KR101605114B1 - Method of manufacturing eco-friendly deodorant included Wasabia koreana for removing sick house syndrome - Google Patents
Method of manufacturing eco-friendly deodorant included Wasabia koreana for removing sick house syndrome Download PDFInfo
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- 208000008842 sick building syndrome Diseases 0.000 title claims abstract description 23
- 239000002781 deodorant agent Substances 0.000 title claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 241000390128 Eutrema Species 0.000 title 1
- 239000000843 powder Substances 0.000 claims abstract description 29
- 239000000203 mixture Substances 0.000 claims abstract description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 244000195452 Wasabia japonica Species 0.000 claims abstract description 14
- 235000000760 Wasabia japonica Nutrition 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims abstract description 10
- 235000019441 ethanol Nutrition 0.000 claims abstract description 9
- 239000008213 purified water Substances 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 240000003291 Armoracia rusticana Species 0.000 claims abstract description 3
- 235000011330 Armoracia rusticana Nutrition 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 4
- 238000007602 hot air drying Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 2
- 230000006835 compression Effects 0.000 claims 1
- 238000007906 compression Methods 0.000 claims 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract description 45
- 238000012360 testing method Methods 0.000 abstract description 16
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract description 12
- 239000000463 material Substances 0.000 abstract description 12
- 238000009833 condensation Methods 0.000 abstract description 9
- 230000005494 condensation Effects 0.000 abstract description 9
- 241000233866 Fungi Species 0.000 abstract description 6
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract description 3
- 239000008096 xylene Substances 0.000 abstract description 3
- 239000012855 volatile organic compound Substances 0.000 description 9
- 239000003054 catalyst Substances 0.000 description 7
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 6
- 241000894006 Bacteria Species 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 238000004332 deodorization Methods 0.000 description 4
- 235000019645 odor Nutrition 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- 230000001877 deodorizing effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 208000011580 syndromic disease Diseases 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- -1 titanium phosphate compound Chemical class 0.000 description 2
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 206010003645 Atopy Diseases 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 206010057190 Respiratory tract infections Diseases 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 231100000597 Sick building syndrome Toxicity 0.000 description 1
- 108010073771 Soybean Proteins Proteins 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229920005822 acrylic binder Polymers 0.000 description 1
- 239000000809 air pollutant Substances 0.000 description 1
- 231100001243 air pollutant Toxicity 0.000 description 1
- 238000004887 air purification Methods 0.000 description 1
- 229930013930 alkaloid Natural products 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000000840 anti-viral effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 231100000676 disease causative agent Toxicity 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000001962 electrophoresis Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 150000002338 glycosides Chemical class 0.000 description 1
- 150000001261 hydroxy acids Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000000243 photosynthetic effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229910052704 radon Inorganic materials 0.000 description 1
- SYUHGPGVQRZVTB-UHFFFAOYSA-N radon atom Chemical compound [Rn] SYUHGPGVQRZVTB-UHFFFAOYSA-N 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000002602 strong irritant Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 241000712461 unidentified influenza virus Species 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/013—Deodorant compositions containing animal or plant extracts, or vegetable material
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
- A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/20—Method-related aspects
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Botany (AREA)
- Zoology (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
본 발명은 고추냉이를 주재로 한 새집증후군 제거용 친환경 탈취제의 제조방법에 관한 것으로, (a) 고추냉이 분말 100 중량부에 대하여 정제수 10,000 ~ 13,000 중량부를 혼합하는 단계와; (b) 무수 에틸알코올 5 ~ 13 중량부를 더 충전한 다음, 교반기를 50 ~ 80rpm으로 30 ~ 90분 동안 회전시켜 혼합하는 단계와; (c) 백수오 분말 10 ~ 45 중량부, 벽오동(벽오동나무 열매) 분말 30 ~ 55 중량부 및 유기게르마늄 분말 1.5 ~ 2.5 중량부를 더 충전한 다음 교반기를 2,500 ~ 3,000rpm으로 30 ~ 60분간 교반한 후 여과하는 단계를 포함함으로써, 새집증후군 물질의 대표물질인 포름알데히드, 톨루엔, 자일렌 및 벤젠 등과 같은 휘발성 유기화합물(VOC)을 실내 마감재 표면에 간단한 도포를 통해 용이하고 확실하게 제거할 수 있는 바, 이는 시험성적서에 명기된 바와 같이 120분 이내에 48 μmol/mol의 농도의 포름알데히드를 90.0% 까지 탈취하고, 결로성 곰팡이를 480분 이내에 94.6%까지 제거할 수 있는 효과가 있다.(A) mixing 10,000 to 13,000 parts by weight of purified water with respect to 100 parts by weight of wasabi powder; (b) mixing the purified deodorant with 100 parts by weight of purified horseradish powder; (b) 5 to 13 parts by weight of anhydrous ethyl alcohol is further charged, and then the mixture is stirred by rotating the stirrer at 50 to 80 rpm for 30 to 90 minutes; (c) 10 to 45 parts by weight of white powder, 30 to 55 parts by weight of powder of Wakodong (nutshell) and 1.5 to 2.5 parts by weight of organic germanium powder are further charged, and then the mixture is stirred at 2,500 to 3,000 rpm for 30 to 60 minutes (VOC) such as formaldehyde, toluene, xylene and benzene, which are representative materials of the sick house syndrome material, can be easily and reliably removed on the surface of the interior finishing material by simple application. , It is possible to deodorize formaldehyde at a concentration of 48 μmol / mol up to 90.0% within 120 minutes and to remove the condensation fungus up to 94.6% within 480 minutes as specified in the test report.
