KR100634334B1 - Liquid complex fertilizer composition using high active calcium and essential trace elements - Google Patents
Liquid complex fertilizer composition using high active calcium and essential trace elements Download PDFInfo
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- KR100634334B1 KR100634334B1 KR1020040074659A KR20040074659A KR100634334B1 KR 100634334 B1 KR100634334 B1 KR 100634334B1 KR 1020040074659 A KR1020040074659 A KR 1020040074659A KR 20040074659 A KR20040074659 A KR 20040074659A KR 100634334 B1 KR100634334 B1 KR 100634334B1
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- fertilizer composition
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 40
- 239000000203 mixture Substances 0.000 title claims abstract description 35
- 239000007788 liquid Substances 0.000 title claims abstract description 27
- 239000011573 trace mineral Substances 0.000 title claims abstract description 22
- 235000013619 trace mineral Nutrition 0.000 title claims abstract description 22
- 239000011575 calcium Substances 0.000 title abstract description 33
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title abstract description 32
- 229910052791 calcium Inorganic materials 0.000 title abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 38
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 27
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000000292 calcium oxide Substances 0.000 claims abstract description 22
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000002131 composite material Substances 0.000 claims abstract description 19
- 239000002689 soil Substances 0.000 claims abstract description 18
- 239000011572 manganese Substances 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 14
- 229910052742 iron Inorganic materials 0.000 claims abstract description 12
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 11
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 11
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052796 boron Inorganic materials 0.000 claims abstract description 11
- 239000000460 chlorine Substances 0.000 claims abstract description 11
- 239000010949 copper Substances 0.000 claims abstract description 11
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 11
- 239000011733 molybdenum Substances 0.000 claims abstract description 11
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 11
- 239000011701 zinc Substances 0.000 claims abstract description 11
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 10
- 229910052802 copper Inorganic materials 0.000 claims abstract description 10
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 10
- 230000004720 fertilization Effects 0.000 claims abstract description 8
- 238000001354 calcination Methods 0.000 claims abstract 2
- 235000012054 meals Nutrition 0.000 claims abstract 2
- 239000012153 distilled water Substances 0.000 claims description 5
- 238000003973 irrigation Methods 0.000 claims description 4
- 230000002262 irrigation Effects 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 9
- 239000000843 powder Substances 0.000 abstract description 9
- 241000607479 Yersinia pestis Species 0.000 abstract description 6
- 230000012010 growth Effects 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 241000196324 Embryophyta Species 0.000 description 28
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
- 210000003462 vein Anatomy 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 8
- 238000010304 firing Methods 0.000 description 7
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 6
- 235000003228 Lactuca sativa Nutrition 0.000 description 6
- 235000011941 Tilia x europaea Nutrition 0.000 description 6
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 6
- 239000004571 lime Substances 0.000 description 6
- 241000208822 Lactuca Species 0.000 description 5
- 239000001569 carbon dioxide Substances 0.000 description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- 235000013399 edible fruits Nutrition 0.000 description 5
- 239000000575 pesticide Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 240000003040 Solanum lycopersicum var. cerasiforme Species 0.000 description 4
- 150000001669 calcium Chemical class 0.000 description 4
- 230000002950 deficient Effects 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 240000007124 Brassica oleracea Species 0.000 description 3
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 3
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 3
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 235000003953 Solanum lycopersicum var cerasiforme Nutrition 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000000920 calcium hydroxide Substances 0.000 description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 3
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical class [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000013522 chelant Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 230000007812 deficiency Effects 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 238000007865 diluting Methods 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 230000008635 plant growth Effects 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000011684 sodium molybdate Substances 0.000 description 3
- 235000015393 sodium molybdate Nutrition 0.000 description 3
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 206010006956 Calcium deficiency Diseases 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 235000020188 drinking water Nutrition 0.000 description 2
- 239000003651 drinking water Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 230000017074 necrotic cell death Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000009329 organic farming Methods 0.000 description 2
- 235000019629 palatability Nutrition 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000004328 sodium tetraborate Substances 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 208000024891 symptom Diseases 0.000 description 2
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 description 2
- UOMQUZPKALKDCA-UHFFFAOYSA-K 2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxymethyl)amino]acetate;iron(3+) Chemical compound [Fe+3].OC(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UOMQUZPKALKDCA-UHFFFAOYSA-K 0.000 description 1
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 206010010957 Copper deficiency Diseases 0.000 description 1
- 206010011703 Cyanosis Diseases 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 206010020850 Hyperthyroidism Diseases 0.000 description 1
- 206010022971 Iron Deficiencies Diseases 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- 229910004616 Na2MoO4.2H2 O Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000011609 ammonium molybdate Substances 0.000 description 1
- 235000018660 ammonium molybdate Nutrition 0.000 description 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical group [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
- 229940010552 ammonium molybdate Drugs 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 229960002413 ferric citrate Drugs 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical group [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- NPFOYSMITVOQOS-UHFFFAOYSA-K iron(III) citrate Chemical compound [Fe+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NPFOYSMITVOQOS-UHFFFAOYSA-K 0.000 description 1
- 229940099596 manganese sulfate Drugs 0.000 description 1
- 239000011702 manganese sulphate Substances 0.000 description 1
- 235000007079 manganese sulphate Nutrition 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical group [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 238000003900 soil pollution Methods 0.000 description 1
- 210000001082 somatic cell Anatomy 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- WQSRXNAKUYIVET-UHFFFAOYSA-N sulfuric acid;zinc Chemical group [Zn].OS(O)(=O)=O WQSRXNAKUYIVET-UHFFFAOYSA-N 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002349 well water Substances 0.000 description 1
- 235000020681 well water Nutrition 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D3/00—Calcareous fertilisers
- C05D3/02—Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
- C05G5/23—Solutions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
Abstract
본 발명은 고 활성칼슘 및 필수미량원소를 이용한 액상 복합비료 조성물 및 이의 제조방법에 관한 것으로, 보다 상세하게는 농작물의 생장에 필요한 칼슘 보급원의 공급과 필수미량요소의 결핍을 억제하기 위해서, 패각분(貝殼粉) 유래의 산화 칼슘을 포화 용해한 고 활성칼슘액에 필요한 필수미량원소를 선택적으로 첨가한 액상 복합비료 조성물 및 이의 제조방법에 관한 것이다.The present invention relates to a liquid composite fertilizer composition using a high active calcium and essential trace elements, and a method for preparing the same, and more particularly, in order to suppress the supply of calcium supply source and the lack of essential trace elements required for the growth of crops, The present invention relates to a liquid composite fertilizer composition in which an essential trace element is selectively added to a highly active calcium solution obtained by saturatedly dissolving calcium oxide derived from powder and a method for producing the same.
