KR101905673B1 - Biocide composition comprising carbamate compound and controlling method using the same - Google Patents

Abstract

The present invention relates to a biocidal composition comprising a carbamate compound and a method of controlling the same, which comprises a pyrethroid compound, a solvent and a carbamate compound to form iodopropynyl butylcarbamate (3 (2-propynylbutyl carbamate) and 3- (N, N-butyl-N-acetyl) aminopropionic acid ethyl ester, which are effective for controlling a wide range of fungi, And a method for controlling the same.

Description

TECHNICAL FIELD The present invention relates to a biocide composition containing a carbamate compound and a method for controlling the same,

The present invention relates to a biocidal composition and a method of controlling the same, and more particularly to a biocidal composition comprising 3-iodo-2-propynylbutyl carbamate and 3- (Nn-butyl-N-acetyl) aminopropionic acid The present invention relates to a biocidal composition which is low in toxicity to human body including ethyl ester and which has an improved antibacterial activity and is effective for controlling a wide range of fungi, and a method of controlling the same.

Biocides are chemical or biological substances used to destroy, prevent or harm harmful organisms (life forms). The US Environmental Protection Agency (EPA) has developed a variety of toxicological and biocidal products for biocidal products, including preservatives, pesticides, disinfectants and pesticides used in the control of organisms that harm or damage natural or manufactured products as well as human or animal health It is defined as a substance group. Although the US EPA definition includes plant protection products and some veterinary medicines, there are roughly two definitions of the two definitions. The terms biocide and insecticide are interchanged, in order to avoid confusion with plant protection products, the insecticide clearly refers to food and feed materials, including both biocidal and plant protection products, Food and non-food materials.

However, because of their inherent properties and usage patterns, biocides may adversely affect humans, animals, and the environment and should be used with extreme caution. In addition, biocides are often composed of a mixture of one or more active substances together with a coagulant such as a stabilizer, an antiseptic, and a colorant. Because these substances can work together to produce complex effects, the risk assessment for each of these substances alone can underestimate the actual risk of the product as a whole. In addition, when the amount of the biocidal agent is too small, the number of the bacteria is small, and the effect of controlling the fungus is small.

In order to solve such problems, there has been recently a prior art relating to a mixture containing phentlufen and a method of treating the same. However, no specific mixtures have been described including a specific weight ratio of 3-iodo-2-propynylbutyl carbamate and 3- (N-n-butyl-N-acetyl) aminopropionic acid ethyl ester.

Therefore, in order to overcome the above-mentioned problems, it is necessary to use an environmentally friendly biocide, which is well-mixed with other materials and works together with other materials to exhibit harmful complex effects, And a control method using the same.

KR 10-1397947 KR 10-1533168

SUMMARY OF THE INVENTION It is an object of the present invention to solve the above-mentioned problems of the prior art and the technical problems required from the past.

It is an object of the present invention to provide an environmentally friendly biocidal agent and a method of controlling the same through experiments, and it is well-formulated with other materials and works with other materials to prevent harmful complex effects, To provide a constant weight ratio of 3-iodo-2-propynylbutyl carbamate, 3- (Nn-butyl-N-acetyl) aminopropionic acid ethyl ester and carbamate compounds effective in controlling fungi have.

It is still another object of the present invention to provide a biocidal composition comprising a carbamate compound and a method of controlling the same.

To achieve these objects, a biocidal composition comprising a carbamate-based compound of the present invention and a method of controlling the biocide composition,

Pyrethroid-based compounds, solvents, and carbamate-based compounds.

In one preferred embodiment of the present invention, the biocidal composition comprising the carbamate-based compound may further comprise 3- (N-n-butyl-N-acetyl) aminopropionic acid ethyl ester and a preservative.

In one preferred embodiment of the present invention, the carbamate-based compound is selected from the group consisting of 3-iodo-2-propynylbutyl carbamate, Bendiocarb, Isoprocarb, Carbaryl ) And Propoxur. ≪ / RTI >

In one preferred embodiment of the present invention, 0.1 to 20 parts by weight of a carbamate-based compound, 0.1 to 10 parts by weight of a pyrethroid-based compound, 3- (Nn-butyl- N-acetyl) aminopropionic acid ethyl ester and 0.1 to 10 parts by weight of a preservative.

In one preferred embodiment of the present invention, the weight ratio of 3- (Nn-butyl-N-acetyl) aminopropionic acid ethyl ester to the pyrethroid compound is from 1: 1 to 1:30, The weight ratio of 3- (Nn-butyl-N-acetyl) aminopropionic acid ethyl ester to 1: 1 to 1:30 can be used.

In one preferred embodiment of the invention, the preservative is selected from the group consisting of n-alkyl dimethyl benzyl ammonium chloride, benzethonium chloride, Cetrimonium chloride and Cetrimonium bromide ). ≪ / RTI >

In one preferred example of the present invention, 0.1 to 20 parts by weight of a triazole-based compound may be further added to 100 parts by weight of the biocidal composition.

In one preferred embodiment of the present invention, the pyrethroid-based compound comprises at least one of Tetramethrin, Allethrin, Phenothrin, and Metofluthrin, .

In one preferred embodiment of the present invention, the fungi applied to the biocidal composition include Aspergillus niger black fungus, Trichoderma viride blue mushroom fungus, Penicillium sp. Blue mold fungus, Rhizopus sp. Aureobasidium sp. Black fungus and Trametes versicolor white rot fungus.

In one preferred embodiment of the present invention, the biocidal composition may be diluted 1 to 100 times by dilution volume.

INDUSTRIAL APPLICABILITY As described above, the biocide composition containing a carbamate compound according to an embodiment of the present invention provides an environmentally friendly biocidal agent and a method of controlling the same using an experiment.

In addition, the biocidal composition containing a carbamate compound according to an embodiment of the present invention is effective in providing a biocidal composition having low toxicity to human body.

In addition, the biocidal composition containing a carbamate compound according to an embodiment of the present invention has an improved antibacterial activity and is effective for controlling a wide range of fungus.

In addition, the biocide composition comprising a carbamate compound according to an embodiment of the present invention may contain a pyrethroid compound, a 3- (Nn-butyl-N-acetyl) aminopropionic acid ethyl ester and a carbamate- .

In addition, the biocide composition containing a carbamate compound according to an embodiment of the present invention provides a biocidal composition including a carbamate compound and a method of controlling the same.

The biocide composition containing the carbamate compound according to an embodiment of the present invention can be controlled by diluting it with a diluent and then treating it with wood or soil. Even if treated with a pigment-coated wood, Which can maintain a stable color difference value without stain and color change, can be used to maintain the color of pigment-coated wood, especially monochrome.

1 is a photograph showing an experimental result of antifungal activity against Aspergillus niger black fungus according to Experimental Example 1. Fig.
FIG. 2 is a photograph showing the results of an antifungal activity test on Trichoderma viride blue mushroom strain according to Experimental Example 1. FIG.
Fig. 3 is a graph showing the results of Penicillium sp. This photograph shows the result of the antifungal activity test against the blue fungus.
Fig. 4 is a graph showing the effect of Rhizopus sp. This is a photograph showing the result of the antifungal activity test against the rot fungus.
Fig. 5 is a graph showing the results of the measurement of Aureobasidium sp. This photograph shows the result of the antifungal activity test for black yeast.
6 is a photograph showing the results of an antifungal activity test on Trametes versicolor white rot fungi according to Experimental Example 1. FIG.
Fig. 7 is a graph showing the results of the first-time trial of the polyols according to Experimental Example 2. Fig.
FIG. 8 is a graph showing the results of a two-time trial of the polyol according to Experimental Example 2. FIG.
FIG. 9 is a graph showing the results of the experiment for three times of the polyol according to Experimental Example 2. FIG.
10 is a graph showing the average color difference of three times of the polyols according to Experimental Example 2. Fig.
11 is a view showing the result of the first glue experiment according to Experimental Example 2. Fig.
12 is a diagram showing the results of the experiment of the glue two-fold test according to Experimental Example 2. Fig.
Fig. 13 is a diagram showing the results of the experiment of three times glue according to Experimental Example 2. Fig.
14 is a graph showing the average color difference of three times of glue according to Experimental Example 2. FIG.
15 is a diagram showing a chromaticity diagram according to Experimental Example 2. FIG.

BRIEF DESCRIPTION OF THE DRAWINGS The above and other objects, features and advantages of the present invention will be more apparent from the following detailed description taken in conjunction with the accompanying drawings, in which: FIG. In the following description of the present invention, a detailed description of known functions and configurations incorporated herein will be omitted when it may make the subject matter of the present invention rather unclear. The terms described below are defined in consideration of the structure, role and function of the present invention, and may be changed according to the intention of the user, the intention of the operator, or the custom.

The present invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. These embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art to which the present invention pertains, It is only defined by the scope of the claims. Therefore, the definition should be based on the contents throughout this specification.

Throughout the specification, when an element is referred to as " comprising ", it means that it can include other elements as well, without excluding other elements unless specifically stated otherwise.

Also, the term " control " in this specification means to include prevention, avoidance as well as elimination and death of bacterial infection.

As described above, the conventional biocidal agents have fewer kinds and numbers of microorganisms to be applied, and have problems such as harmful to humans and animals according to specific weight ratios.

Thus, the present inventors have found through experimentation that a pyrethroid compound, ethyl 3- (N-butyl-N-acetyl) aminopropionic acid ester and 3-iodo-2-propynylbutyl carbamate It is possible to increase the bactericidal effect or the preservative effect through bactericidal inhibition while reducing harm to humans and animals. Thus, the present invention has been completed. Further, stability of the present invention was secured through the stability test for monochromatic pigments.

