KR101915787B1 - Composition for hair of oil in water type - Google Patents

Abstract

An object of the present invention is to provide a composition for an underwater type hair having a high level of styling force, quick-drying property and foot color feeling, and sufficient stability over a conventional underwater type temporary salt base.
The composition for an underwater type hair of the present invention comprises 30 to 60% by mass of water, 3.5 to 30% by mass of an oil fraction, a pearl powder and 1% by mass or more of a coloring agent (excluding a coloring agent contained in a pulp powder) And a surfactant, wherein a mass ratio of the pearl powder and the surfactant is 3: 1 to 1: 1.

Description

TECHNICAL FIELD [0001] The present invention relates to a composition for an underwater type hair,

TECHNICAL FIELD [0001] The present invention relates to a composition for an underwater type (oil-in-water) hair, and more particularly, to a composition for hair for hair dyeing and hair straightening.

[0002] In recent years, an increase in the number of white hair dyeing demand due to an aging of hair, and the fashion of color hair have been popular. Salt flakes are classified as temporary flocks, semi-permanent flocks and permanent flocks in view of the persistence of color in the hair. Semi-permanent salt fresheners and permanent salt fresheners have the advantage of not being well colored even if they are shampooed, but the operation is complicated. On the other hand, the temporary salt base is advantageous in that it can be easily stained by simply applying it to a desired site, and is suitable for use before going out. In addition, since the temporary lather can be easily washed with shampoo, it is convenient when it is difficult to change the color of the painted color when the painted color is dissatisfied, and the demand in the market is also high.

[0003] Conventionally, a temporary salt fountain has been used as a coating agent for fixing a coloring material to hair and preventing secondary contamination adherence to clothes, a coloring material mainly including an inorganic pigment having high hiding power, , And a colored film is formed on the hair to cover the white hair or the sprayed state filled with the aerosol can with the aerosol can is applied to the surface of the hair , And then fixed by drying.

On the other hand, a conditioner is used to trim hair, and various properties such as a liquid state, a gel state, a cream state and a solid state are known. In order to exert its main function, the repulsive force, a film-forming polymer or an oil agent in a solid state at room temperature is often used. Particularly, the water-in-oil type correcting agent has an advantage that it can be easily applied and can be uniformly applied to the hair, has a good retentive property such as a setting retention ability, a light feeling or a three-dimensional feeling can be given to the hair, (For example, Patent Documents 1 and 2).

[0005] It is also known that the temporary salt base is an underwater type (for example, Patent Documents 3 and 4). The underwater type temporary glue spray can be applied and straightened with a finger, is excellent in usability, and can be combined with a styling force to some extent by the compounding agent.

[0006] Japanese Patent Publication No. 4676902 Japanese Laid-Open Patent Publication No. 2015-98446 Japanese Patent Publication No. 3071396 Japanese Patent Application Laid-Open No. 2004-10540

However, the coating agent such as an emulsion resin is unstable such as coagulation at a low temperature and coalescence of an emulsion under a high temperature environment, and the formulation itself is liable to become unstable, It was difficult to increase the styling power. In addition, in the case of an underwater type, emulsion stability may be impaired, and it is difficult to improve the quick drying property because it is impossible to form a volatile solvent that is quick-drying such as ethanol. Moreover, in the case of an underwater type, it is difficult to stably formulate a powder that gives sufficient coloration on the hair because the powder absorbs oil.

The present invention has been made in view of the above circumstances, and it is an object of the present invention to provide a composition for hair type underwater having a high styling force, quick-drying property and foot color feeling and sufficient stability.

SUMMARY OF THE INVENTION [0009] In order to solve the above problems, the present inventors have intensively studied and, as a result, have found that a water-in-oil type composition containing a specific amount of water can be obtained by blending a specific amount of pearl powder with another coloring agent At the same time, by setting the mass ratio of the pulp powder and the surfactant to a specific range, it is possible to sufficiently secure the dispersibility and the storage stability of the underwater type composition while raising the styling power, quick drying property and color development feeling The present invention has been accomplished on the basis of these findings.

That is, the present invention provides a process for producing a pearlescent material, which comprises mixing 30 to 60% by mass of water, at least 1% by mass of an emulsion, 3.5 to 30% by mass of a pearl powder and a colorant (excluding colorants contained in the pulp powder) Wherein the weight ratio of the pearl powder to the surfactant is from 3: 1 to 1: 1.