Description
본 발명은 고추냉이를 주재로 한 새집증후군 제거용 친환경 탈취제 제조방법에 관한 것이다.
The present invention relates to a method for manufacturing an eco-friendly deodorant for removing sick house syndrome based on wasabi.
새집증후군은 집이나 건물을 새로 지을 때 사용하는 건축자재나 벽지 등에서 배어나오는 휘발성 벤젠·톨루엔·클로로포롬·아세톤·스타이렌·포름알데히드 등의 발암물질로 인한 불편함을 총칭하는 용어로써, 집을 지을 때 포함된 라돈, 석면, 일산화탄소, 이산화탄소, 질소산화물, 오존, 미세먼지, 부유세균과 같은 오염물질을 포함하기도 있다.Sick house syndrome is a generic term for the inconvenience caused by carcinogens such as volatile benzene, toluene, chloroform, acetone, styrene, and formaldehyde that come from building materials and wallpaper used to build new homes and buildings. It may also contain contaminants such as radon, asbestos, carbon monoxide, carbon dioxide, nitrogen oxides, ozone, fine dust, and airborne bacteria.
특히, 포름알데히드는 실온에서 자극성이 강한 냄새를 띤 무색의 기체로 새집증후군의 대표적인 물질이라 할 수 있다.In particular, formaldehyde is a colorless gas with a strong irritant odor at room temperature and is a representative material of sick house syndrome.
이러한 새집증후군을 제거하기 위해 제안된 대한민국 등록특허 제808094호(등록일자: 2008.2.21., 발명의 명칭: 새집 증후군의 원인이 되는 포름알데히드 및 휘발성 유기화합물을 제거하기 위한 탈취 및 항균성 조성물)는 새집 증후군 개선의 원인이 되는 포름알데히드 및 휘발성 유기화합물을 제거하기 위해, ⅰ) 광합성 세균, 슈퍼버그, 항산화 효모균 및 이들의 조합으로 이루어진 군에서 선택된 1종의 미생물 20∼60중량%; ⅱ) 피톤치드 수액, 테르펜, 폴리페놀, 알칼로이드, 글리코시드 및 이들의 조합으로 이루어진 군에서 선택된 1종의 식물성 정유 15∼35 중량%; ⅲ) 하이드록시에시드 10∼20 중량%; ⅳ) 질산은 1∼10 중량%; ⅴ) 대두 단백질, 견 단백질, 콜라겐 및 이들의 조합으로 이루어진 군에서 선택된 1종의 천연 단백질 5∼20 중량%; 및 ⅵ) 인산티타늄계 화합물 5∼20 중량%;를 포함하는 탈취 및 항균성 조성물이 개시되어 있다.Korean Patent Registration No. 808094 (registered on Feb. 21, 2008, entitled "Deodorizing and Antimicrobial Composition for Removing Formaldehyde and Volatile Organic Compound Causing Sick House Syndrome") proposed to eliminate this sick house syndrome In order to remove formaldehyde and volatile organic compounds which cause sick house syndrome improvement, 20 to 60% by weight of one microorganism selected from the group consisting of: i) photosynthetic bacteria, super bugs, antioxidant yeasts and combinations thereof; Ii) 15 to 35% by weight of one plant essential oil selected from the group consisting of phytoncide sap, terpenes, polyphenols, alkaloids, glycosides and combinations thereof; Iii) 10 to 20% by weight of hydroxy acid; Iv) 1 to 10% by weight of silver nitrate; V) 5 to 20% by weight of one natural protein selected from the group consisting of soy protein, dog protein, collagen and combinations thereof; And vi) 5 to 20% by weight of a titanium phosphate compound.
그러나, 이러한 종래 기술의 조성물은 초기 효과가 장시간 지속되지 못하는 문제점이 있었다.
However, such conventional compositions have a problem in that the initial effect can not be sustained for a long time.