Specifically, a biocidal composition comprising a carbamate compound according to the present invention will be described below.

First, a biocide composition containing a carbamate compound according to an embodiment of the present invention includes a carbamate compound, and the carbamate compound is a compound having a structure such as carbamic acid, -Methylcarbamate, an alkyl-N-phenyl carbamate which is a herbicide, and dicycamic acid which is a fungicide. Insecticide is inhibited by acetylcholinesterase, herbicide is inhibited by cell division, and sterilization is by mitosis (enzyme inhibition) of vegetable pathogens, and toxicity to animals is relatively weak. Carbamate-based insecticides act on each site as well as organophosphorus to inhibit both intrinsic and virulent cholinesterase and show toxic effects. However, the inhibitory action of cholinesterase by carbamate-type insecticide is reversible and relatively less toxic than organic phosphorous. The symptoms of poisoning are the same as those of organic phosphorus, but carbamate insecticides do not pass through the blood-brain barrier, so headache, respiratory paralysis, and central nervous system symptoms are relatively weak. Treatment of addiction is also very effective atropine.

The carbamate-based compounds of the present invention can be prepared by reacting 3-iodo-2-propynylbutyl carbamate, Bendiocarb, Isoprocarb, Carbaryl and Propoxur, Or the like. Preferably 3-iodo-2-propynylbutyl carbamate (IPBC). IPBC is a water-soluble preservative used worldwide in the paint and coatings, wood preservatives, personal care and cosmetics industries. IPBC, a carbamate-based biocide, was invented in the 1970s and has a long history as an antifungal technology. IPBC was first developed for use in the paint and coating industry as a dry film preservative to protect domestic and exterior coatings from the propagation of fungi. IPBC is generally used at a very low level for a wide range of fungi and is used in a variety of indoor and outdoor coating formulations worldwide. IPBC is an effective disinfectant at very low concentrations in cosmetics and other products, and the sensitivity of the person tested is very low.

In addition, Bendiocarb is a white solid, insoluble in water and used as a contact pesticide. Isoprocarb is an insecticide developed in 1970 under the name of 'Etroporphine', also known as Mipcine or MIPC. It does not dissolve in water but slightly soluble in acetone and methineol. Isoprocarb is a contact pesticide and is used as an antiseptic agent for brown rice bran and leucocyte of rice and can be mixed with most pesticides. However, the prolonged spraying of 10 days or less with the paddy weed medicine propafil will cause weakness, and caution should be exercised. Carbaryl is well soluble in most polar solvents such as dimethylformamide and dimethyl sulfoxide. Light · It is a stable compound for heat and hydrolysis and has no metal corrosivity. It is a contact pesticide with a slight permeability and is an effective insecticide effective for pests such as fruit trees and vegetables. Propoxur is a white to yellowish crystalline powder that is faint and unusual odor and is used as an insecticide.

The carbamate-based compound may include, but is not limited to, 0.1 to 20 parts by weight, preferably 1 to 10 parts by weight, more preferably 5 to 7 parts by weight, based on the total weight of the biocidal composition. When the carbamate compound is contained in an amount of less than 0.1 part by weight, there is a problem that the kind and number of the applied species are not sufficient, and sufficient control effect is not exerted. When the carbamate compound is contained in an amount exceeding 20 parts by weight, Substances can exhibit harmful complex effects together, and are not only detrimental to the human body due to excessive control effects, but also cause residues to be left intoxicated. Accordingly, when the carbamate-based compound is contained in an amount of 0.1 to 20 parts by weight based on the total amount of the biocidal composition, it is well-mixed with other materials and does not exhibit harmful complex effects by acting with other materials, Can be improved to provide an environmentally friendly biocide effective for controlling a wide range of fungi.

Pyrethroid-based compounds refer to pyrethrins or derivative compounds thereof, which are active ingredients of pyrethrums. Pyretrin-I and pyretrin-II, both of which are contact toxic to insects. In addition to pyrethrin, insecticides obtained from the bug bug include cinerin I, Ⅱ, jasmonine I and Ⅱ, which are collectively called pyrethroid. Although Permethrin has generally excellent residual efficacy, it has a very low toxicity to human body. Pyrethroids are known to be useful in the treatment of allergic diseases such as allethrin, bifenthrin, cyfluthrin, cypermethrin, cyphenothrin, deltamethrin, Esfenvalerate, Etofenprox, Fenpropathrin, Fenvalerate, Flucythrinate, Flumethrin, Imiprothrin, Lambda- Lambda-Cyhalothrin, Metofluthrin, Permethrin, Prallethrin, Resmethrin, Silafluofen, tau-Fluvalinate, -Tetramethrin, Tralomethrin, and Transfluthrin, which are known to those skilled in the art.

The pyrethroid compound of the present invention may preferably include at least one of tetramethrin, allethrin, phenothrin and metofluthrin, , And more preferably metofluthrin. Specifically, metofluthrin is a compound that is a compound of the formula (I), which is 2,3,5,6-tetrafluoro-4- (methoxymethyl) benzyl (1R, 3R) -2,2- Propyl-1-enyl) cyclopropanecarboxylate [2,3,5,6tetrafluoro-4- (methoxymethyl) benzyl (1R, 3R) -2,2- ) cyclopropanecarboxylate], and is represented by the following formula (1):

[Chemical Formula 1]

.

.

In addition, Tetramethrin is a white crystalline solid, a powerful synthetic insecticide based on pyrethroids. It is generally used as an insecticide and affects insect nervous system. Alethrin (Allethrin) is an allyl homolog of the natural insecticide Cinein I, which was synthesized by M. Schechter, N. Green and F. La Forge in 1949. It does not dissolve in water and dissolves well in many organic solvents. Like the natural pyrethrins, it exhibits fast-acting insecticidal action against houseflies and the like, and is almost non-toxic to humans, livestock, and plants. Phenothrin, also called sumithrin and d-phenothrin, is a synthetic pyrethroid that kills adult fleas and ticks.

The pyrethroid compound may include, but is not limited to, 0.1 to 10 parts by weight, preferably 0.5 to 5 parts by weight, more preferably 0.7 to 3 parts by weight, based on the total weight of the biocide composition. When the pyrethroid compound is contained in an amount of less than 0.1 part by weight, there is a problem that the kind and number of the applied individual are not sufficient, and sufficient control effect is not exhibited. When the pyrethroid compound is contained in an amount exceeding 10 parts by weight, There is a problem that other substances may exhibit harmful combined effects and are harmful to the human body due to the excessive control effect and also cause residues to remain and lead to an addiction phenomenon. Therefore, the pyrethroid- When 10 parts by weight of the composition is contained, the composition is well-mixed with other materials and works together with other materials to provide an environmentally-friendly biocide effective for controlling a wide range of fungi, .

The biocidal composition comprising a carbamate compound according to an embodiment of the present invention comprises 3- (Nn-butyl-N-acetyl) aminopropionic acid ethyl ester, wherein the 3- (Nn-butyl- ) Aminopropionic acid ethyl ester is a synthetic insecticide classified as biopesticide by EPA and is effective against mosquitoes, ticks, flies, fleas and harmful to humans and animals. 3- (N-N-Butyl-N-acetyl) aminopropionic acid ethyl ester prevents insect access without affecting the insect itself. It is safe as a skin-friendly ingredient and does not accumulate in living organisms or the environment. In particular, 3- (N-N-butyl-N-acetyl) aminopropionic acid ethyl ester has received the U grade, which is considered to be the least dangerous by WHO, to be used in global infant lotion brands. Genetic toxicity test Mutation, chromosome test No abnormality was found. No abnormality was found in fetal and early embryogenesis test and second generation toxicity test.

Specifically, 3- (N-n-butyl-N-acetyl) aminopropionic acid ethyl ester is represented by the following formula 2:

(2)

The ethyl 3- (N-butyl-N-acetyl) aminopropionic acid ester is contained in an amount of 1 to 50 parts by weight, preferably 10 to 30 parts by weight, more preferably 17 to 23 parts by weight, based on the total amount of the biocide composition And the weight ratio of 3- (Nn-butyl-N-acetyl) aminopropionic acid ethyl ester to the pyrethroid compound may be 1: 1 to 1:30, (N-butyl-N-acetyl) aminopropionic acid ethyl ester may be in a weight ratio of 1: 1 to 1:30, but is not limited thereto. When the amount of the ethyl 3- (N-butyl-N-acetyl) aminopropionic acid ester is less than 1 part by weight, the kind and the number of the applied individual can not be sufficient, If it is contained in the amount of more than 1 part by weight, other substances in the biocide may exhibit harmful combined effects, and it is not only harmful to the human body due to the excessive control effect, -Butyl-N-acetyl) aminopropionic acid ethyl ester is contained in an amount of 1 to 50 parts by weight based on the total amount of the biocidal composition, it is blended with other materials and works together with other materials, It is possible to provide an eco-friendly biocidal agent which is effective in controlling a wide range of fungi by improving the antimicrobial activity with less toxicity.

In addition, the biocidal composition comprising a carbamate compound according to an embodiment of the present invention may contain a preservative. The preservative may comprise at least one of n-alkyl dimethyl benzyl ammonium chloride, benzethonium chloride, Cetrimonium chloride and Cetrimonium bromide. have.

