KR100577841B1 - Composting method of organic waste such as food waste - Google Patents
Composting method of organic waste such as food waste Download PDFInfo
- Publication number
- KR100577841B1 KR100577841B1 KR1020030005374A KR20030005374A KR100577841B1 KR 100577841 B1 KR100577841 B1 KR 100577841B1 KR 1020030005374 A KR1020030005374 A KR 1020030005374A KR 20030005374 A KR20030005374 A KR 20030005374A KR 100577841 B1 KR100577841 B1 KR 100577841B1
- Authority
- KR
- South Korea
- Prior art keywords
- fermentation
- microorganisms
- corrosive
- tank
- composting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000010815 organic waste Substances 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 title claims abstract description 20
- 238000009264 composting Methods 0.000 title claims abstract description 14
- 239000010794 food waste Substances 0.000 title claims abstract description 13
- 244000005700 microbiome Species 0.000 claims abstract description 81
- 238000000855 fermentation Methods 0.000 claims abstract description 36
- 230000004151 fermentation Effects 0.000 claims abstract description 36
- 239000002361 compost Substances 0.000 claims abstract description 18
- 230000008569 process Effects 0.000 claims abstract description 17
- 239000002689 soil Substances 0.000 claims abstract description 17
- 230000032683 aging Effects 0.000 claims abstract description 12
- 230000005070 ripening Effects 0.000 claims abstract description 12
- 238000009629 microbiological culture Methods 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000654 additive Substances 0.000 claims abstract description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 16
- 239000011707 mineral Substances 0.000 claims description 16
- 230000000813 microbial effect Effects 0.000 claims description 13
- 239000001963 growth medium Substances 0.000 claims description 9
- 239000008188 pellet Substances 0.000 claims description 6
- 230000004913 activation Effects 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 230000008961 swelling Effects 0.000 claims description 5
- 230000003213 activating effect Effects 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 238000005273 aeration Methods 0.000 claims description 3
- 230000004907 flux Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000003415 peat Substances 0.000 claims description 3
- 238000003860 storage Methods 0.000 claims description 3
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims 1
- 239000010802 sludge Substances 0.000 claims 1
- 238000011144 upstream manufacturing Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 15
- 239000003518 caustics Substances 0.000 abstract description 11
- 239000002207 metabolite Substances 0.000 abstract description 9
- 230000031068 symbiosis, encompassing mutualism through parasitism Effects 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000011033 desalting Methods 0.000 abstract description 3
- 230000035800 maturation Effects 0.000 abstract description 2
- 239000004067 bulking agent Substances 0.000 abstract 1
- 230000018044 dehydration Effects 0.000 abstract 1
- 238000006297 dehydration reaction Methods 0.000 abstract 1
- 238000002203 pretreatment Methods 0.000 abstract 1
- 231100001010 corrosive Toxicity 0.000 description 20
- 238000006243 chemical reaction Methods 0.000 description 17
- 235000019645 odor Nutrition 0.000 description 14
- 230000012010 growth Effects 0.000 description 11
- 239000000463 material Substances 0.000 description 7
- 230000008635 plant growth Effects 0.000 description 7
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000011368 organic material Substances 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- 244000000010 microbial pathogen Species 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 241000607479 Yersinia pestis Species 0.000 description 4
- 230000002503 metabolic effect Effects 0.000 description 4
- 150000008442 polyphenolic compounds Chemical class 0.000 description 4
- 102000004169 proteins and genes Human genes 0.000 description 4
- 108090000623 proteins and genes Proteins 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- 241000233866 Fungi Species 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 230000003042 antagnostic effect Effects 0.000 description 3
- 235000014633 carbohydrates Nutrition 0.000 description 3
- 238000012258 culturing Methods 0.000 description 3
- 235000013601 eggs Nutrition 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 235000005985 organic acids Nutrition 0.000 description 3
- 239000011782 vitamin Substances 0.000 description 3
- 235000013343 vitamin Nutrition 0.000 description 3
- 229940088594 vitamin Drugs 0.000 description 3
- 229930003231 vitamin Natural products 0.000 description 3
- 241000186361 Actinobacteria <class> Species 0.000 description 2
- 241000194106 Bacillus mycoides Species 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
- 241000228168 Penicillium sp. Species 0.000 description 2
- 241000589774 Pseudomonas sp. Species 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 238000010564 aerobic fermentation Methods 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 229940088710 antibiotic agent Drugs 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- -1 carbohydrate compounds Chemical class 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000005556 hormone Substances 0.000 description 2
- 229940088597 hormone Drugs 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000000693 micelle Substances 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 150000004053 quinones Chemical class 0.000 description 2
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 1
- 241000228245 Aspergillus niger Species 0.000 description 1
- 102000030523 Catechol oxidase Human genes 0.000 description 1
- 108010031396 Catechol oxidase Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241000223218 Fusarium Species 0.000 description 1
- 241001558145 Mucor sp. Species 0.000 description 1
- 241000863434 Myxococcales Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 102000004316 Oxidoreductases Human genes 0.000 description 1
- 108090000854 Oxidoreductases Proteins 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 210000003855 cell nucleus Anatomy 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000007952 growth promoter Substances 0.000 description 1
- 239000003864 humus Substances 0.000 description 1
- 230000003100 immobilizing effect Effects 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000003307 slaughter Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F9/00—Fertilisers from household or town refuse
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
- C05F11/08—Organic fertilisers containing added bacterial cultures, mycelia or the like
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Fertilizers (AREA)
Abstract
본 발명은 음식물쓰레기와 같은 유기성 폐기물의 퇴비화과정에서 악취발생이 저감되며 발효가 촉진되면서 양질의 퇴비를 제조하는 방법을 제시하는 것을 목적으로 한다.An object of the present invention is to provide a method for producing high-quality compost while reducing the occurrence of odor during the composting process of organic waste, such as food waste.