이러한 문제점을 해소하기 위하여 제안된 본 출원인의 대한민국 등록특허 제1247161호(등록일자: 2013. 3. 19., 발명의 명칭: 새집증후군 제거용 나노산소 촉매제 제조방법)는 (1) 스테인레스 재질 탱크에 사염화티탄과 정제된 용수를 상온에서 1 : 100 비율로 탱크에 충전한 후 암모니아수를 0.20 내지 0.39 mol을 첨가하여 1차 교반하는 단계와; (2) 분리된 하층 용제인 순수한 이산화티탄 용액을 추출하여 스테인레스 재질의 탱크에 충전하는 단계와; (3) 질산 0.23 내지 0.35 mol을 첨가하여 교반한 후 실리카졸 0.12 내지 0.25 mol을 더 첨가하여 20 내지 50분간 2차 교반하는 단계와; (4) 아크릴 바인더 0.013 내지 0.03 mol과 미소량의 분산제 및 미소량의 EDTA를 함께 첨가하여 3차 교반하는 단계를 포함하는 새집증후군 제거용 나노산소 촉매제 제조방법이 개시되어 있다.In order to overcome such a problem, Korean Patent No. 1247161 of the present applicant (registered on March 19, 2013, entitled "Method for preparing nano oxygen catalyst for removal of sick house syndrome") proposed the present applicant to (1) Charging the tank with titanium tetrachloride and refined water at a ratio of 1: 100 at room temperature, adding 0.20 to 0.39 mol of aqueous ammonia, and stirring the mixture; (2) extracting a pure titanium dioxide solution, which is a separated lower layer solvent, and filling it into a stainless steel tank; (3) adding 0.23 to 0.35 mol of nitric acid, stirring the mixture, further adding 0.12 to 0.25 mol of silica sol, and stirring the mixture for 20 to 50 minutes; (4) adding 0.013 to 0.03 mol of an acrylic binder, a small amount of a dispersing agent and a small amount of EDTA together, and stirring the mixture for a third time, thereby producing a catalyst for removing sick house syndrome.
이러한 본 출원인의 등록특허는 새집증후군의 대표물질인 포름알데히드, 톨루엔, 자일렌 및 벤젠 등과 같은 휘발성 유기화합물(VOC)을 실내 마감재 표면에 간단한 도포를 통해 용이하고 확실하게 제거할 수 있는 바, 이는 시험성적서에 명기된 바와 같이 120분 이내에 48 μmol/mol의 농도의 포름알데히드를 89.6% 까지 탈취할 수 있음을 확인할 수 있으며, 휘발성 유기화합물이나 기타 오염물질과는 직접 반응하지 않는 촉매 타입으로써 반영구적으로 효능이 저하되지 않고 사용할 수 있는 특징이 있다. 이외에 본 출원인의 다른 등록특허 제1247162호(등록일자: 2013. 3. 19., 발명의 명칭: 정전기 방지 ＣＮＴ를 함유한 새집증후군 제거용 나노산소 촉매제 제조방법) 및 등록특허 제1328657호(등록일자: 2013. 11. 6., 발명의 명칭: 새집증후군 제거용 나노산소 촉매제) 역시 동일 유사한 효과가 있다.Such registered patent of the present applicant can easily and reliably remove volatile organic compounds (VOC) such as formaldehyde, toluene, xylene and benzene, which are representative materials of sick house syndrome, on the surface of the interior finishing material by simple application, As indicated in the test report, it can be confirmed that formaldehyde of 48 μmol / mol can be deodorized up to 89.6% within 120 minutes, and it is a catalyst type which does not react directly with volatile organic compounds or other contaminants. There is a feature that can be used without deteriorating the efficacy. In addition, another registered patent No. 1247162 of the present applicant (registration date: Mar. 19, 201, title of the invention: a method for producing a nano oxygen catalyst for removing sick house syndrome containing antistatic CNT) and registered patent No. 1328657 : Nov. 11, 201, entitled "Nano-oxygen catalyst for sick house syndrome removal") have the same effect.
그러나, 본 출원인의 나노산소 촉매제는 촉매 타입으로 반영구적으로 새집증후군을 제거할 수 있는 반면, 천연 성분이 아닌 화학 물질로 제조되어 100% 친환경적이지 못한 단점이 있었다.
However, the applicant's nano-oxygen catalyst has a disadvantage in that it can be semi-permanently removed from the sick house syndrome as a catalyst type, but is not 100% eco-friendly since it is made of a chemical substance which is not a natural ingredient.
상기와 같은 문제점을 해결하고자 창출된 본 발명의 목적은, 새집증후군 및 아토피의 주요 원인물질인 포름알데히드와 휘발성 유기화합물들을 제거하되, 인체에 무해하며 친환경적인 재료를 사용한 고추냉이를 주재로 한 새집증후군 제거용 친환경 탈취제를 제공함에 있다.
