KR100513641B1 - Optical filter for plasma display panel and manufacturing method thereof - Google Patents
Optical filter for plasma display panel and manufacturing method thereof Download PDFInfo
- Publication number
- KR100513641B1 KR100513641B1 KR10-2002-0006507A KR20020006507A KR100513641B1 KR 100513641 B1 KR100513641 B1 KR 100513641B1 KR 20020006507 A KR20020006507 A KR 20020006507A KR 100513641 B1 KR100513641 B1 KR 100513641B1
- Authority
- KR
- South Korea
- Prior art keywords
- layer
- film
- optical filter
- transparent substrate
- glass substrate
- Prior art date
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J11/00—Gas-filled discharge tubes with alternating current induction of the discharge, e.g. alternating current plasma display panels [AC-PDP]; Gas-filled discharge tubes without any main electrode inside the vessel; Gas-filled discharge tubes with at least one main electrode outside the vessel
- H01J11/20—Constructional details
- H01J11/34—Vessels, containers or parts thereof, e.g. substrates
- H01J11/44—Optical arrangements or shielding arrangements, e.g. filters, black matrices, light reflecting means or electromagnetic shielding means
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/38—Devices for influencing the colour or wavelength of the light
- H01J61/40—Devices for influencing the colour or wavelength of the light by light filters; by coloured coatings in or on the envelope
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J9/00—Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
- H01J9/24—Manufacture or joining of vessels, leading-in conductors or bases
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2211/00—Plasma display panels with alternate current induction of the discharge, e.g. AC-PDPs
- H01J2211/20—Constructional details
- H01J2211/34—Vessels, containers or parts thereof, e.g. substrates
- H01J2211/44—Optical arrangements or shielding arrangements, e.g. filters or lenses
- H01J2211/442—Light reflecting means; Anti-reflection means
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Electromagnetism (AREA)
- Plasma & Fusion (AREA)
- Manufacturing & Machinery (AREA)
- Devices For Indicating Variable Information By Combining Individual Elements (AREA)
- Optical Filters (AREA)
Abstract
본 발명은 플라즈마 디스플레이 패널용 광학필터 및 그 제조방법을 제공한다. 상기 광학필터는 글래스 기판; 상기 글래스 기판의 전면에 형성되며, 투명 기판(a)과, 상기 투명 기판의 전면에 형성된 반사방지막(b), 상기 투명 기판의 후면에 형성된 근적외선 차단 및 선택적 흡광층(c), 상기 근적외선 차단 및 선택적 흡광층 상부에 형성된 점착층(d)을 포함하여 이루어지고, 상기 점착층이 글래스 기판의 전면과 직접적으로 접촉되어 있는 반사방지성 광투과필름; 상기 글래스 기판의 후면에 형성된 접착용 중간막; 상기 접착용 중간막 상부에 형성되는 전자파 차폐층; 및 상기 전자파 차폐층 상부에 형성된 반사방지막을 포함하는 것을 특징으로 한다. 본 발명의 PDP용 광학필터는 근적외선 차단 물질과 광선택 흡광 물질을 포함하는 층을 반사방지막이 형성된 투명 기판의 후면에 형성하여 이들을 일체화시킴으로써 휘도 저하와 관련된 광학필터의 총두께를 감소시켜 필터의 경량, 박형화가 가능하고 그 구조를 투과율을 향상시키면서 필터의 경량화 및 박형화가 가능해지고, 그 적층구조를 단순화함으로써 제조공정이 단순화되고 제조단가가 줄어들고 제조수율이 향상된다.The present invention provides an optical filter for a plasma display panel and a method of manufacturing the same. The optical filter is a glass substrate; A transparent substrate (a) formed on the front surface of the glass substrate, an antireflection film (b) formed on the front surface of the transparent substrate, a near infrared blocking and an optional light absorbing layer (c) formed on the rear surface of the transparent substrate, the near infrared blocking, and An anti-reflective light transmissive film including an adhesive layer (d) formed on the selective light absorbing layer, wherein the adhesive layer is in direct contact with the front surface of the glass substrate; An adhesive interlayer formed on a rear surface of the glass substrate; An electromagnetic shielding layer formed on the adhesive interlayer; And an anti-reflection film formed on the electromagnetic shielding layer. The optical filter for PDP of the present invention forms a layer including a near infrared ray blocking material and a light selective absorbing material on the back side of a transparent substrate on which an anti-reflection film is formed and integrates them, thereby reducing the total thickness of the optical filter associated with a decrease in brightness, thereby reducing the weight of the filter. In addition, it is possible to reduce the thickness and to reduce the weight and thickness of the filter while improving the structure of the structure, and to simplify the lamination structure, the manufacturing process is simplified, the manufacturing cost is reduced, and the manufacturing yield is improved.
Description
본 발명은 플라즈마 디스플레이 패널용 광학필터 및 그 제조방법에 관한 것으로서, 보다 상세하기로는 근적외선 차단 기능과 광선택 흡광 기능을 갖는 층이 반사 방지층과 일체화되어 있는 플라즈마 디스플레이 패널용 광학필터와 이의 제조방법에 관한 것이다.The present invention relates to an optical filter for a plasma display panel and a method of manufacturing the same, and more particularly, to an optical filter for a plasma display panel and a method for manufacturing the same, wherein a layer having a near infrared ray blocking function and a light selective absorbing function is integrated with an antireflection layer. It is about.
플라즈마 디스플레이 패널(Plasma Display Panel: PDP)은 다른 화상표시장치에 비하여 대형화가 용이하고, 박형의 발광형 표시장치로서 향후 고품질 디지털 텔레비전으로서 가장 적합한 특성를 갖추고 있는 것으로 평가하고 있다.Plasma Display Panel (PDP) is easy to be enlarged compared to other image display devices, and it is evaluated as a thin light emitting display device having the most suitable characteristics as a high quality digital television in the future.
그러나, PDP는 전자파 및 근적외선의 방출량이 많고 형광체의 표면반사가 높을 뿐만 아니라 봉입가스인 헬륨에서 방출되는 오렌지광으로 인하여 색순도가 음극선관에 미치지 못한다는 단점이 있다. 따라서 PDP에서 발생되는 전자파 및 근적외선에 의한 인체의 유해함과 정밀기기의 오작동을 방지할 뿐만 아니라, 표면 반사를 줄이고 색순도를 향상시키기 위하여 전자파 차폐, 근적외선 차단, 표면 반사 방지 및 색순도 개선 기능을 갖는 PDP용 광학필터를 채용하고 있다.However, PDP has a disadvantage in that the emission amount of electromagnetic waves and near infrared rays is high, the surface reflection of the phosphor is high, and the color purity does not reach the cathode ray tube due to the orange light emitted from the encapsulated gas helium. Therefore, not only to prevent harmful effects of human body and malfunction of precision instruments caused by electromagnetic waves and near-infrared rays, but also to reduce surface reflection and improve color purity, PDP with electromagnetic shielding, near-infrared blocking, surface reflection prevention and color purity improvement Optical filter is adopted.
