KR101037333B1 - Manufacturing method of a multi-pattern coating composition excellent in antimicrobial, stain resistance, scratch resistance and yellowing resistance, the multi-pattern coating composition prepared thereby and a method of forming a multi-pattern coating film using the same - Google Patents
Manufacturing method of a multi-pattern coating composition excellent in antimicrobial, stain resistance, scratch resistance and yellowing resistance, the multi-pattern coating composition prepared thereby and a method of forming a multi-pattern coating film using the same Download PDFInfo
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- KR101037333B1 KR101037333B1 KR1020110023006A KR20110023006A KR101037333B1 KR 101037333 B1 KR101037333 B1 KR 101037333B1 KR 1020110023006 A KR1020110023006 A KR 1020110023006A KR 20110023006 A KR20110023006 A KR 20110023006A KR 101037333 B1 KR101037333 B1 KR 101037333B1
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Images
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/36—Successively applying liquids or other fluent materials, e.g. without intermediate treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
본 발명은 항균성, 내오염성, 내스크래치성 및 내황변성이 우수한 다채무늬 도료 조성물의 제조방법, 이에 의해 제조된 다채무늬 도료 조성물 및 이를 이용한 도막 형성 방법에 관한 것으로, 수성 아크릴 에멀젼 수지, 수분산 우레탄 수지 또는 수용성 에폭시 수지 중 어느 하나의 유기물 수지 30~50중량%, 물 5~20중량%, 실리카졸 30~50중량%, 나노은(Nano Silver) 0.1~0.5중량%, 소포제 0.1~1중량% 및 항균제 0.5~2중량%를 혼합하여 하도층 도료 조성물을 제조하는 단계(단계 1); 수성 아크릴 에멀젼 수지, 수분산 우레탄 수지 또는 수용성 에폭시 수지 중 어느 하나의 유기물 수지 25~40중량%, 실리카졸 25~40중량%, 실리카 5~15중량%, 나노은(Nano Silver) 0.1~0.5중량%, 이산화티타늄(TiO2) 5~15중량%, 클레이(Clay) 5~10중량%, 아크릴계 증점제 1~5중량%, 소포제 0.1~1중량% 및 우레탄계 증점제 2~5중량%를 혼합하여 바탕층 도료 조성물을 제조하는 단계(단계 2); 및 수성 아크릴 에멀젼 수지, 수분산 우레탄 수지 또는 수용성 에폭시 수지 중 어느 하나의 유기물 수지 25~40중량%, 실리카졸 20~35중량%, 실리카 10~15중량%, 나노은(Nano Silver) 0.1~0.5중량%, 클레이(Clay) 5~10중량%, 아크릴계 증점제 2~10중량%, 소포제 0.1~1중량% 및 우레탄계 증점제 2~5중량%를 혼합하여 패턴층 도료 조성물을 제조하는 단계(단계 3); 를 포함하여 제조하면, 종래의 외부상에 내부상을 분산시켜 제조하는 다채무늬 도료에 비해 제조공정이 간단하고, 다채무늬 도료의 경도를 향상시켜 내오염성 및 내스크래치성이 우수하면서도 크랙(crack)이 발생하지 않는 장점이 있으며, 자외선에도 색상과 도막의 변화가 없는 내황변성이 우수하고 방수 및 발수 기능으로 인해 건축 내장 도료 뿐만 아니라 외장 도료로 사용가능하며, 항균성 및 오염 제거성이 우수한 효과가 있다.The present invention relates to a method for producing a multi-pattern coating composition excellent in antimicrobial, stain resistance, scratch resistance and yellowing resistance, a multi-pattern coating composition prepared by this and a method for forming a coating film using the same, an aqueous acrylic emulsion resin, a water-dispersed urethane 30-50 wt% of organic resin of any one of resin or water-soluble epoxy resin, 5-20 wt% of water, 30-50 wt% of silica sol, 0.1-0.5 wt% of Nano Silver, 0.1-1 wt% of antifoaming agent and Mixing the antimicrobial agent 0.5 to 2% by weight to prepare a bottom coat composition (step 1); 25-40% by weight of organic resin of any one of aqueous acrylic emulsion resin, water-dispersed urethane resin or water-soluble epoxy resin, 25-40% by weight of silica sol, 5-15% by weight of silica, 0.1-0.5% by weight of nano silver , 5-15 wt% of titanium dioxide (TiO 2 ), 5-10 wt% of clay, 1-5 wt% of acrylic thickener, 0.1-1 wt% of antifoaming agent, and 2-5 wt% of urethane thickener. Preparing a coating composition (step 2); And 25-40% by weight of the organic resin of any one of an aqueous acrylic emulsion resin, a water-dispersed urethane resin, or a water-soluble epoxy resin, 20-35% by weight of silica sol, 10-15% by weight of silica, and 0.1-0.5% by weight of nano silver. Preparing a pattern layer coating composition by mixing%, 5-10 wt% of clay, 2-10 wt% of an acrylic thickener, 0.1-1 wt% of an antifoaming agent, and 2-5 wt% of a urethane thickener (step 3); When manufactured, the manufacturing process is simpler than the multi-patterned paint prepared by dispersing the inner phase of the conventional external phase. The hardness of the multi-patterned paint is improved to improve the hardness and scratch resistance, but also to crack. It does not occur, it is excellent in yellowing resistance without change of color and coating even in ultraviolet light, and can be used as exterior paint as well as interior paint due to waterproof and water repellent function, and has excellent antibacterial and decontamination property. .
Description
본 발명은 항균성, 내오염성, 내스크래치성 및 내황변성이 우수한 다채무늬 도료 조성물의 제조방법, 이에 의해 제조된 다채무늬 도료 조성물 및 이를 이용한 다채무늬 도막 형성 방법에 관한 것으로, 보다 상세하게는 외부상에 내부상을 분산시켜 제조하는 종래의 다채무늬 도료에 비해 제조공정이 간단하고, 고경도이면서도 크랙(crack)이 발생하지 않는, 항균성, 내오염성, 내스크래치성 및 내황변성이 우수한 다채무늬 도료 조성물의 제조방법, 이에 의해 제조된 다채무늬 도료 조성물 및 이를 이용한 다채무늬 도막 형성 방법에 관한 것이다.
The present invention relates to a method for producing a multi-pattern coating composition excellent in antimicrobial, stain resistance, scratch resistance and yellowing resistance, a multi-pattern coating composition prepared thereby and a method for forming a multi-pattern coating film using the same, in more detail Compared to the conventional multi-pattern paints produced by dispersing the internal phase in the fabric, the manufacturing process is simpler, and the high-hardness, crack-free, antimicrobial, fouling, scratch and yellowing resistance are excellent. It relates to a method of manufacturing, a colorful pattern coating composition produced by this and a method of forming a colorful pattern coating film using the same.
일반적으로 건축물의 내외면에는 장식성을 높여 고급스러운 멋을 내면서 실내외의 세련된 분위기를 연출하기 위하여 별도로 고가의 천연석재나 인조석으로 마감처리하고 있으나, 상기 방법은 높은 비용을 요한다. 그에 따라 장식성을 높이기 위한 하나의 방법으로 입체문양 효과를 내면서 천연석과 같은 다양한 질감을 낼 수 있을 뿐만 아니라 다양한 색채를 낼 수 있는 다채무늬 도료를 사용하여 건축물 내외면을 처리하는 방법이 개발되고 있다.
In general, the interior and exterior surfaces of the building to be decorated with expensive natural stone or artificial stone separately in order to create a stylish atmosphere of the interior and exterior while increasing the decorativeness, but the method requires a high cost. Accordingly, a method of treating interior and exterior surfaces of a building using various pattern paints that can produce various textures such as natural stones, as well as various colors while producing a three-dimensional pattern effect, has been developed as one method for enhancing decorativeness.
