KR101399385B1 - Manufacturing method of detergent for aircraft exterior - Google Patents
Manufacturing method of detergent for aircraft exterior Download PDFInfo
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- KR101399385B1 KR101399385B1 KR1020120158689A KR20120158689A KR101399385B1 KR 101399385 B1 KR101399385 B1 KR 101399385B1 KR 1020120158689 A KR1020120158689 A KR 1020120158689A KR 20120158689 A KR20120158689 A KR 20120158689A KR 101399385 B1 KR101399385 B1 KR 101399385B1
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- sodium
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- cleaning
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- 239000003599 detergent Substances 0.000 title claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 40
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 26
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000012153 distilled water Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 18
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000012964 benzotriazole Substances 0.000 claims abstract description 14
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 13
- 239000001488 sodium phosphate Substances 0.000 claims abstract description 13
- 229910000162 sodium phosphate Inorganic materials 0.000 claims abstract description 13
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims abstract description 13
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 11
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 11
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 11
- 239000001509 sodium citrate Substances 0.000 claims abstract description 9
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims abstract description 9
- 238000004140 cleaning Methods 0.000 claims description 24
- 239000004115 Sodium Silicate Substances 0.000 claims 1
- 235000019795 sodium metasilicate Nutrition 0.000 claims 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims 1
- 229910052911 sodium silicate Inorganic materials 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 14
- 229910052708 sodium Inorganic materials 0.000 abstract description 14
- 239000011734 sodium Substances 0.000 abstract description 14
- 238000003756 stirring Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 description 18
- 238000012360 testing method Methods 0.000 description 16
- 239000012459 cleaning agent Substances 0.000 description 14
- 238000002845 discoloration Methods 0.000 description 14
- 238000000034 method Methods 0.000 description 12
- 239000003973 paint Substances 0.000 description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
- 230000007797 corrosion Effects 0.000 description 7
- 238000005260 corrosion Methods 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 5
- 239000011247 coating layer Substances 0.000 description 4
- 230000035515 penetration Effects 0.000 description 4
- 229910000853 7075 T6 aluminium alloy Inorganic materials 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 238000005238 degreasing Methods 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- CBKZKUAVHKDICU-UHFFFAOYSA-M sodium 2H-benzotriazole benzoate Chemical compound N1N=NC2=C1C=CC=C2.C(C2=CC=CC=C2)(=O)[O-].[Na+] CBKZKUAVHKDICU-UHFFFAOYSA-M 0.000 description 3
- BYWFNXATMCFRTD-UHFFFAOYSA-K trisodium carbonic acid phosphate Chemical compound [Na+].[Na+].[Na+].OC(O)=O.[O-]P([O-])([O-])=O BYWFNXATMCFRTD-UHFFFAOYSA-K 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 238000004925 denaturation Methods 0.000 description 2
- 230000036425 denaturation Effects 0.000 description 2
- -1 ferrous metals Chemical class 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 239000003440 toxic substance Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 235000013334 alcoholic beverage Nutrition 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 231100001234 toxic pollutant Toxicity 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/12—Carbonates bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/14—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3281—Heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
본 발명의 항공기 외장 세척제의 제조방법은 세척제 1ℓ에 대해서 1.0g 내지 2.0g의 소디움 메타실리케이트(Sodium Metasilicate)와 2.5g 내지 5.0g의 소디움 카보네이트(Sodium Carbonate)와 2.5g 내지 5.0g의 소디움 포스페이트(Sodium Phosphate)와 2.5g 내지 5.0g의 소디움 벤조에이트(sodium benzoate)와 2.5g 내지 5.0g의 소디움 사이트레이트(Sodium Citrate)를 증류수에 혼합 교반하여 제1혼합물을 형성하는 제1혼합단계(S10)와, 세척제 1ℓ에 대해서 2.5g 내지 5.0g의 벤조트리아졸(Benzotriazole)을 폴리에틸렌 글리콜(Polyethylene Glycol)에 혼합하여 제2혼합물을 형성하는 제2혼합단계(S20)와, 제1혼합물과 제2혼합물을 혼합 교반하여 제3혼합물을 형성하는 제3혼합단계(S30)와, 제3혼합물에 식용 주정(酒精)과 에틸렌 글리콜 모노부틸 에테르(Ethylene Glycol Monobutyl Ether)를 혼합 교반하여 세척제를 형성하는 제4혼합단계(S40)로 구성되며, 증류수와 폴리에틸렌 글리콜과 식용 주정과 에틸렌 글리콜 모노부틸 에테르를 16:1:1.5:1.5 부피비율로 혼합하도록 구성된다.The method of manufacturing an aircraft exterior detergent of the present invention is characterized in that it comprises 1.0 g to 2.0 g of sodium methasilicate, 2.5 g to 5.0 g of sodium carbonate and 2.5 g to 5.0 g of sodium phosphate A first mixing step (S10) of mixing 2.5g to 5.0g of sodium benzoate and 2.5g to 5.0g of sodium citrate in distilled water to form a first mixture, And a second mixing step (S20) of mixing 2.5 g to 5.0 g of benzotriazole with polyethylene glycol to form a second mixture with respect to 1 liter of the cleanser, and mixing the first mixture with the second mixture A third mixing step (S30) of forming a third mixture by mixing and stirring the first mixture and an ethylene glycol monobutyl ether; The fourth consists of the mixing step (S40), the distilled water and the polyethylene glycol and edible alcohol and ethylene glycol monobutyl ether 16: is adapted to mix a volume ratio of 1.5: 1: 1.5.
