KR101676796B1 - A method for manufacturing of sponge powder having acicular structure and a sponge powder having acicular structure manufactured therefrom - Google Patents

Abstract

The present invention relates to a method for producing a sponge powder having a needle-like structure and a sponge powder having a needle-like structure manufactured therefrom, the method comprising: a pulverizing step of pulverizing the sponge to produce a sponge powder; And a reaction step in which the sea surface powder is charged into an aqueous hydrochloric acid solution and reacted. The aqueous hydrochloric acid solution is 200 to 600 parts by weight based on 100 parts by weight of the sea surface powder.
According to the present invention, by realizing a needle structure having a high ratio of acicular structure and minimizing adverse effects on skin, it is possible to provide various physical properties such as blood circulation, cell division promotion, There is an advantage that the reproduction effect can be realized.

Description

TECHNICAL FIELD [0001] The present invention relates to a method of manufacturing a sea surface powder having a needle-like structure and a sponge powder having a needle-like structure manufactured therefrom. BACKGROUND ART < RTI ID = 0.0 >

The present invention relates to a method for producing a sponge powder having a needle-like structure and a sponge powder having a needle-like structure prepared therefrom, and more particularly to a method for producing a sponge powder having a sponge structure by reacting a sponge with an aqueous hydrochloric acid solution and various physical / , About 70% or more acicular structure, and a sponge powder having a needle-like structure prepared therefrom.

Sponges are primitive marine organisms with no muscle, nerves or organs, and more than 5,000 species are present and are found regardless of the depth of the sea surface. And the skeleton is a tissue that functions as a needle-like skeleton existing in the body of invertebrate animals and mainly composed of silicic acid and calcium carbonate. In particular, sponges have single-, tri-, tetra-, or multi-axial fragments mainly composed of calcium carbonate or silicic acid.

Sponges are mainly sponge-like lumps of various colors, such as orange or turquoise, mainly in the sea, but freshwater sponges also exist. Sponges are the organisms at the beginning of the tissue with the cells in a cluster, and the body consists of sponge fibers, spicules that form the body wall, and cells that loosely bind to the fragments. The bone fragments are mainly composed of components such as calcareous, silicic acid or silica, and can be observed through a microscope since they are about 100 micrometers in size.

Sponges can also be divided into lime spongy, normal spongy, hexagonal spongy, and bone spongy, depending on the skeletal composition. The fibrous skeleton of sponges is absorbed by the capillary phenomenon and is used for bath, medical, art, cosmetic, slab printing, and machine cleaning.

Therefore, development to discover new uses as functional cosmetics such as promoting skin regeneration through physical / chemical treatments of bone fragments and the like of spongy animals as well as utilizing the physical properties of fragments of marine animals in the past Is required.

International Patent Publication No. 2005-034839

Disclosure of the Invention The present invention has been made to solve the above problems, and it is an object of the present invention to provide a sea surface powder having a needle-like structure containing about 70% or more acicular structure through a reaction of a sea surface with an aqueous hydrochloric acid solution and various physical / The purpose.

In addition, by implementing a needle structure with a high percentage of needle-shaped structure and minimized adverse effects on the skin, it is possible to obtain various skin cell regeneration effects such as blood circulation and cell division promotion as well as physical effects of skin exfoliation due to penetration of micro- It is an object of the present invention to provide a method for producing sea surface powder having an acicular structure that can be realized.

According to another aspect of the present invention, there is provided a method of manufacturing a sponge powder having a needle-shaped structure, the method comprising: grinding a sponge to produce a sponge powder; And a reaction step of adding the sea surface powder to an aqueous hydrochloric acid solution to react. The aqueous hydrochloric acid solution may be 200 to 600 parts by weight based on 100 parts by weight of the sea surface powder.

A first agitating step in which after the reaction step, the sea surface powder is filtered with a first filter, and then the sea surface powder is put into water and stirred; A second agitation step in which the sea surface powder is filtered with a second filter, and then charged into an organic solvent and stirred; And a drying step of filtering the sponge powder with a third filter and drying the sponge to produce a sea-surface powder having a needle-like structure.