PDP는 전자파 차폐성능에 따라 업무용과 민생용으로 구분할 수 있고, PDP용 광학필터는 그 용도에 따라 그 구성이 상이하다.PDP can be classified into business use and public use according to the electromagnetic shielding performance, and the optical filter for PDP has a different configuration depending on its use.
즉, 업무용 PDP의 광학필터는 기재의 이면에 은과 같은 금속과 고굴절율의 산화물을 교대로 적층하여 전자파 및 근적외선 차단층을 형성한다. 이어서 상기 결과물의 양면에 반사방지막을 형성함으로써 완성한다.That is, the optical filter of the commercial PDP alternately stacks a metal such as silver and an oxide of high refractive index on the back surface of the substrate to form an electromagnetic wave and a near infrared blocking layer. Subsequently, it is completed by forming antireflection films on both surfaces of the resultant product.
한편, 민생용 PDP의 광학필터는 도전성 메쉬를 2매의 투명 기판사이에 삽입하고 그 표면에 반사방지 필름을 접합시키고, 그 결과물의 이면에 근적외선 차단 필름을 접합한 다음, 그 상부에 반사방지 필름을 적층하여 형성하거나(일본 특개평 11-74683), 1매의 투명 기판의 표면에 도전성 메쉬와 반사방지 필름을 순서대로 접합하고 그 이면에 근적외선 차단 필름을 적층시키는 방법이 제안되었다(일본 특개평 13-134198).On the other hand, the optical filter of the consumer PDP inserts a conductive mesh between two transparent substrates, bonds an anti-reflection film to the surface thereof, and bonds a near-infrared blocking film to the back side of the resultant, and then an anti-reflection film on the top thereof. (Japanese Patent Laid-Open No. 11-74683), or a method of laminating a conductive mesh and an antireflection film on the surface of a single transparent substrate in order and laminating a near infrared ray blocking film on the back side thereof has been proposed. 13-134198).
그런데, 상술한 방법들중, 2매의 투명기판을 이용하는 광학필터는 그 자체의 두께 및 중량으로 인하여 박형화 및 경량화가 어렵다는 문제점이 있다. 그리고 1매의 투명기판의 표면에 근적외선 차단 필름을 접합시키는 방법은 기재를 1매만 사용하므로 경량화는 가능하지만 근적외선 차단 필름을 별도로 접합해야 하므로 접합 공정 자체가 복잡하고 수율 저하의 원인이 되며 특히 근적외선 차단 필름의 기재로 사용되는 열가소성 수지로 인하여 광학필터의 두께가 증가하고 최종 필터의 투과율이 저하된다는 단점이 있다.However, among the above-described methods, the optical filter using two transparent substrates has a problem that it is difficult to thin and light due to its thickness and weight. In addition, the method of bonding the near-infrared blocking film to the surface of a single transparent substrate uses only one substrate, which makes it possible to reduce the weight. However, since the near-infrared blocking film must be bonded separately, the bonding process itself is complicated and the yield decreases. The thermoplastic resin used as the substrate of the film has the disadvantage that the thickness of the optical filter is increased and the transmittance of the final filter is decreased.
이에 본 발명이 이루고자 하는 기술적 과제는 상기 문제점을 해결하여 제조공정이 단순화되고 경량화가 가능하면서 광투과율 및 휘도 특성이 개선된 PDP용 광학필터 및 그 제조방법을 제공하는 것이다.Accordingly, the technical problem to be achieved by the present invention is to solve the above problems, to provide a PDP optical filter and a method of manufacturing the same, which can simplify the manufacturing process, reduce weight, and improve light transmittance and luminance characteristics.
상기 기술적 과제를 이루기 위하여 본 발명에서는,In the present invention to achieve the above technical problem,
글래스 기판;Glass substrates;
상기 글래스 기판의 전면에 형성되며, Is formed on the front of the glass substrate,
투명 기판(a)과, A transparent substrate (a),
상기 투명 기판의 전면에 형성된 반사방지막(b), An anti-reflection film (b) formed on the entire surface of the transparent substrate,
상기 투명 기판의 후면에 형성된 근적외선 차단 및 선택적 흡광층(c), Near-infrared blocking and selective light absorbing layer (c) formed on the rear surface of the transparent substrate,
상기 근적외선 차단 및 선택적 흡광층 상부에 형성된 점착층(d)을 포함하여 이루어지고, 상기 점착층이 글래스 기판의 전면과 직접적으로 접촉되어 있는 반사방지성 광투과필름;An anti-reflective light transmissive film including an adhesive layer (d) formed on the near-infrared blocking and selective light absorbing layer, wherein the adhesive layer is in direct contact with the front surface of the glass substrate;
상기 글래스 기판의 후면에 형성된 접착용 중간막;An adhesive interlayer formed on a rear surface of the glass substrate;
상기 접착용 중간막 상부에 형성되는 전자파 차폐층; 및An electromagnetic shielding layer formed on the adhesive interlayer; And
상기 전자파 차폐층 상부에 형성된 반사방지막을 포함하는 것을 특징으로 하는 플라즈마 디스플레이 패널용 광학필터를 제공한다.It provides an optical filter for a plasma display panel comprising an anti-reflection film formed on the electromagnetic shielding layer.
상기 반사방지성 광투과필름의 근적외선 차단 및 선택적 흡광층이, 반사막이 형성된 투명 기판의 후면에 형성되어 일체화되어 있다.The near-infrared blocking and selective light absorbing layer of the antireflective light transmissive film is formed on the rear surface of the transparent substrate on which the reflective film is formed and integrated.
상기 접착용 중간막은 에틸렌-비닐 아세테이트 공중합체, 폴리비닐부티랄 또는 그 혼합물로 이루어지며, 상기 전자파 차폐층은 금속 섬유 또는 금속 피복 유기 섬유로 이루어진 도전성 메쉬이거나, 금속 섬유 또는 금속 피복 유기 섬유으로 이루어진 동박을 패턴화시켜 얻은 도전성 메쉬인 것이 바람직하다.The adhesive interlayer is made of ethylene-vinyl acetate copolymer, polyvinyl butyral or a mixture thereof, and the electromagnetic shielding layer is a conductive mesh made of metal fibers or metal coated organic fibers, or made of metal fibers or metal coated organic fibers. It is preferable that it is a conductive mesh obtained by patterning copper foil.
