KR101045982B1 - Manufacturing method of ultrafast waterproof concrete road pavement composition using modified acrylic polymer and road pavement composition prepared thereby - Google Patents

Abstract

The present invention relates to a method for preparing a super fast-waterproof concrete road pavement composition using a modified acrylic polymer and a road pavement composition prepared by the same, which is applied to new or repaired road pavement of asphalt concrete road and cement concrete road at room temperature, It is for improving durability. To this end, the present invention comprises a first step of producing a mixture of cemented carbide waterproof cement and aggregate; A second step of preparing a blended water of the modified acrylic polymer and water; The third step of mixing the mixture and the blended water; characterized in that consisting of, unlike the conventional fast curing paving concrete (VES-LMC) composition using latex, not only gives the waterproofing of the cross-linking packaging material, but also various It is possible to improve the high strength, high adhesion, economic efficiency, workability, durability, and finish when repairing and paving asphalt road.

Description

TECHNICAL FIELD OF MANUFACTURING ROAD PAVEMENT MATERIAL OF VERY-EARLY STRENGTH WATERPROOF CONCRETE USING REFORMING ACRYLIC POLYMER AND ROAD PAVEMENT MATERIAL MANUFACTURED BY THIS}

The present invention relates to a method for manufacturing a road pavement composition and a road pavement composition produced by the same, more specifically, to improve the waterproofness, durability, etc. by applying to new or repair road pavement of asphalt concrete road and cement concrete road at room temperature The present invention relates to a method for producing a superfast waterproof concrete road pavement composition using a modified acrylic polymer, and a road pavement composition prepared thereby.

Generally, the bottom plate of a bridge is the most frequent member in bridge members because it is easily exposed to cracks due to plastic shrinkage and dry shrinkage from the beginning of construction, and is directly exposed to repeated traffic loads and various environmental conditions. After the cross-section paving, the requirements for the cross-section paving are easy to secure flatness, high waterproofness, large flexural tensile strength and resistance to cracking. There is a need for waterproofing layer construction between the slab and the pavement pointed out, lifting water, water generation, damage to the structure due to chloride penetration, increased maintenance costs due to frequent repair work, and civil complaints. Poor ride quality due to lack of flatness of bridge, increased driving noise, waterproof And cracking resistance is excellent and the low chloride penetration by reduced carrying capacity due to the early deterioration of concrete floors, etc. generated by the bridge deck has been introduced packing method using a latex blend modified concrete (LMC) in Korea.

Although styrene-butadiene copolymerized latex is used for general concrete, various construction methods developed by using durable cross-linking and concrete pavement, such as resistance to freeze-thawing and scaling and prevention of neutralization by polymer cement complex hydrate, have been applied. Renovation works that require traffic blocking cause road inconvenience and users' discomfort, and road paving products using cemented carbide are showing good line. In particular, fast-moving concrete is used because the traffic must be opened within 3 to 5 hours after the start of construction, but the freeze-thawing resistance, durability, etc. are weaker than general Portland cement due to the properties of superhard cement. There is a problem that often occurs. Accordingly, in order to supplement the durability of concrete, polymer cemented carbide concrete using aqueous SBR latex has been actively used as a repair material, and cemented carbide concrete using such polymer has excellent resistance to freezing-thawing and scaling. Due to its high waterproofness and adhesiveness, it greatly compensated for the shortcomings of using only cemented carbide, water and aggregate, and greatly contributed to improving the quality of road repair work.

