[go: up one dir, main page]

KR100577841B1 - Composting method of organic waste such as food waste - Google Patents

Composting method of organic waste such as food waste Download PDF

Info

Publication number
KR100577841B1
KR100577841B1 KR1020030005374A KR20030005374A KR100577841B1 KR 100577841 B1 KR100577841 B1 KR 100577841B1 KR 1020030005374 A KR1020030005374 A KR 1020030005374A KR 20030005374 A KR20030005374 A KR 20030005374A KR 100577841 B1 KR100577841 B1 KR 100577841B1
Authority
KR
South Korea
Prior art keywords
fermentation
microorganisms
corrosive
tank
composting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020030005374A
Other languages
Korean (ko)
Other versions
KR20040068821A (en
Inventor
서희동
서영준
서영진
Original Assignee
서희동
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 서희동 filed Critical 서희동
Priority to KR1020030005374A priority Critical patent/KR100577841B1/en
Publication of KR20040068821A publication Critical patent/KR20040068821A/en
Application granted granted Critical
Publication of KR100577841B1 publication Critical patent/KR100577841B1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F9/00Fertilisers from household or town refuse
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00Other organic fertilisers
    • C05F11/08Organic fertilisers containing added bacterial cultures, mycelia or the like
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Fertilizers (AREA)

Abstract

본 발명은 음식물쓰레기와 같은 유기성 폐기물의 퇴비화과정에서 악취발생이 저감되며 발효가 촉진되면서 양질의 퇴비를 제조하는 방법을 제시하는 것을 목적으로 한다.An object of the present invention is to provide a method for producing high-quality compost while reducing the occurrence of odor during the composting process of organic waste, such as food waste.

이를 위하여 본 발명은, 음식물쓰레기와 같은 유기성 폐기물을 이물질제거, 파쇄, 탈수, 탈 염과 같은 전 처리를 한 다음에 혼화기(1)에 이송하여 팽윤제(Bulking agent) 및 기타첨가제를 주입하여 함수율이 60wt% 정도 되게 조정한 후에 발효숙성공정(4)으로 보내어 발효숙성이 완료되면 이물질선별기(8)로 이송하여 이물질을 분리 제거한 완숙퇴비(10)를 만드는 과정에서 악취발생의 저감 및 발효를 촉진하기 위해서 발효숙성공정(4)에서 배출되는 침출수를 이용하여 미생물배양공정에서 유기물질을 안정된 부식물질로 전환하는 폴리페놀(Polyphenol)성대사산물을 배설하는 부식화미생물 및 이들 미생물과 상호공생관계에 있는 토양미생물을 배양하여 발효숙성공정(4)에 공급하여 발효 숙성기간의 단축 및 악취발생을 저감하면서 완숙된 퇴비를 제조한다.To this end, the present invention, the organic waste such as food waste, pre-treatment such as debris removal, crushing, dehydration, desalting and then transferred to the admixture (1) to inject a bulking agent and other additives After adjusting the water content to about 60wt%, it is sent to the fermentation aging process (4), and when fermentation is completed, it is transferred to the foreign matter selector (8) to reduce the odor and reduce the fermentation in the process of making the mature compost (10). Corrosive microorganisms and the mutual symbiosis with these microorganisms that excrete polyphenolic metabolites that convert organic substances into stable corrosive substances in the microbial culture process by using the leachate discharged from fermentation aging process (4). By cultivating the soil microorganism in the fermentation ripening process (4) to produce a mature compost while reducing the fermentation ripening period and reducing the occurrence of odor.

특이한 사항은, 종래에 주로 적용하던 퇴비제조공정에 비해서 악취발생이 월등히 저감되면서 발효 숙성기간이 단축됨으로써 시설비 및 운전비용이 절감되면서 양질의 완숙퇴비가 생산되기 때문에 유기성 폐기물의 퇴비화공정에 널리 이용될 것으로 기대된다.It is unusual to be widely used in organic waste composting process because the production of high-quality ripened compost is produced by reducing the cost of fermentation and operation, and reducing the cost of fermentation. It is expected to be.

유기성 폐기물, 부식화, 발효숙성, 부식물질, 악취, 퇴비화Organic Waste, Corrosive, Fermentation Maturation, Corrosive, Odor, Composting

Description

음식물쓰레기와 같은 유기성 폐기물의 퇴비화방법{Composting method of organic wastes the same garbage}Composting method of organic wastes the same garbage}

도 1은 제1 유기성 폐기물의 퇴비제조 공정도1 is a composting manufacturing process of the first organic waste

도 2는 제2 유기성 폐기물의 퇴비제조 공정도2 is a composting manufacturing process of the second organic waste

〈도면의 주요부분에 대한 부호의 설명〉<Explanation of symbols for main parts of drawing>

1: 혼화기 2: 혼화기 믹서(Mixer)1: Mixer 2: Mixer Mixer

3: 이송 컨베이어(Conveyer) 4: 발효숙성공정3: Transfer Conveyor 4: Fermentation Maturation Process

5: 로터리 믹서(Rotary mixer) 6: 삽 차5: rotary mixer 6: shovel

7: 호퍼(Hopper) 8: 이물질 선별기7: Hopper 8: Foreign material sorter

9: 완숙퇴비 이송컨베이어 10: 완숙퇴비9: Full Compost Transfer Conveyor 10: Full Compost

11: 미생물활성화조 12 : 생물반응기(Bio-reactor)11: microbial activation tank 12: bio-reactor

13: 광물질 및 부식물질펠렛트(Pellet) 충전층13: Mineral and Corrosive Pellet Filling Layer

14: 미생물배양조 15: 미생물농축조14: microbial culture tank 15: microbial concentration tank

16: 미생물농축조 레이크(Rake) 17 : 미생물반송펌프(Pump)16: Microbial Concentration Tank Rake 17: Microbial Transfer Pump

18: 배양액저장조 19: 배양액이송펌프18: culture medium storage tank 19: culture medium transfer pump

20: 송풍기(Air blower) 21: 미생물활성화조순환펌프20: Air blower 21: Microorganism activation tank circulation pump