상기 반사방지성 광투과필름에서의 근적외선 차단 및 선택 적 흡광층이 근적외선 차단 물질과 광선택 흡광 물질을 포함하며, 근적외선 차단 물질은 니켈 착체계와 디암모늄계의 혼합색소, 구리 이온과 아연 이온을 함유하는 화합물 색소, 시아닌 색소 및 안트라퀴논 색소로 이루어진 군으로부터 선택된 하나 이상이고, 상기 선택적 흡광 물질은 옥타페닐테트라아자포피린, 테트라아자포피린 고리에 금속(M) 원자가 중심 그룹으로 존재하고, 암모니아, 물, 할로겐으로 이루어진 군으로부터 선택된 하나의 리간드가 상기 금속 원자와 배위결합을 이룬 유도체 색소로 이루어진 군으로부터 선택된 하나 이상을 사용하는 것이 바람직하다. The near-infrared blocking and selective absorbing layer in the anti-reflective light transmitting film includes a near-infrared blocking material and a light-selective absorbing material, and the near-infrared blocking material includes a mixed complex of nickel complex and diammonium, copper ions and zinc ions. At least one selected from the group consisting of compound dyes, cyanine dyes and anthraquinone dyes, wherein the selective light absorbing material is a metal (M) atom in the octaphenyltetraazapopyrin, tetraazapophyrin ring as a central group, ammonia, water It is preferable to use at least one ligand selected from the group consisting of derivative dyes in which one ligand selected from the group consisting of halogen coordinates with the metal atom.
본 발명의 다른 기술적 과제는, Another technical problem of the present invention,
(A) 투명 기판의 전면에 반사방지막을 형성하는 단계;(A) forming an anti-reflection film on the entire surface of the transparent substrate;
(B) 투명 기판의 후면에 근적외선 차단 및 선택적 흡광층을 형성하는 단계;(B) forming a near infrared ray blocking and selective light absorbing layer on the back side of the transparent substrate;
(C) 상기 근적외선 차단 및 선택적 흡광층 상부에 점착층을 형성하는 단계;(C) forming a pressure-sensitive adhesive layer on top of the near-infrared blocking and selective light absorbing layer;
(D) 상기 점착층 상부에 이형층을 형성하여 반사방지성 광투과필름을 형성하는 단계;(D) forming a release layer on the adhesive layer to form an antireflective light transmitting film;
(E) 글래스 기판의 후면에 접착용 중간막과 전자파 차폐층과 반사방지막을 순차적으로 형성하는 단계;(E) sequentially forming an adhesive interlayer, an electromagnetic shielding layer and an antireflection film on the rear surface of the glass substrate;
(F) 상기 (D) 단계로부터 형성된 반사방지성 광투과필름의 이형층을 제거하고, 이의 점착층을 상기 (E) 단계로부터 얻어진 글래스 기판의 전면에 적층하는 단계를 포함하는 것을 특징으로 하는 상술한 플라즈마 디스플레이 패널용 광학필터의 제조방법에 의하여 이루어진다. (F) removing the release layer of the antireflective light transmitting film formed from the step (D), and laminating the adhesive layer thereof on the entire surface of the glass substrate obtained from the step (E). It is made by a method of manufacturing an optical filter for a plasma display panel.
PDP용 광학필터는 리모콘의 오작동을 방지하기 위하여 근적외선 차단 성능이 중요한 요구 특성으로 되어 있다. 특히 최근에는 PDP의 휘도를 향상시킴에 따라 근적외선의 발생량도 많아지고 있기 때문에 더 한층 고도의 근적외선 차단 성능이 필요하다. The optical filter for PDP has an important characteristic of near infrared cut-off to prevent malfunction of the remote control. In particular, as the brightness of the PDP is improved, the generation of near-infrared rays also increases, so a higher level of near-infrared cutoff is required.
PDP용 전면필터의 투명기판으로서 아크릴 수지판을 사용하는 경우, 기판 재료의 아크릴 수지중에 구리 계열 재료를 배합시키는 것으로 근적외선 차단 성능을 부여할 수는 있지만, 아크릴 수지는 열에 약하고 열변형의 위험성이 있기 때문에 PDP용 전면 광학필터의 투명기판으로서 바람직하지 못하다. 이 때문에 본 발명에서는 투명기판으로는 내열성이 우수한 글래스 기판을 사용하여 양호한 근적외선 차단 성능을 갖는 PDP용 광학필터를 제조한다.In the case of using an acrylic resin plate as a transparent substrate of a front filter for a PDP, although a near-infrared ray blocking performance can be imparted by incorporating a copper-based material into the acrylic resin of the substrate material, the acrylic resin is weak to heat and has a risk of thermal deformation. Therefore, it is not preferable as a transparent substrate of the front optical filter for PDP. For this reason, in this invention, the glass substrate which is excellent in heat resistance is used as a transparent substrate, and the optical filter for PDP which has favorable near-infrared cut off performance is manufactured.
이하, 본 발명을 보다 상세하게 설명하기로 한다.Hereinafter, the present invention will be described in more detail.
본 발명의 플라즈마 디스플레이 패널용 광학필터는, 근적외선 차단 기능과 선택적 흡광 기능에 의한 색순도 향상 기능을 갖는 층을 반사방지막이 형성된 투명 기판의 후면에 형성하여 반사방지막과 근적외선 차단층이 일체화된 반사방지성 광투과 필름을 형성하고, 이를 글래스 기판의 전면에 배치한 것이다. 본 발명의 광학필터를 첨부된 도면을 참조하여 그 적층구조를 보다 상세하게 설명하면 다음과 같다.In the optical filter for plasma display panel of the present invention, a layer having a near infrared ray blocking function and a color purity improving function by a selective light absorption function is formed on the rear surface of the transparent substrate on which the antireflective film is formed, thereby the antireflective film and the near infrared ray blocking layer are integrated. A light transmissive film is formed, which is disposed on the front surface of the glass substrate. Referring to the attached optical filter of the present invention with reference to the accompanying drawings in more detail as follows.
본 발명의 반사방지성 광투과필름(10)은 도 1과 같은 구조를 갖는다. The antireflective light transmissive film 10 of the present invention has a structure as shown in FIG. 1.
도 1을 참조하면, 반사방지성 광투과필름(10)은 투명 기판(12)의 전면에 반사방지막(11)을 형성하고, 상기 투명기판(12)의 후면에 근적외선 차단 및 선택적 흡광층(13)과 점착층(14)과 이형층(15)이 순차적으로 적층되어 있다. Referring to FIG. 1, the antireflective light transmissive film 10 forms an antireflection film 11 on the front surface of the transparent substrate 12, and blocks the near infrared rays and the selective light absorbing layer 13 on the rear surface of the transparent substrate 12. ), The adhesive layer 14 and the release layer 15 are sequentially stacked.
상기 반사방지성 광투과필름(10)에 있어서, 투명기판(12)은 폴리에틸렌테레프탈레이트, 폴리카보네이트, 폴리메틸메타크릴레이트, 트리아세테이트셀룰로오스(TAC), 폴리에테르설폰(PES)으로 이루어진 열가소성 수지로 이루어지며, 이 투명기판의 광투과율은 80% 이상, 보다 바람직하게는 90% 이상인 것이 바람직하다. 그리고 이 투명기판의 두께는 25 내지 150㎛인 것이 반사방지성 광투과 필름의 투명도 측면에서 바람직하다.In the anti-reflective light transmitting film 10, the transparent substrate 12 is a thermoplastic resin consisting of polyethylene terephthalate, polycarbonate, polymethyl methacrylate, triacetate cellulose (TAC), polyether sulfone (PES) The light transmittance of the transparent substrate is preferably 80% or more, more preferably 90% or more. In addition, the thickness of the transparent substrate is preferably 25 to 150 µm in view of the transparency of the antireflective light transmitting film.
