KR100523676B1 - Liquid insecticidal preparation for heat fumigation and insecticidal method by heat fumigation - Google Patents
Liquid insecticidal preparation for heat fumigation and insecticidal method by heat fumigation Download PDFInfo
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- KR100523676B1 KR100523676B1 KR1019960039596A KR19960039596A KR100523676B1 KR 100523676 B1 KR100523676 B1 KR 100523676B1 KR 1019960039596 A KR1019960039596 A KR 1019960039596A KR 19960039596 A KR19960039596 A KR 19960039596A KR 100523676 B1 KR100523676 B1 KR 100523676B1
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- isopropyl
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- saturated hydrocarbon
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- 239000007788 liquid Substances 0.000 title claims abstract description 25
- 230000000749 insecticidal effect Effects 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 238000003958 fumigation Methods 0.000 title claims description 25
- 238000000034 method Methods 0.000 title claims description 11
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 22
- 230000000361 pesticidal effect Effects 0.000 claims abstract description 22
- 229930195734 saturated hydrocarbon Natural products 0.000 claims abstract description 21
- 230000002745 absorbent Effects 0.000 claims abstract description 16
- 239000002250 absorbent Substances 0.000 claims abstract description 16
- 238000010438 heat treatment Methods 0.000 claims abstract description 15
- -1 isopropyl ester Chemical class 0.000 claims abstract description 11
- 150000001875 compounds Chemical class 0.000 claims abstract description 7
- 239000002728 pyrethroid Substances 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 42
- 238000009472 formulation Methods 0.000 claims description 38
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- 150000004665 fatty acids Chemical class 0.000 claims description 9
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 claims description 9
- 125000001931 aliphatic group Chemical group 0.000 claims description 7
- NDJKXXJCMXVBJW-UHFFFAOYSA-N Heptadecane Natural products CCCCCCCCCCCCCCCCC NDJKXXJCMXVBJW-UHFFFAOYSA-N 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 6
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 6
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 claims description 6
- 229940089456 isopropyl stearate Drugs 0.000 claims description 6
- RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 claims description 6
- YCOZIPAWZNQLMR-UHFFFAOYSA-N pentadecane Chemical compound CCCCCCCCCCCCCCC YCOZIPAWZNQLMR-UHFFFAOYSA-N 0.000 claims description 6
- ZPWFUIUNWDIYCJ-UHFFFAOYSA-N propan-2-yl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC(C)C ZPWFUIUNWDIYCJ-UHFFFAOYSA-N 0.000 claims description 6
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 claims description 6
- IIYFAKIEWZDVMP-UHFFFAOYSA-N tridecane Chemical compound CCCCCCCCCCCCC IIYFAKIEWZDVMP-UHFFFAOYSA-N 0.000 claims description 6
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 claims description 6
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 claims description 5
- AMEMLELAMQEAIA-UHFFFAOYSA-N 6-(tert-butyl)thieno[3,2-d]pyrimidin-4(3H)-one Chemical compound N1C=NC(=O)C2=C1C=C(C(C)(C)C)S2 AMEMLELAMQEAIA-UHFFFAOYSA-N 0.000 claims description 5
- 229940033357 isopropyl laurate Drugs 0.000 claims description 5
- 229940074928 isopropyl myristate Drugs 0.000 claims description 5
- 229940075495 isopropyl palmitate Drugs 0.000 claims description 5
- 239000000575 pesticide Substances 0.000 claims description 4
- SBNFWQZLDJGRLK-RTWAWAEBSA-N (1R)-trans-phenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-RTWAWAEBSA-N 0.000 claims description 3
- 125000002723 alicyclic group Chemical group 0.000 claims description 3
- 229940038384 octadecane Drugs 0.000 claims description 3
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 claims description 3
- 229960000490 permethrin Drugs 0.000 claims description 3
- 229960003536 phenothrin Drugs 0.000 claims description 3
- 206010017472 Fumbling Diseases 0.000 claims description 2
- 239000003090 pesticide formulation Substances 0.000 claims description 2