대한민국등록특허 제10-0541628호(2006.01.10.)에는 에멀젼화된 졸을 외부상으로 하고, 여기에 내부상인 수성겔을 분산시켜 제조되는 에멀젼 수적형 다채무늬 도료조성물이 개시되어 있으며, 대한민국등록특허 제10-0854445호(2008.08.27.)에는 수성졸과 색상제를 만든 다음 이들을 혼합하여 정형화된 입자크기의 무늬를 갖는 외부상인 에멀젼화된 수성졸을 제조한 다음 여기에 내부상인 수성 겔을 분산시킴으로서 양호한 화강암 무늬를 형성할 수 있는 화강암 무늬 형성용 에멀젼 수적형 다채무늬 도료조성물이 개시되어 있다. Republic of Korea Patent No. 10-0541628 (October 10, 2006) discloses an emulsion droplet type colorful pattern paint composition prepared by emulsifying sol as an external phase, and dispersed therein an aqueous gel. Patent No. 10-0854445 (2008.08.27.) Makes an aqueous sol and a colorant, and then mixes them to prepare an emulsified aqueous sol, which is an external phase having a pattern of a particle size of a standardized form, and then an aqueous gel that is an internal phase is added thereto. Disclosed is a granular pattern forming emulsion water droplet-type colorful pattern coating composition capable of forming a good granite pattern by dispersing.
상기 다채무늬도료는 화강암 무늬를 얻을 수 있는 장점이 있지만, 제조공정이 복잡한 단점이 있으며, 항균성, 내오염성, 내스크래치성 및 내황변성이 미흡한 문제가 있다.
The colorful pattern paint has the advantage of obtaining a granite pattern, but the manufacturing process has a complex disadvantage, there is a problem of insufficient antibacterial, stain resistance, scratch resistance and yellowing resistance.
본 발명자들은 외부상에 내부상을 분산시켜 제조하는 종래의 다채무늬 도료에 비해 제조공정이 간단하고, 고경도이면서도 크랙(crack)이 발생하지 않는, 항균성, 내오염성, 내스크래치성 및 내황변성이 우수한 다채무늬 도료 조성물을 개발하였다.
The inventors of the present invention have a simpler manufacturing process than conventional multi-pattern paints produced by dispersing the internal phase on the outer phase, and have high hardness and no cracking, and have antibacterial, stain resistance, scratch resistance and yellowing resistance. Excellent colorful pattern paint compositions have been developed.
본 발명의 목적은 외부상에 내부상을 분산시켜 제조하는 종래의 다채무늬 도료에 비해 제조공정이 간단하고, 고경도이면서도 크랙(crack)이 발생하지 않는, 항균성, 내오염성, 내스크래치성 및 내황변성이 우수한 다채무늬 도료 조성물의 제조방법, 이에 의해 제조된 다채무늬 도료 조성물 및 이를 이용한 다채무늬 도막 형성 방법을 제공하는 것이다.
It is an object of the present invention that the manufacturing process is simpler than the conventional multi-patterned paint prepared by dispersing the inner phase on the outer phase, and has high hardness and no crack, antibacterial, stain resistance, scratch resistance and sulfur resistance. It is to provide a method for producing a colorful pattern coating composition excellent in denaturation, a colorful pattern coating composition prepared by this, and a method for forming a colorful pattern coating film using the same.
상기 목적을 달성하기 위하여 본 발명은 다음과 같은 수단을 제공한다.In order to achieve the above object, the present invention provides the following means.
본 발명은 수성 아크릴 에멀젼 수지, 수분산 우레탄 수지 또는 수용성 에폭시 수지 중 어느 하나의 유기물 수지 30~50중량%, 물 5~20중량%, 실리카졸 30~50중량%, 나노은(Nano Silver) 0.1~0.5중량%, 소포제 0.1~1중량% 및 항균제 0.5~2중량%를 혼합하여 하도층 도료 조성물을 제조하는 단계(단계 1); 수성 아크릴 에멀젼 수지, 수분산 우레탄 수지 또는 수용성 에폭시 수지 중 어느 하나의 유기물 수지 25~40중량%, 실리카졸 25~40중량%, 실리카 5~15중량%, 나노은(Nano Silver) 0.1~0.5중량%, 이산화티타늄(TiO2) 5~15중량%, 클레이(Clay) 5~10중량%, 아크릴계 증점제 1~5중량%, 소포제 0.1~1중량% 및 우레탄계 증점제 2~5중량%를 혼합하여 바탕층 도료 조성물을 제조하는 단계(단계 2); 및 수성 아크릴 에멀젼 수지, 수분산 우레탄 수지 또는 수용성 에폭시 수지 중 어느 하나의 유기물 수지 25~40중량%, 실리카졸 20~35중량%, 실리카 10~15중량%, 나노은(Nano Silver) 0.1~0.5중량%, 클레이(Clay) 5~10중량%, 아크릴계 증점제 2~10중량%, 소포제 0.1~1중량% 및 우레탄계 증점제 2~5중량%를 혼합하여 패턴층 도료 조성물을 제조하는 단계(단계 3); 를 포함하는 것을 특징으로 하는 항균성, 내오염성, 내스크래치성 및 내황변성이 우수한 다채무늬 도료 조성물의 제조방법을 제공한다.The present invention is an organic resin of any one of an aqueous acrylic emulsion resin, a water-dispersed urethane resin or a water-soluble epoxy resin 30-50% by weight, water 5-20% by weight, silica sol 30-50% by weight, Nano Silver 0.1 ~ Mixing 0.5 wt%, antifoaming agent 0.1-1 wt%, and antibacterial 0.5-2 wt% to produce an undercoat coating composition (step 1); 25-40% by weight of organic resin of any one of aqueous acrylic emulsion resin, water-dispersed urethane resin or water-soluble epoxy resin, 25-40% by weight of silica sol, 5-15% by weight of silica, 0.1-0.5% by weight of nano silver , 5-15 wt% of titanium dioxide (TiO 2 ), 5-10 wt% of clay, 1-5 wt% of acrylic thickener, 0.1-1 wt% of antifoaming agent, and 2-5 wt% of urethane thickener. Preparing a coating composition (step 2); And 25-40% by weight of the organic resin of any one of an aqueous acrylic emulsion resin, a water-dispersed urethane resin, or a water-soluble epoxy resin, 20-35% by weight of silica sol, 10-15% by weight of silica, and 0.1-0.5% by weight of nano silver. Preparing a pattern layer coating composition by mixing%, 5-10 wt% of clay, 2-10 wt% of an acrylic thickener, 0.1-1 wt% of an antifoaming agent, and 2-5 wt% of a urethane thickener (step 3); It provides a method for producing a multi-colored coating composition excellent in antimicrobial, stain resistance, scratch resistance and yellowing resistance comprising a.
상기 단계 2에서, 탄산칼슘(CaCO3) 2~5중량%가 추가적으로 포함되는 것을 특징으로 한다.In step 2, calcium carbonate (CaCO 3 ) is characterized in that it is additionally included 2 to 5% by weight.
상기 단계 2 이후에, 상기 바탕층 도료 조성물 100중량부에 대하여 착색안료 0.5~10중량부를 혼합하는 단계; 가 추가되는 것을 특징으로 한다.After the step 2, mixing 0.5 to 10 parts by weight of the colored pigment with respect to 100 parts by weight of the base layer coating composition; It is characterized in that the addition.
상기 단계 3 이후에, 상기 패턴층 도료 조성물 100중량부에 대하여 착색안료 0.5~10중량부를 혼합하는 단계; 가 추가되되, 상기 패턴층 도료 조성물에 포함되는 착색안료는 상기 바탕층 도료 조성물에 포함되는 착색안료와 서로 다른 색상인 것을 특징으로 한다.After the step 3, mixing 0.5 to 10 parts by weight of the colored pigment with respect to 100 parts by weight of the pattern layer coating composition; Is added, the coloring pigment included in the pattern layer coating composition is characterized in that the color is different from the coloring pigment included in the base layer coating composition.
또한, 본 발명은, 상기 제조방법으로 제조되는 것을 특징으로 하는 항균성, 내오염성, 내스크래치성 및 내황변성이 우수한 다채무늬 도료 조성물을 제공한다.In addition, the present invention provides a multi-pattern coating composition excellent in antimicrobial, fouling resistance, scratch resistance and yellowing resistance, characterized in that the production method.
또한, 본 발명은, 피도면의 표면 처리 단계(S1); 상기 피도면에 상기 하도층 도료 조성물을 도장하는 단계(S2); 상기 하도층 도장된 도막을 경화시키는 단계(S3); 상기 하도층 도장된 도막 위에 상기 바탕층 도료 조성물을 도장하는 단계(S4); 상기 바탕층 도장된 도막을 경화시키는 단계(S5); 상기 바탕층 도장된 도막 위에 상기 패턴층 도료 조성물을 도장하는 단계(S6); 및 상기 패턴층 도장된 도막을 경화시키는 단계(S7); 를 포함하는 것을 특징으로 하는 항균성, 내오염성, 내스크래치성 및 내황변성이 우수한 다채무늬 도료 조성물을 이용한 다채무늬 도막 형성 방법을 제공한다.In addition, the present invention, the surface treatment step (S1) of the surface to be coated; Painting the undercoat composition on the surface to be coated (S2); Curing the undercoat coated film (S3); Painting the base layer coating composition on the bottom coat layer (S4); Curing the base layer coated coating film (S5); Painting the pattern layer coating composition on the base layer coated film (S6); And curing the coating layer coated with the pattern layer (S7); It provides a multi-pattern coating film formation method using a multi-pattern coating composition excellent in antimicrobial, stain resistance, scratch resistance and yellowing resistance.
