KR101197773B1 - The inorganic adhesive composition for furnitures and the inorganic adhesive for furnitures utilizing thereof - Google Patents
The inorganic adhesive composition for furnitures and the inorganic adhesive for furnitures utilizing thereof Download PDFInfo
- Publication number
- KR101197773B1 KR101197773B1 KR1020090132453A KR20090132453A KR101197773B1 KR 101197773 B1 KR101197773 B1 KR 101197773B1 KR 1020090132453 A KR1020090132453 A KR 1020090132453A KR 20090132453 A KR20090132453 A KR 20090132453A KR 101197773 B1 KR101197773 B1 KR 101197773B1
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- parts
- furniture
- mineral powder
- inorganic adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000000853 adhesive Substances 0.000 title claims abstract description 47
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 46
- 239000000203 mixture Substances 0.000 title claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 57
- 229910001868 water Inorganic materials 0.000 claims abstract description 57
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 56
- 239000011707 mineral Substances 0.000 claims abstract description 56
- 239000011230 binding agent Substances 0.000 claims abstract description 54
- 239000000843 powder Substances 0.000 claims abstract description 36
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 34
- 239000007788 liquid Substances 0.000 claims abstract description 34
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 33
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 33
- 102000004190 Enzymes Human genes 0.000 claims abstract description 24
- 108090000790 Enzymes Proteins 0.000 claims abstract description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910001514 alkali metal chloride Inorganic materials 0.000 claims abstract description 17
- 238000002156 mixing Methods 0.000 claims abstract description 17
- 229910001617 alkaline earth metal chloride Inorganic materials 0.000 claims abstract description 16
- 239000002562 thickening agent Substances 0.000 claims abstract description 16
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 14
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- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 12
- 150000001875 compounds Chemical class 0.000 claims abstract description 12
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 12
- 150000001342 alkaline earth metals Chemical class 0.000 claims abstract description 11
- 239000000440 bentonite Substances 0.000 claims abstract description 11
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 11
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 11
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 10
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 9
- 238000002360 preparation method Methods 0.000 claims abstract description 4
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- 239000004094 surface-active agent Substances 0.000 claims description 7
- 229910052900 illite Inorganic materials 0.000 claims description 6
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical group [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 claims description 4
- 229910052676 chabazite Inorganic materials 0.000 claims description 4
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- 239000004615 ingredient Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 23
- 238000003912 environmental pollution Methods 0.000 abstract description 11
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 abstract description 10
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- 208000008842 sick building syndrome Diseases 0.000 abstract description 8
- 238000000034 method Methods 0.000 abstract description 7
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- 238000009833 condensation Methods 0.000 abstract description 4
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- 238000002425 crystallisation Methods 0.000 abstract description 4
- 230000008025 crystallization Effects 0.000 abstract description 4
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- 229920000642 polymer Polymers 0.000 abstract 1
- 239000011734 sodium Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 239000013078 crystal Substances 0.000 description 8
- 230000005484 gravity Effects 0.000 description 8
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical group Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000011435 rock Substances 0.000 description 5
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- 229910004298 SiO 2 Inorganic materials 0.000 description 4
- 230000009931 harmful effect Effects 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- -1 aluminum silicate hydrates Chemical class 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 210000003462 vein Anatomy 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 239000010438 granite Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
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- 239000007769 metal material Substances 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 235000019795 sodium metasilicate Nutrition 0.000 description 2
- 208000024891 symptom Diseases 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 206010011224 Cough Diseases 0.000 description 1
- 206010013082 Discomfort Diseases 0.000 description 1
- 229910052692 Dysprosium Inorganic materials 0.000 description 1
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- 229910052693 Europium Inorganic materials 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 229910052689 Holmium Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
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- 208000003251 Pruritus Diseases 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
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- 206010043521 Throat irritation Diseases 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
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- 150000001768 cations Chemical class 0.000 description 1
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- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
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- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 1
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- PMYUVOOOQDGQNW-UHFFFAOYSA-N hexasodium;trioxido(trioxidosilyloxy)silane Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] PMYUVOOOQDGQNW-UHFFFAOYSA-N 0.000 description 1
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- 150000004677 hydrates Chemical class 0.000 description 1
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- 150000002500 ions Chemical class 0.000 description 1
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- 239000007791 liquid phase Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000005415 magnetization Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
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- BWAUQTFFVCLSOS-UHFFFAOYSA-N sodiosodium hydrate Chemical compound O.[Na].[Na] BWAUQTFFVCLSOS-UHFFFAOYSA-N 0.000 description 1
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- XREXPQGDOPQPAH-QKUPJAQQSA-K trisodium;[(z)-18-[1,3-bis[[(z)-12-sulfonatooxyoctadec-9-enoyl]oxy]propan-2-yloxy]-18-oxooctadec-9-en-7-yl] sulfate Chemical compound [Na+].[Na+].[Na+].CCCCCCC(OS([O-])(=O)=O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(CCCCCC)OS([O-])(=O)=O)COC(=O)CCCCCCC\C=C/CC(CCCCCC)OS([O-])(=O)=O XREXPQGDOPQPAH-QKUPJAQQSA-K 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
- C08L1/26—Cellulose ethers
- C08L1/28—Alkyl ethers
- C08L1/286—Alkyl ethers substituted with acid radicals, e.g. carboxymethyl cellulose [CMC]
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J1/00—Adhesives based on inorganic constituents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C08K2003/166—Magnesium halide, e.g. magnesium chloride
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
본 발명은 가구용 무기접착제 조성물과 이를 이용한 가구용 무기접착제에 관한 것으로, 소듐실리케이트 100중량부에 대하여 액상의 결합제 3 ~ 10중량부, 광물질 분말 5 ~ 30중량부, 셀라이트 5 ~ 15중량부 및 증점제 1 ~ 8중량부 첨가되어 구성되어지되, 상기 액상의 결합제는 a) 알칼리금속염화물 및 알칼리토금속염화물로 구성되는 군으로부터 선택된 적어도 1종 이상의 화합물을 친수성(hydrophilic) 효소(enzyme) 표면에 소수성(hydrophobic) 폴리머(polymer)를 결합시켜 제조한 양친매성(amphiphilic) 계면활성효소(surface-active enzyme)와 클러스터화된 물의 혼합물에 투입하여 알칼리금속 또는 알칼리토금속을 용출시킨 용액에, b) 액상의 결합제 제조시 사용되는 클러스터화 된 물 전체 사용량에 대하여 1중량% 미만의 희토류 원소를 함유하는 물과, c) pH조절제를 혼합하여 제조한 것이고, 상기 광물질 분말은 일라이트, 제올라이트, 벤토나이트, 몬모릴로나이트, 캐버자이트, 휼란다이트, 스틸바이트, 로몬타이트로 구성되는 군으로부터 선택되는 적어도 1종 이상이며, 소듐실리케이트, 액상의 결합제, 광물질분말, 셀라이트 및 증점제를 준비하는 단계; 상기 성분들을 균일하게 혼합하는 단계로 구성되는 방법으로 가구용 무기접착제를 제조하고, 이를 사용하여 가구용 목재, 석재, 합성수지재 등의 자재 접착시켜 가구를 제조함으로써 소듐실리케이트, 광물질분말, 셀라이트에 존재하는 무기물 및 바인더 내부의 무기물 용탈(dissolusion) → 아쿠아졸 형성(formation of aquasols) → 응축(condensation) → 겔 형성(gel formation) → 결정화(crystallization)하는 반응으로 강한 결합력이 발휘되기 때문에 일정 접착력 이상의 가구를 제조할 수 있을 뿐만 아니라 유기 바인더를 사용하지 않아 새집증후군을 유발하는 물질의 배출이 없고, 무기물로만 이루어진 바인더를 사용함으로써 환경오염을 유발하는 물질의 배출이 없어 폐기시에도 환경 오염을 유발하지 않으며, 경제적이고 간단한 방법으로 가구의 접착제로 사용될 수 있다.The present invention relates to an inorganic adhesive composition for furniture and an inorganic adhesive for furniture using the same, with respect to 100 parts by weight of sodium silicate, liquid binder 3 to 10 parts by weight, mineral powder 5 to 30 parts by weight, celite 5 to 15 parts by weight and thickener 1 to 8 parts by weight is added, wherein the liquid binder is a) hydrophobic (hydrophobic) at least one compound selected from the group consisting of alkali metal chlorides and alkaline earth metal chlorides on the surface of the hydrophilic enzyme (enzyme) B) Preparation of a liquid binder in a solution in which an alkali metal or an alkaline earth metal is eluted by adding to a mixture of amphiphilic surface-active enzyme prepared by combining polymers and clustered water. C) mixing the pH-adjusting agent with water containing less than 1% by weight of rare earth elements relative to the total amount of clustered water used The mineral powder is at least one selected from the group consisting of elite, zeolite, bentonite, montmorillonite, caberzite, hydrandite, stilbite, lomontite, sodium silicate, liquid binder Preparing a mineral powder, celite and a thickener; The inorganic adhesive for furniture is manufactured by the method comprising the steps of uniformly mixing the components, and by using this to bond the materials such as furniture wood, stone, synthetic resin materials to produce furniture present in sodium silicate, mineral powder, celite Disinlusion of minerals and minerals inside the binder → Formation of aquasols → Condensation → Gel formation → Crystallization Not only can it be manufactured, there is no emission of substances that cause sick house syndrome due to the absence of organic binders, and there is no emission of substances that cause environmental pollution by using only binders that do not cause environmental pollution at disposal. Can be used as an adhesive for furniture in an economical and simple way .