본 발명은 패각분을 소성하고 통전하여 제조된 산화칼슘과; 수용성 철원, 수용성 염소원, 수용성 붕소원, 수용성 망간원, 수용성 아연원, 수용성 구리원 및 수용성 몰리브덴원으로 이루어진 원소원군에서 적어도 1종 이상 선택된 필수미량원소; 및 물을 포함하여 이루어지는 액상 복합비료 조성물 및 이의 시비방법을 제공한다.The present invention is calcium oxide prepared by calcining shell current and energized; At least one essential trace element selected from the group of elements consisting of a water-soluble iron source, a water-soluble chlorine source, a water-soluble boron source, a water-soluble manganese source, a water-soluble zinc source, a water-soluble copper source, and a water-soluble molybdenum source; And it provides a liquid composite fertilizer composition comprising a water and a fertilization method thereof.
본 발명의 액상 복합비료 조성물은 식물체의 품질을 향상하고 병충해 발생을 억제하며, 생산품의 신선도를 유지하고 유통기간의 획기적인 연장과 토양환경을 개선하는 효과가 있다.The liquid composite fertilizer composition of the present invention has the effect of improving the quality of the plant and suppressing the occurrence of pests, maintaining the freshness of the product, and significantly extend the shelf life and improve the soil environment.
액상복합비료조성물, 패각분, 고 활성칼슘, 필수미량원소Liquid complex fertilizer composition, shell meal, high active calcium, essential trace element
Description
도 1은 본 발명에 따른 조성물의 500배(우측)와 1,000배(좌측) 희석액을 엽면시비하여 재배한 쌈추(배추와 양배추의 교잡종)를 나타낸 사진.Figure 1 is a photograph showing the ssamchu (hybrid and cabbage hybrid) cultivated by foliar fertilization of 500 times (right) and 1,000 times (left) dilution of the composition according to the present invention.
본 발명은 고 활성칼슘 및 필수미량원소를 이용한 액상 복합비료 조성물 및 이의 제조방법에 관한 것으로, 보다 상세하게는 농작물의 생장에 필요한 칼슘 보급원의 공급과 필수미량요소의 결핍을 억제하기 위해서, 패각분(貝殼粉) 유래의 산화 칼슘을 포화 용해한 고 활성칼슘액에 필요한 필수미량원소를 선택적으로 첨가한 액상 복합비료 조성물 및 이의 제조방법에 관한 것이다.The present invention relates to a liquid composite fertilizer composition using a high active calcium and essential trace elements, and a method for preparing the same, and more particularly, in order to suppress the supply of calcium supply source and the lack of essential trace elements required for the growth of crops, The present invention relates to a liquid composite fertilizer composition in which an essential trace element is selectively added to a highly active calcium solution obtained by saturatedly dissolving calcium oxide derived from powder and a method for producing the same.
일반적으로 식물은 동물처럼 음식물을 섭취하는 것이 아니라 스스로 양분을 합성하여 사용하는 데, 빛에너지와 공기 중의 이산화탄소와 토양속의 물을 사용하여 포도당을 합성한다.In general, plants do not consume foods like animals, but rather synthesize food by themselves, and synthesize glucose using light energy, carbon dioxide in the air, and water in the soil.
그러나, 식물은 물과 이산화탄소 이외에 식물이 살아가는 데는 반드시 필요한 원소들이 있는데, 식물필수원소 16종이 알려져 있다.However, plants have elements other than water and carbon dioxide, which are essential for the living of plants. 16 kinds of plant essential elements are known.
그리고, 상기 필수원소 16종은 사용량에 따라 탄소, 수소, 산소, 질소, 인, 칼륨, 칼슘, 마그네슘, 황의 다량원소와, 철, 망간, 구리, 아연, 붕소, 몰리브덴,염소의 미량원소로 나누는데, 식물필수원소가 부족할 경우, 식물은 정상적인 생장이 불가능하게 된다.In addition, the 16 essential elements are divided into trace elements of carbon, hydrogen, oxygen, nitrogen, phosphorus, potassium, calcium, magnesium, sulfur, and iron, manganese, copper, zinc, boron, molybdenum, and chlorine according to the amount used. In the absence of plant essential elements, plants cannot grow normally.
따라서, 식물체를 경작하여 이를 생산품으로 하는 농업에 있어서는 상기 필수원소를 강화한 비료를 많이 사용하고 있는 실정이다.Therefore, in farming plants and producing them, many fertilizers using the above-mentioned essential elements are used.
이 중 칼슘은 토양 내에 많이 존재해도 토양의 상태나 환경조건에 따라 흡수나 축적하는데 제한을 받아 지상부에서는 칼슘부족으로 인하여 생리장해가 발생하고 병에 대한 저항력을 감소시키며 과실의 저장력이 약화되는 현상이 나타나는데, 이를 해소하기 위해서 칼슘염을 살포하여 식물체 내 칼슘함량을 증가시키는 방법이 있다.Among them, even though calcium is present in the soil, it is limited to absorption and accumulation according to soil conditions and environmental conditions. Therefore, in the above-ground part, calcium deficiency causes physiological disorders, reduces resistance to disease, and weakens storage capacity of fruits. In order to solve this problem, there is a method of increasing calcium content in plants by spraying calcium salt.
구체적으로 우리나라의 칼슘제는 비료관리법 공정규격에 의해 석회질비료로 소석회 외 6종, 복합비료로는 제4종 복합비료 2종, 기타 비료로 액상석회(엽면시비용)와 수용성 분상석회로 설정되어 있으며, 가장 많이 사용하는 액상석회 비료는 17% 이상의 함량을 보증해야한다.Specifically, the calcium agent in Korea has been set up as 6 types of complex fertilizers including lime, 4 types of complex fertilizers, 4 types of complex fertilizers, and 4 types of fertilizers as liquid lime (leaf surface cost) and water-soluble powdered lime. Most liquid lime fertilizers, however, should guarantee a content of at least 17%.