상기 S2 에서, 하도층 도료 조성물은 로울러 또는 붓을 이용하여 10~20㎛의 두께로 도장하며, 상기 S4 에서, 바탕층 도료 조성물은 로울러, 붓 또는 스프레이를 이용하여 15~30㎛의 두께로 도장하며, 상기 S6 에서, 패턴층 도료 조성물은 스프레이를 이용하여 50~150㎛의 두께로 도장하는 것을 특징으로 한다.
In S2, the undercoat coating composition is coated with a thickness of 10 to 20㎛ using a roller or a brush, and in S4, the undercoat coating composition is painted with a thickness of 15 to 30㎛ using a roller, a brush or a spray. And, in S6, the pattern layer coating composition is characterized in that the coating to a thickness of 50 ~ 150㎛ using a spray.
본 발명에 따른 다채무늬 도료는 외부상에 내부상을 분산시켜 제조하는 종래의 다채무늬 도료에 비해 제조공정이 간단하고, 다채무늬 도료의 경도를 향상시켜 내오염성 및 내스크래치성이 우수하면서도 크랙(crack)이 발생하지 않는 장점이 있다. 또한, 본 발명의 다채무늬 도료 조성물은 자외선에도 색상과 도막의 변화가 없는 내황변성이 우수하고 방수 및 발수 기능으로 인해 건축 내장 도료 뿐만 아니라 외장 도료로 사용가능하며, 항균성 및 오염 제거성이 우수한 효과가 있다.
The multicolored paint according to the present invention has a simpler manufacturing process than the conventional multicolored paint produced by dispersing the inner phase on the outside, and improves the hardness of the multicolored paint, thereby providing excellent cracking resistance and scratch resistance. There is an advantage that no crack occurs. In addition, the multi-colored coating composition of the present invention is excellent in yellowing resistance without change in color and coating film even in ultraviolet light, and can be used as an exterior coating as well as an interior coating due to the waterproofing and water repellent function, and has excellent antibacterial and decontamination properties. There is.
도 1은 본 발명에 따른 패턴층 도료 조성물을 한번에 1가지 색상으로 도장한 다채무늬 도료의 사진.
도 2는 본 발명에 따른 패턴층 도료 조성물을 한번에 2가지 색상으로 도장한 다채무늬 도료의 사진.1 is a photograph of a colorful pattern paint coated with one color at a time the pattern layer coating composition according to the present invention.
Figure 2 is a photograph of a colorful pattern paint coated with two colors at a time the pattern layer coating composition according to the present invention.
이하, 본 발명을 상세히 설명하면 다음과 같다.
Hereinafter, the present invention will be described in detail.
종래의 다채무늬 도료는 수성졸, 에멀젼졸 등의 외부상에 유기용제, 수성겔 등의 내부상을 분산시키는 방법으로 다채무늬 도료를 제조함으로 화강석과 같은 천연석의 분위기를 연출하는 장점이 있지만, 제조방법이 복잡한 문제가 있다.
Conventional colorful pattern paint has the advantage of producing an atmosphere of natural stone, such as granite, by manufacturing a colorful pattern paint by dispersing the internal phase of an organic solvent, an aqueous gel, etc. in the external phase such as aqueous sol, emulsion sol, etc. The method is complicated.
본 발명에서는 입체문양 효과를 내면서 다양한 색상을 발현할 수 있는 다채무늬 도료를 간단한 제조방법으로 제공함에 특징이 있다.
In the present invention is characterized by providing a colorful pattern paint that can express a variety of colors while having a three-dimensional pattern effect in a simple manufacturing method.
또한, 종래의 다채무늬 도료는 고급스러운 분위기를 연출할 수 있는 장점이 있지만, 경도가 약해 내오염성 및 내스크래치성이 약한 단점이 있으며, 다채무늬 도료의 경도를 높이면 다채무늬 도료에 크랙(crack)이 발생하는 문제가 있다.
In addition, the conventional colorful pattern paint has the advantage that can create a luxurious atmosphere, but the weakness of the hardness and weakness of the stain resistance and scratch resistance, and increase the hardness of the colorful pattern paint (cracks) in the colorful pattern paint There is a problem that occurs.
본 발명은 다채무늬 도료의 경도를 향상시켜 내오염성 및 내스크래치성이 우수하면서도 크랙(crack)이 발생하지 않는 다채무늬 도료 조성물을 제공함에 특징이 있다.
The present invention is characterized by providing a colorful pattern coating composition which improves the hardness of the colorful pattern paint and is excellent in stain resistance and scratch resistance but does not generate cracks.
아울러, 본 발명의 다채무늬 도료 조성물은 자외선에도 색상과 도막의 변화가 없는 내황변성이 우수하고 방수 및 발수 기능으로 인해 건축 내장 도료뿐만 아니라 건축 외장 도료로 사용가능한 특징이 있다.
In addition, the multi-pattern coating composition of the present invention is excellent in yellowing resistance without change in color and coating film even in ultraviolet light, and has a feature that can be used as a building exterior paint as well as a building interior paint due to waterproof and water repellent function.
먼저, 본 발명에 따른 항균성, 내오염성, 내스크래치성 및 내황변성이 우수한 다채무늬 도료 조성물의 제조방법을 설명한다.
First, the manufacturing method of the colorful pattern coating composition excellent in antimicrobial, staining resistance, scratch resistance, and yellowing resistance according to the present invention.
본 발명의 다채무늬 도료 조성물의 제조방법은,The manufacturing method of the colorful pattern coating composition of this invention,
수성 아크릴 에멀젼 수지, 수분산 우레탄 수지 또는 수용성 에폭시 수지 중 어느 하나의 유기물 수지 30~50중량%, 물 5~20중량%, 실리카졸 30~50중량%, 나노은(Nano Silver) 0.1~0.5중량%, 소포제 0.1~1중량% 및 항균제 0.5~2중량%를 혼합하여 하도층 도료 조성물을 제조하는 단계(단계 1);30-50% by weight of the organic resin of any one of an aqueous acrylic emulsion resin, a water-dispersed urethane resin or a water-soluble epoxy resin, 5-20% by weight of water, 30-50% by weight of silica sol, 0.1-0.5% by weight of nano silver , 0.1-1% by weight of antifoaming agent and 0.5-2% by weight of antimicrobial agent to prepare a coating layer composition (step 1);
수성 아크릴 에멀젼 수지, 수분산 우레탄 수지 또는 수용성 에폭시 수지 중 어느 하나의 유기물 수지 25~40중량%, 실리카졸 25~40중량%, 실리카 5~15중량%, 나노은(Nano Silver) 0.1~0.5중량%, 이산화티타늄(TiO2) 5~15중량%, 클레이(Clay) 5~10중량%, 아크릴계 증점제 1~5중량%, 소포제 0.1~1중량% 및 우레탄계 증점제 2~5중량%를 혼합하여 바탕층 도료 조성물을 제조하는 단계(단계 2); 및25-40% by weight of organic resin of any one of aqueous acrylic emulsion resin, water-dispersed urethane resin or water-soluble epoxy resin, 25-40% by weight of silica sol, 5-15% by weight of silica, 0.1-0.5% by weight of nano silver , 5-15 wt% of titanium dioxide (TiO 2 ), 5-10 wt% of clay, 1-5 wt% of acrylic thickener, 0.1-1 wt% of antifoaming agent, and 2-5 wt% of urethane thickener. Preparing a coating composition (step 2); And
수성 아크릴 에멀젼 수지, 수분산 우레탄 수지 또는 수용성 에폭시 수지 중 어느 하나의 유기물 수지 25~40중량%, 실리카졸 20~35중량%, 실리카 10~15중량%, 나노은(Nano Silver) 0.1~0.5중량%, 클레이(Clay) 5~10중량%, 아크릴계 증점제 2~10중량%, 소포제 0.1~1중량% 및 우레탄계 증점제 2~5중량%를 혼합하여 패턴층 도료 조성물을 제조하는 단계(단계 3);를 포함한다.