The preservative of the present invention may more preferably comprise n-alkyl dimethyl benzyl ammonium chloride, wherein benzalkonium chloride, also known as BZK, BKC, BAC, alkyldimethylbenzylammonium chloride and ADBAC, is a quaternary ammonium It is an organic salt classified as a compound. It has three main categories of use: biocides, preservatives and phase transfer agents. ADBAC is a mixture of alkylbenzyldimethylammonium chloride wherein the alkyl groups have varying even alkyl chain lengths. Benzalkonium chloride is a less harmless substance in the human body. In the present invention, n-alkyl dimethyl benzyl ammonium chloride preferably contains C12-16 alkyl dimethylbenzyl ammonium chloride, which is preferably a fungus, especially a black mold (aspergillus niger ) Or blue mushroom (trichoderma viride) to inhibit the bactericidal effect or to increase the preservative is a substance. Alternatively, a small amount of C12-16 alkyldimethylamine may be included. They are preferably present in a state of being dissolved in a mixed solvent of ethanol and water (weight ratio of C12-16 alkyldimethylbenzyl ammonium chloride and / or C12-16 alkyldimethylamine: mixed solvent = 6: 1 to 3: 1) , But is not limited thereto. Specifically, C12-16 alkyl dimethyl benzyl ammonium chloride is represented by the following formula (3): < EMI ID =

(3)

Also, C12-16 alkyldimethyl amines are represented by the following formula (4): < EMI ID =

[Chemical Formula 4]

In addition, benzethonium chloride is used as a sterilizing aid, deodorant and preservative. Cetrimonium chloride is used as a preservative, antistatic agent, local disinfectant and regulator. Cetrimonium bromide is an effective disinfectant for bacteria and fungi and is one of the components of the cetrimide disinfectant. In addition to being used in hair conditioners as an antistatic agent and softener, it is also used in the laboratory for DNA extraction.

The preservative may include, but is not limited to, 0.1 to 10 parts by weight, preferably 0.5 to 5 parts by weight, more preferably 0.7 to 3 parts by weight, based on the total weight of the biocidal composition. When the preservative is contained in an amount of less than 0.1 part by weight, the biocidal agent may be deteriorated. When the preservative is included in an amount exceeding 10 parts by weight, other substances in the biocidal agent may exhibit harmful combined effects, It is harmful to the human body and there is a problem that the residue is left to cause an addiction phenomenon. Therefore, when the preservative is included in 0.1 to 10 parts by weight based on the total amount of the biocide composition, it is well mixed with other materials, It is possible to provide an eco-friendly biocidal agent which is effective for controlling a wide range of fungi by improving the antimicrobial activity while showing no harmful complex effect and being less toxic to the human body.

The solvent may include at least one of a thiophene compound, dichloromethane, chloroform, benzene, diethyl ether and tetrahydrofuran. Thiophene compounds are insoluble in water, but dissolve in most organic solvents such as ethanol and ether. It is contained in coal tar, and because it has a boiling point similar to that of benzene, it is difficult to separate by distillation. Therefore, it is contained in industrial benzene in a small amount. It is produced by the action of trisodium phosphate on sodium succinate, but it is synthesized industrially from butane and sulfur. It is used as a raw material for synthesis of solvents and dyes.

Dichloromethane is a compound obtained by chlorinating methyl chloride or reducing chloroform with zinc and acetic acid. Reaction solvent, refrigerant, etc. Chloroform is used as an insecticide and a fungicide, and is also used as a solvent for extraction and as an analytical reagent. Industrially, it is used as a solvent such as oil and fat, synthetic resin, rubber, alkaloid and penicillin. Benzene is contained in a large amount in gas and tar generated in petroleum reforming oil and coal coal. It is a volatile colorless liquid belonging to aromatic hydrocarbons. It is soluble in most organic solvents but does not dissolve in water. Solvents, industrial raw materials, medicines, and agricultural chemicals. Diethyl ether is widely used as a solvent because it dissolves most organic compounds well. Tetrahydrofuran is a structure in which diethyl ether, which is often used as a solvent for organic compounds, is considered to form a ring at the carbon end, and has the property of ether. It has a higher boiling point than diethyl ether and dissolves well in water, so it is widely used as a solvent.

The biocide composition comprising a carbamate-based compound according to an embodiment of the present invention may further include a triazole-based compound. Triazole antifungal agents include fluconazole, isavuconazole, itraconazole, voriconazole, pramiconazole, ravuconazole, and posaconazole. . Protective microbial agents for triazole plants include epoxiconazole, de: triadimenol, propiconazole, prothioconazole, metconazole, ciproconazole cyproconazole, tebuconazole, flusilazole, and paclobutrazol. The triazole-based compound may include 0.1 to 20 parts by weight, preferably 1 to 10 parts by weight, more preferably 5 to 7 parts by weight, based on the total weight of the biocidal composition, but is not limited thereto. When the amount of the triazole-based compound is less than 0.1 part by weight, there is a problem that the kind and number of the applied species are not sufficient, and sufficient control effect is not exerted. When the amount exceeds 20 parts by weight, There is a problem that the substances may cause harmful combined effects and are detrimental to the human body due to excessive control effect and also cause residual substances to remain and poisoning phenomenon. Therefore, the triazole type compound is added in an amount of 0.1 to 20 wt. It is possible to provide an environmentally friendly biocidal agent which is effective for controlling a wide range of fungi by improving the antibacterial activity while being less toxic to the human body because it does not show a harmful complex effect by acting with other materials well together with other materials .

In addition, the biocidal composition containing the carbamate compound according to an embodiment of the present invention may contain other substances as the remainder.

Such other materials may also contain one or more surfactants and any other inert ingredients such as protective colloids, adhesives, thickeners, thixotropic agents, penetrants, preservatives, stabilizers, defoamers, cryoprotectants, sequestering agents, Pigments, colorants and polymers.

Examples of the penetrating agent include fatty alcohol alkoxylates, mineral oils, vegetable oils, mineral oils, and esters of vegetable oils. Examples of the stabilizer include epoxidized animal and plant oils, nonionic polyoxyethylene surfactants, anionic polyoxyethylene Surfactants, polyhydric alcohols and basic substances. Examples of the defoaming agent include trade name Anti-mousse (manufactured by BELCHIM CROP PROTECTION), and examples of the cryoprotectant include ethylene glycol, propylene glycol and the like.

The carrier may be a solid carrier and a liquid carrier. Examples of the solid carrier include starch, sugar, cellulose powder, cyclodextrin, activated carbon, soybean powder, wheat flour, rice hull powder, wood flour, fish meal, , Vegetable powders such as powdered milk; Mineral powders such as talc, kaolin, bentonite, organic bentonite, calcium carbonate, calcium sulfate, sodium bicarbonate, zeolite, diatomaceous earth, white carbon, clay, alumina, silica, sulfur powder and slaked lime. Examples of the liquid carrier include water; Vegetable oils such as soybean oil and cottonseed oil; Animal oil such as bovine fat, light oil; Alcohols such as ethyl alcohol and ethylene glycol; Ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone and isophorone; Ethers such as dioxane; Aliphatic hydrocarbons such as kerosine, kerosene, liquid paraffin, and cyclohexane; Aromatic hydrocarbons such as toluene, xylene, trimethylbenzene, tetramethylbenzene, and solvent naphtha; Halogenated hydrocarbons such as chlorobenzene; Acid amides such as N, N-dimethylformamide; Esters such as acetic acid ethyl ester and glycerin of fatty acid; Nitriles such as acetonitrile; Sulfur-containing compounds such as dimethyl sulfoxide, and N-methyl-2-pyrrolidone.

The biocidal composition comprising the carbamate-based compound may be formulated into various known forms and may be formulated into a variety of forms including, but not limited to, flowable formulations, suspensions, microsuspension, emulsions (e. G., Sucrose emulsions, microemulsions) Wettable powders), granular concentrates, pastes, and the like.

On the other hand, fungi applied to the biocidal composition include Aspergillus niger black fungus, Trichoderma viride blue mushroom fungus, Penicillium sp. Blue mold fungus, Rhizopus sp. Aureobasidium sp. Black fungus and Trametes versicolor white rot fungus. Aspergillus niger Black mold is a fungus involved in the solubilization of insoluble phosphate and potassium in the soil. Trichoderma viride Blue mushroom can produce a variety of enzymes, including cellulase and chitinolytic enzymes that can degrade cellulose and chitin. Penicillium sp. The blue fungus is a mold with a broom-shaped conidia bag. Rhizopus sp. Rosaceae is a fungus belonging to fused fungi and multiplying even under anaerobic conditions. Aureobasidium sp. Black yeast has a weak nitrogen fixation ability and is a mold with black pigment. Trametes versicolor White rot fungus is a kind of mold which decomposes cellulose, hemicellulose and lignin of wood.

The present invention also relates to a method for controlling a biocidal composition comprising a carbamate compound, comprising diluting a biocidal composition comprising the carbamate compound in a diluent and treating the composition with wood or soil to provide.

In order to treat the biocidal composition containing the carbamate compound in wood or soil to be used in the control, it may be diluted with a diluent at a suitable dilution rate. Specifically, the biocide composition containing the carbamate- The composition may be diluted 1 to 100 times by volume in the diluent, preferably 30 to 70 times, more preferably 50 to 70 times, but not always limited thereto. By maintaining an appropriate magnification as described above, it is possible to maximize the effect according to the biocidal composition including the carbamate compound, and even if the pigment is coated on the wood, it is possible to maintain a stable color difference value without stain and color change . Water may also be used as a diluent for diluting the biocidal composition containing the carbamate compound.