22: 자석(영구자석 또는 전자석) 23: 정류기22: magnet (permanent magnet or electromagnet) 23: rectifier

24: 자화기 25: 자철광괴(磁鐵鑛塊)24: magnetizer 25: magnetite mass

본 발명은 음식물쓰레기와 같은 유기성 폐기물의 퇴비화과정에서 미네랄(Minerals)성분을 쉽게 용출할 수 있는 광물질과 부식물질을 이용하여 유기물질을 부식물질로 전환하는 폴리페놀(Polyphenol)성 화합물을 대사산물로 배설하는 부식화미생물 및 이들 미생물과 상호공생관계에 있는 토양미생물을 배양하여 이 배양액을 발효숙성과정에 공급하여 악취발생을 저감하며 발효숙성기간을 단축하면서 양질의 완숙퇴비를 제조하는 방법을 제시하는 것이다.The present invention is a metabolite of a polyphenolic compound that converts organic materials to corrosive substances using minerals and corrosives that can easily elute minerals during composting of organic waste such as food waste. By cultivating the excreted corrosive microorganisms and soil microorganisms that are mutually symbiotic with these microorganisms, this culture solution is fed to the fermentation ripening process to reduce the odor and reduce the fermentation ripening period, and propose a method for producing a good mature compost will be.

일반적으로 전술한 음식물쓰레기와 같은 유기성 폐기물의 퇴비화에서는 톱밥, 왕겨, 수피와 같은 팽윤제를 주입하여 함수율을 60wt% 정도 조정한 다음에 로터리 믹서(Rotary mixer)로 뒤집기를 하면서 호기성 발효를 하는데 발효과정의 초기 단계에서는 탄수화합물, 단순단백질과 같이 미생물에 의해서 쉽게 분해하는 물질이 분해하면서 산소농도가 떨어지면 혐기성 미생물이 활동하면서 부패가 일어나면 암모니아(NH3 ), 유화수소(H2S), 메르캅탄(Mercaptan), 휘발성 아민, 휘발성 알코올, 휘발성 유기산 …등과 같은 악취물질이 발생하면서 심한 악취를 발생하며, 또한 파리와 같은 해충이 번식하면서 2차 오염을 야기하는 문제점이 있으며, 혐기성 미생물이 활동하게 되면 낙산과 같은 식물의 성장에 유해한 대사산물을 생성하기 때문에 퇴비의 품질을 저하하는 등의 문제점이 있다.In general, in the composting of organic waste such as food waste described above, swelling agents such as sawdust, rice hull, and bark are injected to adjust the water content by about 60wt%, and then the aerobic fermentation is carried out by inverting with a rotary mixer. In the early stages of carbohydrates, simple proteins such as simple proteins are easily decomposed by microorganisms, while the oxygen concentration drops, anaerobic microorganisms are active and decay occurs when ammonia (NH 3 ), hydrogen sulfide (H 2 S), mercaptan ( Mercaptan), volatile amines, volatile alcohols, volatile organic acids… Bad odors occur as odorous substances occur, and pests such as flies breed and cause secondary pollution, and when anaerobic microorganisms are active, they produce metabolites that are harmful to plant growth such as butyric acid. Therefore, there is a problem such as lowering the quality of the compost.

본 발명의 목적은 상기와 같은 문제점을 해소하기 위해서, 음식물쓰레기와 같은 유기성 폐기물을 이용하여 퇴비를 생성하는 공정에서 발생하는 악취발생을 저감하면서 짧은 발효숙성기간에 양질의 완숙퇴비를 만들 수 있는 방법을 제시하는데 본 발명의 목적이 있는 것이다.An object of the present invention is to solve the above problems, by using organic waste such as food waste to reduce the odor generated in the process of producing compost while producing a good mature compost in a short fermentation ripening period It is an object of the present invention to present.

이와 같은 목적을 달성하기 위한 본 발명은, 전술한 음식물쓰레기와 같은 유기성 폐기물을 이물질제거, 파쇄, 탈 염과 같은 전 처리를 한 다음에 팽윤제 및 기타 첨가제를 주입하여 교반 혼화한 후에 발효숙성공정에서 미네랄공급이 용이한 광물과 부식물질 펠렛트나 이들에 자석 및 자철광을 사용하여 유기물질을 부식물질로 전환하는 부식화미생물 및 이들 미생물과 상호공생관계에 있는 토양미생물을 배양하여 발효숙성공정에 살포함으로써 악취발생을 저감하면서 짧은 발효숙성기간에 완숙퇴비를 만든다.In order to achieve the above object, the present invention is a fermentation aging process after mixing the organic waste such as food waste, pretreatment such as debris removal, crushing, and desalting, followed by stirring and mixing by injecting swelling agent and other additives. Minerals and corrosive pellets that can easily supply minerals, or cultivate corrosive microorganisms that convert organic materials to corrosive substances by using magnets and magnetites, and soil microorganisms in mutual symbiosis with these microorganisms This reduces maturity and makes ripe compost in a short fermentation period.

이하 첨부된 도면에 의해서 본 발명의 내용을 상세히 설명하면 다음과 같다.Hereinafter, the contents of the present invention will be described in detail with reference to the accompanying drawings.

음식물쓰레기와 같은 유기성 폐기물을 퇴비로 자원화 경우 염분과 이물질은 전 처리공정에서 파쇄처리, 이물질제거, 탈염처리와 같은 전 처리를 한 다음에 혼화기(1)에 주입하고, 농·수산부산물, 도축공장부산물과 같이 이물질이 문제가 되는 경우에는 전 처리공정에서 이물질을 제거한 다음에 혼화기(1)에 주입한다.When recycling organic waste such as food waste into compost, salt and foreign substances are pretreated in the pretreatment process such as shredding, debris removal, and desalination, and then injected into the blender (1). Agricultural and marine by-products and slaughter If a foreign matter is a problem, such as a factory by-product, the foreign matter is removed in the pretreatment process and then injected into the admixture (1).