- 229960002380 dibutyl phthalate Drugs 0.000 claims 2
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 claims 2
- 230000008020 evaporation Effects 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 239000011521 glass Substances 0.000 description 5
- 241000255925 Diptera Species 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- JQCXWCOOWVGKMT-UHFFFAOYSA-N diheptyl phthalate Chemical compound CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 241000238631 Hexapoda Species 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- UWCVGPLTGZWHGS-ZORIOUSZSA-N pergolide mesylate Chemical compound CS(O)(=O)=O.C1=CC([C@H]2C[C@@H](CSC)CN([C@@H]2C2)CCC)=C3C2=CNC3=C1 UWCVGPLTGZWHGS-ZORIOUSZSA-N 0.000 description 2
- ZCVAOQKBXKSDMS-PVAVHDDUSA-N (+)-trans-(S)-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)O[C@@H]1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-PVAVHDDUSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 241000144210 Culex pipiens pallens Species 0.000 description 1
- 239000005896 Etofenprox Substances 0.000 description 1
- FSYXMFXBRJFYBS-UHFFFAOYSA-N Furamethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCC1=CC=C(CC#C)O1 FSYXMFXBRJFYBS-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 241000257226 Muscidae Species 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000003146 anticoagulant agent Substances 0.000 description 1
- 229940127219 anticoagulant drug Drugs 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229960001901 bioallethrin Drugs 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- YREQHYQNNWYQCJ-UHFFFAOYSA-N etofenprox Chemical compound C1=CC(OCC)=CC=C1C(C)(C)COCC1=CC=CC(OC=2C=CC=CC=2)=C1 YREQHYQNNWYQCJ-UHFFFAOYSA-N 0.000 description 1
- 229950005085 etofenprox Drugs 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- UTUZBCDXWYMYGA-UHFFFAOYSA-N silafluorene Chemical compound C12=CC=CC=C2CC2=C1C=CC=[Si]2 UTUZBCDXWYMYGA-UHFFFAOYSA-N 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M1/00—Stationary means for catching or killing insects
- A01M1/20—Poisoning, narcotising, or burning insects
- A01M1/2022—Poisoning or narcotising insects by vaporising an insecticide
- A01M1/2061—Poisoning or narcotising insects by vaporising an insecticide using a heat source
- A01M1/2077—Poisoning or narcotising insects by vaporising an insecticide using a heat source using an electrical resistance as heat source
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/18—Vapour or smoke emitting compositions with delayed or sustained release
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Toxicology (AREA)
- Insects & Arthropods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
Abstract
제제 총량을 기준으로 하여, 피레트로이드 화합물(a) 0.1 내지 15중량%, 고급 지방산의 이소프로필 에스테르 또는 디부틸 프탈레이트(b) 0.3 내지 10중량% 및 비점이 180 내지 310℃인 포화 탄화수소(c)를 포함하는 가열 증산용 액체 살충 제제는 다공성 흡수 심지를 그 속에 침지시킴으로써 제제를 심지에 흡수시키고 제제에 침지된 부분과 다른 심지 부분을 가열함으로써 제제를 증산시켜 사용할 때 장시간 안정한 살충 효과로 다공성 흡수 심지가 막히지 않으면서 안정하게 증산된다.Saturated hydrocarbons (c) having from 0.1 to 15% by weight of the pyrethroid compound (a), from 0.3 to 10% by weight of isopropyl ester or dibutyl phthalate (b) and from 180 to 310 ° C The liquid pesticidal preparation for heating evaporation comprising a porous absorbent wick with a stable insecticidal effect for a long time when the product is absorbed into the wick by immersing the porous absorbent wick in the wick, and the immersed portion of the preparation and other wicking parts are heated for use. Is stably increased without clogging.
Description
본 발명의 목적은 고급 지방산의 이소프로필 에스테르 또는 디부틸 프탈레이트를 액체 살충 제제에 가함으로써 흡수 심지의 응고를 방지하고 제제의 안정한 훈증(fumigation)을 가능하게 하면서 장시간 동안 안정된 살충 효과를 유지시키는 것이다.It is an object of the present invention to maintain the stable pesticidal effect for a long time by adding isopropyl ester or dibutyl phthalate of higher fatty acids to the liquid pesticidal formulation, preventing the wicking of the absorbent wick and allowing stable fumigation of the formulation.
본 발명은 신규한 가열 훈증용 액체 살충 제제 및 가열 훈증에 의한 살충 방법에 관한 것이다.The present invention relates to a novel liquid pesticidal preparation for heat fumigation and pesticidal methods by heat fumigation.