하지만, 일반적으로 액상석회는 물에 잘 용해되지 않기 때문에 17%를 함유시키기 위해서는 대부분이 침전물로 첨전되어 식물체가 용이하게 이용하기가 어려워져서, 칼슘제의 낭비가 심해지는 문제점이 있다.However, in general, liquid lime does not dissolve well in water, so in order to contain 17% of the liquid lime, most of it is impregnated with sediments, which makes it difficult to easily use plants, which causes a problem of increased waste of calcium.
또한, 최근에는 원가가 싼 질산칼슘제를 많이 이용하고 있는데, 이의 경우는 칼슘과 질소를 동시에 공급할 수 있는 장점이 있어 수경재배에는 적합하나, 우리나 라 밭 토양은 외국과 달리 질소 함량이 기준치보다 과다하기 때문에, 질산염에 의해 토양과 식수 오염이 쉽고, 오염된 식수를 과다하게 섭취할 경우에는 청색증, 발암성물질 생성 및 갑상선비대증이 발생되는 요인으로 작용할 수 있다.In addition, recently, calcium nitrates, which are inexpensive, have been used a lot. In this case, calcium and nitrogen can be supplied at the same time, so it is suitable for hydroponic cultivation. Therefore, soil and drinking water contamination by nitrate is easy, and excessive consumption of contaminated drinking water may act as a factor causing cyanosis, carcinogenic substances and hyperthyroidism.
한편, 필수미량원소에서 철(Fe)이 결핍되면 농작물의 선단엽이나 새로 나온 잎에 나타나며 엽맥은 녹색을 남기는데 엽맥 사이는 담록색에서 황백화로 변하며, 증상이 심해지면 잎 전체가 황백화현상이 발생된다.On the other hand, if iron (Fe) is deficient in essential trace elements, it appears on the front or new leaves of crops, and the leaf veins leave green, and the leaf veins are changed from pale green to yellowish white, and when the symptoms worsen, the whole leaf becomes yellowish. do.
그리고, 붕소(B)가 결핍되면 줄기와 잎이 경화되어 뻣뻣하고 약해져서 자실 낙과가 심해지고 자실의 표면이나 내부에도 장해가 발생하기 쉽다.When boron (B) is deficient, the stems and leaves harden and become stiff and weak, resulting in severe fruit fruit falling, and the occurrence of obstacles on the surface and inside of the fruit fruit.
망간(Mn)은 엽맥 사이가 담록색에서 황색으로 변하거나 식물종에 따라 작은 반점이 발생하는 경우도 있으며, 철 결핍에 의한 황백화와는 달리, 잎이 일찍 말라죽어서 줄기에서 떨어지는 경우가 발생한다.Manganese (Mn) may change from light green to yellow between leaf veins, or small spots may occur depending on plant species. Unlike iron bleaching due to iron deficiency, leaves may dry early and fall from stems.
그리고, 아연(Zn)이 결핍되면 잎이 작아지거나 로젯 모양이 되고 때로는 엽맥 사이가 담록색에서 황색으로 변하며, 잎맥 사이에서 반점이 발생하여 빠르게 퍼지면 잎은 두꺼워지게 된다.In addition, when zinc (Zn) is deficient, the leaves become smaller or rosette-shaped, and sometimes between the veins turn from pale green to yellow, and spots occur between the leaf veins, which spread quickly, and the leaves become thick.
구리(Cu)는 결핍 시 상위엽의 엽맥 사이에 작은 반점모양의 황백화가 발생되며, 선단엽은 녹색이 엷어지고 시들어서 아래로 처지게 되고, 결핍증이 심하게 되면 선단엽은 낙하산잎 증상을 나타낸다.In case of copper deficiency, small spot-like yellowing occurs between the upper lobes of the upper lobe, and the tip leaves become thin and wilted and sag down, and when the deficiency becomes severe, the tip leaves show parachute leaf symptoms.
그리고, 몰리브덴(Mo)이 결핍되면 잎 전체가 먼저 녹색을 잃고 황화되며 잎 끝은 위로 구부러진다. 그리고 엽맥 근처가 담록색으로 남고 또 엽맥 사이가 구름과 같이 퇴색된다. 그리고 다른 원소결핍증과 달리 잎 조직이 괴사되고 더 심해지 면 생장점도 괴사되는 문제점이 발생한다.And, if molybdenum (Mo) is deficient, the entire leaf first loses its green color and is yellowed, and the leaf tip is bent upward. The veins near the veins remain pale green and the veins between the veins fade like clouds. And, unlike other elemental deficiencies, necrosis and worsening of leaf tissue causes necrosis of growth points.
따라서, 상기와 같은 문제점을 해결하기 위해서는 질산칼슘으로 제조하지 않으면서 식물체가 용이하게 이용할 수 있는 칼슘 수용액과 상기 칼슘 수용액에 최소량의 필수미량원소를 함유시켜 식물체 생장에 최대 효과를 나타낼 수 있는 액상 복합비료 조성물의 개발이 필요하게 되었다.Therefore, in order to solve the above problems, a liquid complex which can exhibit the maximum effect on plant growth by containing a minimum amount of essential trace elements in the aqueous calcium solution and the calcium aqueous solution that can be easily used by plants without manufacturing with calcium nitrate There is a need for the development of fertilizer compositions.
상기와 같은 문제점을 해결하기 위해, 본 발명자는 식물체에 최소량으로 사용하여 최대의 효과를 얻을 수 있는 칼슘 수용액을 제조하고, 상기 칼슘 수용액에 필수미량원소를 선택적으로 포함하여 식물체의 품질을 향상시키고, 병충해 발생을 억제하며, 생산품의 신선도를 유지하고 유통기간을 획기적으로 연장하며, 농약 및 비료의 사용을 최대한 억제할 수 있어 토양 환경을 개선할 수 있는 액상 복합비료 조성물을 개발하고자 하였으며, 이를 완성하였다.In order to solve the above problems, the present inventors produce a calcium aqueous solution that can be used to obtain the maximum effect by using the minimum amount in the plant, and optionally include the essential trace elements in the calcium aqueous solution to improve the quality of the plant, We aimed to develop a liquid complex fertilizer composition that can improve the soil environment by suppressing the occurrence of pests, maintaining the freshness of products, significantly extending the shelf life, and minimizing the use of pesticides and fertilizers. .