In the pulverizing step, the sponge may include fragments of hexactinellid sponge. In the reaction step, the aqueous hydrochloric acid solution is formed by stirring hydrochloric acid and water at a concentration of 25 to 40 wt% The weight ratio of the hydrochloric acid and the water may be 1: 5 to 1:15.

In the first agitation step, the first filter may be a sieve having a size of 150 to 450 mesh. In the first agitation step, the water may be 200 to 500 parts by weight per 100 parts by weight of the sea- And in the second agitation step, the second filter is a paper filter, and the organic solvent may include ethanol.

Also, in the second agitation step, the organic solvent may be 150-300 parts by weight based on 100 parts by weight of the sea surface powder, and the drying step may be performed by drying the sea surface powder at 60-100 ° C for 10-30 hours , And the third filter may be a paper filter.

The sponge powder having the acicular structure formed by the drying step may be 85 to 95 parts by weight with respect to 100 parts by weight of the sponge powder in the pulverization step.

Next, the sea-surface powder having an acicular structure produced by the method for producing sea-surface powder having the needle-like structure, comprises 45 to 55% by weight of silica, 40 to 50% by weight of calcium oxide, 0.5 to 3% by weight of aluminum oxide, 0 to 2% by weight, and 0 to 0.5% by weight of iron oxide.

According to the method of manufacturing a sea surface powder having an acicular structure of the present invention and the sea surface powder having an acicular structure produced therefrom, unlike the prior art, the sea surface is treated with a hydrochloric acid aqueous solution and various physical / There is an advantage that it can include a needle-shaped structure.

In addition, by implementing a needle structure with a high percentage of needle-shaped structure and minimized adverse effects on the skin, it is possible to obtain various skin cell regeneration effects such as blood circulation and cell division promotion as well as physical effects of skin exfoliation due to penetration of micro- There are advantages to be implemented.

FIG. 1 is a photograph of a 400-fold enlarged photograph of sea surface powder prior to the reaction step (S20) in the method of manufacturing sea surface powder having an acicular structure according to the present invention.
FIG. 2 is a photograph of a 400-fold enlarged photograph of sea surface powder after the reaction step (S20) of the method of manufacturing sea surface powder having acicular structure according to the present invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, a preferred embodiment of the present invention will be described in detail with reference to the accompanying drawings, which show a method of manufacturing a sea surface powder having an acicular structure according to the present invention and a sea surface powder having an acicular structure manufactured therefrom. The present invention may be better understood by the following examples, which are for the purpose of illustrating the present invention and are not intended to limit the scope of protection defined by the appended claims.

The method of manufacturing a sea surface powder having an acicular structure according to the present invention includes a crushing step (S10), a reaction step (S20), a first stirring step (S30), a second stirring step (S40) and a drying step .

First, the pulverization step (S10) is a step of pulverizing the sea surface to produce a sea surface powder. This is an essential process for increasing the reactivity of the sea surface components and for achieving an excellent spreading effect to the skin.

The sponge may be a hexactinellid sponge, preferably Venus Flower Basket. In addition, it preferably includes the fragments of the sea surface.

The pulverizing step (S10) is preferably carried out in such a manner that pulverization is carried out such that the average particle diameter of the sea surface powder is 50 to 300 탆, preferably 75 to 200 탆, more preferably 100 to 150 탆, And is effective for application to the skin.

Here, there is a method of expressing the average size of the population by numerical value by the measurement method, but it is generally used that the diameter of the mode indicating the maximum value of the distribution, the median corresponding to the median value of the integral distribution curve (Average number, length average, area average, mass average, volume average, etc.), and unless otherwise specified in the present invention, the average particle diameter is a number average particle diameter, and D50 Of the particle diameter of the particles).

In the reaction step S20, the sea surface powder is put into an aqueous hydrochloric acid solution to react. This is an optimized process by which hydrochloric acid treatment of sea surface powder forms an efficient needle bed structure and removes the impurities contained in these.

In the reaction step S20, the aqueous hydrochloric acid solution is preferably formed by stirring hydrochloric acid and water at a concentration of 25 to 40 wt%, more preferably at a concentration of 30 to 38 wt% of hydrochloric acid and water, Is effectively formed by stirring hydrochloric acid and water in a concentration of 34 to 36% by weight. Considering mixing with water in this concentration range of hydrochloric acid, it is possible to maximize the reactivity and form an effective needle-shaped structure.