It is an object of the present invention, which is created to solve the above-mentioned problems, to eliminate formaldehyde and volatile organic compounds, which are the main causative agents of sick house syndrome and atopy, and to provide a new home for horseradish, which is harmless to the human body and uses eco- And to provide an eco-friendly deodorant for removing the syndrome.
이러한 본 발명의 목적은, (a) 고추냉이 분말 100 중량부에 대하여 정제수 10,000 ~ 13,000 중량부를 혼합하는 단계와; (b) 무수 에틸알코올 5 ~ 13 중량부를 더 충전한 다음, 교반기를 50 ~ 80rpm으로 30 ~ 90분 동안 회전시켜 혼합하는 단계와; (c) 백수오 분말 10 ~ 45 중량부, 벽오동(벽오동나무 열매) 분말 30 ~ 55 중량부 및 유기게르마늄 분말 1.5 ~ 2.5 중량부를 더 충전한 다음 교반기를 2,500 ~ 3,000rpm으로 30 ~ 60분간 교반한 후 여과하는 단계를 포함하는 고추냉이를 주재로 한 새집증후군 제거용 친환경 탈취제의 제조방법에 의해 달성될 수 있다.(A) mixing 10,000 to 13,000 parts by weight of purified water with respect to 100 parts by weight of wasabi powder; (b) 5 to 13 parts by weight of anhydrous ethyl alcohol is further charged, and then the mixture is stirred by rotating the stirrer at 50 to 80 rpm for 30 to 90 minutes; (c) 10 to 45 parts by weight of white powder, 30 to 55 parts by weight of powder of Wakodong (nutshell) and 1.5 to 2.5 parts by weight of organic germanium powder are further charged, and then the mixture is stirred at 2,500 to 3,000 rpm for 30 to 60 minutes Followed by filtration of the hatchery syndromes based on wasabi.
바람직하게는, 본 발명의 상기 고추냉이 분말은 고추냉이의 잔뿌리를 제거하여 20 ~ 25℃에서 이온수로 2 ~ 5회 세척한 후 70 ~ 95℃에서 2 ~ 3시간 열풍 건조하여 압착 여과하고, 120 ~ 150℃에서 열풍건조하여 10 ~ 85메시(mesh)로 분쇄된 것을 특징으로 한다.Preferably, the wasabi powder of the present invention is washed with ionized water at 20 to 25 ° C for 2 to 5 times at a temperature of 20 to 25 ° C, followed by hot air drying at 70 to 95 ° C for 2 to 3 hours, Followed by hot-air drying at 150 ° C to be pulverized to 10 to 85 mesh.
바람직하게는, 본 발명의 상기 백수오 분말은 10 ~ 50 메시, 상기 벽오동 분말은 10 ~ 30 메시 및 상기 유기게르마늄 분말은 100 ~ 250 메시의 입경을 갖는 것을 특징으로 한다.Preferably, the white pearl powder of the present invention has 10 to 50 mesh, the wall pore powder has 10 to 30 mesh, and the organic germanium powder has a particle diameter of 100 to 250 mesh.
바람직하게는, 본 발명의 상기 (c)단계 이후에, 80 ~ 120℃로 10 ~ 25분 동안 가열하여 알코올 성분을 완전히 배기시켜 제거한 후, 밀폐 용기에 담아 5 ~ 15℃ 온도에서 보관하는 (d)단계를 더 포함하는 것을 특징으로 한다.
Preferably, after the step (c) of the present invention, the alcohol component is completely removed by evacuation by heating at 80 to 120 ° C for 10 to 25 minutes, and then the solution is stored in a sealed container at a temperature of 5 to 15 ° C ). ≪ / RTI >
이상과 같은 본 발명은 새집증후군 물질의 대표물질인 포름알데히드, 톨루엔, 자일렌 및 벤젠 등과 같은 휘발성 유기화합물(VOC)을 실내 마감재 표면에 간단한 도포를 통해 용이하고 확실하게 제거할 수 있는 바, 이는 시험성적서에 명기된 바와 같이 120분 이내에 48 μmol/mol의 농도의 포름알데히드를 90.0% 까지 탈취할 수 있음을 확인할 수 있다.The present invention can easily and reliably remove volatile organic compounds (VOC) such as formaldehyde, toluene, xylene and benzene, which are representative materials of sick building syndrome material, on the surface of the interior finishing material by simple application, As indicated in the test report, it can be confirmed that formaldehyde with a concentration of 48 μmol / mol can be deodorized up to 90.0% within 120 minutes.
또한, 본 발명은 결로성 곰팡이를 480분 이내에 94.6%까지 제거할 수 있는 효과가 있다.
In addition, the present invention has the effect of removing condensation fungus up to 94.6% within 480 minutes.
이하, 본 발명의 실시예를 도면을 참조하여 설명하기로 한다.
Hereinafter, embodiments of the present invention will be described with reference to the drawings.