25-40% by weight of organic resin of any one of aqueous acrylic emulsion resin, water-dispersed urethane resin or water-soluble epoxy resin, 20-35% by weight silica sol, 10-15% by weight silica, 0.1-0.5% by weight nano silver 5 to 10 wt% of clay, 2 to 10 wt% of an acrylic thickener, 0.1 to 1 wt% of an antifoaming agent, and 2 to 5 wt% of a urethane thickener to prepare a pattern layer coating composition (Step 3); Include.
상기 하도층 도료 조성물은 피도면과의 부착력을 향상시키고 항균성을 보강하는 역할을 수행한다.
The undercoat coating composition serves to enhance adhesion to the surface to be coated and to reinforce antibacterial properties.
도막을 형성하는 유기질 바인더는 피도물의 종류에 따라 수성 아크릴 에멀젼 수지, 수분산 우레탄 수지 또는 수용성 에폭시 수지 중에서 어느 하나를 선택하여 사용할 수 있다.The organic binder which forms a coating film can select and use either an aqueous acrylic emulsion resin, a water-dispersible urethane resin, or a water-soluble epoxy resin according to the kind of to-be-processed object.
상기 수성 아크릴 에멀젼 수지는 도막을 형성하는 유기질 바인더로써, 함량이 높아지면 도료가 광택을 내게 되고, 무광도료로 사용할 경우에는 함량을 낮추게 된다.The aqueous acrylic emulsion resin is an organic binder for forming a coating film, the content is glossed when the content is high, and when used as a matte paint it is lowered.
상기 수분산 우레탄 수지는 우레탄 수지를 물에 분산시키는 기계적 특성이 우수하고, 고성능 도막을 형성하게 되며, 무황변 타입으로 내수성, 내약품성, 내가수분해 안정성을 좋게 한다.The water-dispersed urethane resin is excellent in mechanical properties to disperse the urethane resin in water, to form a high-performance coating film, yellowing type to improve the water resistance, chemical resistance, hydrolysis stability.
상기 수용성 에폭시 수지는 내약품성, 내수성, 내마모성 등의 성능을 좋게 하고, 냄새와 독성이 발생하지 않으며, 습한 도장면, 기존 수성도료면, 기타 도료면에도 우수한 접착력과 방수 효과를 갖게 한다.The water-soluble epoxy resin improves the performance of chemical resistance, water resistance, abrasion resistance, and the like, does not generate odors and toxicity, and has excellent adhesion and waterproof effects on wet paint surfaces, existing water-based paint surfaces, and other paint surfaces.
상기 유기물 수지는 30~50중량% 포함되는 것이 바람직하며, 30중량% 미만 포함되면 피도면과의 부착력이 미흡하며 내수성이 약해질 수 있고, 50중량% 초과 포함되면 강도가 약해지며 은폐력이 떨어져서 도장 작업시 시간이 많이 소요되는 문제가 있다.
The organic resin is preferably contained 30 to 50% by weight, if less than 30% by weight is insufficient adhesion to the coating and the water resistance may be weak, when contained more than 50% by weight the strength is weakened and the hiding power falls paint work There is a problem that takes a lot of time.
상기 실리카졸(Silica Sol)은 알콜과 실리카의 합성 후 암모니아로 수용화시켜 도막의 조밀성을 부여하는 저장 안정성이 우수한 실리카졸을 사용하는 것이 바람직하다. 본 발명에서 실리카졸은 도막의 경도와 강도를 향상시키고 도막의 조밀성을 강화시켜 내오염성을 향상시키기 위해 포함된다. 상기 실리카졸은 30~50중량% 포함되는 것이 바람직하며, 30중량% 미만 포함되면 도막의 강도와 경도가 약해져서 내스크래치성 및 내오염성이 미흡할 수 있고, 50중량% 초과 포함되면 도막이 너무 강해서 유리가 깨지듯이 도막이 깨지는 문제가 있다.
The silica sol is preferably used as the silica sol having excellent storage stability which is solubilized with ammonia after synthesis of alcohol and silica to impart the compactness of the coating film. Silica sol in the present invention is included to improve the hardness and strength of the coating film and to enhance the denseness of the coating film to improve the stain resistance. The silica sol is preferably contained 30 to 50% by weight, if less than 30% by weight of the coating film strength and hardness is weakened scratch resistance and stain resistance may be insufficient, when contained more than 50% by weight glass is too strong There is a problem that the film is broken.
상기 나노은(Nano Silver)은 항균성 부여를 위해 포함된다. 상기 은(Ag)의 델타플러스 이온이 미생물과 강력하고도 순간적인 결합을 하여 세포막을 파괴하고 세포를 교란시키며, 은(Ag)의 촉매작용을 통해 산소가 활성산소로 전환되어 항균 및 살균작용을 한다. 상기 나노은은 0.1~0.5중량% 포함되는 것이 바람직하며, 0.1중량% 미만 포함되면 항균 및 살균효과가 떨어지며, 0.5중량% 초과 포함되면 도료와의 상용성 문제가 있거나 변색의 문제가 있다.
The nano silver is included to impart antimicrobial properties. The delta plus ion of silver (Ag) strongly and instantaneously binds to microorganisms, destroying cell membranes and disturbing cells, and oxygen is converted into active oxygen through the catalytic action of silver (Ag) to perform antibacterial and bactericidal activity. do. The nano silver is preferably included 0.1 to 0.5% by weight, and less than 0.1% by weight of the antimicrobial and bactericidal effect is lowered, when contained in more than 0.5% by weight there is a compatibility problem with the paint or a problem of discoloration.
상기 소포제는 0.1~1중량% 포함되는 것이 바람직하며, 0.1중량% 미만 포함되면 기포 방지 효과가 떨어지고, 1중량% 초과 포함되면 습윤성이 떨어지고 불규칙한 도막이 생성될 수 있다.
The antifoaming agent is preferably included 0.1 to 1% by weight, if less than 0.1% by weight of the anti-foaming effect is reduced, when included in more than 1% by weight may be the wettability and irregular coating film can be produced.
상기 항균제는 상기 나노은(Nano Silver)과 함께 사용하면 도료의 자체 저장성이 향상되어 고가의 나노은의 사용함량을 절감시키면서도 항균성을 향상시킬 수 있으므로 0.5~2중량% 포함되는 것이 바람직하다.
When the antimicrobial agent is used together with the nano silver, the self-storage property of the paint is improved, and thus, the antimicrobial property may be improved while reducing the use amount of the expensive nano silver.
상기 바탕층 도료 조성물은 피도면을 은폐하는 효과와 원하는 색상을 발현하고 도막의 내후성을 향상시키는 역할을 수행한다.
The base layer coating composition serves to conceal the surface to be coated and the desired color and to improve the weather resistance of the coating film.
상기 실리카(Silica)는 도막의 강도를 향상시키기 위해 포함된다. 상기 실리카는 5~15중량% 포함되는 것이 바람직하며, 5중량% 미만 포함되면 도막의 강도가 미흡할 수 있고, 15중량% 초과 포함되면 은폐력이 떨어져서 피도물이 비치는 문제가 있다.
The silica is included to improve the strength of the coating film. The silica is preferably contained 5 to 15% by weight, if less than 5% by weight may be insufficient strength of the coating film, if included more than 15% by weight has a problem in that the cover is reflected off.
상기 이산화티타늄(TiO2)은 백색안료로서 은폐, 즉 피도물이 비치지 않고 깨끗한 상태를 유지하기 위해 포함된다. 상기 이산화티타늄은 5~15중량% 포함되는 것이 바람직하며, 5중량% 미만 포함되면 은폐가 충분하지 않아 피도면이 비칠 수 있고, 15중량% 초과 포함되면 도막의 접착력이 떨어지는 문제가 있다.
The titanium dioxide (TiO 2 ) is included as a white pigment to conceal, that is, to maintain a clean state without the coating. The titanium dioxide is preferably contained 5 to 15% by weight, if less than 5% by weight is not enough concealed to be coated surface, if more than 15% by weight there is a problem that the adhesion of the coating film is lowered.