다공성 흡수 심지의 일부를 액체 살충 제제에 침지시킴으로써 제제를 심지에 흡수시키고 제제에 침지된 부분과는 상이한 심지 부분을 가열함으로써 흡수된 제제를 훈증시킴을 포함하여, 열에 의해 액체 살충 제제를 훈증시키는 종래의 방법에서는, 흡수 심지의 응고, 가열 훈증 도중의 제제의 조성 변화 등으로 인해 안정한 살충 효과로 장시간 동안 제제를 안정하게 훈증시키기가 곤란하였으며, 이에 따라 안정한 살충 효과를 가지면서 안정하게 훈증시킬 수 있는 가열 훈증용 액체 살충 제제를 개발하는 것이 필요하다.A conventional method of fumigation of a liquid pesticidal formulation by heat, including fumbling the absorbent formulation by absorbing the formulation into the wick by heating a portion of the porous absorbent wick in the liquid pesticidal formulation and heating the wick portion different from the portion immersed in the formulation. In the method of the present invention, it was difficult to stir the formulation stably for a long time due to the stable insecticidal effect due to the coagulation of the absorbent wick and the change of the composition of the formulation during the heating fumigation, and thus it was possible to stably fumigation while having a stable insecticidal effect. It is necessary to develop liquid pesticidal preparations for heat fumigation.
본 발명의 제1 양태에 따라, 제제 총량을 기준으로 하여, (a) 피레트로이드 화합물 0.1 내지 15중량%, (b) 고급 지방산의 이소프로필 에스테르 또는 디부틸 프탈레이트 0.3 내지 10중량% 및 (c) 비점이 180 내지 310℃인 포화 탄화수소(들)를 포함하는 액체 살충 제제가 제공된다.According to a first aspect of the invention, based on the total amount of the formulation, (a) 0.1 to 15% by weight of the pyrethroid compound, (b) 0.3 to 10% by weight of isopropyl ester or dibutyl phthalate of the higher fatty acid and (c) Liquid pesticide formulations are provided comprising saturated hydrocarbon (s) having a boiling point of 180 to 310 ° C.
본 발명의 제2 양태에 따라, 다공성 흡수 심지의 일부를 액체 살충 제제에 침지시킴으로써 제제를 심지에 흡수시키고 제제에 침지된 부분과는 상이한 심지 부분을 가열함으로써 흡수된 제제를 훈증시킴을 포함하는 가열 훈증에 의한 살충 방법을 제공하는데, 여기서, 액체 살충 제제는 제제 총량을 기준으로 하여, (a) 피레트로이드 화합물 0.1 내지 15중량%, (b) 고급 지방산의 이소프로필 에스테르 또는 디부틸 프탈레이트 0.3 내지 10중량% 및 (c) 비점이 180 내지 310℃인 포화 탄화수소(들)를 포함한다.According to a second aspect of the invention, a heating comprising absorbing a formulation into a wick by immersing a portion of the porous absorbent wick in a liquid pesticidal formulation and fumigation of the absorbed formulation by heating a wick portion different from the portion immersed in the formulation. A method of pesticide by fumigation, wherein the liquid pesticidal formulation is based on the total amount of the formulation: (a) 0.1 to 15% by weight of the pyrethroid compound, (b) isopropyl ester or dibutyl phthalate of higher fatty acids, 0.3 to 10 Wt% and (c) saturated hydrocarbon (s) having a boiling point of 180 to 310 ° C.
본 발명의 제3 양태에 따라, 가열 훈증을 위한 흡수 심지용 응고 방지제로서 고급 지방산의 이소프로필 에스테르 또는 디부틸 프탈레이트가 사용된다.According to a third aspect of the invention, isopropyl ester or dibutyl phthalate of higher fatty acids is used as the anticoagulant for absorption wicks for heat fumigation.
본 발명의 액체 살충 제제의 가열 훈증에는 흡수 심지의 응고가 결코 일어나지 않아 장시간 동안 안정한 살충 효과를 유지하면서 안정한 훈증이 가능하다.Heating fumigation of the liquid insecticidal formulation of the present invention does not occur coagulation of the absorbent wick, so that stable fumigation is possible while maintaining a stable insecticidal effect for a long time.
본 발명에 사용될 수 있는 피레트로이드 화합물의 예에는 알레트린, 바이오알레트린, 에스바이오트린, 프랄레트린, 푸라메트린, 엠펜트린, 레스메트린, 페노트린, 퍼메트린, 트란스플루트린, 테랄레트린, 실라플루오펜, 에토펜프록스 등이 포함된다.Examples of pyrethroid compounds that can be used in the present invention include allerthrin, bioalletrin, esbiothrin, praletrin, furamethrin, empentrin, resmethrin, phenothrin, permethrin, transflutrin, te Laletrin, silafluorene, etofenprox and the like.
