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KR101275456B1 - Solid fuel using rice hull charcoal and manufacturing method therefor - Google Patents

Solid fuel using rice hull charcoal and manufacturing method therefor Download PDF

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Publication number
KR101275456B1
KR101275456B1 KR1020110065710A KR20110065710A KR101275456B1 KR 101275456 B1 KR101275456 B1 KR 101275456B1 KR 1020110065710 A KR1020110065710 A KR 1020110065710A KR 20110065710 A KR20110065710 A KR 20110065710A KR 101275456 B1 KR101275456 B1 KR 101275456B1
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chaff
tar
chaff charcoal
charcoal
weight
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KR20130004001A (en
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서용교
박용철
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주식회사 대원지에스아이
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • C10L5/445Agricultural waste, e.g. corn crops, grass clippings, nut shells or oil pressing residues
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/80Destroying solid waste or transforming solid waste into something useful or harmless involving an extraction step
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/54Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
    • C10L2290/544Extraction for separating fractions, components or impurities during preparation or upgrading of a fuel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Materials Engineering (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

본 발명은 왕겨숯을 이용한 고형화 연료 및 그 제조방법에 관한 것으로, 보다 상세하게는 왕겨숯 분말 70~80중량%와 타르 20~30중량%로 이루어져 펠렛 형태로 성형한 고형화 연료 및, 상기 고형화 연료를 제조하는 방법으로서 왕겨를 열분해하는 왕겨탄화공정(S100)과, 상기 열분해된 왕겨숯을 분쇄하는 왕겨숯 분쇄공정(S200)과, 왕겨의 열분해시 배출되는 합성가스를 응축하여 합성가스로부터 왕겨초액을 응축하는 초액응축공정(S210)과, 상기 왕겨초액에서 타르를 침전시켜 추출하는 타르추출공정(S220)과, 상기 왕겨숯 분말 70~80중량%와 타르 20~30중량%를 혼합하여 왕겨숯 분말의 열량을 높임과 아울러 왕겨숯 분말이 응집될 수 있도록 하는 타르혼합공정(S300)과, 상기 왕겨숯-타르 혼합물을 성형기(40)에 투입하여 펠렛을 형성하는 펠렛성형공정(S400)을 포함하는 고형화 연료의 제조방법을 구성함으로써, 타르 성분에 의하여 왕겨숯 분말의 열량을 높일 수 있을 뿐만 아니라, 왕겨숯 분말의 응집이 가능하며, 다른 한편으론 종래 폐기되었던 타르 성분의 활용이 가능하여 보다 환경친화적이라 할 수 있는 '왕겨숯을 이용한 고형화 연료 및 그 제조방법'에 관한 것이다.The present invention relates to a solidified fuel using chaff charcoal and a method for manufacturing the same, more specifically, the solidified fuel formed in pellet form consisting of 70 to 80% by weight of chaff charcoal powder and 20 to 30% by weight of tar, and the solidifying fuel As a method of producing a chaff charcoal process (S100) for pyrolyzing chaff, and the chaff charcoal grinding process (S200) for crushing the pyrolyzed chaff charcoal, and the condensed synthesis gas discharged during the pyrolysis of rice husk condensed from the chaff Condensation of the supernatant (S210) and the tar extraction step (S220) to extract the precipitate by extracting the tar from the chaff herb solution, and the chaff charcoal powder 70-80% by weight and tar 20-30% by weight of chaff charcoal It includes a tar mixing process (S300) to increase the calorie of the powder and to aggregate the rice husk charcoal powder, and a pellet molding process (S400) to form the pellet by injecting the chaff char-tar mixture into the molding machine 40 doing By constructing a solidified fuel manufacturing method, not only can the calorie charcoal powder be increased by the tar component, but the coal charcoal powder can be agglomerated, and on the other hand, it is possible to utilize the tar component that has been disposed of in the past, which is more environmentally friendly. It can be referred to as 'solidified fuel using chaff charcoal and its manufacturing method'.