Description
본 발명은 항공기 외장 세척제의 제조방법에 관한 것으로, 특히 항공기의 외부 표면의 세척시 항공기 외부 표면에 코팅된 코팅층의 손상이나 변색을 방지하고, 항공기의 외장에 장착된 부품들의 부식 및 환경오염을 방지할 수 있고, 독성 물질이 발생되지 않아 인체에 무해하여 작업자의 환경 개선 및 작업자를 보호할 수 있는 항공기 외장 세척제의 제조방법에 관한 것이다.The present invention relates to a method of manufacturing an aircraft exterior cleaner, and in particular, to prevent damage or discoloration of a coating layer coated on an outer surface of an aircraft when cleaning an outer surface of an aircraft, and to prevent corrosion and environmental pollution of parts mounted on the exterior of an aircraft The present invention relates to a method for manufacturing an aircraft exterior cleaner which is harmless to a human body and which can improve the environment of a worker and protect a worker.
통상 항공기의 운항 후에는 세척제를 사용하여 항공기 외부 표면을 세척한다. Typically, after the flight of the aircraft, the outer surface of the aircraft is cleaned with a cleaning agent.
항공기 외장 표면의 세척시, 항공기의 외부 표면에 코팅된 코팅층이 손상되거거나 변색이 발생되지 말아야 하며, 세척 후에는 나사 조임부분이나 각종 기계 연결부위에 부식이 발생되어서는 안된다.When cleaning the outer surface of the aircraft, the coating layer on the outer surface of the aircraft should not be damaged or discolored, and after cleaning, there should be no corrosion on the threaded part or any mechanical connection.
종래의 경우 항공기 외장 세척제의 제조시, 벤젠, 톨루엔, 경유, TC, HF, TEC 등의 할로겐 용매나, 탄화수소계열의 용매 또는 석유화학 용매 등을 사용하는 것이 일반적이다.In the prior art, halogen solvents such as benzene, toluene, light oil, TC, HF and TEC, hydrocarbon solvents or petrochemical solvents are generally used in the manufacture of aircraft exterior cleaners.
상기와 같은 할로겐 용매, 탄화수소계열의 용매 및 석유화학 용매를 사용하는 종래의 세척제는 대기 공해와 유독성 오염 물질을 방출하게 되어 불필요한 폐수를 양산함으로 이러한 폐수를 처리하기 위한 별도의 비용이 증가될 뿐만 아니라, 항공기 외장 표면의 세척시 유기용매의 휘발시 발생되는 냄새로 인하여 작업자의 건강에 악영향을 주고, 작업능률이 저하되는 문제점이 있다. Conventional detergents using halogen solvents, hydrocarbon solvents and petrochemical solvents as described above emit atmospheric pollution and toxic pollutants, and unnecessary wastewater is produced. Therefore, a separate cost for treating such wastewater is increased , The odor generated when the organic solvent is volatilized during the cleaning of the outer surface of the aircraft adversely affects the health of the operator and the working efficiency is lowered.
본 발명의 목적은 항공기의 외부 표면의 세척시 항공기 외부 표면에 코팅된 코팅층의 손상이나 변색을 방지하고, 항공기의 외장에 장착된 부품들의 부식을 방지하고, 세척제의 조성 성분들은 모두 친환경 조성물로 이루지므로 환경오염을 방지할 수 있을 뿐만 아니라 독성 물질도 발생되지 않아 인체에 무해하며, 작업자의 환경 개선 및 작업자를 보호할 수 있는 항공기 외장 세척제의 제조방법을 제공하는 데 있다.It is an object of the present invention to prevent damage or discoloration of the coating layer coated on the outer surface of an aircraft when cleaning the outer surface of an aircraft and to prevent corrosion of parts mounted on the outer surface of the aircraft, The present invention provides a method of manufacturing an aircraft exterior cleaner which can prevent environmental pollution and is not harmful to human bodies because toxic substances are not generated, thereby improving the environment of the worker and protecting workers.