상기 투명기판(12)의 전면에 내스크래치성을 위하여 아크릴 수지로 된 하드코팅막을 선택적으로 형성하기도 한다.A hard coating film made of acrylic resin may be selectively formed on the entire surface of the transparent substrate 12 for scratch resistance.
상기 반사방지막(11)으로는 투명기판(12)의 굴절율보다 작은 저굴절율 단층막 또는 고굴절율 투명막과 저굴절율 투명막을 교대로 적층한 다층막이 사용된다. 여기에서 저굴절율 투명막은 SiO2, MgF2, Al2O3 등과 같이 굴절율이 1.6 이하의 실리콘계 유기재료, 불소계 유기재료 등의 저굴절율 재료를 이용하며, 고굴절율 투명막은 ITO(Indium Tin Oxide), ZnO, Al을 도핑한 ZnO, TiO2, ZrO 등의 굴절율 1.6 이상의 고굴절율 재료를 이용하며, 이러한 고굴절율 재료를 아크릴수지, 폴리에스테르 등과 같은 바인더에 분산시킨 것을 사용한다. 이러한 반사방지막은, 상기 저굴절율 재료 또는 고굴절율 재료를 진공성막하는 방법 또는 상기 재료들이 포함된 용액을 습식방법으로 롤 코팅, 다이코팅하여 제조된다.As the anti-reflection film 11, a low refractive index single layer film smaller than the refractive index of the transparent substrate 12 or a multilayer film in which a high refractive index transparent film and a low refractive index transparent film are alternately laminated is used. Here, the low refractive index transparent film is made of low refractive index materials such as silicon-based organic materials and fluorine-based organic materials having a refractive index of 1.6 or less, such as SiO 2 , MgF 2 , Al 2 O 3, and the like, and the high refractive index transparent film is made of indium tin oxide (ITO), ZnO, Al doped ZnO, TiO 2 , ZrO and other high refractive index material of 1.6 or more is used, and the high refractive index material is dispersed in a binder such as acrylic resin, polyester and the like. Such an antireflection film is manufactured by vacuum coating the low refractive index material or the high refractive index material or by roll coating and die coating a solution containing the materials by a wet method.
상기 반사방지막(11)의 광학적 두께(nd)는 고굴절율막과 저굴절율막은 각각 약 λ/4(여기서 λ는 파장)가 되도록 형성한다.The optical thickness nd of the antireflection film 11 is formed such that the high refractive index film and the low refractive index film are about λ / 4 (where λ is the wavelength).
상기 근적외선 차단 및 선택적 흡광층(13)은 근적외선 차단 물질과 광선택 흡광 물질을 함유하고 있다. 이 때 선택적 흡광 색소는 전체 고형분 100 중량부를 기준으로 하여 0.01 내지 0.5 중량부의 양으로 사용하면 적당하고 근적외선 차폐 색소는 전체 고형분 100 중량부를 기준으로 하여 0.3 내지 5중량부의 양으로 사용하는 것이 바람직하다. 만약 선택적 흡광 물질의 함량이 0.01 중량부 미만이면 선택적 흡광 기능이 저하되어 색순도 향상 효과를 기대할 수 없고 0.5 중량부를 초과하면 필터의 칼라 밸런스(color balance)가 왜곡되고 투과율이 저하하여 바람직하지 못하다.The near-infrared blocking and selective light absorbing layer 13 contains a near-infrared blocking material and a photo-selective light absorbing material. At this time, the selective light absorbing dye is suitable to use in an amount of 0.01 to 0.5 parts by weight based on 100 parts by weight of total solids, and the near-infrared shielding dye is preferably used in an amount of 0.3 to 5 parts by weight based on 100 parts by weight of total solids. If the content of the selective light absorbing material is less than 0.01 parts by weight, the selective light absorbing function is lowered, and color purity improvement effects cannot be expected. If the content of the light absorbing material is more than 0.5 parts by weight, the color balance of the filter is distorted and the transmittance is lowered.
본 발명의 근적외선 차단 및 선택적 흡광층(13)을 구성하는 근적외선 차단 물질은 투명성을 손상시키는 일이 없고 양호한 근적외선 차단 성능(예를 들어, 850-1250nm 근적외선 파장 영역에 있어 근적외선을 흡수하는 성능)을 갖는 물질로서, 국내 공개특허공보 2001-39727에 개시된 화학식 4 내지 6의 화합물을 사용할 수 있는데, 구체적인 예를 들어 니켈 착체계와 디암모늄계의 혼합색소(예: 상품명 IRG022(일본화약사))나 구리, 아연 이온을 함유하는 화합물 색소 또는 유기물 색소를 사용한다. The near-infrared blocking material constituting the near-infrared blocking and selective light absorbing layer 13 of the present invention does not impair transparency and has good near-infrared blocking performance (for example, the ability to absorb near infrared rays in the 850-1250nm near-infrared wavelength region). As the material having a compound of Formulas 4 to 6 disclosed in Korean Laid-Open Patent Publication No. 2001-39727, for example, a mixed pigment of nickel complex and diammonium (eg, trade name IRG022 (Japanese Chemical Company)) or Compound dyes or organic dyes containing copper and zinc ions are used.
상기 선택적 흡광 물질에 대해서는 국내 공개특허공보 20001-26838 및 2001-39727이 참조로서 통합된다. 여기에 개시된 선택적 흡광 물질은 옥타페닐테트라아자포피린, 또는 테트라아자포피린 고리에 금속(M) 원자가 중심 그룹으로 존재하고, 암모니아, 물, 할로겐으로 이루어진 군으로부터 선택된 하나의 리간드가 상기 금속 원자와 배위결합을 이룬 유도체들로서, 상기 금속은 아연(Zn), 팔라듐(Pd), 마그네슘(Mg), 망간(Mn), 코발트(Co), 구리(Cu), 루테늄(Ru), 로듐(Rh), 철(Fe), 니켈(Ni), 바나듐(V), 주석(Sn), 티타늄(Ti)으로 이루어진 군으로부터 선택된 하나 이상이다.For the selective light absorbing material, Korean Patent Laid-Open Publications 20001-26838 and 2001-39727 are incorporated by reference. The selective light absorbing material disclosed herein is a metal (M) valence center group in an octaphenyltetraazapophyrin or tetraazapophyrin ring, and a ligand selected from the group consisting of ammonia, water, and halogen is coordinated with the metal atom. As the derivatives, the metal is zinc (Zn), palladium (Pd), magnesium (Mg), manganese (Mn), cobalt (Co), copper (Cu), ruthenium (Ru), rhodium (Rh), iron ( Fe), nickel (Ni), vanadium (V), tin (Sn), titanium (Ti) is one or more selected from the group consisting of.