가구, 광물질분말, 무기질 바인더, 새집증후군 Furniture, mineral powder, inorganic binder, sick house syndrome
Description
본 발명은 가구용 무기접착제 조성물과 이를 이용한 가구용 무기접착제에 관한 것으로, 좀 더 구체적으로는 소듐실리케이트 100중량부에 대하여 액상의 결합제 3 ~ 10중량부, 광물질 분말 5 ~ 30중량부, 셀라이트 5 ~ 15중량부 및 증점제 1 ~ 8중량부 첨가되어 구성되어지되, 상기 액상의 결합제는 a) 알칼리금속염화물 및 알칼리토금속염화물로 구성되는 군으로부터 선택된 적어도 1종 이상의 화합물을 친수성(hydrophilic) 효소(enzyme) 표면에 소수성(hydrophobic) 폴리머(polymer)를 결합시켜 제조한 양친매성(amphiphilic) 계면활성효소(surface-active enzyme)와 클러스터화된 물의 혼합물에 투입하여 알칼리금속 또는 알칼리토금속을 용출시킨 용액에, b) 액상의 결합제 제조시 사용되는 클러스터화 된 물 전체 사용량에 대하여 1중량% 미만의 희토류 원소를 함유하는 물과, c) pH조절제를 혼합하여 제조한 것이고, 상기 광물질 분말은 일라이트, 제올라이트, 벤토나이트, 몬모릴로나이트, 캐버자이트, 휼란다이트, 스틸바이트, 로몬타이트로 구성되는 군으로부터 선택되는 적어도 1종 이상이며, 소듐실리케이트, 액상의 결합제, 광물질분말, 셀라이트 및 증점제를 준비하는 단계; 상기 성분들을 균일하게 혼합하는 단계로 구성되는 방법으로 가구용 무기접착제를 제조하고, 이를 사용하여 가구용 목재, 석재, 합성수지재 등의 자재 접착시켜 가구를 제조함으로써 소듐실리케이트, 광물질분말, 셀라이트에 존재하는 무기물 및 바인더 내부의 무기물 용탈(dissolusion) → 아쿠아졸 형성(formation of aquasols) → 응축(condensation) → 겔 형성(gel formation) → 결정화(crystallization)하는 반응으로 강한 결합력이 발휘되기 때문에 일정 접착력 이상의 가구를 제조할 수 있을 뿐만 아니라 유기 바인더를 사용하지 않아 새집증후군을 유발하는 물질의 배출이 없고, 무기물로만 이루어진 바인더를 사용함으로써 환경오염을 유발하는 물질의 배출이 없어 폐기시에도 환경 오염을 유발하지 않으며, 경제적이고 간단한 방법으로 가구의 접착제로 사용될 수 있는 가구용 무기접착제 조성물과 이를 이용한 가구용 무기접착제에 관한 것이다.The present invention relates to an inorganic adhesive composition for furniture and an inorganic adhesive for furniture using the same, more specifically, 3 to 10 parts by weight of a liquid binder, 5 to 30 parts by weight of mineral powder, and 5 to 3 parts by weight of sodium silicate. 15 parts by weight and one to eight parts by weight of a thickener are added, wherein the liquid binder is a) hydrophilic enzyme (enzyme) at least one or more compounds selected from the group consisting of alkali metal chlorides and alkaline earth metal chlorides In a solution in which an alkali metal or alkaline earth metal is eluted by adding a mixture of amphiphilic surface-active enzyme and clustered water prepared by bonding a hydrophobic polymer to the surface, b ) Water containing less than 1% by weight of rare earth elements based on the total amount of clustered water used in the manufacture of liquid binders, c) is prepared by mixing a pH adjuster, the mineral powder is at least one selected from the group consisting of illite, zeolite, bentonite, montmorillonite, caberzite, hydrandite, steel bite, lomontite, Preparing sodium silicate, liquid binder, mineral powder, celite and thickener; The inorganic adhesive for furniture is manufactured by the method comprising the steps of uniformly mixing the components, and by using this to bond the materials such as furniture wood, stone, synthetic resin materials to produce furniture present in sodium silicate, mineral powder, celite Disinlusion of minerals and minerals inside the binder → Formation of aquasols → Condensation → Gel formation → Crystallization Not only can it be manufactured, there is no emission of substances that cause sick house syndrome due to the absence of organic binders, and there is no emission of substances that cause environmental pollution by using only binders that do not cause environmental pollution at disposal. Can be used as an adhesive for furniture in an economical and simple way It relates to furniture made of an inorganic adhesive composition as furniture inorganic adhesive using the same.
일반적으로 가구란 실내에 배치하여 생활에 사용하는 도구의 총칭으로서, 의자나 책상같이 움직일 수 있는 것을 가리키지만, 넓은 뜻으로는 건물에 붙여 만든 옷장이나 벽난로 등도 포함되며, 공간별로 실내용과 실외용, 기능별로 수납, 장식, 휴식용 등으로 분류되고, 그 종류도 매우 다양하다.Generally, furniture is a general term for tools used in daily life by placing them in a room, and they can move like chairs or desks, but in a broad sense, they include a wardrobe or a fireplace made by attaching to a building. It is classified into storage, decoration, and relaxation by function, and there are various kinds.
대부분의 가구는 목재를 주로 사용하고, 합성수지재의 부속품이나 금속재의 골조 등으로 이루어지는 데 목재를 주로 이용하는 가구는 천연의 무늬가 미려감이 있어 많이 사용되지만 내구성이 좋지 못하고 건조됨에 따라 형태 변형이 일어나고 화재에 취약한 단점이 있고, 합성수재를 주로 사용하는 가구는 폐기시 환경오염을 유발하고 화재에 취약하며 인체에 유해한 물질의 유출되는 경향이 있고 표면 질감이 좋지 못한 문제점이 있고, 금속재를 주로 사용하는 가구는 부식 가능성이 높고 무거우며 무늬가 없어 단조로운 느낌을 갖는 단점이 있다.Most furniture is mainly made of wood and made of synthetic resin materials and metal frames. Furniture made of wood is often used because of its beautiful natural patterns. The furniture which mainly uses synthetic wood has the disadvantage of being vulnerable to the problem, which causes environmental pollution at the time of disposal, is vulnerable to fire, has a tendency of spilled substances harmful to the human body, the surface texture is poor, and the furniture mainly uses metal materials. Has the disadvantage of high corrosion potential, heavy and unpatterned monotonous feeling.