혼화기(1)에 주입된 음식물쓰레기와 같은 유기성 폐기물에 천매암(千枚岩)을 작물의 종류, 토양의 특성, 용도 등을 고려하여 유기질/무기물의 비가 0.8∼10의 범위로 주입하고, 톱밥 또는 이탄(토탄)과 같은 팽윤제(Bulking agent)을 수분조절, 공극률(통기성)향상, C/N비의 조정 등의 목적으로 함수율이 60wt%정도 되게 공급하여 혼화기 믹서(2)로 교반 혼합한 다음에 발효숙성공정(4)으로 이송한다.In order to inject organic waste such as food waste into the admixture (1), cheonmaeam is infused into the organic / inorganic ratio in the range of 0.8 to 10 in consideration of the type of crop, soil characteristics, and use. Alternatively, a swelling agent such as peat may be supplied at a moisture content of about 60 wt% for controlling moisture, improving porosity, adjusting C / N ratio, etc. It is then transferred to the fermentation aging process (4).

발효숙성공정(4)에 유입된 유기성 폐기물은 로터리 믹서(Rotary mixer; 5)로 뒤집기를 하면서 호기성 발효를 하면 초기에는 탄수화합물, 단순단백질과 같이 미생물에 의해서 분해가 용이한 물질이 분해되면서 분해열에 의해서 온도가 상승하게 되면, 고온성 미생물(Thermophilic microbes)이 활동하게 되면서 유해병원성 미생물, 해충의 유충(幼蟲) 및 알, 잡초의 씨앗 등이 사멸처리되며, 고온성 미생물의 먹이가 되는 유기물질이 고갈하게 되면 온도가 떨어지면서 중온성미생물(Mesophilic microbes)이 활동하게 되며, 미분해된 난분해성 유기물질은 미생물의 대사산물과 반응하여 안정된 부식물질로 전환되어 발효숙성이 완료되면 삽 차(6) 등에 의해서 이물질선별기(8)로 보내어 이물질을 분리 제거하여 완숙된 퇴비를 생산한다.The organic waste introduced into the fermentation aging process (4) is inverted by a rotary mixer (5) and subjected to aerobic fermentation.In the early stages, materials that are easily decomposed by microorganisms, such as carbohydrate compounds and simple proteins, are decomposed to heat of decomposition. When the temperature rises, thermophilic microbes are activated, and harmful pathogenic microorganisms, pest larvae and eggs, and seeds of weeds are killed, and organic matter that is fed to the thermophilic microbes When depleted, mesophilic microbes become active as the temperature drops, and undigested, non-degradable organic matter reacts with the metabolites of microorganisms, converting them into stable corrosive substances, and when fermentation is matured, it is inserted. It is sent to the foreign matter sorter (8) by the separation to remove the foreign matter to produce a mature compost.

발효숙성공정(4)에서 숙성된 완숙퇴비가 생산되는 반응 메커니즘(Mechanisms)은 다음과 같다.The reaction mechanisms (Mechanisms) in which the ripened compost produced in the fermentation aging process (4) are produced are as follows.

발효 초기단계에는 1차 미생물에 의해서 분해가 용이한 탄수화합물, 단순단백질 등이 CO2, H2O와 같은 간단한 무기물질로 분해가 된다.In the early stage of fermentation, carbohydrate compounds and simple proteins, which are easily decomposed by primary microorganisms, are decomposed into simple inorganic substances such as CO 2 and H 2 O.

Figure 112003501532845-pat00001
Figure 112003501532845-pat00001

이때 산소공급이 부족하게 되어 혐기성 상태가 되면 혐기성 미생물이 활동하게 되면서 유기물질은 CO2, CH4, NH3, H2S와 같은 간단한 무기물질과 휘발성 아민류, 휘발성 알코올류, 휘발성 유기산류, 메르캅탄류와 같은 저분자성 유기물질로 분해가 일어나면서 악취가 발생하게 되므로 충분한 공기(산소)를 공급해야 한다.At this time, when the oxygen supply is insufficient and becomes anaerobic, anaerobic microorganisms are activated, and organic materials include simple inorganic substances such as CO 2 , CH 4 , NH 3 and H 2 S, volatile amines, volatile alcohols, volatile organic acids, and mercury. Decomposition to low-molecular organic materials such as captans causes odors, so sufficient air (oxygen) must be supplied.

여기서 지나친 공기를 주입하게 되면 열손실이 심하여 온도가 60℃까지 상승하지 않으면 유기성 폐기물 중에 함유되어 있는 유해병원성 미생물, 해충의 유충 및 알, 잡초의 씨앗 등이 사멸되지 않을 수 있으며, 공기공급이 약간 부족하게 되어 온도상승이 80℃ 이상 장시간 유지하게 되면 중온성 미생물이 사멸하게 되어 후단에서 완숙발효가 일어나지 않으면서 미숙 퇴비가 생산될 수 있으며, 산소공급이 지나치게 부족하면 혐기성 상태가 되어 심한 악취가 발생하면서 식물생육에 유해한 낙산과 같은 혐기성 미생물의 대사산물이 생성될 수 있기 때문에 적절한 산소공급 및 수분조절을 하면서 혐기성 미생물의 생육을 억제하도록 해야 한다.If the air is injected too much, the heat loss is severe, and if the temperature does not rise to 60 ℃, harmful pathogenic microorganisms, pest larvae and eggs, seeds of weeds, etc. contained in organic waste may not be killed. If the temperature rise is maintained for more than 80 ℃ for a long time, mesophilic microorganisms are killed and immature compost can be produced without ripening fermentation at the rear stage, and if the oxygen supply is insufficient, it becomes anaerobic and severe odor occurs. However, metabolic products of anaerobic microorganisms such as butyric acid, which are harmful to plant growth, can be produced. Therefore, it is necessary to suppress the growth of anaerobic microorganisms with proper oxygen supply and moisture control.

Figure 112003501532845-pat00002
Figure 112003501532845-pat00002

다시 말해서 ②의 반응이 일어나게 되면 심한 악취를 발생하면서 식물에 유해한 낙산과 같은 미생물대사산물이 생성될 수 있기 때문에 충분한 산소를 공급하여 ②의 반응은 최대한 억제 되도록 운전해야 한다.In other words, when the reaction of ② occurs, a bad odor can be generated and microbial metabolites such as butyric acid, which are harmful to plants, can be produced, so that the reaction of ② should be operated to be suppressed as much as possible by supplying sufficient oxygen.