According to the current quality control standards of superhard LMC for bridge deck repair and resurfacing, the superhard cement, latex and superhard LMC formulation standards and compression, adhesive strength and cracking after hardening are specified. The quality standards of cemented carbide are based on powder level, stability, condensation time and compressive strength, and the quality standards of latex are solid content, pH, solidification amount, viscosity, surface tension, residual volume of 200, average particle size and freeze-thawing. There is a standard of stability and butadiene content. The ultrafast diameter LMC formulation is based on the range of compressive strength, unit latex amount, water / cement ratio, coarse aggregate size, slump, and air volume. However, the criteria for selecting materials suitable for bridge deck repair and bridge material packaging requirements are limited to specific product groups, and the quality improvement is limited. In particular, water-based styrene-butadiene latex (SBL) Copolymer of styrene and butadiene, the amount of styrene is used is 60-70%, butadiene is 30-40%, and the average size of particles dispersed by emulsifying the synthesized polymer in water is defined as 140-250nm. I'm doing it. The polymer particles are used according to the characteristics of the film through a process of continuous contact and film formation during drying. If the amount of styrene having a Tg (glass transition temperature) of about 100 ° C. is high, the elasticity is reduced and the stickiness is less. The main uses are paper coating, fiber coating, and cement mixing. In order to properly use the film properties of the polymer, it is necessary to work above the film formation minimum temperature (MFFT) of the polymer and is an important factor in the properties of the polymer cement composite. Aqueous emulsions or latexes for cement, which are widely used in Korea, include acrylic, vinyl acetate, and styrene-butadiene latex, and vinyl acetate has an average particle diameter of 2-30 µm for adhesion purposes. Styrenebutadiene latex is used as a cement-modified product with an average particle diameter of 0.1-0.3㎛. Depending on the application, styrene-rich products are yellow for UV rays and decompose, so they are classified for internal use and UV-resistant acrylic products for external exposure.

In order to supplement the strong properties of cement, a material using high elastic polymer is called polymer cement (PC) in the academic world, and concrete using polymer cement is called polymer cement concrete (PCC or PMC). Cement admixtures are important for mixing with cement. When the polymer is mixed with cement, the polymer dispersion must not be solidified by mechanical diffusion or by free calcium ions (Ca ²⁺ ) in the cement. Polymer cement concrete forms composite hydrates through the process of polymers forming films by shifting particles between several micrometers of cement particles by hydration with water and growing particles. By combining waterproof properties, it improves waterproofness and breathability and ultimately improves durability by preventing concrete neutralization, increasing abrasion resistance, and freeze-thawing resistance.

Factors affecting the properties of polymer cement are the type of polymer, polymer cement ratio (P / C,%), temperature, and workability and physical properties after curing. Evaluation of polymer cement concrete is divided into evaluation of workability before hardening of concrete and evaluation of physical properties of hardened body after construction. Depending on the type and amount of polymer used, the compatibility with cement is important because of its large influence on workability, such as fluidity, viscosity, air volume, and water retention, and it may be necessary to modify the polymer to suit the characteristics of cemented carbide, sand, aggregate, etc. In particular, considering the workability in the field, it should be possible to select a polymer suitable for the polymer concrete mixing conditions.

Although the quality of superhard polymeric modified concrete using SBR latex, which has been the most common until recently, has improved overall quality, when it is applied in an environment exposed to the outside air, the surface is rapidly dried due to rapid film formation on the surface, resulting in poor surface finish and surface cracking. As a result, the surface treatment may be performed separately. In addition, the phenomena of white turbidity when contacted with water after the initial hydration of SBR latex means that a homogeneous dry film was not formed during the filming process, which led to the weakening of water resistance, which was exposed to ultraviolet rays during the long-term life prediction of the road. There is a limit of durability, such as wear resistance is weak on the concrete surface. This may affect not only the problem of SBR latex but also the initial hydration reaction condition of polymer cement system and the work process during surface treatment due to early opening. Cement has the greatest influence on the physical properties of these polymers. Particularly in road pavement materials where the amount of polymer used is from 15% to 20% of cement, forced reaction cement is essential to exert quality properties regardless of hydration conditions, and reaction sequence consumes moisture in polymer cement system. Then, the hydration reaction step occurs, followed by drying of the evaporation process of water. If the hydration reaction is not normal, the film is dried from the surface first, which leads to wrinkles and cracks on the surface.