Description

왕겨숯을 이용한 고형화 연료 및 그 제조방법{SOLID FUEL USING RICE HULL CHARCOAL AND MANUFACTURING METHOD THEREFOR}Solidified fuel using chaff charcoal and its manufacturing method {SOLID FUEL USING RICE HULL CHARCOAL AND MANUFACTURING METHOD THEREFOR}

본 발명은 왕겨숯을 이용한 고형화 연료 및 그 제조방법에 관한 것으로, 더욱 상세하게는 미곡종합처리장에서 부산물로 발생하는 왕겨를 탄화시킨 왕겨숯을 분쇄 및 타르와 혼합 성형하여 펠렛(pellet) 형태의 고형화 연료로 제조하되, 특히 왕겨의 탄화과정에서 발생하는 합성가스로부터 타르 성분을 응축 및 추출하여 상기 분쇄된 왕겨숯 분말과 혼합함으로써, 타르 성분에 의하여 왕겨숯 분말의 열량을 높일 뿐만 아니라, 왕겨숯 분말의 응집이 가능하며, 다른 한편으론 종래 폐기되었던 타르 성분을 효율적으로 활용하므로 보다 환경친화적이라 할 수 있는 '왕겨숯을 이용한 고형화 연료 및 그 제조방법'에 관한 것이다.
The present invention relates to a solidified fuel using chaff charcoal and a method of manufacturing the same, and more particularly, by shaping and mixing and shaping charcoal charcoal carbonized chaff generated as a by-product in a rice grain processing plant and solidified pellet (pellet) form Prepared as a fuel, in particular, by condensing and extracting the tar component from the syngas generated during the carbonization of chaff and mixed with the crushed chaff charcoal powder, not only to increase the calorie content of chaff charcoal powder by the tar component, chaff charcoal powder It is possible to agglomerate, and on the other hand, because it effectively utilizes the tar component that has been conventionally discarded, it relates to a 'solidified fuel using chaff charcoal and its manufacturing method' which is more environmentally friendly.

일반적으로 고형화 연료에는 합성수지나 종이, 나무, 섬유 등 여러 가지 폐자재가 소재로 이용되는데, 상기 고형화 연료는 안정적인 소재 공급과 유통이 가능하고, 저렴하며, 그 제조가 용이하여야 할 뿐만 아니라, 무엇보다 충분한 열량을 갖는 소재가 고형화 연료로 사용되기에 적합하다.
Generally, various waste materials such as synthetic resin, paper, wood, and fiber are used as the solidifying fuel, and the solidifying fuel is capable of supplying and distributing stable materials, inexpensive, and easy to manufacture. Materials with sufficient calories are suitable for use as solidifying fuels.

한편, 왕겨는 벼의 도정과정에서 대량으로 생성되는 부산물로서 국내에서 연간 약 백만 톤이 발생하여 그 물량이 충분함과 아울러 연중 도정으로 항상 일정량이 발생하므로 안정적인 공급이 가능할 뿐만 아니라, 저렴하며, 최종 소비지 근처에서 생산되어 그 유통이 편리하다는 점에서 고형화 연료로 사용하기에 적합하다.
On the other hand, chaff is a by-product produced in large quantities in the rice milling process, which generates about 1 million tonnes annually in Korea, and its quantity is sufficient. It is suitable for use as a solidified fuel because it is produced near a consumer area and its distribution is convenient.

그러나 왕겨는 상기와 같이 여러 가지 장점을 갖는 우수한 소재임에도 불구하고 유류 대체 연료인 연탄이나 화목 등의 고체연료에 비해 연료로서의 이용률이 매우 낮고, 대부분의 경우에 있어서는 농업용 퇴비재료로 이용되거나 축산업용으로 사용되었으며, 일부 탄화처리하여 연료로 활용하고 있는 실정이다.
However, although chaff is an excellent material having various advantages as described above, the utilization of chaff is very low as a fuel compared to solid fuels such as briquettes and firewood, which are alternative fuels, and in most cases, it is used as agricultural compost material or for livestock industry. It is used, and some carbonization is used as fuel.

이와 같이 왕겨가 대체 연료로서의 이용률이 낮은 이유는 성분조성이 탄소 35%, 수소 5%, 산소 39%, 회분 20%로 이루어져 연소온도가 화목이나 톱밥 등의 고체연료보다 상대적으로 높고, 규소를 다량 함유한 판상의 구조로 되어 있어 발열량이 부족하기 때문이었다.
The low utilization rate of chaff as an alternative fuel is composed of 35% carbon, 5% hydrogen, 39% oxygen, and 20% ash, and its combustion temperature is relatively higher than that of solid fuels such as wood and sawdust. It was because the plate-like structure contained was insufficient in the amount of heat generated.

