KR100692100B1 - Hair dye composition for oxidation dyeing of keratin fibers - Google Patents
Hair dye composition for oxidation dyeing of keratin fibers Download PDFInfo
- Publication number
- KR100692100B1 KR100692100B1 KR1020060029434A KR20060029434A KR100692100B1 KR 100692100 B1 KR100692100 B1 KR 100692100B1 KR 1020060029434 A KR1020060029434 A KR 1020060029434A KR 20060029434 A KR20060029434 A KR 20060029434A KR 100692100 B1 KR100692100 B1 KR 100692100B1
- Authority
- KR
- South Korea
- Prior art keywords
- formula
- group
- carbon atoms
- composition
- alkyl group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims abstract description 55
- 238000004043 dyeing Methods 0.000 title claims abstract description 21
- 239000000118 hair dye Substances 0.000 title claims abstract description 14
- 102000011782 Keratins Human genes 0.000 title claims abstract description 6
- 108010076876 Keratins Proteins 0.000 title claims abstract description 6
- 239000000835 fiber Substances 0.000 title claims abstract description 6
- 238000007254 oxidation reaction Methods 0.000 title abstract description 24
- 230000003647 oxidation Effects 0.000 title abstract description 20
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 32
- 239000010452 phosphate Substances 0.000 claims abstract description 32
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 27
- 239000004094 surface-active agent Substances 0.000 claims abstract description 27
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 22
- 229920006317 cationic polymer Polymers 0.000 claims abstract description 20
- 230000003750 conditioning effect Effects 0.000 claims abstract description 18
- 238000011161 development Methods 0.000 claims abstract description 14
- 125000004432 carbon atom Chemical group C* 0.000 claims description 23
- 125000000217 alkyl group Chemical group 0.000 claims description 16
- -1 alkyl phosphate esters Chemical class 0.000 claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 14
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 150000007522 mineralic acids Chemical class 0.000 claims description 6
- 150000007524 organic acids Chemical class 0.000 claims description 6
- 229920006395 saturated elastomer Polymers 0.000 claims description 6
- 125000004417 unsaturated alkyl group Chemical group 0.000 claims description 6
- 230000001590 oxidative effect Effects 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 4
- 150000001450 anions Chemical class 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- NAWXUBYGYWOOIX-SFHVURJKSA-N (2s)-2-[[4-[2-(2,4-diaminoquinazolin-6-yl)ethyl]benzoyl]amino]-4-methylidenepentanedioic acid Chemical compound C1=CC2=NC(N)=NC(N)=C2C=C1CCC1=CC=C(C(=O)N[C@@H](CC(=C)C(O)=O)C(O)=O)C=C1 NAWXUBYGYWOOIX-SFHVURJKSA-N 0.000 claims description 2
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 2
- 238000007792 addition Methods 0.000 claims description 2
- 125000003282 alkyl amino group Chemical group 0.000 claims description 2
- 150000001408 amides Chemical class 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 claims description 2
- 125000004185 ester group Chemical group 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 125000002757 morpholinyl group Chemical group 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 2
- 125000003386 piperidinyl group Chemical group 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 2
- 150000003457 sulfones Chemical class 0.000 claims description 2
- 150000003462 sulfoxides Chemical class 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 125000004434 sulfur atom Chemical group 0.000 claims description 2
- 125000004122 cyclic group Chemical group 0.000 claims 1
- 125000005842 heteroatom Chemical group 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 239000000975 dye Substances 0.000 abstract description 29
- 230000035515 penetration Effects 0.000 abstract description 6
- 238000001179 sorption measurement Methods 0.000 abstract description 5
- 238000002845 discoloration Methods 0.000 abstract description 2
- 230000001737 promoting effect Effects 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 27
- 239000002243 precursor Substances 0.000 description 13
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 7
- 230000006866 deterioration Effects 0.000 description 6
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 6
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 150000001767 cationic compounds Chemical class 0.000 description 5
- 239000007800 oxidant agent Substances 0.000 description 5
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000006482 condensation reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000003700 hair damage Effects 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-araboascorbic acid Natural products OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 235000019482 Palm oil Nutrition 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000004318 erythorbic acid Substances 0.000 description 3
- 235000010350 erythorbic acid Nutrition 0.000 description 3
- 229940026239 isoascorbic acid Drugs 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002540 palm oil Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 235000010265 sodium sulphite Nutrition 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- UFPKLWVNKAMAPE-UHFFFAOYSA-N (4-aminophenyl)azanium;hydrogen sulfate Chemical compound OS(O)(=O)=O.NC1=CC=C(N)C=C1 UFPKLWVNKAMAPE-UHFFFAOYSA-N 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 2
- OBCSAIDCZQSFQH-UHFFFAOYSA-N 2-methyl-1,4-phenylenediamine Chemical compound CC1=CC(N)=CC=C1N OBCSAIDCZQSFQH-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- 229940018563 3-aminophenol Drugs 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000003113 alkalizing effect Effects 0.000 description 2
- 229920006318 anionic polymer Polymers 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 229940081733 cetearyl alcohol Drugs 0.000 description 2