The cement manufacturing method used for the cemented carbide polymer cement concrete is based on Clinker based on calcium fluoroaluminate mineral C ₁₁ A ₇ CF ₂ (11CaO · 7Al ₂ O ₃ · CaF ₂ ). Cement, gypsum and admixtures are prepared (Registration No. 10-0033581, 10-0005309, Japanese Patent Application No. 52-139819). Second, CA (CaO · Al ₂ O ₃ ), C among calcium aluminate minerals _{2 a (2CaO · Al 2 O} 3), C 12 a 7 (12CaO · 7Al 2 O 3) to which the method of manufacturing put a Portland cement, gypsum and admixtures to the alumina cement containing as a main component, and the third with ah wingye clinker Calcium sulfoaluminate (3CaO.3Al ₂ O ₃ .CaSO ₄ ) as a main component is a method of manufacturing cement (Registration No. 10-0755272, 10-0310657, 10-0220340, 10-0122033). Among them, the third method is the latest method of manufacturing an improved cemented carbide cement composition. The clinker has a lower firing temperature (1,200 to 1,350 ° C) than other technologies, and is easy to manufacture. When the combination ratio is suitably used, the initial strength is excellent and the long-term strength is stably expressed. In addition, in the manufacture of fast-hard concrete, until now, simply according to the method of preparing a composition (registration number 10-0403979) in which an antifoaming agent and a coagulant retardant, aggregate, and water were previously dissolved in an Irwin-based cemented carbide cement or A method of mixing latex used in cemented carbide cement with SBR latex and acrylic resin is proposed (Patent 10-0807850, 10-0696313), and fly ash, silica fume, blast furnace slag as a mixed material in cement. Methods of mixing fine powders and the like (registered patent 10-0696313, 10-0618297, and published patent 10-2005-0031097) and the like have been studied. Cement for the manufacture of fast-hard concrete is usually designed to meet the commercial strength within 3 to 5 hours by mixing with water, but when used as a polymer concrete or mortar by mixing an aqueous polymer such as SBR latex or There is a big difference in the property expression properties. In particular, the use of fly ash, slag fine powder, silica fume, etc., which are slow in reactivity, may be advantageous in terms of long-term strength, but it is not an effective method in the field requiring initial strength.

The strength of the cemented carbide is measured by Ca ²⁺ ions eluted from cement and slaked lime and Al ³⁺ ions eluted from calcium aluminate immediately after contact with water, resulting in calcium aluminate hydrate (CaO · Al ₂ O ₃ · nH ₂ O), which is then reacted with gypsum in cement to produce ettringite (3CaO.Al ₂ O ₃ .3CaSO ₄ .32H ₂ O) to rapidly cure.

Therefore, the quality of superhard cement, such as the strength expression rate, strength expression rate, and workability, depends on the control of the rate and amount of ettringite mineral formation, and the technology of stably maintaining the hydrate. Clinker minerals (3CaO · 3Al ₂ O ₃ · CaSO ₄ ) and some components of gypsum, hydrated lime and cement are highly reactive when mixed with water, causing active hydration reactions. You'll be on your way in minutes. Here, ettringite hydrate combined with sulfate (SO ₄ ^2- ) is monosulfate (3CaO · Al ₂ O ₃ · CaSO ₄ · 12H ₂ O) and calcium when there is insufficient supply of each component that maintains its composition as an unstable hydrate. Transition to aluminate hydrate (CaO.Al ₂ O ₃ .nH ₂ O) or the like results in low strength expression.