이를 위하여 본 발명은, 음식물쓰레기와 같은 유기성 폐기물을 이물질제거, 파쇄, 탈수, 탈 염과 같은 전 처리를 한 다음에 혼화기(1)에 이송하여 팽윤제(Bulking agent) 및 기타첨가제를 주입하여 함수율이 60wt% 정도 되게 조정한 후에 발효숙성공정(4)으로 보내어 발효숙성이 완료되면 이물질선별기(8)로 이송하여 이물질을 분리 제거한 완숙퇴비(10)를 만드는 과정에서 악취발생의 저감 및 발효를 촉진하기 위해서 발효숙성공정(4)에서 배출되는 침출수를 이용하여 미생물배양공정에서 유기물질을 안정된 부식물질로 전환하는 폴리페놀(Polyphenol)성대사산물을 배설하는 부식화미생물 및 이들 미생물과 상호공생관계에 있는 토양미생물을 배양하여 발효숙성공정(4)에 공급하여 발효 숙성기간의 단축 및 악취발생을 저감하면서 완숙된 퇴비를 제조한다.To this end, the present invention, the organic waste such as food waste, pre-treatment such as debris removal, crushing, dehydration, desalting and then transferred to the admixture (1) to inject a bulking agent and other additives After adjusting the water content to about 60wt%, it is sent to the fermentation aging process (4), and when fermentation is completed, it is transferred to the foreign matter selector (8) to reduce the odor and reduce the fermentation in the process of making the mature compost (10). Corrosive microorganisms and the mutual symbiosis with these microorganisms that excrete polyphenolic metabolites that convert organic substances into stable corrosive substances in the microbial culture process by using the leachate discharged from fermentation aging process (4). By cultivating the soil microorganism in the fermentation ripening process (4) to produce a mature compost while reducing the fermentation ripening period and reducing the occurrence of odor.
특이한 사항은, 종래에 주로 적용하던 퇴비제조공정에 비해서 악취발생이 월등히 저감되면서 발효 숙성기간이 단축됨으로써 시설비 및 운전비용이 절감되면서 양질의 완숙퇴비가 생산되기 때문에 유기성 폐기물의 퇴비화공정에 널리 이용될 것으로 기대된다.It is unusual to be widely used in organic waste composting process because the production of high-quality ripened compost is produced by reducing the cost of fermentation and operation, and reducing the cost of fermentation. It is expected to be.
유기성 폐기물, 부식화, 발효숙성, 부식물질, 악취, 퇴비화Organic Waste, Corrosive, Fermentation Maturation, Corrosive, Odor, Composting
Description
도 1은 제1 유기성 폐기물의 퇴비제조 공정도1 is a composting manufacturing process of the first organic waste
도 2는 제2 유기성 폐기물의 퇴비제조 공정도2 is a composting manufacturing process of the second organic waste
〈도면의 주요부분에 대한 부호의 설명〉<Explanation of symbols for main parts of drawing>
1: 혼화기 2: 혼화기 믹서(Mixer)1: Mixer 2: Mixer Mixer
3: 이송 컨베이어(Conveyer) 4: 발효숙성공정3: Transfer Conveyor 4: Fermentation Maturation Process
5: 로터리 믹서(Rotary mixer) 6: 삽 차5: rotary mixer 6: shovel
7: 호퍼(Hopper) 8: 이물질 선별기7: Hopper 8: Foreign material sorter
9: 완숙퇴비 이송컨베이어 10: 완숙퇴비9: Full Compost Transfer Conveyor 10: Full Compost
11: 미생물활성화조 12 : 생물반응기(Bio-reactor)11: microbial activation tank 12: bio-reactor
13: 광물질 및 부식물질펠렛트(Pellet) 충전층13: Mineral and Corrosive Pellet Filling Layer
14: 미생물배양조 15: 미생물농축조14: microbial culture tank 15: microbial concentration tank
16: 미생물농축조 레이크(Rake) 17 : 미생물반송펌프(Pump)16: Microbial Concentration Tank Rake 17: Microbial Transfer Pump
18: 배양액저장조 19: 배양액이송펌프18: culture medium storage tank 19: culture medium transfer pump
20: 송풍기(Air blower) 21: 미생물활성화조순환펌프20: Air blower 21: Microorganism activation tank circulation pump
22: 자석(영구자석 또는 전자석) 23: 정류기22: magnet (permanent magnet or electromagnet) 23: rectifier
24: 자화기 25: 자철광괴(磁鐵鑛塊)24: magnetizer 25: magnetite mass
본 발명은 음식물쓰레기와 같은 유기성 폐기물의 퇴비화과정에서 미네랄(Minerals)성분을 쉽게 용출할 수 있는 광물질과 부식물질을 이용하여 유기물질을 부식물질로 전환하는 폴리페놀(Polyphenol)성 화합물을 대사산물로 배설하는 부식화미생물 및 이들 미생물과 상호공생관계에 있는 토양미생물을 배양하여 이 배양액을 발효숙성과정에 공급하여 악취발생을 저감하며 발효숙성기간을 단축하면서 양질의 완숙퇴비를 제조하는 방법을 제시하는 것이다.The present invention is a metabolite of a polyphenolic compound that converts organic materials to corrosive substances using minerals and corrosives that can easily elute minerals during composting of organic waste such as food waste. By cultivating the excreted corrosive microorganisms and soil microorganisms that are mutually symbiotic with these microorganisms, this culture solution is fed to the fermentation ripening process to reduce the odor and reduce the fermentation ripening period, and propose a method for producing a good mature compost will be.