본 발명에 사용될 수 있는 이소프로필 에스테르의 예에는 통상 탄소수가 12 내지 18인 지방산의 이소프로필 에스테르(예: 이소프로필 라우레이트, 이소프로필 미리스테이트, 이소프로필 팔미테이트, 이소프로필 스테아레이트 등)가 포함된다.Examples of isopropyl esters that can be used in the present invention usually include isopropyl esters of fatty acids having 12 to 18 carbon atoms (eg, isopropyl laurate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, etc.). do.
본 발명에 사용될 수 있는, 비점이 180 내지 310℃인 포화 탄화수소(들)는 단일 포화 탄화수소 또는 이들 2가지 이상의 혼합물(이는 모든 경우에 액체 상태여야 한다)일 수 있으며, 예를 들면 운데칸, 도데칸, 트리데칸, 테트라데칸, 펜타데칸, 헥사데칸, 헵타데칸, 옥타데칸 등과 같은 지방족 포화 탄화수소(들), 및 지방족 포화 탄화수소(들)에 상응하는 지환족 포화 탄화수소(들)가 포함된다. 포화 탄화수소(들)로서는, 넘버 0 솔벤트 H(No. 0 Solvent H; Nippon Oil Co., Ltd., Japan), 넘버 0 솔벤트 M(No. O Solvent M; Nippon Oil Co., Ltd., Japan), 넘버 0 솔벤트 L(No. O Solvent L; Nippon Oil Co., Ltd., Japan), 노멀 파라핀(Normal Paraffin; Sanseki-Texaco Chemical Co., Japan), 데오토미솔 A-1(Deotomisole A-1; Yoshitomi Pharmaceutical Industries Ltd., Japan), 아이피 솔벤트 2028(IP Solvent 2028, Idemitsu Petrochemical Co., Japan), 네오티오졸(Neothiosol; Chuo Kasei K.K., Japan), 노파르 12(Norpar 12; Exxon Chemical Co., USA), 노파르 13(Norpar 13; Exxon Chemical Co., USA), 노파르 15(Norpar 15; Exxon Chemical Co., USA), 이소파르 엠(Isopar M; Exxon Chemical Co., USA), 이소파르 엘(Isopar L; Exxon Chemical Co., USA), 이소파르 브이(Isopar V; Exxon Chemical Co., USA), 엑솔 디80(Exxsol D80; Exxon Chemical Co., USA), 엑솔 디110(Exxsol D110; Exxon Chemical Co., USA), 엑솔 디130(Exxsol D130; Exxon Chemical Co., USA) 등과 같은 시판되고 있는 지방족 및 지환족 포화 탄화수소(들)가 사용될 수 있다.Saturated hydrocarbon (s) having a boiling point of 180 to 310 ° C., which may be used in the present invention, may be a single saturated hydrocarbon or a mixture of two or more thereof, which should be liquid in all cases, for example undecane, dode Aliphatic saturated hydrocarbon (s) such as cannes, tridecane, tetradecane, pentadecane, hexadecane, heptadecane, octadecane, and the like, and alicyclic saturated hydrocarbon (s) corresponding to aliphatic saturated hydrocarbon (s). As the saturated hydrocarbon (s), No. 0 Solvent H; Nippon Oil Co., Ltd., Japan, No. 0 Solvent M; Nippon Oil Co., Ltd., Japan No. 0 Solvent L; Nippon Oil Co., Ltd., Japan, Normal Paraffin; Sanseki-Texaco Chemical Co., Japan, Deotomisole A-1 Yoshitomi Pharmaceutical Industries Ltd., Japan, IP Solvent 2028, Idemitsu Petrochemical Co., Japan, Neothiosol; Chuo Kasei KK, Japan, Norpar 12; Exxon Chemical Co. , USA), Norpar 13; Exxon Chemical Co., USA, Norpar 15; Exxon Chemical Co., USA, Isopar M; Exxon Chemical Co., USA, Isopar Isopar L; Exxon Chemical Co., USA; Isopar V; Exxon Chemical Co., USA; Exxsol D80; Exxon Chemical Co., USA; Exxsol D110 Exxon Chemical Co., USA), Exxsol D130; Exxon Chemical Co., USA, etc. Aliphatic and cycloaliphatic available on the market can be used as the saturated hydrocarbon (s).