In general, during the hydration reaction of polymer cement, the adsorption characteristics of cement particles and the thickening effect of the polymer increase the viscosity of the paste to 5000 cps (Brookfield, 23 ℃), which is almost 10 times when the viscosity of the polymer cement is 0.15. Due to the decrease and delay of diffusion rate, the hydration reaction is significantly delayed, which leads to a delay in strength characteristics and polymer film formation. In order to improve this problem, a method prepared by appropriately mixing the Arwin-based clinker pulverized to artificially present a certain amount of free CaSO ₄ in the mineral composition and portland cement, gypsum, coagulation control agent, curing accelerator (see Patent 10). -0755272) is also proposed, but because of the properties described, in order to obtain the required strength in the manufacture of cemented carbide polymer concrete, cemented carbide with excellent initial hydration characteristics should be used, and concrete until cemented carbide is reacted. It is necessary to maintain the homogeneous wet state between inside and outside of the surface to eliminate the dryness of the surface part.There are various variables such as strength, adhesive strength and waterproofness after curing. Various research on the situation is required.

The present invention has been made to solve the above-described problems of the prior art, unlike the conventional fast-concrete concrete composition for road repair using a polymer latex, to produce a super fast cement having a high degree of hydration in a high polymer usage formulation The acrylic dispersant with excellent stability is given to UV rays to improve the compatibility with hydrophobicity and cement. Improved strength, durability and economy It is an object of the present invention to provide a method for producing a superfast waterproof concrete road pavement composition using a modified acrylic polymer and a road pavement composition prepared thereby.

In order to achieve the above object, the present invention, the first step of producing a mixture of cemented carbide waterproof cement and aggregate; A second step of preparing a blended water of the modified acrylic polymer and water; And a third step of mixing the mixture and the blended water.

Here, the cemented carbide waterproofing cement includes an Arwin-based clinker powder including calcium sulfoaluminate (3CaO.3Al ₂ O ₃ .CaSO ₄ ), gypsum powder mixed with anhydrous gypsum and hemihydrate gypsum, portland cement, and silica fume. In addition, it is characterized in that it further comprises a high fluidizing agent, a coagulation delay agent, a curing accelerator, a waterproof powder resin treated with silane, a shrinkage reducing agent and an antifoaming agent.

In addition, the waterproof powder resin is prepared by emulsifying the silane reacting with Si in cement or concrete to synthesize with an EVA (Ethylene Vinyl Acetate) emulsion and then powderized, the shrinkage reducing agent is a glycol-based shrinkage reducing agent having a wetting function It features.

As described above, the method of manufacturing a super-fast-waterproof concrete road pavement composition using the modified acrylic polymer according to the present invention, and the road pavement composition prepared thereby is waterproof, unlike the conventional fast-concrete concrete composition for road repair using a polymer latex The surface of the surface finishing process after casting is made by using a superhard cement manufactured to increase the initial hydration rate and a modified acrylic polymer modified with a polyethylene wax emulsion of an acrylic polymer which is highly durable against UV rays while increasing compatibility with cement. It can maintain the wet state of the product to reduce the dryness and improve the workability, strength and durability during construction.

Hereinafter, with reference to the embodiments will be described a method for producing a super-fast-waterproof concrete road pavement composition using the modified acrylic polymer according to the present invention and the road pavement composition prepared thereby.

According to the present invention, a method of manufacturing a cemented carbide waterproof concrete road pavement composition using the modified acrylic polymer basically includes a first step of preparing a mixture of cemented carbide waterproofing cement and aggregate, and a second step of preparing a blended water of the modified acrylic polymer and water. And a third step of mixing the mixture and the blended water.

The cemented carbide waterproofing cement used in the present invention is an Arwin-based clinker powder containing calcium sulfoaluminate (3CaO.3Al ₂ O ₃ .CaSO ₄ ), gypsum powder mixed with anhydrous gypsum and hemihydrate gypsum, and portland cement. And, silica fume, including a high fluidizing agent, coagulation delay agent, curing accelerator, silane-treated waterproof resin, shrinkage reducing agent and antifoaming agent can be obtained better properties.