발효숙성공정(4)의 전 단계에서 ①과 같은 호기성 반응이 일어나게 되면서 반응열에 의해서 온도가 상승하게 되면 호열성 미생물이 활동하게 되면서 열에 약한 유해병원성 미생물, 해충의 유충 및 알, 잡초의 씨앗 등이 사멸하게 되며, 이때 상당량의 수분이 증발하게 된다.During the fermentation aging process (4), when the aerobic reaction such as ① occurs and the temperature rises due to the heat of reaction, the thermophilic microorganisms are activated and the harmful pathogenic microorganisms, pest larvae and eggs, seeds of weeds, etc. It will die, and a significant amount of water will evaporate.

여기서 온도 상승으로 인하여 지나친 수분이 증발하게 되면 후단의 발효 숙성이 원활하게 일어나지 않을 수 있기 때문에 침출수 등을 살포하여 함수율을 조절하는 것이 좋다.If excessive moisture is evaporated due to the temperature rise here, fermentation aging may not occur smoothly in the latter stage, so it is good to adjust the water content by spraying leachate or the like.

유기성 폐기물 중 호열성 미생물의 먹이가 되는 영양물질이 소멸하게 되면 호열성 미생물의 대사활동은 둔화하면서 온도가 떨어지면 중온성 미생물이 활동하게 된다.When the nutrients that feed the thermophilic microorganisms disappear from the organic waste, the metabolic activity of the thermophilic microorganisms is slowed down and the mesophilic microorganisms are activated when the temperature drops.

중온성 미생물 중에는 방선균(放線菌)류, 바실루스 마이코이데스(Bacillus mycoides)와 같은 간균(桿菌)류, 믹소박데리아(Myxobacteria)류, 곰팡이류(Aspergillus niger, Penicillium sp., Mucor sp., Fusarium sp. 등)와 같이 유기물질을 부식물질로 전환하는 폴리페놀(Polyphenol)성 화합물을 대사산물로 배설하는 부식화미생물 및 이들 미생물과 상호공생관계에 있는 토양미생물이 활동하게 되면서 유기물질을 안정된 부식물질로 전환하게 된다.Among the mesophilic microorganisms are actinomycetes, Bacillus mycoides such as Bacillus mycoides, Myxobacteria, fungi (Aspergillus niger, Penicillium sp., Mucor sp., Fusarium) corrosive microorganisms that excrete polyphenolic compounds, which convert organic substances into corrosive substances, as metabolites and soil microorganisms that are mutually symbiotic with these microorganisms. Will be converted into matter.

Figure 112003501532845-pat00003
Figure 112003501532845-pat00003

폴리페놀성 화합물은 공기 중에서 산화효소(Polyphenoloxidase)의 촉매작용에 의해서 퀴논(Quinone)화합물로 산화되면서 과산화수소(H2O2)가 생성되며, 과산화수소는 미생물이 배설하는 효소와 반응해서 산화효소를 생성한다.Polyphenolic compounds are oxidized to quinone compounds by the catalysis of polyphenoloxidase in the air to produce hydrogen peroxide (H 2 O 2 ), and hydrogen peroxide reacts with enzymes excreted by microorganisms to produce oxidase. do.

Figure 112003501532845-pat00004
Figure 112003501532845-pat00004

퀴논화합물은 미생물에 의해서 분해가 어려운 리그닌(Lignin), 셀룰로오스(Cellulose), 타닌(Tannin)과 같은 물질과 중축합반응(重縮合反應)을 하여 물에 불용성이면서 비휘발성인 안정된 부식물질로 전환된다.Quinone compounds are polycondensation reactions with materials such as lignin, cellulose, and tannin, which are difficult to decompose by microorganisms, and are converted into stable corrosive materials that are insoluble and nonvolatile in water. .

Figure 112003501532845-pat00016
Figure 112003501532845-pat00016

이때 악취를 발생하는 암모니아(NH3), 유화수소(H2S), 휘발성 아민류, 휘발성 알코올류, 휘발성 유기산류, 메르캅탄류와 같은 물질을 부식물질에 부동화(不動化 ; Immobilization) 됨으로써 악취발생이 저감하게 된다.At this time, odor is generated by immobilizing substances such as ammonia (NH 3 ), hydrogen sulfide (H 2 S), volatile amines, volatile alcohols, volatile organic acids, and mercaptans, which generate odors, to corrosive substances. This reduces.

Figure 112003501532845-pat00017
Figure 112003501532845-pat00017

부식물질은 토양의 조암광물(造岩鑛物)에 함유되어 있는 활성미네랄성분과 반응하여 킬레이트(Chelate)성 부식산미네랄착염 상태인 콜로이드 미셀(Colloidal micelle)형태의 부식물질이 생성된다.The corrosive reacts with the active minerals contained in the coarse minerals of the soil to produce colloidal micelle in the form of chelate hydrochloric acid mineral complex.

Figure 112003501532845-pat00018
Figure 112003501532845-pat00018

또한, 부식화미생물 및 이들 미생물과 상호 공생관계에 있는 토양미생물은 악취발생을 유발하는 부패성 미생물 및 유해병원성 미생물의 생육을 억제하는 항생물질을 배설하여 이들 미생물의 생육을 억제함으로써 상호길항관계를 유지하게 된다.In addition, corrosive microorganisms and soil microorganisms which have mutual symbiosis with these microorganisms maintain mutual antagonistic relationship by suppressing the growth of these microorganisms by suppressing the growth of antibiotics that inhibit the growth of decaying microorganisms and pathogenic microorganisms causing odor. Done.

따라서 부식화미생물 및 이들 미생물과 상호 공생관계에 있는 토양미생물의 생육환경조건을 최적의 상태로 유지하여 주면 악취발생은 억제하게 된다.Therefore, if the growth environment conditions of corrosive microorganisms and soil microorganisms which are in symbiosis with these microorganisms are maintained in an optimal state, the occurrence of odor is suppressed.