일반적으로 전술한 음식물쓰레기와 같은 유기성 폐기물의 퇴비화에서는 톱밥, 왕겨, 수피와 같은 팽윤제를 주입하여 함수율을 60wt% 정도 조정한 다음에 로터리 믹서(Rotary mixer)로 뒤집기를 하면서 호기성 발효를 하는데 발효과정의 초기 단계에서는 탄수화합물, 단순단백질과 같이 미생물에 의해서 쉽게 분해하는 물질이 분해하면서 산소농도가 떨어지면 혐기성 미생물이 활동하면서 부패가 일어나면 암모니아(NH3 ), 유화수소(H2S), 메르캅탄(Mercaptan), 휘발성 아민, 휘발성 알코올, 휘발성 유기산 …등과 같은 악취물질이 발생하면서 심한 악취를 발생하며, 또한 파리와 같은 해충이 번식하면서 2차 오염을 야기하는 문제점이 있으며, 혐기성 미생물이 활동하게 되면 낙산과 같은 식물의 성장에 유해한 대사산물을 생성하기 때문에 퇴비의 품질을 저하하는 등의 문제점이 있다.In general, in the composting of organic waste such as food waste described above, swelling agents such as sawdust, rice hull, and bark are injected to adjust the water content by about 60wt%, and then the aerobic fermentation is carried out by inverting with a rotary mixer. In the early stages of carbohydrates, simple proteins such as simple proteins are easily decomposed by microorganisms, while the oxygen concentration drops, anaerobic microorganisms are active and decay occurs when ammonia (NH 3 ), hydrogen sulfide (H 2 S), mercaptan ( Mercaptan), volatile amines, volatile alcohols, volatile organic acids… Bad odors occur as odorous substances occur, and pests such as flies breed and cause secondary pollution, and when anaerobic microorganisms are active, they produce metabolites that are harmful to plant growth such as butyric acid. Therefore, there is a problem such as lowering the quality of the compost.
본 발명의 목적은 상기와 같은 문제점을 해소하기 위해서, 음식물쓰레기와 같은 유기성 폐기물을 이용하여 퇴비를 생성하는 공정에서 발생하는 악취발생을 저감하면서 짧은 발효숙성기간에 양질의 완숙퇴비를 만들 수 있는 방법을 제시하는데 본 발명의 목적이 있는 것이다.An object of the present invention is to solve the above problems, by using organic waste such as food waste to reduce the odor generated in the process of producing compost while producing a good mature compost in a short fermentation ripening period It is an object of the present invention to present.
이와 같은 목적을 달성하기 위한 본 발명은, 전술한 음식물쓰레기와 같은 유기성 폐기물을 이물질제거, 파쇄, 탈 염과 같은 전 처리를 한 다음에 팽윤제 및 기타 첨가제를 주입하여 교반 혼화한 후에 발효숙성공정에서 미네랄공급이 용이한 광물과 부식물질 펠렛트나 이들에 자석 및 자철광을 사용하여 유기물질을 부식물질로 전환하는 부식화미생물 및 이들 미생물과 상호공생관계에 있는 토양미생물을 배양하여 발효숙성공정에 살포함으로써 악취발생을 저감하면서 짧은 발효숙성기간에 완숙퇴비를 만든다.In order to achieve the above object, the present invention is a fermentation aging process after mixing the organic waste such as food waste, pretreatment such as debris removal, crushing, and desalting, followed by stirring and mixing by injecting swelling agent and other additives. Minerals and corrosive pellets that can easily supply minerals, or cultivate corrosive microorganisms that convert organic materials to corrosive substances by using magnets and magnetites, and soil microorganisms in mutual symbiosis with these microorganisms This reduces maturity and makes ripe compost in a short fermentation period.
이하 첨부된 도면에 의해서 본 발명의 내용을 상세히 설명하면 다음과 같다.Hereinafter, the contents of the present invention will be described in detail with reference to the accompanying drawings.
음식물쓰레기와 같은 유기성 폐기물을 퇴비로 자원화 경우 염분과 이물질은 전 처리공정에서 파쇄처리, 이물질제거, 탈염처리와 같은 전 처리를 한 다음에 혼화기(1)에 주입하고, 농·수산부산물, 도축공장부산물과 같이 이물질이 문제가 되는 경우에는 전 처리공정에서 이물질을 제거한 다음에 혼화기(1)에 주입한다.When recycling organic waste such as food waste into compost, salt and foreign substances are pretreated in the pretreatment process such as shredding, debris removal, and desalination, and then injected into the blender (1). Agricultural and marine by-products and slaughter If a foreign matter is a problem, such as a factory by-product, the foreign matter is removed in the pretreatment process and then injected into the admixture (1).
혼화기(1)에 주입된 음식물쓰레기와 같은 유기성 폐기물에 천매암(千枚岩)을 작물의 종류, 토양의 특성, 용도 등을 고려하여 유기질/무기물의 비가 0.8∼10의 범위로 주입하고, 톱밥 또는 이탄(토탄)과 같은 팽윤제(Bulking agent)을 수분조절, 공극률(통기성)향상, C/N비의 조정 등의 목적으로 함수율이 60wt%정도 되게 공급하여 혼화기 믹서(2)로 교반 혼합한 다음에 발효숙성공정(4)으로 이송한다.In order to inject organic waste such as food waste into the admixture (1), cheonmaeam is infused into the organic / inorganic ratio in the range of 0.8 to 10 in consideration of the type of crop, soil characteristics, and use. Alternatively, a swelling agent such as peat may be supplied at a moisture content of about 60 wt% for controlling moisture, improving porosity, adjusting C / N ratio, etc. It is then transferred to the fermentation aging process (4).