상기 근적외선 차단 및 선택적 흡광층(13)을 형성하는 방법에 대하여 살펴보면, 상술한 근적외선 차단 물질과 선택적 흡광 물질을 플라스틱 수지 및 유기용매와 혼합하고, 이를 반사방지막(11)이 형성된 투명 기판(12)의 후면에 도포함으로써 반사방지막과, 근적외선 차단 및 선택적 흡광층을 일체화시킨다. 여기에서 도포방법은 통상적인 도포방식이 적용될 수 있으며, 예를 들어 롤 코팅, 다이 코팅, 스핀 코팅이 사용된다. Referring to the method of forming the near infrared ray blocking and selective light absorbing layer 13, the above-described near infrared ray blocking material and the selective light absorbing material are mixed with a plastic resin and an organic solvent, and the antireflection film 11 is formed on the transparent substrate 12. The antireflection film, the near-infrared cut off and the selective light absorbing layer are integrated by coating on the back surface of the film. The coating method may be a conventional coating method, for example, roll coating, die coating, spin coating is used.
상기 근적외선 차단 및 선택적 흡광층(13)의 두께는 1 내지 20㎛인 것이 바람직하며, 특히 2 내지 10㎛인 것이 근적외선 차단 성능면에서 보다 바람직하다.It is preferable that the thickness of the near-infrared cut-off and selective light-absorbing layer 13 is 1 to 20 탆, and more preferably 2 to 10 탆 in terms of near-infrared cut-off performance.
상기 플라스틱 수지로는 폴리(메틸 메타크릴레이트), 폴리비닐알콜, 폴리카보네이트, 에틸렌비닐아세테이트, 폴리(비닐부티랄), 폴리에틸렌테레프탈레이트 등을 사용하며, 이의 함량은 유기용매 100 중량부를 기준으로 하여 5 내지 40 중량부를 사용한다. 만약 플라스틱 수지의 함량이 5 중량부 미만인 경우에는 요구 물성 구현을 위한 두께 확보가 곤란하고, 40 중량부를 초과하는 경우에는 코팅 특성이 저하되므로 바람직하지 못하다.As the plastic resin, poly (methyl methacrylate), polyvinyl alcohol, polycarbonate, ethylene vinyl acetate, poly (vinyl butyral), polyethylene terephthalate, etc. are used, and the content thereof is based on 100 parts by weight of an organic solvent. 5 to 40 parts by weight is used. If the content of the plastic resin is less than 5 parts by weight, it is difficult to secure the thickness for implementing the required physical properties, and if it exceeds 40 parts by weight, it is not preferable because the coating properties are lowered.
상기 유기용매로는 톨루엔, 자일렌, 프로필알콜, 이소프로필알콜, 메틸셀루솔브, 에틸셀루솔브, 디메틸포름아미드, 메틸에틸케톤 등을 사용한다.Toluene, xylene, propyl alcohol, isopropyl alcohol, methyl cell solution, ethyl cell solution, dimethyl formamide, methyl ethyl ketone and the like are used as the organic solvent.
본 발명의 근적외선 차단 및 선택적 흡광층(13)에는 각 파장 영역의 투과율을 조절하거나 백색도를 구현하기 위하여 통상의 아조 염료, 시아닌 염료, 디페닐메탄 염료, 트리페닐메탄 염료, 프탈로시아닌 염료, 크산텐계 염료, 디페닐렌계 염료, 인디고, 포피린 등의 염료 또는 색소의 퇴색성을 방지하여 내광성을 향상시키기 위한 라디칼 반응 억제제와 같은 첨가제를 첨가할 수도 있다. 이러한 첨가제의 함량은 근적외선 차단 및 선택적 흡광층(13)을 구성하는 고형분 100 중량부를 기준으로 하여 0.05 내지 3 중량부이다. 만약 첨가제의 함량이 0.05 중량부 미만이면 부가에 따른 효과가 미미하고, 3 중량부를 초과하면 근적외선 차단 및 선택적 흡광층(13)의 물성이 저하되어 바람직하지 못하다.In the near-infrared blocking and selective light absorbing layer 13 of the present invention, azo dyes, cyanine dyes, diphenylmethane dyes, triphenylmethane dyes, phthalocyanine dyes, and xanthene dyes are used to control the transmittance of each wavelength region or to realize whiteness. And additives such as radical reaction inhibitors for preventing fading of dyes or pigments such as diphenylene dyes, indigo and porphyrins and improving light resistance. The content of such additives is 0.05 to 3 parts by weight based on 100 parts by weight of solids constituting the near infrared ray blocking and selective light absorbing layer 13. If the content of the additive is less than 0.05 parts by weight, the effect of the addition is insignificant, and if it exceeds 3 parts by weight, the near-infrared cut off and the physical properties of the selective light-absorbing layer 13 is not preferable.
상기 근적외선 차단 및 선택적 흡광층(13) 상부에 형성된 점착층(14)은 투명성(가시광 투과율 80% 이상), 내환경성, 내열성, 습윤성, 응집성, 점착성이 우수한 중합체 점착제로 이루어지며, 예를 들어 아크릴계 수지 점착제, 폴리에스테르계 수지 점착제, 고무계 점착제 등을 사용하며, 그중에서도 특히 투명성면에서 아크릴계 수지 점착제를 사용하는 것이 보다 바람직하다. The adhesive layer 14 formed on the near-infrared blocking and selective light absorbing layer 13 is made of a polymer adhesive having excellent transparency (visible light transmittance of 80% or more), environmental resistance, heat resistance, wettability, cohesiveness, and adhesiveness. A resin adhesive, a polyester resin adhesive, a rubber adhesive, etc. are used, Especially, it is more preferable to use an acrylic resin adhesive from a transparency viewpoint.
본 발명의 점착층(14)의 두께는 10 내지 50㎛인 것이 바람직하며, 경우에 따라서는 자외선, 흡수제, 적외선 흡수제, 노화 방지제, 도료 가공 조제, 필터 자체의 색조를 조정하기 위한 염료, 안료 등의 착색제, 카본블랙, 소수성 실리카, 탄산칼슘 등과 같은 충전제 등의 각종 첨가제를 더 포함하기도 한다.It is preferable that the thickness of the adhesion layer 14 of this invention is 10-50 micrometers, In some cases, a ultraviolet-ray, an absorber, an infrared absorber, anti-aging agent, a paint processing aid, dye for adjusting the color tone of the filter itself, a pigment, etc. Various additives, such as a coloring agent, a filler, such as carbon black, hydrophobic silica, calcium carbonate, etc. may also be included.