As described above, the biocidal composition comprising a carbamate compound according to an embodiment of the present invention may include pyrethroid compound, 3- (Nn-butyl-N-acetyl) aminopropionic acid ethyl ester, , A solvent and a carbamate-based compound, and is characterized in that a sterilizing effect or an antiseptic effect is enhanced through a bactericide inhibition together with an effect of controlling and avoiding.

The biocide composition containing the carbamate compound may be diluted with a diluent and then treated with wood or soil to obtain a stable color difference value without stain and color change even when treated with the pigment- A sustainable bar can be used to maintain the color of the pigment coated wood, especially mono.

Hereinafter, preferred embodiments of the present invention will be described in order to facilitate understanding of the present invention. However, the following examples are provided only for the purpose of easier understanding of the present invention, and the present invention is not limited by the following examples.

[Example]

≪ Example 1 >

1% by weight of C 12-16 alkyl dimethylbenzyl ammonium chloride, 72% by weight of CR-DM 25T (solvent), 1% by weight of metofluthrin, ethyl ester of 3- (N, N-butyl- % And IPBC 6 wt%, based on the total weight of the composition.

≪ Example 2 >

1% by weight of C 12-16 alkyl dimethylbenzyl ammonium chloride, 72% by weight of CR-DM 25T (solvent), 1% by weight of metofluthrin, ethyl ester of 3- (N, N-butyl- % Of propiconazole and 6 wt% of propiconazole were prepared.

≪ Example 3 >

20% by weight of ethyl 3-aminopropionate, 1% by weight of C12-16 alkyldimethylbenzylammonium chloride, 66% by weight of CR-DM25T (solvent), 1% by weight of metofluthrin, 3- (Nn- , 6% by weight of IPBC, and 6% by weight of propiconazole (propiconazole).

[Comparative Example]

≪ Comparative Example 1 &

The biocide composition was prepared in the same manner as in Example 1 except that 6% by weight of IPBC was not included and 6% by weight of water was included.

≪ Comparative Example 2 &

A biocidal composition was prepared in the same manner as in Example 1, except that 20% by weight of ethyl 3- (N-butyl-N-acetyl) aminopropionic acid ethyl ester was not contained and 20% by weight of water was contained .

[Experimental Example]

<Experimental Examples 1 to 6> Antifungal activity test

The test strain was tested immediately after being sold to the active culture condition in the BRC KCTC. The biocidal composition containing the carbamate compound prepared in Examples 1 to 3 and Comparative Examples 1 and 2 was diluted with water to 60 times. Each diluted composition was mixed with Aspergillus niger black fungus, Trichoderma viride blue mushroom fungus, Penicillium sp. Blue mold fungus, Rhizopus sp. Aureobasidium sp. Antifungal efficacy tests were conducted on each of the black yeast and Trametes versicolor white rot fungi. Each test strain was inoculated with 250 μl of each dilution solution and the control solution in a PDA medium in which each test strain was smoothed by 1 × 10 ⁶ spores / mL or more (The inoculation amount of the test group is 40 mL / m ^{2 in} terms of area ratio).

<Experimental Method>

1. Mix the pigment and adhesive (glue, polyol), and apply it in a uniform direction so that all surfaces are concealed on the slide glass. If it is completely dried, reapply and repeat 3 times in total. (In case of cyanine green, The dispersion of the pigment was not smooth, so 0.25 ml of dispersant was added.)

2. Test specimens are prepared separately for the single material of the interlocking material, taking into consideration the influence of the cross-linking agent.

3. The test piece coated with pigment is dried at 25 ℃ for 4 days.

4. Measure the chromaticity of each specimen before applying the solution.

5. Apply the solution to the specimen in three divided doses for each test group.

6. Apply 500 ml per 1 m 2 of coating capacity. 4.75 ml of the solution per 15 test pieces was applied once.

7. Apply by spraying on the specimen surface.

8. Measure chromaticity after each application.

9. Calculate final color difference data.

Item IPBC Propiconazole Metofluthrin IR3535 BTC2125M CR-DM25T Sum(%) Example 1 6 - One 20 One 72 100 Example 2 - 6 One 20 One 72 100 Example 3 6 6 One 20 One 66 100 Item IPBC water Metofluthrin IR3535 BTC2125M CR-DM25T Sum(%) Comparative Example 1 - 6 One 20 One 72 100 Comparative Example 2 6 20 One - One 72 100

(Wherein IR3535 is 3- (N-n-butyl-N-acetyl) aminopropionic acid ethyl ester and BTC2125M is C12-16 alkyldimethylbenzylammonium chloride.

Item Strain name Black mold Blue fungus Blue dot mushroom fungus Milky fungus Black yeast White rot fungus Example 1 +++ +++ +++ +++ +++ +++ Example 2 - - + - - - Example 3 +++ +++ +++ +++ +++ +++ Comparative Example 1 - - - - - - Comparative Example 2 - - - - - -

As shown in Table 2, in the case of Example 2 using only 6.0% propiconazole as an antifungal main component in Experimental Examples 1 to 3, no antifungal properties were observed in all strains except Trichoderma viride . In the other strains except Trichoderma viride, the turbidity of the growth medium of the bacterium was lower or the growth condition was poor.

In addition, in Examples 1 and 3 using 6.0% IPBC as an antifungal main component, the growth inhibitory ability against all fungal strains was shown, and no possibility of harmful microorganisms such as fungi and pathogenic bacteria was observed until 10 days after the test run period And the antifungal activity was confirmed.

On the other hand, in the case of Comparative Example 1, which was prepared with water not including ethyl 3- (N-butyl-N-acetyl) aminopropionate and Comparative Example 2, which contained water without IPBC, And no antifungal properties were observed.

Accordingly, 0.1 to 20 parts by weight of a carbamate compound, 0.1 to 10 parts by weight of a pyrethroid compound, 0.1 to 10 parts by weight of 3- (Nn-butyl-N-acetyl) aminopropionate 1 to 50 parts by weight of an ester, 0.1 to 20 parts by weight of a triazole-based compound and 0.1 to 10 parts by weight of a preservative, wherein the weight ratio of 3- (Nn-butyl-N-acetyl) aminopropionic acid ethyl ester to the pyrethroid- 1: 10 to 1: 30, wherein the weight ratio of 3- (Nn-butyl-N-acetyl) aminopropionic acid ethyl ester to the carbamate compound is from 1:10 to 1:30, Can exhibit excellent results in the antifungal properties.

&Lt; Experimental Examples 7 to 12 >

The biocide composition was diluted and tested for stability against monochlor pigments. The monoclonal stability evaluation experiment was carried out by modifying the experimental method of monoclonal stability evaluation of '2013, Kangdae-day', development of evaluation technology for evaluation of biological damage prevention technology and recognition standard, National Cultural Properties Research Institute, Korea Traditional Culture University.

Psalm making Slide glass, brush, water and dispersant Monochromatic pigment Yellow, yellow, yellow, yellow, yellow, yellow, permanent orange, scarlet,
Cyanine green, lower leaves, Coagulant Glue, polyol (water-based acrylic emulsion) Color difference measuring device Connie Minolta CM-2600d Experimental solution Water (negative control), biochemical product (experimental group), positive control group (Han Chem Kid Keeper A)

<Experimental Method>

After mixing the pigment and adhesive (glue, polysiloxane), coat all the surfaces on the slide glass in a uniform direction and then reapply them. Repeat the procedure three times in total. (In the case of cyanine green, It was made by adding 0.25ml of dispersant because dispersion was not smooth.) Specimen for the single material of the cross-linking agent should be prepared separately considering the effect of the cross-linking agent. The test piece coated with the pigment is dried for 4 days at 25 ° C. Measure the chromaticity of each specimen before solution coating. Then, the solution is applied to the specimen in three times according to each test group. Apply 500 ml per 1 m 2 of the specimen by spraying. Apply 4.75 ml of solution per 15 specimens. The chromaticity is measured after coating each time, and the final color difference data is calculated.

Pre-application chromaticity (1 time) Color difference before application - Color difference before application - Glue L a b L a b white lead Positive control group 91.9 -0.64 2.74 white lead Positive control group 94.97 -2.32 2.14 Experimental group 90.55 -0.35 2.76 Experimental group 94.41 -2.08 1.99 Negative control group 92.72 -0.58 2.65 Negative control group 94.49 -2.31 2 whiting Positive control group 60.49 2.74 9.69 whiting Positive control group 70.26 1.39 7.13 Experimental group 59.87 2.42 8.82 Experimental group 77.78 1.45 7.26 Negative control group 60.48 2.69 10.53 Negative control group 78.08 1.36 7.12 Cyanine green Positive control group 25.77 -7.57 -0.94  Cyanine green Positive control group 24.53 -10.34 -0.48 Experimental group 25.59 -7.71 -1.35 Experimental group 24.82 -8.66 -0.74 Negative control group 25.96 -7.72 -0.83 Negative control group 26.07 -9.94 -0.7 Lower Positive control group 39.91 -14.45 14.1 Lower Positive control group 40.48 -15.14 15.22 Experimental group 40.11 -14.48 14.16 Experimental group 37.58 -15.93 16.63 Negative control group 39.7 -14.38 14.08 Negative control group 39.02 -15.59 16.28 sulfur Positive control group 79.36 22.41 90.27 sulfur Positive control group 78.67 24.38 95.08 Experimental group 79.42 22.46 90.59 Experimental group 78.4 23.77 93.86 Negative control group 79.47 22.78 90.32 Negative control group 78.51 24.3 93.99 ocher Positive control group 60.76 16.56 48.01 ocher Positive control group 65.85 17.35 55.53 Experimental group 60.67 16.61 47.88 Experimental group 66.4 17.2 55.39 Negative control group 60.31 16.63 48.12 Negative control group 64.74 18.25 57.76 chrome Positive control group 79.72 22.35 89.86 chrome Positive control group 77.54 26.83 86.22 Experimental group 79.51 24.78 91.47 Experimental group 77.22 26.01 87.63 Negative control group 79.86 23.43 91.18 Negative control group 77.45 26.09 87.62 scarlet Positive control group 41.54 50.66 28.9 scarlet Positive control group 41.56 50.84 30.15 Experimental group 41.23 50.7 29.1 Experimental group 41.62 51.1 30.32 Negative control group 41.56 50.69 28.9 Negative control group 41.56 51.57 31.05 Permanent orange Positive control group 50.63 53.36 44.23 Permanent orange Positive control group 48.68 54.41 47.25 Experimental group 50.63 53.16 44.06 Experimental group 48.74 54.1 48.19 Negative control group 50.59 53.09 43.93 Negative control group 48.8 54.14 48.21