따라서, 대부분의 가구들은 표면재로는 목재를 주로 사용하고 합성수지재 부속품이나 금속재를 사용하여 제조되지만 교차되는 면의 접착이나 보강재의 접착에 유기 접착제가 주로 사용되고 있다.Therefore, most furniture is mainly made of wood as a surface material and manufactured using synthetic resin accessories or metal materials, but organic adhesives are mainly used for bonding of intersecting surfaces or reinforcing materials.
그러나, 가구용 판재, 보강재를 접착시키기 위하여 사용되는 유기 접착제는 인체에 유해한 물질들을 많이 배출되는 단점이 있다. 특히, 유기 접착제는 고휘발성의 용매를 사용하게 되므로 새집증후군을 유발하는 주요한 원인으로 지적되고 있다.However, the organic adhesive used to bond the furniture plate, reinforcement has a disadvantage that a lot of substances harmful to the human body is discharged. In particular, organic adhesives are pointed to be a major cause of sick house syndrome because of the use of a highly volatile solvent.
특히, 새집증후군은 집이나 건물을 새로 지을 때 사용하는 건축자재나 벽지 등에서 나오는 유해물질로 인해 거주자들이 느끼는 건강상 문제 및 불쾌감을 이르는 용어로서, 벤젠, 톨루엔, 클로로포름, 아세톤, 스타이렌, 포름알데하이드 등의 발암물질이 포함되어 있고, 라돈, 석면, 일산화탄소, 이산화탄소, 질소산화물, 오존, 미세먼지, 부유세균과 같은 오염물질도 있으며, 사람이 새집증후군에 짧은 기간 노출이 되면 두통, 눈?코?목의 자극, 기침, 가려움증, 현기증, 피로감, 집중력 저하 등의 증상이 생길 수 있고, 오랜 기간 노출이 되면 호흡기질환, 심장병, 암 등의 질병이 나타날 수도 있으며, 새로운 가구도 새집증후군을 유발하는 중요한 요소로 인식되고 있다.In particular, sick house syndrome is a term used to refer to the health problems and discomforts of residents due to harmful substances from building materials and wallpaper used to rebuild houses or buildings. Benzene, toluene, chloroform, acetone, styrene, formaldehyde Carcinogens, and other contaminants such as radon, asbestos, carbon monoxide, carbon dioxide, nitrogen oxides, ozone, fine dust and airborne bacteria. Headaches, eyes and nose? Symptoms such as throat irritation, coughing, itching, dizziness, tiredness, and decreased concentration can cause symptoms such as respiratory disease, heart disease, and cancer. It is recognized as an element.
따라서, 본 발명의 목적은 일정 접착력 이상의 가구를 제조할 수 있을 뿐만 아니라 유기 바인더를 사용하지 않아 새집증후군을 유발하는 물질의 배출이 없고, 무기물로만 이루어진 바인더를 사용함으로써 환경오염을 유발하는 물질의 배출이 없어 폐기시에도 환경 오염을 유발하지 않으며, 경제적이고 간단한 방법으로 가구의 접착제로 사용될 수 있는 가구용 무기 접착제 조성물을 제공하는 데 있다.Therefore, an object of the present invention is to not only produce furniture with a certain adhesive strength, but also to avoid the release of substances causing the sick house syndrome by not using an organic binder, and to discharge the substances causing environmental pollution by using a binder composed only of inorganic substances. The present invention provides an inorganic adhesive composition for furniture which does not cause environmental pollution even when disposed of and which can be used as an adhesive for furniture in an economical and simple manner.
본 발명의 다른 목적은 상기 목적의 조성물을 이용한 가구용 무기접착제를 제공하는 데 있다.Another object of the present invention to provide an inorganic adhesive for furniture using the composition of the above object.
상기 목적들 뿐만 아니라 용이하게 표출될 수 있는 또 다른 목적들을 달성하기 위하여 본 발명에서는 소듐실리케이트 100중량부에 대하여 액상의 결합제 3 ~ 10중량부, 광물질 분말 5 ~ 30중량부, 셀라이트 5 ~ 15중량부 및 증점제 1 ~ 8중량부 첨가되어 구성되어지되, 상기 액상의 결합제는 a) 알칼리금속염화물 및 알칼리토금속염화물로 구성되는 군으로부터 선택된 적어도 1종 이상의 화합물을 친수성(hydrophilic) 효소(enzyme) 표면에 소수성(hydrophobic) 폴리머(polymer)를 결합시켜 제조한 양친매성(amphiphilic) 계면활성효소(surface-active enzyme)와 클러스터화된 물의 혼합물에 투입하여 알칼리금속 또는 알칼리토금속을 용출시킨 용액에, b) 액상의 결합제 제조시 사용되는 클러스터화 된 물 전체 사용량에 대하여 1중량% 미만의 희토류 원소를 함유하는 물과, c) pH조절제를 혼합하여 제조한 것이고, 상기 광물질 분말은 일라이트, 제올라이트, 벤토나이트, 몬모릴로나이트, 캐버자이트, 휼란다이트, 스틸바이트, 로몬타이트로 구성되는 군으로부터 선택되는 적어도 1종 이상이며, 소듐실리케이트, 액상의 결합제, 광물질분말, 셀라이트 및 증점제를 준비하는 단계; 상기 성분들을 균일하게 혼합하는 단계로 구성되는 방법으로 가구용 무기접착제를 제조하고, 이를 사용하여 가구용 목재, 석재, 합성수지재 등의 자재 접착시켜 가구를 제조함으로써 소듐실리케이트, 광물질분말, 셀라이트에 존재하는 무기물 및 바인더 내부의 무기물 용탈(dissolusion) → 아쿠아졸 형성(formation of aquasols) → 응축(condensation) → 겔 형성(gel formation) → 결정화(crystallization)하는 반응으로 강한 결합력이 발휘되기 때문에 일정 접착력 이상의 가구를 제조할 수 있을 뿐만 아니라 유기 바인더를 사용하지 않아 새집증후군을 유발하는 물질의 배출이 없고, 무기물로만 이루어진 바인더를 사용함으로써 환경오염을 유발하는 물질의 배출이 없어 폐기시에도 환경 오염을 유발하지 않으며, 경제적이고 간단한 방법으로 가구의 접착제로 사용될 수 있도록 하였다.In order to achieve not only the above objects but also other objects that can be easily expressed, the present invention provides 3 to 10 parts by weight of a liquid binder, 5 to 30 parts by weight of mineral powder, and 5 to 15 parts by weight of sodium silicate. It is composed by adding 1 to 8 parts by weight and a thickener and the liquid binder is a) hydrophilic (enzyme) surface of at least one compound selected from the group consisting of alkali metal chlorides and alkaline earth metal chlorides In a solution in which an alkali metal or an alkaline earth metal is eluted by adding a mixture of amphiphilic surface-active enzyme and clustered water prepared by combining a hydrophobic polymer to Water containing less than 1% by weight of rare earth elements relative to the total amount of clustered water used to prepare the liquid binder, c) a pH bath It is prepared by mixing the agent, the mineral powder is at least one selected from the group consisting of illite, zeolite, bentonite, montmorillonite, caberzite, hydrandite, steel bite, lomonite, sodium silicate, Preparing a liquid binder, mineral powder, celite and thickener; The inorganic adhesive for furniture is manufactured by the method comprising the steps of uniformly mixing the components, and by using this to bond the materials such as furniture wood, stone, synthetic resin materials to produce furniture present in sodium silicate, mineral powder, celite Disinlusion of minerals and minerals inside the binder → Formation of aquasols → Condensation → Gel formation → Crystallization Not only can it be manufactured, there is no emission of substances that cause sick house syndrome due to the absence of organic binders, and there is no emission of substances that cause environmental pollution by using only binders that do not cause environmental pollution at disposal. Can be used as an adhesive for furniture in an economical and simple way It was registered.