발효숙성공정(4)에 유입된 유기성 폐기물은 로터리 믹서(Rotary mixer; 5)로 뒤집기를 하면서 호기성 발효를 하면 초기에는 탄수화합물, 단순단백질과 같이 미생물에 의해서 분해가 용이한 물질이 분해되면서 분해열에 의해서 온도가 상승하게 되면, 고온성 미생물(Thermophilic microbes)이 활동하게 되면서 유해병원성 미생물, 해충의 유충(幼蟲) 및 알, 잡초의 씨앗 등이 사멸처리되며, 고온성 미생물의 먹이가 되는 유기물질이 고갈하게 되면 온도가 떨어지면서 중온성미생물(Mesophilic microbes)이 활동하게 되며, 미분해된 난분해성 유기물질은 미생물의 대사산물과 반응하여 안정된 부식물질로 전환되어 발효숙성이 완료되면 삽 차(6) 등에 의해서 이물질선별기(8)로 보내어 이물질을 분리 제거하여 완숙된 퇴비를 생산한다.The organic waste introduced into the fermentation aging process (4) is inverted by a rotary mixer (5) and subjected to aerobic fermentation.In the early stages, materials that are easily decomposed by microorganisms, such as carbohydrate compounds and simple proteins, are decomposed to heat of decomposition. When the temperature rises, thermophilic microbes are activated, and harmful pathogenic microorganisms, pest larvae and eggs, and seeds of weeds are killed, and organic matter that is fed to the thermophilic microbes When depleted, mesophilic microbes become active as the temperature drops, and undigested, non-degradable organic matter reacts with the metabolites of microorganisms, converting them into stable corrosive substances, and when fermentation is matured, it is inserted. It is sent to the foreign matter sorter (8) by the separation to remove the foreign matter to produce a mature compost.
발효숙성공정(4)에서 숙성된 완숙퇴비가 생산되는 반응 메커니즘(Mechanisms)은 다음과 같다.The reaction mechanisms (Mechanisms) in which the ripened compost produced in the fermentation aging process (4) are produced are as follows.
발효 초기단계에는 1차 미생물에 의해서 분해가 용이한 탄수화합물, 단순단백질 등이 CO2, H2O와 같은 간단한 무기물질로 분해가 된다.In the early stage of fermentation, carbohydrate compounds and simple proteins, which are easily decomposed by primary microorganisms, are decomposed into simple inorganic substances such as CO 2 and H 2 O.
이때 산소공급이 부족하게 되어 혐기성 상태가 되면 혐기성 미생물이 활동하게 되면서 유기물질은 CO2, CH4, NH3, H2S와 같은 간단한 무기물질과 휘발성 아민류, 휘발성 알코올류, 휘발성 유기산류, 메르캅탄류와 같은 저분자성 유기물질로 분해가 일어나면서 악취가 발생하게 되므로 충분한 공기(산소)를 공급해야 한다.At this time, when the oxygen supply is insufficient and becomes anaerobic, anaerobic microorganisms are activated, and organic materials include simple inorganic substances such as CO 2 , CH 4 , NH 3 and H 2 S, volatile amines, volatile alcohols, volatile organic acids, and mercury. Decomposition to low-molecular organic materials such as captans causes odors, so sufficient air (oxygen) must be supplied.
여기서 지나친 공기를 주입하게 되면 열손실이 심하여 온도가 60℃까지 상승하지 않으면 유기성 폐기물 중에 함유되어 있는 유해병원성 미생물, 해충의 유충 및 알, 잡초의 씨앗 등이 사멸되지 않을 수 있으며, 공기공급이 약간 부족하게 되어 온도상승이 80℃ 이상 장시간 유지하게 되면 중온성 미생물이 사멸하게 되어 후단에서 완숙발효가 일어나지 않으면서 미숙 퇴비가 생산될 수 있으며, 산소공급이 지나치게 부족하면 혐기성 상태가 되어 심한 악취가 발생하면서 식물생육에 유해한 낙산과 같은 혐기성 미생물의 대사산물이 생성될 수 있기 때문에 적절한 산소공급 및 수분조절을 하면서 혐기성 미생물의 생육을 억제하도록 해야 한다.If the air is injected too much, the heat loss is severe, and if the temperature does not rise to 60 ℃, harmful pathogenic microorganisms, pest larvae and eggs, seeds of weeds, etc. contained in organic waste may not be killed. If the temperature rise is maintained for more than 80 ℃ for a long time, mesophilic microorganisms are killed and immature compost can be produced without ripening fermentation at the rear stage, and if the oxygen supply is insufficient, it becomes anaerobic and severe odor occurs. However, metabolic products of anaerobic microorganisms such as butyric acid, which are harmful to plant growth, can be produced. Therefore, it is necessary to suppress the growth of anaerobic microorganisms with proper oxygen supply and moisture control.
다시 말해서 ②의 반응이 일어나게 되면 심한 악취를 발생하면서 식물에 유해한 낙산과 같은 미생물대사산물이 생성될 수 있기 때문에 충분한 산소를 공급하여 ②의 반응은 최대한 억제 되도록 운전해야 한다.In other words, when the reaction of ② occurs, a bad odor can be generated and microbial metabolites such as butyric acid, which are harmful to plants, can be produced, so that the reaction of ② should be operated to be suppressed as much as possible by supplying sufficient oxygen.
발효숙성공정(4)의 전 단계에서 ①과 같은 호기성 반응이 일어나게 되면서 반응열에 의해서 온도가 상승하게 되면 호열성 미생물이 활동하게 되면서 열에 약한 유해병원성 미생물, 해충의 유충 및 알, 잡초의 씨앗 등이 사멸하게 되며, 이때 상당량의 수분이 증발하게 된다.During the fermentation aging process (4), when the aerobic reaction such as ① occurs and the temperature rises due to the heat of reaction, the thermophilic microorganisms are activated and the harmful pathogenic microorganisms, pest larvae and eggs, seeds of weeds, etc. It will die, and a significant amount of water will evaporate.