Table 1 below shows 40 to 60 parts by weight of a powder containing calcium sulfoaluminate 30 to 60% by weight and pulverized Irwin-based clinker having a specific surface area of 4,000 to 8,000 cm ² / g. 20 to 40 parts by weight of gypsum powder with a surface area of 4,000 to 6,000 cm ² / g and anhydrous gypsum and hemihydrate gypsum and 20 to 40 parts by weight of ordinary portland cement with a specific surface area of 3,500 to 4,500 cm ² / g And, it shows the physical properties of the cemented carbide prepared by mixing 3 to 15 parts by weight of silica fume having a specific surface area of 150,000 to 250,000 cm ² / g by the blain.

In addition, with respect to 100 parts by weight of the cemented carbide waterproofing cement, 0.3 to 1.0 parts by weight of a high fluidizing agent, 0.2 to 1.0 parts by weight of a coagulation delay agent, 0.1 to 1.0 parts by weight of a curing accelerator having an average particle size of 3 to 10 μm, and silane When added 1.0 to 6.0 parts by weight of the treated waterproof powder resin, 0.2 to 1.0 parts by weight of shrinkage reducing agent, and 0.1 to 1.0 parts by weight of the antifoaming agent, the physical properties were better than those of the super fast-water waterproofing cement of Table 1.

Here, the waterproof powder resin is prepared by emulsifying the silane reacting with SiO ₂ in cement or concrete to synthesize with an EVA (Ethylene Vinyl Acetate) emulsion, and then powderized. Usually, the air bubbles (capillary pore) present in concrete are hydrophilic groups. The OH group is easily in contact with moisture, but when silane is present, the OH group and the dust silane combine and then form a hydrocarbon group (alkyl) on the surface of the bubble to show water repellency when water is introduced. Processed waterproof powder resin is used, and emulsified alkyl trialcohol silane is powdered by spray drying method, so when used in cemented carbide waterproofing cement, viscosity increase phenomenon and bubble caused by high powder level are trapped. It not only reduces the phenomena, but also softens the plastering and after curing, To maximize the waterproof characteristics.

In addition, the shrinkage reducing agent is a glycol-based shrinkage reducing agent having a wetting function, and the viscosity is increased when the superfine powder waterproof cement and the nano-sized polymer particles having high powder density are mixed during the phenomenon that may occur during construction of the superhard polymer concrete. Stickiness is increased. In the site exposed to outdoor air, the effect of temperature and wind increases the dryness and even a slight delay in the plastering process increases wrinkles or residual cracks on the surface. In order to improve the dispersibility of various inorganic particles and increase the wettability of the polymer cement slurry by adding a glycol-based shrinkage reducing agent such as 2,2-dimethyl-1,3-propanediol, It increases the pot life of and significantly reduces the occurrence of cracks on the surface by preventing sudden moisture escape from the surface.

On the other hand, the polymer alone cannot obtain the adhesive strength and strength, and the cement alone cannot obtain the adhesive strength and elasticity, but the cement miscible polymer is combined with the cement to complement each other's physical properties of the cement and the polymer. You can get it. The polymer forms a film as the water evaporates, and the polymer film is formed between the cement particles to have adhesion and elasticity. In the polymer cement paste mixed with polymer and cement, cement functions as a binder to help the polymer form a film, and the strength of the polymer cement is increased by rehydrating the cement under curing conditions that repeat the wet and dry processes. This is because of sufficient hydration reaction and film formation of the polymer. In order for the polymer to form a film, the polymer particles must be deformed and fused by capillary pressure of water, and the deformation fusion is possible only at a certain temperature or higher. The minimum temperature required for the polymer to form a film is called the minimum film forming temperature (MFFT). When the capillary pressure is applied between the polymer particles to form a film by fusion between particles, that is, when the film is dried at a condition where the film temperature is higher than the minimum film temperature (film temperature> MFFT), a firm film is formed. On the contrary, under the condition that the film forming temperature is lower than the minimum film forming temperature (film forming temperature <MFFT), the deformation fusion in two stages does not proceed and the white powder becomes white to form a film. This does not form a good film even when cured or heated again at a high temperature. Conventional polymer dispersions have their own minimum film forming temperatures above 0 ° C., and the minimum film forming temperatures of commercially available cement admixtures usually range from 0 to 5 ° C. The biggest governance of the lowest film temperature is the glass transition temperature (Tg) of the polymer. The glass transition temperature is lower gradually as the molecular weight of the polymer becomes smaller and lowers in proportion to the amount even when a plasticizer is added to the polymer. As such, the polymer used by mixing with cement has different properties depending on the environment used, and an optimal product should be selected or manufactured and used.