Figure 112003501532845-pat00008
Figure 112003501532845-pat00008

그리고 사상균류, 슈도모나스(Pseudomonas sp.)와 같은 미생물은 부식물질을 먹이로 섭취하여 대사산물 중 식물성장에 유용한 생리적 활성물질인 비타민(Vitamin)류와 성장촉진물질인 호르몬(Hormon)류와 같은 식물성장에 유용한 물질을 배설한다.Microorganisms such as filamentous fungi and Pseudomonas sp. Feed on corrosive substances and feed on plants such as vitamins (Vitamin), which are useful for plant growth, and hormones (Hormon), which are useful for plant growth. Excrete substances useful for growth;

Figure 112003501532845-pat00019
Figure 112003501532845-pat00019

유기물질을 부식물질로 전환하는 폴리페놀(Polyphenol)성 화합물을 배설하는 전술한 부식화미생물과 이들 미생물과 상호공생관계에 있는 토양미생물은 세포막이나 세포핵 중에는 미네랄 함량이 높은 특성이 있음으로 미네랄 및 활성물질을 충분히 공급하였을 때 이들 미생물과 상호공생관계에 있는 토양미생물들의 대사활동이 활발하게 되면서, 길항관계에 있는 부패를 야기하는 혐기성 미생물이나 병원성 미생물 등은 생육이 억제하게 된다.The above-mentioned corrosive microorganisms that excrete polyphenolic compounds that convert organic substances into corrosive substances and soil microorganisms which have mutual symbiosis with these microorganisms have high mineral content in cell membranes or cell nuclei. When enough substances are supplied, the metabolic activity of soil microorganisms which are mutually symbiotic with these microorganisms becomes active, and anaerobic microorganisms and pathogenic microorganisms that cause antagonistic decay are suppressed from growth.

본 발명은 유기물질을 부패하여 악취를 발생시키는 혐기성 미생물의 생육을 최대한 억제하여 전술한 ②의 반응을 방지하기 위해서는 혐기성 미생물과 상호길항관계에 있는 부식물질을 생성하는 부식화미생물과 공생관계에 있는 토양미생물을 배양하여 발효숙성공정(4)의 전단에 공급하며, 잉여배양액은 액비화공정이나 폐수처리공정으로 보낸다.The present invention in order to inhibit the growth of anaerobic microorganisms that cause odors by decaying organic substances to the maximum to prevent the reaction of the above ② to have a symbiotic relationship with the corrosive microorganisms that produce corrosive substances that are antagonistic relationship with anaerobic microorganisms Soil microorganisms are cultured and supplied to the front end of the fermentation ripening process (4), and the excess culture liquid is sent to the liquefaction process or wastewater treatment process.

부식화미생물과 이들 미생물과 상호공생관계에 있는 토양미생물을 배양하기 위한 배양액으로는 발효숙성공정에서 배출되는 침출수를 미생물배양조(14)에 공급하고, 송풍기(20)로부터 공기를 주입하여 폭기를 하면서 배양된 배양액은 미생물농축조(15)로 보내어 청등액은 상부로 익류하여 배양액저장조(18)로 보낸 다음에 배양액이송펌프(19)에 의해서 발효숙성공정(4)의 고온발효부 전단에 공급하며, 미생물과 부식전구물질(腐植前驅物質)인 고형물질이 미생물농축조(15) 하부에 침전된 오니(미생물균체)는 미생물반송펌프(17)에 의해서 종균용으로 미생물배양조(14) 및 미생물활성화조(11)로 반송하면서 발효숙성공정(4)의 전단과 고온발효부의 후단에 공급한다.As a culture medium for culturing corrosive microorganisms and soil microorganisms having mutual symbiosis with these microorganisms, leachate discharged from the fermentation aging process is supplied to the microbial culture tank 14, and air is blown from the blower 20 to aeration. While culturing the culture solution is sent to the microbial concentrator 15, the blue water is fed to the top to the culture medium storage tank 18, and then supplied to the front end of the high temperature fermentation step of the fermentation ripening process (4) by the culture medium transfer pump (19) , Microorganisms and microbial solids, which are corrosive precursors, are deposited in the lower part of the microbial concentrator (15), and microbial culture tank (14) and microbial activation are used for spawning by microbial transfer pump (17). While conveying to the tank 11, it supplies to the front end of the fermentation aging process 4, and the rear end of a high temperature fermentation part.

미생물활성화조(11)에는 미네랄 공급이 용이한 유문암(流紋岩) 또는 대사이드(Dacite)질의 부석(浮石)과 킬레이트성 풀브산미네랄착염(Chelatic mineral fulvate)성분이 많은 해양성 부식산콜로이드미셀(Colloidal micelle) 형태의 부식토(이탄)를 펠렛트(Pellet)형태로 성형 가공한 것을 충전한 생물반응기(Bio-reactor; 12)를 설치하고 송풍기(20)로부터 공기를 미생물활성화조(11)와 생물반응기(12)에 공급하면서 폭기를 하면 공급된 미생물배양액은 전술한 광물질 및 부식물질펠렛트(Pellet)의 충전층(13)을 순환하면서 유기물질을 부식물질로 전환하는 폴리페놀성 대사산물을 배설하는 부식화미생물과 상호공생관계에 있는 토양미생물은 생육에 필요한 각종 미네랄성분과 기타 활성물질을 공급받아 활발한 대사활동을 하면서 활성화된 미생물을 미생물배양조(14)에 공급하면 이들 미생물이 우점종(優占種)으로 생육하는 환경 분위기로 전환된다.The microorganism activator 11 has marine corrosive colloid micelles containing a lot of rhyolite or dacite feldspar and chelating mineral fulvate that are easily supplied with minerals. A bio-reactor (12) filled with a colloidal micelle-shaped humus (peel) formed into pellets was installed, and air was blown from the blower 20 to the microorganism activator 11 and the organism. When the aeration is supplied while supplying to the reactor 12, the supplied microbial culture liquid excites the polyphenolic metabolite that converts the organic material into the corrosive material while circulating the packed bed 13 of the above-described mineral and corrosive pellets. Soil microorganisms, which are mutually symbiotic with corrosive microorganisms, are supplied with various minerals and other active substances necessary for growth, and have active metabolism and supply the activated microorganisms to the microorganism culture tank (14). The microorganism is switched to the environment atmosphere to grow as a dominant species (優 占 種).