여기서 온도 상승으로 인하여 지나친 수분이 증발하게 되면 후단의 발효 숙성이 원활하게 일어나지 않을 수 있기 때문에 침출수 등을 살포하여 함수율을 조절하는 것이 좋다.If excessive moisture is evaporated due to the temperature rise here, fermentation aging may not occur smoothly in the latter stage, so it is good to adjust the water content by spraying leachate or the like.
유기성 폐기물 중 호열성 미생물의 먹이가 되는 영양물질이 소멸하게 되면 호열성 미생물의 대사활동은 둔화하면서 온도가 떨어지면 중온성 미생물이 활동하게 된다.When the nutrients that feed the thermophilic microorganisms disappear from the organic waste, the metabolic activity of the thermophilic microorganisms is slowed down and the mesophilic microorganisms are activated when the temperature drops.
중온성 미생물 중에는 방선균(放線菌)류, 바실루스 마이코이데스(Bacillus mycoides)와 같은 간균(桿菌)류, 믹소박데리아(Myxobacteria)류, 곰팡이류(Aspergillus niger, Penicillium sp., Mucor sp., Fusarium sp. 등)와 같이 유기물질을 부식물질로 전환하는 폴리페놀(Polyphenol)성 화합물을 대사산물로 배설하는 부식화미생물 및 이들 미생물과 상호공생관계에 있는 토양미생물이 활동하게 되면서 유기물질을 안정된 부식물질로 전환하게 된다.Among the mesophilic microorganisms are actinomycetes, Bacillus mycoides such as Bacillus mycoides, Myxobacteria, fungi (Aspergillus niger, Penicillium sp., Mucor sp., Fusarium) corrosive microorganisms that excrete polyphenolic compounds, which convert organic substances into corrosive substances, as metabolites and soil microorganisms that are mutually symbiotic with these microorganisms. Will be converted into matter.
폴리페놀성 화합물은 공기 중에서 산화효소(Polyphenoloxidase)의 촉매작용에 의해서 퀴논(Quinone)화합물로 산화되면서 과산화수소(H2O2)가 생성되며, 과산화수소는 미생물이 배설하는 효소와 반응해서 산화효소를 생성한다.Polyphenolic compounds are oxidized to quinone compounds by the catalysis of polyphenoloxidase in the air to produce hydrogen peroxide (H 2 O 2 ), and hydrogen peroxide reacts with enzymes excreted by microorganisms to produce oxidase. do.
퀴논화합물은 미생물에 의해서 분해가 어려운 리그닌(Lignin), 셀룰로오스(Cellulose), 타닌(Tannin)과 같은 물질과 중축합반응(重縮合反應)을 하여 물에 불용성이면서 비휘발성인 안정된 부식물질로 전환된다.Quinone compounds are polycondensation reactions with materials such as lignin, cellulose, and tannin, which are difficult to decompose by microorganisms, and are converted into stable corrosive materials that are insoluble and nonvolatile in water. .
이때 악취를 발생하는 암모니아(NH3), 유화수소(H2S), 휘발성 아민류, 휘발성 알코올류, 휘발성 유기산류, 메르캅탄류와 같은 물질을 부식물질에 부동화(不動化 ; Immobilization) 됨으로써 악취발생이 저감하게 된다.At this time, odor is generated by immobilizing substances such as ammonia (NH 3 ), hydrogen sulfide (H 2 S), volatile amines, volatile alcohols, volatile organic acids, and mercaptans, which generate odors, to corrosive substances. This reduces.
부식물질은 토양의 조암광물(造岩鑛物)에 함유되어 있는 활성미네랄성분과 반응하여 킬레이트(Chelate)성 부식산미네랄착염 상태인 콜로이드 미셀(Colloidal micelle)형태의 부식물질이 생성된다.The corrosive reacts with the active minerals contained in the coarse minerals of the soil to produce colloidal micelle in the form of chelate hydrochloric acid mineral complex.
또한, 부식화미생물 및 이들 미생물과 상호 공생관계에 있는 토양미생물은 악취발생을 유발하는 부패성 미생물 및 유해병원성 미생물의 생육을 억제하는 항생물질을 배설하여 이들 미생물의 생육을 억제함으로써 상호길항관계를 유지하게 된다.In addition, corrosive microorganisms and soil microorganisms which have mutual symbiosis with these microorganisms maintain mutual antagonistic relationship by suppressing the growth of these microorganisms by suppressing the growth of antibiotics that inhibit the growth of decaying microorganisms and pathogenic microorganisms causing odor. Done.
따라서 부식화미생물 및 이들 미생물과 상호 공생관계에 있는 토양미생물의 생육환경조건을 최적의 상태로 유지하여 주면 악취발생은 억제하게 된다.Therefore, if the growth environment conditions of corrosive microorganisms and soil microorganisms which are in symbiosis with these microorganisms are maintained in an optimal state, the occurrence of odor is suppressed.