또한, 왕겨는 작은 입자의 형태로 이루어져 있기 때문에 고형화 연료로 제조하기 위해서는 응집제를 혼합하여야 하는데, 별도의 응집제를 사용함으로 인하여 결과적으로 고형화 연료의 원가가 상승하는 문제점이 있었기 때문이다.
In addition, since the chaff is made in the form of small particles, in order to produce a solidified fuel, a flocculant must be mixed, because the cost of the solidified fuel is increased as a result of using a separate flocculant.

본 발명은 상기와 같은 문제점을 해결하기 위한 것으로, 왕겨를 탄화시킨 왕겨숯을 분쇄 및 성형하여 펠렛(pellet) 형태의 고형화 연료로 제조하되, 상기 왕겨숯에 타르를 혼합하여 부족한 왕겨숯의 열량을 높임과 아울러 상기 타르에 의하여 왕겨숯 분말이 응집되도록 한 고형화 연료를 제공하는데 본 발명의 목적이 있다. 또한, 상기 왕겨숯 분말과 혼합되는 타르를 왕겨의 탄화과정에서 발생하는 합성가스로부터 추출하여 혼합하는 고형화 연료의 제조방법을 구성함으로써 외부 자원을 필요치 않을 뿐만 아니라 종래 왕겨숯 제조시 폐기되던 타르 성분을 효율적으로 활용하는데 다른 목적이 있다.
The present invention is to solve the problems as described above, by pulverizing and shaping the charcoal charcoal charcoal chaff produced by the solidified fuel of the pellet (pellet) form, by mixing the tar with the chaff charcoal calorie of insufficient chaff charcoal It is an object of the present invention to provide a solidification fuel in which the chaff charcoal powder is agglomerated by the tar. In addition, by constructing a method of manufacturing a solidified fuel extracting and mixing the tar mixed with the chaff charcoal powder from the carbonization of the chaff charcoal, not only external resources are required, but also the tar components discarded during the manufacture of the chaff charcoal There is another purpose to use it efficiently.

상기의 목적을 달성하기 위한 본 발명의 구성은, 왕겨숯 분말 70~80중량%와 타르 20~30중량%로 이루어져 펠렛 형태로 성형된 '왕겨숯을 이용한 고형화 연료'를 특징으로 한다.
The configuration of the present invention for achieving the above object, consisting of 70 to 80% by weight chaff charcoal powder and 20 to 30% by weight tar is characterized in that the 'solidified fuel using chaff charcoal' molded in the form of pellets.

그리고 본 발명은, 제한된 공기가 유입되는 탄화로에 왕겨를 투입하여 고온으로 열분해하는 왕겨탄화공정과, 상기 탄화로에서 배출되는 왕겨숯을 분쇄기로 투입하여 왕겨숯 분말을 형성하는 왕겨숯 분쇄공정과, 상기 왕겨숯 분말 70~80중량%와 타르 20~30중량%를 교반기에 혼합하여 왕겨숯 분말의 열량을 높임과 아울러 왕겨숯 분말이 응집될 수 있도록 하는 타르혼합공정과, 상기 왕겨숯-타르 혼합물을 성형기에 투입하여 펠렛을 형성하는 펠렛성형공정을 포함하는 '왕겨숯을 이용한 고형화 연료의 제조방법'에 다른 특징이 있다.
And the present invention, the chaff charcoal process for thermally decomposing chaff into a carbonized furnace into which limited air is introduced, and the chaff charcoal crushing process for adding chaff charcoal discharged from the carbonization furnace into a grinder to form chaff charcoal powder; In addition, by mixing the 70 to 80% by weight of chaff charcoal powder and 20 to 30% by weight of tar in a stirrer to increase the calorie of chaff charcoal powder and to aggregate the chaff charcoal powder and the chaff charcoal-tar There is another feature of the method for preparing solidified fuel using chaff charcoal, including a pellet molding process in which the mixture is introduced into a molding machine to form pellets.