1. 고추냉이를 주재로 한 새집증후군 제거용 친환경 탈취제 1. Eco-friendly deodorant for removing sick house syndrome based on wasabi
주재료인 고추냉이 분말 100 중량부에 대하여 정제수 10,000 ~ 13,000 중량부를 스테인레스스틸 탱크(이하, "탱크"라 한다)에 충전한다. 여기서, 고추냉이 분말은 고추냉이의 잔뿌리를 제거하여 20 ~ 25℃에서 이온수로 2 ~ 5회 세척한 후 70 ~ 95℃에서 2 ~ 3시간 열풍 건조한다. 그런 다음, 압착하여 여과한 후 120 ~ 150℃에서 열풍건조하여 10 ~ 85메시(mesh)로 분쇄되어 제조된다.10,000 parts by weight to 13,000 parts by weight of purified water is charged into a stainless steel tank (hereinafter referred to as "tank ") with respect to 100 parts by weight of wasabi powder as the main material. Here, the wasabi powder is washed with ionized water 2 ~ 5 times at 20 ~ 25 ℃ and then hot air dried at 70 ~ 95 ℃ for 2 ~ 3 hours. Then, it is compressed, filtered, and then hot-air dried at 120 to 150 ° C to be pulverized to 10 to 85 mesh.
이후, 무수 에틸알코올 5 ~ 13 중량부를 탱크에 충전한 다음, 교반기를 50 ~ 80rpm으로 30 ~ 90분 동안 회전시켜 혼합한다.Then, 5 to 13 parts by weight of anhydrous ethyl alcohol is charged into the tank, and the mixture is stirred by rotating the stirrer at 50 to 80 rpm for 30 to 90 minutes.
그런 다음, 백수오 분말 10 ~ 45 중량부, 벽오동(벽오동나무 열매) 분말 30 ~ 55 중량부 및 유기게르마늄 분말 1.5 ~ 2.5 중량부를 충전한 다음 교반기를 2,500 ~ 3,000rpm으로 30 ~ 60분간 교반한 후 여과한다. 여기서, 백수오 분말은 10 ~ 50 메시(mesh), 벽오동 분말은 10 ~ 30 메시 그리고, 유기게르마늄 분말은 100 ~ 250 메시의 입경을 갖는 것이 바람직하다. 특히, 유기게르마늄 분말은 신맛이 나는 흰색 분말로써 물에 잘 녹기 위해서 위와 같은 입경을 갖는 것이 중요하다.Then, 10 to 45 parts by weight of white powders, 30 to 55 parts by weight of Wang Dong-Dong (powdered nuts) powder and 1.5 to 2.5 parts by weight of organic germanium powder are charged, and the mixture is agitated at 2,500 to 3,000 rpm for 30 to 60 minutes Filter. In this case, it is preferable that the particle size of the white pearl powder is 10 to 50 mesh, the wall pore powder is 10 to 30 mesh, and the organic germanium powder has a particle size of 100 to 250 mesh. In particular, organic germanium powder is an acidic white powder, and it is important to have the above-mentioned particle size in order to dissolve well in water.
마지막으로, 80 ~ 120℃로 10 ~ 25분 동안 가열하여 알코올 성분을 완전히 배기시켜 제거한 후, 밀폐 용기에 담아 5 ~ 15℃ 정도의 저온에서 보관한다.
Finally, it is heated at 80 to 120 ° C for 10 to 25 minutes to completely remove the alcohol component and then stored in a sealed container at a low temperature of about 5 to 15 ° C.
여기서, 벽오동 분말이 25 중량부 미만이거나 60 중량부 이상인 경우에는 하기의 시험성적서와 동일한 방법으로 포름알데히드의 탈취율을 시험하면 70% 미만으로 탈취율이 현저히 저하된다. 따라서, 백수오 분말은 본 실시예에서 예시하고 있는 중량부를 지키는 것이 바람직하다.
Herein, when the wall epoxy powder is less than 25 parts by weight or more than 60 parts by weight, the deodorization ratio of formaldehyde is less than 70% when the deodorization rate is tested in the same manner as the following test report. Therefore, it is preferable that the white powder and the powder are in the weight portion exemplified in this embodiment.
본 발명에 의한 친환경 탈취제는, 고추냉이와 벽오동의 강력한 살균작용으로 실내 마감재에 도포된 경우 각종 병원균, 곰팡이의 번식을 원천 차단함은 물론, 공기 중의 박테리아를 접촉에 의해 살균할 수 있는 특징이 있다.
The eco-friendly deodorant according to the present invention is characterized by being able to sterilize bacteria in the air by not only blocking the propagation of various pathogens and fungi when applied to the interior finishing material due to a strong sterilizing action of wasabi and wall scoop .