본 발명에 따른 가구용 무기 접착제 조성물은 강한 결합력이 발휘되기 때문에 일정 접착력 이상의 가구를 제조할 수 있을 뿐만 아니라 유기 바인더를 사용하지 않아 새집증후군을 유발하는 물질의 배출이 없고, 무기물로만 이루어진 바인더를 사용함으로써 환경오염을 유발하는 물질의 배출이 없어 폐기시에도 환경 오염을 유발하지 않으며, 경제적이고 간단한 방법으로 가구의 접착제로 사용될 수 있다.Since the inorganic adhesive composition for furniture according to the present invention exhibits a strong bonding force, it is possible not only to manufacture furniture having a certain adhesive strength, but also by using an organic binder, and without the release of a substance causing the sick house syndrome, by using a binder composed only of inorganic materials. Since there is no emission of substances that cause environmental pollution, it does not cause environmental pollution even when disposed of, and can be used as an adhesive for furniture in an economical and simple manner.
본 발명에 따른 가구용 무기 접착제 조성물은 소듐실리케이트 100중량부에 대하여 액상의 결합제 3 ~ 10중량부, 광물질 분말 5 ~ 30중량부, 셀라이트 5 ~ 15중량부 및 증점제 1 ~ 8중량부 첨가되어 구성되어지되, 상기 액상의 결합제는 a) 알칼리금속염화물 및 알칼리토금속염화물로 구성되는 군으로부터 선택된 적어도 1종 이상의 화합물을 친수성(hydrophilic) 효소(enzyme) 표면에 소수성(hydrophobic) 폴리머(polymer)를 결합시켜 제조한 양친매성(amphiphilic) 계면활성효소(surface-active enzyme)와 클러스터화된 물의 혼합물에 투입하여 알칼리금속 또는 알칼리토금속을 용출시킨 용액에, b) 액상의 결합제 제조시 사용되는 클러스터화 된 물 전체 사용량에 대하여 1중량% 미만의 희토류 원소를 함유하는 물과, c) pH조절제를 혼합하여 제조한 것이고, 상기 광물질 분말은 일라이트, 제올라이트, 벤토나이트, 몬모릴로나이트, 캐버자이트, 휼란다이트, 스틸바이트, 로몬타이트로 구성되는 군으로부터 선택되는 적어도 1종 이상인 것으로 특징지워진다.The inorganic adhesive composition for furniture according to the present invention is composed of 3 to 10 parts by weight of a liquid binder, 5 to 30 parts by weight of mineral powder, 5 to 15 parts by weight of celite, and 1 to 8 parts by weight of thickener based on 100 parts by weight of sodium silicate. Wherein the liquid binder is a) at least one compound selected from the group consisting of alkali metal chlorides and alkaline earth metal chlorides by combining a hydrophobic (hydrophobic) polymer on the surface of the hydrophilic enzyme (enzyme) Into a mixture of amphiphilic surface-active enzyme prepared and the clustered water to elute the alkali metal or alkaline earth metal, b) the entire clustered water used to prepare a liquid binder It is prepared by mixing water containing less than 1% by weight of rare earth elements with respect to the amount used, and c) a pH adjusting agent, wherein the mineral powder is Sites, characterized by at least one kind selected from zeolite, bentonite, montmorillonite, chabazite, hyul randayi bit, byte steel, the group consisting of romon tight.
또한, 본 발명에 따른 가구용 무기 접착제는 소듐실리케이트 100중량부에 대하여 액상의 결합제 3 ~ 10중량부, 광물질 분말 5 ~ 30중량부, 셀라이트 5 ~ 15중량부 및 증점제 1 ~ 8중량부 첨가되어 구성되어지되, 상기 액상의 결합제는 a) 알칼리금속염화물 및 알칼리토금속염화물로 구성되는 군으로부터 선택된 적어도 1종 이상의 화합물을 친수성(hydrophilic) 효소(enzyme) 표면에 소수성(hydrophobic) 폴리머(polymer)를 결합시켜 제조한 양친매성(amphiphilic) 계면활성효소(surface-active enzyme)와 클러스터화된 물의 혼합물에 투입하여 알칼리금속 또는 알칼리토금속을 용출시킨 용액에, b) 액상의 결합제 제조시 사용되는 클러스터화 된 물 전체 사용량에 대하여 1중량% 미만의 희토류 원소를 함유하는 물과, c) pH조절제를 혼합하여 제조한 것이고, 상기 광물질 분말은 일라이트, 제올라이트, 벤토나이트, 몬모릴로나이트, 캐버자이트, 휼란다이트, 스틸바이트, 로몬타이트로 구성되는 군으로부터 선택되는 적어도 1종 이상이며, 상기 성분들을 균일하게 혼합한 것으로 특징지워진다.In addition, the inorganic adhesive for furniture according to the present invention is added to 3 to 10 parts by weight of a liquid binder, 5 to 30 parts by weight of mineral powder, 5 to 15 parts by weight of celite and 1 to 8 parts by weight of thickener based on 100 parts by weight of sodium silicate. The liquid binder may include a) binding a hydrophobic polymer to at least one compound selected from the group consisting of alkali metal chlorides and alkaline earth metal chlorides on a hydrophilic enzyme surface. In a solution of eluted alkali metal or alkaline earth metal by adding a mixture of amphiphilic surface-active enzyme and clustered water, which is prepared by It is prepared by mixing water containing less than 1% by weight of rare earth elements with respect to the total amount used, and c) a pH adjusting agent, the mineral powder is At least one selected from the group consisting of yite, zeolite, bentonite, montmorillonite, caberzite, hullandite, steel bite, and lomontite, and is characterized by uniformly mixing the above components.
일반적으로 소듐실리케이트는 규산의 나트륨염이며, 수용액이나 고체 상태로 이용 가능하고, 규산소다라고도 한다. 조성에 따라 메타규산나트륨(Na2SiO3), 그 수화물인 오쏘규산나트륨(Na4SiO4), 이규산나트륨(Na2Si2O5) 등 여러 가지가 있으나, 보통은 메타규산나트륨을 말한다. 수화물도 있으나, 무수물은 석영과 탄산나트륨의 혼합물을 1,000℃로 가열 융해하여 고체화시켜서 만든다. 메타규산나트륨은 물에 잘 녹으며, 수용액은 가수분해하여 알칼리성이 된다. In general, sodium silicate is the sodium salt of silicic acid, can be used in an aqueous solution or in a solid state, and is also called sodium silicate. Depending on the composition, sodium metasilicate (Na 2 SiO 3 ), its hydrate sodium sodium silicate (Na 4 SiO 4 ), sodium disilicate (Na 2 Si 2 O 5 ), etc. There are various kinds, but usually refers to sodium metasilicate . Hydrates are also available, but anhydrides are made by melting and melting a mixture of quartz and sodium carbonate to 1,000 ° C. Sodium metasilicate is well soluble in water, and the aqueous solution is hydrolyzed to become alkaline.
2Na2SiO3 + H2O → Na2Si2O5 + 2NaOH2Na 2 SiO 3 + H 2 O → Na 2 Si 2 O 5 + 2 NaOH
소듐실리케이트는 SiO2/Na2O의 몰비와 농도에 따라 다양한 성질을 나타내며, 소듐실리케이트의 몰비는 SiO2/Na2O의 중량비 × 1.032의 식으로 계산된다.Sodium silicate exhibits various properties depending on the molar ratio and concentration of SiO 2 / Na 2 O, and the molar ratio of sodium silicate is calculated by the formula of the weight ratio of SiO 2 / Na 2 O × 1.032.
본 발명에 있어서, 소듐실리케이트는 접착제의 주요 성분으로 사용되는 것으로 20℃에서의 비중이 1.590 이상이고, 20℃에서의 Be` 52 ~ 54, 산화나트륨(Na2O) 14 ~ 15%, 이산화규소(SiO2) 34 ~ 36%, 산화철(Fe2O3) 0.05% 이하, 물불용분 0.2% 이하인 것을 사용하는 것이 효과적이다.In the present invention, sodium silicate is used as the main component of the adhesive, the specific gravity at 20 ℃ is 1.590 or more, Be` 52 to 54 at 20 ℃, sodium oxide (Na 2 O) 14 to 15%, silicon dioxide It is effective to use (SiO 2 ) 34 to 36%, iron oxide (Fe 2 O 3 ) 0.05% or less, and water insoluble content 0.2% or less.