또한 본 발명은, 상기 탄화로에서 배출되는 합성가스를 응축기로 유입하여 합성가스로부터 왕겨초액을 응축하는 초액응축공정과, 상기 응축된 왕겨초액을 침전탱크로 유입하여 왕겨초액에 포함된 타르 성분을 침전시킨 다음 상기 타르 성분을 타르혼합공정에서 사용할 수 있도록 교반기로 공급하는 타르추출공정을 더 포함하는 '왕겨숯을 이용한 고형화 연료의 제조방법'과, 상기 왕겨숯 분쇄공정에 있어 탄화로에서 배출되는 왕겨숯 50~95중량%와 생왕겨 5~50중량%를 분쇄기로 투입하여 왕겨숯 분말을 형성하는 '왕겨숯을 이용한 고형화 연료의 제조방법'에 또 다른 특징이 있다.
The present invention also provides a condensation process of condensing rice hull liquor from the synthesis gas by introducing the syngas discharged from the carbonization furnace into a condenser, and introducing the tar component contained in the rice husk herb solution by introducing the condensed chaff liquor into the precipitation tank. 'Preparation method of solidifying fuel using chaff charcoal', which further comprises a tar extraction step of precipitating and supplying the tar component to a stirrer for use in a tar mixing process, and discharged from a carbonization furnace in the chaff charcoal grinding process. There is another feature of the method of preparing solidified fuel using chaff charcoal, which is prepared by adding 50 to 95% by weight of chaff charcoal and 5 to 50% by weight of fresh chaff as a grinder.

상기와 같은 구성의 본 발명에 의하면, 왕겨숯을 분쇄 및 성형하여 펠렛(pellet) 형태의 고형화 연료로 제조함에 있어, 왕겨의 탄화과정에서 발생하는 합성가스로부터 타르 성분을 응축 및 추출하여 상기 분쇄된 왕겨숯 분말과 혼합함으로써, 타르 성분에 의하여 왕겨숯 분말의 열량을 높일 수 있는 효과가 있을 뿐만 아니라, 별도의 응집제를 사용하지 않고 왕겨숯 분말의 응집이 가능하므로 제조비용을 절감할 수 있는 효과가 있다. 그리고 종래 폐기되었던 타르 성분을 효율적으로 활용하므로 결과적으로 환경친화적인 고형화 연료를 제조하는 효과 또한 있다.
According to the present invention having the above-described configuration, in the manufacture of a pelletized solid fuel by crushing and shaping chaff charcoal, condensation and extraction of the tar component from the syngas generated during the carbonization process of chaff, By mixing with the chaff charcoal powder, not only has the effect of increasing the calorie content of the chaff charcoal powder by the tar component, but also can reduce the manufacturing cost because it is possible to aggregate the chaff charcoal powder without using a separate flocculant. have. In addition, since the tar component used in the prior art is efficiently utilized, there is also an effect of producing an environmentally friendly solidified fuel.

도 1은 본 발명의 일 실시예에 따른 왕겨숯을 이용한 고형화 연료의 제조방법을 나타내는 순서도
도 2는 본 발명의 다른 실시예에 따른 왕겨숯을 이용한 고형화 연료의 제조방법을 나타내는 순서도
도 3은 본 발명에 따른 왕겨숯을 이용한 고형화 연료의 제조방법을 나타내는 공정도
1 is a flow chart showing a method for producing a solidified fuel using chaff charcoal according to an embodiment of the present invention
Figure 2 is a flow chart showing a method for producing a solidified fuel using chaff charcoal according to another embodiment of the present invention
Figure 3 is a process chart showing a method for producing a solidified fuel using chaff charcoal according to the present invention

이하 본 발명의 바람직한 실시예에 따른 왕겨숯을 이용한 고형화 연료의 구성을 살펴보면, 상기 고형화 연료는 왕겨숯 분말 70~80중량%와 타르 20~30중량%를 혼합하여 펠렛의 형태로 성형하거나, 또는 왕겨숯 분말 50~95중량%과 생왕겨 분말 5~50중량%를 혼합한 왕겨숯-생왕겨 혼합분말 70~80중량%에 대하여 타르 20~30중량%를 혼합하여 펠렛의 형태로 성형한다. 이때, 상기 펠렛은 직경 6~8mm 및 길이 6~30mm로 형성함이 바람직하지만, 본 발명은 상기 펠렛의 크기에 한정하지 않는다.
Looking at the configuration of the solidified fuel using chaff charcoal according to a preferred embodiment of the present invention, the solidified fuel is molded in the form of pellets by mixing 70 to 80% by weight of chaff charcoal powder and 20 to 30% by weight of tar, or 50 to 95% by weight of chaff charcoal powder and 5 to 50% by weight of raw chaff powder are mixed in a form of pellets by mixing 20-30% by weight of tar with respect to 70-80% by weight of chaff charcoal-raw chaff mixed powder. At this time, the pellet is preferably formed with a diameter of 6 ~ 8mm and a length of 6 ~ 30mm, the present invention is not limited to the size of the pellet.