그리고 사상균류, 슈도모나스(Pseudomonas sp.)와 같은 미생물은 부식물질을 먹이로 섭취하여 대사산물 중 식물성장에 유용한 생리적 활성물질인 비타민(Vitamin)류와 성장촉진물질인 호르몬(Hormon)류와 같은 식물성장에 유용한 물질을 배설한다.Microorganisms such as filamentous fungi and Pseudomonas sp. Feed on corrosive substances and feed on plants such as vitamins (Vitamin), which are useful for plant growth, and hormones (Hormon), which are useful for plant growth. Excrete substances useful for growth;
유기물질을 부식물질로 전환하는 폴리페놀(Polyphenol)성 화합물을 배설하는 전술한 부식화미생물과 이들 미생물과 상호공생관계에 있는 토양미생물은 세포막이나 세포핵 중에는 미네랄 함량이 높은 특성이 있음으로 미네랄 및 활성물질을 충분히 공급하였을 때 이들 미생물과 상호공생관계에 있는 토양미생물들의 대사활동이 활발하게 되면서, 길항관계에 있는 부패를 야기하는 혐기성 미생물이나 병원성 미생물 등은 생육이 억제하게 된다.The above-mentioned corrosive microorganisms that excrete polyphenolic compounds that convert organic substances into corrosive substances and soil microorganisms which have mutual symbiosis with these microorganisms have high mineral content in cell membranes or cell nuclei. When enough substances are supplied, the metabolic activity of soil microorganisms which are mutually symbiotic with these microorganisms becomes active, and anaerobic microorganisms and pathogenic microorganisms that cause antagonistic decay are suppressed from growth.
본 발명은 유기물질을 부패하여 악취를 발생시키는 혐기성 미생물의 생육을 최대한 억제하여 전술한 ②의 반응을 방지하기 위해서는 혐기성 미생물과 상호길항관계에 있는 부식물질을 생성하는 부식화미생물과 공생관계에 있는 토양미생물을 배양하여 발효숙성공정(4)의 전단에 공급하며, 잉여배양액은 액비화공정이나 폐수처리공정으로 보낸다.The present invention in order to inhibit the growth of anaerobic microorganisms that cause odors by decaying organic substances to the maximum to prevent the reaction of the above ② to have a symbiotic relationship with the corrosive microorganisms that produce corrosive substances that are antagonistic relationship with anaerobic microorganisms Soil microorganisms are cultured and supplied to the front end of the fermentation ripening process (4), and the excess culture liquid is sent to the liquefaction process or wastewater treatment process.
부식화미생물과 이들 미생물과 상호공생관계에 있는 토양미생물을 배양하기 위한 배양액으로는 발효숙성공정에서 배출되는 침출수를 미생물배양조(14)에 공급하고, 송풍기(20)로부터 공기를 주입하여 폭기를 하면서 배양된 배양액은 미생물농축조(15)로 보내어 청등액은 상부로 익류하여 배양액저장조(18)로 보낸 다음에 배양액이송펌프(19)에 의해서 발효숙성공정(4)의 고온발효부 전단에 공급하며, 미생물과 부식전구물질(腐植前驅物質)인 고형물질이 미생물농축조(15) 하부에 침전된 오니(미생물균체)는 미생물반송펌프(17)에 의해서 종균용으로 미생물배양조(14) 및 미생물활성화조(11)로 반송하면서 발효숙성공정(4)의 전단과 고온발효부의 후단에 공급한다.As a culture medium for culturing corrosive microorganisms and soil microorganisms having mutual symbiosis with these microorganisms, leachate discharged from the fermentation aging process is supplied to the
미생물활성화조(11)에는 미네랄 공급이 용이한 유문암(流紋岩) 또는 대사이드(Dacite)질의 부석(浮石)과 킬레이트성 풀브산미네랄착염(Chelatic mineral fulvate)성분이 많은 해양성 부식산콜로이드미셀(Colloidal micelle) 형태의 부식토(이탄)를 펠렛트(Pellet)형태로 성형 가공한 것을 충전한 생물반응기(Bio-reactor; 12)를 설치하고 송풍기(20)로부터 공기를 미생물활성화조(11)와 생물반응기(12)에 공급하면서 폭기를 하면 공급된 미생물배양액은 전술한 광물질 및 부식물질펠렛트(Pellet)의 충전층(13)을 순환하면서 유기물질을 부식물질로 전환하는 폴리페놀성 대사산물을 배설하는 부식화미생물과 상호공생관계에 있는 토양미생물은 생육에 필요한 각종 미네랄성분과 기타 활성물질을 공급받아 활발한 대사활동을 하면서 활성화된 미생물을 미생물배양조(14)에 공급하면 이들 미생물이 우점종(優占種)으로 생육하는 환경 분위기로 전환된다.The
그리고 도 2에서와 같이 미생물활성화조(11)의 미생물배양액을 미생물활성화조순환펌프(21)에 의해서 자속밀도(磁束密度)가 10,000G(Gauss)이상 착자(着磁)된 영구자석이나 전자석(22)의 자계(磁界)와 자속밀도가 200G이상 착자된 자철광괴(磁 鐵鑛塊 ; 25)가 충전된 자화기(24)를 순환시키면 자기유체역학(MHD ; Magneto-Hydro-Dynamics)전압이 발생하면서 전자의 파동(波動)에 의해서 물 분자의 집단체(集團體 ; Cluster)가 미세화(微細化) 되면서 표면장력(表面張力)이 적어져 침투력(浸透力)이 향상되면 미생물의 세포막의 투과율이 향상되어 미생물의 대사활동을 더욱더 활발하게 한다.As shown in FIG. 2, the permanent magnet or electromagnet having the magnetic flux density of at least 10,000 G (Gauss) magnetized by the microbial activating
전술한 유기물질을 부식물질로 전환하는 폴리페놀성대사산물을 배설하는 부식화미생물 및 이들 미생물과 상호공생관계에 있는 토양미생물을 배양하는 배양공정에서 배양된 미생물배양액을 발효숙성공정(4)에 주입하면 반응식②의 부패반응은 최대한 억제되면서 악취발생물질은 반응식⑦에서와 같이 부동화(不動化)반응에 의해서 비휘발성의 안정된 부식(전구)물질로 전환됨으로써 악취발생이 저감되는 반면에 퇴비화공정에서 유용한 반응인 반응식① 및 ③에서 ⑨까지의 부식화반응이 활발하게 일어나므로 발효숙성기간이 단축하게 된다.The microbial culture liquid cultured in the culture step of culturing the corrosive microorganisms that excrete polyphenolic metabolites converting the above-mentioned organic substances into the corrosive substances and the soil microorganisms having mutual symbiosis with these microorganisms is subjected to the fermentation ripening step (4). When injected, the decay reaction of the
그리고 방선균류, 페니실륨류(Penicillium sp.)와 같은 미생물이 공생하면서 반응식⑩의 반응이 일어나 악취발생을 유발하는 부패성 미생물 및 유해병원성 미생물의 생육을 억제하는 항생물질이 다량 함유되어 있으며, 식물의 식물성장에 유용한 생리적 활성물질인 비타민(Vitamin)류와 성장촉진물질인 호르몬(Hormon)류와 같은 식물성장에 유용한 물질을 대사산물로 배설하는 사상균류, 슈도모나스(Pseudomonas sp.)와 같은 공생미생물의 생육도 활성화되면서 반응식⑩ 및 ⑪의 반응이 활발하게 일어남으로써 식물성장에 유용한 물질이 다량 함유되어있는 양질의 퇴비가 생산된다.And microorganisms such as actinomycetes and penicillium sp. Coexist with the reaction of the reaction formula and contain a large amount of antibiotics that inhibit the growth of rot and microorganisms that cause odor. Symbiotic microorganisms such as Pseudomonas sp., A fungus that excretes substances useful for plant growth, such as vitamins, which are useful for plant growth, and hormones, which are growth promoters, as metabolites. As the growth is also activated, the reactions of
삭제delete