따라서, 본 발명의 목적은 패각분을 소성하고 통전하여 제조된 산화칼슘과;Therefore, an object of the present invention is calcium oxide prepared by firing and energizing shell shell;
수용성 철원, 수용성 염소원, 수용성 붕소원, 수용성 망간원, 수용성 아연원, 수용성 구리원 및 수용성 몰리브덴원으로 이루어진 원소원군에서 적어도 1종 이상 선택된 필수미량원소; 및 물을 포함하여 이루어지는 액상 복합비료 조성물을 제공하는 것이다.At least one essential trace element selected from the group of elements consisting of a water-soluble iron source, a water-soluble chlorine source, a water-soluble boron source, a water-soluble manganese source, a water-soluble zinc source, a water-soluble copper source, and a water-soluble molybdenum source; And it provides a liquid composite fertilizer composition comprising water.
또한, 본 발명의 다른 목적은 상기 조성물을 희석하여 엽면시비 또는 토양관수 중 선택된 방법으로 식물에 사용하는 액상 복합비료의 시비방법을 제공하는 것이다.In addition, another object of the present invention is to provide a method for fertilizing a liquid complex fertilizer for use in plants by the method of diluting the composition by foliar fertilization or soil irrigation.
상기와 같은 목적을 달성하기 위하여, 본 발명은 패각분을 소성하고 통전하여 제조된 산화칼슘과; 수용성 철원, 수용성 염소원, 수용성 붕소원, 수용성 망간원, 수용성 아연원, 수용성 구리원 및 수용성 몰리브덴원으로 이루어진 원소원군에서 적어도 1종 이상 선택된 필수미량원소; 및 물을 포함하여 이루어지는 액상 복합비료 조성물을 제공한다.In order to achieve the above object, the present invention is a calcium oxide prepared by firing and energizing shell shell; At least one essential trace element selected from the group of elements consisting of a water-soluble iron source, a water-soluble chlorine source, a water-soluble boron source, a water-soluble manganese source, a water-soluble zinc source, a water-soluble copper source, and a water-soluble molybdenum source; And it provides a liquid composite fertilizer composition comprising water.
또한, 다른 목적을 달성하기 위하여, 본 발명은 조성물을 증류수 또는 통상의 물 중 선택된 용매에 600∼1,200배로 희석하고, 상기 희석한 조성물을 엽면시비 또는 토양관수 중 선택된 방법으로 식물에 시비하는 방법을 제공한다.In addition, in order to achieve another object, the present invention is a method of diluting the composition in a solvent selected from distilled water or ordinary water 600 to 1,200 times, and the method of fertilizing the diluted composition to the plant by a method selected from foliar fertilization or soil irrigation to provide.
이하, 본 발명을 상세히 설명하기로 한다.Hereinafter, the present invention will be described in detail.
이때, 사용되는 기술 용어 및 과학 용어에 있어서 다른 정의가 없다면, 이 발명이 속하는 기술 분야에서 통상의 지식을 가진 자가 통상적으로 이해하고 있는 의미를 가진다.At this time, if there is no other definition in the technical terms and scientific terms used, it has a meaning commonly understood by those of ordinary skill in the art.
또한, 종래와 동일한 기술적 구성 및 작용에 대한 반복되는 설명은 생략하기로 한다.In addition, repeated description of the same technical configuration and operation as in the prior art will be omitted.
본 발명은 패각류로부터 식물체가 가장 잘 흡수할 수 있는 완전 용해 상태인 수산화칼슘 수용액을 제조하여, 식물체에 작은 농도의 칼슘 수용액을 사용하여도 식물체에서 칼슘결핍증이 발생하지 않고 병에 대한 저항력을 갖게 하며, 생산 후에도 생산품의 신선도 유지 및 유통기간의 획기적인 연장이 가능한 효과를 제공하면서, 과도한 사용으로 인한 토양의 오염을 방지한다. The present invention produces a fully dissolved calcium hydroxide aqueous solution that can be best absorbed by the plant from the shellfish, even if a small amount of calcium aqueous solution is used in the plant does not cause calcium deficiency in the plant and has resistance to disease This prevents soil contamination from excessive use while providing the effect of maintaining the freshness of products and significantly extending their shelf life even after production.
그리고, 상기 수산화칼슘 수용액에 외부 조건에 따라 식물체에 필요한 필수미량원소군에서 적어도 1개 이상의 원소를 토양 등의 외부 조건에 따라 선택하여 포함시킴으로써, 마그네슘, 철 등 각종 미네랄이 종합적으로 배합된 이상적인 밸런스를 이룬 액상 복합비료 조성물이 제조되게 한다.In addition, by containing at least one element from the essential trace element group required for the plant according to external conditions in the aqueous solution of calcium hydroxide according to the external conditions such as soil, an ideal balance in which various minerals such as magnesium and iron are combined A liquid composite fertilizer composition is achieved.
이와같이, 본 발명에 따라 제조된 액상 복합비료 조성물은 경작지에 있어서, 연작(連作)과 비료의 과다사용으로 인한 토양 오염을 완화시키고 토양환경을 개선하며, 농약과 비료사용을 최대한 조절하면서 식물체의 생장을 촉진하므로 유기농업 구현이 가능할 수 있게 한다.As such, the liquid composite fertilizer composition prepared according to the present invention, in the arable land, to alleviate soil contamination and improve the soil environment due to excessive use of the fertilizer (과 作) and fertilizer, and to improve the growth of the plant while maximizing the use of pesticides and fertilizers To promote organic farming.
그리고, 본 발명에서 사용되는 산화칼슘은 종래 산화칼슘과는 달리 물에 용해될 수 있는 수용성의 특성을 갖고 있기 때문에, 종래 산화칼슘과 구분하기 위해 고 활성칼슘이라 칭하기로 한다.In addition, since calcium oxide used in the present invention has a water-soluble property that can be dissolved in water, unlike conventional calcium oxide, it will be referred to as high active calcium to distinguish it from conventional calcium oxide.