그리고 도 2에서와 같이 미생물활성화조(11)의 미생물배양액을 미생물활성화조순환펌프(21)에 의해서 자속밀도(磁束密度)가 10,000G(Gauss)이상 착자(着磁)된 영구자석이나 전자석(22)의 자계(磁界)와 자속밀도가 200G이상 착자된 자철광괴(磁 鐵鑛塊 ; 25)가 충전된 자화기(24)를 순환시키면 자기유체역학(MHD ; Magneto-Hydro-Dynamics)전압이 발생하면서 전자의 파동(波動)에 의해서 물 분자의 집단체(集團體 ; Cluster)가 미세화(微細化) 되면서 표면장력(表面張力)이 적어져 침투력(浸透力)이 향상되면 미생물의 세포막의 투과율이 향상되어 미생물의 대사활동을 더욱더 활발하게 한다.As shown in FIG. 2, the permanent magnet or electromagnet having the magnetic flux density of at least 10,000 G (Gauss) magnetized by the microbial activating tank 11 of the microbial activating tank circulating pump 21. Circulating magnetizer 24 filled with magnetron mass (25) magnetized with magnetic field and magnetic flux density of 200G or higher) generates magneto-hydrodynamics (MHD) voltage. The microscopic clusters of water molecules are reduced by the wave of the electrons, and the surface tension is reduced, and the penetration force is improved. Improves the metabolic activity of microorganisms.

전술한 유기물질을 부식물질로 전환하는 폴리페놀성대사산물을 배설하는 부식화미생물 및 이들 미생물과 상호공생관계에 있는 토양미생물을 배양하는 배양공정에서 배양된 미생물배양액을 발효숙성공정(4)에 주입하면 반응식②의 부패반응은 최대한 억제되면서 악취발생물질은 반응식⑦에서와 같이 부동화(不動化)반응에 의해서 비휘발성의 안정된 부식(전구)물질로 전환됨으로써 악취발생이 저감되는 반면에 퇴비화공정에서 유용한 반응인 반응식① 및 ③에서 ⑨까지의 부식화반응이 활발하게 일어나므로 발효숙성기간이 단축하게 된다.The microbial culture liquid cultured in the culture step of culturing the corrosive microorganisms that excrete polyphenolic metabolites converting the above-mentioned organic substances into the corrosive substances and the soil microorganisms having mutual symbiosis with these microorganisms is subjected to the fermentation ripening step (4). When injected, the decay reaction of the reaction equation ② is suppressed as much as possible, and the odor generating material is converted into a non-volatile stable corrosion (bulb) material by the passivation reaction as in the reaction equation ⑦. Corrosion reactions from reaction equations ① and ③ to ⑨, which are useful reactions, occur actively, thereby reducing the fermentation ripening period.

그리고 방선균류, 페니실륨류(Penicillium sp.)와 같은 미생물이 공생하면서 반응식⑩의 반응이 일어나 악취발생을 유발하는 부패성 미생물 및 유해병원성 미생물의 생육을 억제하는 항생물질이 다량 함유되어 있으며, 식물의 식물성장에 유용한 생리적 활성물질인 비타민(Vitamin)류와 성장촉진물질인 호르몬(Hormon)류와 같은 식물성장에 유용한 물질을 대사산물로 배설하는 사상균류, 슈도모나스(Pseudomonas sp.)와 같은 공생미생물의 생육도 활성화되면서 반응식⑩ 및 ⑪의 반응이 활발하게 일어남으로써 식물성장에 유용한 물질이 다량 함유되어있는 양질의 퇴비가 생산된다.And microorganisms such as actinomycetes and penicillium sp. Coexist with the reaction of the reaction formula and contain a large amount of antibiotics that inhibit the growth of rot and microorganisms that cause odor. Symbiotic microorganisms such as Pseudomonas sp., A fungus that excretes substances useful for plant growth, such as vitamins, which are useful for plant growth, and hormones, which are growth promoters, as metabolites. As the growth is also activated, the reactions of reaction formulas ⑪ and 일 occur actively, producing high quality compost containing a large amount of substances useful for plant growth.

삭제delete

삭제delete

삭제delete

전술한 기술내용으로부터 자명하듯이, 본 발명은 음식물쓰레기와 같은 유기성 폐기물을 이물질제거, 파쇄, 탈염과 같은 전 처리를 한 다음에 팽윤제 및 기타첨가물을 주입하고 발효숙성공정에서 유기물질을 안정된 부식물질로 전환하는 부식화미생물 및 이들 미생물과 상호공생관계에 있는 토양미생물을 배양한 배양액을 공급하였을 때 악취발생이 월등히 저감되며, 발효숙성기간이 단축되면서 양질의 퇴비를 생산할 수 있기 때문에 유기성 폐기물의 퇴비화공정에 널리 보급될 것으로 기대된다.As is apparent from the above description, the present invention is to pre-treat organic waste such as food waste, pretreatment such as debris removal, crushing and desalting, and then injecting swelling agent and other additives, and stably corroding organic materials in the fermentation aging process. Odor generation is greatly reduced by supplying the cultured culture of corrosive microorganisms that convert into substances and soil microorganisms that have mutual symbiosis with these microorganisms, and it is possible to produce high-quality compost with a short fermentation ripening period. It is expected to be widely used in the composting process.