상기 클레이(Clay)는 무기질 충진재로 도료의 점성을 올려주고 안료의 침강을 방지해주는 역할을 하기 위해 포함된다. 상기 클레이는 5~10중량% 포함되는 것이 바람직하며, 5중량% 미만 포함되면 점성이 너무 낮아 도장 작업시 도료가 흘러내릴 수 있고, 10중량% 초과 포함되면 점성이 너무 높아서 도장면이 깨끗하게 펴지지 않고, 붓 또는 로울러 자국이 보여서 미관상 보기 싫게 되는 문제가 있다.
The clay is included to increase the viscosity of the paint as an inorganic filler and to prevent the sedimentation of the pigment. The clay is preferably contained 5 to 10% by weight, if less than 5% by weight of the viscosity is too low, the paint can flow down during the painting work, if more than 10% by weight of the viscosity is too high so that the painted surface does not spread clean There is a problem that I can't see aesthetically because I see a brush, a roller or a roller mark.
상기 증점제는 도료의 유동성을 조절하기 위해 포함된다. 아크릴계 증점제는 1~5중량% 포함되며, 우레탄계 증점제는 2~5중량% 포함되는 것이 바람직하다.
The thickener is included to control the flowability of the paint. Acrylic thickener is contained 1 to 5% by weight, urethane-based thickener is preferably contained 2 to 5% by weight.
상기 바탕층 도료 조성물에 탄산칼슘(CaCO3) 2~5중량%가 추가적으로 포함될 수도 있다. 상기 탄산칼슘은 도료에서 충진재 역할, 즉 도료를 도장시 도막의 두께를 두껍게 하기 위하여 사용된다.
2-5% by weight of calcium carbonate (CaCO 3 ) may be additionally included in the base layer coating composition. The calcium carbonate is used as a filler in the paint, that is, to thicken the thickness of the coating film when painting the paint.
상기 단계 2 이후에, 상기 바탕층 도료 조성물에 착색안료를 혼합하는 단계가 추가될 수 있으며, 상기 착색안료는 색상을 부여함으로써 시각적 효과를 내기 위해 포함된다. 상기 바탕층 도료 조성물 100중량부에 대하여 착색안료 0.5~10중량부를 혼합하는 것이 바람직하며, 0.5중량부 미만 포함되면 색상을 발현하지 못하는 문제가 있으며, 10중량부 초과 포함되면 비경제적인 문제가 있다.
After the step 2, the step of mixing the pigment pigment in the base layer coating composition may be added, the pigment pigment is included to give a visual effect by giving a color. It is preferable to mix 0.5 to 10 parts by weight of the coloring pigment with respect to 100 parts by weight of the base layer coating composition, and if it is included less than 0.5 parts by weight, there is a problem in that the color is not expressed, and when it is included in an amount of more than 10 parts by weight, there is an uneconomic problem.
상기 패턴층 도료 조성물은 시각적으로 다채무늬 효과를 나타내는 역할을 수행한다.
The pattern layer coating composition visually plays a role of showing a colorful pattern effect.
상기 단계 3 이후에, 상기 패턴층 도료 조성물에 착색안료를 혼합하는 단계가 추가될 수 있으며, 상기 패턴층 도료 조성물에 포함되는 착색안료는 상기 바탕층 도료 조성물에 포함되는 착색안료의 색상과 다른 색상을 사용하는 것이 바람직하다. 상기 패턴층 도료 조성물 100중량부에 대하여 착색안료 0.5~10중량부를 혼합하는 것이 바람직하며, 0.5중량부 미만 포함되면 다채무늬 색상이 발현되지 못하는 문제가 있으며, 10중량부 초과 포함되면 다채무늬의 심미감이 떨어지는 문제가 있다.
After the step 3, the step of mixing the coloring pigment in the pattern layer coating composition may be added, the coloring pigment included in the pattern layer coating composition is different from the color of the coloring pigment included in the base layer coating composition Preference is given to using. It is preferable to mix 0.5 to 10 parts by weight of the colored pigment with respect to 100 parts by weight of the pattern layer coating composition, and if less than 0.5 parts by weight, the color pattern color may not be expressed. There is a problem of falling.
본 발명의 일 실시예로, 상기 바탕층 도료 조성물을 백색으로 도장한 후에, 상기 패턴층 도료 조성물을 흑색, 구형으로 도장하게 되면 화강석과 같은 모양의 질감을 얻을 수 있다.
In one embodiment of the present invention, after the base layer coating composition is painted in white, when the pattern layer coating composition is painted in black and spherical shape, a texture like granite can be obtained.
상기 패턴층 도료 조성물은 한번에 1가지 색상으로 도장할 수도 있고, 한번에 2가지 색상으로 도장할 수도 있다. The pattern layer coating composition may be painted in one color at a time, or may be painted in two colors at a time.
상기 패턴층 도료 조성물을 한번에 1가지 색상으로 도장한 다채무늬 도료를 도 1에 나타내었으며, 패턴층 도료 조성물을 한번에 2가지 색상으로 도장한 다채무늬 도료를 도 2에 나타내었다.
The multi-pattern paint coating the pattern layer coating composition in one color at a time is shown in FIG. 1, and the multi-pattern paint coating the pattern layer coating composition in two colors at a time is shown in FIG. 2.
또한, 본 발명은 상기 제조방법으로 제조된 항균성, 내오염성, 내스크래치성 및 내황변성이 우수한 다채무늬 도료 조성물을 제공한다.
In addition, the present invention provides a multi-pattern coating composition excellent in antimicrobial, stain resistance, scratch resistance and yellowing resistance prepared by the above production method.
본 발명의 항균성, 내오염성, 내스크래치성 및 내황변성이 우수한 다채무늬 도료 조성물은 콘크리트 미장면, 목재, 철재, MDF(medium density fiberboard), 석고보드 등의 건축자재에 접착성이 매우 뛰어난 장점이 있다.
The multi-pattern paint composition having excellent antimicrobial, staining, scratch and yellowing resistance of the present invention has the advantage of excellent adhesion to building materials such as concrete plastering surface, wood, steel, medium density fiberboard (MDF), gypsum board, etc. have.
또한, 본 발명의 항균성, 내오염성, 내스크래치성 및 내황변성이 우수한 다채무늬 도료 조성물은 학교, 학원, 유치원 등의 교육시설, 군부대, 기숙사 등의 집단이용시설, 관공서, 호텔, 아파트 등의 내부공간, 병원, 보건소, 약국 등의 세균이 우려되는 공간, 제약공장, 식품공장, 식당 등의 청결을 요구하는 공간에 다채무늬 도료로 유용하게 사용될 수 있다.
In addition, the antimicrobial, fouling resistance, scratch resistance and yellowing resistance of the multi-colored coating composition of the present invention is used in educational facilities such as schools, academies, kindergartens, military units, dormitories, etc. It can be usefully used as a colorful pattern paint in spaces, hospitals, public health centers, pharmacies, etc., spaces that require cleanliness, pharmaceutical factories, food factories, restaurants.
다음은 본 발명에 따른 항균성, 내오염성, 내스크래치성 및 내황변성이 우수한 다채무늬 도료 조성물을 이용한 다채무늬 도막 형성 방법을 설명한다.
The following describes a method for forming a multicolored coating film using a multicolored coating composition having excellent antimicrobial, staining resistance, scratch resistance and yellowing resistance according to the present invention.
본 발명의 다채무늬 도료 조성물을 이용한 다채무늬 도막 형성 방법은,The colorful pattern coating film formation method using the colorful pattern coating composition of this invention,
피도면의 표면 처리 단계(S1);Surface treatment step S1 of the surface to be coated;
상기 피도면에 상기 하도층 도료 조성물을 도장하는 단계(S2);Painting the undercoat composition on the surface to be coated (S2);
상기 하도층 도장된 도막을 경화시키는 단계(S3);Curing the undercoat coated film (S3);
상기 하도층 도장된 도막 위에 상기 바탕층 도료 조성물을 도장하는 단계(S4);Painting the base layer coating composition on the bottom coat layer (S4);
상기 바탕층 도장된 도막을 경화시키는 단계(S5);Curing the base layer coated coating film (S5);
상기 바탕층 도장된 도막 위에 상기 패턴층 도료 조성물을 도장하는 단계(S6); 및Painting the pattern layer coating composition on the base layer coated film (S6); And
상기 패턴층 도장된 도막을 경화시키는 단계(S7);Curing the coating layer coated with the pattern layer (S7);
를 포함한다.
It includes.
상기 S1은 피도면의 오염물질을 깨끗이 제거한 후, 건조시키는 단계이다. 도장시 함수율 8% 이하에서, pH 7~9에서 도장하는 것이 바람직하다. 신축 건물의 시멘트는 25℃, 습도 50%를 기준으로 28일 이상 양생시킨 후 도장하는 것이 바람직하다.
