KR101441360B1 - Cosmetic composition for oily cleansing - Google Patents
Cosmetic composition for oily cleansing Download PDFInfo
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- KR101441360B1 KR101441360B1 KR1020070137795A KR20070137795A KR101441360B1 KR 101441360 B1 KR101441360 B1 KR 101441360B1 KR 1020070137795 A KR1020070137795 A KR 1020070137795A KR 20070137795 A KR20070137795 A KR 20070137795A KR 101441360 B1 KR101441360 B1 KR 101441360B1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/042—Gels
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
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- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/26—Optical properties
- A61K2800/262—Transparent; Translucent
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Abstract
본 발명은 유성 클렌징용 화장료 조성물에 관한 것으로서, 더욱 상세하게는 투명 또는 반투명한 액상 또는 젤상을 나타내며, 비이온성 계면활성제와 이온성 계면활성제의 조합을 통하여 내수성과 뛰어난 클렌징력을 가짐과 동시에 기존에 비해 사용성과 마사지감이 향상되고 물세안 후 잔여감이 개선된 유성 클렌징용 화장료 조성물에 관한 것이다.The present invention relates to a cosmetic composition for oily cleansing, and more particularly, to a cosmetic composition for oily cleansing which is transparent or semitransparent in a liquid or gel phase and has a water resistance and an excellent cleansing power through the combination of a nonionic surfactant and an ionic surfactant. The present invention relates to a cosmetic composition for oily cleansing which has improved usability and massage feeling and improved residual feeling after water cleansing.
클렌징 * 비이온성계면활성제 * 이온성계면활성제 * 씻김성 * 내수성 Cleansing * Nonionic Surfactant * Ionic Surfactant * Washability * Water Resistance
Description
본 발명은 비이온성 계면활성제와 이온성 계면활성제의 조합을 통하여 기존보다 마사지감과 도포성이 개선되고 물세안 후 오일감이 감소된 유성 클렌징용 화장료 조성물에 관한 것이다.The present invention relates to a cosmetic composition for oily cleansing which is improved in massage feeling and spreadability and reduced in oiliness after water cleansing through the combination of a nonionic surfactant and an ionic surfactant.
피부의 더러움이나 메이크업을 지우기 위한 클렌징 화장료로서 크림상, 유액상, 젤상, 오일상, 액상 등이 있으며, 제형적 분류에 따르면 에멀젼, 유성, 수성 타입이 있다.Cleansing cosmetics for cleansing the dirt and make-up of the skin include cream, oil, gel, oily, and liquid, and emulsion, oily, and aqueous type according to the formulation classification.
수성 타입의 경우 물과 폴리올을 이용한 베이스에 소량의 오일과 이온성 및 비이온성 계면활성제를 혼합 사용하여 클렌징 효과를 부여한 것으로, 사용감이 산뜻하다는 특징을 가지고 있으나, 메이크업 제거력이 낮다는 단점을 지니고 있다. In the case of the aqueous type, a cleansing effect is imparted by mixing a small amount of oil with an ionic and nonionic surfactant in a base using water and a polyol. However, it has a disadvantage in that the feeling of use is neat, but the makeup removing power is low .
유성 타입을 대표하는 클렌징 오일은 수상을 포함하지 않고 100% 오일을 사용한 것으로 메이크업과 외부에서 피부에 부착되는 더러움과의 용해성이 매우 우수하여 탁월한 클렌징 효과가 있다는 장점이 있다. 그러나 점도가 낮은 오일상이므로 흐르기 쉬워 사용시 불편함이 있고 사용감도 다양화하기 어려우며, 사용 후 오일이 피부에 남아 있게 되면 씻김성이 나빠져서 반드시 물세안 후 이중 세안을 필요로 한다는 단점을 가지고 있다. Cleansing oil, which represents oil-based type, does not contain a water-based oil and uses 100% oil. It has an excellent cleansing effect because it has excellent solubility with makeup and dirt adhered to skin from the outside. However, since it is easy to flow because it is low viscosity oil, it is inconvenient to use and it is difficult to diversify feeling of use, and if oil remains on the skin after use, the washability is deteriorated.