상기의 목적을 달성하기 위하여 본 발명의 항공기 외장 세척제의 제조방법은In order to accomplish the above object, the present invention provides a method for manufacturing an aircraft exterior cleaner,
항공기의 외부 표면을 세척하기 위한 항공기 외장 세척제의 제조방법에 있어서, 상기 세척제 1ℓ에 대해서 1.0g 내지 2.0g의 소디움 메타실리케이트(Sodium Metasilicate)와 2.5g 내지 5.0g의 소디움 카보네이트(Sodium Carbonate)와 2.5g 내지 5.0g의 소디움 포스페이트(Sodium Phosphate)와 2.5g 내지 5.0g의 소디움 벤조에이트(sodium benzoate)와 2.5g 내지 5.0g의 소디움 사이트레이트(Sodium Citrate)를 증류수에 혼합 교반하여 제1혼합물을 형성하는 제1혼합단계; 상기 세척제 1ℓ에 대해서 2.5g 내지 5.0g의 벤조트리아졸(Benzotriazole)을 폴리에틸렌 글리콜(Polyethylene Glycol)에 혼합하여 제2혼합물을 형성하는 제2혼합단계; 상기 제1혼합물과 제2혼합물을 혼합 교반하여 제3혼합물을 형성하는 제3혼합단계; 및 상기 제3혼합물에 식용 주정(酒精)과 에틸렌 글리콜 모노부틸 에테르(Ethylene Glycol Monobutyl Ether)를 혼합 교반하여 세척제를 형성하는 제4혼합단계(S40)를 구비하며, A method of manufacturing an aircraft exterior detergent for cleaning an outer surface of an aircraft, the method comprising: providing 1.0 grams to 2.0 grams of sodium methasilicate, 2.5 grams to 5.0 grams of sodium carbonate, g to 5.0 g of sodium phosphate, 2.5 to 5.0 g of sodium benzoate and 2.5 to 5.0 g of sodium citrate are mixed and stirred in distilled water to form a first mixture A first mixing step; A second mixing step of mixing 2.5 g to 5.0 g of benzotriazole with polyethylene glycol to 1 liter of the cleaner to form a second mixture; Mixing the first mixture and the second mixture to form a third mixture; And a fourth mixing step (S40) of mixing an edible alcohol and ethylene glycol monobutyl ether with the third mixture to form a detergent,
상기 증류수와 폴리에틸렌 글리콜과 식용 주정과 에틸렌 글리콜 모노부틸 에테르를 16:1:1.5:1.5 부피비율로 혼합하는 것을 특징으로 한다.The distilled water, the polyethylene glycol, the edible alcohol, and the ethylene glycol monobutyl ether are mixed in a volume ratio of 16: 1: 1.5: 1.5.
본 발명의 항공기 외장 세척제의 제조방법은 항공기의 외부 표면의 세척시 항공기 외부 표면에 코팅된 코팅층의 손상이나 변색을 방지하고, 항공기의 외장에 장착된 부품들의 부식을 방지하고, 세척제의 조성 성분들은 모두 친환경 조성물로 이루지므로 환경오염을 방지할 수 있을 뿐만 아니라 독성 물질도 발생되지 않아 인체에 무해하며, 작업자의 환경 개선 및 작업자를 보호할 수 있다. The method of manufacturing an aircraft exterior detergent of the present invention prevents damage or discoloration of the coating layer coated on the outer surface of the aircraft during cleaning of the outer surface of the aircraft and prevents corrosion of components mounted on the outer surface of the aircraft, All of them are made of an environmentally friendly composition, so that not only environmental pollution but also toxic substances are not generated, which is harmless to the human body, and it is possible to improve the worker environment and protect the workers.
도 1은 본 발명의 항공기 외장 세척제의 제조방법의 공정순서도이다.BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a process flow chart of a method for manufacturing an aircraft exterior cleaner of the present invention.
이하, 첨부된 도면을 참조하여 본 발명의 항공기 외장 세척제의 제조방법을 상세히 설명하고자 한다.DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, a method for manufacturing an aircraft exterior cleaner of the present invention will be described in detail with reference to the accompanying drawings.
도 1은 본 발명의 항공기 외장 세척제의 제조방법의 공정순서도이다. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a process flow chart of a method for manufacturing an aircraft exterior cleaner of the present invention.
도 1에 도시된 바와 같이 본 발명의 항공기 외장 세척제의 제조방법은 세척제 1ℓ에 대해서 1.0g 내지 2.0g의 소디움 메타실리케이트(Sodium Metasilicate)와 2.5g 내지 5.0g의 소디움 카보네이트(Sodium Carbonate)와 2.5g 내지 5.0g의 소디움 포스페이트(Sodium Phosphate)와 2.5g 내지 5.0g의 소디움 벤조에이트(sodium benzoate)와 2.5g 내지 5.0g의 소디움 사이트레이트(Sodium Citrate)를 증류수에 혼합 교반하여 제1혼합물을 형성하는 제1혼합단계(S10)와, 세척제 1ℓ에 대해서 2.5g 내지 5.0g의 벤조트리아졸(Benzotriazole)을 폴리에틸렌 글리콜(Polyethylene Glycol)에 혼합하여 제2혼합물을 형성하는 제2혼합단계(S20)와, 제1혼합물과 제2혼합물을 혼합 교반하여 제3혼합물을 형성하는 제3혼합단계(S30)와, 제3혼합물에 식용 주정(酒精)과 에틸렌 글리콜 모노부틸 에테르(Ethylene Glycol Monobutyl Ether)를 혼합 교반하여 세척제를 형성하는 제4혼합단계(S40)로 구성되며, 증류수와 폴리에틸렌 글리콜과 식용 주정과 에틸렌 글리콜 모노부틸 에테르를 16:1:1.5:1.5 부피비율로 혼합하도록 구성된다.