2. 천연 친환경 탈취제의 특성 2. Characteristics of Natural Eco-deodorant
먼저, 고추냉이를 주재로 한 새집증후군 제거용 친환경 탈취제는 고추냉이를 주재료로 하여 무수 에틸알코올, 백수오 분말, 벽오동 분말 및 유기게르마늄 분말로부터 교반과 여과 공정을 통해 강력한 탈취기능을 갖는 액상타입의 천연 탈취제이다.First, the eco - friendly deodorizer for removing the sick house syndrome based on wasabi is made from anhydrous ethyl alcohol, white water powder, wall electrophoresis powder and organic germanium powder by using stirring and filtration process. It is a natural deodorant.
그리고, 이러한 본 발명의 천연 친환경 탈취제는 실내 마감재에 직접 도포하여 새집증후군의 여러 원인물질들을 2차 오염원의 배출없이 신속하게 제거하는 천연 탈취제 조성물이다(표 2 참조).The natural eco-friendly deodorant of the present invention is a natural deodorant composition which is directly applied to indoor finishes to rapidly remove various causative substances of sick house syndrome without discharging secondary pollutants (see Table 2).
또한 본 발명의 구성은 안정된 중성의 액상타입으로, 화학적으로 안정적이며 인체에 무해한 물성을 가진 신소재이다.
The composition of the present invention is a stable, neutral liquid type, chemically stable, and has new physical properties that are harmless to human body.
3. 천연 친환경 탈취제의 주요 기능 3. Main function of natural eco-friendly deodorant
- 휘발성 유기 화합물 제거- Removal of volatile organic compounds
- 향균(멸균)작용: 병원성 대장균, 인플루엔자 바이러스, 박테리아 등의 유해세균 제거- Antibacterial (sterilization) action: elimination of harmful bacteria such as pathogenic Escherichia coli, influenza virus, bacteria
- 악취제거: 담배의 니코틴, 곰팡이, 화장실의 암모니아 냄새 등의 각종 악취제거- Removing odor: Removing various odors such as nicotine, mold, ammonia odor in toilet
특히 본 발명의 탈취제는 결로성 곰팡이를 94.6%까지 제거할 수 있는 효과가 있다(표 3 참조).In particular, the deodorant of the present invention has the effect of removing the dewy fungus up to 94.6% (see Table 3).
- 공기정화: 질소산화물 또는 유황산화물인 대기오염물질을 분해하여 정화- Air purification: decompose and purify air pollutants such as nitrogen oxides or sulfur oxides.
- 오염방지: 초 친수성 코팅막을 형성하여 피도포 대상물의 오염을 사전방지- Pollution prevention: Preventing contamination of objects to be coated by forming ultra-hydrophilic coating film
특히, 본 발명의 유기게르마늄은 수용성 물질로써 원적외선 방사 및 항바이러스 작용이 있다.
In particular, the organic germanium of the present invention is a water-soluble substance and has far-infrared radiation and antiviral action.
4. 천연 친환경 탈취제의 항목별 성능지표 4. Performance indicators of natural eco-friendly deodorant items
본 발명의 항목별 성능지표는 하기 표 1과 같은 성능지표를 갖는다.The performance indicators for each item of the present invention have the performance indicators as shown in Table 1 below.
5. 포름알데히드 탈취 시험 5. Formaldehyde deodorization test
시험 방법은 체적 2m3의 밀폐용기 내부에 50mm(H) X 150mm(V) X 10mm(T) 크기의 유리판을 안착시키고, 그 유리판의 상부면에 48 μmol/mol의 농도의 포름알데히드를 도포한 동일한 조건하에서, 대조구와 실시예 1을 동일량 분무하여 시험 전후의 포름알레히드 방출량을 측정하여 대조구와 실시예 1의 포름알데히드 제거율을 측정하되, 시험의 정밀도를 높이기 위하여 10회 이상 반복하여 시험의 평균값을 기록한다. 여기서, 대조구는 정제수이며, 실시예 1은 본 발명에 의한 탈취제이다. 시험 조건은 온도 25±0.5℃, 상대습도 25±5%이다.In the test method, a glass plate having a size of 50 mm (H) X 150 mm (V) X 10 mm (T) was placed in a closed container having a volume of 2 m 3 and a formaldehyde having a concentration of 48 μmol / Under the same conditions, the amount of formaldehyde released before and after the test was measured by spraying the same amount of the control and Example 1, and the formaldehyde removal rate of the control and Example 1 was measured. To increase the precision of the test, Record the average value. Here, the control is purified water, and Example 1 is a deodorant according to the present invention. The test conditions are a temperature of 25 ± 0.5 ° C and a relative humidity of 25 ± 5%.
본 발명의 천연 친환경 탈취제의 포름알데히드 탈취능은 자체 검정결과 표 2와 같은 결과를 얻을 수 있었다.The deodorization ability of formaldehyde of the natural eco-friendly deodorizer of the present invention was found to be as shown in Table 2 as a result of self-testing.
