in that the treatment.
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KR960009775A (en) 1994-08-12 1996-03-22 김광호 Standard clock selection device and control method of local exchange
JP2004100083A (en) * 2002-09-09 2004-04-02 Tasuku:Kk Functional fabric
JP2010065368A (en) * 2008-08-12 2010-03-25 Yyl:Kk Method and apparatus of producing antibacterial and antiviral fiber
KR20120105335A (en) * 2011-03-15 2012-09-25 박중호 Anti-bacterial the fibers process
KR20160147496A (en) * 2015-06-15 2016-12-23 백익현 Manufacturing method of lacguer component-reinforced natural yarns and lacguer component-reinforced textile using thereof
KR101848434B1 (en) * 2018-02-19 2018-04-12 황길봉 dye for natural dyeing composition having lacquer and antibiotics dyed cloth using the same

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR960009775A (en) 1994-08-12 1996-03-22 김광호 Standard clock selection device and control method of local exchange
JP2004100083A (en) * 2002-09-09 2004-04-02 Tasuku:Kk Functional fabric
JP2010065368A (en) * 2008-08-12 2010-03-25 Yyl:Kk Method and apparatus of producing antibacterial and antiviral fiber
KR20120105335A (en) * 2011-03-15 2012-09-25 박중호 Anti-bacterial the fibers process
KR20160147496A (en) * 2015-06-15 2016-12-23 백익현 Manufacturing method of lacguer component-reinforced natural yarns and lacguer component-reinforced textile using thereof
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