비점이 180 내지 310℃인 포화 탄화수소(들)의 양은 특별히 한정되지 않지만, 본 발명의 제제의 총량을 기준으로 하여 통상 50 내지 99.6중량%이다.The amount of saturated hydrocarbon (s) having a boiling point of 180 to 310 ° C. is not particularly limited, but is usually 50 to 99.6% by weight based on the total amount of the formulation of the present invention.
본 발명의 액체 살충 제제는 경우에 따라 향료, 및 BHT와 같은 안정화제 등을 함유할 수 있다.The liquid pesticide preparation of the present invention may optionally contain a flavoring agent, a stabilizer such as BHT, and the like.
다공성 흡수 심지의 일부(예를 들면, 하부)를 본 발명의 액체 살충 제제에 침지시킴으로써 제제를 심지에 흡수시키고 침지된 부분과는 상이한 심지 부분(예를 들면, 침지된 부분이 하부인 경우 상부)을 가열함으로써 훈증시킬 수 있다.A part of the porous absorbent wick (eg, the bottom) is immersed in the liquid pesticidal formulation of the present invention to absorb the formulation into the wick and the wick portion that is different from the immersed portion (eg, the top if the immersed portion is the bottom). Can be fumigation by heating.
본 발명에 사용될 수 있는 흡수 심지용 다공성 재료의 예에는 카복시메틸 셀룰로즈 전분, 아라비아 고무, 젤라틴, 폴리비닐 알콜 등과 같은 결합제와 결합시키고 성형시킨 점토, 활석, 고령토, 규조토, 석고, 퍼얼라이트, 벤토나이트, 산성 백토, 유리 섬유, 석면 등과 같은 무기 분말이 포함된다. 흡수 심지는 경우에 따라 안료, 방부제 등을 함유할 수 있다.Examples of porous materials for absorbent wicks that can be used in the present invention include clays, talc, kaolin, diatomaceous earth, gypsum, pearlite, bentonite, which are bonded and molded with binders such as carboxymethyl cellulose starch, gum arabic, gelatin, polyvinyl alcohol, and the like. Inorganic powders such as acidic clay, glass fibers, asbestos and the like. Absorption wick may contain a pigment, a preservative, etc. as needed.
흡수 심지는 전기 히터와 같은 순환 가열기로 간접 가열하여 약 100 내지 160℃로 가열할 수 있다.The absorbent wick can be heated indirectly with a circulating heater, such as an electric heater, to about 100 to 160 ° C.
가열 훈증에 의한 본 발명의 살충 방법은 문헌(참조. JP-B-2-25885 등)에 기술되어 있는 살충용 가열 훈증형 장치에 적용시 매우 효과적이다.The insecticidal method of the present invention by heating fumigation is very effective when applied to the insecticidal heating fumigation type apparatus described in the literature (cf. JP-B-2-25885, etc.).
본 발명의 방법으로 살충되는 곤충은 본 발명의 액체 살충 제제에 함유된 피레트로이드 화합물에 의해 살충되며, 곤충의 예에는 모기, 집파리 등이 포함된다.Insects that are killed by the methods of the present invention are killed by pyrethroid compounds contained in the liquid pesticide preparations of the present invention, and examples of the insects include mosquitoes, house flies, and the like.
본 발명은 실시예를 참고하여 이하 상세히 설명될 것이다.The invention will be described in detail below with reference to examples.
실시예 1Example 1
성분(a)로서 프랄레트린과 성분(b)로서 이소프로필 팔미테이트를 노파르 13(Norpar 13; Exxon Chemical Co. USA가 시판하는 포화 탄화수소의 상표)에 용해시켜 각각 2.6중량% 및 7.7중량%로 만들어 본 발명의 액체 살충 제제를 수득한다. 제제를 도 1에 나타낸 바와 같이 흡수 심지가 제공되어 있는 살충용 가열 훈증형 장치 속의 45ml들이 용기에 넣는다.Proletrine as component (a) and isopropyl palmitate as component (b) were dissolved in Norpar 13 (trademark of saturated hydrocarbon sold by Exxon Chemical Co. USA) and 2.6 wt% and 7.7 wt%, respectively. To obtain a liquid pesticidal formulation of the present invention. The formulation is placed in a 45 ml container in a pesticidal heating fumigation apparatus provided with an absorbent wick as shown in FIG. 1.