The S1 is a step of drying after removing the contaminants on the surface to be cleaned. It is preferable to apply | coat at pH 7-9 at water content of 8% or less at the time of coating. Cement of new buildings is preferably coated after curing for at least 28 days based on 25 ℃, 50% humidity.
상기 S2는 상기 오염물질이 제거된 피도면에 상기 하도층 도료 조성물을 로울러 또는 붓을 이용하여 10~20㎛의 두께로 도장하는 단계이며, 투명 상태의 도막이 형성된다. 상기 하도층 도료 조성물에 포함되어 있는 실리케이트 입자들이 시멘트와 반응하여 미세한 기공을 메워 빗물의 침투를 방지하는 방수효과가 우수하게 된다.
The S2 is a step of coating the undercoat coating composition to a thickness of 10 ~ 20㎛ by using a roller or a brush on the to-be-painted to-be-painted surface, a transparent film is formed. The silicate particles contained in the undercoat composition react with cement to fill the fine pores, thereby preventing the rainwater from penetrating.
상기 S3은 하도층 도장된 도막을 4~50℃에서 5~24시간 동안 경화시키는 단계이다.
The S3 is a step of curing the undercoat coating film at 4 ~ 50 ℃ for 5 to 24 hours.
상기 S4는 하도층 도장된 도막 위에 상기 바탕층 도료 조성물을 로울러, 붓 또는 스프레이를 이용하여 15~30㎛의 두께로 도장하는 단계이다.
The S4 is a step of coating the base layer coating composition on the coating layer coated with a coating layer to a thickness of 15 ~ 30㎛ using a brush or a spray.
상기 S5는 바탕층 도장된 도막을 4~50℃에서 5~24시간 동안 경화시키는 단계이다.
S5 is a step of curing the base layer coated coating film for 5 to 24 hours at 4 ~ 50 ℃.
상기 S6은 바탕층 도장된 도막 위에 상기 패턴층 도료 조성물을 스프레이를 이용하여 50~150㎛의 두께로 도장하는 단계이다. 상기 패턴층은 전체를 도장하는 것이 아니므로 입체감 있는 질감을 구현하기 위하여 본타일 건, 무늬코트 건 등 스프레이 건으로 도장하는 것이 바람직하다.
The S6 is a step of coating the pattern layer coating composition to a thickness of 50 ~ 150㎛ using a spray on the base layer painted coating. Since the pattern layer is not to paint the whole, it is preferable to paint with a spray gun such as a bone tile gun and a pattern coat gun in order to realize a three-dimensional texture.
상기 S7은 패턴층 도장된 도막을 4~50℃에서 5~24시간 동안 경화시키는 단계이다.
The S7 is a step of curing the coating film coated with a pattern layer for 5 to 24 hours at 4 ~ 50 ℃.
이하, 실시 예를 통하여 본 발명의 구성 및 효과를 더욱 상세히 설명하고자 한다. 이들 실시 예는 오로지 본 발명을 예시하기 위한 것일 뿐 본 발명의 범위가 이들 실시 예에 의해 제한되는 것은 아니다.
Hereinafter, the configuration and effects of the present invention through the embodiments will be described in more detail. These examples are only for illustrating the present invention, but the scope of the present invention is not limited by these examples.
수성 아크릴 에멀젼 수지 45g, 물 10g, 실리카졸 42g, 나노은(Nano Silver) 0.3g, 소포제 0.7g 및 항균제 2g 을 혼합하고 500rpm 으로 1시간 동안 교반하여 하도층 도료 조성물을 제조하였다.45 g of an aqueous acrylic emulsion resin, 10 g of water, 42 g of silica sol, 0.3 g of Nano Silver, 0.7 g of an antifoaming agent, and 2 g of an antibacterial agent were mixed and stirred at 500 rpm for 1 hour to prepare an undercoat composition.
수성 아크릴 에멀젼 수지 35g, 실리카졸 30g, 실리카 10g, 나노은(Nano Silver) 0.3g, 이산화티타늄(TiO2) 10g, 클레이(Clay) 8g, 아크릴계 증점제 3g, 소포제 0.7g, 우레탄계 증점제 3g 및 연한 갈색의 착색안료 5g을 혼합하고 2,000rpm 으로 3시간 동안 교반하여 바탕층 도료 조성물을 제조하였다. 35 g of aqueous acrylic emulsion resin, 30 g of silica sol, 10 g of silica, 0.3 g of nano silver, 10 g of titanium dioxide (TiO 2 ), 8 g of clay, 3 g of acrylic thickener, 0.7 g of defoaming agent, 3 g of urethane thickener, and light brown 5g of the coloring pigment was mixed and stirred at 2,000 rpm for 3 hours to prepare a base layer coating composition.
수성 아크릴 에멀젼 수지 35g, 실리카졸 30g, 실리카 15g, 나노은(Nano Silver) 0.3g, 클레이(Clay) 8g, 아크릴계 증점제 8g, 소포제 0.7g, 우레탄계 증점제 3g 및 베이지색의 착색안료 5g을 혼합하고 2,000rpm 으로 3시간 동안 교반하여 패턴층 도료 조성물을 제조하였다.
35 g of aqueous acrylic emulsion resin, 30 g of silica sol, 15 g of silica, 0.3 g of nano silver, 8 g of clay, 8 g of acrylic thickener, 0.7 g of antifoaming agent, 3 g of urethane thickener, and 5 g of colored pigment pigment were mixed and 2,000 rpm By stirring for 3 hours to prepare a pattern layer coating composition.
[비교예 1]Comparative Example 1
K 사의 수성페인트(내부 1급)을 구입하였다.
K water-based paint (internal grade 1) was purchased.
[비교예 2]Comparative Example 2
D 사의 수성페인트(외부 1급)을 구입하였다.
D water-based paint (external grade 1) was purchased.
[비교예 3]Comparative Example 3
K 사의 유성페인트(락카무광)을 구입하였다.
K oil paint (Lackka matte) was purchased.
[비교예 4][Comparative Example 4]
S 사의 유성페인트(코팅제)를 구입하였다.
The oil paint (coating agent) of S company was purchased.
[실험예 1]Experimental Example 1
MDF 판넬 위에 실시예 1에서 제조한 하도층 도료 조성물을 로울러를 이용하여 10㎛의 두께로 도포한 후, 20℃에서 10시간 동안 자연 경화시켰다. 상기 하도층 도장된 도막 위에 실시예 1에서 제조한 바탕층 도료 조성물을 로울러를 이용하여 25㎛의 두께로 도포한 후, 20℃에서 24시간 동안 자연 경화시켰다. 상기 바탕층 도장된 도막 위에 실시예 1에서 제조한 패턴층 도료 조성물을 스프레이를 이용하여 150㎛의 두께로 도포한 후, 20℃에서 24시간 동안 자연 경화시켜 본 발명의 시험용 시편을 제작하였다.The undercoat coating composition prepared in Example 1 on the MDF panel was applied to a thickness of 10㎛ using a roller, and then naturally cured at 20 ℃ for 10 hours. The base layer coating composition prepared in Example 1 was applied on the undercoating coating film to a thickness of 25 μm using a roller, and then naturally cured at 20 ° C. for 24 hours. The coating layer coating composition prepared in Example 1 was applied on the base layer coated coating film to a thickness of 150 μm using a spray, and then spontaneously cured at 20 ° C. for 24 hours to prepare a test specimen of the present invention.
MDF 판넬 위에 비교예 1의 K 사의 수성페인트(내부 1급)을 25㎛의 두께로 도포한 후, 20℃에서 24시간 동안 경화시켜 비교용 시편을 제작하였다.Aqueous paint (internal grade 1) of K Company of Comparative Example 1 was applied on an MDF panel at a thickness of 25 μm, and cured at 20 ° C. for 24 hours to prepare a comparative specimen.
MDF 판넬 위에 비교예 2의 D 사의 수성페인트(외부 1급)을 25㎛의 두께로 도포한 후, 20℃에서 24시간 동안 경화시켜 비교용 시편을 제작하였다.Aqueous paint (outer grade 1) of D Company of Comparative Example 2 was applied on an MDF panel at a thickness of 25 μm, and cured at 20 ° C. for 24 hours to prepare a comparative specimen.