상기 점착층(14)의 형성시, 통상의 도포방법이 사용할 수 있다. 예를 들어, 콤마 코팅, 롤 코팅, 다이 코팅 등을 사용할 수 있고 그중에서도 후도 코팅의 용이성 측면에서 콤마 코팅이 보다 유리한 도포방법이라고 할 수 있다.In forming the adhesive layer 14, a conventional coating method can be used. For example, comma coating, roll coating, die coating, or the like can be used, and among them, comma coating is more advantageous in terms of ease of after coating.
한편, 상기 점착층(14)위에는 이 층을 보호하고 취급성을 용이하기 위하여 이형층(15)을 형성한다. On the other hand, a release layer 15 is formed on the adhesive layer 14 to protect the layer and to facilitate handling.
상기 이형층(15)은 폴리에틸렌테레프탈레이트, 폴리에틸렌 필름과 같은 기재 상부에 실리콘계 이형제가 얇게 도포된 필름으로서, 이와 같은 이형층(15)은 점착제를 도포하고 이를 건조하는 과정과 동시에 라미네이션되어 형성된다. 이러한 이형층(15)은 일체화된 반사방지성 광투과 필름(10)을 글래스 기판(12)의 전면에 접합시킬 때 박리된다.The release layer 15 is a film in which a silicone-based release agent is thinly coated on a substrate such as polyethylene terephthalate or polyethylene film, and the release layer 15 is laminated by simultaneously applying a pressure-sensitive adhesive and drying it. The release layer 15 is peeled off when the integrated antireflective light transmissive film 10 is bonded to the entire surface of the glass substrate 12.
한편, 본 발명의 PDP용 광학필터(20)는 글래스 기판(21)의 전면(입사광이 조사되는 방향)에 반사방지성 광투과필름(25)이 형성된다. 여기에서 반사방지성 광투과필름(25)은 도 1의 반사방지성 광투과필름(10)에서 이형층(15)이 제거된 상태로 점착층(14)이 글래스 기판(21)의 전면과 직접적으로 접촉되어 있다. 그리고 글래스 기판(21)의 후면에는 접착용 중간막(22)과 전자파 차폐층(23)과 반사방지막(24)이 순차적으로 형성되어 있다. On the other hand, in the PDP optical filter 20 of the present invention, the antireflective light transmissive film 25 is formed on the entire surface of the glass substrate 21 (the direction in which incident light is irradiated). Herein, the antireflective light transmissive film 25 has the adhesive layer 14 directly on the front surface of the glass substrate 21 with the release layer 15 removed from the antireflective light transmissive film 10 of FIG. 1. In contact with An adhesive interlayer 22, an electromagnetic shielding layer 23, and an anti-reflection film 24 are sequentially formed on the rear surface of the glass substrate 21.
상술한 구조를 갖는 광학필터는, 다음과 같은 과정에 따라 제조된다.The optical filter having the above-described structure is manufactured according to the following procedure.
투명 기판(12)의 전면에 반사방지막(11)을 형성한다. 이어서, 투명 기판(12)의 후면에 근적외선 차단 및 선택적 흡광층(13)을 형성하고, 상기 근적외선 차단 및 선택적 흡광층(13) 상부에 점착층(14) 및 이형층(15)을 순차적으로 형성하여 반사방지성 광투과필름(10)을 만든다.An antireflection film 11 is formed on the entire surface of the transparent substrate 12. Subsequently, the near infrared ray blocking and selective light absorbing layer 13 are formed on the rear surface of the transparent substrate 12, and the adhesive layer 14 and the release layer 15 are sequentially formed on the near infrared ray blocking and selective light absorbing layer 13. To make an antireflective light transmissive film 10.
이와 별도로, 글래스 기판(21)의 후면에 접착용 중간막(22)과 전자파 차폐층(23)와 반사방지막(24)을 순차적으로 형성한다. 이 때 상기 결과물을 적층한 다음, 열접착공정이 필요하다. 이 때 열처리온도는 100 내지 200℃, 약 120℃의 범위이며, 열처리시간은 온도에 따라 가변적인데, 만약 120℃에서 열처리하는 경우에는 약 30분 정도이다.Separately, the adhesive interlayer 22, the electromagnetic shielding layer 23, and the anti-reflection film 24 are sequentially formed on the rear surface of the glass substrate 21. At this time, the resultant is laminated, and then a thermal bonding process is required. At this time, the heat treatment temperature is in the range of 100 to 200 ° C. and about 120 ° C., and the heat treatment time varies depending on the temperature. If heat treatment is performed at 120 ° C., it is about 30 minutes.
이어서, 상기 반사방지성 광투과필름(10)에서 이형층(15)을 제거하고, 이의 점착층(14)을 글래스 기판(21)의 전면에 접촉되도록 적층함으로써 본 발명의 광학필터(20)가 완성된다. Subsequently, the optical filter 20 of the present invention is removed by removing the release layer 15 from the antireflective light transmissive film 10 and laminating the adhesive layer 14 so as to contact the entire surface of the glass substrate 21. Is completed.
상기 접착용 중간막(22)은 전자파 차폐층(23)와 글래스(21)을 접착시키는 역할을 하는 층으로서, 이는 에틸렌-비닐아세테이트(EVA) 공중합체, 폴리비닐부티랄 등과 같은 접착수지와, 자외선, 흡수제, 적외선 흡수제, 노화 방지제, 도료 가공 조제, 필터 자체의 색조를 조정하기 위한 염료, 안료 등의 착색제, 카본블랙, 소수성 실리카, 탄산칼슘 등과 같은 충전제 등과 같은 첨가제를 선택적으로 사용하여 형성된다. 그리고 이 접착용 중간막(22)의 두께는 25 내지 500㎛인 것이 바람직하다.The adhesive interlayer 22 serves to bond the electromagnetic wave shielding layer 23 and the glass 21. The adhesive interlayer 22 is an adhesive resin such as ethylene-vinylacetate (EVA) copolymer, polyvinyl butyral, and ultraviolet rays. And additives such as absorbers, infrared absorbers, anti-aging agents, paint processing aids, dyes for adjusting the color tone of the filter itself, colorants such as pigments, fillers such as carbon black, hydrophobic silica, calcium carbonate and the like. And it is preferable that the thickness of this adhesive intermediate film 22 is 25-500 micrometers.
상기 접착용 중간막(22) 상부에 형성된 전자파 차폐층(23)은 전자파를 차폐하는 역할을 하며, 이의 구체적인 예로서 금속섬유 및/또는 금속 피복 유기 섬유로 이루어진 도전성 메쉬이거나 또는 금속섬유 및/또는 금속 피복 유기 섬유로 이루어진 동박을 패턴화시켜 얻어진 도전성 메쉬를 들 수 있고, 이러한 도전성 메쉬를 사용하면, 파손시의 비산 방지 효과를 얻을 수 있어 안전성이 높다.The electromagnetic shielding layer 23 formed on the adhesive interlayer 22 serves to shield electromagnetic waves, and as a specific example thereof, is a conductive mesh made of metal fibers and / or metal coated organic fibers or metal fibers and / or metals. The electrically conductive mesh obtained by patterning the copper foil which consists of a coating organic fiber is mentioned. When such a conductive mesh is used, the scattering prevention effect at the time of a damage can be obtained, and safety is high.