- RNPXCFINMKSQPQ-UHFFFAOYSA-N dicetyl hydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCOP(O)(=O)OCCCCCCCCCCCCCCCC RNPXCFINMKSQPQ-UHFFFAOYSA-N 0.000 description 2
- 229940093541 dicetylphosphate Drugs 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000982 direct dye Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- UBHWBODXJBSFLH-UHFFFAOYSA-N hexadecan-1-ol;octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO.CCCCCCCCCCCCCCCCCCO UBHWBODXJBSFLH-UHFFFAOYSA-N 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 239000002453 shampoo Substances 0.000 description 2
- 239000011734 sodium Chemical group 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- QIJRTFXNRTXDIP-UHFFFAOYSA-N (1-carboxy-2-sulfanylethyl)azanium;chloride;hydrate Chemical compound O.Cl.SCC(N)C(O)=O QIJRTFXNRTXDIP-UHFFFAOYSA-N 0.000 description 1
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- 229940113490 2,4-diaminophenoxyethanol hydrochloride Drugs 0.000 description 1
- KZTWOUOZKZQDMN-UHFFFAOYSA-N 2,5-diaminotoluene sulfate Chemical compound OS(O)(=O)=O.CC1=CC(N)=CC=C1N KZTWOUOZKZQDMN-UHFFFAOYSA-N 0.000 description 1
- PBVFDMZFBPZIMC-UHFFFAOYSA-N 2-(2,4-diaminophenoxy)ethanol;hydrochloride Chemical compound Cl.NC1=CC=C(OCCO)C(N)=C1 PBVFDMZFBPZIMC-UHFFFAOYSA-N 0.000 description 1
- GHQGYLAEJFNSOX-UHFFFAOYSA-N 2-(methylamino)phenol;sulfuric acid Chemical compound OS(O)(=O)=O.CNC1=CC=CC=C1O GHQGYLAEJFNSOX-UHFFFAOYSA-N 0.000 description 1
- VLZVIIYRNMWPSN-UHFFFAOYSA-N 2-Amino-4-nitrophenol Chemical compound NC1=CC([N+]([O-])=O)=CC=C1O VLZVIIYRNMWPSN-UHFFFAOYSA-N 0.000 description 1
- DOPJTDJKZNWLRB-UHFFFAOYSA-N 2-Amino-5-nitrophenol Chemical compound NC1=CC=C([N+]([O-])=O)C=C1O DOPJTDJKZNWLRB-UHFFFAOYSA-N 0.000 description 1
- SHUIDGXTJAQFJO-UHFFFAOYSA-N 2-aminophenol;sulfuric acid Chemical compound [O-]S([O-])(=O)=O.[NH3+]C1=CC=CC=C1O.[NH3+]C1=CC=CC=C1O SHUIDGXTJAQFJO-UHFFFAOYSA-N 0.000 description 1
- HVHNMNGARPCGGD-UHFFFAOYSA-N 2-nitro-p-phenylenediamine Chemical compound NC1=CC=C(N)C([N+]([O-])=O)=C1 HVHNMNGARPCGGD-UHFFFAOYSA-N 0.000 description 1
- HDGMAACKJSBLMW-UHFFFAOYSA-N 4-amino-2-methylphenol Chemical compound CC1=CC(N)=CC=C1O HDGMAACKJSBLMW-UHFFFAOYSA-N 0.000 description 1
- RAUWPNXIALNKQM-UHFFFAOYSA-N 4-nitro-1,2-phenylenediamine Chemical compound NC1=CC=C([N+]([O-])=O)C=C1N RAUWPNXIALNKQM-UHFFFAOYSA-N 0.000 description 1
- YGRFRBUGAPOJDU-UHFFFAOYSA-N 5-(2-hydroxyethylamino)-2-methylphenol Chemical compound CC1=CC=C(NCCO)C=C1O YGRFRBUGAPOJDU-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 244000208060 Lawsonia inermis Species 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- VEGZHURRCWERMK-UHFFFAOYSA-N benzene-1,3-diamine;hydrochloride Chemical compound Cl.NC1=CC=CC(N)=C1 VEGZHURRCWERMK-UHFFFAOYSA-N 0.000 description 1
- MCIURFJELJKSNV-UHFFFAOYSA-N benzene-1,4-diamine;hydron;chloride Chemical compound Cl.NC1=CC=C(N)C=C1 MCIURFJELJKSNV-UHFFFAOYSA-N 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Inorganic materials [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000009918 complex formation Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 229960001305 cysteine hydrochloride Drugs 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- YAGKRVSRTSUGEY-UHFFFAOYSA-N ferricyanide Chemical compound [Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] YAGKRVSRTSUGEY-UHFFFAOYSA-N 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004404 heteroalkyl group Chemical group 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 230000003752 improving hair Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 229940018564 m-phenylenediamine Drugs 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- PETZRPLPRZXTAD-UHFFFAOYSA-N n-(4-aminophenyl)nitramide;hydrochloride Chemical compound Cl.NC1=CC=C(N[N+]([O-])=O)C=C1 PETZRPLPRZXTAD-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- RBWOKKSOBWYZQH-UHFFFAOYSA-N s-octyl benzenecarbothioate Chemical compound CCCCCCCCSC(=O)C1=CC=CC=C1 RBWOKKSOBWYZQH-UHFFFAOYSA-N 0.000 description 1
- 229940001482 sodium sulfite Drugs 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
- A61K8/556—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/432—Direct dyes
- A61K2800/4324—Direct dyes in preparations for permanently dyeing the hair
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
본 발명은 케라틴 섬유의 산화염색용 염모제 조성물에 관한 것으로서, 더욱 상세하게는 포스페이트계 계면활성제, 비이온성 계면활성제 및 특정 양이온성 중합체를 함유하는 것을 특징으로 하는 산화염색용 염모제 조성물에 관한 것이다. 본 발명의 산화염색용 염모제 조성물은 모발의 탈색과 염료의 모발내 침투를 촉진시켜 발색이 우수할 뿐만 아니라, 양이온성 중합체의 모발 흡착이 증진되어 컨디셔닝 효과도 우수하다.The present invention relates to a hair dye composition for oxidation dyeing of keratin fibers, and more particularly, to a hair dye composition for oxidation dyeing, comprising a phosphate-based surfactant, a nonionic surfactant, and a specific cationic polymer. The dyeing agent composition for oxidation dyeing of the present invention promotes discoloration of hair and penetration of dye into the hair, thereby improving color development, and promoting hair adsorption of the cationic polymer, thereby providing an excellent conditioning effect.
Description
본 발명은 케라틴 섬유의 산화염색용 염모제 조성물에 관한 것으로서, 더욱 상세하게는 포스페이트계 계면활성제, 비이온성 계면활성제 및 특정 양이온성 중합체를 함유하는 것을 특징으로 하는 산화염색용 염모제 조성물에 관한 것이다. 본 발명의 산화염색용 염모제 조성물은 모발의 탈색과 염료의 모발내 침투를 촉진시켜 발색이 우수할 뿐만 아니라, 양이온성 중합체의 모발 흡착이 증진되어 컨디셔닝 효과도 우수하다.The present invention relates to a hair dye composition for oxidation dyeing of keratin fibers, and more particularly, to a hair dye composition for oxidation dyeing, comprising a phosphate-based surfactant, a nonionic surfactant, and a specific cationic polymer. The dyeing agent composition for oxidation dyeing of the present invention promotes discoloration of hair and penetration of dye into the hair, thereby improving color development, and promoting hair adsorption of the cationic polymer, thereby providing an excellent conditioning effect.