검정결과는 표 2와 같이, 120분 이내에 농도 48 μmol/mol의 포름알데히드를 90.0% 까지 탈취할 수 있음을 확인할 수 있다.As a result of the test, it can be seen that formaldehyde with a concentration of 48 μmol / mol can be deodorized up to 90.0% within 120 minutes as shown in Table 2.
따라서, 본 발명의 실시예 1은 새집증후군의 대표 물질인 포름알레히드에 대한 매우 강력한 탈취능이 있다는 것이 판명되었다.Thus, it was found that Example 1 of the present invention has a very strong deodorizing ability against formaldehyde, which is a representative material of sick house syndrome.
6. 결로성 곰팡이 제거시험 6. Condensation Mold Removal Test
시험 방법은 체적 10m3의 챔버 내부에 결로성 곰팡이가 형성된 1,100mm(H) X 600mm(V) X 5mm(T) 크기의 벽지를 투입하고, 그 벽지의 상부면에 대조구와 실시예 2를 동일량 분무한 후 60분 마다 대조구 및 실시예 2의 곰팡이 제거율을 측정하되, 시험의 정밀도를 높이기 위하여 10회 이상 반복하여 시험의 평균값을 기록한다. 여기서, 대조구는 정제수이며, 실시예 2은 본 발명에 의한 탈취제이다. 시험 조건은 온도 25±0.5℃, 상대습도 25±5%이다.The test method was as follows: A 1,100 mm (H) X 600 mm (V) X 5 mm (T) sized wallpaper in which a condensation mold was formed in a chamber having a volume of 10 m 3 was put into the chamber. The amount of fungus removal in the control and Example 2 is measured every 60 minutes after the spraying, and the average value of the test is repeated 10 times or more in order to increase the precision of the test. Here, the control is purified water, and Example 2 is a deodorizing agent according to the present invention. The test conditions are a temperature of 25 ± 0.5 ° C and a relative humidity of 25 ± 5%.
결로성 곰팡이가 형성된 벽지는 1,000mm(H) X 1,000mm(V) X 5mm(T) 크기이며, 위 벽지의 결로성 곰팡이가 형성된 부분은 500mm(H) X 250mm(V)으로 각기 50mm(H) X 50mm(V) 크기로 구분하여 50개의 부분으로 나누며, 표 3은 시험 전후에 결로형 곰팡이의 발생 부분수를 기재하였다. 예를 들어, 시험 초기인 0분의 경우 대조구 및 실시예 2 모두 결로형 곰팡이 발생 부분수는 모두 50개 이었으며, 60분 경과후 대조구는 49개, 실시예 2는 38개 이었다.The wall with condensation fungus is 1,000mm (H) X 1,000mm (V) X 5mm (T) and the part where the condensation mold is formed is 500mm (H) X 250mm (V) ) X 50 mm (V) size, and divided into 50 parts. Table 3 shows the number of parts of the dew condensation mold before and after the test. For example, in the case of 0 min at the initial stage of the test, the number of the dew condensation molds was 50 in all of the control and Example 2, and 49 in the control and 38 in the Example 2 after 60 minutes.
표 3을 참조하면, 본 발명의 실시예 2는 360분 이내에 결로성 곰팡이의 발생 부분수를 2.7로 줄여 94.6%의 곰팡이 제거율을 보이고 있음을 확인할 수 있었다. 결과적으로, 본 발명의 실시예 2는 결로성 곰팡이에 대한 매구 강한 살균능이 있다는 것이 판명되었다.
Referring to Table 3, in Example 2 of the present invention, it was confirmed that the number of moult of molds was reduced to 2.7 within 360 minutes and 94.6% of mildew removal rate was exhibited. As a result, it was found that Example 2 of the present invention has strong antimicrobial activity against dew condensation mold.
이상과 같은 본 발명은 일 실시예에 한정되어 설명되었으나, 이에 한정되지 않고 본 발명의 기술적 사상을 토대로 변형되는 실시예들은 모두 본 발명의 권리범위에 속함이 분명하다.While the present invention has been described with reference to exemplary embodiments, it is to be understood that the invention is not limited to the disclosed exemplary embodiments.
Claims (4)
(b) 무수 에틸알코올 5 ~ 13 중량부를 더 충전한 다음, 교반기를 50 ~ 80rpm으로 30 ~ 90분 동안 회전시켜 혼합하는 단계와;
(c) 백수오 분말 10 ~ 45 중량부, 벽오동(벽오동나무 열매) 분말 30 ~ 55 중량부 및 유기게르마늄 분말 1.5 ~ 2.5 중량부를 더 충전한 다음 교반기를 2,500 ~ 3,000rpm으로 30 ~ 60분간 교반한 후 여과하는 단계를 포함하는 고추냉이를 주재로 한 새집증후군 제거용 친환경 탈취제의 제조방법.