상기 금속 섬유 및 금속 피복 유기 섬유의 금속으로는, 동, 스테인레스, 알루미늄, 니켈, 티탄, 텅스텐, 주석, 철, 은, 크롬, 탄소 또는 이러한 합금을 사용하며, 그중에서도 동, 니켈, 스테인레스, 알루미늄 등이 바람직하다. 그리고 상기 금속 피복 유기 섬유의 유기 재료로는 폴리에스테르, 나일론, 염화비닐리덴, 아라미드, 비닐론, 셀룰로오스 등이 사용된다. As the metal of the metal fiber and the metal-coated organic fiber, copper, stainless, aluminum, nickel, titanium, tungsten, tin, iron, silver, chromium, carbon or an alloy thereof is used, among which copper, nickel, stainless, aluminum, and the like. This is preferable. As the organic material of the metal-coated organic fiber, polyester, nylon, vinylidene chloride, aramid, vinylon, cellulose and the like are used.
상기 전자파 차폐층(23) 즉, 도전성 메쉬의 두께는 10 내지 100㎛인 것이 바람직하며, 이의 개구율은 50 내지 95%, 라인폭은 5 내지 50㎛, 라인 피치는 100 내지 500㎛인 것이 바람직하다.The electromagnetic shielding layer 23, that is, the thickness of the conductive mesh is preferably 10 to 100㎛, the opening ratio thereof is 50 to 95%, the line width is 5 to 50㎛, the line pitch is preferably 100 to 500㎛. .
상기 전자파 차폐층(23) 상부에 형성된 반사방지막(24)은 반사방지성 광투과필름(10)을 구성하는 반사방지막(11)의 경우와 동일한 재료 및 형성방법에 따른다. The anti-reflection film 24 formed on the electromagnetic shielding layer 23 is made of the same material and forming method as in the case of the anti-reflection film 11 constituting the anti-reflective light transmitting film 10.
이하, 본 발명을 하기 실시예를 들어 설명하기로 하되, 본 발명이 하기 실시예로만 한정되는 것은 아니다.Hereinafter, the present invention will be described with reference to the following examples, but the present invention is not limited only to the following examples.
합성예 1Synthesis Example 1
반응기에 메틸에틸케톤(MEK) 1000ml를 부가하고 이를 가온하면서 여기에 폴리(메틸메타크릴레이트) 300g을 부가하여 완전히 용해하였다. 1000 ml of methyl ethyl ketone (MEK) was added to the reactor, and while heating it, 300 g of poly (methyl methacrylate) was added thereto to completely dissolve it.
이어서, 반응기에 옥타페닐테트라아자포피린 100mg과 IRG022(일본 화약사) 150mg을 부가하여 용해시켰다. Subsequently, 100 mg of octaphenyl tetraaza porphyrin and 150 mg of IRG022 (Japanese chemical company) were added and dissolved in the reactor.
그 후, 상기 반응 혼합물에 아크리딘 오렌지(Acridine Orange)(알드리치 케미칼사) 120mg을 이소프로필알콜 50ml에 용해한 용액을 천천히 가하여 근적외선 차단 및 선택적 흡광 코팅제를 제조하였다.Thereafter, a solution of 120 mg of Acridine Orange (Aldrich Chemical Co., Ltd.) in 50 ml of isopropyl alcohol was slowly added to the reaction mixture to prepare a near-infrared shield and a selective light absorbing coating.
실시예 1Example 1
상기 합성예 1에 따라 제조된 근적외선 차단 및 선택적 흡광 코팅제를 하드코팅층, 지르코늄산화물계 고굴절율막, 플루오로실록산계 저굴절율막이 순차 적층되어 형성된 반사방지막이 형성된 PET 필름의 이면에 마이크로 그라비아 방식으로 롤 코팅한 후, 이를 100℃에서 건조하여 근적외선 차단 및 선택적 흡광층을 약 10㎛의 두께로 형성하였다.The near-infrared blocking and selective absorbing coating agent prepared according to Synthesis Example 1 was rolled in a microgravure manner on the back surface of the antireflection film formed by stacking a hard coating layer, a zirconium oxide-based high refractive index film, and a fluorosiloxane-based low refractive index film sequentially. After coating, it was dried at 100 ° C. to form a near infrared barrier and selective light absorbing layer with a thickness of about 10 μm.
상기 근적외선 차단 및 선택적 흡광층 상부에 아크릴계 점착제를 콤마 코팅 방법에 따라 도포한 후, 건조하여 점착층을 형성하였다. 이어서 이 점착층 상부에 PET 기재 상부에 실리콘계 이형제가 도포되어 제조된 이형필름을 적층하여 반사방지성 광투과 필름을 완성하였다.After applying the acrylic pressure-sensitive adhesive on the near-infrared light and the selective light-absorbing layer according to the comma coating method, it was dried to form an adhesive layer. Subsequently, the antireflective light transmitting film was completed by laminating a release film prepared by applying a silicone release agent on the PET substrate on the adhesive layer.
글래스 기판(크기 600×1000㎟, 두께 3㎜)의 후면에 EVA층과 도전성 메쉬(라인폭: 10㎛, 라인 피치: 300㎛, 개구율: 약 93%)와 지르코늄산화물계 고굴절율막, 플루오로실록산계 저굴절율막이 순차 적층되어 형성된 반사방지막을 순차적으로 적층하고, 이를 진공 프레스기를 사용하여 약 120℃에서 30분동안 가열접착시켰다.EVA layer and conductive mesh (line width: 10 µm, line pitch: 300 µm, opening ratio: about 93%), zirconium oxide-based high refractive index film, fluoro on the back of glass substrate (size 600 × 1000 mm2, thickness 3 mm) The antireflection film formed by sequentially stacking the siloxane low refractive index films was sequentially stacked, and was heat-bonded at about 120 ° C. for 30 minutes using a vacuum press.
상기 글래스의 다른 일 면에 라미네이터기(속도: 약 1.0m/min)를 이용하여 상기 과정에 따라 형성된 반사방지성 광투과필름을 적층함으로써 PDP용 광학필터를 완성하였다.The PDP optical filter was completed by laminating an antireflective light transmitting film formed according to the above process using a laminator (speed: about 1.0 m / min) on the other side of the glass.
비교예 1Comparative Example 1
폴리에틸렌테레트탈레이트(PET) 필름(두께: 125㎛)의 전면에 합성예 1에 따라 제조된 근적외선 차단 및 선택적 흡광제를 도포 및 건조하여 근적외선 및 선택 적 흡광층을 형성하였다. The near-infrared blocking and selective light absorbers prepared according to Synthesis Example 1 were applied and dried on the entire surface of the polyethylene terephthalate (PET) film (thickness: 125 μm) to form a near-infrared and selective light absorbing layer.