그러나, 소듐실리케이트만을 사용할 경우에는 접착력이 가구용으로 사용하기에는 미흡한 단점이 있다.However, when only sodium silicate is used, there is a disadvantage that the adhesive strength is insufficient for use for furniture.
따라서, 본 발명에서는 소듐실리케이트 100중량부에 대하여 액상의 결합제 3 ~ 10중량부, 광물질 분말 5 ~ 30중량부 및 셀라이트 5 ~ 15중량부를 혼합하여 접착력을 향상시켰으며, 상기 액상의 결합제는 a) 알칼리금속염화물 및 알칼리토금속염화물로 구성되는 군으로부터 선택된 적어도 1종 이상의 화합물을 친수성(hydrophilic) 효소(enzyme) 표면에 소수성(hydrophobic) 폴리머(polymer)를 결합시켜 제조한 양친매성(amphiphilic) 계면활성효소(surface-active enzyme)와 클러스터화된 물의 혼합물에 투입하여 알칼리금속 또는 알칼리토금속을 용출시킨 용액에, b) 액상의 결합제 제조시 사용되는 클러스터화 된 물 전체 사용량에 대하여 1중량% 미만의 희토류 원소를 함유하는 물과, c) pH조절제를 혼합하여 제조하였고, 상기 광물질 분말은 일라이트, 제올라이트, 벤토나이트, 몬모릴로나이트, 캐버자이트, 휼란다이트, 스틸바이트, 로몬타이트로 구성되는 군으로부터 선택되는 적어도 1종 이상이다.Therefore, in the present invention, the adhesive strength was improved by mixing 3 to 10 parts by weight of the liquid binder, 5 to 30 parts by weight of the mineral powder, and 5 to 15 parts by weight of celite, based on 100 parts by weight of the sodium silicate. Amphiphilic surfactant prepared by combining at least one compound selected from the group consisting of alkali metal chlorides and alkaline earth metal chlorides with a hydrophobic polymer on the surface of a hydrophilic enzyme. Rare earth of less than 1% by weight, based on the total amount of clustered water used in the preparation of liquid binders, in a solution eluted with alkali metals or alkaline earth metals in a mixture of surface-active enzyme and clustered water. C) a pH adjusting agent was prepared by mixing water containing the element, and the mineral powder was elite, zeolite, bentonite, Parent reels is at least one or more nitro, chabazite, hyul randayi agent, selected from the steel bytes, the group consisting of romon tight.
바인더에서 사용되는 알칼리금속염화물 및 알칼리토금속염화물로는 Li ,Na, K, Rb, Cs, Si, Al, Fe, Ca, Na, K, Mg의 염화물을 의미하는 것으로 1종 이상이 사용되어야 하고, 알칼리금속염화물 및 알칼리토금속염화물은 계면활성효소(surface-active enzyme)와 클러스터화된 물에 의해서 미네랄 입자가 콜로이드 용액을 형성하고, 형성된 콜로이드 용액은 소듐실리케이트의 미네랄과 결합하여 접착력 향상 기능을 나타내게 된다.Alkali metal chlorides and alkaline earth metal chlorides used in the binder means chlorides of Li, Na, K, Rb, Cs, Si, Al, Fe, Ca, Na, K, and Mg. Alkali metal chlorides and alkaline earth metal chlorides form a colloidal solution of mineral particles by the surface-active enzyme and the clustered water, and the colloidal solution formed is combined with the minerals of sodium silicate to show an adhesion enhancement function. .
또한, 계면활성효소(surface-active enzyme)는 친수성(hydrophilic)인 효소(enzyme) 표면에 소수성(hydrophobic)인 폴리머(polymer)를 결합시켜서 양친매성(amphiphilic)이 나타내도록 한 것으로 알칼리금속염화물 및 알칼리토금속염화물의 활성화를 보조하는 역할을 하는 것으로, 클러스터화된 물의 중량에 대하여 0.1 ~ 3중량%의 양을 사용하는 것이 효과적이며, 계면활성 효소의 사용량이 클러스터화된 물의 중량에 대하여 0.1중량% 미만일 경우에는 알칼리금속염화물 및 알칼리토금속염화물의 활성화가 미약한 단점이 있고, 3중량%를 초과할 경우에는 경제적이지 못한 문제점이 있다.In addition, the surface-active enzyme binds a hydrophobic polymer to the surface of an hydrophilic enzyme to show amphiphilic properties. Alkali metal chloride and alkali It is effective to support the activation of the earth metal chloride, it is effective to use the amount of 0.1 to 3% by weight based on the weight of the clustered water, the amount of the surfactant is less than 0.1% by weight relative to the weight of the clustered water In the case of the alkali metal chloride and alkaline earth metal chloride activation is weak disadvantage, when it exceeds 3% by weight is not economical problem.
보통 물은 35개 내외의 물분자가 연결되어 대단히 큰 클러스터를 이루고 있으며, 아황산가스, 탄산가스, 일산화탄소, 염소 가스등이 물에 녹아 들어가면 이것들이 물분자의 클러스터 사이에 붙어 엉키게 될 뿐만 아니라 이들 가스류가 물에 용해되어 황산, 아황산, 탄산, 염산등으로 되면서 물을 산성화시키고, 수은, 납, 카드뮴, 알루미늄을 비롯한 유독중금속류도 클러스터에 엉키게 된다. 이렇게 물을 산성화시키는 가스류나 유독금속을 포함하고 있는 클러스터가 큰 물은 인체에 유해한 효과를 나타낼 뿐만 아니라 본 발명에서는 결합력의 저하 원인이 되어 본 발명에서 얻고자 하는 효과가 발현되지 않게 된다. Normally, water is composed of about 35 water molecules, forming a very large cluster. When sulfur dioxide, carbon dioxide, carbon monoxide, and chlorine gas are dissolved in water, they are not only entangled between clusters of water molecules but also entangled. As it is dissolved in water, sulfuric acid, sulfurous acid, carbonic acid, and hydrochloric acid are acidified, and toxic heavy metals such as mercury, lead, cadmium, and aluminum are entangled in clusters. Such a large water cluster containing gas streams or toxic metals to acidify the water not only has a harmful effect on the human body, but also causes a decrease in the binding force in the present invention, thereby preventing the effect to be obtained in the present invention.
따라서, 본 발명에서는 4 ~ 14㎛대의 원적외선방사, 자화처리, 초음파처리 등을 통하여 물분자의 클러스터를 5 ~ 6개의 분자로 세분화하여 물분자의 클러스터 사이에 엉키어있던 유독가스를 공중으로 날려보내고 중금속류는 침전시켜 상등액만을 취한 클러스터화된 물을 사용한다.Therefore, in the present invention, the cluster of water molecules is subdivided into 5-6 molecules through far-infrared radiation, magnetization, and ultrasonic treatment in the range of 4 to 14 μm to blow toxic gases entangled between the clusters of water molecules into the air. Heavy metals are precipitated using clustered water with supernatant only.
클러스터화된 물은 공지된 다양한 방법으로 제조 가능하고, 공지된 안정화 방법으로 안정화시킨 것을 사용하는 것이 바람직하며, 클러스터화되지 않은 물을 본 발명에서 사용할 경우에는 바인더의 결합력이 저하되는 문제점이 있다.The clustered water can be prepared by a variety of known methods, it is preferable to use a stabilized by a known stabilization method, there is a problem that the binding force of the binder is lowered when using the non-clustered water in the present invention.