MDF 판넬 위에 비교예 3의 K 사의 유성페인트(락카무광)을 25㎛의 두께로 도포한 후, 20℃에서 24시간 동안 경화시켜 비교용 시편을 제작하였다.On the MDF panel, the oil paint (lacca matte) of K Company of Comparative Example 3 was applied at a thickness of 25 μm, and cured at 20 ° C. for 24 hours to prepare a comparative specimen.
MDF 판넬 위에 비교예 4의 S 사의 유성페인트(코팅제)를 25㎛의 두께로 도포한 후, 20℃에서 24시간 동안 경화시켜 비교용 시편을 제작하였다.
The oil paint (coating agent) of S Company of Comparative Example 4 was applied on the MDF panel at a thickness of 25 μm, and cured at 20 ° C. for 24 hours to prepare a comparative specimen.
이들 각 시편에 대해 내황변성, 표면 경도, 내오염성, 오염 제거성, 내스크래치성, 항균성을 실험하여 그 결과를 표 1에 나타내었다.
For each of these specimens, the yellowing resistance, surface hardness, contamination resistance, decontamination resistance, scratch resistance, and antimicrobial resistance were tested and the results are shown in Table 1.
내황변성 시험은 QUV×7일 방치 후 변색(황변) 여부를 관찰하였다.The yellowing resistance test was observed for discoloration (yellowing) after QUV × 7 days left.
표면 경도 시험은 JIS K-5400의 연필 경도법을 사용하였다. 연필 경도 시험기를 사용하여 건조된 도막에 연필의 종류별로 45°각도로 그었을 때의 긁힘 정도를 육안으로 판정하였다.The surface hardness test used the pencil hardness method of JISK-5400. The degree of scratches when the dried coating film was drawn at a 45 ° angle for each kind of pencil was visually determined using a pencil hardness tester.
내오염성 시험은 미네랄 스피리트에 흑색의 카본을 20%로 분산시킨 용액을 제조하여 시편에 스프레이 한 후 80±2℃, 5시간 침적 건조시킨 후 물 세척 실험을 통하여 물 세척 전후의 명도지수차로 판정하였다.The pollution resistance test was performed by preparing a solution in which black carbon was dispersed at 20% in mineral spirits, spraying the specimen, and drying it for 80 hours at 80 ± 2 ° C. .
오염 제거성 시험은 도료 건조 도막을 수성 싸인펜, 유성 매직, 크레용에 의해 오염시킨 후 일정시간 경과 후에 에탄올과 물을 1:1로 희석한 희석액에 적신 헝겊으로 10회 문질러서 오염 제거 정도를 측정하였다.The decontamination test measured the degree of decontamination by rubbing the paint dry coating film with an aqueous sign pen, oil magic, and crayons after a certain time and rubbing 10 times with a cloth soaked in a diluted solution of ethanol and water 1: 1.
내스크래치성 시험은 500g 하중의 사파이어 침으로 그어 표면의 긁힘을 관찰하였다.
The scratch resistance test was carried out with a 500 g load of sapphire needle to observe the surface scratches.
제거성
pollution
Removability
표 1에 나타낸 바와 같이, 실시예 1의 다채무늬 조성물을 코팅한 시편은 내황변성, 표면 경도, 내오염성, 오염 제거성, 내스크래치성 및 항균성이 매우 뛰어난 것을 확인할 수 있다.
As shown in Table 1, it can be confirmed that the specimen coated with the multi-pattern composition of Example 1 is very excellent in yellowing resistance, surface hardness, stain resistance, decontamination, scratch resistance and antibacterial properties.
[비교예 5][Comparative Example 5]
실시예 1에서, 나노은 및 항균제를 포함시키지 않고 나노은 및 항균제의 함량 만큼 수성 아크릴 에멀젼 수지의 함량을 더하여, 도료 조성물을 제조하였다.
In Example 1, the coating composition was prepared by adding the content of the aqueous acrylic emulsion resin by the content of the nanosilver and the antimicrobial agent without including the nanosilver and the antimicrobial agent.
[실험예 2]Experimental Example 2
실시예 1 및 비교예 5에서 제조한 도료 조성물의 항균성을 평가하기 위하여, 실험예 1과 같이 도장한 시편을 한국화학융합시험연구원에 의뢰하였다. In order to evaluate the antimicrobial properties of the coating compositions prepared in Example 1 and Comparative Example 5, the specimen coated in the same manner as in Experiment 1 was commissioned by the Korea Institute of Chemical Fusion Testing.
시험물질의 항균효과를 평가하기 위해 Japanese Industrial Standards Z 2801 항균가공제품-항균성 시험방법-항균효과 (JIS Z 2801)의 필름밀착법에 따라 그람 음성균인 대장균(Escherichia coli)과 그람 양성균인 황색포도상구균(Staphylococcus aureus)을 이용하여 시험을 실시하였다.Japanese Industrial Standards Z 2801 to evaluate the antimicrobial activity of the test substance antibacterial products - Antimicrobial Test Methods - gram negative E. coli in accordance with the film adhesion method of the antimicrobial activity (JIS Z 2801) (Escherichia coli ) and Gram-positive bacteria Staphylococcus aureus ) was used to test.
시험균을 접종 후 모든 시편은 35±1℃, 상대습도 90%이상에서 24±1시간 배양하였고 이후 각 시편에서 균을 회수하여 생균수를 측정하였다.After inoculation, all specimens were incubated for 24 ± 1 hours at 35 ± 1 ° C and 90% relative humidity. Afterwards, bacteria were collected from each specimen and the number of viable cells was measured.
항균활성치(R)은 아래 계산식에 의해 계산하였다.Antimicrobial activity value (R) was calculated by the following formula.
항균활성치(R)= [log(B/A)/log(C/A)] = [log(B/C)]Antimicrobial activity (R) = [log (B / A) / log (C / A)] = [log (B / C)]
상기 식에서 A : 무가공 시편의 접종직후의 생균수의 평균치Where A is the average number of viable cells immediately after inoculation of the raw specimens
B : 무가공 시편의 24시간 후의 생균수의 평균치 B: Average number of viable cells after 24 hours of unprocessed specimens
C : 항균가공 시편의 24시간 후의 생균수의 평균치 C: Mean value of viable cell count after 24 hours of antimicrobial test specimen
상기 시험 조건하에서, 항균 효과를 알아본 결과를 표 2에 나타내었다.Under the test conditions, the results of examining the antimicrobial effect are shown in Table 2.
(비교예 5)Raw specimens
(Comparative Example 5)
1.2×105
1.2 × 10 5
(실시예 1)Antibacterial Specimen
(Example 1)
(비교예 5)Raw specimens
(Comparative Example 5)
1.4×105
1.4 × 10 5
(실시예 1)Antibacterial Specimen
(Example 1)
항균활성치 1 이상 : 항균효과 90.00% 이상Antibacterial activity 1 or more: Antibacterial effect 90.00% or more
항균활성치 2 이상 : 항균효과 99.00% 이상Antimicrobial activity level 2 or more: Antibacterial effect 99.00% or more
항균활성치 3 이상 : 항균효과 99.90% 이상Antimicrobial activity level above 3: Antibacterial effect above 99.90%
항균활성치 4 이상 : 항균효과 99.99% 이상
Antimicrobial Activity Level 4 or higher: Antimicrobial Effect 99.99% or higher
표 2를 보면, 실시예 1의 도료 조성물을 도장한 시편은 대장균의 항균활성치는 3.4로서 항균효과가 99.90% 이상, 황색포도상구균의 항균활성치는 1.8로서 항균효과가 90.00% 이상으로서, 항균력이 우수한 것이 확인할 수 있다.Table 2 shows that the specimen coated with the coating composition of Example 1 had an antimicrobial activity of 3.4. The antimicrobial activity was above 99.90%, and the antimicrobial activity of the Staphylococcus aureus was 1.8 and the antibacterial effect was above 90.00%. It can be confirmed.