The weight ratio of the hydrochloric acid to the water may be 1: 5 to 1:15, preferably 1: 8 to 1:12, more preferably 1: 9 to 1:11, , 1:10. If the ratio is less than 1: 5, the ratio of acicular structure may be lowered due to the high ratio of hydrochloric acid. If the ratio is more than 1:15, the ratio of hydrochloric acid is lowered, There is a difficult problem.

In the first agitation step (S30), the sea surface powder is filtered with a first filter, and then the sea surface powder is put into water and stirred. This is a process for maintaining the needle-shaped structure by suppressing the side reaction by removing the residual hydrochloric acid from the sea surface powder through the reaction step (S20).

Here, the first filter may be a sieve having a size of 150 to 450 mesh. Preferably, it is effective to use a sieve having a size of 200 to 400 mesh, more preferably a size of 250 to 350 mesh. If it is less than 150 mesh or exceeds 450 mesh, there is a problem that it is difficult to filter off spongy powder particles or side-walled residues that are not sufficiently formed with needle-shaped structure.

In the first agitation step S30, the water may be 200 to 500 parts by weight, preferably 300 to 400 parts by weight, more preferably 310 to 340 parts by weight, based on 100 parts by weight of the sea surface powder. . When the amount is less than 200 parts by weight, it is difficult to sufficiently wash the side reaction materials such as residual hydrochloric acid. When the amount exceeds 500 parts by weight, the working efficiency is lowered.

In the second stirring step (S40), the sea surface powder is filtered with a second filter, and then the filtrate is stirred in an organic solvent. This is a purification process that removes materials that do not react with acids.

Here, the second filter may be a paper filter. Since the sea surface powder particles having a large size are removed by the agglomeration phenomenon, the paper filter is effective for removing the substances washed in the water in the first agitation step (S30).

The organic solvent is a substance which does not react with an acid, and serves to remove residues that can be removed with an organic solvent without being removed with water, and preferably includes ethanol.

The organic solvent may be 150 to 300 parts by weight, preferably 180 to 250 parts by weight, more preferably 180 to 200 parts by weight based on 100 parts by weight of the sea surface powder. This is effectively the content of organic solvent to remove residues.

Finally, in the drying step (S50), the sea surface powder is filtered with a third filter and then dried to produce a sea surface powder having a needle-like structure. This is a process for producing a sea surface powder having a sufficiently high acicular structure with high purity through final purification.

Here, the third filter may be a paper filter. The paper filter is effective for removing the substance washed out in the organic solvent in the second stirring step (S40).

In the drying step (S50), the sea surface powder may be dried at 60 to 100 DEG C for 10 to 30 hours. Preferably, it can be dried at 70 to 90 ° C for 15 to 25 hours, more preferably at 75 to 85 ° C for 18 to 22 hours. As a result of several experiments, it was confirmed that dried sea surface powder which can be applied to the skin efficiently without changing the needle bed structure under these conditions can be provided.

Also, with respect to 100 parts by weight of the sponge powder in the pulverization step, the sponge powder having the needle-shaped structure produced by the drying step (s50) may be 85 to 95 parts by weight. Preferably 86 to 90 parts by weight, and more preferably 87 to 89 parts by weight. This indicates that the yield of the final sponge powder after the initial sponge powder used in the pulverization step (S10) has gone through all the steps of the present invention, and that by about 90% by the method of producing the sponge powder having the acicular structure of the present invention, Was obtained in the same manner as in Example 1.

Next, a sponge powder having an acicular structure produced by the method for producing sea surface powder of the present invention comprises 45 to 55% by weight of silica, 40 to 50% by weight of calcium oxide, 0.5 to 3% by weight of aluminum oxide, 2% by weight, and 0 to 0.5% by weight of iron oxide. This shows the structure of the final sea surface powder when the sea surface is formed through various treatment processes by the manufacturing method of the sea surface powder of the present invention, and such sea surface powder composition can be made by the present invention.

In addition, under such a composition, it is possible to exhibit excellent functionality such as skin cell regeneration while minimizing adverse effects on the skin.