삭제delete
삭제delete
전술한 기술내용으로부터 자명하듯이, 본 발명은 음식물쓰레기와 같은 유기성 폐기물을 이물질제거, 파쇄, 탈염과 같은 전 처리를 한 다음에 팽윤제 및 기타첨가물을 주입하고 발효숙성공정에서 유기물질을 안정된 부식물질로 전환하는 부식화미생물 및 이들 미생물과 상호공생관계에 있는 토양미생물을 배양한 배양액을 공급하였을 때 악취발생이 월등히 저감되며, 발효숙성기간이 단축되면서 양질의 퇴비를 생산할 수 있기 때문에 유기성 폐기물의 퇴비화공정에 널리 보급될 것으로 기대된다.As is apparent from the above description, the present invention is to pre-treat organic waste such as food waste, pretreatment such as debris removal, crushing and desalting, and then injecting swelling agent and other additives, and stably corroding organic materials in the fermentation aging process. Odor generation is greatly reduced by supplying the cultured culture of corrosive microorganisms that convert into substances and soil microorganisms that have mutual symbiosis with these microorganisms, and it is possible to produce high-quality compost with a short fermentation ripening period. It is expected to be widely used in the composting process.
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020030005374A KR100577841B1 (en) | 2003-01-27 | 2003-01-27 | Composting method of organic waste such as food waste |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020030005374A KR100577841B1 (en) | 2003-01-27 | 2003-01-27 | Composting method of organic waste such as food waste |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20040068821A KR20040068821A (en) | 2004-08-02 |
KR100577841B1 true KR100577841B1 (en) | 2006-05-12 |
Family
ID=37357851
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020030005374A Expired - Fee Related KR100577841B1 (en) | 2003-01-27 | 2003-01-27 | Composting method of organic waste such as food waste |
Country Status (1)
Country | Link |
---|---|
KR (1) | KR100577841B1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100976848B1 (en) | 2008-04-25 | 2010-08-20 | 배연호 | Compost production method using food waste |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100792166B1 (en) * | 2006-01-19 | 2008-01-09 | (주)지앤엘 | Waste and waste treatment methods containing organic matter |
KR100909845B1 (en) * | 2007-11-22 | 2009-07-28 | 오션 스타 주식회사 | Organic Fertilizer Manufacturing Method |
KR101765488B1 (en) | 2015-02-12 | 2017-08-23 | 주식회사 티에스엔티글로벌 | Apparatus for fermenting an organic waste and fertilizer of livestock excretion using soil microorganism, biofield generating apparatus for the same, microorganism battery for the same and microorganism condenser for the same |
KR102504601B1 (en) | 2021-04-08 | 2023-03-02 | 한국기계연구원 | Foreign matter removal device and dewatering system having the same |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20020030674A (en) * | 2000-10-19 | 2002-04-25 | 윤종용 | method of numerically analyzing growth degree of grains on a semiconductor wafer by using a SEM image and apparatus for realizing the same |
-
2003
- 2003-01-27 KR KR1020030005374A patent/KR100577841B1/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20020030674A (en) * | 2000-10-19 | 2002-04-25 | 윤종용 | method of numerically analyzing growth degree of grains on a semiconductor wafer by using a SEM image and apparatus for realizing the same |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100976848B1 (en) | 2008-04-25 | 2010-08-20 | 배연호 | Compost production method using food waste |
Also Published As
Publication number | Publication date |
---|---|
KR20040068821A (en) | 2004-08-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP2015167912A (en) | Livestock excreta treating system | |
Vyas et al. | Vermicomposting with microbial amendment: implications for bioremediation of industrial and agricultural waste | |
KR20040017512A (en) | Production method of seed-bed soil. | |
EA028181B1 (en) | Method of production of organic fertilizer | |
KR100577841B1 (en) | Composting method of organic waste such as food waste | |
KR100472969B1 (en) | Manufacturing method of a liquefied fertilizer | |
Ezeah et al. | Design principles of sustainable composting and recovery of value from compost | |
Gupta et al. | Vermitechnology for organic waste recycling | |
KR20180124232A (en) | Manufacturing method of liquid manure | |
KR100480181B1 (en) | Manufacturing method for magnetized fertilizer. | |
CN115368195B (en) | Sludge composting method and application thereof | |
KR101712526B1 (en) | Composition for treating organic waste water, treatment method of organic waste water using thereof and nutrient solution manufactured by the same | |
RU2141932C1 (en) | Bio-organic fertilizer | |
KR100624783B1 (en) | High-efficiency wastewater treatment method | |
KR100518722B1 (en) | Method of garbage treatment | |
KR100487582B1 (en) | Device for treating sludge of sewage or organic wastewater and method thereof | |
JP2525563B2 (en) | Method and apparatus for manufacturing organic fertilizer | |
KR100343197B1 (en) | An Organic Compound Decomposing Material and the Use thereof | |
KR20040048758A (en) | Method of making fertilizer (compost) by fermenting organic waste (food + livestock) by using coco peat, molasses (CMS) and charcoal, and fertilizer (compost) produced thereby | |