계면활성효소와 클러스터화된 물의 혼합물에 알칼리금속염화물 및 알칼리토금속염화물로 구성되는 군으로부터 선택된 적어도 1종 이상의 화합물을 투입하여 용해한다. 이 때 알칼리금속염화물 및 알칼리토금속염화물로 구성되는 군으로부터 선택된 적어도 1종 이상의 화합물의 사용량은 클러스터화된 물의 중량에 대하여 1 ~ 60중량%의 양을 사용하는 것이 효과적이며, 알칼리금속염화물 및 알칼리토금속염화물로 구성되는 군으로부터 선택된 적어도 1종 이상의 화합물이 1중량% 미만으로 사용될 경우에는 소듐실리케이트로부터 유래되는 미네랄 성분과의 결합력이 저하되는 단점이 있고, 60중량%를 초과할 경우에는 첨가 상승 효과가 미약하다.At least one compound selected from the group consisting of alkali metal chlorides and alkaline earth metal chlorides is added to and dissolved in a mixture of surfactant and clustered water. At this time, the amount of the at least one compound selected from the group consisting of alkali metal chlorides and alkaline earth metal chlorides is effective to use the amount of 1 to 60% by weight based on the weight of the clustered water, alkali metal chloride and alkaline earth metal When at least one compound selected from the group consisting of chlorides is used in less than 1% by weight, there is a disadvantage in that the binding strength with mineral components derived from sodium silicate is lowered. Weak
계면활성효소와 클러스터화된 물의 혼합물에 알칼리금속 및/또는 알칼리토금속염화물을 용해시킨 용액에 희토류 원소를 소량 함유하는 물과 pH조절제를 혼합한 액상의 결합제를 제조한다.A liquid binder is prepared in which water containing a small amount of rare earth elements and a pH adjusting agent are mixed in a solution in which an alkali metal and / or alkaline earth metal chloride is dissolved in a mixture of surfactant and clustered water.
희토류 원소로는 란탄늄, 세륨, 프라세오디뮴, 네오디뮴, 프로메튬, 사마륨, 유로피움, 가돌리늄, 테르비움, 디스프로슘, 홀미움, 에르비움, 투리움, 이트븀, 루테늄, 스칸듐, 이트륨 등이 사용 가능하며, 게르마늄도 사용 가능하다. 희토류 원소를 소량 함유하는 물은 알칼리금속 및/또는 알칼리토금속염화물의 보조제로서의 기능을 수행함과 동시에 살균 및 정균 작용에 의하여 미네랄과 콜로이드 용액의 결합이 용이하게 이루어지도록 하는 기능을 한다. 희토류 원소의 함유량은 전체 클러스터화된 물의 중량에 대하여 1중량% 미만으로 사용하는 것이 효과적이며, 희토류 원소를 함유하는 물에서도 물은 클러스터화된 물을 사용한다.Rare earth elements include lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, turlium, yttbium, ruthenium, scandium, yttrium, etc. Also available. Water containing a small amount of rare earth elements functions as an adjuvant of alkali metals and / or alkaline earth metal chlorides, and at the same time, functions to easily combine minerals and colloidal solutions by sterilization and bacteriostatic action. The content of the rare earth element is effective to use less than 1% by weight based on the total weight of the clustered water, and even in the water containing the rare earth element, water is used as the clustered water.
한편, 제조되는 액상의 결합제에 pH 조절제를 사용하여 제조되는 제품의 pH 가 약알칼리성이 되도록 하며, pH 조절제의 사용량은 요구되는 pH에 따라 적절히 조절될 수 있다.On the other hand, by using a pH adjuster in the liquid binder to be prepared to make the pH of the product to be weakly alkaline, the amount of the pH adjuster can be appropriately adjusted according to the required pH.
상기와 같이 제조되는 액상의 결합제는 사용되는 소듐실리케이트 100중량부에 대하여 3 ~ 10중량부를 사용하는 것이 바람직하며, 액상의 결합제가 3중량부 미만일 경우에는 제조되는 접착제의 접착력 향상이 미약할 뿐만 아니라 점도가 너무 높아지는 단점이 있으며, 액상의 결합제가 10중량부를 초과할 경우에는 초과 첨가에 대한 접착력 향상 정도가 미약하여 경제적이지 못하고, 점도가 낮아져 취급이 용이하지 못한 문제점이 있다.It is preferable to use 3 to 10 parts by weight based on 100 parts by weight of the sodium silicate used as the liquid binder prepared as described above, and when the liquid binder is less than 3 parts by weight, the adhesive improvement of the prepared adhesive is not only weak. There is a disadvantage in that the viscosity is too high, when the liquid binder exceeds 10 parts by weight, the degree of adhesion improvement for the excess addition is weak and not economical, the viscosity is low, there is a problem that the handling is not easy.
상기 광물질 분말은 일라이트, 제올라이트, 벤토나이트, 몬모릴로나이트, 캐버자이트, 휼란다이트, 스틸바이트, 로몬타이트로 구성되는 군으로부터 선택되는 적어도 1종 이상의 분말이 사용될 수 있다.The mineral powder may be at least one powder selected from the group consisting of elite, zeolite, bentonite, montmorillonite, caberzite, hydrandite, steel bite, and lomontite.
상기 광물질 분말은 200 ~ 325메쉬(mesh)의 입도를 갖는 것을 사용하는 것이 효과적이며, 입도가 200메쉬 미만일 경우에는 제조되는 접착제의 접착력이 만족스럽지 못한 문제점이 있고, 325메쉬를 초과할 경우에는 제조 원가가 상승되어 경제적이지 못하다.The mineral powder is effective to use those having a particle size of 200 ~ 325 mesh (mesh), when the particle size is less than 200 mesh, there is a problem that the adhesive strength of the adhesive produced is not satisfactory, if the excess exceeds 325 mesh It is not economic because of rising costs.
일라이트는 단사정계에 속하는 운모족 광물로서, 굳기 1 ~ 2, 비중 2.6 ~ 2.9, 조흔색은 백색이고, 화학조성은 (K,H3O)Al2(Si,Al)4O10(H2O,OH)2이다. 화학성분으로 보아, 백운모에 가까운 것도 있으나 비교적 SiO2, MgO, H2O가 많고, K2O는 적으며, 알루미늄이 풍부한 이질(泥質) 또는 응회암질(凝灰岩質) 퇴적암 중에 산출되 며, 열수성(熱水性) 광상모암의 변질광물로서 산출된다.The illite is a monoclinic mineral belonging to the monoclinic system, having a hardness of 1 to 2, specific gravity of 2.6 to 2.9, streaked color of white, and chemical composition of (K, H 3 O) Al 2 (Si, Al) 4 O 10 (H 2 O, OH) 2 . In terms of chemical composition, some are close to dolomite, but relatively high in SiO 2 , MgO, H 2 O, and low in K 2 O, and are produced in aluminium-rich heterogeneous or tuff sedimentary rocks. Calculated as a denatured mineral of hydrothermal gneiss.
제올라이트는 알칼리 및 알칼리토금속의 규산알루미늄 수화물인 광물을 총칭으로서 색깔은 무색 투명하거나 백색 반투명하고, 비석이라고도 하며, 종류는 많으나 함수량이 많은 점, 결정의 성질, 산상 등에 공통성이 있다. 굳기는 6을 넘지 않으며, 비중은 약 2.2이고, 주요한 종류로서 방비석, 어안석, 캐버자이트, 소다비석, 휼란다이트, 스틸바이트, 로몬타이트, 이네사이트 등이 있고, 현무암이나 휘록응회암 등 염기성 화성암의 공동(空洞) 속이나 열극에서 산출되며, 때로는 화강암, 편마암 중에 2차 광물로서 존재한다.Zeolite is a generic term for minerals that are aluminum silicate hydrates of alkali and alkaline earth metals. Colors are colorless, transparent or white translucent, and are also called zeolites. Hardness does not exceed 6, specific gravity is about 2.2, and the main types are boulderstone, fisheye stone, caberite, soda-stone, hydrandite, steel bite, lomontite, and insite, and basic igneous rocks such as basalt and whirlwind. Produced in the cavity of or in the thermosphere, sometimes as a secondary mineral in granite and gneiss.