이하 본 발명의 바람직한 실시예에 따른 왕겨숯을 이용한 고형화 연료의 제조방법을 공정별로 구분하여 상세히 살펴보는바, 본 발명은 도 1에 도시된 바와 같이 왕겨탄화공정(S100), 왕겨숯 분쇄공정(S200), 타르혼합공정(S300), 펠렛성형공정(S400) 및 펠렛건조공정(S500)을 주요 구성으로 하고, 도 2에 도시된 바와 같이 초액응축공정(S210) 및 타르추출공정(S220)을 부가적인 구성으로 더 포함한다.
Hereinafter, the method for preparing a solidified fuel using chaff charcoal according to a preferred embodiment of the present invention will be described in detail by the process. The present invention shows a rice husk carbonization process (S100) and chaff charcoal grinding process (as shown in FIG. 1). S200), tar mixing process (S300), pellet molding process (S400) and pellet drying process (S500) as the main configuration, as shown in Figure 2 the liquid-liquid condensation process (S210) and tar extraction process (S220) It further includes as an additional configuration.

<왕겨탄화공정>&Lt; Process of rice husk carbonization &

왕겨탄화공정(S100)은 제한된 공기가 유입되는 탄화로(10)에 왕겨를 투입하여 고온으로 열분해하는 공정으로서, 도 3의 도시와 같이 탄화로(10)의 상측으로부터 탄화로(10)의 내부로 유입되는 왕겨는 탄화로(10) 하부의 흡기구를 통하여 제한된 공기가 유입되는 상태에서 상기 탄화로(10)에 구비된 버너에 의하여 300~700℃로 열분해 되고, 상기 열분해에 의하여 탄화된 왕겨숯은 탄화로(10)의 하부로 배출되며, 열분해 과정에서 발생한 합성가스는 탄화로(10)의 상측을 통하여 배기 되는바, 본 발명은 상기와 같은 탄화로(10)의 세부 구성에 한정하지 않는다.
Rice husk carbonization process (S100) is a step of thermally decomposing the chaff into the carbonization furnace 10 into which limited air is introduced, and pyrolysis at a high temperature, as shown in FIG. 3, from the upper side of the carbonization furnace 10 to the inside of the carbonization furnace 10. The chaff introduced into the rice is thermally decomposed to 300 ~ 700 ℃ by the burner provided in the carbonization furnace 10 in a state in which limited air is introduced through the inlet port under the carbonization furnace 10, and the charcoal charred by the pyrolysis. Silver is discharged to the lower portion of the carbonization furnace 10, the synthesis gas generated in the pyrolysis process is exhausted through the upper side of the carbonization furnace 10, the present invention is not limited to the detailed configuration of the carbonization furnace 10 as described above .

<왕겨숯 분쇄공정>Chaff charcoal grinding process

왕겨숯 분쇄공정(S200)은 상기 탄화로(10)에서 배출되는 왕겨숯을 분쇄기(20)로 투입하여 왕겨숯 분말을 형성하는 공정으로서, 본 발명은 상기 분쇄기(20)의 형식이나 종류에 한정하지 않는다. 한편, 상기 분쇄기(20)에는 왕겨숯만을 투입하여 순수한 왕겨숯 분말을 형성할 수도 있지만, 부가적으로 상기 탄화로(10)에서 배출되는 왕겨숯 50~95중량%와 생왕겨 5~50중량%를 분쇄기(20)로 투입함으로써 생왕겨 분말이 함유된 왕겨숯 분말을 형성할 수도 있다. 이 경우 생왕겨를 탄화하는 비용을 절감할 수 있으므로, 궁극적으로는 보다 저렴한 비용으로 고형화 연료를 제조할 수 있다.
Chaff charcoal grinding step (S200) is a step of forming the chaff charcoal powder by injecting chaff charcoal discharged from the carbonization furnace 10 into the grinder 20, the present invention is limited to the type or type of the grinder 20 I never do that. On the other hand, in the grinder 20 may be added only chaff charcoal to form a pure chaff charcoal powder, additionally 50 to 95% by weight chaff charcoal discharged from the carbonization furnace 10 and 5 to 50% by weight chaff The chaff charcoal powder containing the raw chaff powder may be formed by adding the to the grinder 20. In this case, the cost of carbonizing raw rice hulls can be reduced, thus ultimately producing a solidified fuel at a lower cost.