최근 지속력이 우수한 메이크업 제품의 개발이 늘고 있어 클렌징 효과가 가장 탁월한 오일 타입의 제품에 대한 시장 선호도가 점점 증가하고 있으며, 클렌징 시장에서 가치가 매우 높아지고 있다. 따라서 일정량의 수상을 포함하여 젖은 손에서 사용할 수 있게 하거나 유성 점도조절제를 사용하여 쉽게 흘러내리는 것을 막는 등 여러 가지 단점을 개선한 제품들이 등장하고 있다. 그러나 물세안 후 잔여감의 측면에서는 비이온성 계면활성제의 종류 및 비율을 바꾸더라도 큰 진보가 없었다.With the recent development of make-up products with superior sustainability, the market for oil-type products with the most excellent cleansing effect is increasingly increasing in the market, and the value in the cleansing market is increasing. Therefore, there are some products that improve various disadvantages such as being able to use in a wet hand including a certain amount of water, or to prevent easy flow by using an oil viscosity controlling agent. However, in terms of residual after water washing, there was no significant improvement in the type and ratio of nonionic surfactants.
따라서 본 발명은 뛰어난 메이크업 제거력과 내수성을 지니는 투명 또는 반투명 액상, 또는 젤상의 클렌징 조성물의 제형을 만듦과 동시에 사용시 도포용이성, 마사지감 및 세안 후 잔여감을 크게 개선시킨 유상의 클렌징 화장료 조성물을 제공하는 것을 목적으로 한다.Accordingly, it is an object of the present invention to provide an oily cleansing cosmetic composition which is improved in ease of application, feeling of massage and remnant feeling after cleansing, while forming a clear or translucent liquid or gel-like cleansing composition having excellent makeup removing power and water resistance The purpose.
상기 목적을 달성하기 위하여, 본 발명은 비이온성 계면활성제, 이온성 계면활성제, 유상 성분 및 수상 성분을 함유하는 유성 클렌징용 화장료 조성물을 제공한다.In order to achieve the above object, the present invention provides a cosmetic composition for oily cleansing, which comprises a nonionic surfactant, an ionic surfactant, an oily component and an aqueous phase component.
본 발명의 유성 클렌징용 화장료 조성물은 클렌징력이 우수하고 내수성을 가짐과 동시에 비이온성 계면활성제와 음이온성 계면활성제의 적절한 조합 및 비율을 이용하여 기존 유성 클렌징 제품의 씻김성에 대한 고질적인 문제점을 크게 개선함과 동시에 마사지감과 도포성 또한 개선되었다.The cosmetic composition for oily cleansing according to the present invention has excellent cleansing power and water resistance and at the same time greatly improves the existing problems of washability of existing oily cleansing products by using an appropriate combination and ratio of nonionic surfactant and anionic surfactant At the same time, the feeling of massage and applicability were improved.
본 발명의 클렌징용 화장료 조성물은 비이온성 계면활성제, 이온성 계면활성 제, 유상 성분 및 수상 성분을 포함한다.The cosmetic composition for cleansing of the present invention includes a nonionic surfactant, an ionic surfactant, an oil component and an aqueous component.
본 발명에서 사용하는 비이온성 계면활성제는 소수기로는 탄소수 C10-54의 탄화수소기 또는 탄화수소 실리콘을 사용할 수 있고, 상기 탄화수소기 또는 탄화수소 실리콘의 탄화수소기는 직쇄형, 분지형을 포함하는 것이며, 다중결합을 모두 포함하는 것이고, 보다 구체적으로는 알킬, 디메틸 실리콘을 사용할 수 있으며, 친수기로는 폴리글리세릴 계, 폴리에틸렌글리콜(polyethylene glycol) 계, 글루코시드 계 등을 사용할 수 있다. 본 발명에서는 라우릴 글루코시드, 데실 글루코시드 등의 글루코시드계, PEG-20 글리세릴 트리이소스테아레이트, PEG-15 글리세릴 이소스테아레이트 등의 폴리에틸렌글리콜(polyethylene glycol) 계, 폴리글리세릴-3 디이소스테아레이트, 폴리글리세릴-10 디올리에이트 등의 폴리글리세릴계의 비이온성 계면활성제를 사용하였다. The nonionic surfactant used in the present invention may be a hydrocarbon group or hydrocarbon silicone having a carbon number of 10 to 54 as a hydrophobic group, and the hydrocarbon group or the hydrocarbon group of the hydrocarbon silicone includes a linear or branched type, More specifically, alkyl or dimethyl silicone can be used. As the hydrophilic group, a polyglyceryl series, a polyethylene glycol series, a glucoside series, or the like can be used. In the present invention, a polyethylene glycol type such as glucoside type such as lauryl glucoside and decyl glucoside, PEG-20 glyceryl triisostearate and PEG-15 glyceryl isostearate, polyglyceryl-3 Polyglyceryl type nonionic surfactants such as diisostearate and polyglyceryl-10 diallylate were used.