또한, 금광맥 그 밖의 광맥 중에 산출되는 경우도 있고, 결정구조적으로 각 원자의 결합이 느슨하여, 그 사이를 채우고 있는 수분을 고열로 방출시켜도 골격은 그대로 있으므로 다른 미립물질을 흡착할 수가 있는 성질을 이용해서 흡착제로 사용하며, 크기가 다른 미립물질을 분리시키는 분자체로도 사용된다.In addition, it is sometimes produced in gold or other veins, and the structure of each atom is loose in crystal structure, and even though the moisture filling the space is released at high heat, the skeleton remains the same so that other fine substances can be adsorbed. It is used as an adsorbent and is also used as a molecular sieve to separate particulates of different sizes.
벤토나이트는 운모와 같은 결정구조를 하는 단사정계에 속하는 광물인 몬모릴로나이트가 주로 들어있는 점토로서, 빛깔은 백색, 회색, 담갈색, 담녹색등을 나타내며, 주물형의 결합제, 요업원료의 혼입제, 연고의 기초제 등 다양한 분야에 사용되고, 석영, 장석(長石), 제올라이트 등을 포함한 것이 많으며, 물을 흡착하여 팽윤하고, 양이온 교환성이 뚜렷한 것 등 몬모릴로나이트의 성질과 흡사하다.Bentonite is a clay mainly containing montmorillonite, a mineral belonging to the monoclinic system having a crystalline structure like mica, and its color is white, gray, light brown, light green, etc., and it is found in casting type binder, ceramic raw material mixing agent and ointment base. It is used in a variety of fields, including quartz, feldspar, zeolite, and the like, and is similar to the properties of montmorillonite such as swelling by adsorbing water and having excellent cation exchangeability.
몬모릴로나이트는 단사정계의 광물로 점토광물의 일종으로, 굳기 1 ~ 1.5, 비중 2 ~ 1.5, 백색, 회색, 담홍색, 청색, 녹색을 띄며, 수분을 흡수하여 7 ~ 10배 부피가 증가하는 성질이 있으며, 이온 교환성이 높고, 150% ~ 500%의 함수량에서 잠착력이 있고, 내부마찰저항이 작은 특징을 가지며, 알로미늄이 풍부한 광물이나 암석의 변질로 생성되고, 화학성분은 (Al, Mg)2Si4O10(OH)2?4H2O이다.Montmorillonite is a monoclinic mineral that is a kind of clay mineral. It has hardness 1 ~ 1.5, specific gravity 2 ~ 1.5, white, gray, pink, blue, green, and absorbs moisture to increase the volume 7 to 10 times. It has high ion exchangeability, has a tackiness at water content of 150% to 500%, has a small internal friction resistance, and is produced by alteration of mineral-rich minerals or rocks.The chemical composition is (Al, Mg ) 2 Si 4 O 10 (OH) 2 -4H 2 O.
캐버자이트는 사방비석, 능비석이라고도 하고, 굳기는 3 ~ 5, 비중은 2.08 ~ 2.16이며, 무색 투명이나 백색을 띠고, 염기를 교환하는 성질이 뚜렷하며 결정구조는 변하지 않고, 화학성분이 다양하게 변화하는데, 대체적으로 mCa7Si26 Al14O88?40H2O+n(Na,K)4Ca3Si30Al10O80?4H2O로 표시된다. 정육면체에 가까운 것이 많고, 능면체의 면에 쪼개짐이 있으며, 결정구조는 변화하지 않고, 나트륨과 칼슘의 교환, 물의 함유량의 변화 등을 볼 수 있다. Caberzite is also known as tombstone and tombstone, has hardness of 3 to 5, specific gravity of 2.08 to 2.16, colorless and transparent, white, clear base exchange properties, no change in crystal structure, and various chemical composition. to, and is generally represented by a mCa 7 Si 26 Al 14 O 88 ? 40H 2 O + n (Na, K) 4 Ca 3 Si 3 0Al 10 O 80? 4H 2 O. Many are close to a cube, and there are cracks on the surface of the rhombohedron. The crystal structure does not change, and the exchange of sodium and calcium and the change of water content can be seen.
휼란다이트는 운모와 같은 결정구조를 가지는 단사정계에 속하는 광물로 색깔은 무색 또는 백색을 띠며 때로 적갈색을 띠고, 주로 화산암 또는 퇴적암 속에 맥상으로 산출되며, 휘비석이라고도 한다. 화학성분은 CaAl2Si7O18?6H2O이고, 판상결정을 이루며 크게 발달되어 있는 면에는 완전한 쪼개짐이 있고, 쪼개짐면은 진주광택이 강하며, 무색 또는 백색으로 투명 또는 반투명하고, 때로 적갈색 ?적색 등을 띤다. 굳기 3.5 ~ 4, 비중 2.2이다. 염산에는 운무상의 유리규산을 내며 녹고, 주로 화산암, 때로는 퇴적암 속에 맥상으로 산출된다. Hullandite is a mineral belonging to the monoclinic system with mica-like crystal structure. It is colorless or white in color and sometimes reddish brown. It is mainly produced as a vein in volcanic or sedimentary rocks and is also called a pitolite. The chemical composition is CaAl 2 Si 7 O 18 6 6H 2 O, and the plate-shaped crystals have large cracks, and the cracks have a strong split, and the cracks are pearlescent, transparent or translucent to colorless or white, and sometimes reddish brown. ? Red, etc. Hardness 3.5-4, specific gravity 2.2. Hydrochloric acid melts with cloud-free silicic acid and produces veins in mainly volcanic and sometimes sedimentary rocks.
스틸바이트는 운모와 같은 결정체인 단사정계에 속하는 광물로 속비석이라고도 하고, 색깔은 무색, 백색, 황색, 갈색, 적색이며 투명 또는 반투명을 띤다. 유리광택이 나며 벽개면이나 열개면은 진주광택이 난다. 금속 광상, 화강암, 편마암 등과 함께 산출되고, 화학성분은CaAl2Si7O18?7H2O으로 굳기 3.5 ~ 4.0, 비중 2.1 ~ 2.2이며, 염산에서 유리규산을 방출하면서 녹아 아교화한다.The steel bite is a mineral belonging to the monoclinic system, which is a mica-like crystal, and it is also called a rapid stone. The color is colorless, white, yellow, brown, red and transparent or translucent. The glass is glossy and the cleaved or ten sides are pearlescent. It is produced together with metal deposits, granite, gneiss, etc., and its chemical composition is CaAl 2 Si 7 O 18 ˜7H 2 O, which has a hardness of 3.5 to 4.0 and a specific gravity of 2.1 to 2.2.
로몬타이트는 탁비석이라고도 하고, 화학성분은 CaAl2Si4O12?4H2O이며, 긴기둥 모양의 결정을 이루고 끝은 죽창 모양으로 비스듬히 뾰족하다. 신선한 것은 무색 투명하지만, 건조한 대기 중에서는 쉽게 수분을 잃고 붕괴하여 백색 분말이 되며, 굳기 3 ~ 3.5, 비중 2.25 ~ 2.35이고, 무른 성질을 갖는다.Lomontite is also known as turbidite, and its chemical composition is CaAl 2 Si 4 O 12 â € “4H 2 O. It has long columnar crystals and its tip is obliquely pointed obliquely. Fresh is colorless and transparent, but in a dry atmosphere it easily loses moisture and decays to form a white powder. It has a hardness of 3 to 3.5 and a specific gravity of 2.25 to 2.35.
본 발명에서 광물질 분말은 접착력 향상을 위하여 사용되는 것으로, 사용되는 소듐실리케이트 100중량부에 대하여 5 ~ 30중량부가 사용되는 것이 효과적이며, 광물질 분말의 사용량이 5중량부 미만일 경우에는 제조되는 접착제의 접착력 향상 효과가 미약한 단점이 있고, 30중량부를 초과할 경우에는 점도가 낮아 취급이 용이하지 못하여 바람직하지 않다.In the present invention, the mineral powder is used to improve the adhesion, it is effective to use 5 to 30 parts by weight based on 100 parts by weight of the sodium silicate, and when the amount of the mineral powder used is less than 5 parts by weight, the adhesive strength of the adhesive prepared There is a disadvantage in that the improvement effect is weak, and when it exceeds 30 parts by weight, the viscosity is low, so handling is not easy, which is not preferable.