The composition for an underwater type hair according to the present invention can exhibit a higher styling power, quick drying property and coloring feeling than a conventional underwater type temporary paste, and can have sufficient stability.

The water-based hair composition of the present invention preferably contains 2% by mass or more of an anionic surfactant as a surfactant from the viewpoint of compatibility with quick drying, styling power, coloring property and usability at a higher level.

According to the present invention, it is possible to provide a composition for an underwater type hair having a high level of styling force, quick-drying property and foot color feeling, and sufficient stability over conventional underwater type temporary paste preparations.

The composition for hair type according to the present embodiment includes water, an emulsion, a pearl powder, a coloring agent (except for the coloring agent contained in the pulp powder), and a surfactant.

The water to be blended in the composition for underwater type hair of the present embodiment is not particularly limited as long as it contains water as a main component.

The blending amount of water in the composition for hair type underwater according to the present embodiment may be 30 to 60 mass% based on the total amount of the composition (total amount). By blending water in this range, it is possible to improve the styling ability and fast drying property while maintaining a sufficient emulsified state.

From the viewpoints of quick drying property and styling power, the blending amount of water is preferably 58 mass% or less, and more preferably 53 mass% or less. From the viewpoints of dispersibility and storage stability, the amount of water to be blended is preferably 35 mass% or more, and more preferably 40 mass% or more.

Examples of the emulsion include wax, candelilla wax, carnauba wax, rice bran wax, lanolin, wax, spermaceti, shellac, Waxes such as cotton wax, wood wax, hydrogenated jojoba oil, ozocerite, ceresin, paraffin wax, polyethylene, microcrystalline wax, wax, and petrolatum; myristic acid, palmitic acid, stearic acid, hydroxystearic acid, lauric acid, lanolin acid, behenic acid, (behenic acid), and higher fatty acids such as myristyl alcohol, cetyl alcohol, stearyl alcohol, chimyl alcohol, behenyl alcohol, batyl alcohol and cetostearyl alcohol Alcohols, chain-like polysiloxanes, cyclic polysiloxanes, Silicone oils such as silicone resins, silicone rubbers, various modified polysiloxanes, and acrylic silicon, which form a three-dimensional network structure, fluorine-based oils such as perfluoropolyether, perfluorodecane and perfluorooctane, . The emulsions may be used singly or in combination of two or more kinds.

The blending amount of the emulsion in the water-in-oil type hair composition of the present embodiment is not particularly limited, but from the standpoint of the styling power and stability, the mass ratio of water to emulsion is preferably 1: 0.2 to 1: 0.6 .

The pearl powder can be used without particular limitation as long as it is a powder having pearl luster generally used for general purposes. Examples of such powders include titanium oxide, iron oxide-coated titanium oxide mica, iron oxide-coated titanium oxide mica, iron oxide-coated titanium oxide mica, iron oxide-coated titanium oxide mica, carmine-coated titanium oxide mica, Iron Blue Coated Titanated Mica), iron oxide / camphor mica titanium, iron oxide mica titanium, iron oxide / iron oxide mica titanium, chromium oxide treated mica titanium, titanium black titanium oxide mica titanium, synthetic mica, titanium oxide coated mica, glass powder Glass powder, titanium oxide-coated glass powder, polyethylene terephthalate, polyester film laminated powder, mica piece, acrylic resin-coated aluminum powder (containing a coloring material) Titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, oxy Bismuth chloride, bismuth chloride, fish flakes, aluminum flake, stainless flake, titanium oxide coated alumina, pearl shell, gold foil, gold vapor deposition resin film and metal vapor deposition resin film. The pulp powder may be used singly or in combination of two or more.

The blended amount of the pulp powder in the composition for hair type underwater according to the present embodiment may be 3.5 to 30 mass% based on the total amount of the composition. By blending the pearl powder in such a range, it is possible to improve the color feeling on the hair while maintaining a sufficient emulsified state.

[0022] From the viewpoint of dispersibility, the blended amount of the pulp powder is preferably 30 mass% or less, and more preferably 28 mass% or less. From the viewpoint of improving usability, styling ability, fast drying property and coloring feeling to a higher level, the blended amount of the pulp powder is preferably 7% by mass or more, more preferably 9% by mass or more.