일반적으로 모발을 포함한 케라틴 섬유의 산화염색용 조성물은 산화염료 전구체와 커플러를 함유하는 1제(염모제)와 과산화수소를 함유하는 2제(산화제)로 구성되며, 사용전 혼합을 통해 염료간에 산화축합반응이 이루어져 발색을 나타내게 된다.In general, the composition for oxidation dyeing of keratin fibers, including hair, is composed of one agent (dye) containing an oxidized dye precursor and a coupler and a second agent (oxidant) containing hydrogen peroxide, and the oxidation condensation reaction between dyes through mixing before use This is achieved by the color development.
그 과정에서 염료간 조기 산화반응이 이루어질 경우 염료가 모발 내로 침투되지 못해 충분한 발색이 이루어지지 않으며, 또한 산화반응을 위해 사용되는 알칼리제와 산화제의 작용으로 인해 모발손상이 나타나게 된다.In the process, the early oxidation reaction between the dyes do not penetrate into the hair, so that sufficient color development is not achieved, and hair damage occurs due to the action of the alkali and oxidizing agents used for the oxidation reaction.
상기 문제를 해결하기 위하여, 특허출원 제 2004-0002775호 '산화염색용 염모제 조성물'에서는 포스페이트계 계면활성제에 의한 다층 라멜라 액정 구조형성에 의해 산화염료 전구체와 커플러 사이의 반응을 지연시켜 발색력을 높이는 방법을 개시하고 있으나, 모발 손상에 대해서는 특별한 대응안이 제시되고 있지 않다.In order to solve the above problem, Patent Application No. 2004-0002775 'Oxidation Dyeing Hair Composition' is a method of increasing the color development by delaying the reaction between the oxide dye precursor and the coupler by forming a multi-layer lamellar liquid crystal structure by a phosphate-based surfactant However, no special countermeasures have been proposed for hair damage.
상기 모발손상에 대해서는 양이온성 화합물을 사용하여 모발에 흡착시켜줌으로써 모발 표면의 마찰을 줄여주고, 윤기를 부여하며, 전기적 성질을 바꾸어 정전기를 감소시키는 컨디셔닝 효과를 부여하는 방법이 사용된다. 이러한 효과를 높이기 위해서는 통상적으로 양이온 화합물 중에서도 특히 양이온 밀도가 높게 치환된 중합체를 사용하는 것이 유리하며 미국특허 제 4,217,914호 등에 대표적인 화합물이 개시되어 있다.The hair damage is adsorbed to the hair by using a cationic compound to reduce the friction of the surface of the hair, to give a shine, to change the electrical properties to give a conditioning effect to reduce the static electricity. In order to enhance such an effect, it is generally advantageous to use a polymer substituted with a high cation density among the cationic compounds, and a typical compound is disclosed in US Pat. No. 4,217,914 and the like.
그러나, 모발 발색력 향상과 컨디셔닝 효과를 동시에 높이기 위해 포스페이트계 계면활성제와 양이온성 중합체를 함께 사용할 경우, 음이온 성질을 띄는 포스페이트계 계면활성제와 양이온성 중합체 간에 이온결합에 의한 콤플렉스를 형성하며, 그 비율에 따라 침전 형성 또는 계면활성제 성능 저하에 의한 분리현상 또는 콤플렉스의 모발 불균일 흡착에 의한 컨디셔닝 효과 저하 등의 문제가 있다.However, when phosphate-based surfactants and cationic polymers are used together to improve hair color development and conditioning effects simultaneously, an ionic bond complex between phosphate-based surfactants and cationic polymers having anionic properties is formed, Therefore, there is a problem such as separation phenomenon due to precipitation formation or deterioration of surfactant performance, or deterioration of the conditioning effect due to hair non-uniform adsorption of the complex.
이에 본 발명자들은 상기와 같은 종래의 문제점을 해결하기 위하여 본 발명에 의한 산화염색용 염모제 조성물이 포스페이트계 계면활성제와 양이온성 중합체를 함께 사용하는 경우에도 침전 형성이나 안정성 저하를 일으키지 않으며, 우수한 발색력과 컨디셔닝 효과를 동시에 만족시킬 수 있 있음을 밝혀내어 본 발명을 완성 하게 되었다.Therefore, the present inventors do not cause precipitation formation or deterioration of stability even when the oxidizing dye-dye composition according to the present invention is used together with a phosphate-based surfactant and a cationic polymer in order to solve the conventional problems as described above. The present invention was found to be able to satisfy the conditioning effect at the same time.
따라서, 본 발명의 목적은 포스페이트계 계면활성제, 비이온성 계면활성제 및 특정 양이온성 중합체를 함유하는 것을 특징으로 하는 산화염색용 염모제 조성물을 제공하는 것이다.Accordingly, it is an object of the present invention to provide a hair dye composition for oxidation dyeing, comprising a phosphate-based surfactant, a nonionic surfactant, and a specific cationic polymer.
상기 기술적 과제를 달성하기 위하여, 본 발명의 케라틴 섬유의 산화염색용 염모제 조성물은 상기 조성물 총 중량에 대하여 포스페이트계 계면활성제 0.01 내지 15 중량%, 비이온성 계면활성제 0.01 내지 15 중량% 및 양이온성 중합체 0.01 내지 15 중량%를 함유하며, 포스페이트계 계면활성제와 비이온성 계면활성제가 1:0.1 내지 1:20의 중량 조성비로 구성되는 염모제 조성물을 제공한다.In order to achieve the above technical problem, the hair dye composition for oxidation dyeing keratin fibers of the present invention is 0.01 to 15% by weight of the phosphate-based surfactant, 0.01 to 15% by weight of the nonionic surfactant and 0.01% cationic polymer based on the total weight of the composition To 15 wt%, wherein the phosphate-based surfactant and the nonionic surfactant are provided in a weight ratio of 1: 0.1 to 1:20.
본 발명의 염모제 조성물에 있어서, 포스페이트계 계면활성제 화합물로는 알킬 포스페이트 에스테르나 알콕실레이티드 포스페이트 에스테르를 단독 또는 이들을 혼합하여 사용할 수 있는데, 알킬 포스페이트 에스테르로는 하기 화학식 1, 화학식 2, 화학식 3으로 표시되는 화합물 또는 이들의 혼합물을 사용할 수 있고, 알콕실레이티드 포스페이트 에스테르로는 하기 화학식 4, 화학식 5, 화학식 6으로 표시되는 화합물 또는 이들의 혼합물을 사용할 수 있다.In the hair dye composition of the present invention, as the phosphate-based surfactant compound, alkyl phosphate esters or alkoxylated phosphate esters may be used alone or in combination thereof. As alkyl phosphate esters, the following formulas (1), (2) and (3) may be used. The compound to be represented or a mixture thereof can be used, and as the alkoxylated phosphate ester, the compound represented by the following formula (4), (5) and (6) can be used.