According to the current guideline for repacking and repairing bridge deck plates using superhard LMC, the quality standards of SBR latex are shown in Table 2 below, but some of the material specifications are used as control items for the formulation properties and construction quality of related materials. Not suitable for

Item Test specification unit result Solid content KS M 6516-2006 % 46-49 200 residual flow KSA ISO 13320-1 g / ℓ 0.5 or less pH KS M 6516-2006 8.5-12.0 Freeze-thaw stability FHWA-RD-78-35 0.1 or less Butadiene Content FHWA-RD-78-35 % 30-40 importance KS M 0004-1997 Amount of coagulation KS M 6030-2004 % 0.1 or less Viscosity KS M 6516-2006 Mpa.s 100 or less Average particle size FHWA-RD-78-35 Å 1400-2500 Surface tension KS M 6516-2006 dyn / cm. 50 or less

For the same reason as described, the modified acrylic polymer used in the present invention is adjusted by applying the physical property standards of the cement miscible polymer based on the proven polymer cement research data. It is decided based on acrylic considering ~ 300nm, and it is mixed with cement so that it is alkali-treated to avoid collision due to the difference of pH value of polymer in strong alkali atmosphere. Since it is mixed with the cement of fine particles, it has good mixing with cement and does not entrain bubbles in the material.The standard for the amount of polymer used depends on the polymer cement ratio (P / C ratio,%). It is preferable to use within the range of ˜2.0, Table 3 below shows the physical properties of the modified acrylic polymer used in the present invention.

Test Items Standard unit standard result Solid content KS M 6516-2006 % 46-49 50 200 residual flow KSA ISO 13320-1 g / ℓ 0.5 or less 0.1 pH KS M 6516-2006 8.5-12.0 9.2 Freeze-thaw stability FHWA-RD-78-35 0.1 or less NA importance KS M 0004-1997 1.016 Amount of coagulation KS M 6030-2004 % 0.1 or less 0.06 Viscosity KS M 6516-2006 Mpa.s 100 or less 49 Average particle size FHWA-RD-78-35 Å 1400-2500 1600 Surface tension KS M 6516-2006 dyn / cm. 50 or less 37

<Examples>

A superhard waterproof cement was prepared by mixing 30 parts by weight of gypsum powder mixed with anhydrous gypsum and hemihydrate gypsum, 30 parts by weight of ordinary Portland cement, and 8 parts by weight of silica fume, based on 50 parts by weight of pulverized Irwin-based clinker. 100 parts by weight of the cemented carbide waterproof cement, 0.6 parts by weight of a high fluidizing agent, 0.6 parts by weight of a coagulation retardant, 0.6 parts by weight of a curing accelerator, 3.0 parts by weight of a waterproof powder resin treated with silane, and a shrinkage reducing agent. 0.6 parts by weight and the anti-foaming agent 0.6 parts by weight was further added to prepare a road pavement composition, Table 4 below shows the physical property test results of the concrete prepared from the road pavement composition of the present invention.