Examples of the colorant include inorganic pigments such as carbon black, titanium oxide, titanium black oxide, iron oxide black, iron oxide yellow, iron oxide, bengala, , Red No. 104, red No. 106, red No. 227, yellow No. 4, yellow No. 5, yellow No. 203, green No. 3, green No. 201, green No. 205, blue No. 1, blue No. 2, blue No. 202 Red No. 202, red No. 207, yellow No. 201, No. Yellow No. 204, No. No. No. Yellow No. 205, No. No. No. 202, green No. 205, , Blue No. 201, Blue No. 204, Orange No. 201, Orange No. 204, and Purple No. 201. The colorant may be used alone or in combination of two or more.

The blending amount of the coloring agent in the composition for hair type in the embodiment of the present invention may be 1% by mass or more based on the total amount of the composition, and from the viewpoint of compatibility between the coloring property and the dispersibility or the storage stability at a high level , Preferably 1 to 10 mass%, and more preferably 3 to 9 mass%.

In the present embodiment, from the viewpoint of the coloring property, it is preferable that 1 mass% or more of the inorganic pigment is contained in an amount of 1 mass% or more based on the total amount of the composition. From the viewpoint of the hiding property, titanium oxide, iron oxide, By mass or more of at least one coloring agent selected from the group consisting of

Examples of the surfactant include a nonionic surfactant, an anionic surfactant, a cationic surfactant and a positive surfactant.

Examples of the nonionic surfactant include POE alkyl ethers such as polyoxyethylene (POE) cetyl ether, POE alkylphenyl ethers, POE polyoxypropylene alkyl ethers, sorbitan fatty acid esters, polyethylene Glycol fatty acid esters, and sucrose fatty acid esters.

Examples of the anionic surfactant include sodium lauryl sulfate and sodium POE lauryl ether sulfate. In addition, a higher fatty acid anionic surfactant can also be incorporated. As an anion of a higher fatty acid, a higher fatty acid salt and / or a higher fatty acid and an alkali for neutralizing the higher fatty acid salt are added so as to include one or more of the corresponding anion.

Examples of the cationic surfactant include lauryltrimethylammonium chloride and stearyltrimethylammonium chloride. Specific examples of the amphoteric surfactant include 2-undecyl-N, N, N- (hydroxyethylcarboxy Methyl) -2-imidazoline sodium, and the like.

[0030] The surfactant may be used singly or in combination of two or more.

The blending amount of the surfactant in the water-in-oil type hair composition of the present embodiment can be set so that the mass ratio of the pearl powder and the surfactant is 3: 1 to 1: 1. In this case, it is possible to secure sufficient dispersibility and storage stability while sufficiently raising the styling ability, fast drying property and color development feeling of the underwater type hair composition.

In the present embodiment, from the viewpoint of stability, it is preferable that the mass ratio of the pearl powder and the surfactant is 2: 1 to 1: 1.

The water-in-oil type hair composition of the present embodiment preferably contains 2% by mass or more of an anionic surfactant as a surfactant from the viewpoint of compatibility with quick drying, styling power, coloring property and usability at a higher level, More preferably 2.5% by mass or more, and still more preferably 3% by mass or more.

The composition for an underwater type hair of the present embodiment may contain other components besides water, an oil agent, a pearl powder, a colorant and a surfactant. Examples of the other components include oil, moisturizing agent, preservative, antioxidant, ultraviolet absorber, medicine, perfume, alcohol, powder, pH adjuster, salt, gelling agent, defoamer Defoaming agent), a coating agent, a thickening agent, and the like.

The composition for an underwater type hair of the present embodiment can be used for applications such as temporary hair hair, regular hair, treatments, and permanent hair dye.

The composition for an underwater type hair of the present embodiment can be produced, for example, according to the following procedure. The components of water, emulsion, pearl powder, colorant and surfactant and, if necessary, other components are mixed and emulsified by a phase inversion emulsification method using a homomixer, A hair-like composition can be prepared. The mixing and emulsification may be performed separately or simultaneously.

[Example]

Hereinafter, the present invention will be described more specifically by way of examples, but the present invention is not limited to the following examples.