As shown in FIG. 1, the method for manufacturing an aircraft exterior cleaner of the present invention comprises 1.0 g to 2.0 g of sodium methasilicate, 2.5 g to 5.0 g of sodium carbonate, and 2.5 g To 5.0 g of sodium phosphate, 2.5 to 5.0 g of sodium benzoate and 2.5 to 5.0 g of sodium citrate are mixed and stirred in distilled water to form a first mixture A second mixing step S20 of mixing 2.5 g to 5.0 g of benzotriazole with polyethylene glycol to 1 liter of the cleaning agent to form a second mixture; A third mixing step (S30) of mixing and mixing the first mixture and the second mixture to form a third mixture; mixing the third mixture with an alcoholic beverage and an ethylene glycol monobutyl ether And consists of a fourth mixing stage (S40) for forming a cleaning agent and, with distilled water and the polyethylene glycol and edible alcohol and ethylene glycol monobutyl ether 16: is adapted to mix a volume ratio of 1.5: 1: 1.5.
상기의 구성에 따른 본 발명인 항공기 외장 세척제의 제조방법의 동작은 다음과 같다.The operation of the method for manufacturing an aircraft exterior cleaner according to the present invention is as follows.
본 발명의 항공기 외장 세척제를 제조하기 위해 사용되는 용매들인 증류수와 폴리에틸렌 글리콜과 식용 주정과 에틸렌 글리콜 모노부틸 에테르를 16:1:1.5:1.5 부피비율로 혼합하여 사용한다.Distilled water, polyethylene glycol, edible liquor and ethylene glycol monobutyl ether, which are solvents used to produce the aircraft exterior detergent of the present invention, are mixed at a volume ratio of 16: 1: 1.5: 1.5.
따라서, 세척제 1ℓ를 제조하기 위해서 증류수는 800㎖이고, 폴리에틸렌 글리콜은 50㎖이고, 식용 주정과 에틸렌 글리콜 모노부틸 에테르는 각각 75㎖를 혼합하도록 한다.Therefore, in order to prepare 1 liter of the detergent, distilled water is 800 ml, polyethylene glycol is 50 ml, and 75 ml of the edible alcohol and ethylene glycol monobutyl ether are mixed.
도 1에 도시된 바와 같이 제1혼합단계(S10)는 800㎖의 증류수에 1.0g 내지 2.0g의 소디움 메타실리케이트(Sodium Metasilicate)와 2.5g 내지 5.0g의 소디움 카보네이트(Sodium Carbonate)와 2.5g 내지 5.0g의 소디움 포스페이트(Sodium Phosphate)와 2.5g 내지 5.0g의 소디움 벤조에이트(sodium benzoate)와 2.5g 내지 5.0g의 소디움 사이트레이트(Sodium Citrate)를 혼합한 후 증류수에 상기의 약품들이 충분히 용해되도록 실온에서 분당 25RPM으로 회전하는 교반기를 사용하여 대략 20분정도 혼합 교반시켜 제1혼합물을 형성한다.As shown in FIG. 1, the first mixing step (S10) comprises adding 1.0 g to 2.0 g of sodium methasilicate, 2.5 g to 5.0 g of sodium carbonate and 2.5 g to 5.0 g of sodium carbonate to 800 ml of distilled water. After mixing 5.0 g of sodium phosphate with 2.5 g to 5.0 g of sodium benzoate and 2.5 g to 5.0 g of sodium citrate, The mixture is stirred for about 20 minutes using a stirrer rotating at room temperature at 25 RPM per minute to form a first mixture.
소디움 메타실리케이트는 항공기 외장 표면의 세척 작용과 탈지 작용을 하고, 소디움 카보네이트와 소디움 포스페이트는 세척과 방청 작용을 하며, 소디움 벤조에이트는 철금속에 대한 방청 작용을 하며, 소디움 사이트레이트는 소디움 메타실리케이트와 소디움 카보네이트와 소디움 포스페이트에 의한 세척 반응을 촉진시켜 준다.Sodium methosilicate has a cleaning action and degreasing action on the exterior surface of the aircraft. Sodium carbonate and sodium phosphate have a washing and anti-rusting action. Sodium benzoate has antirust effect against ferrous metals. Sodium citrate is sodium methasilicate It promotes the washing reaction by sodium carbonate and sodium phosphate.
소디움 메타실리케이트와 소디움 카보네이트와 소디움 포스페이트는 강알칼리성을 가지므로, 적정량 보다 많은 양이 함유된 세척제를 사용할 경우 항공기 외장 표면에 코팅된 아크릴에 손상이 발생될 수 있으므로, 적정량을 사용하여야 한다.Since sodium methasilicate, sodium carbonate and sodium phosphate have strong alkalinity, when using a detergent containing more than the proper amount, it may cause damage to the acrylic coated on the outer surface of the aircraft. Therefore, the proper amount should be used.