도 1에서, 도면부호 1은 액체 살충 제제이고, 2는 순환 가열기이며, 3은 다공성 흡수 심지이고, 4는 제제(1)를 담는 용기이며, 다공성 흡수 심지(3)의 하부는 제제(1)에 침지시켜 심지(3)에 제제(1)를 흡수시키고, 심지(3)의 상부는 순환 가열기(2)로 가열한다.In FIG. 1, reference numeral 1 denotes a liquid insecticide formulation, 2 a circulating heater, 3 a porous absorption wick, 4 a container containing the formulation 1, and a lower portion of the porous absorption wick 3 is the formulation 1. It is immersed in the wick (3) to absorb the formulation (1), the upper part of the wick (3) is heated by the circulation heater (2).
실시예 2Example 2
성분(a)로서의 프랄레트린과 성분(b)로서의 디부틸 프탈레이트를 노파르 13(Exxon Chemical Co. USA가 시판하는 포화 탄화수소의 상표)에 용해시켜 각각 2.6중량% 및 7.7중량%로 만들어 본 발명의 액체 살충 제제를 수득한다. 제제를 도 1에 나타낸 바와 같은 흡수 심지가 제공되어 있는 살충용 가열 훈증형 장치 속의 45ml들이 용기에 넣는다.Praphthalin as component (a) and dibutyl phthalate as component (b) were dissolved in Nopar 13 (trademark of saturated hydrocarbons marketed by Exxon Chemical Co. USA) to give 2.6% by weight and 7.7% by weight, respectively. Obtain a liquid pesticidal formulation of. The formulation is placed in a 45 ml container in a pesticidal heating fumigation apparatus provided with an absorbent wick as shown in FIG. 1.
실시예 3Example 3
알레트린과 이소프로필 팔미테이트를 위에서 언급한 네오티오졸에 용해시켜 각각 3.5중량% 및 5.0중량%로 만들어 본 발명의 액체 살충 제제를 수득한다.Alletrin and isopropyl palmitate are dissolved in the neothioazoles mentioned above to 3.5% and 5.0% by weight, respectively, to obtain the liquid pesticidal formulation of the present invention.
실시예 4Example 4
트란스플루트린과 이소프로필 스테아레이트를 위에서 언급한 노파르 15에 용해시켜 각각 4.0중량% 및 1.0중량%로 만들어 본 발명의 액체 살충 제제를 수득한다.Transflutrin and isopropyl stearate are dissolved in Nopar 15 mentioned above to 4.0% and 1.0% by weight, respectively, to obtain a liquid pesticidal formulation of the present invention.
실시예 5Example 5
도 2a에 나타낸 장치를 사용한다.The apparatus shown in FIG. 2A is used.
직경이 4cm이고 높이가 12cm인 2개의 유리 파이프(11) 속에 모기 암컷 성충(Culex pipiens pallens) 10마리를 각각 넣는다. 그런 다음, 유리 파이프(11)의 양단 각각을 나일론 망으로 막는다. 유리 파이프는 폭이 약 5cm이고 유리 파이프(11)를 세팅하기 위한 개별적인 테이퍼화된 구멍(16)을 갖는 금속성 판(17)에 합체된 금속성 링(13)이 바닥에 제공되어 있는, 직경이 20cm이고 높이가 30cm인 원통형 플라스틱 커버(12) 속에 넣고 유리 파이프(11)를 개별 테이퍼화된 구멍(16)에 각각 세팅한다. 직경이 20cm이고 높이가 80cm인 금속성 실린더(14)를 원통형 커버(12)의 바닥 끝에 설치한다. 미리 가열시킨, 실시예 1 또는 2에서 수득한 살충용 가열 훈증형 장치(15)를 금속성 실린더(14)의 바닥에 제공한다. 흡수 심지의 상부를 120 내지 135℃로 간접 가열한다. 떨어진 모기 암컷 성충의 수를 시험 시작 후 5시간, 105시간, 205시간, 305시간 및 405시간과 같은 상이한 시간 간격으로 계수하여 KT50 값(모기 암컷 성충의 50%를 살충하는데 소요된 시간: 분)을 프로빗(Probit) 분석으로 계산한다.Ten female mosquitoes (Culex pipiens pallens) are placed in two glass pipes 11, 4 cm in diameter and 12 cm in height. Then, each end of the glass pipe 11 is closed with a nylon net. The glass pipe is about 5 cm in width and 20 cm in diameter, provided with a metallic ring 13 at the bottom, which is incorporated into the metallic plate 17 having individual tapered holes 16 for setting the glass pipe 11. Into a cylindrical plastic cover 12, 30 cm high, and the glass pipes 11 are set in individual tapered holes 16, respectively. A metallic cylinder 14, 20 cm in diameter and 80 cm in height, is installed at the bottom end of the cylindrical cover 12. The insecticidal heating fumigation apparatus 15 obtained in Example 1 or 2, which was preheated, is provided at the bottom of the metallic cylinder 14. The upper part of the absorbent wick is indirectly heated to 120 to 135 ° C. The number of fallen mosquito female adults was counted at different time intervals, such as 5 hours, 105 hours, 205 hours, 305 hours, and 405 hours after the start of the test, resulting in KT 50 values (time spent killing 50% of mosquito female adults: minutes ) Is calculated by Probit analysis.