Test Items Test specification unit standard result Condensation Time KS F 2436: 2007 hour minute Presentation 45 Formulation Design Data Compressive Strength (4 hours) KS F 2405: 2005 MPa 21 or more 26.3 Compressive Strength (1 Day) KS F 2405: 2005 MPa (Based on opening hours) 31.1 Compressive Strength (7 Days) KS F 2405: 2005 MPa 34.8 Flexural strength (4 hours) KS F 2408: 2000 MPa 3.15 or higher 5.73 Flexural Strength (1 day) KS F 2408: 2000 MPa (Based on opening hours) 5.94 Flexural strength (7 days) KS F 2408: 2000 MPa 6.59 Adhesion strength (4 hours) ASTM C 1583 MPa 1.4 or higher 1.8 Adhesion strength (1 day) ASTM C 1583 MPa (Based on opening hours) 2.6 Adhesion strength (7 days) ASTM C 1583 MPa 3.1 Length change rate (21 days)-hardening shrinkage ASTM C 157 % 0.15 or less 0.0461 Chlorine ion penetration resistance (21 days) ASTM C 1202 Coulomb Less than 2000 124 Scaling Resistance (56cycles) SS 13 7244 A method kg / m ² 1.0 or less 0.1 1cycle = 1 day Relative dynamic modulus of elasticity (freeze melting, 300 cycles) ASTM C 666 % 80 or more 85 Modulus of elasticity (7 days) ASTM C 469 Mpa 3.4 ~ 7.0 * 103 29790 Wear resistance ASTM C 779 mm 15 or less (30 minutes) ASR resistance ASTM C 1260 % 0.15 or less Coefficient of thermal expansion AASHTO TP 60 0.80 ~ 12.0 * 10 ^-6 / ℃ Waterproof (Water Absorption) KS F 4926 Crack promotion test (time for crack start) ASTM A 501 O-RING Crack Promotion Test (Crack Width) STM A 501 O-RING

Referring to Table 4, the experimental results according to the embodiment showed that the physical properties of the super hard waterproof concrete road pavement composition using the modified acrylic polymer of the present invention was not only higher than the existing physical properties standards, but also excellent in workability. Penetration resistance (chlorine ion permeability), especially for salinity, is generally very high when its value is over 4,000 coulombs, and is poor. In the range of 1,000 to 100 coulombs, a very low level was evaluated. Under 100 coulombs, the water permeability was evaluated. In the case of the road pavement material according to the present invention, the penetration resistance against salinity was 124 coulombs.

Claims (6)

delete delete A first step of preparing a mixture of cemented carbide waterproofing cement and aggregate;
A second step of preparing a blended water of the modified acrylic polymer and water;
A third step of mixing the mixture and the blended water;
The cemented carbide waterproofing cement includes an Arwin-based clinker powder including calcium sulfoaluminate (3CaO.3Al ₂ O ₃ .CaSO ₄ ), gypsum powder mixed with anhydrous gypsum and hemihydrate gypsum, portland cement, and silica fume. A super fast-water-resistant waterproof concrete road pavement composition manufacturing method using a modified acrylic polymer, characterized in that it further comprises a high fluidizing agent, a coagulation delaying agent, a curing accelerator, a waterproof powder resin treated with a silane, a shrinkage reducing agent and an antifoaming agent. The method according to claim 3,
The waterproof powder resin is a super fast-water-resistant waterproof concrete road pavement composition using a modified acrylic polymer, characterized in that it is prepared by emulsifying the silane reacting with SiO ₂ in cement or concrete to synthesize with an EVA (Ethylene Vinyl Acetate) emulsion Manufacturing method. The method according to claim 3,
The shrinkage reducing agent is a glycol-based shrinkage reducing agent having a wetting function, characterized in that the method for producing a super fast waterproofing concrete road pavement composition using a modified acrylic polymer. A road pavement composition prepared by a method for producing a super fast-wearing waterproof concrete road pavement composition using a modified acrylic polymer, according to any one of claims 3 to 5.