As shown in FIG. 1 and FIG. 2, when the sea surface powder according to the manufacturing method of the present invention was divided into 400 times magnification before and after the reaction step (S20), it was found that sufficient needle structure was not obtained before the reaction step (S20) Whereas, after the reaction step (S20), the distinct acicular structure is uniformly distributed. That is, through this experiment, it has been proved that, in the case of the present invention, a sufficient needle bed structure can be secured.

In addition, the needle part (Table 1) and the liquid part (Table 2), which were prepared by mixing the sea surface powder and the herbal composite extract according to the production method of the present invention, were directly mixed with each other as follows .

Ingredients content(%) Sea surface powder 93.5 Herb Complex Extract Powder 6.5

Here, the herb complex extract may be prepared by mixing various kinds of herbs.

Ingredients content(%) Purified water 73.97 Hydroxyethyl cellulose (HEC) 0.8 Levulinic acid 5.0 Glycolic acid 10.0 Triethanolamine (TEA) 4.6 Red ginseng extract (Rg2) 0.03 Organic aloe vera leaf extract 0.1 Organic green tea extract 0.1 Organic wedge extract 0.1 Organic licorice extract 0.1 Organic centipedes extract 0.1 glycerin 3.0 Diglycerin 2.0 TWEEN # 20 0.1

As a result of comparing the result of the one-time and four-time operations on the facial skin by mixing the acupuncture part and the liquid part before the treatment, it can be confirmed that the skin tone is remarkably improved as shown in FIG. 3, Likewise, the effect of sharply reducing pores was confirmed.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed exemplary embodiments. It is clear that the present invention can be suitably modified and applied in the same manner. Therefore, the above description does not limit the scope of the present invention, which is defined by the limitations of the following claims.

Claims (12)

A crushing step of crushing the sea surface to produce a sea surface powder;
A reaction step of charging the sea surface powder into an aqueous hydrochloric acid solution to cause a reaction;
A first agitation step of filtering the sea surface powder after the reaction step with a first filter, then filtering the sea surface powder filtered with the first filter, and stirring the water;
A second agitating step of filtering the sea surface powder after the first agitation step with a second filter, adding the agitation powder to the organic solvent and stirring the same; And
And a drying step of filtering the sea surface powder after the second agitation step with a third filter and then drying to produce a sea surface powder having an acicular structure.
The method according to claim 1,
Wherein the aqueous hydrochloric acid solution has an acicular structure in an amount of 200 to 600 parts by weight per 100 parts by weight of the sea surface powder.
The method according to claim 1,
Wherein, in the crushing step, the sponge has a needle-like structure including fragments of hexactinellid sponge.
The method according to claim 1,
In the reaction step, the hydrochloric acid aqueous solution is formed by stirring hydrochloric acid and water at a concentration of 25 to 40 wt%, and the weight ratio of hydrochloric acid and water is 1: 5 to 1:15. .
The method according to claim 1,
Wherein the first filter has a needle-like structure having a sieve of 150 to 450 mesh size in the first agitation step.
The method according to claim 1,
Wherein the water is 200 to 500 parts by weight per 100 parts by weight of the sea surface powder in the first agitation step. The method according to claim 1,
In the second agitation step, the second filter is a paper filter, and the organic solvent has an acicular structure including ethanol.
The method according to claim 1,
Wherein the organic solvent has an acicular structure in an amount of 150 to 300 parts by weight based on 100 parts by weight of the sea surface powder in the second agitation step.
The method according to claim 1,
Wherein the drying step comprises drying the sea surface powder at 60 to 100 DEG C for 10 to 30 hours, and the third filter is a paper filter having a needle-like structure.
The method according to claim 1,
Wherein the sponge powder having the needle-like structure produced by the drying step has an acicular structure in an amount of 85 to 95 parts by weight based on 100 parts by weight of the sponge powder in the pulverization step.
A sponge powder having an acicular structure produced by the method for producing sponge powder having the acicular structure according to any one of claims 1 to 10.
12. The method of claim 11,
The sponge powder having the needle-shaped structure comprises an acicular phase containing 45 to 55% by weight of silica, 40 to 50% by weight of calcium oxide, 0.5 to 3% by weight of aluminum oxide, 0 to 2% by weight of magnesium oxide, and 0 to 0.5% Sponge powder with structure.

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