<초액응축공정><Solid Condensation Process>

초액응축공정(S210)은 상기 탄화로(10)에서 배출되는 합성가스를 응축기(21)로 유입하여 합성가스로부터 왕겨초액을 응축하는 부가적 공정이다. 상기에 있어 응축기(21)의 내부에는 다수의 응축관이 형성되어 냉매(냉각수 등)가 순환함에 따라, 응축기(21)로 유입된 고온의 합성가스에서 결로현상이 유도되어 왕겨초액을 얻을 수 있다. 한편, 상기 왕겨초액을 추출한 후 응축기(21)에서 배출되는 합성가스는 통상의 열교환기(미도시)로 공급하여 열회수 하거나, 또는 합성가스를 고도로 정제한 후 발전기(미도시) 엔진의 연료로 사용함으로써 에너지화할 수 있다.
The liquid liquor condensation process (S210) is an additional process of condensing rice hull liquor from the syngas by introducing the syngas discharged from the carbonization furnace 10 into the condenser 21. In the condenser 21, a plurality of condensation tubes are formed in the condenser 21 as the refrigerant (cooling water, etc.) is circulated, condensation may be induced in the high temperature synthesis gas introduced into the condenser 21 to obtain chaff herb solution. . On the other hand, the syngas discharged from the condenser 21 after extracting the rice husk herb is supplied to a heat exchanger (not shown) to heat recovery, or after highly purified synthesis gas used as a fuel for the generator (not shown) Energy can be achieved by doing this.

<타르추출공정><Tar Extraction Process>

타르추출공정(S220)은 상기 응축된 왕겨초액을 침전탱크(22)로 유입하여 왕겨초액에 포함된 타르 성분을 침전시키는 부가적 공정인바, 상기 침전탱크(22)의 하부에 침전된 타르 성분은 후술할 교반기(30)로 공급되어 타르혼합공정(S300)에서 사용된다. 한편, 상기 타르 성분이 침전 및 추출된 왕겨초액은 상기 침전탱크(22) 내에서 숙성된 이후 농약이나 살충제 등의 농업용 또는 각종 세정제품 등의 원료로 사용한다.
The tar extraction process (S220) is an additional process of injecting the condensed rice hull liquor into the settling tank 22 to precipitate the tar component contained in the rice hull liquor, and the tar component deposited on the lower portion of the settling tank 22 is It is supplied to the stirrer 30 to be described later is used in the tar mixing process (S300). Meanwhile, the chaff herb solution from which the tar component is precipitated and extracted is aged in the precipitation tank 22, and then used as a raw material for agricultural or various cleaning products such as pesticides or insecticides.

<타르혼합공정><Tar mixing process>

타르혼합공정(S300)은 상기 왕겨숯 분말 70~80중량%와 타르 20~30중량%를 교반기(30)에 혼합하는 공정으로서, 이때 타르가 혼합된 왕겨숯 분말은 그 열량이 높아질 뿐만 아니라, 상기 타르에 의하여 별도의 응집제가 필요없이 왕겨숯 분말이 응집될 수 있다. 한편, 상기 왕겨숯 분쇄공정(S200)에서 왕겨숯 50~95중량%에 대하여 생왕겨 5~50중량%를 혼합한 경우에는 상기 생왕겨 분말이 함유된 왕겨숯 분말 70~80중량%에 대하여 타르 20~30중량%가 혼합된다. 또한, 상기 부가적 공정으로서 초액응축공정(S210) 및 타르추출공정(S220)을 실시하지 않는 경우에는 상기 타르는 외부로부터 공급받을 수 있다.
Tar mixing process (S300) is a step of mixing 70 ~ 80% by weight of chaff charcoal powder and 20 to 30% by weight of tar in the stirrer (30), wherein the tar is chaff charcoal powder is not only high calorie, The tar may be aggregated chaff charcoal powder without the need for a separate flocculant. On the other hand, when the chaff charcoal crushing process (S200) is mixed with chaff charcoal 5 to 50% by weight relative to the chaff charcoal 50 to 95% by weight of the chaff charcoal powder containing the raw chaff powder 70 to 80% by weight of tar 20-30% by weight is mixed. In addition, when the liquid-liquid condensation step (S210) and the tar extraction step (S220) are not performed as the additional step, the tar may be supplied from the outside.