그리고, 고 활성칼슘을 제조하기 위해서 본 발명에서는 패각류를 깨끗이 수세하고 건조한 다음, 곱게 분쇄한다.In the present invention, shells are washed with water, dried, and then finely ground to produce high active calcium.
이때, 상기 패각분의 입경은 1∼5㎜로 사용하는 것이 바람직한데, 1㎜미만인 경우에는 가루가 날리기 쉬어 작업성이 좋지 않고, 5㎜를 초과한 경우에는 소성시간이 연장되고 소성효율도 더 이상 증가하지 않기 때문이다.At this time, the shell diameter of the shell powder is preferably used to 1 ~ 5mm, when less than 1mm powder is easy to fly, workability is not good, when exceeding 5mm the firing time is extended and the firing efficiency is further Because it does not increase over.
그리고 본 발명은 상기 패각분을 로(爐)에 넣고 1,200∼1,800℃에서 소성하여 패각분의 탄산칼슘에서 탄산가스를 제거하고, 산화철 등의 불순물을 휘산시켜 순도 높은 산화칼슘을 생산하는 단계와, 상기 제조된 산화칼슘을 통전기에 넣고 20,000∼100,000 V의 전압에서 통전시키는 단계를 거쳐 본 발명의 고 활성칼슘을 제조한다.And the present invention is to put the shell powder in the furnace (bak) and calcined at 1,200 ~ 1,800 ℃ to remove the carbon dioxide gas from the calcium carbonate of the shell powder, volatilizing impurities such as iron oxide to produce a high purity calcium oxide, The prepared calcium oxide is put into an electricity collector and subjected to a step of energizing at a voltage of 20,000 to 100,000 V to prepare the high active calcium of the present invention.
그리고, 본 발명에 따라 제조된 활성칼슘은 다른 산화칼슘과는 달리 물 1ℓ에 800∼1,200㎎이 완전 용해되는 수용성 칼슘의 특성을 갖는다.The activated calcium prepared according to the present invention, unlike other calcium oxide, has the property of water-soluble calcium in which 800 to 1,200 mg is completely dissolved in 1 L of water.
이때, 본 발명에서는 소성온도 범위로 1200∼1,800℃를 유지하고 바람직하게는 1,500℃를 유지하는 데, 이는 1,200℃ 미만일 경우에는 온도하향에 따른 탄산가스 제거효율 저하되어 소성 기간이 길어지고, 1,800℃를 초과하면 온도 상승효과가 미미하기 때문이다.At this time, the present invention maintains 1200 ~ 1,800 ℃ in the firing temperature range and preferably maintain 1,500 ℃, which is less than 1,200 ℃ when the carbon dioxide gas removal efficiency is lowered due to the temperature is lowered, the firing period is longer, 1,800 ℃ This is because the temperature increase effect is insignificant.
그리고, 소성시간은 패각분에서 더 이상의 탄산가스가 배출되지 않는 시점까지 수행하는 데, 약 1∼3 시간동안 수행하는 것이 효율적으로 바람직하다.And, the firing time is carried out to the point where no more carbon dioxide gas is discharged from the shell powder, it is preferably performed for about 1 to 3 hours.
또한, 본 발명에서 상기 통전기(通電器)로는 고전압 출력기를 탄소 판(carbon plate)에 연결하여 통전시킴으로써 산화칼슘에 고전압을 인가할 수 있는 장치를 사용하는 것이 바람직하고, 상기 통전기를 통하여 산화칼슘을 20,000∼100,000 V의 고전압 범위에서 통전시키는 데, 고전압으로 인한 열과 전기에너지가 산화칼슘에 인가되면 산화칼슘 내의 원자간 인력을 약화시켜 산화칼슘의 수용성을 향상시키게 된다.In the present invention, it is preferable to use a device capable of applying a high voltage to calcium oxide by energizing a high voltage output device to a carbon plate as the current collector, and oxidizing the current through the current collector. The calcium is energized in the high voltage range of 20,000 to 100,000 V. When heat and electrical energy due to the high voltage are applied to the calcium oxide, the interatomic attraction in the calcium oxide is weakened to improve the calcium oxide solubility.
이때, 본 발명에서는 고전압의 범위로 20,000∼100,000 V를 유지하여 통전시키고 바람직하게는 30,000 V로 통전시키는 데, 이는 20,000V 미만인 경우에는 수용성의 활성칼슘을 수득하는 효율이 저하되고, 100,000V를 초과하면 초과 볼트(V)에 따른 활성칼슘의 수득효과가 미미하기 때문이다.At this time, in the present invention, the current is maintained by maintaining 20,000 to 100,000 V in the range of high voltage, preferably at 30,000 V, which is less than 20,000 V, the efficiency of obtaining water-soluble activated calcium is lowered, and exceeds 100,000 V. This is because the effect of obtaining the active calcium according to the excess volts (V) is insignificant.
그리고, 본 발명에 따라 제조된 활성칼슘은 물 1ℓ에 800∼1,200㎎을 포화 용해시켜 수산화칼슘 수용액 제조의 칼슘원으로 사용된다.In addition, the activated calcium prepared according to the present invention is used as a calcium source in the preparation of calcium hydroxide aqueous solution by dissolving 800-1,200 mg in 1 L of water.
한편, 본 발명에서는 식물생육에 필수적인 미량원소로 공지된 철(Fe), 염소(Cl), 붕소(B), 망간(Mn), 아연(Zn), 구리(Cu) 및 몰리브덴(Mo)을 외부 환경조건, 예를 들면 토양의 종류에 따라서 미량원소의 결핍현상이 예상되는 곳에 필요한 미량원소를 선택하여 본 발명에 따른 수산화칼슘 수용액에 포함하여 사용한다.Meanwhile, in the present invention, iron (Fe), chlorine (Cl), boron (B), manganese (Mn), zinc (Zn), copper (Cu) and molybdenum (Mo), which are known as trace elements essential for plant growth, are external. Depending on the environmental conditions, for example, the type of soil, the microelements are selected where the deficiency of trace elements is expected to be used and included in the aqueous calcium hydroxide solution according to the present invention.