Claims (2)

① 음식물쓰레기와 같은 유기성 폐기물을 이물질의 제거, 파쇄처리, 염분의 제거와 같은 전 처리를 한 다음에 퇴비제조공정의 혼화기(1)에 주입한다.① Organic wastes such as food waste are pre-treated such as removing foreign matters, crushing, and salts, and then injected into the composting machine (1) of the composting process. ② 다음에, 첨가제로 천매암(千枚岩)을 작물의 종류, 토양의 특성, 용도를 고려하여 유기질/무기물의 비가 0.8∼10의 범위로 주입한다.② Next, cheonmaeam is added as an additive in an organic / inorganic ratio ranging from 0.8 to 10, taking into account the type of crop, soil characteristics, and use. ③ 다음에, 팽윤제(수분조절)로 톱밥 또는 이탄(토탄)을 함수율이 60wt%범위로 공급한 후에 혼화기 믹서(2)로 교반 혼합한다.(3) Next, sawdust or peat (peat) is supplied in the range of 60 wt% with a swelling agent (water control), followed by stirring and mixing with the mixer mixer 2. ④ 다음에, 발효숙성공정(4)으로 보내어 로터리 믹서(Rotary mixer; 5)로 뒤집기를 하면서 배출되는 침출수를 미생물배양조(14)에 공급하고, 송풍기(20)로부터 공기를 주입하여 폭기를 하면서 배양한 배양액은 미생물농축조(15)로 보내어 상부로 익류하는 것은 배양액저장조(18)로 보내고, 미생물농축조(15)하부에 침전된 오니는 미생물반송펌프(17)에 의해서 미생물 배양조(14)와, 미네랄 공급이 용이한 광물질인 유문암(流紋岩) 또는 대사이드(Dacite)질의 부석(浮石)과 부식물질을 펠렛트(Pellet)를 충전한 생물반응기(Bio-reactor; 12)가 내장된 미생물활성화조(11)로 반송하여 송풍기(20)로부터 공기를 미생물활성화조(11)와 생물반응기(12)에 공급하여 폭기를 하면서 배양한 배양액은 광물질과 부식물질 펠렛트(Pellet)의 충전층(13)을 순환하면서 미생물을 활성화하여 미생물배양조(14)로 보내는 미생물배양공정에서 배양한 부식화미생물 및 이들 미생물과 상호공생관계에 있는 토양미생물 배양액과 농축된 미생물을 발효숙성공정(4)의 전단과 고온발효부의 후단에 공급하는 공정에 의해서 유기성 폐기물을 퇴비화한다.(4) Next, the leachate discharged while being sent to the fermentation aging process (4) and inverted by a rotary mixer (5) is supplied to the microbial culture tank (14), and air is blown from the blower (20) to aeration. The culture medium is sent to the microorganism concentration tank (15), and the upstream is sent to the culture medium storage tank (18), the sludge deposited under the microorganism concentration tank (15) by the microbial transfer pump (17) and the microorganism culture tank (14) Microorganisms with bio-reactor (12) filled with pellets filled with pyrites and luteite or daphite of minerals that are easily supplied with minerals The culture medium conveyed to the activation tank 11 and supplied with air from the blower 20 to the microorganism activation tank 11 and the bioreactor 12 and aerated to form a packed bed of mineral and corrosive pellets ( 13) activate microorganisms by circulating The step of supplying the corrosive microorganisms cultured in the microbial culture step sent to the culture tank 14 and the soil microbial culture medium and the concentrated microorganisms which are mutually related to these microorganisms to the front end of the fermentation ripening step (4) and the rear end of the high temperature fermentation part. To compost organic waste. 상술한 퇴비화공정에 의해서 음식물쓰레기와 같은 유기성 폐기물을 퇴비화하는 방법.A method for composting organic waste such as food waste by the above composting process. 제1항에 있어서, 미생물활성화조(11)의 미생물배양액을 미생물활성화조순환펌프(21)에 의해서 자속밀도(磁束密度)가 10,000G(Gauss)이상 착자(着磁)된 영구자석이나 전자석(22)의 자계(磁界)가 200G이상 착자된 자철광괴(25)가 충전된 자화기(24)를 순환시키는 설비를 추가한 공정에 의해서 음식물쓰레기와 같은 유기성 폐기물을 퇴비화하는 방법.The permanent magnet or electromagnet (22) according to claim 1, wherein the microbial culture liquid of the microorganism activating tank (11) is magnetized by a microorganism activating tank circulation pump (21) with a magnetic flux density of 10,000 G (Gauss) or more. A method of composting organic waste such as food waste by a step of adding a facility for circulating a magnetizer 24 filled with a magnetite mass 25 magnetized with a magnetic field of 200 g or more.
KR1020030005374A 2003-01-27 2003-01-27 Composting method of organic waste such as food waste Expired - Fee Related KR100577841B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020030005374A KR100577841B1 (en) 2003-01-27 2003-01-27 Composting method of organic waste such as food waste

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020030005374A KR100577841B1 (en) 2003-01-27 2003-01-27 Composting method of organic waste such as food waste

Publications (2)

Publication Number Publication Date
KR20040068821A KR20040068821A (en) 2004-08-02
KR100577841B1 true KR100577841B1 (en) 2006-05-12

Family

ID=37357851

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020030005374A Expired - Fee Related KR100577841B1 (en) 2003-01-27 2003-01-27 Composting method of organic waste such as food waste

Country Status (1)

Country Link
KR (1) KR100577841B1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100976848B1 (en) 2008-04-25 2010-08-20 배연호 Compost production method using food waste

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100792166B1 (en) * 2006-01-19 2008-01-09 (주)지앤엘 Waste and waste treatment methods containing organic matter
KR100909845B1 (en) * 2007-11-22 2009-07-28 오션 스타 주식회사 Organic Fertilizer Manufacturing Method
KR101765488B1 (en) 2015-02-12 2017-08-23 주식회사 티에스엔티글로벌 Apparatus for fermenting an organic waste and fertilizer of livestock excretion using soil microorganism, biofield generating apparatus for the same, microorganism battery for the same and microorganism condenser for the same
KR102504601B1 (en) 2021-04-08 2023-03-02 한국기계연구원 Foreign matter removal device and dewatering system having the same

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020030674A (en) * 2000-10-19 2002-04-25 윤종용 method of numerically analyzing growth degree of grains on a semiconductor wafer by using a SEM image and apparatus for realizing the same

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020030674A (en) * 2000-10-19 2002-04-25 윤종용 method of numerically analyzing growth degree of grains on a semiconductor wafer by using a SEM image and apparatus for realizing the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100976848B1 (en) 2008-04-25 2010-08-20 배연호 Compost production method using food waste