본 발명에서 셀라이트는 상기 광물질 분말의 보조 기능을 행하는 것으로 플루오르 이온을 유리시켜 제조되는 접착제의 접착력 향상은 물론 방부, 방식 효과를 향상시키기 위하여 사용되는 것으로, 화학식은 MgF2이고, 분자량 62.3인 정방정계의 광물로서 밀도가 3.14이고, 경도가 5이며, 절주상 프리즈마틱~침상의 결정, 섬유상집합체 성상을 나타낸다.In the present invention, the celite is used to improve the adhesive strength of the adhesive prepared by releasing fluorine ions as an auxiliary function of the mineral powder, as well as antiseptic and anticorrosive effect, and the chemical formula is MgF 2 and has a molecular weight of 62.3. As a mineral in the form of a mineral, the density is 3.14, the hardness is 5, and it exhibits columnar prismatic to needle-like crystals and fibrous aggregate properties.
상기 셀라이트는 소듐실리케이트 100중량부에 대하여 5 ~ 15중량부가 사용되는 것이 효과적이며, 셀라이트의 사용량이 5중량부 미만일 경우에는 첨가 효과가 미약한 단점이 있고, 15중량부를 초과할 경우에는 초과 첨가에 따른 효과 상승 정도가 미약하여 경제적이지 못하다.The celite is effective to use 5 to 15 parts by weight based on 100 parts by weight of sodium silicate, the addition effect is weak when the amount of celite is less than 5 parts by weight, the excess exceeds 15 parts by weight The degree of effect increase due to the addition is not economical.
상기와 같은 구성의 접착제 조성물은 점도가 낮아 증점제를 소듐실리케이트 100중량부에 대하여 1 ~ 8중량부를 첨가하여 접착제로서 적당한 점도가 되도록 한다. 증점제로는 본 발명이 속하는 기술 분야에서 통상적으로 사용되는 것을 모두 사용할 수 있지만 본 발명에서는 카르복시메텔셀룰로오스를 사용하였다.The adhesive composition of the above-mentioned structure is low in viscosity, and 1-8 weight part of thickeners are added with respect to 100 weight part of sodium silicates, and it becomes a suitable viscosity as an adhesive agent. As the thickener, any one commonly used in the art to which the present invention pertains may be used, but in the present invention, carboxymethyl cellulose was used.
본 발명에 따른 가구용 무기 접착제는 소듐실리케이트 100중량부에 대하여 액상의 결합제 3 ~ 10중량부, 광물질 분말 5 ~ 30중량부, 셀라이트 5 ~ 15중량부 및 증점제 1 ~ 8중량부 첨가되어 구성되어지되, 상기 액상의 결합제는 a) 알칼리금속염화물 및 알칼리토금속염화물로 구성되는 군으로부터 선택된 적어도 1종 이상의 화합물을 친수성(hydrophilic) 효소(enzyme) 표면에 소수성(hydrophobic) 폴리머(polymer)를 결합시켜 제조한 양친매성(amphiphilic) 계면활성효소(surface-active enzyme)와 클러스터화된 물의 혼합물에 투입하여 알칼리금속 또는 알칼리토금속을 용출시킨 용액에, b) 액상의 결합제 제조시 사용되는 클러스터화 된 물 전체 사용량에 대하여 1중량% 미만의 희토류 원소를 함유하는 물과, c) pH조절제를 혼합하여 제조한 것이고, 상기 광물질 분말은 일라이트, 제올라이트, 벤토나이트, 몬모릴로나이트, 캐버자이트, 휼란다이트, 스틸바이트, 로몬타이트로 구성되는 군으로부터 선택되는 적어도 1종 이상이며, 상기 성분들을 균일하게 혼합하여 제조한다.The inorganic adhesive for furniture according to the present invention is composed of 3 to 10 parts by weight of a liquid binder, 5 to 30 parts by weight of mineral powder, 5 to 15 parts by weight of celite, and 1 to 8 parts by weight of a thickener based on 100 parts by weight of sodium silicate. The binder of the liquid phase is prepared by a) combining at least one compound selected from the group consisting of alkali metal chlorides and alkaline earth metal chlorides with a hydrophobic polymer on the surface of a hydrophilic enzyme. In a solution in which an alkali or alkaline earth metal is eluted by adding a mixture of amphiphilic surface-active enzyme and clustered water, b) the total amount of clustered water used to prepare the liquid binder. It is prepared by mixing water containing less than 1% by weight of rare earth elements with a pH adjuster, the mineral powder is illite, It is at least one selected from the group consisting of zeolite, bentonite, montmorillonite, caberzite, hydrandite, stilbite, and lomontite, and is prepared by uniformly mixing the above components.
본 발명의 무기 접착제 제조 방법에 있어서 소듐실리케이트, 액상의 결합제, 광물질분말, 셀라이트와 증점제의 혼합은 건식, 반건식, 습식으로 상기 설명한 조성 비율에 따라서 배합할 수 있으며, 소듐실리케이트 및 광물질분말, 셀라이트의 함수율에 따라 조성 비율을 조절할 수 있다. In the inorganic adhesive production method of the present invention, the sodium silicate, the liquid binder, the mineral powder, the celite and the thickener may be mixed according to the above-described composition ratios of dry, semi-dry, and wet, sodium silicate, mineral powder, and cell. The composition ratio can be adjusted according to the moisture content of the light.
상기 소듐실리케이트, 액상의 결합제, 광물질분말, 셀라이트와 증점제의 혼합은 특별히 한정되지 않고, 본 발명이 속하는 기술 분야에서 통상적으로 사용되는 방법을 선택하여 적용할 수 있다. Mixing of the sodium silicate, the liquid binder, the mineral powder, the celite and the thickener is not particularly limited, and may be applied by selecting a method commonly used in the art.
본 발명에 의한 무기접착제의 작용 기전은 명확히 밝혀지지는 않았지만 소듐실리케이트, 광물질 분말 및 셀라이트의 무기물이 클러스터화된 물과 함께 강하게 결합되어 높은 접착력을 나타낸다.The mechanism of action of the inorganic adhesive according to the present invention is not clear, but the inorganic silicates of sodium silicate, mineral powder and celite are strongly bound together with the clustered water to show high adhesion.
즉, 무기물이 클로스터화된 물에 용탈(dissolusion) → 아쿠아졸 형성(formation of aquasols) → 응축(condensation) → 겔 형성(gel formation) → 결정화(crystallization)하는 반응으로 강한 접착력이 발휘되어 가구용 접착제에서 요구되는 접착력 이상의 접착력을 얻을 수 있으며, 유기 결합제의 사용으로 인한 문제점 및 합성수지재의 문제점을 해결할 수 있고, 무기물로만 이루어진 바인더를 사용함으로써 오염물의 배출이 없어 환경 오염을 유발하지 않고, 경제적일 뿐만 아니라 간단한 방법으로 가구를 제조할 수 있다.In other words, strong adhesion is exerted by dissolving → aquasol formation → condensation → gel formation → crystallization in inorganic clotized water. Adhesion beyond the required adhesion can be obtained, can solve the problems caused by the use of the organic binder and the synthetic resin material, and by using a binder made only of inorganic material, there is no discharge of contaminants, economical and simple Furniture can be manufactured by the method.
도 1은 본 발명에 따른 가구용 무기접착제의 작용 매카니즘을 설명하는 모식도이고,1 is a schematic diagram illustrating the mechanism of action of the inorganic adhesive for furniture according to the present invention,
도 2는 본 발명의 가구용 무기접착제를 사용하여 목재와 목재, 목재와 석재를 접착시킨 상태의 사진이다.Figure 2 is a photograph of a state in which the wood and wood, wood and stone bonded using the inorganic adhesive for furniture of the present invention.
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KR102075349B1 (en) | 2019-04-09 | 2020-03-03 | 김우찬 | method of eco-friendly fiber board |
KR20210097385A (en) | 2020-01-30 | 2021-08-09 | (주)해냄 | Eco-Friendly Furniture Exterior Panel |
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