이때, 상기 식물생육의 필수적인 미량원소는 수용성 철원, 수용성 염소원, 수용성 붕소원, 수용성 망간원, 수용성 아연원, 수용성 구리원 및 수용성 몰리브덴원에서 채택된 원소를 사용하여 수산화칼슘 수용액에 혼합 및 액화하여 사용하는 데, 그 예로서 수용성 철원은 황산제일철, 구연산철 및 EDTA-Fe(킬레이트철)을 선택하여 사용하고, 수용성 염소원은 염소산나트륨(NaClO3)을 사용하며, 수용성 붕소원은 붕사(borax;Na2B4O7·10H2O) 또는 붕산(boric acid;H 3BO3)을 사용하고, 수용성 망간원은 황산망간 또는 킬레이트 망간(EDTA-Mn)을 사용하며, 수용성 아연원은 황산아연 또는 킬레이트 아연(EDTA-Zn)을 사용하고, 수용성 구리원은 황산동을 사용하며 수용성 몰리브덴원은 몰리브덴산 암모늄계[ammonium molybdate;(NH4)2O·mMoO·nH2O] 또는 몰리브덴산소다(Sodium molybdate; Na2MoO4·2H2O)를 사용하는 것이 바람직하다.At this time, the essential trace elements of the plant growth is mixed and liquefied in an aqueous calcium hydroxide solution using elements selected from water soluble iron source, water soluble chlorine source, water soluble boron source, water soluble manganese source, water soluble zinc source, water soluble copper source and water soluble molybdenum source. For example, the water-soluble iron source is selected from ferrous sulfate, ferric citrate and EDTA-Fe (iron chelate), the water-soluble chlorine source uses sodium chlorate (NaClO 3 ), the water-soluble boron source is borax (borax) ; Na 2 B 4 O 7 10H 2 O) or boric acid (H 3 BO 3 ) is used, the water-soluble manganese source is manganese sulfate or chelate manganese (EDTA-Mn), the water-soluble zinc source is sulfuric acid Zinc or chelate zinc (EDTA-Zn) is used, the water soluble copper source uses copper sulfate, and the water soluble molybdenum source is ammonium molybdate (NH 4) 2 OmMoO nH 2 O or sodium molybdate (Sodium molybdate). ; Preference is given to using Na 2 MoO 4 .2H 2 O).
또한, 본 발명에서는 상기 미네랄의 사용량을 수용성 철원은 500∼1,000㎎, 수용성 염소원은 500∼1,000㎎, 수용성 붕소원은 500∼1,000㎎, 수용성 망간원은 500∼1,000㎎, 수용성 아연원은 500∼1,000㎎, 수용성 구리원은 500∼1,000㎎ 및 수용성 몰리브덴원은 5∼10㎎로 하는 것이 바람직한데, 이는 본 발명에 따른 조성물을 희석하여 사용할 경우, 식물에 필요한 적절한 미량원소의 필요량이 되기 때문이다.In the present invention, the amount of the mineral used is 500 to 1,000 mg of water soluble iron source, 500 to 1,000 mg of water soluble chlorine source, 500 to 1,000 mg of water soluble boron source, 500 to 1,000 mg of water soluble manganese source, 500 of water soluble zinc source. It is preferable to use -1000 mg, water-soluble copper source 500-1,000 mg, and water-soluble molybdenum source 5-10 mg, since the required amount of the appropriate trace element required for plants is diluted when the composition according to the present invention is diluted. to be.
그리고, 본 발명의 조성물은 600∼1,200배로 희석하여 원액의 과다사용에 따른 식물체의 과도한 성분의 흡수를 방지한다.Then, the composition of the present invention is diluted 600 to 1,200 times to prevent the absorption of excess components of the plant due to overuse of the stock solution.
이때, 상기 희석용매는 통상의 물 또는 증류수를 사용할 수 있는데, 사용농가의 편리성 등을 고려하여 수돗물, 저수지물, 우물물 등을 사용하는 것이 바람직하다.At this time, the diluting solvent may be used ordinary water or distilled water, it is preferable to use tap water, reservoir water, well water, etc. in consideration of the convenience of the farm.
그리고, 본 발명에 따른 조성물의 유효량은 재배상태나 외부조건 등에 따라 횟수나 사용량이 달라질 수 있어, 한정되는 것은 아니나, 통상적으로 1회에 희석액을 평당 2리터를 사용하는 것이 바람직하다.In addition, the effective amount of the composition according to the present invention may vary depending on the cultivation state or external conditions, etc., but is not limited, but it is usually preferred to use 2 liters per square diluent at a time.
이와 같이, 본 발명에 따라 제조된 액상 복합비료 조성물은 식물체가 가장 잘 흡수하는 칼슘이온(Ca2+)을 함유하고 있어, 각종 식물체의 생장을 촉진하며, 식물체의 체세포를 치밀하게 하여 품질을 향상시키고, 병충해 발생의 억제 및 예방효과를 갖는다.As described above, the liquid composite fertilizer composition prepared according to the present invention contains calcium ions (Ca 2+ ) which are best absorbed by plants, thereby promoting the growth of various plants and densifying somatic cells of the plants to improve their quality. And inhibits and prevents the development of pests.
그리고, 생산품의 신선도를 유지하고 유통기간의 획기적인 연장이 가능하도록 하며, 농약과 비료사용을 최대한 조절할 수 있기 때문에, 연작과 비료의 과다사용으로 인한 토양 산성화와 경질화를 완화시키고 토양환경을 개선하면서 유기농업 구현을 가능하게 한다.In addition, to maintain the freshness of the product, and to significantly extend the shelf life, and to control the use of pesticides and fertilizers as much as possible, while reducing the acidification and hardening of the soil caused by excessive use of crops and fertilizers, while improving the soil environment Enable organic farming.
또한, 본 발명의 조성물은 인체나 식물체에 대하여 독성이 전혀 없어, 남녀노소 누구라도 용이하게 사용해도 된다.In addition, the composition of the present invention is not toxic to humans or plants at all, and may be easily used by anyone of men and women of all ages.