Also Published As

Publication number Publication date
KR20040068821A (en) 2004-08-02

Similar Documents

Publication Publication Date Title
JP2015167912A (en) Livestock excreta treating system
Vyas et al. Vermicomposting with microbial amendment: implications for bioremediation of industrial and agricultural waste
KR20040017512A (en) Production method of seed-bed soil.
EA028181B1 (en) Method of production of organic fertilizer
KR100577841B1 (en) Composting method of organic waste such as food waste
KR100472969B1 (en) Manufacturing method of a liquefied fertilizer
Ezeah et al. Design principles of sustainable composting and recovery of value from compost
Gupta et al. Vermitechnology for organic waste recycling
KR20180124232A (en) Manufacturing method of liquid manure
KR100480181B1 (en) Manufacturing method for magnetized fertilizer.
CN115368195B (en) Sludge composting method and application thereof
KR101712526B1 (en) Composition for treating organic waste water, treatment method of organic waste water using thereof and nutrient solution manufactured by the same
RU2141932C1 (en) Bio-organic fertilizer
KR100624783B1 (en) High-efficiency wastewater treatment method
KR100518722B1 (en) Method of garbage treatment
KR100487582B1 (en) Device for treating sludge of sewage or organic wastewater and method thereof
JP2525563B2 (en) Method and apparatus for manufacturing organic fertilizer
KR100343197B1 (en) An Organic Compound Decomposing Material and the Use thereof
KR20040048758A (en) Method of making fertilizer (compost) by fermenting organic waste (food + livestock) by using coco peat, molasses (CMS) and charcoal, and fertilizer (compost) produced thereby
KR100482988B1 (en) Manufacturing method of feedstuff for domestic animals
KR200313908Y1 (en) Malodorant removing equipment for waste organic materials
KR100424157B1 (en) Composting method for organic waste substrate by using activated humic substances and humification bacteria
KR102747047B1 (en) Method for redecing sludge and odor, multicomplex fermentation microorganism liquors using the same, and manufacturing method thereof
CN120004675A (en) Directional humification micro-factory for agricultural waste compost and application thereof
Ilyin et al. Environmentally proved methods of cascade conversion of organic waste using a microbial complex with filamentous fungi

Legal Events

Date Code Title Description
A201 Request for examination
PA0109 Patent application

Patent event code: PA01091R01D

Comment text: Patent Application

Patent event date: 20030127

PA0201 Request for examination
AMND Amendment
PG1501 Laying open of application
E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

Comment text: Notification of reason for refusal

Patent event date: 20050111

Patent event code: PE09021S01D

AMND Amendment
E90F Notification of reason for final refusal
PE0902 Notice of grounds for rejection

Comment text: Final Notice of Reason for Refusal

Patent event date: 20050517

Patent event code: PE09021S02D

AMND Amendment
E601 Decision to refuse application
PE0601 Decision on rejection of patent

Patent event date: 20050926

Comment text: Decision to Refuse Application

Patent event code: PE06012S01D

Patent event date: 20050517

Comment text: Final Notice of Reason for Refusal

Patent event code: PE06011S02I

Patent event date: 20050111

Comment text: Notification of reason for refusal

Patent event code: PE06011S01I

J201 Request for trial against refusal decision
PJ0201 Trial against decision of rejection

Patent event date: 20051026

Comment text: Request for Trial against Decision on Refusal

Patent event code: PJ02012R01D

Patent event date: 20050926

Comment text: Decision to Refuse Application

Patent event code: PJ02011S01I

Appeal kind category: Appeal against decision to decline refusal

Decision date: 20051207

Appeal identifier: 2005101007301

Request date: 20051026

AMND Amendment
PB0901 Examination by re-examination before a trial

Comment text: Amendment to Specification, etc.

Patent event date: 20051120

Patent event code: PB09011R02I

Comment text: Request for Trial against Decision on Refusal

Patent event date: 20051026

Patent event code: PB09011R01I

Comment text: Amendment to Specification, etc.

Patent event date: 20050603

Patent event code: PB09011R02I

Comment text: Amendment to Specification, etc.

Patent event date: 20050216

Patent event code: PB09011R02I

Comment text: Amendment to Specification, etc.

Patent event date: 20030210

Patent event code: PB09011R02I

B701 Decision to grant
PB0701 Decision of registration after re-examination before a trial

Patent event date: 20051207

Comment text: Decision to Grant Registration

Patent event code: PB07012S01D

Patent event date: 20051201

Comment text: Transfer of Trial File for Re-examination before a Trial

Patent event code: PB07011S01I

GRNT Written decision to grant
PR0701 Registration of establishment

Comment text: Registration of Establishment

Patent event date: 20060502

Patent event code: PR07011E01D

PR1002 Payment of registration fee

Payment date: 20060502

End annual number: 3

Start annual number: 1

PG1601 Publication of registration
PR1001 Payment of annual fee

Payment date: 20091103

Start annual number: 4

End annual number: 4

PR1001 Payment of annual fee

Payment date: 20100503

Start annual number: 5

End annual number: 5

PR1001 Payment of annual fee

Payment date: 20110503

Start annual number: 6

End annual number: 6

PR1001 Payment of annual fee

Payment date: 20120502

Start annual number: 7

End annual number: 7

FPAY Annual fee payment

Payment date: 20130502

Year of fee payment: 8

PR1001 Payment of annual fee

Payment date: 20130502

Start annual number: 8

End annual number: 8

FPAY Annual fee payment

Payment date: 20140507

Year of fee payment: 9

PR1001 Payment of annual fee

Payment date: 20140507

Start annual number: 9

End annual number: 9

FPAY Annual fee payment

Payment date: 20150506

Year of fee payment: 10

PR1001 Payment of annual fee

Payment date: 20150506

Start annual number: 10

End annual number: 10

FPAY Annual fee payment

Payment date: 20160503

Year of fee payment: 11

PR1001 Payment of annual fee

Payment date: 20160503

Start annual number: 11

End annual number: 11

LAPS Lapse due to unpaid annual fee
PC1903 Unpaid annual fee

Termination category: Default of registration fee

Termination date: 20180213