<펠렛성형공정><Pellet molding process>

펠렛성형공정(S400)은 상기 타르혼합공정(S300)에서 교반된 왕겨숯-타르 혼합물을 성형기(40)에 투입하여 펠렛을 형성하는 공정이다. 이때, 상기 펠렛은 직경 6~8mm 및 길이 6~30mm로 형성함이 바람직하다.
Pellet molding step (S400) is a step of forming a pellet by injecting the chaff char-tar mixture stirred in the tar mixing step (S300) to the molding machine (40). At this time, the pellets are preferably formed with a diameter of 6 ~ 8mm and a length of 6 ~ 30mm.

<펠렛건조공정>Pellet drying process

펠렛건조공정(S500)은 상기 펠렛성형공정(S400)에서 소정의 형상 및 규격으로 성형된 펠렛을 건조시키는 공정으로서 자연건조 또는 열풍건조를 선택할 수 있는바, 본 발명은 상기 펠렛의 건조방법에 한정하지 않는다.
Pellet drying step (S500) is a step of drying the pellets formed in a predetermined shape and standard in the pellet molding step (S400) can be selected natural drying or hot air drying bar, the present invention is limited to the drying method of the pellet I never do that.

이하, 상기와 같은 구성의 본 발명에 따른 '왕겨숯을 이용한 고형화 연료 및 그 제조방법'의 작용을 살펴보면, 탄화로(10)에서 열분해 된 왕겨숯을 분쇄 및 성형하여 펠렛(pellet) 형태의 고형화 연료로 구성함에 있어서, 상기 분쇄된 왕겨숯 분말에 대하여 타르를 혼합함으로써 왕겨숯 분말의 열량을 4,100~4,800㎉/㎏까지 높일 수 있을 뿐만 아니라, 별도의 응집제를 필요치 않고도 왕겨숯 분말의 응집이 가능하다.
Hereinafter, looking at the action of the 'solidified fuel using chaff charcoal and the method for producing the chaff charcoal according to the present invention as described above, by pulverizing and shaping the chaff charcoal pyrolyzed in the carbonization furnace 10 to solidify the pellet (pellet) form In the composition of fuel, by mixing the tar with the crushed chaff charcoal powder can not only increase the calorie content of chaff charcoal powder to 4,100 ~ 4,800㎉ / ㎏, it is possible to aggregate the chaff charcoal powder without the need of a separate flocculant Do.

특히, 왕겨의 탄화과정에서 발생하는 합성가스로부터 타르 성분을 응축 및 추출하여 상기 왕겨숯 분말과 혼합함으로써, 고형화 연료의 제작비용을 절감할 수 있음은 물론이고, 다른 한편으론 종래 폐기되었던 타르 성분을 효율적으로 활용하므로 결과적으로 보다 환경친화적이라 할 수 있다.
In particular, by condensing and extracting the tar component from the syngas generated during the carbonization of rice husk and mixing with the chaff charcoal powder, it is possible to reduce the production cost of the solidified fuel, and on the other hand, As it is used efficiently, it is more environmentally friendly.