(Examples 1 to 8 and Comparative Examples 1 to 11)

And a composition for an underwater type hair having a composition (mass%) shown in Tables 1 to 3 was prepared. Concretely, a mixture obtained by mixing an emulsion, a surfactant, a pulp powder and a colorant is mixed and emulsified with a mixture of components other than the above, which has been heated to 85 to 90 ° C in advance, To obtain an underwater type hair composition.

Details of each component shown in the table are as follows.

Mica titanium A: Timiron Supersilk MP-1005 (Merck)

Mica titanium B: Prestige Yellow Gold (manufactured by SUDARSHAN CHEMICAL INDUSTRIES LIMITED)

Black iron oxide coated mica Titanium A: Colorona Patina Silver (manufactured by Merck Ltd.)

Binkala coated mica Titanium: Colorona Gold Plus MP-25 (manufactured by Merck Ltd.)

Black iron oxide coated mica titanium B: Colorona Mica Black (manufactured by Merck Ltd.)

<Evaluation Method of Composition for Underwater Type Hair>

The following evaluations were carried out using the compositions for hair type in water obtained in Examples 1 to 8 and Comparative Examples 1 to 11 as samples.

[0041] [Quick-drying]

0.3 g of the sample was applied from the tip of a black hair (10 cm in length and 1 g in weight) to 5 cm and left at room temperature (25 ° C ± 1 ° C). When the hair bundle was touched, The time until the sample was not measured was measured and evaluated according to the following criteria. The sample was observed by observing it with eyes.

◎: Drying time is within 20 seconds.

○: Drying time is over 20 seconds and less than 1 minute.

△: Drying time is over 1 minute and less than 3 minutes.

X: Drying time exceeds 3 minutes.

[Styling power, intensity of feeling, color development]

From the panelists of 20, answers were received regarding whether or not the hair was good for the styling ability (ease of hair straightening), the strength of the feeling to be felt, and the color development.

◎: More than 18 people answered that they are good

○: 14 or more, less than 18 responded that they were good

△: More than 10 persons, less than 14 persons answered that it is good

X: Less than 10 people answered that it is good

[Storage Stability]

The sample was placed in a container and left for 1 month at room temperature (25 DEG C +/- 1 DEG C). The appearance of the sample was visually observed and evaluated.

○: Abnormal (abnormal) is not seen

X: Separation visible

[Dispersibility]

The state of the sample (O / W emulsion) immediately after the preparation was visually observed, and the presence or absence of the precipitation, aggregation, emulsion particle breakage or coalescence of the pulp powder, colorant and emulsion was checked, Respectively.

○: No aggregates or sediments are seen

X: Agglomerates or sediments are seen

[Table 1]

[Table 2]

[Table 3]

[Table 4]

[Table 5]

As shown in Table 4, it was confirmed that the compositions for hair type in water of Examples 1 to 8 were satisfactory in all of strength, color development, fast drying, styling power, storage stability and dispersibility.

On the other hand, the composition for hair type in water of Comparative Example 4, in which the ratio of the pulp powder to the surfactant was less than 1, was inferior in terms of the feeling of hung feeling, color development, storage stability and dispersibility, In Comparative Example 5 and Comparative Example 6, in which the mass ratio of the pulp powder to the surfactant exceeds 3 and the blend amount of the pulp powder exceeds 30 mass%, the result is inferior in storage stability and dispersibility .

The composition for an underwater type hair of Comparative Example 10 in which the mass ratio of the pulp powder to the surfactant is in the range of 3: 1 to 1: 1, but the blending amount of water is more than 60% by mass, And styling power. In addition, the composition for hair type in water of Comparative Example 11, in which the blending amount of the coloring agent was less than 1% by mass, did not achieve sufficient coloring.

Claims (2)

1 mass% of water, 30 to 60 mass% of water, 3.5 to 30 mass% of an oil agent, a pearl powder, and a coloring agent (except for the colorant contained in the pulp powder) And a surfactant, wherein a mass ratio of the pulp powder to the surfactant is 3: 1 to 1: 1,
A composition for an underwater type (oil-in-water type) hair. The method according to claim 1,
And 2% by mass or more of an anionic surfactant as the surfactant.
A composition for underwater type hair.