제2혼합단계(S20)는 50㎖의 폴리에틸렌 글리콜(Polyethylene Glycol)에 2.5g 내지 5.0g의 벤조트리아졸(Benzotriazole)을 혼합하여 벤조트리아졸이 폴리에틸렌 글리콜에 완전히 용해시켜 제2혼합물을 형성한다.In the second mixing step (S20), 2.5 g to 5.0 g of benzotriazole is mixed with 50 ml of polyethylene glycol, and benzotriazole is completely dissolved in polyethylene glycol to form a second mixture.
벤조트리아졸은 증류수에 용해되지 않으므로, 벤조트리아졸을 유기용매인 폴리에틸렌 글리콜에 용해시키며, 항공기 외장 세척시 폴리에틸렌 글리콜은 탈지 작용을 하며, 벤조트리아졸은 비철금속에 대한 방청 작용을 한다.Since benzotriazole is not dissolved in distilled water, benzotriazole is dissolved in polyethylene glycol, which is an organic solvent, and polyethylene glycol is defatted when washed in an aircraft exterior, and benzotriazole has anti-corrosive action against non-ferrous metals.
제3혼합단계(S30)는 제1혼합물과 제2혼합물을 혼합한 후 실온에서 분당 25RPM으로 회전하는 교반기를 사용하여 두 혼합물이 충분히 섞일때까지 교반시켜 제3혼합물을 형성한다.In the third mixing step (S30), the first mixture and the second mixture are mixed and stirred using a stirrer rotating at 25 RPM per minute at room temperature until the two mixture are sufficiently mixed to form a third mixture.
제4혼합단계(S40)는 제3혼합물에 75㎖의 식용 주정(酒精)과 75㎖의 에틸렌 글리콜 모노부틸 에테르(Ethylene Glycol Monobutyl Ether)를 혼합 교반하여 1000㎖의 세척제를 제조한다.In the fourth mixing step (S40), 75 ml of an alcoholic alcohol and 75 ml of ethylene glycol monobutyl ether are mixed and stirred to prepare a 1000 ml of a detergent.
식용 주정과 에틸렌 글리콜 모노부틸 에테르는 모두 탈지 작용을 하며, 이들은 항공기 외장에 코팅된 페인트의 변성에 영향을 주므로, 증류수와 식용 주정과 에틸렌 글리콜 모노부틸 에테르는 16:1.5:1.5 부피비율로 혼합하도록 하며, 증류수 대비 식용 주정과 에틸렌 글리콜 모노부틸 에테르가 상기 부피비율보다 크면 항공기 외장에 코팅된 페인트의 변색이 발생한다.Both edible liquor and ethylene glycol monobutyl ether are defatting, which affects the denaturation of the paint coated on the aircraft exterior, so distilled water, edible liquor and ethylene glycol monobutyl ether are mixed in a 16: 1.5: 1.5 volume ratio And when the edible alcohol and ethylene glycol monobutyl ether relative to the distilled water are larger than the above volume ratio, discoloration of the paint coated on the aircraft exterior occurs.
상기와 같이 본 발명의 항공기 외장 세척제는 소디움 벤조에이트와 벤조트리아졸에 의해 항공기 외장 세척후 볼트류나 항공기 외부에 장착된 기계부품들의 발청을 방지할 수 있고, 세척 및 탈지 작용을 하는 약품들을 사용하여 항공기 외장 세척시 세척력 및 탈지력이 우수하며, 항공기 외장에 코팅된 페인트의 변색이 발생되지 않으며, 종래의 탄화수소계 용매나 할로겐 용매 대신에 식용 주정을 혼합하여 인체에 무해하다.As described above, the aircraft exterior cleaner of the present invention can prevent bleeding of bolts or mechanical parts mounted on the outside of the aircraft after cleaning the exterior of the aircraft by using sodium benzoate and benzotriazole, and by using chemicals for cleaning and degreasing It has excellent cleaning and degreasing power when cleaning the exterior of aircraft, does not cause discoloration of paint coated on the exterior of aircraft, and harmless to human body by mixing edible spirit instead of conventional hydrocarbon solvent or halogen solvent.
상기와 같이 제조된 본 발명의 항공기 외장 세척제의 방청비교실험을 위해 세척제의 용매는 800㎖의 증류수와 50㎖의 폴리에틸렌 글리콜과 75㎖의 식용 주정과 75㎖의 에틸렌 글리콜 모노부틸 에테르를 사용하여 세척제 1000ml를 제조하였으며, 세척제 1000ml에 대해서 본 발명의 세척제의 각 용질의 조성 함량을 상이하게 하여 시료의 표면 부식 유무를 실험하였으며, 이에 대한 방청비교실험은 아래의 표 1에 나타난 바와 같다.