비이온성 계면활성제는 조성물 총 중량에 대하여 5~50중량%의 양으로 함유된다. 5 중량% 미만으로 함유될 경우 씻김성이 나빠지고 50 중량%를 초과하여 첨가되게 되면 피부 건조증 유발과 단가 증가등의 단점을 지니고 있기 때문이다.The nonionic surfactant is contained in an amount of 5 to 50% by weight based on the total weight of the composition. If it is contained in an amount of less than 5% by weight, the washability deteriorates. If it is added in an amount of more than 50% by weight, it causes disadvantages such as induction of skin dryness and increase of the unit price.
본 발명에서 사용하는 이온성 계면활성제는 음이온성 계면활성제로, 음이온성 계면활성제의 종류가 엄격하게 제한되지는 않으나, 사용하는 오일과의 상용성을 고려하고 화장료의 피부 안정성과 사용 후 피부 자극의 최소화를 위해 아미노산계 또는 인산계 음이온성 계면활성제를 사용한다. 아미노산계 음이온성 계면활성제로는 메틸 카프로일 타우레이트와 포타슘 코코일 글리시네이트, 인산계 음이온성 계면활성제로는 소디움 라우레스-1 포스페이트 등을 사용할 수 있다. 그러나 상기한 물질들은 일예에 불과하며 상기한 바에 한정되지 않는다.The ionic surfactant used in the present invention is an anionic surfactant and the type of the anionic surfactant is not strictly limited. However, considering the compatibility with the oil used, the skin stability of the cosmetic and the skin irritation after use For minimization, an amino acid or phosphoric anionic surfactant is used. As the amino acid anionic surfactant, methyl caproyl taurate and potassium cocoyl glycinate may be used. As the phosphate anionic surfactant, sodium laureth-1 phosphate and the like may be used. However, the above-mentioned materials are merely examples and the present invention is not limited thereto.
음이온성 계면활성제는 피부 자극과 제형 안전성을 고려하여 조성물 총 중량에 대하여 0.01~5중량% 함유되며, 상기 범위의 음이온성 계면활성제를 함유할 때 물의 헹굼성이 특히 향상된다. 혼합하는 음이온성 계면활성제에 의해 헹굼성이 크게 향상되기 때문에 사용하는 비이온성 계면활성제의 종류를 다양화 할 수 있으며, 사용량을 줄일 수 있다. The anionic surfactant is contained in an amount of 0.01 to 5% by weight based on the total weight of the composition in consideration of skin irritation and formulation safety, and the rinsability of the water is particularly improved when the anionic surfactant is contained in the above range. Since the rinseability is greatly improved by the mixing anionic surfactant, the kind of the nonionic surfactant to be used can be diversified and the use amount can be reduced.
본 발명에서 사용하는 유상 성분은 일반적으로 화장품에 사용되고 있는 것이라면 특별히 제한되지 않고, 1종 이상을 메이크업 제거력과 안정도를 고려하여 선택할 수 있으며, 바람직하게는 탄화수소, 에스테르, 트리글리세라이드, 식물성오일, 실리콘 오일 중 1종 이상을 사용할 수 있다. 투명한 제형을 제조하기 위해서는 특별히 탄화수소오일이 효율적이며 유성 성분의 굴절률(Reflective index, 빛이 등방성(等方性)을 갖는 두 종류의 매질(媒質)의 경계면을 통과할 때 굴절하게 되는데, 이 때 입사각과 굴절각 사이에 성립되는 스넬의 법칙(굴절의 법칙)에서 상수(常數)의 값을 동일하게 맞추면 투명도를 맞출 수 있다. The oily component to be used in the present invention is not particularly limited as long as it is generally used in cosmetics, and one or more oily components can be selected in consideration of makeup removing power and stability, and preferable examples thereof include hydrocarbons, esters, triglycerides, vegetable oils, May be used. In order to produce a transparent formulation, hydrocarbon oil is particularly effective and refracts when it passes through the interface between two kinds of mediums having a refractive index (light refractive index, isotropic) of an oily component. In this case, (The law of refraction) which is established between the refraction angle and the refraction angle, the transparency can be matched if the value of the constant is made the same.