상기 화학식 1, 2 및 3에서, R1, R2 및 R3는 서로 독립적으로 탄소수가 8 내지 30인 직쇄 알킬기이고, X는 수소원자 또는 Na이다.In Formulas 1, 2, and 3, R 1 , R 2, and R 3 are each independently a linear alkyl group having 8 to 30 carbon atoms, and X is a hydrogen atom or Na.
상기 화학식 4, 5 및 6에서, R4, R5 및 R6은 서로 독립적으로 탄소수가 1 내지 40인 직쇄 알킬기이고, X는 수소원자 또는 Na이고, a, b 및 c는 서로 독립적으로 1 내지 50의 정수이다.In Formulas 4, 5, and 6, R 4 , R 5, and R 6 are each independently a linear alkyl group having 1 to 40 carbon atoms, X is a hydrogen atom or Na, and a, b, and c are each independently 1 to It is an integer of 50.
본 발명의 상기 비이온성 계면활성제는 통상적으로 화장품이나 염모제에서 사용되는 화합물들을 단독 또는 이들을 혼합하여 사용할 수 있는데, 하기 화학식 7, 화학식 8, 화학식 9로 표시되는 화합물 또는 이들의 혼합물을 사용할 수 있다.The nonionic surfactants of the present invention may be used alone or in combination thereof, which are typically used in cosmetics or hair dyes, and the compounds represented by the following Chemical Formula 7, Formula 8, and Formula 9 or a mixture thereof may be used.
상기 화학식 7에서, R7은 탄소수가 8 내지 20인 알킬기이고, R8 및 R9는 서로 독립적으로 탄소수가 1 내지 3인 알킬기이다.In Formula 7, R 7 is an alkyl group having 8 to 20 carbon atoms, and R 8 and R 9 are independently alkyl groups having 1 to 3 carbon atoms.
상기 화학식 8에서, R10은 탄소수가 8 내지 20인 알킬기이고, x는 0 또는 1이다.In Formula 8, R 10 is an alkyl group having 8 to 20 carbon atoms, and x is 0 or 1.
상기 화학식 9에서, R11은 탄소수가 8 내지 20인 알킬기이고, y는 3 내지 50의 정수이다.In Formula 9, R 11 is an alkyl group having 8 to 20 carbon atoms, y is an integer of 3 to 50.
상기 화학식 7로 표시되는 비이온성 계면활성제로는 라우릴디메틸아민옥사이드 및 야자유알킬디메틸아민옥사이드 등이 있으며, 상기 화학식 8로 표시되는 비이온성 계면활성제로는 라우릴산디에탄올아미드, 야자유지방산디에탄올아미드 및 야자유지방산모노에탄올아미드 등이 있으며, 상기 화학식 9로 표시되는 비이온성 계면활성제로는 폴리옥시에틸렌라우릴에테르 및 폴리옥시에틸렌노닐페닐에테르 등이 있다.Nonionic surfactants represented by Formula 7 include lauryldimethylamine oxide and palm oil alkyldimethylamine oxide, and the like, and nonionic surfactants represented by Formula 8 include lauryl acid diethanolamide and palm oil fatty acid diethanolamide. And palm oil fatty acid monoethanolamide. Examples of the nonionic surfactant represented by Formula 9 include polyoxyethylene lauryl ether and polyoxyethylene nonylphenyl ether.
본 발명의 상기 특정 양이온성 중합체는 하기 화학식 10에 대응하는 단위를 포함하는 단일 또는 공중합체, 화학식 11에 대응하는 반복 단위로 이루어지는 중합체, 화학식 12에 대응하는 반복 단위로 이루어진 중합체들을 단독 또는 이들을 혼합하여 사용할 수 있다. The specific cationic polymer of the present invention is a single or copolymer comprising a unit corresponding to the following formula (10), a polymer consisting of repeating units corresponding to formula (11), polymers consisting of repeating units corresponding to formula (12) alone or mixed thereof Can be used.
상기 화학식 10에서, k와 t는 0 또는 1이고, k+t의 합은 1이고, R12는 수소원자 또는 메틸기이고, R13과 R14는 서로 독립적으로 또는 동시에 탄소수가 1 내지 22인 포화 또는 불포화 알킬기, 탄소수가 1 내지 5인 히드록시알킬기, 저급(C1~C4) 아미도알킬기, 또는 질소원자를 공통적으로 가진 R13과 R14는 피페리디닐기 또는 모르폴리닐기와 같은 헤테로시클릭기이고, X-는 무기산 또는 유기산으로부터 유도된 음이온이다.In Chemical Formula 10, k and t are 0 or 1, the sum of k + t is 1, R 12 is a hydrogen atom or a methyl group, and R 13 and R 14 are each independently or simultaneously saturated with 1 to 22 carbon atoms. Or a heteroalkyl such as R 13 and R 14 having an unsaturated alkyl group, a hydroxyalkyl group having 1 to 5 carbon atoms, a lower (C 1 to C 4 ) amidoalkyl group, or a nitrogen atom in common, and a piperidinyl group or a morpholinyl group Is a click group and X − is an anion derived from an inorganic acid or an organic acid.
상기 화학식 11에서, R15, R16, R17 및 R18은 서로 독립적으로 또는 동시에 탄 소수가 1 내지 22인 포화 또는 불포화 알킬기, 벤질기, 탄소수가 1 내지 5인 히드록시알킬기, 에틸렌옥사이드기가 1 내지 20개 부가된 히드록시알킬기, 또는 프로필렌옥사이드기가 1 내지 20개 부가된 히드록시알칼기이고, A1과 A2는 서로 독립적으로 또는 동시에 탄소수가 1 내지 22인 포화 또는 불포화 알킬기, 히드록시알킬기, 에틸렌옥사이드기가 1 내지 20개 부가된 알킬기, 프로필렌옥사이드기가 1 내지 20개 부가된 알킬기, 또는 주쇄에 연결되거나 삽입된 1개 이상의 방향족 고리 또는 1개 이상의 산소 또는 황 원자 또는 술폭시드, 술폰, 디술피드, 아미노, 알킬아미노, 히드록실, 4차 암모늄, 우레이도, 아미드 또는 에스테르기를 포함할 수 있는 폴리메틸렌기이고, X-는 무기산 또는 유기산으로부터 유도된 음이온이다.In Formula 11, R 15 , R 16 , R 17 And R 18 is independently or simultaneously a saturated or unsaturated alkyl group having 1 to 22 carbon atoms, benzyl group, hydroxyalkyl group having 1 to 5 carbon atoms, hydroxyalkyl group having 1 to 20 ethylene oxide groups added, or propylene oxide The group is a hydroxyalkae group having 1 to 20 additions, A 1 and A 2 are independently or at the same time a saturated or unsaturated alkyl group having 1 to 22 carbon atoms, hydroxyalkyl group, alkyl group having 1 to 20 ethylene oxide groups added, Alkyl group having 1 to 20 additional propylene oxide groups, or at least one aromatic ring or at least one oxygen or sulfur atom or sulfoxide linked or inserted into the main chain, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, and also, an amide or a polymethylene group which can comprise an ester group, X - is a sound derived from an inorganic or organic acid A whole.