실시예 1에서 성분(b)로서 사용된 이소프로필 팔미테이트 대신에 디헵틸 프탈레이트를 사용하여 비교 시험을 또한 실시한다. 결과는 다음 표에서와 같다.A comparative test is also conducted using diheptyl phthalate in place of the isopropyl palmitate used as component (b) in Example 1. The results are shown in the following table.
위의 표에서 명백한 바와 같이, 디부틸 프탈레이트와 이소프로필 팔미테이트대신에 디헵틸 프탈레이트가 성분(b)로서 사용되는 경우 낮은 살충 효과가 관찰되었다.As evident from the table above, a low pesticidal effect was observed when diheptyl phthalate was used as component (b) instead of dibutyl phthalate and isopropyl palmitate.
이러한 성분(b)를 전혀 사용하지 않는 경우에 대해 유사한 시험을 실시하였을 때, 시험 시작후 약 300시간째에 흡수 심지의 응고로 인해 유효 성분(a)의 휘발이 저하되어 살충 효과가 장시간 유지될 수 없었다.When a similar test was performed on the case where no component (b) was used at all, about 300 hours after the start of the test, the volatilization of the active ingredient (a) was lowered due to the solidification of the absorbent wick, so that the insecticidal effect was maintained for a long time. Could not.
본 발명의 액체 살충 제제의 가열 훈증에 의한 본 발명의 살충 방법은 안정한 살충 효과를 유지하면서 장시간 동안 제제를 안정하게 훈증시킬 수 있다.The pesticidal method of the present invention by heat fumigation of the liquid pesticidal formulation of the present invention can stably fumigation the formulation for a long time while maintaining a stable insecticidal effect.
도 1은 가열 훈증에 의한 본 발명의 살충 방법에 적용할 수 있는 장치의 예이다.1 is an example of a device that can be applied to the insecticidal method of the present invention by heating fumigation.
도 2a는 실시예 5에 사용되는 장치를 도시한 것이다.FIG. 2A shows the apparatus used in Example 5. FIG.
도 2b는 도 2a의 금속성 링의 상부 단면도이다.FIG. 2B is a top sectional view of the metallic ring of FIG. 2A.
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| JP95-236874 | 1995-09-14 | ||
| JP95-236873 | 1995-09-14 | ||
| JP7236873A JPH0977606A (en) | 1995-09-14 | 1995-09-14 | Heat transpiration insecticide method |
| JP23687495A JP3783251B2 (en) | 1995-09-14 | 1995-09-14 | Heat transpiration insecticide method |
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| KR970014564A KR970014564A (en) | 1997-04-28 |
| KR100523676B1 true KR100523676B1 (en) | 2005-12-26 |
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| GB0525981D0 (en) * | 2005-12-21 | 2006-02-01 | Reckitt Benckiser Au Pty Ltd | An emanating device |
| US7455245B2 (en) | 2006-07-14 | 2008-11-25 | S.C. Johnson & Son, Inc. | Diffusion device |
| US20080027143A1 (en) * | 2006-07-14 | 2008-01-31 | Munagavalasa Murthy S | Chemical formulation for an insecticide |
| JP5326320B2 (en) * | 2007-03-30 | 2013-10-30 | 住友化学株式会社 | Pest control composition and pest control method |
| ES2348893B1 (en) * | 2008-09-12 | 2011-10-05 | Sumitomo Chemical Company, Limited | STRUCTURAL BODY, METHOD TO PRODUCE IT, VAPOR DOSAGE DEVICE, STEAM DOSAGE METHOD AND KIT FOR DOSAGE VAPOR. |
| GB201205562D0 (en) * | 2012-03-29 | 2012-05-09 | Reckitt & Colman Overseas | Liquid insecticidal compositions |
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| JPS5428818A (en) * | 1977-08-05 | 1979-03-03 | Fumakilla Ltd | Method of enhancing effect of pesticide smoked in short time |