이하, 실시 예를 통하여 본 발명을 더욱 상세히 설명한다. 하지만, 실시 예는 오로지 본 발명을 구체적으로 설명하기 위한 것으로, 이들 실시예의 범위가 본 발명에 국한되지는 않는다.Hereinafter, the present invention will be described in more detail with reference to the following examples. However, the examples are only for illustrating the present invention in detail, and the scope of these examples is not limited to the present invention.
또한, 반복적인 설명인 경우에는 생략한다.In addition, it abbreviate | omits when it is repeated description.
[실시예 1] 고 활성칼슘 제조Example 1 Preparation of Highly Active Calcium
평균 입경이 3㎜인 패각분을 전기로에 넣고 1,800℃에서 3시간동안 소성을 하였고, 상기 소성물을 고전압이 인가되는 탄소판 위에 올려놓고 30,000 V에서 60분동안 통전하였다.The shell powder having an average particle diameter of 3 mm was placed in an electric furnace, and fired at 1,800 ° C. for 3 hours. The fired product was placed on a carbon plate to which high voltage was applied and energized at 30,000 V for 60 minutes.
[실시예 2] 액상 복합비료 조성물 제조Example 2 Preparation of Liquid Composite Fertilizer Composition
상기 실시예 1에 의해 완성된 고 활성칼슘을 증류수 1ℓ에 800㎎을 넣고 완전히 용해하여 수산화칼슘 수용액을 제조하고, 상기 칼슘 수용액에 붕산(H3BO3) 500㎎과 몰리브덴산 소다(Na2MoO4·2H2O)를 첨가하여 혼합하여 본 발명에 따른 액상 복합비료 조성물을 완성하였다.800 mg of the high active calcium prepared in Example 1 was added to 1 L of distilled water and completely dissolved to prepare an aqueous calcium hydroxide solution. 500 mg of boric acid (H 3 BO 3 ) and sodium molybdate (Na 2 MoO 4 ) were added to the aqueous calcium solution. 2H 2 O) was added and mixed to complete the liquid composite fertilizer composition according to the present invention.
[실험예 1]Experimental Example 1
본 실험예는 상기 실시예 1에서 완성된 활성 칼슘의 물리적인 특성을 하기 표 1의 측정항목에 대하여 측정하고, 종래의 산화칼슘과 비교하여 차이점을 알아보고자 하였다.In this experimental example, the physical properties of the activated calcium completed in Example 1 were measured for the measurement items shown in Table 1 below, and compared with the conventional calcium oxide, to find out the difference.
이때, pH는 1ℓ의 증류수에 산화칼슘 1g을 용해하고 pH를 측정하였으며, 반응속도는 8시간동안 산화칼슘이 물에 용해되어 감소하는 양을 시간마다 측정하고 이를 1시간당 감소한 양으로 나타내었다.At this time, the pH was dissolved 1g of calcium oxide in 1 liter of distilled water and the pH was measured, and the reaction rate was measured every hour for the amount of calcium oxide dissolved in water for 8 hours and expressed as a reduced amount per hour.
이의 결과, 본 발명의 pH가 종래의 칼슘보다 매우 높고, 반응속도는 약 3배이상, 전도도에 있어서는 무려 18배나 우수한 것을 알 수 있었으며, 이는 본 발명의 활성 칼슘의 흡수율과 용해성이 아주 우수하다는 것을 입증한 것이다. As a result, it was found that the pH of the present invention is much higher than that of conventional calcium, and the reaction rate is about 3 times or more and 18 times higher in conductivity, which is very excellent in the absorption rate and solubility of the active calcium of the present invention. It is proven.
[실험예 2] Experimental Example 2
본 실험예는 상기 실시예 2에서 완성된 액상 복합비료 조성물을 물로 500배와 1,000배로 희석하고, 이를 경작물에 시비하여 그 효과를 알아보고자 하였다.This experimental example was to dilute the liquid composite fertilizer composition completed in Example 2 to 500 times and 1,000 times with water, and to fertilize it to the crops to find the effect.
(1) 쌈추의 엽면 시비(1) leaf foliar fermentation
배추와 양배추의 교잡종인 쌈추를 충청도의 한 재배농가에서 재배하면서 통상적인 엽면 시비의 방법으로 본 발명의 액상 복합비료 조성물을 사용하였다.The hybrid composite fertilizer composition of the present invention was used as a conventional method of foliar fertilization while ssamchugi, a hybrid of cabbage and cabbage, was grown in a cultivated farm in Chungcheong-do.
그 결과, 500배와 1,000배 희석액 시비군에서 종래 시비하지 않고 재배하였을 경우의 병충해 발생 빈도보다 육안으로 확인될 정도로 낮아짐을 확인할 수 있었으며(미도시), 도 1에서 도시된 바와 같이, 실험군에 있어서는 1,000배 희석군이 500배 희석군보다 생장 및 발육 정도가 더욱 우수한 것을 알 수 있었다.As a result, it was confirmed that the frequency of insect pests when cultivated without conventional fertilization in the 500- and 1,000-fold dilution fertilization group was as low as visually confirmed (not shown), as shown in Figure 1, in the experimental group The 1,000-fold dilution group showed better growth and development than the 500-fold dilution group.
[실험예 2] 생산품의 신선도 및 유통기간 연장효과Experimental Example 2 Extension of Freshness and Shelf Life of Products
본 발명의 비료 조성물을 시비하여 재배한 방울토마토와 상추의 기호도와 신선도 및 유통가능 기간을 알아보고자 패널 테스트(장건형, 식품의 기호성 관능검사, 개문사, 1975)와 시간경과에 따른 생산품 외관의 변형 유무를 병행 실시하였다.In order to determine the palatability, freshness and shelf life of cherry tomatoes and lettuce grown by fertilizing the fertilizer composition of the present invention, the panel test (janggyeong type, palatability sensory test of food, introductory history, 1975) and the modification of the appearance of the product over time The presence or absence was performed in parallel.