(a) mixing 10,000 to 13,000 parts by weight of purified water with respect to 100 parts by weight of wasabi powder;
(b) 5 to 13 parts by weight of anhydrous ethyl alcohol is further charged, and then the mixture is stirred by rotating the stirrer at 50 to 80 rpm for 30 to 90 minutes;
(c) 10 to 45 parts by weight of white powder, 30 to 55 parts by weight of powder of Wakodong (nutshell) and 1.5 to 2.5 parts by weight of organic germanium powder are further charged, and then the mixture is stirred at 2,500 to 3,000 rpm for 30 to 60 minutes And filtering the sick house syndrome based on wasabi.
상기 고추냉이 분말은 고추냉이의 잔뿌리를 제거하여 20 ~ 25℃에서 이온수로 2 ~ 5회 세척한 후 70 ~ 95℃에서 2 ~ 3시간 열풍 건조하여 압착 여과하고, 120 ~ 150℃에서 열풍건조하여 10 ~ 85메시(mesh)로 분쇄된 것을 특징으로 하는 고추냉이를 주재로 한 새집증후군 제거용 친환경 탈취제의 제조방법.
The method according to claim 1,
The horseradish powder was washed with ionized water at 20 to 25 ° C for 2 to 5 times at a temperature of 20 to 25 ° C, followed by hot air drying at 70 to 95 ° C for 2 to 3 hours, followed by compression filtration and hot air drying at 120 to 150 ° C Wherein the powder is pulverized to 10 to 85 mesh. 2. The method for producing an eco-friendly deodorant for removing sick house syndrome based on wasabi.
상기 백수오 분말은 10 ~ 50 메시, 상기 벽오동 분말은 10 ~ 30 메시 및 상기 유기게르마늄 분말은 100 ~ 250 메시의 입경을 갖는 것을 특징으로 하는 고추냉이를 주재로 한 새집증후군 제거용 친환경 탈취제의 제조방법.
The method according to claim 1,
Wherein said powdery white powder has a particle size of 10 to 50 mesh, said wall active powder has 10 to 30 mesh and said organic germanium powder has a particle size of 100 to 250 mesh. Way.
상기 (c)단계 이후에, 80 ~ 120℃로 10 ~ 25분 동안 가열하여 알코올 성분을 완전히 배기시켜 제거한 후, 밀폐 용기에 담아 5 ~ 15℃ 온도에서 보관하는 (d)단계를 더 포함하는 것을 특징으로 하는 고추냉이를 주재로 한 새집증후군 제거용 친환경 탈취제의 제조방법.The method according to claim 1,
(D) further comprising the step of heating the mixture at 80 to 120 ° C. for 10 to 25 minutes to completely remove the alcohol component after the step (c), removing the alcohol component from the mixture, and storing the mixture in a sealed container at a temperature of 5 to 15 ° C. A method for manufacturing an eco-friendly deodorant for removing sick house syndrome based on wasabi.
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| KR102015472B1 (en) | 2019-04-23 | 2019-08-28 | 장지원 | Manufacturing method for environment-friendly deodorant and environment-friendly deodorant manufactured by the same |
| KR102092283B1 (en) | 2019-10-10 | 2020-03-23 | 유한회사 성화실업 | Fluid deodorant composition |
| KR102132978B1 (en) | 2019-10-17 | 2020-07-10 | (주)성원화장품 | Phytoncide deodorant and Manufactuing method of the same |
| KR102263854B1 (en) | 2020-10-29 | 2021-06-14 | (주)엔젤에스캄 | Composition for removing oder, and manufacturing mehtod thereof |
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| JPWO2017038728A1 (en) | 2015-08-28 | 2018-06-14 | 出光興産株式会社 | COMPOUND, MATERIAL FOR ORGANIC ELECTROLUMINESCENT ELEMENT, ORGANIC ELECTROLUMINESCENT ELEMENT, AND ELECTRONIC DEVICE |
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| JP2002114617A (en) | 2000-10-04 | 2002-04-16 | Yamaso Micron:Kk | Natural deodorizing antimicrobial agent, deodorizing antimicrobial product using the same and deodorizing antimicrobial method using the same |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| KR102015472B1 (en) | 2019-04-23 | 2019-08-28 | 장지원 | Manufacturing method for environment-friendly deodorant and environment-friendly deodorant manufactured by the same |
| KR102092283B1 (en) | 2019-10-10 | 2020-03-23 | 유한회사 성화실업 | Fluid deodorant composition |
| KR102132978B1 (en) | 2019-10-17 | 2020-07-10 | (주)성원화장품 | Phytoncide deodorant and Manufactuing method of the same |
| KR102263854B1 (en) | 2020-10-29 | 2021-06-14 | (주)엔젤에스캄 | Composition for removing oder, and manufacturing mehtod thereof |
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