| JPS59104303A (en) * | 1982-12-03 | 1984-06-16 | Sumitomo Chem Co Ltd | High dose electric mat |
| EG18025A (en) * | 1986-07-18 | 1993-06-30 | Sumitomo Chemical Co | A method for killing insects by heating fumigation |
| JPS63152305A (en) * | 1986-08-15 | 1988-06-24 | Fumakiraa Kk | Insecticidal composition for heat transpiration |
| DE3737272C2 (en) * | 1986-11-19 | 1989-10-26 | Fumakilla Ltd | HEATING GASKET OPERATING |
| EG20223A (en) * | 1992-07-17 | 1997-11-30 | Sumitomo Chemical Co | Insecticidal composition of 2,3,5,6 tetrafluorbenzyl (+) -1R,trans -2,2- dimethyl -3- (2,2- dichlorovinyl) cyclopropanecarboxylate |
| AU5157293A (en) * | 1992-10-19 | 1994-05-09 | Earth Chemical Co. Ltd. | Regulation agent for vaporability of heat-vaporized medicine for liquid absorbing core, and method of regulating vaporability of heat-vaporized medicine |
| DE4328959A1 (en) * | 1993-08-27 | 1995-03-02 | Globol Gmbh | Mixture of volatile substances |
-
1996
- 1996-09-05 AU AU64444/96A patent/AU708907B2/en not_active Ceased
- 1996-09-06 MY MYPI96003693A patent/MY118334A/en unknown
- 1996-09-11 ES ES009601927A patent/ES2142205B1/en not_active Expired - Fee Related
- 1996-09-11 FR FR9611073A patent/FR2738718B1/en not_active Expired - Fee Related
- 1996-09-13 KR KR1019960039596A patent/KR100523676B1/en not_active Expired - Fee Related
- 1996-09-13 IT IT96RM000625A patent/IT1290148B1/en active IP Right Grant
- 1996-09-14 TW TW085111255A patent/TW383213B/en not_active IP Right Cessation
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| KR200481113Y1 (en) | 2015-11-19 | 2016-08-16 | 주식회사 세이프퓸 | Fumigation Apparatus |
| US10806135B2 (en) | 2017-02-03 | 2020-10-20 | SAFEFUME Co., Ltd | Fumigation vaporizer |
| KR101944269B1 (en) | 2018-05-28 | 2019-02-01 | 주식회사 세이프퓸 | Fumigation Apparatus |
| KR102068359B1 (en) | 2018-12-07 | 2020-01-22 | 주식회사 세이프퓸 | Fumigation Apparatus |
| KR20210042648A (en) | 2019-10-10 | 2021-04-20 | 대한민국(농촌진흥청장) | Fumigation Apparatus |
| KR102188414B1 (en) | 2020-06-22 | 2020-12-09 | 주식회사 세이프퓸 | Fumigation Apparatus |
| KR102356292B1 (en) | 2021-06-04 | 2022-02-10 | 주식회사 세이프퓸 | Fumigation Apparatus |
| KR102456664B1 (en) | 2022-04-18 | 2022-10-24 | 주식회사 세이프퓸 | Fumigation Apparatus |
| KR102526405B1 (en) | 2022-09-15 | 2023-04-27 | 경북대학교 산학협력단 | Ethyl formate fumigation apparatus using without vaporizer in greenhouse |
Also Published As
| Publication number | Publication date |
|---|---|
| MX9604050A (en) | 1997-07-31 |
| ES2142205A1 (en) | 2000-04-01 |
| AU6444496A (en) | 1997-03-20 |
| ITRM960625A1 (en) | 1998-03-13 |
| IT1290148B1 (en) | 1998-10-19 |
| AU708907B2 (en) | 1999-08-12 |
| FR2738718B1 (en) | 1998-10-16 |
| KR970014564A (en) | 1997-04-28 |
| FR2738718A1 (en) | 1997-03-21 |
| TW383213B (en) | 2000-03-01 |
| MY118334A (en) | 2004-10-30 |
| ES2142205B1 (en) | 2000-10-16 |
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