Long Positive control group 59.17 48.42 51.78

Long Positive control group 59.82 49.87 57.73 Experimental group 58.29 48.2 51.63 Experimental group 60.2 49.16 56.49 Negative control group 59.43 48.44 52.02 Negative control group 60.61 49.62 59.29 Kwak Positive control group 32.02 3.62 -27.73 Kwak Positive control group 35.39 1.65 -31.99 Experimental group 30.9 4.24 -29.97 Experimental group 38.3 0.8 -28.98 Negative control group 30.88 4.34 -27.89 Negative control group 38.62 -0.66 -26.58 Gypsum Positive control group 54.14 -31.37 11.32 Gypsum Positive control group 62.57 -30.57 11.95 Experimental group 54.13 -30.78 10.78 Experimental group 62.11 -30.72 11.88 Negative control group 53.8 -30.81 10.98 Negative control group 62.49 -30.76 11.53 Masonry Positive control group 37.41 27.38 19.32 Masonry Positive control group 34.71 25.16 16.56 Experimental group 37.35 27.15 19.12 Experimental group 31.18 25.52 17.39 Negative control group 37.29 27.5 19.51 Negative control group 32.37 26.16 18.28 County Office Positive control group 23.6 8.6 -21.47 County Office Positive control group 31.8 23.95 -62.18 Experimental group 23.36 6.56 -15.95 Experimental group 31.34 24.16 -61.89 Negative control group 23.72 8.56 -20.99 Negative control group 31.53 24.2 -62.62 Business Positive control group 24.64 12.77 -30.74 Business Positive control group 28.48 23.01 -55.46 Experimental group 24.02 12.29 -29.64 Experimental group 28.33 23.84 -56.99 Negative control group 23.12 8.22 -20.72 Negative control group 29.13 23.93 -57.44

Before coating (2 times) Color difference before application - Color difference before application - Glue L a b L a b white lead Positive control group 90.43 1.81 2.37 white lead Positive control group 96.69 -0.19 1.56 Experimental group 91.67 0.91 2.91 Experimental group 96.86 -0.25 1.99 Negative control group 90.58 3.11 2.87 Negative control group 96.8 -0.28 2.01 whiting Positive control group 59.94 0.84 9.77 whiting Positive control group 77.73 1.43 7.41 Experimental group 62.43 0.67 9.05 Experimental group 77.71 1.33 7.6 Negative control group 60.79 0.9 9.98 Negative control group 77.59 1.28 7.49 Cyanine green Positive control group 23 -12.4 -1.22 Cyanine green Positive control group 21.21 -10.14 -1.16 Experimental group 23.36 -12.92 -1.08 Experimental group 20.95 -10.82 -1.41 Negative control group 24.42 -10.06 -1.14 Negative control group 21 -10.23 -1.12 Lower Positive control group 38.37 -13.13 11.84 Lower Positive control group 37.4 -15.43 16.22 Experimental group 38.36 -12.88 11.74 Experimental group 36.87 -15.63 15.87 Negative control group 38.36 -13.01 11.81 Negative control group 37.04 -15.39 15.42 sulfur Positive control group 78.3 24.42 87.91 sulfur Positive control group 79.3 24.97 88.47 Experimental group 78.03 23.1 87.78 Experimental group 75.21 27.65 89.01 Negative control group 78.52 25.09 88.91 Negative control group 76.84 27.44 88.92 ocher Positive control group 59.67 17.24 47.48 ocher Positive control group 58.87 19.59 52.76 Experimental group 59.72 17.75 47.94 Experimental group 60.61 19.91 55.75 Negative control group 59.48 17.19 47.67 Negative control group 59.51 19.55 53.73 chrome Positive control group 77.52 22 87.66 chrome Positive control group 78.22 27.42 92.12 Experimental group 78.05 21.67 88.72 Experimental group 79.78 25.31 91.31 Negative control group 77.62 21.68 87.71 Negative control group 79.19 25.95 91.46 scarlet Positive control group 40.37 47.61 26.36 scarlet Positive control group 43.38 50.06 27.9 Experimental group 40.21 48.09 26.82 Experimental group 42.85 49.99 28.18 Negative control group 40.49 47.77 26.55 Negative control group 43.01 50.37 28.58

Permanent orange Positive control group 48.78 51.12 42.56 Permanent orange Positive control group 48.09 54.19 46.14 Experimental group 48.7 50.92 42.45 Experimental group 48.78 54.66 46.85 Negative control group 48.82 51.15 42.85 Negative control group 48.18 54.15 46.83 Long Positive control group 57.72 46.1 49.58 Long Positive control group 58.96 50.37 56.25 Experimental group 57.74 45.97 49.44 Experimental group 59.49 50.08 58.11 Negative control group 57.41 45.4 49.31 Negative control group 59.3 50.29 58.44 Kwak Positive control group 28.21 5.52 -33.68 Kwak Positive control group 37.55 2.83 -32.69 Experimental group 28.3 5.18 -32.9 Experimental group 34.33 4.11 -35.78 Negative control group 28.17 5.36 -33.01 Negative control group 37.73 1.12 -32.06 Gypsum Positive control group 56.69 -33.81 12.37 Gypsum Positive control group 64.63 -32.14 12.22 Experimental group 56.6 -33.7 12.37 Experimental group 64.57 -32.54 12.47 Negative control group 56.29 -32.43 11.61 Negative control group 64.71 -32.17 12.27 Masonry Positive control group 36.68 25.65 17.64 Masonry Positive control group 33.24 26.01 16.96 Experimental group 35.68 20.81 13.67 Experimental group 33.23 25.76 16.6 Negative control group 36.4 23.1 15.59 Negative control group 33.34 25.93 16.93 County Office Positive control group 23.94 19.21 -38.31 County Office Positive control group 33.58 22.99 -63.85 Experimental group 24.07 22.39 -43.91 Experimental group 33.72 23.23 -63.95 Negative control group 23.73 19.1 -37.87 Negative control group 33.29 23.3 -63.66 Business Positive control group 22.54 21.9 -45.93 Business Positive control group 30.68 23.16 -57.98 Experimental group 22.58 22.07 -46.25 Experimental group 31.03 23.22 -58.3 Negative control group 23.17 21.94 -46.85 Negative control group 30.08 23.42 -58.39

Before coating (3 times) Color difference before application - Color difference before application - Glue L a b L a b white lead Positive control group 90.92 2.79 2.86 white lead Positive control group 95.94 -0.18 1.08 Experimental group 91.22 1.83 2.54 Experimental group 96.09 -0.2 1.28 Negative control group 91.16 1.65 2.78 Negative control group 96.7 -0.26 1.91 whiting Positive control group 61.82 0.73 9.11 whiting Positive control group 77.77 1.35 7.43 Experimental group 61.09 0.63 7.54 Experimental group 77.89 1.38 7.51 Negative control group 60.87 0.59 9.57 Negative control group 77.57 1.29 7.43 Cyanine green Positive control group 24.44 -8.97 -1.28 Cyanine green Positive control group 20.98 -9.98 -1.06 Experimental group 23.91 -9.65 -1.02 Experimental group 20.77 -10.91 -1.2 Negative control group 24.85 -9.79 -1.21 Negative control group 20.97 -10.32 -0.91 Lower Positive control group 38.3 -13.09 11.85 Lower Positive control group 37.61 -15.2 15.96 Experimental group 38.38 -12.97 11.72 Experimental group 37.08 -15.37 15.43 Negative control group 38.39 -13.03 11.78 Negative control group 37.35 -15.35 16.16 sulfur Positive control group 78.42 24.64 88.31 sulfur Positive control group 76.95 26.23 91.02 Experimental group 78.48 24.71 88.4 Experimental group 77.9 24.42 89.18 Negative control group 78.71 25.46 88.71 Negative control group 77.79 26.22 91 ocher Positive control group 59.69 17.29 47.63 ocher Positive control group 59.03 19.7 52.01 Experimental group 59.56 17.24 47.41 Experimental group 58.02 19.18 50.43 Negative control group 59.58 17.23 47.51 Negative control group 58.91 19.45 53.11 chrome Positive control group 76.91 19.9 86.17 chrome Positive control group 78.8 26.52 92.04 Experimental group 77.31 22.2 86.99 Experimental group 78.5 27.24 92.72 Negative control group 77.21 20.82 87.09 Negative control group 78.8 27.21 92.53 scarlet Positive control group 40.55 47.94 26.7 scarlet Positive control group 42.43 50.74 29.28 Experimental group 40.68 47.81 26.49 Experimental group 42.4 50.98 29.65 Negative control group 40.38 48.02 26.83 Negative control group 43.04 49.94 27.88 Permanent orange Positive control group 48.99 51.02 42.7 Permanent orange Positive control group 47.8 54.71 46.86 Experimental group 48.97 50.9 42.82 Experimental group 47.79 54.31 46.4 Negative control group 49.05 51.21 43.08 Negative control group 47.89 54.04 44.93 Long Positive control group 57.79 45.87 49.72 Long Positive control group 59.53 50.23 57.72 Experimental group 57.8 45.62 49.69 Experimental group 59.47 50.03 54.8 Negative control group 57.83 45.91 50.01 Negative control group 59.31 49.89 57.46 Kwak Positive control group 28.41 5.47 -33.67 Kwak Positive control group 33.82 5.67 -38.27 Experimental group 28.6 4.76 -32.49 Experimental group 36.29 3.16 -34.87 Negative control group 28.47 5.55 -33.8 Negative control group 35.48 4.38 -36.24 Gypsum Positive control group 55.78 -32.76 11.82 Gypsum Positive control group 64.28 -32.18 12.41 Experimental group 56.42 -33.06 11.95 Experimental group 64.58 -32.2 12.32 Negative control group 55.85 -34.21 12.62 Negative control group 64.55 -32.26 12.26 Masonry Positive control group 36.68 25.3 17.33 Masonry Positive control group 33.24 25.85 16.84 Experimental group 36.74 26.08 18.02 Experimental group 32.08 26.46 17.47 Negative control group 36.74 25.94 17.92 Negative control group 31.75 26.95 17.54 County Office Positive control group 23.72 22.54 -44.19 County Office Positive control group 33.91 23.07 -63.98 Experimental group 24.31 20.78 -41.9 Experimental group 33.59 23.41 -63.89 Negative control group 24.55 22.2 -44.02 Negative control group 33.65 23.4 -64 Business Positive control group 22.78 21.95 -46.23 Business Positive control group 30.19 23.68 -58.53 Experimental group 22.43 22.12 -46.35 Experimental group 30.09 23.45 -58.56 Negative control group 22.03 21.61 -45.35 Negative control group 30.68 23.22 -57.94