In order to compare the rustproofing performance of the aircraft exterior cleaner of the present invention manufactured as described above, the solvent of the cleaning agent was washed with 800 ml of distilled water, 50 ml of polyethylene glycol, 75 ml of edible alcohol and 75 ml of ethylene glycol monobutyl ether, 1000 ml were prepared. The composition of each solute of the cleaning agent of the present invention was varied with respect to 1000 ml of the cleaning agent to test whether the surface of the sample was corroded or not.
본 발명에 세척제 용질의 조성 함량
The composition content of the cleaning solvent solute
7075-T6
알루미늄 함금Anodized
7075-T6
Aluminum alloy
알루미늄 함금
Coated 7075-T6
Aluminum alloy
카보네이트Sodium
Carbonate
포스페이트Sodium
Phosphate
사이트레이트Sodium
Site rate
벤조에이트Sodium
Benzoate
상기 표 1에 나타난 방청비교실험은 미국표준규격 ASTM F1110에 의한 샌드위치 부식 실험(Sandwich Corrosion Test) 방법에 의해 실험 한 것으로, 가로 1인치와, 세로 3인치의 양극산화처리된 7075-T6 알루미늄함금과 코팅된 7075-T6 알루미늄함금 시편의 중앙에 세척액을 함침시킨 유리섬유지(필터지)를 넣고 양 시편을 방수테이프를 사용하여 밀봉 접착시키고 대략 48시간 경과 후 시편 표면의 부식 여부를 판정하였으며, 시편 표면 부식이 5% 이하이면 방청성이 있는 것으로 정상으로 판정하였으며, 그렇지 않은 경우 실패로 판정하였다.The rust-inhibitive comparison test shown in Table 1 was conducted by a Sandwich Corrosion Test method according to ASTM F1110 of the American Society for Testing and Materials (ASTM F1110). The test was conducted by using 7075-T6 anodized aluminum alloy having a width of 1 inch and a length of 3 inches The glass islands (filter paper) impregnated with a washing solution in the center of the coated 7075-T6 aluminum alloy specimen were sealed, and both specimens were sealed with a waterproof tape. After about 48 hours, corrosion of the surface of the specimen was determined. If surface corrosion is less than 5%, it is judged to be rust-proof. Otherwise, it is judged as failure.
표 1에서 나타난 바와 같이 세척제의 함유 성분들 중 방청 작용을 하는 소디움 벤조에이트와 벤조트리아졸은 각각 세척제 1000㎖에 대해서 2.5g 이상인 경우 방청이 정상인 것을 알 수 있다.
As shown in Table 1, when sodium benzoate and benzotriazole, which have a rust-inhibiting action, are contained in the cleaning agent in an amount of 2.5 g or more per 1000 ml of the cleaning agent, the rust inhibition is normal.
본 발명에 세척제 용질의 조성 함량
The composition content of the cleaning solvent solute
Second experiment
카보네이트Sodium
Carbonate
포스페이트Sodium
Phosphate
사이트레이트Sodium
Site rate
벤조에이트Sodium
Benzoate
표 2는 본 발명의 항공기 외장 세척제의 아크릴관입실험(Acrylic Crazing Test)에 관한 것으로, 세척제의 용매는 800㎖의 증류수와 50㎖의 폴리에틸렌 글리콜과 75㎖의 식용 주정과 75㎖의 에틸렌 글리콜 모노부틸 에테르를 사용하여 세척제 1000ml를 제조하였으며, 세척제 1000ml에 대해서 본 발명의 세척제의 각 용질의 조성 함량을 상이하게 하여 실험하였다.Table 2 shows the Acrylic Crazing Test of the aircraft exterior cleaner of the present invention. The solvent of the cleaning agent is 800 ml of distilled water, 50 ml of polyethylene glycol, 75 ml of edible alcohol and 75 ml of ethylene glycol monobutyl Ether was used to prepare 1000 ml of a detergent, and 1000 ml of the detergent was tested by varying the content of each solute of the detergent of the present invention.
아크릴관입실험은 미국표준규격 ASTM F484에 따른 방법에 의해 실험 한 것으로, 신장된 아크릴에 표 2에 나타난 바와 같이 용질의 함유량을 가변시켜 제조된 각각의 세척제를 도포하여 아크릴의 갈라짐이나 파손 등의 외부 손상 여부를 실험한 것이다.The acrylic penetration test was conducted by the method according to ASTM F484 of the American National Standard. As shown in Table 2, each of the cleaning agents prepared by varying the content of the solute was applied to the elongated acrylic, Damage was tested.
표 2에서 살펴본 바와 같이 세척제의 조성 성분들 중 강알칼리성을 띄는 소디움 메타실리케이트, 소디움 카보네이트 및 소디움 포스페이트의 함유량이 적정량 보다 클 경우에는 아크릴이 손상되는 것을 알 수 있다.
As can be seen from Table 2, acrylic is damaged when the content of sodium methasilicate, sodium carbonate, and sodium phosphate, which are strongly alkaline among the components of the cleaning agent, is larger than a proper amount.