유상 성분은 조성물 총 중량에 대하여 20~90중량%, 바람직하게는 30~70중량% 함유된다. 또한 유상 성분에 디메치콘, 사이클로메치콘 등의 실리콘오일을 씻김성과 제형 안정도를 고려하여 조성물 총 중량에 대하여 10~30 중량%를 혼합하게 되면 립스틱 및 아이메이크업 제품과 클렌징용 화장료 조성물과의 혼합이 용이해져 쉽게 제거가 될 수 있다. The oil component is contained in an amount of 20 to 90% by weight, preferably 30 to 70% by weight based on the total weight of the composition. When silicone oil such as dimethicone or cyclomethicone is mixed with the oil component in an amount of 10 to 30% by weight based on the total weight of the composition in consideration of washability and formulation stability, mixing of lipstick, eye makeup product and cosmetic composition for cleansing It becomes easy and can be easily removed.
본 발명에서 사용하는 수상 성분은 조성물 총 중량에 대하여 3~50중량%, 바 람직하게는 3~30중량% 함유되는 것이 충분한 내수성을 가질 수 있으면서 헹굼성이 양호하여 바람직하다. 수상에는 물 이외에 글리세린, 1,3-부틸렌글리콜, 디프로필렌글리콜, 프로필렌글리콜, 헥실렌글리콜 등 다가알코올류 또는 폴리올에 소수기를 부가시켜 개질 시킨 성분이 조성물 총 중량에 대하여5~40 중량% 함유될 수 있다. 수상이 조성물 총 중량에 대하여 50중량%를 초과하여 함유될 경우 제형의 안정도에 영향을 줄 수 있으므로 수상의 함량이 50중량%를 넘지 않는 것이 좋다. 또한 수상을 포함하지 않아도 제형은 만들어질 수 있으나 점도가 너무 낮아 도포시 쉽게 흘러내리는 등 사용성이 저하되므로 일정량 이상의 수상을 포함하는 것이 좋다.The water component used in the present invention is preferably contained in an amount of 3 to 50% by weight, more preferably 3 to 30% by weight, based on the total weight of the composition. The aqueous phase may contain, in addition to water, a polyhydric alcohol such as glycerin, 1,3-butylene glycol, dipropylene glycol, propylene glycol, hexylene glycol or the like or a component modified by adding a hydrophobic group to the polyol in an amount of 5 to 40% . When the water phase is contained in an amount of more than 50% by weight based on the total weight of the composition, it may affect the stability of the formulation, so that the content of the water phase should not exceed 50% by weight. In addition, formulations can be made without including water phase, but viscosity is too low, so it is easy to flow down upon application, so the usability is lowered.
본 발명에서 제조한 제형은 수상을 함유한 오일 제형으로서, 외관상 투명 혹은 반투명하게 보이는 단일상의 제형을 의미하며 계면활성제 및 유상의 함량 및 성분비에 따라 젤 또는 액상타입이 가능하다. The formulations prepared in the present invention are aqueous phase-containing oil formulations, which means a single-phase formulation that appears to be transparent or translucent in appearance, and can be a gel or a liquid type depending on the content and composition ratio of the surfactant and oil phase.
이하, 실시예 및 시험예를 통하여 본 발명을 보다 상세히 설명한다. 그러나 본 발명의 범위가 이들 예로만 한정되는 것은 아니다. 배합량은 중량%를 나타낸다.Hereinafter, the present invention will be described in more detail with reference to examples and test examples. However, the scope of the present invention is not limited to these examples. The compounding amount represents weight%.
[참조예] 실시예 및 비교예의 제조[Reference Example] Preparation of Examples and Comparative Examples
선정된 원료에 대해서 효율을 나타낼 수 있는 함량을 정하여 하기 표 1에 표시한 유상, 수상, 계면활성제상, 수상의 함량대로 실시예 1~5 및 비교예 1~4를 제조하였다. The contents that can indicate the efficiency with respect to the selected raw materials were determined, and Examples 1 to 5 and Comparative Examples 1 to 4 were prepared according to the contents of oil phase, water phase, surfactant phase, and water phase shown in Table 1 below.
제조 방법은 우선 유상과 계면활성제상을 70℃까지 가온하고 200~400rpm에서 교반한 다음, 여기에 70℃까지 가온된 수상을 투입하여 10분간 혼합을 진행하였다. 혼합 후 30℃로 냉각하여 24시간 동안 30℃ 항온 챔버에서 보관한 뒤 상분리나 현탁이 없는 제형임을 확인하였다.In the preparation method, the oil phase and the surfactant phase were heated to 70 ° C, stirred at 200 to 400 rpm, and then the aqueous phase heated to 70 ° C was added thereto, followed by mixing for 10 minutes. After mixing, the mixture was cooled to 30 ° C. and stored in a constant temperature chamber at 30 ° C. for 24 hours, and it was confirmed that the formulation was free of phase separation or suspension.