Chromaticity after the third application (one time) After the third application, color difference - Color difference after the third application - glue L a b L a b white lead Positive control group 91.17 -0.29 2.92 white lead Positive control group 93.42 -2.07 2.41 Experimental group 89.1 -0.22 3.22 Experimental group 93.64 -2.18 2.43 Negative control group 91.88 -0.37 3.18 Negative control group 93.63 -2.32 2.26 whiting Positive control group 57.5 3.36 10.63 whiting Positive control group 77.46 1.53 7.74 Experimental group 56.39 2.93 9.98 Experimental group 77.13 1.55 7.65 Negative control group 57.68 2.69 9.76 Negative control group 77.33 1.39 7.29 Cyanine green Positive control group 24.55 -4.59 -1.29 Cyanine green Positive control group 24.28 -9.76 -0.31 Experimental group 24.06 -4.52 -2.34 Experimental group 23.87 -3.31 -1.36 Negative control group 25.01 -7.43 -1.32 Negative control group 25.32 -7.91 -0.81 Lower Positive control group 39.43 -14.15 14.17 Lower Positive control group 39.03 -14.5 13.95 Experimental group 39.53 -14.25 14.25 Experimental group 37.21 -15.35 15.95 Negative control group 39.41 -13.86 13.81 Negative control group 38.88 -15.15 15.9 sulfur Positive control group 78.91 22.68 90 sulfur Positive control group 77.79 25.03 93.71 Experimental group 78.09 22.72 89.74 Experimental group 77.52 24.96 92.78 Negative control group 78.56 22.54 90.02 Negative control group 77.53 25.57 92.46 ocher Positive control group 60.3 16.34 46.8 ocher Positive control group 65 17.7 55.54 Experimental group 60.28 16.41 47.05 Experimental group 66.03 17.63 55.38 Negative control group 59.67 16.39 46.57 Negative control group 64 18.56 56.9 chrome Positive control group 79.43 21.87 88.4 chrome Positive control group 76.1 25.93 81.82 Experimental group 78.76 24.67 90.59 Experimental group 77.04 26.15 87.16 Negative control group 78.98 23.5 89.75 Negative control group 76.77 26.24 86.66 scarlet Positive control group 41.9 50.58 28.8 scarlet Positive control group 41.1 51.79 31.45 Experimental group 41.06 50.54 29.13 Experimental group 40.86 51.28 29.5 Negative control group 41.34 49.5 27.8 Negative control group 41.32 50.16 29.19 Permanent orange Positive control group 50.61 52.84 43.1 Permanent orange Positive control group 47.9 54.03 46.32 Experimental group 50.33 51.89 41.86 Experimental group 47.9 53.11 45.97 Negative control group 50.16 52.22 42.77 Negative control group 47.99 53.05 45.96 Long Positive control group 59.36 48.13 51.26 Long Positive control group 59.08 50.1 57.29 Experimental group 59.53 48.1 49.9 Experimental group 59.32 49.94 54.42 Negative control group 60.15 45.65 44.56 Negative control group 64.21 43.9 42.67 Kwak Positive control group 31.64 3.67 -27.36 Kwak Positive control group 34.49 1.8 -31.56 Experimental group 30.91 4.31 -29.74 Experimental group 38.04 0.77 -28.04 Negative control group 31.14 3.96 -27.12 Negative control group 37.26 -0.58 -25.78 Gypsum Positive control group 53.31 -30.5 10.91 Gypsum Positive control group 61.34 -30.72 12.38 Experimental group 53.52 -30.55 10.85 Experimental group 61.75 -30.03 11.58 Negative control group 53.99 -31.36 11.29 Negative control group 61.22 -30.4 11.45 Masonry Positive control group 37.74 26.84 18.9 Masonry Positive control group 34.39 25.03 16.52 Experimental group 36.38 26.07 18.15 Experimental group 33.45 23.78 15.8 Negative control group 36.57 25.63 17.78 Negative control group 32.55 22.9 14.62 County Office Positive control group 23.55 6.43 -15.47 County Office Positive control group 29.46 24.72 -60.05 Experimental group 22.97 6.28 -14.59 Experimental group 30.44 24.34 -60.45 Negative control group 22.69 8.33 -19.61 Negative control group 30.63 24.16 -61.01 Business Positive control group 24.83 4.8 -11.16 Business Positive control group 26.9 23.14 -53.35 Experimental group 23.05 4.89 -12.98 Experimental group 27.49 23.63 -55.16 Negative control group 21.41 6.23 -15.99 Negative control group 28.84 24.18 -57.28

Chromaticity after the third application (2 times) After the third application, color difference - Color difference after the third application - glue L a b L a b white lead Positive control group 89.96 1.46 2.65 white lead Positive control group 94.57 -0.51 1.88 Experimental group 90.98 0.76 3.79 Experimental group 96.26 -0.62 2.38 Negative control group 90.47 3.05 3.03 Negative control group 96.1 -0.65 2.58 whiting Positive control group 57.67 0.61 9.58 whiting Positive control group 76.24 1.07 8.51 Experimental group 60.33 0.73 10.37 Experimental group 76.52 1.22 8.04 Negative control group 60.23 0.52 8.72 Negative control group 76.38 1.14 7.87 Cyanine green Positive control group 21.71 -7.75 -1.7 Cyanine green Positive control group 21.18 -9.44 -1.06 Experimental group 23.78 -10.02 -0.97 Experimental group 21.64 -8.14 -1.84 Negative control group 24.2 -7.55 -1.97 Negative control group 22.36 -7.36 -1.4 Lower Positive control group 38.66 -12.59 11.25 Lower Positive control group 36.03 -14.57 14.7 Experimental group 38.45 -12.81 11.89 Experimental group 37.42 -14.86 14.44 Negative control group 38.1 -12.93 11.77 Negative control group 36.94 -15.2 15.05 sulfur Positive control group 78.05 23.89 87.24 sulfur Positive control group 77.99 26.07 87.29 Experimental group 77.65 22.54 86.88 Experimental group 74.83 27.01 86.53 Negative control group 78.11 24.61 88.54 Negative control group 76.08 27.92 88.03 ocher Positive control group 59.35 16.53 46.52 ocher Positive control group 55.74 18.16 47.77 Experimental group 59.17 16.68 46.18 Experimental group 59.54 19.57 52.97 Negative control group 59.29 16.76 46.7 Negative control group 58.15 18.89 49.76 chrome Positive control group 77.22 21.52 86.6 chrome Positive control group 76.92 28.61 90.89 Experimental group 77.73 20.75 86.63 Experimental group 79.25 25.29 90.4 Negative control group 77.14 21.16 85.64 Negative control group 78.84 25.88 90.13 scarlet Positive control group 40.27 46.7 24.96 scarlet Positive control group 42.49 50.19 28.42 Experimental group 40.13 46.09 24.8 Experimental group 41.29 50.02 28.79 Negative control group 39.74 47.01 26.2 Negative control group 42.96 49.68 27.74 Permanent orange Positive control group 47.98 50.03 41.39 Permanent orange Positive control group 47.14 53.62 45.02 Experimental group 47.97 48.76 40.55 Experimental group 47.41 52.69 45.5 Negative control group 48.22 50.42 42.41 Negative control group 47.06 52.66 44.36 Long Positive control group 57.4 44.96 48.12 Long Positive control group 58.23 50.3 55.3 Experimental group 57.21 45.47 49.47 Experimental group 59.73 49.56 55.75 Negative control group 57.26 45.18 49.52 Negative control group 64.16 40.87 37.51 Kwak Positive control group 27.73 5.59 -32.92 Kwak Positive control group 37.31 2.8 -32.63 Experimental group 27.76 5.23 -32.42 Experimental group 34.8 3.56 -34.23 Negative control group 28.2 5.22 -32.92 Negative control group 37.86 1.23 -31.65 Gypsum Positive control group 55.74 -33.56 12.22 Gypsum Positive control group 63.07 -33.2 12.77 Experimental group 55.23 -33.67 12.23 Experimental group 63.83 -32.7 12.38 Negative control group 54.59 -32.04 11.33 Negative control group 63.7 -32.4 12.36 Masonry Positive control group 37.02 25.99 17.71 Masonry Positive control group 32.55 24.74 15.8 Experimental group 35.05 21.6 14.62 Experimental group 32.83 23.5 15.17 Negative control group 35.91 23.37 15.5 Negative control group 33.43 24.42 15.45 County Office Positive control group 24.67 11.88 -25.93 County Office Positive control group 31.62 22.96 -61.96 Experimental group 25.84 21.23 -41.77 Experimental group 31.78 23.63 -62.34 Negative control group 25.61 17.27 -35.54 Negative control group 32.91 23.28 -63.06 Business Positive control group 21.92 19.57 -41.19 Business Positive control group 27.43 23.39 -54.66 Experimental group 21.67 20.59 -43.85 Experimental group 29.39 22.72 -56.62 Negative control group 23.31 21.13 -46 Negative control group 29.84 23.37 -57.88