상기 표 1의 방청비교실험과 표 2의 아크릴관입실험에 의해 본 발명의 항공기 외장 세척제의 조성 성분들의 경우, 세척제 1000ml에 대해서 각각 소디움 메타실리케이트는 1.0g 내지 2.0g이고, 소디움 카보네이트는 2.5g 내지 5.0g이고, 소디움 포스페이트는 2.5g 내지 5.0g이고, 소디움 벤조에이트는 2.5g 내지 5.0g이고, 소디움 사이트레이트는 2.5g 내지 5.0g이고, 벤조트리아졸은 2.5g 내지 5.0g인 것이 바람직한 것임을 알 수 있다.
According to the rustproofing comparison test of Table 1 and the acrylic penetration test of Table 2, the composition components of the aircraft exterior cleaner of the present invention were 1.0 g to 2.0 g of sodium methasilicate and 2.5 g to 10 g of sodium carbonate, respectively, 5.0 g, the sodium phosphate is 2.5 g to 5.0 g, the sodium benzoate is 2.5 g to 5.0 g, the sodium citrate is 2.5 g to 5.0 g, and the benzotriazole is 2.5 g to 5.0 g. .
없음discoloration
none
없음discoloration
none
표 3은 표 1의 방청비교실험과 표 2의 아크릴관입실험에 의해 본 발명의 항공기 외장 세척제의 용질들로 선택된 바람직한 용질의 조성 함유량에 대해서 증류수와 식용 주정과 에틸렌 글리콜 모노부틸 에테르의 용매의 함유량을 변화시켜서 항공기 외장에 코팅되는 페인트의 색상 변화를 실험한 페인트 연화실험(Paint Softening Test)을 한 것이다.Table 3 shows the contents of the distilled water, the solvent of the edible alcohol and the solvent of the ethylene glycol monobutyl ether in relation to the content of the composition of the preferable solute selected as the solutes of the aircraft exterior cleaner of the present invention by the rustproofing comparison test of Table 1 and the acrylic penetration test of Table 2 (Paint Softening Test), which tests the color change of the paint coated on the exterior of the aircraft.
페인트 연화실험은 미국표준규격 ASTM F502에 따른 방법에 의해 실험 한 것으로, 페인트는 BAC 5885에 의한 BMS 10-79의 밑칠페인트와 BAC 5845에 의한 BMS 10-46의 에나멜을 사용하였으며, 이와 같이 구성된 페인트 상에 표 3에 나타난 바와 같이 증류수와 식용 주정과 에틸렌 글리콜 모노부틸 에테르의 용매의 함유량을 가면시켜 제조된 각각의 세척제를 분사한 후 페인트의 변성 여부를 관찰하였다.The paint softening test was carried out by the method according to ASTM F502 of the USA standard. The paint used was an undercoat of BMS 10-79 by BAC 5885 and an enamel of BMS 10-46 by BAC 5845, , As shown in Table 3, each detergent prepared by dissolving the distilled water, the edible alcohol and the solvent of ethylene glycol monobutyl ether was sprayed, and the denaturation of the paint was observed.
표 3의 페인트 연화실험에 따라, 증류수와 식용 주정과 에틸렌 글리콜 모노부틸 에테르는 16:1.5:1.5 부피비율로 혼합하는 것이 바람직함을 알 수 있다.
According to the paint softening experiment shown in Table 3, it is preferable that the distilled water, the edible alcohol and the ethylene glycol monobutyl ether are mixed at a ratio of 16: 1.5: 1.5 by volume.
본 발명에 세척제 용질의 조성 함량
The composition content of the cleaning solvent solute
세척율(%)
Cleaning rate (%)
카보네이트Sodium
Carbonate
포스페이트Sodium
Phosphate
사이트레이트Sodium
Site rate
벤조에이트Sodium
Benzoate
표 4는 본 발명의 항공기 외장 세척제의 세척력 실험에 관한 것으로, 표 3의 페인트 연화실험에 따라 선택된 세척제의 용매의 함유량을 800㎖의 증류수와 50㎖의 폴리에틸렌 글리콜과 75㎖의 식용 주정과 75㎖의 에틸렌 글리콜 모노부틸 에테르를 사용하여 표 1의 방청비교실험과 표 2의 아크릴관입실험과 동일하게 본 발명의 세척제의 각 용질의 조성 함량을 다르게 하여 세척력을 실험하였다.Table 4 relates to the cleaning power test of the aircraft exterior cleaner of the present invention. The contents of the solvent of the cleaning agent selected according to the paint softening test of Table 3 were changed to 800 ml of distilled water, 50 ml of polyethylene glycol, Of ethylene glycol monobutyl ether was used to test the cleaning performance by changing the compositions of the respective solutes of the cleaning agent of the present invention in the same manner as in the rustproofing comparative experiment of Table 1 and the acrylic penetration experiment of Table 2. [
세척력 실험은 대한민국 표준규격 KSM 2715에 따라 25℃의 세척온도로, 50ppm(CaCl2)의 세척경도의 환경에서 Terg-O 미터기기를 사용하여 세척력을 측정하였다.The cleaning power was measured using a Terg-O meter in an environment of a cleaning hardness of 50 ppm (CaCl 2) at a cleaning temperature of 25 ° C according to the Korean Standard Standard KSM 2715.