상기 화학식 12에서, p는 1 내지 6의 정수이고, D는 0 또는 -(CH2)r-CO-(식 중, r은 4 또는 7을 나타낸다)이고, X-는 무기산 또는 유기산으로부터 유도된 음이온이다.In Formula 12, p is an integer of 1 to 6, D is 0 or-(CH 2 ) r -CO- (where r represents 4 or 7), X - is derived from an inorganic acid or an organic acid It is an anion.
이하, 본 발명을 보다 구체적으로 설명한다.Hereinafter, the present invention will be described in more detail.
본 발명의 조성물은 상기 조성물 총 중량에 대하여 상기 화학식 1, 2 및 3에 대응하는 알킬포스페이트 에스테르 화합물, 또는 상기 화학식 4, 5 및 6에 대응하는 알콕실레이티드 포스페이트 에스테르 화합물을 0.01 내지 15 중량%로 함유한다. 이러한 화합물은 다층 라멜라 액정 구조의 형성을 용이하게 하여, 산화염료 전구체와 커플러 사이의 축합반응이 모발에 적용되기 전에 일어나는 것을 지연시킴으로써 산화염료 전구체와 커플러의 모발내 침투 속도를 증가시키고 더 깊이 침투할 수 있게 도와주는 역할을 한다. 포스페이트계 계면활성제 화합물의 함량은 0.01 내지 15 중량%, 바람직하게는 0.5 내지 5 중량%인데, 그 함량이 0.01 중량% 미만이면 산화염료 전구체와 커플러 사이의 축합반응이 모발에 적용되기 전에 일어나는 것을 충분히 지연시키지 못하며, 15 중량%를 초과하면 산화염료 전구체 및 커플러의 모발내 침투를 지나치게 억제하여 충분한 발색이 이루어지지 않는다.The composition of the present invention is 0.01 to 15% by weight of the alkyl phosphate ester compound corresponding to the formulas (1), (2) and (3), or the alkoxylated phosphate ester compound corresponding to the formulas (4), (5) and (6), based on the total weight of the composition. It contains. Such compounds facilitate the formation of a multilayer lamellar liquid crystal structure, increasing the rate of penetration of the oxide precursor and coupler in the hair and penetrating deeper by delaying the condensation reaction between the oxide precursor and the coupler before being applied to the hair. It helps to help. The content of the phosphate-based surfactant compound is 0.01 to 15% by weight, preferably 0.5 to 5% by weight, if the content is less than 0.01% by weight so that the condensation reaction between the oxide dye precursor and the coupler takes place before the hair is applied to the hair. If it is more than 15% by weight, the penetration of the oxidized dye precursor and the coupler into the hair is excessively suppressed and sufficient color development is not achieved.
또한, 본 발명의 조성물은 조성물 총 중량을 기준으로 상기 화학식 10, 11 및 12에 대응하는 특정 양이온성 중합체 0.01 내지 15 중량%를 함유한다. 산화반응을 위해 사용되는 알칼리제와 산화제의 작용으로 인해 발생되는 모발손상에 대해서 양이온성 화합물을 사용하여 모발에 흡착시킴으로써 모발 표면의 마찰을 줄여주고, 윤기를 부여하며, 전기적 성질을 바꾸어 정전기를 감소시키는 컨디셔닝 효과를 부여해 준다. 이러한 효과를 높이기 위해서는 통상적으로 양이온 화합물 중에서도 특히 양이온 밀도가 높게 치환된 상기 양이온 중합체를 사용하는 것이 유리하다. 양이온성 중합체의 함량은 0.01 내지 15 중량%, 바람직하게는 0.1 내지 5중량 %인데, 그 함량이 0.01 중량% 미만이면 충분한 컨디셔닝 효과를 나타내지 못하며, 15 중량%를 초과하면 산화염료 전구체 및 커플러의 모발 내 침투를 방해하여 충분한 발색이 이루어지지 않고, 화합물이 모발에 지나치게 흡착되어 오히려 컨디셔닝 효과가 저하되는 문제점이 있다.In addition, the composition of the present invention contains 0.01 to 15% by weight of the specific cationic polymer corresponding to the above formulas (10), (11) and (12) based on the total weight of the composition. Adsorption on the hair using cationic compounds to the hair damage caused by the action of the alkali and oxidizing agents used for the oxidation reaction reduces the friction on the surface of the hair, gives it luster and changes the electrical properties to reduce static electricity. Gives a conditioning effect. In order to enhance such an effect, it is usually advantageous to use the above cationic polymer substituted with a particularly high cation density among the cationic compounds. The content of the cationic polymer is 0.01 to 15% by weight, preferably 0.1 to 5% by weight. If the content is less than 0.01% by weight, it does not exhibit sufficient conditioning effect. If the content is more than 15% by weight, the hair of the oxidative precursor and the coupler There is a problem in that a sufficient color development is not achieved by preventing penetration, and the compound is excessively adsorbed onto the hair, and thus the conditioning effect is lowered.