이때, 상기 패널 테스트는 지원자 20명(남자 2명, 여자 18명)을 대상으로 본 발명에 따른 생산품과 종래 생산품을 각각 섭취하도록 한 다음, 맛(상추는 식감), 외관에 대한 기호도를 측정하게 하고, 이의 결과를 5점 척도법으로 하기 표 2에 나타내었다.At this time, the panel test is to take the products according to the present invention and the conventional products for 20 applicants (two men, 18 women), and then measure the taste (the lettuce texture), the degree of appearance for appearance The results are shown in Table 2 below using a five-point scale method.
또한, 본 발명에 따른 방울토마토와 상추는 비닐하우스에서 재배하는 재배농가에 의뢰하여, 1,000배를 희석한 본 발명의 조성물을 통상적인 시비방법으로 1회에 평당 2리터로 관수 및 분사하여 재배한 것을 사용하였으며, 비교예는 시중에서 판매되고 있는 상품을 구입하여 실험에 사용하였다.In addition, the cherry tomatoes and lettuce according to the present invention was cultivated by irrigation and spraying at a rate of 2 liters per square water at a time by the conventional fertilizing method of the composition of the present invention, which was diluted 1,000 times by the cultivation farm grown in a plastic house In the comparative example, a commercially available product was purchased and used in an experiment.
또한, 유통기간은 3일 단위로 상온에서 보관한 다음, 최종 3주일동안 외관 변형의 추이를 육안으로 확인하였다.In addition, the shelf life was stored at room temperature for three days, and then visually confirmed the change in appearance deformation during the final three weeks.
그리고, 이의 결과를 하기 표 3에 나타내었다.And the results thereof are shown in Table 3 below.
이와같이, 본 발명에 따라 제조된 액상 복합비료 조성물은 식물체의 품질을 향상시키고, 병충해 발생의 억제 및 예방효과를 가지며, 생산품의 신선도를 유지하고 유통기간의 획기적인 연장이 가능한 것을 알 수 있었다.As such, the liquid composite fertilizer composition prepared according to the present invention was found to improve the quality of the plant, to have the effect of suppressing and preventing the occurrence of pests, to maintain the freshness of the product and to significantly extend the shelf life.
뿐 만아니라, 농약과 비료사용을 최대한 조절할 수 있어, 연작과 비료의 과다사용으로 인한 토양오염을 완화시키고 토양환경을 개선할 수 있을 것으로 예상된다.In addition, it is expected that the use of pesticides and fertilizers can be controlled as much as possible, so as to alleviate soil pollution and improve the soil environment due to excessive use of crops and fertilizers.
이상과 같이, 본 발명의 액상 복합비료 조성물은 식물체의 품질을 향상시키고 병충해 발생을 억제하며, 생산품의 신선도를 유지하고 유통기간의 획기적인 연장 효과가 있다.As described above, the liquid composite fertilizer composition of the present invention improves the quality of the plant and suppresses the occurrence of pests, maintains the freshness of the product and has a significant extension of the shelf life.
더 나아가, 본 발명은 효과에 비하여 사용량이 적기 때문에 농약 및 비료의 사용을 최대한 억제할 수 있어 토양환경을 개선할 수 있다. Furthermore, the present invention can reduce the use of pesticides and fertilizers as much as possible because the amount is less than the effect can improve the soil environment.
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| KR1020040074659A KR100634334B1 (en) | 2004-09-17 | 2004-09-17 | Liquid complex fertilizer composition using high active calcium and essential trace elements |
| PCT/KR2005/003086 WO2006080614A1 (en) | 2004-09-17 | 2005-09-16 | A aqueous composite fertilizer with high activated calcium and micro-element |
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| KR20220078373A (en) | 2020-12-03 | 2022-06-10 | 농업회사법인 주식회사 쉘바이오텍 | Manufacturing method of highly activated Calcium ionic solution |
| KR102603982B1 (en) | 2023-06-28 | 2023-11-21 | 폿츠컴퍼니 주식회사 | Fertilizer composition containing active ingredients of oyster shells |
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| US8025966B2 (en) | 2008-02-29 | 2011-09-27 | The Procter & Gamble Company | Fibrous structures |
| US7811665B2 (en) | 2008-02-29 | 2010-10-12 | The Procter & Gamble Compmany | Embossed fibrous structures |
| US7960020B2 (en) | 2008-02-29 | 2011-06-14 | The Procter & Gamble Company | Embossed fibrous structures |
| KR101117864B1 (en) * | 2011-03-28 | 2012-03-09 | 윤상용 | Rice having high persentage of fe, ca, and method for growing a rice plant |
| KR101657653B1 (en) * | 2015-02-25 | 2016-09-22 | 서옥명 | Composition of calcium agent for preventing physiological disorder of apple tree |
| KR102130706B1 (en) * | 2018-06-11 | 2020-07-06 | 안상우 | Preparation method of slow-release fertilizer using oyster shells |
| CN109852395B (en) * | 2019-03-15 | 2021-04-02 | 深圳市芭田生态工程股份有限公司 | Oyster shell powder and preparation method thereof, soil heavy metal passivator and organic fertilizer |
| KR102544269B1 (en) * | 2021-05-06 | 2023-06-19 | 한국생산기술연구원 | An apparatus for simultaneously producing calcium-based material and activated carbon using a shell, and a method for simultaneously producing calcium-based material and activated carbon using the same |
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| JPS5697231A (en) * | 1979-12-31 | 1981-08-05 | Koji Mitsuo | Preparation of solid or liquid substance usable as drug, food, cosmetic, feed, fertilizer, etc. |
| KR920000307A (en) * | 1990-06-05 | 1992-01-29 | 이노우에 란고 | Liquid medicine containing calcium ion composition |
| JPH07228506A (en) * | 1993-04-28 | 1995-08-29 | Honichi Muramatsu | Ion contained in minerals, and method for producing active agent applying electromagnetic wave |
| KR100270228B1 (en) * | 1996-10-04 | 2000-10-16 | 이규헌 | Process for producing calcium oxide |
| JP2000072610A (en) * | 1998-08-31 | 2000-03-07 | Daikei Shokuhin:Kk | Germicide, its production, toothphase, sterilizing water, sterilization of food, sterilization and preservation of seed, food containing baked scallop shell and its production |
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| KR102603982B1 (en) | 2023-06-28 | 2023-11-21 | 폿츠컴퍼니 주식회사 | Fertilizer composition containing active ingredients of oyster shells |
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