표 4에 나타난 바와 같이, 세척제 1000ml에 대해서 각각 1.0g의 소디움 메타실리케이트와, 2.5g의 소디움 카보네이트와, 2.5g의 소디움 포스페이트와 2.5g의 소디움 벤조에이트와 2.5g의 소디움 사이트레이트와 2.5g의 벤조트리아졸을 혼합하여 세척제를 제조하더라고 세척력은 93%로, 우수한 세척력을 가지고 있음을 알 수 있다.As shown in Table 4, 1.0 g of sodium methasilicate, 2.5 g of sodium carbonate, 2.5 g of sodium phosphate, 2.5 g of sodium benzoate, 2.5 g of sodium citrate and 2.5 g of Benzotriazole was mixed to prepare a cleaning agent, the cleaning power was 93%, indicating that the cleaning power was excellent.
Claims (1)
상기 세척제 1ℓ에 대해서 1.0g 내지 2.0g의 소디움 메타실리케이트(Sodium Metasilicate)와 2.5g 내지 5.0g의 소디움 카보네이트(Sodium Carbonate)와 2.5g 내지 5.0g의 소디움 포스페이트(Sodium Phosphate)와 2.5g 내지 5.0g의 소디움 벤조에이트(sodium benzoate)와 2.5g 내지 5.0g의 소디움 사이트레이트(Sodium Citrate)를 증류수에 혼합 교반하여 제1혼합물을 형성하는 제1혼합단계(S10);
상기 세척제 1ℓ에 대해서 2.5g 내지 5.0g의 벤조트리아졸(Benzotriazole)을 폴리에틸렌 글리콜(Polyethylene Glycol)에 혼합하여 제2혼합물을 형성하는 제2혼합단계(S20);
상기 제1혼합물과 제2혼합물을 혼합 교반하여 제3혼합물을 형성하는 제3혼합단계(S30); 및
상기 제3혼합물에 식용 주정(酒精)과 에틸렌 글리콜 모노부틸 에테르(Ethylene Glycol Monobutyl Ether)를 혼합 교반하여 세척제를 형성하는 제4혼합단계(S40)를 구비하며,
상기 증류수와 폴리에틸렌 글리콜과 식용 주정과 에틸렌 글리콜 모노부틸 에테르를 16:1:1.5:1.5 부피비율로 혼합하는 것을 특징으로 하는 항공기 외장 세척제의 제조방법.A method of manufacturing an aircraft exterior cleaner for cleaning an outer surface of an aircraft,
Sodium Metasilicate, 2.5 to 5.0 g of Sodium Carbonate, 2.5 to 5.0 g of Sodium Phosphate and 2.5 to 5.0 g of Sodium Phosphate, Of sodium benzoate and 2.5 g to 5.0 g of sodium citrate in distilled water to form a first mixture (S10);
A second mixing step (S20) in which 2.5 g to 5.0 g of benzotriazole is mixed with polyethylene glycol to 1 liter of the cleaner to form a second mixture;
A third mixing step (S30) of mixing the first mixture and the second mixture to form a third mixture; And
And a fourth mixing step (S40) of mixing an edible alcohol and ethylene glycol monobutyl ether into the third mixture to form a detergent,
Wherein the distilled water, the polyethylene glycol, the edible alcohol, and the ethylene glycol monobutyl ether are mixed in a volume ratio of 16: 1: 1.5: 1.5.
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR19990010425A (en) * | 1997-07-16 | 1999-02-18 | 성재갑 | Detergent composition |
JP2004067977A (en) | 2002-06-14 | 2004-03-04 | Ishihara Chem Co Ltd | Detergent composition |
KR20110019118A (en) * | 2009-08-19 | 2011-02-25 | 주식회사 엘지생활건강 | Liquid detergent composition |
KR20120072431A (en) * | 2010-12-24 | 2012-07-04 | 주식회사 이디크린 | Cleaner for metal |
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KR19990010425A (en) * | 1997-07-16 | 1999-02-18 | 성재갑 | Detergent composition |
JP2004067977A (en) | 2002-06-14 | 2004-03-04 | Ishihara Chem Co Ltd | Detergent composition |
KR20110019118A (en) * | 2009-08-19 | 2011-02-25 | 주식회사 엘지생활건강 | Liquid detergent composition |
KR20120072431A (en) * | 2010-12-24 | 2012-07-04 | 주식회사 이디크린 | Cleaner for metal |
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US11019548B2 (en) | 2017-11-24 | 2021-05-25 | Samsung Electronics Co., Ltd. | Electronic device and communication method thereof |
US11218938B2 (en) | 2017-11-24 | 2022-01-04 | Samsung Electronics Co., Ltd. | Electronic device and communication method thereof |
US12192843B2 (en) | 2017-11-24 | 2025-01-07 | Samsung Electronics Co., Ltd. | Electronic device and communication method using 4G and 5G communication based on temperature |
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