또한, 본 발명의 조성물은 조성물 총 중량을 기준으로 상기 화학식 7, 8 및 9에 대응하는 비이온성 계면활성제 화합물 0.01 내지 15중량%를 함유하며, 상기 포스페이트계 계면활성제와 비이온성 계면활성제가 1:0.1 내지 1:20의 중량 조성비를 갖는 것을 특징으로 한다. 모발 발색력 향상과 컨디셔닝 효과를 동시에 높이기 위해 상기 포스페이트계 계면활성제와 상기 특정 양이온성 중합체를 함께 사용할 경우, 음이온 성질을 띄는 포스페이트계 계면활성제와 양이온성 중합체 간에 이온결합에 의한 콤플렉스를 형성하며, 그 비율에 따라 침전 형성 또는 계면활성제 성능 저하에 의한 분리현상 또는 콤플렉스의 모발 불균일 흡착에 의한 컨디셔닝 효과 저하 등의 문제가 있다. 이에 특정 조성비로써 비이온성 계면활성제가 첨가될 경우 음이온성 포스페이트계 계면활성제와 함께 더 강한 유화구조를 형성하여 제형의 유동성을 떨어뜨리고, 구조적으로 입체장애효과(steric hindrance)를 통해 음이온성 포스페이트계 계면활성제와 양이온성 중합체의 접촉 면적 및 접촉 확률을 저하시켜 직접적인 콤플렉스 형성을 억제하는 작용을 나타낸다. 또한, 일부 콤플렉스가 형성되어도 비이온성 계면활성제가 이를 안정하게 유지시켜 주는 작용을 한다. 포스페이트계 계면활성제와 비이온성 계면활성제의 중량 조성비는 1:0.1 내지 1:20, 더 바람직하게는 1:0.5 내지 1:5 비율인데, 비이온성 계면활성제의 비율이 1:0.1 미만이면 충분한 콤플렉스 형성 억제효과를 나타내지 못하며, 1:20 초과하면 포스페이트계 계면활성제에 의한 발색력 향상효과가 충분히 나타나지 못하는 문제가 있다.In addition, the composition of the present invention contains 0.01 to 15% by weight of the nonionic surfactant compound corresponding to Formula 7, 8 and 9, based on the total weight of the composition, wherein the phosphate-based surfactant and nonionic surfactant 1: It is characterized by having a weight composition ratio of 0.1 to 1:20. When the phosphate-based surfactant and the specific cationic polymer are used together to improve the hair color development and the conditioning effect at the same time, an ionic bond complex between the phosphate-based surfactant and the cationic polymer having anionic properties is formed and the ratio thereof. Therefore, there are problems such as separation due to precipitation formation or deterioration of surfactant performance or deterioration in conditioning effect due to hair non-uniform adsorption of complexes. Therefore, when a nonionic surfactant is added at a specific composition ratio, it forms a stronger emulsified structure together with the anionic phosphate-based surfactant to reduce the fluidity of the formulation, and structurally anionic phosphate-based interface through the steric hindrance It exhibits the action of inhibiting direct complex formation by lowering the contact area and the contact probability of the active agent and the cationic polymer. In addition, even when some complexes are formed, a nonionic surfactant functions to keep them stable. The weight composition ratio of the phosphate-based surfactant and the nonionic surfactant is 1: 0.1 to 1:20, more preferably 1: 0.5 to 1: 5, and the ratio of the nonionic surfactant is less than 1: 0.1 to form a sufficient complex. It does not exhibit an inhibitory effect, and when it exceeds 1:20, there is a problem in that the coloring improvement effect by the phosphate-based surfactant does not appear sufficiently.
본 발명의 산화염색용 염모제 조성물은 통상적인 산화염료 전구체와 커플러를 함유하는데, 바람직하게는 2종 이상의 산화염료 전구체와 커플러를 함유한다.The dyeing agent composition for oxidation dyeing of the present invention contains a conventional oxide dye precursor and a coupler, and preferably contains two or more oxide dye precursors and a coupler.
산화염료 전구체 및 커플러로는 현재 알려진 대부분의 산화염료 전구체와 커플러를 사용할 수 있다. 이와 같은 산화염료 전구체로는 o-아미노페놀, p-아미노페놀, 염산 톨루엔-2,5-디아민, 염산 p-페닐렌디아민, 톨루엔-2,5-디아민, 황산 p-페닐렌디아민, 황산 p-메칠아미노페놀, 황산 o-아미노페놀, 황산 p-아미노페놀, 황산 톨루엔-2,5-디아민 및 황산 p-페닐렌디아민 등을 들 수 있는데, 산화염료 전구체의 배합량은 0.001~5.0 중량%로 사용된다. 커플러로는 2-메칠-5-히드록시에칠 아미노페놀, p-아미노-o-크레솔, m-아미노페놀, 염산 2,4-디아미노페녹시에탄올, 염산 m-페닐렌디아민, m-페닐렌디아민, α-나프톨, 레소르시놀 및 2-메칠레소르시놀 등을 사용할 수 있으며, 상기 커플러의 배합량은 0.001~5.0 중량%로 사용된다.Oxide dye precursors and couplers may use most of the known oxide dye precursors and couplers. Such oxidizing dye precursors include o-aminophenol, p-aminophenol, toluene-2,5-diamine hydrochloride, p-phenylenediamine hydrochloride, toluene-2,5-diamine, p-phenylenediamine sulfate and p sulfate Methylaminophenol, o-aminophenol sulfate, p-aminophenol sulfate, toluene-2,5-diamine sulfate and p-phenylenediamine sulfate, and the like. The amount of the oxide dye precursor is 0.001 to 5.0% by weight. Used. Couplers include 2-methyl-5-hydroxyethyl aminophenol, p-amino-o-cresol, m-aminophenol, 2,4-diaminophenoxyethanol hydrochloride, m-phenylenediamine hydrochloride, m- Phenylenediamine, α-naphthol, resorcinol and 2-metholesorcinol and the like can be used, the compounding amount of the coupler is used in 0.001 to 5.0% by weight.
또한, 본 발명의 목적을 저해하지 않는 범위 내에서 통상적으로 사용되는 직접염료를 첨가할 수 있는데, 이와 같은 직접염료로는 아리아놀(Arianol) 염료, p-니트로-o-페닐렌디아민, 니트로-p-페닐렌디아민, 2-아미노-4-니트로페놀, 2-아미노-5-니트로페놀, 염산니트로-p-페닐렌디아민 및 피크라민산 기타 식물성 염료인 헨나(Henna) 등을 사용할 수 있다.In addition, a direct dye commonly used within the scope of not impairing the object of the present invention can be added, such a direct dye, such as arianol dye, p-nitro-o-phenylenediamine, nitro- p-phenylenediamine, 2-amino-4-nitrophenol, 2-amino-5-nitrophenol, nitro-p-phenylenediamine hydrochloride and pyraminic acid and other vegetable dyes such as Henna may be used.