Claims (7)
수성 아크릴 에멀젼 수지, 수분산 우레탄 수지 또는 수용성 에폭시 수지 중 어느 하나의 유기물 수지 25~40중량%, 실리카졸 25~40중량%, 실리카 5~15중량%, 나노은(Nano Silver) 0.1~0.5중량%, 이산화티타늄(TiO2) 5~15중량%, 클레이(Clay) 5~10중량%, 아크릴계 증점제 1~5중량%, 소포제 0.1~1중량% 및 우레탄계 증점제 2~5중량%를 혼합하여 바탕층 도료 조성물을 제조하는 단계(단계 2); 및
수성 아크릴 에멀젼 수지, 수분산 우레탄 수지 또는 수용성 에폭시 수지 중 어느 하나의 유기물 수지 25~40중량%, 실리카졸 20~35중량%, 실리카 10~15중량%, 나노은(Nano Silver) 0.1~0.5중량%, 클레이(Clay) 5~10중량%, 아크릴계 증점제 2~10중량%, 소포제 0.1~1중량% 및 우레탄계 증점제 2~5중량%를 혼합하여 패턴층 도료 조성물을 제조하는 단계(단계 3);
를 포함하는 것을 특징으로 하는 항균성, 내오염성, 내스크래치성 및 내황변성이 우수한 다채무늬 도료 조성물의 제조방법.
30-50% by weight of the organic resin of any one of an aqueous acrylic emulsion resin, a water-dispersed urethane resin or a water-soluble epoxy resin, 5-20% by weight of water, 30-50% by weight of silica sol, 0.1-0.5% by weight of nano silver , 0.1-1% by weight of antifoaming agent and 0.5-2% by weight of antimicrobial agent to prepare a coating layer composition (step 1);
25-40% by weight of organic resin of any one of aqueous acrylic emulsion resin, water-dispersed urethane resin or water-soluble epoxy resin, 25-40% by weight of silica sol, 5-15% by weight of silica, 0.1-0.5% by weight of nano silver , 5-15 wt% of titanium dioxide (TiO 2 ), 5-10 wt% of clay, 1-5 wt% of acrylic thickener, 0.1-1 wt% of antifoaming agent, and 2-5 wt% of urethane thickener. Preparing a coating composition (step 2); And
25-40% by weight of organic resin of any one of aqueous acrylic emulsion resin, water-dispersed urethane resin or water-soluble epoxy resin, 20-35% by weight silica sol, 10-15% by weight silica, 0.1-0.5% by weight nano silver Preparing a pattern layer coating composition by mixing 5-10 wt% of clay, 2-10 wt% of an acrylic thickener, 0.1-1 wt% of an antifoaming agent, and 2-5 wt% of a urethane thickener;
Antimicrobial, fouling resistance, scratch resistance and yellowing resistance excellent method for producing a multicolored coating composition comprising a.
탄산칼슘(CaCO3) 2~5중량%가 추가적으로 포함되는 것을 특징으로 하는 항균성, 내오염성, 내스크래치성 및 내황변성이 우수한 다채무늬 도료 조성물의 제조방법.
The method of claim 1, wherein in step 2,
Calcium carbonate (CaCO 3 ) 2 to 5% by weight of the antimicrobial, stain resistance, scratch resistance and yellowing resistance excellent method for producing a multi-colored coating composition characterized in that it further comprises.
상기 바탕층 도료 조성물 100중량부에 대하여 착색안료 0.5~10중량부를 혼합하는 단계;
가 추가되는 것을 특징으로 하는 항균성, 내오염성, 내스크래치성 및 내황변성이 우수한 다채무늬 도료 조성물의 제조방법.
The method of claim 1, wherein after Step 2,
Mixing 0.5-10 parts by weight of the colored pigment with respect to 100 parts by weight of the base layer coating composition;
Method for producing a multi-colored coating composition excellent in antibacterial, stain resistance, scratch resistance and yellowing resistance, characterized in that the addition.
상기 패턴층 도료 조성물 100중량부에 대하여 착색안료 0.5~10중량부를 혼합하는 단계; 가 추가되되,
상기 패턴층 도료 조성물에 포함되는 착색안료는 상기 바탕층 도료 조성물에 포함되는 착색안료와 서로 다른 색상인 것을 특징으로 하는 항균성, 내오염성, 내스크래치성 및 내황변성이 우수한 다채무늬 도료 조성물의 제조방법.
The method of claim 3, wherein after Step 3,
Mixing 0.5-10 parts by weight of the colored pigment with respect to 100 parts by weight of the pattern layer coating composition; Is added,
The colored pigment included in the pattern layer paint composition is a different method from the colored pigment included in the base layer paint composition, characterized in that the antimicrobial, stain resistance, scratch resistance and yellowing resistance excellent multi-colored coating composition manufacturing method .
The multi-patterned coating composition excellent in antimicrobial, stain resistance, scratch resistance and yellowing resistance, which is prepared by the method according to any one of claims 1 to 4.
상기 피도면에 제 1항의 하도층 도료 조성물을 도장하는 단계(S2);
상기 하도층 도장된 도막을 경화시키는 단계(S3);
상기 하도층 도장된 도막 위에 제 1항의 바탕층 도료 조성물을 도장하는 단계(S4);
상기 바탕층 도장된 도막을 경화시키는 단계(S5);
상기 바탕층 도장된 도막 위에 제 1항의 패턴층 도료 조성물을 도장하는 단계(S6); 및
상기 패턴층 도장된 도막을 경화시키는 단계(S7);
를 포함하는 것을 특징으로 하는 항균성, 내오염성, 내스크래치성 및 내황변성이 우수한 다채무늬 도료 조성물을 이용한 다채무늬 도막 형성 방법.
Surface treatment step S1 of the surface to be coated;
Painting the undercoat composition of claim 1 on the surface to be coated (S2);
Curing the undercoat coated film (S3);
Painting the base layer coating composition of claim 1 on the undercoat;
Curing the base layer coated coating film (S5);
Coating the pattern layer coating composition of claim 1 on the base layer coated film (S6); And
Curing the coating layer coated with the pattern layer (S7);
Method of forming a multi-colored coating film using a multi-colored coating composition excellent in antimicrobial, stain resistance, scratch resistance and yellowing resistance comprising a.
상기 S2 에서, 하도층 도료 조성물은 로울러 또는 붓을 이용하여 10~20㎛의 두께로 도장하며, 상기 S4 에서, 바탕층 도료 조성물은 로울러, 붓 또는 스프레이를 이용하여 15~30㎛의 두께로 도장하며, 상기 S6 에서, 패턴층 도료 조성물은 스프레이를 이용하여 50~150㎛의 두께로 도장하는 것을 특징으로 하는 항균성, 내오염성, 내스크래치성 및 내황변성이 우수한 다채무늬 도료 조성물을 이용한 다채무늬 도막 형성 방법.The method of claim 6,
In S2, the undercoat coating composition is coated with a thickness of 10 to 20㎛ using a roller or a brush, and in S4, the undercoat coating composition is painted with a thickness of 15 to 30㎛ using a roller, a brush or a spray. In the S6, the pattern layer coating composition is a multi-pattern coating film using a colorful pattern coating composition excellent in antimicrobial, stain resistance, scratch resistance and yellowing resistance, characterized in that the coating with a thickness of 50 ~ 150㎛ Forming method.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100478530B1 (en) | 2004-07-14 | 2005-03-29 | 무한금강고려건재유한공사 | The aqueous multi-colors coating composition for construction |
| KR100541628B1 (en) | 2003-09-04 | 2006-01-10 | 박성수 | Emulsion Droplet Colorful Pattern Coating Composition |
| KR100854445B1 (en) | 2007-03-20 | 2008-08-27 | (주)피티케이 | Manufacturing method of emulsion water droplet-type colorful pattern coating composition for granite pattern forming and emulsion water droplet-type colorful pattern coating composition prepared by the method |
| KR100901141B1 (en) | 2009-02-12 | 2009-06-04 | 삼한건업(주) | Functional Water-Based Paints-Drop-Type Multi-Pattern Paint Compositions and Manufacturing Methods Thereof |
-
2011
- 2011-03-15 KR KR1020110023006A patent/KR101037333B1/en active IP Right Grant
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100541628B1 (en) | 2003-09-04 | 2006-01-10 | 박성수 | Emulsion Droplet Colorful Pattern Coating Composition |
| KR100478530B1 (en) | 2004-07-14 | 2005-03-29 | 무한금강고려건재유한공사 | The aqueous multi-colors coating composition for construction |
| KR100854445B1 (en) | 2007-03-20 | 2008-08-27 | (주)피티케이 | Manufacturing method of emulsion water droplet-type colorful pattern coating composition for granite pattern forming and emulsion water droplet-type colorful pattern coating composition prepared by the method |
| KR100901141B1 (en) | 2009-02-12 | 2009-06-04 | 삼한건업(주) | Functional Water-Based Paints-Drop-Type Multi-Pattern Paint Compositions and Manufacturing Methods Thereof |
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