10: 탄화로 20: 분쇄기
21: 응축기 22: 침전탱크
30: 교반기 40: 성형기
S100: 왕겨탄화공정 S200: 왕겨숯 분쇄공정
S210: 초액응축공정 S220: 타르추출공정
S300: 타르혼합공정 S400: 펠렛성형공정
S500: 펠렛건조공정
10: carbonization furnace 20: grinder
21: condenser 22: settling tank
30: stirrer 40: molding machine
S100: chaff carbonization process S200: chaff charcoal grinding process
S210: supercondensation process S220: tar extraction process
S300: Tar mixing process S400: Pellet forming process
S500: Pellet Drying Process

Claims (4)

삭제delete 삭제delete 제한된 공기가 유입되는 탄화로(10)에 왕겨를 투입하여 고온으로 열분해하는 왕겨탄화공정(S100)과;
상기 탄화로(10)에서 배출되는 왕겨숯을 분쇄기(20)로 투입하여 왕겨숯 분말을 형성하는 왕겨숯 분쇄공정(S200)과;
상기 탄화로(10)에서 배출되는 합성가스를 응축기(21)로 유입하여 합성가스로부터 왕겨초액을 응축하는 초액응축공정(S210)과;
상기 응축된 왕겨초액을 침전탱크(22)로 유입하여 왕겨초액에 포함된 타르 성분을 침전시킨 후, 상기 타르 성분을 타르혼합공정(S300)에서 사용할 수 있도록 교반기(30)로 공급하는 타르추출공정(S220)과;
상기 왕겨숯 분말 70~80중량%와 타르 20~30중량%를 교반기(30)에 혼합하여 왕겨숯 분말의 열량을 높이고, 아울러 왕겨숯 분말이 응집될 수 있도록 하는 타르혼합공정(S300)과;
상기 타르혼합공정(S300)에서 교반된 왕겨숯-타르 혼합물을 성형기(40)에 투입하여 펠렛을 형성하는 펠렛성형공정(S400)을 포함하는 것을 특징으로 하는 왕겨숯을 이용한 고형화 연료의 제조방법.
Rice husk carbonization process (S100) for thermally decomposing at high temperature by injecting rice husk into the carbonization furnace 10 is a limited air flow;
Chaff charcoal crushing process (S200) of forming the chaff charcoal powder by injecting the chaff charcoal discharged from the carbonization furnace 10 into the grinder 20;
A condensation solution (S210) for condensing rice hull liquor from the synthesis gas by introducing the synthesis gas discharged from the carbonization furnace 10 into the condenser 21;
The condensed rice husk liquor is introduced into the precipitation tank 22 to precipitate the tar component contained in the rice husk liquor, and the tar extraction process of supplying the tar component to the stirrer 30 to be used in the tar mixing process (S300). (S220);
70 to 80% by weight of chaff charcoal powder and 20 to 30% by weight of tar in the stirrer (30) to increase the calorie of chaff charcoal powder, and also to mix the chaff charcoal powder (S300);
The method of producing a solidified fuel using chaff charcoal, characterized in that it comprises a pellet forming step (S400) to form a pellet by injecting the chaff char-tar mixture stirred in the tar mixing process (S300) to the molding machine (40).
제3항에 있어서;
상기 왕겨숯 분쇄공정(S200)은, 상기 탄화로(10)에서 배출되는 왕겨숯 50~95중량%와 생왕겨 5~50중량%를 분쇄기(20)로 투입하여 왕겨숯 분말을 형성하는 것을 특징으로 하는 왕겨숯을 이용한 고형화 연료의 제조방법.
4. The method of claim 3, further comprising:
The chaff charcoal grinding step (S200), 50 to 95% by weight of chaff charcoal discharged from the carbonization furnace 10 and 5 to 50% by weight of fresh chaff into the grinder 20 to form chaff charcoal powder Method for producing a solidified fuel using chaff charcoal.
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Publication number Priority date Publication date Assignee Title
KR20220099624A (en) 2021-01-07 2022-07-14 주식회사 대윤 High-efficiency solid fuel containing recycled coffee waste and half-carbonized rice husks and manufacturing method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008001860A (en) * 2006-06-26 2008-01-10 Riscarbo Kk Recycled fuel for biomass resources
KR20110009294A (en) * 2009-07-22 2011-01-28 김상돈 Manufacturing method of solid fuel using chaff

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008001860A (en) * 2006-06-26 2008-01-10 Riscarbo Kk Recycled fuel for biomass resources
KR20110009294A (en) * 2009-07-22 2011-01-28 김상돈 Manufacturing method of solid fuel using chaff

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20220099624A (en) 2021-01-07 2022-07-14 주식회사 대윤 High-efficiency solid fuel containing recycled coffee waste and half-carbonized rice husks and manufacturing method thereof

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