본 발명의 산화염색용 염모제 조성물은 중성에서 알칼리의 pH 범위에서 사용할 수 있는데, 특히 알칼리성의 조건에서 사용하는 것이 모발 팽윤에 의한 염료의 모발 침투 향상과 염료의 산화축합반응이 활발히 일어나므로 효과적이다. 이에 사용되는 알칼리제로는 암모니아수, 모노에탄올아민, 아미노메칠프로판올, 수산화나트륨 및 수산화칼륨 등을 들 수 있다.The dyeing agent composition for oxidation dyeing of the present invention can be used in the pH range of neutral to alkali, and particularly, it is effective to use in alkaline conditions, since the hair penetration improvement of the dye due to hair swelling and the oxidation condensation reaction of the dye occur actively. Alkali agents used therein include ammonia water, monoethanolamine, aminomethylpropanol, sodium hydroxide and potassium hydroxide.
본 발명의 산화염색용 염모제 조성물에는 염모제에 통상적으로 사용되는 성 분을 본 발명의 효과를 떨어뜨리지 않는 범위 내에서 사용할 수 있다. 예를 들면, 산화방지제로서 아스코르빈산, 에리소르빈산, 시스테인하이드로클로라이드, 아황산나트륨 및 티오글리콜산 등을 들 수 있고, 금속 봉쇄제로서 EDTA, 테트라소듐-EDTA 및 펜타소듐펜티테이트 등을 들 수 있으며, 용제로서는 에탄올, 프로필 알코올, 이소프로필 알코올, 프로필렌글리콜, 헥실렌글리콜 및 디에칠렌글리콜 등을 사용 할 수 있고, 점증제로서는 탄소수 14~20의 고급알코올을 단독 또는 이들을 혼합하여 사용할 수 있으며, 비이온성 중합체 및 음이온성 중합체 등을 사용할 수 있고, 컨디셔닝제로는 4급화 암모늄염 및 실리콘 등을 사용할 수 있다.In the dyeing agent composition for oxidation dyeing of the present invention, a component commonly used in hair dyeing agents can be used within a range that does not impair the effects of the present invention. For example, ascorbic acid, erythorbic acid, cysteine hydrochloride, sodium sulfite, thioglycolic acid, etc. are mentioned as antioxidant, EDTA, tetrasodium-EDTA, pentasodium pentate, etc. are mentioned as a metal blocking agent. As the solvent, ethanol, propyl alcohol, isopropyl alcohol, propylene glycol, hexylene glycol and diethylene glycol may be used, and as the thickener, higher alcohols having 14 to 20 carbon atoms may be used alone or in combination thereof. An anionic polymer, an anionic polymer, etc. can be used, A quaternary ammonium salt, silicone, etc. can be used as a conditioning agent.
상기와 같이 제조된 본 발명의 산화염색용 조성물은 염색 직전에 산화제와 혼합하여 모발에 적용하며, 산화제로서는 통상적으로 사용되는 과산화수소, 과산화요소, 알칼리 금속 브로메이트, 페리시아니드, 퍼보레이트 및 퍼술페이트 등을 들 수 있고, 특히 과산화수소를 사용하는 것이 산화반응에 의한 발색 및 탈색 뿐만 아니라 안정한 제형을 구성하는데 있어서도 효과적이다.The composition for oxidation dyeing of the present invention prepared as described above is applied to the hair by mixing with an oxidizing agent just before dyeing, and as the oxidizing agent, hydrogen peroxide, urea peroxide, alkali metal bromate, ferricyanide, perborate and persulfate which are commonly used In particular, the use of hydrogen peroxide is effective in forming a stable formulation as well as coloration and decolorization by the oxidation reaction.
이하 실시예, 비교예 및 시험예를 통하여 본 발명을 더욱 상세히 설명하나, 본 발명이 이들에 의해 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to Examples, Comparative Examples, and Test Examples, but the present invention is not limited thereto.
[실시예 1 ~ 2 및 비교예 1 ~ 4][Examples 1 to 2 and Comparative Examples 1 to 4]
하기 [표 1]에 기재된 조성비에 따라, 수상으로는 정제수, 디소듐이디티에이, 에리쏘르빈산, 소듐설파이트, 프로필렌글라이콜, 염료 및 테트라메칠헥산디아민·디클로로이소프로판올공중합체를 넣고 75℃까지 가온 용해하였다. 유상으로는 세테아릴알코올, 미네랄오일, 폴리옥시에칠렌스테아릴에텔, 스테아트리모늄클로라이드, 디세틸포스페이트 및 세테스-10 포스페이트를 넣고 75℃까지 가온 용해하였다. 상기 유상과 수상을 혼합, 유화한 후 40℃까지 냉각하여 모노에탄올아민, 강암모니아수(28%) 및 조합향을 넣어 균일하게 혼합하여 염모제 조성물을 제조하였다.According to the composition ratio shown in Table 1, purified water, disodium id, erythorbic acid, sodium sulfite, propylene glycol, dye, and tetramethylhexanediamine dichloroisopropanol copolymer were added to the aqueous phase at 75 캜. Dissolved until warm up. Cetearyl alcohol, mineral oil, polyoxyethylene stearyl ether, stearmonium chloride, dicetyl phosphate and cete-10 phosphate were added as an oil phase, and it melt | dissolved by heating to 75 degreeC. After mixing and emulsifying the oil phase and the water phase, the mixture was cooled to 40 ° C., and monoethanolamine, strong ammonia water (28%), and a combination of flavors were mixed to prepare a hair dye composition.
이때, 양이온성 화합물로 사용된 테트라메칠헥산디아민·디클로로이소프로판올공중합체는 하기 화학식으로 표시된다.At this time, the tetramethylhexanediamine dichloroisopropanol copolymer used as a cationic compound is represented by the following chemical formula.
[시험예 1] 안정성 평가Test Example 1 Evaluation of Stability
상기 실시예 및 비교예에 따라 제조한 산화염색용 염모제 조성물을 상온에서 1일간 관찰하여, 그 결과를 하기 [표 2]에 나타내었다.The oxidation dyeing hair dye composition prepared according to the above Examples and Comparative Examples was observed at room temperature for 1 day, and the results are shown in the following [Table 2].