KR100482988B1 (en) | Manufacturing method of feedstuff for domestic animals | |
KR200313908Y1 (en) | Malodorant removing equipment for waste organic materials | |
KR100424157B1 (en) | Composting method for organic waste substrate by using activated humic substances and humification bacteria | |
KR102747047B1 (en) | Method for redecing sludge and odor, multicomplex fermentation microorganism liquors using the same, and manufacturing method thereof | |
CN120004675A (en) | Directional humification micro-factory for agricultural waste compost and application thereof | |
Ilyin et al. | Environmentally proved methods of cascade conversion of organic waste using a microbial complex with filamentous fungi |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
PA0109 | Patent application |
Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 20030127 |
|
PA0201 | Request for examination | ||
AMND | Amendment | ||
PG1501 | Laying open of application | ||
E902 | Notification of reason for refusal | ||
PE0902 | Notice of grounds for rejection |
Comment text: Notification of reason for refusal Patent event date: 20050111 Patent event code: PE09021S01D |
|
AMND | Amendment | ||
E90F | Notification of reason for final refusal | ||
PE0902 | Notice of grounds for rejection |
Comment text: Final Notice of Reason for Refusal Patent event date: 20050517 Patent event code: PE09021S02D |
|
AMND | Amendment | ||
E601 | Decision to refuse application | ||
PE0601 | Decision on rejection of patent |
Patent event date: 20050926 Comment text: Decision to Refuse Application Patent event code: PE06012S01D Patent event date: 20050517 Comment text: Final Notice of Reason for Refusal Patent event code: PE06011S02I Patent event date: 20050111 Comment text: Notification of reason for refusal Patent event code: PE06011S01I |
|
J201 | Request for trial against refusal decision | ||
PJ0201 | Trial against decision of rejection |
Patent event date: 20051026 Comment text: Request for Trial against Decision on Refusal Patent event code: PJ02012R01D Patent event date: 20050926 Comment text: Decision to Refuse Application Patent event code: PJ02011S01I Appeal kind category: Appeal against decision to decline refusal Decision date: 20051207 Appeal identifier: 2005101007301 Request date: 20051026 |
|
AMND | Amendment | ||
PB0901 | Examination by re-examination before a trial |
Comment text: Amendment to Specification, etc. Patent event date: 20051120 Patent event code: PB09011R02I Comment text: Request for Trial against Decision on Refusal Patent event date: 20051026 Patent event code: PB09011R01I Comment text: Amendment to Specification, etc. Patent event date: 20050603 Patent event code: PB09011R02I Comment text: Amendment to Specification, etc. Patent event date: 20050216 Patent event code: PB09011R02I Comment text: Amendment to Specification, etc. Patent event date: 20030210 Patent event code: PB09011R02I |
|
B701 | Decision to grant | ||
PB0701 | Decision of registration after re-examination before a trial |
Patent event date: 20051207 Comment text: Decision to Grant Registration Patent event code: PB07012S01D Patent event date: 20051201 Comment text: Transfer of Trial File for Re-examination before a Trial Patent event code: PB07011S01I |
|
GRNT | Written decision to grant | ||
PR0701 | Registration of establishment |
Comment text: Registration of Establishment Patent event date: 20060502 Patent event code: PR07011E01D |
|
PR1002 | Payment of registration fee |
Payment date: 20060502 End annual number: 3 Start annual number: 1 |
|
PG1601 | Publication of registration | ||
PR1001 | Payment of annual fee |
Payment date: 20091103 Start annual number: 4 End annual number: 4 |
|
PR1001 | Payment of annual fee |
Payment date: 20100503 Start annual number: 5 End annual number: 5 |
|
PR1001 | Payment of annual fee |
Payment date: 20110503 Start annual number: 6 End annual number: 6 |
|
PR1001 | Payment of annual fee |
Payment date: 20120502 Start annual number: 7 End annual number: 7 |
|
FPAY | Annual fee payment |
Payment date: 20130502 Year of fee payment: 8 |
|
PR1001 | Payment of annual fee |
Payment date: 20130502 Start annual number: 8 End annual number: 8 |
|
FPAY | Annual fee payment |
Payment date: 20140507 Year of fee payment: 9 |
|
PR1001 | Payment of annual fee |
Payment date: 20140507 Start annual number: 9 End annual number: 9 |
|
FPAY | Annual fee payment |
Payment date: 20150506 Year of fee payment: 10 |
|
PR1001 | Payment of annual fee |
Payment date: 20150506 Start annual number: 10 End annual number: 10 |
|
FPAY | Annual fee payment |
Payment date: 20160503 Year of fee payment: 11 |
|
PR1001 | Payment of annual fee |
Payment date: 20160503 Start annual number: 11 End annual number: 11 |
|
LAPS | Lapse due to unpaid annual fee | ||
PC1903 | Unpaid annual fee |
Termination category: Default of registration fee Termination date: 20180213 |