Chromaticity after third application (3 times) After the third application, color difference - Color difference after the third application - glue L a b L a b white lead Positive control group 90.66 2.58 3.25 white lead Positive control group 93.03 -0.76 0.63 Experimental group 90.51 1.43 3.09 Experimental group 95.54 -0.51 1.75 Negative control group 91.16 1.35 3.21 Negative control group 95.8 -0.8 2.39 whiting Positive control group 55.32 0.39 8.76 whiting Positive control group 76.77 1.26 8.21 Experimental group 59.61 0.26 9.34 Experimental group 76.36 1.3 8.4 Negative control group 59.83 0.19 8.39 Negative control group 75.67 1.09 7.84 Cyanine green Positive control group 23.72 -7.01 -1.69 Cyanine green Positive control group 20.96 -9.91 -0.84 Experimental group 21.47 -8.53 -1.47 Experimental group 21.46 -8.34 -1.65 Negative control group 24.86 -7.88 -1.46 Negative control group 22.22 -7.87 -1.48 Lower Positive control group 39.09 -12.61 11.39 Lower Positive control group 36.37 -14.64 14.89 Experimental group 38.3 -13.01 12.04 Experimental group 37.8 -15.34 15.15 Negative control group 37.79 -13.09 11.94 Negative control group 37.28 -15.22 15.86 sulfur Positive control group 77.95 23.86 87.11 sulfur Positive control group 75.9 16.54 89.16 Experimental group 77.82 23.44 87.46 Experimental group 76.89 25.03 87.59 Negative control group 77.66 24.88 87.16 Negative control group 77.1 26.68 89.27 ocher Positive control group 59.09 16.56 46.38 ocher Positive control group 58.19 19 45.87 Experimental group 59.24 16.29 46.29 Experimental group 58.51 18.15 47.91 Negative control group 58.93 16.58 46.33 Negative control group 57.96 18.86 49.49 chrome Positive control group 76.71 19.4 85.36 chrome Positive control group 77.69 27.21 91.31 Experimental group 76.9 21.75 85.4 Experimental group 77.59 27.55 90.98 Negative control group 76.26 20.19 84.56 Negative control group 77.84 27.93 90.41 scarlet Positive control group 40.45 46.39 25.04 scarlet Positive control group 41.7 51.16 30.03 Experimental group 40.45 46.18 24.66 Experimental group 41.6 51.33 30.35 Negative control group 40.08 47 26 Negative control group 42.86 49.62 27.63 Permanent orange Positive control group 47.6 48.09 39.28 Permanent orange Positive control group 46.84 54.09 45.81 Experimental group 47.8 49.19 41.25 Experimental group 47.16 53.14 44.06 Negative control group 48.23 50.24 42.34 Negative control group 47.17 53.11 43.24 Long Positive control group 56.95 44.7 47.87 Long Positive control group 58.54 50.47 57.71 Experimental group 57.19 45.02 49.16 Experimental group 60.16 49.49 54.09 Negative control group 57.39 46.14 50.84 Negative control group 64.98 40.49 58.65 Kwak Positive control group 27.76 5.36 -32.4 Kwak Positive control group 33.47 5.55 -37.94 Experimental group 27.73 4.64 -31.59 Experimental group 36.21 2.98 -34.27 Negative control group 29.07 5.39 -34.51 Negative control group 36 3.98 -35.62 Gypsum Positive control group 54.51 -32.65 11.64 Gypsum Positive control group 63.45 -32.56 12.66 Experimental group 54.7 -33.2 11.88 Experimental group 63.72 -32.5 12.33 Negative control group 55.58 -34 12.41 Negative control group 64.19 -32.36 12.27 Masonry Positive control group 36.99 25.5 17.22 Masonry Positive control group 32.92 24.81 15.77 Experimental group 37.06 25.83 17.78 Experimental group 31.38 24.63 15.2 Negative control group 36.7 25.32 17.16 Negative control group 31.59 24.68 15.78 County Office Positive control group 24.09 15.05 -31.58 County Office Positive control group 33.35 22.61 -63.04 Experimental group 24.92 18.4 -40.94 Experimental group 33.29 22.72 -62.73 Negative control group 23.83 22.1 -43.34 Negative control group 33.49 23.22 -63.58 Business Positive control group 21.9 18.94 -40.23 Business Positive control group 26.84 24.09 -55.17 Experimental group 22.02 21.07 -44.43 Experimental group 29.34 23.39 -56.85 Negative control group 21.92 21.13 -44.67 Negative control group 30.48 22.83 -57.33

1-3 times after 3rd application ΔE After the third application, color difference - Color difference after the third application - glue 1st round Second round Three times 1st round Second round Three times white lead Positive control group 0.829337 0.649461 0.513615 white lead Positive control group 1.593079 2.167764 3.001166 Experimental group 1.526761 1.128273 0.983158 Experimental group 0.892468 0.805605 0.787083 Negative control group 1.015185 0.203224 0.524309 Negative control group 0.898499 0.975602 1.154123 whiting Positive control group 3.195012 2.28952 6.51829 whiting Positive control group 7.22715 1.886717 1.271417 Experimental group 3.703525 2.481129 2.359513 Experimental group 0.764591 1.273499 1.771835 Negative control group 2.903946 1.430245 1.62296 Negative control group 0.76961 1.27597 1.953996 Cyanine green Positive control group 3.239028 4.849433 2.127933 Cyanine green Positive control group 0.654064 0.707743 0.231733 Experimental group 3.67384 2.93232 2.722223 Experimental group 5.468949 2.800607 2.698796 Negative control group 1.107565 2.65281 1.926318 Negative control group 2.16691 3.188244 2.808897 Lower Positive control group 0.570351 0.850764 1.032521 Lower Positive control group 2.03101 2.219662 1.730925 Experimental group 0.630397 0.188414 0.332265 Experimental group 0.967316 1.71473 0.773111 Negative control group 0.653758 0.274955 0.623859 Negative control group 0.597997 0.427785 0.334365 sulfur Positive control group 0.590169 0.890112 1.50642 sulfur Positive control group 1.753226 2.0781 9.922611 Experimental group 1.599687 1.126055 1.712338 Experimental group 1.832184 2.589286 1.979975 Negative control group 0.987775 0.73171 1.959949 Negative control group 2.216799 1.264951 1.918489 ocher Positive control group 1.31305 1.236163 1.566972 ocher Positive control group 0.919293 6.06151 6.236602 Experimental group 0.938616 2.131901 1.503097 Experimental group 0.567362 2.998149 2.766116 Negative control group 1.694019 1.077915 1.495794 Negative control group 1.176138 4.24807 3.788799 chrome Positive control group 1.564001 1.201666 0.972677 chrome Positive control group 4.716312 2.149186 1.49703 Experimental group 1.161465 2.30584 1.702557 Experimental group 0.522398 1.053281 1.987913 Negative control group 1.680536 2.187624 2.774941 Negative control group 1.18596 1.377062 2.436062 scarlet Positive control group 0.382099 1.672752 2.273346 scarlet Positive control group 1.674545 1.038942 1.127741 Experimental group 0.235372 2.84373 2.461443 Experimental group 1.132431 1.675291 1.119151 Negative control group 1.63539 1.123655 1.348814 Negative control group 2.346338 1.08821 0.444185 Permanent orange Positive control group 1.244066 1.788016 4.713109 Permanent orange Positive control group 1.271888 1.575373 1.551934 Experimental group 2.557909 2.967912 2.599596 Experimental group 2.571789 2.753234 2.690985 Negative control group 1.512415 1.042353 1.47 Negative control group 2.62806 3.094414 2.05898 Long Positive control group 0.62498 1.879787 2.344568 Long Positive control group 0.891123 1.200125 1.018725 Experimental group 2.130845 0.729246 1.006479 Experimental group 2.380693 2.428497 1.127741 Negative control group 7.997131 0.339116 0.967161 Negative control group 17.94165 23.46105 11.04197 Kwak Positive control group 0.532729 0.90161 1.430909 Kwak Positive control group 1.008662 0.249199 0.495782 Experimental group 0.240624 0.724224 1.257498 Experimental group 0.975756 1.710526 0.631506 Negative control group 0.897162 0.169115 0.943239 Negative control group 1.579873 0.443959 0.902663 Gypsum Positive control group 1.270394 0.99373 1.2874 Gypsum Positive control group 1.311602 1.964612 0.946467 Experimental group 0.655668 1.377461 1.727107 Experimental group 0.834086 0.76243 0.910879 Negative control group 0.659318 1.766494 0.401373 Negative control group 1.32246 1.03976 0.373765 Masonry Positive control group 0.759539 0.485901 0.384968 Masonry Positive control group 0.347707 1.853267 1.526073 Experimental group 1.74591 1.386903 0.471699 Experimental group 3.2724 2.704163 2.998633 Negative control group 2.647301 0.566657 0.981631 Negative control group 4.904651 2.11627 2.876821 County Office Positive control group 6.380549 14.40577 14.67137 County Office Positive control group 3.256593 2.722976 1.186929 Experimental group 1.442255 3.009668 2.637821 Experimental group 1.70763 2.552587 1.382642 Negative control group 1.737297 3.508874 0.995389 Negative control group 1.844912 0.710493 0.484149 Business Positive control group 21.1408 5.317979 6.770118 Business Positive control group 2.639204 4.651645 4.762373 Experimental group 18.25531 2.962853 2.226432 Experimental group 2.0245 2.400417 1.868208 Negative control group 5.408983 1.182455 0.839583 Negative control group 0.41497 0.565862 0.751132