[시험예 1] 사용성 평가[Test Example 1] Usability evaluation
상기에서 제조한 실시예 1~5 및 비교예 1~4의 클렌징용 화장료 조성물에 대하여 20명의 전문 패널이 도포성, 마사지 용이성, 씻김성, 클렌징력 및 내수성을 조사하였다. 일반적인 클렌징용 제품의 사용법에 따라 화장한 얼굴에 사용한 다음 각 항목에 대하여 ‘우수하다’, ‘나쁘다’ 두 항목 중 한 가지를 선택하도록 하였으며, 내수성 측정은 상기 조성물 100중량%에 대하여 30중량%의 물을 첨가한 것의 클렌징력을 측정하여 확인하였다. 도표에 나타낸 평가 방법은 하기와 같으며, 전문 패널이 제시한 평가를 아래와 같은 방법으로 정리하여 나타내었다.Twenty professional panels were tested for applicability, ease of massage, washability, cleansing power and water resistance for the cleansing cosmetic compositions of Examples 1 to 5 and Comparative Examples 1 to 4 prepared above. The product was used on a makeup face according to the usage of a general cleansing product, and then one of two items was selected as 'excellent' and 'bad' for each item. The water resistance was measured by using 30 wt% The cleansing power of water added was measured and confirmed. The evaluation methods shown in the diagrams are as follows, and the evaluation presented by the expert panel is summarized in the following manner.
<평가방법><Evaluation method>
◎: 20명 중 15명 이상이 「우수하다」라고 회답.◎: 15 out of 20 answered "excellent".
○: 20명 중 10~14명이 「우수하다」라고 회답.○: 10 to 14 out of 20 responded "excellent".
△: 20명 중 6~9명이 「우수하다」라고 회답.△: 6 ~ 9 out of 20 responded "Excellent".
×: 20명 중 5명 이하가 「우수하다」라고 회답. X: Less than five out of 20 answered "excellent".
상기 표 2에서 알 수 있는 바와 같이, 기존의 오일 타입의 클렌징용 제품인 비교예 1~4는 도포성이 좋고, 마사지도 용이하게 이루어지며, 내수성도 우수하였지만, 오일의 잔여물이 피부에 남아 씻김성은 그다지 좋지 않음을 알 수 있다. 반면, 본 발명에 의한 실시예 1~5는 전반적으로 사용성에 대하여 높은 평가 점수를 받았으며, 특히 씻김성에 있어서 비교예에 비하여 월등히 개선되었으며, 클렌징력도 우수함을 확인할 수 있다.As can be seen from Table 2, the conventional oil-type cleansing products of Comparative Examples 1 to 4, which had good applicability, easy massage, and excellent water resistance, The sex is not very good. On the other hand, Examples 1 to 5 according to the present invention had a high evaluation score on usability as a whole, and the washability was remarkably improved as compared with Comparative Example, and cleansing power was also excellent.
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KR102223238B1 (en) * | 2019-05-24 | 2021-03-09 | 코스맥스 주식회사 | Cosmetic composition comprising anion surfactant for cleansing |
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KR930009601A (en) * | 1991-11-15 | 1993-06-21 | 도바 다다스 | Cleansing cosmetics |
JPH05208905A (en) * | 1991-03-12 | 1993-08-20 | Lion Corp | Gel composition for skin cleansing |
US6524594B1 (en) * | 1999-06-23 | 2003-02-25 | Johnson & Johnson Consumer Companies, Inc. | Foaming oil gel compositions |
KR20070073186A (en) * | 2006-01-04 | 2007-07-10 | 주식회사 코리아나화장품 | Oily Solid Cleansing Cosmetic Composition Containing Powder Type Anionic Surfactant |
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JPH05208905A (en) * | 1991-03-12 | 1993-08-20 | Lion Corp | Gel composition for skin cleansing |
KR930009601A (en) * | 1991-11-15 | 1993-06-21 | 도바 다다스 | Cleansing cosmetics |
US6524594B1 (en) * | 1999-06-23 | 2003-02-25 | Johnson & Johnson Consumer Companies, Inc. | Foaming oil gel compositions |
KR20070073186A (en) * | 2006-01-04 | 2007-07-10 | 주식회사 코리아나화장품 | Oily Solid Cleansing Cosmetic Composition Containing Powder Type Anionic Surfactant |
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