(평가기준)(Evaluation standard)
○: 내용물 양호, Χ: 내용물 분리○: content is good, C: content is separated
상기 [표 2]를 통해, 본 발명에 따른 비이온성 계면활성제를 포함하며, 포스페이트계 계면활성제와 비이온성 계면활성제가 1:0.1 중량조성비 이상인 실시예 1, 실시예 2, 비교예 2, 비교예 3 및 비교예 4가 이를 포함하지 않는 비교예 1과 비교하여 안정성이 우수함을 확인할 수 있었다.Through Table 2, Examples 1, 2, Comparative Example 2, Comparative Examples comprising a nonionic surfactant according to the present invention, wherein the phosphate-based surfactant and the nonionic surfactant is 1: 0.1 or more by weight ratio 3 and Comparative Example 4 was confirmed to have excellent stability compared to Comparative Example 1 does not include this.
[시험예 2] 발색력 평가Test Example 2 Evaluation of Color Development
상기 실시예 및 비교예에 따라 제조한 산화염색용 염모제 조성물을 6% 과산화수소 용액과 1:1.5 비율로 혼합한 후 백모 트레스에 도포하고 30분간 방치 후 샴푸로 세척, 건조하였다. 건조 후의 모발 트레스를 색차계(HunterLab Labscan XE)를 이용하여 측정하고, 그 결과를 하기 [표 3]에 나타내었으며, 측정은 각 6회 반복 측정 후 평균값을 기록하였다. 단, 비교예 1은 안정성 저하로 인한 내용물 분리 문제로 본 평가에서 제외하였다.The dyeing agent composition for oxidation dyeing according to the above Examples and Comparative Examples was mixed with 6% hydrogen peroxide solution in a ratio of 1: 1.5, applied to white hair tress, left for 30 minutes, washed with shampoo, and dried. Hair tress after drying was measured using a color difference meter (HunterLab Labscan XE), and the results are shown in the following [Table 3], and the measurements were recorded after the average of six repeated measurements. However, Comparative Example 1 was excluded from the evaluation due to the problem of separation of the contents due to stability.
ΔL* : 밝고 어두움을 나타내는 염색 전후의 명도(L*) 차이로서, 값이 클수록 발색력이 우수함.ΔL *: Brightness and lightness (L *) difference before and after dyeing, the higher the value, the better the color development.
상기 [표 3]을 통해, 본 발명에 따른 포스페이트계 계면활성제를 포함하며, 포스페이트계 계면활성제와 비이온성 계면활성제가 1:20 중량조성비 이하인 실시예 1, 실시예 2 및 비교예 4가 이를 포함하지 않는 비교예 3 및 포스페이트계 계면활성제와 비이온성 계면활성제가 1:20 중량조성비 이상인 비교예 2와 비교하여 발색력이 우수함을 확인할 수 있었다.Through Table 3, Examples 1, 2 and Comparative Example 4 containing a phosphate-based surfactant according to the present invention, wherein the phosphate-based surfactant and the nonionic surfactant is 1:20 or less by weight ratio It was confirmed that the color development ability was superior to Comparative Example 3 not compared to Comparative Example 2 and the phosphate-based surfactant and non-ionic surfactant 1: 1: 20 weight composition ratio or more.
[시험예 3] 컨디셔닝 효과 평가[Test Example 3] Conditioning effect evaluation
상기 실시예 및 비교예에 따라 제조한 산화염색용 염모제 조성물을 6% 과산화수소 용액과 1:1.5 비율로 혼합한 후 실험용 사람 모발에 도포하고 30분간 방치 후 샴푸로 세척, 건조하였다. 건조 후의 모발 상에서의 컨디셔닝 효과 차이를 전문 패널 5명이 하기 기준에 따라 평가하고, 그 결과를 하기 [표 4]에 나타내었다. 단, 비교예 1은 안정성 저하로 인한 내용물 분리 문제로 본 평가에서 제외하였다.The dyeing agent composition for oxidation dyeing according to the above Examples and Comparative Examples was mixed with 6% hydrogen peroxide solution in a ratio of 1: 1.5, then applied to experimental human hair, left for 30 minutes, washed with shampoo, and dried. The difference in the conditioning effect on the hair after drying was evaluated by five professional panelists according to the following criteria, and the results are shown in the following [Table 4]. However, Comparative Example 1 was excluded from the evaluation due to the problem of separation of the contents due to stability.
(평가기준)(Evaluation standard)
◎ : 매우 매끄러움, ○: 매끄러움, △ : 보통, Χ: 거침◎: very smooth, ○: smooth, △: normal, Χ: rough
상기 [표 4]를 통해, 본 발명에 따른 특정 양이온성 중합체인 테트라메칠헥산디아민·디클로로이소프로판올공중합체를 포함하는 실시예 1, 실시예 2, 비교예 2 및 비교예 3이 이를 포함하지 않는 비교예 4와 비교하여 컨디셔닝 효과가 우수함을 확인할 수 있었다.Through Table 4, Examples 1, 2, Comparative Example 2 and Comparative Example 3 containing a tetramethylhexanediamine dichloroisopropanol copolymer which is a specific cationic polymer according to the present invention do not include this It was confirmed that the conditioning effect is excellent compared to Example 4.
이상에서 상술한 바와 같이, 본 발명의 조성물은 포스페이트계 계면활성제와 양이온성 중합체를 함께 사용하는 경우에도 침전 형성이나 안정성 저하를 일으키지 않으며, 우수한 발색력과 컨디셔닝 효과를 동시에 만족시킬 수 있는 염모제 조성물을 제조할 수 있다.As described above, the composition of the present invention does not cause precipitation formation or deterioration of stability even when a phosphate-based surfactant and a cationic polymer are used together, thereby preparing a hair dye composition which can simultaneously satisfy excellent color development and conditioning effects. can do.
Claims (7)
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| KR980000423A (en) * | 1996-06-28 | 1998-03-30 | 이능희 | Hair dye composition |
| JP2003221319A (en) | 2002-01-28 | 2003-08-05 | Hoyu Co Ltd | Hair-bleaching composition and hair-dye composition |
| US6818022B2 (en) | 2001-01-19 | 2004-11-16 | Combe Inc. | Hair dye composition |
| KR20050074860A (en) * | 2004-01-14 | 2005-07-19 | 주식회사 엘지생활건강 | Composition for oxidative dyeing of hair |
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| KR980000423A (en) * | 1996-06-28 | 1998-03-30 | 이능희 | Hair dye composition |
| US6818022B2 (en) | 2001-01-19 | 2004-11-16 | Combe Inc. | Hair dye composition |
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| KR20100061261A (en) * | 2008-11-28 | 2010-06-07 | (주)아모레퍼시픽 | Composition for the oxidative dyeing containing natural materials |
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