After the third application, ΔE (average of 3 times) Average color difference of the polyols Average color difference of glue white lead Positive control group 0.664138 white lead Positive control group 2.254003 Experimental group 1.212731 Experimental group 0.828386 Negative control group 0.580906 Negative control group 1.009408 whiting Positive control group 4.00094 whiting Positive control group 3.461761 Experimental group 2.848056 Experimental group 1.269975 Negative control group 1.985717 Negative control group 1.333192 Cyanine green Positive control group 3.405465 Cyanine green Positive control group 0.53118 Experimental group 2.827272 Experimental group 2.749702 Negative control group 1.895564 Negative control group 2.72135 Lower Positive control group 0.817879 Lower Positive control group 1.993865 Experimental group 0.383692 Experimental group 1.151719 Negative control group 0.517524 Negative control group 0.453382 sulfur Positive control group 0.995567 sulfur Positive control group 4.584645 Experimental group 1.47936 Experimental group 2.133815 Negative control group 1.226478 Negative control group 1.80008 ocher Positive control group 1.372062 ocher Positive control group 4.405802 Experimental group 1.524538 Experimental group 2.110543 Negative control group 1.422576 Negative control group 3.071002 chrome Positive control group 1.246115 chrome Positive control group 2.787509 Experimental group 1.723287 Experimental group 1.187864 Negative control group 2.214367 Negative control group 1.666361 scarlet Positive control group 1.442732 scarlet Positive control group 1.280409 Experimental group 1.846848 Experimental group 1.308958 Negative control group 1.369286 Negative control group 1.292911 Permanent orange Positive control group 2.58173 Permanent orange Positive control group 1.466399 Experimental group 2.708472 Experimental group 2.672003 Negative control group 1.341589 Negative control group 2.593818 Long Positive control group 1.616445 Long Positive control group 1.036658 Experimental group 1.288857 Experimental group 1.978977 Negative control group 3.101136 Negative control group 17.48156

Kwak Positive control group 0.955082

Kwak Positive control group 0.584548 Experimental group 0.740782 Experimental group 1.105929 Negative control group 0.669839 Negative control group 0.975499 Gypsum Positive control group 1.183841 Gypsum Positive control group 1.40756 Experimental group 1.253412 Experimental group 0.835798 Negative control group 0.942395 Negative control group 0.911995 Masonry Positive control group 0.543469 Masonry Positive control group 1.242349 Experimental group 1.201504 Experimental group 2.991732 Negative control group 1.39853 Negative control group 3.299247 County Office Positive control group 11.81923 County Office Positive control group 2.388833 Experimental group 2.363248 Experimental group 1.880953 Negative control group 2.08052 Negative control group 1.013184 Business Positive control group 11.0763 Business Positive control group 4.017741 Experimental group 2.594643 Experimental group 2.097708 Negative control group 2.477007 Negative control group 0.577322

(In the case of cyanine green, the color difference values for the first and second rounds were different from those for the first and second rounds, respectively.) In the case of the colloid-yangchong case, The color difference value of the first time is excluded.)

As shown in [Table 4] - [Table 11], in the examples 7 to 12, the color difference is converted into the L * a * b * color system based on the specification of KS A 0063 And the color difference (? E) is calculated to determine the degree of discoloration. The L * a * b color system shows the color before change and the color change direction after change. The color difference is basically evaluated by three basic concepts of lightness, hue and chroma.

The chrominance is a numerical representation of the perceptual differences of two geometric colors, and is quantitatively expressed as a geometric distance between two points in the L * a * b * color space, for example. The color difference ΔE (L *, a *, b *) is calculated as follows.

L: lightness a: red index b: yellow index

The L * value used to represent DELTA E (L *, a *, b *) represents the reflectance (lightness such as human's sensation), and the unit of decimal point can be expressed in steps from 0 to 100. The a * value is a chromaticity diagram, in which + a * is red and -a * is green. The b * value is a chromaticity diagram, where + b * denotes yellow and -b * denotes blue direction.

As a result of Experimental Examples 7 to 12, it was judged that the color difference value of all experimental groups was 3.0 or less, which is stable to monocytes. In addition, the experimental group and the negative control group showed similar patterns.

International standard evaluation table ΔE value evaluation Less than 0 ~ 0.5 When the color difference is trace (trace) 0.5 to less than 1.5 Slight Less than 1.5 ~ 3.0 Noticeable Less than 3.0 ~ 6.0 Appreciable 6.0 to less than 12.0 Much 12.0 or higher Very much

The determination of each color difference is made based on the color difference value by the National Bureau of Standard Unit (NBS) as shown in Table 12 above.

Evaluation criteria of "2013, Kangdae-day, Evaluation of Technology Evaluation and Development of Biocide Control System for Cultural Properties, National Institute of Cultural Properties, Korea Traditional Culture University" Respectively. However, at this time, the color difference DELTA E value of the negative control group should be 1.5 or less.

As shown in Table 11, the average ΔE value of the experimental group was 3.0 or less in this experiment. The pigments having a negative control value of 1.5 or more are selected from the group consisting of a polyol, a polyol, a polyol, a polyglycerol, a polyol, a polyol, a polyol, a polyol, Glue - loess, glue - rye, glue - permanent orange, glue - jade, glue - stone. The pigments with an average ΔE value of more than 3.0 in the negative control group are the polyol-polyol, glue-montan, and glue-polyol.

In the case of glue - jangdan, the negative control group showed a very high color difference value in all three times because the whitening phenomenon occurred in all of these pigments. However, the whitening phenomenon did not occur in the glue - tongue of the experimental group. In the positive control group, the color difference value was 3.0 or more in the case of the polyol, polyol, polyol, polyol, polyol, polyol, polyol, polyol, glue-sulfur, glue-loess and glue.

Considering the chrominance values of the negative control group, the biocidal composition is considered to be stable to monocyte.

It will be understood by those skilled in the art that the foregoing description of the present invention is for illustrative purposes only and that those of ordinary skill in the art can readily understand that various changes and modifications may be made without departing from the spirit or essential characteristics of the present invention. will be. It is therefore to be understood that the above-described embodiments are illustrative in all aspects and not restrictive.

Claims (10)

A pyrethroid-based compound, a solvent, and a carbamate-based compound;
Wherein the pyrethroid-based compound is metofluthrin;
The solvent is thiophene-based;
The carbamate-based compound may be iodopropynyl butyl carbamate (3-iodo-2-
propynylbutyl carbamate);
3- (N-butyl-N-acetyl) aminopropionic acid ethyl ester and a preservative;
0.1 to 20 parts by weight of the 3-iodo-2-propynylbutyl carbamate, 0.1 to 10 parts by weight of the metofluthrin, 1 to 50 parts by weight of 3- (N, N-butyl-N-acetyl) aminopropionic acid ethyl ester and 0.1 to 10 parts by weight of the preservative.
delete delete delete The method according to claim 1,
Wherein the weight ratio of 3- (Nn-butyl-N-acetyl) aminopropionic acid ethyl ester to the pyrethroid compound is from 1: 1 to 1:30, wherein 3- (Nn-butyl- N-acetyl) aminopropionic acid ethyl ester in a weight ratio of 1: 1 to 1: 30.
The method according to claim 1,
The preservative may be at least one of n-alkyl dimethyl benzyl ammonium chloride, benzethonium chloride, Cetrimonium chloride and Cetrimonium bromide. &Lt; / RTI &gt; wherein the carbamate-based compound comprises a carbamate-based compound.
The method according to claim 1,
0.1 to 20 parts by weight of a triazole-based compound.
delete The method according to claim 1,
Fungi killed by the biocidal composition include Aspergillus niger black fungus, Trichoderma viride blue mushroom fungus, Penicillium sp. Blue mold fungus, Rhizopus sp. Aureobasidium sp. Wherein the composition comprises at least one of black fungi and Trametes versicolor white rot fungi.
A method for controlling a biocidal composition according to any one of claims 1, 5, 6, 7, and 9,
Wherein the biocidal composition is diluted 1 to 100 times with respect to the volume of the diluent to control the biocide composition.

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