이어서, 상기 필름의 후면에 점착층과 이형필름을 적층하여 제1필름을 형성하였다.Subsequently, a first film was formed by laminating an adhesive layer and a release film on the back of the film.
그 후, 실시예 1과 동일한 방법에 따라 3mm 글래스의 후면에 EVA층과 도전성 메쉬와 반사방지막이 형성된 필름을 순차적으로 적층하고 글래스 기판의 전면에는 제1필름을 적층하였다.Thereafter, according to the same method as in Example 1, the film on which the EVA layer, the conductive mesh, and the anti-reflection film were sequentially formed was laminated on the back of the 3 mm glass, and the first film was laminated on the front of the glass substrate.
그리고 나서, 마지막으로 상기 제조한 글래스 기판의 전면에 반사방지막이 형성된 필름을 약 1.0m/min의 속도로 점착하여 필터를 PDP용 광학필터를 완성하였다. Then, finally, the film with the anti-reflection film formed on the entire surface of the glass substrate was adhered at a speed of about 1.0 m / min to complete the filter PDP optical filter.
상기 실시예 1 및 비교예 1에 따라 제조된 광학필터를 PDP에 장착한 후, 색도계(일본 미놀타, 상품명: CS1000)를 사용하여 광학필터를 PDP에 장착하기 전후의 백색광의 휘도 및 투과율을 측정하였다.After mounting the optical filters prepared according to Example 1 and Comparative Example 1 on the PDP, the luminance and transmittance of the white light before and after mounting the optical filter on the PDP were measured using a colorimeter (Minolta, Japan, trade name: CS1000). .
상기 측정 결과는 하기 표 1과 같다.The measurement results are shown in Table 1 below.
상기 표 1로부터 알 수 있듯이, 실시예 1에 따라 제조된 광학필터의 휘도는 비교예 1의 경우에 비하여 향상되었으며, 투과율도 개선되었다.As can be seen from Table 1, the brightness of the optical filter manufactured according to Example 1 was improved compared to the case of Comparative Example 1, the transmittance was also improved.
또한, 광학필터의 전체적인 무게에 있어서도 근적외선 차단 필름과 반사방지막을 별도로 제조하여 글래스위에 순서대로 점착하여 제조한 비교예 1의 경우와 비교하여 실시예 1의 광학필터가 필터의 무게가 약 5% 감소하였고, 광학필터의 총두께도 감소하였다. 이와 같이 실시예 1의 경우는 비교예 1의 경우와 비교하여 광학필터의 구조를 단순화하여 제조수율을 향상시킬 수 있었고, 제조단가도 줄일 수 있었다.In addition, in the overall weight of the optical filter, the optical filter of Example 1 reduced the weight of the filter by about 5% compared to the case of Comparative Example 1, which was manufactured by separately preparing a near-infrared blocking film and an antireflection film and sticking them on the glass in order. The total thickness of the optical filter was also decreased. As described above, in the case of Example 1, compared to the case of Comparative Example 1, the structure of the optical filter was simplified to improve the manufacturing yield, and the manufacturing cost was also reduced.
본 발명의 PDP용 광학필터는 근적외선 차단 물질과 광선택 흡광 물질을 포함하는 층을 반사방지막이 형성된 투명 기판의 후면에 형성하여 이들을 일체화시킴으로써 휘도 저하와 관련된 광학필터의 총두께를 감소시켜 필터의 경량, 박형화가 가능하고 그 구조를 투과율을 향상시키면서 필터의 경량화 및 박형화가 가능해지고, 그 적층구조를 단순화함으로써 제조공정이 단순화되고 제조단가가 줄어들고 제조수율이 향상된다.The optical filter for PDP of the present invention forms a layer including a near infrared ray blocking material and a light selective absorbing material on the back side of a transparent substrate on which an anti-reflection film is formed and integrates them, thereby reducing the total thickness of the optical filter associated with a decrease in brightness, thereby reducing the weight of the filter. In addition, it is possible to reduce the thickness and to reduce the weight and thickness of the filter while improving the structure of the structure, and to simplify the lamination structure, the manufacturing process is simplified, the manufacturing cost is reduced, and the manufacturing yield is improved.
도 1은 본 발명의 반사방지성 광투과 필름의 적층구조를 나타낸 단면도이고,1 is a cross-sectional view showing a laminated structure of the antireflective light transmitting film of the present invention,
도 2는 도 1의 반사방지성 광투과필름을 이용하여 형성된 플라즈마 디스플레이 패널용 광학필터의 적층구조를 나타낸 단면도이다.FIG. 2 is a cross-sectional view illustrating a laminated structure of an optical filter for plasma display panel formed using the antireflective light transmitting film of FIG. 1.
<도면의 주요 부호에 대한 간단한 설명><Brief description of the major symbols in the drawings>
11, 24... 반사방지막 12... 투명기판11, 24 ... Anti-reflective film 12 ... Transparent substrate
13... 근적외선 차단 및 선택적 흡광층13 ... NIR blocking and selective light absorbing layer
14... 점착층 15... 이형층14 ... Adhesive layer 15 ... Release layer
22... 접착용 중간막 23... 전자파 차폐층22 ... Adhesive interlayer 23 ... Electromagnetic shielding layer
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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KR10-2002-0006507A KR100513641B1 (en) | 2002-02-05 | 2002-02-05 | Optical filter for plasma display panel and manufacturing method thereof |
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KR10-2002-0006507A KR100513641B1 (en) | 2002-02-05 | 2002-02-05 | Optical filter for plasma display panel and manufacturing method thereof |
Publications (2)
Publication Number | Publication Date |
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KR20030066178A KR20030066178A (en) | 2003-08-09 |
KR100513641B1 true KR100513641B1 (en) | 2005-09-07 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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KR10-2002-0006507A KR100513641B1 (en) | 2002-02-05 | 2002-02-05 | Optical filter for plasma display panel and manufacturing method thereof |
Country Status (1)
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KR (1) | KR100513641B1 (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20050110773A (en) * | 2004-05-19 | 2005-11-24 | 삼성코닝 주식회사 | Filter for plasma display panel and plasma display panel apparatus employing thereof and method for manufacturing thereof |
KR100708690B1 (en) * | 2005-06-09 | 2007-04-17 | 삼성에스디아이 주식회사 | Directly attached film filter and plasma display device having the same. |
KR100751336B1 (en) * | 2005-06-15 | 2007-08-22 | 삼성에스디아이 주식회사 | Directly attached film filter and plasma display device including same |
KR100759563B1 (en) * | 2005-12-24 | 2007-09-18 | 삼성에스디아이 주식회사 | Film filter and plasma display device having same |
KR100760125B1 (en) | 2006-03-17 | 2007-09-18 | 에스케이씨 주식회사 | Flame Retardant Optical Filters |
KR101764581B1 (en) | 2015-09-23 | 2017-08-10 | 청운대학교산학협력단 | Method for producing film coating agent having anti-finger treatemtn and anti-reflection |
-
2002
- 2002-02-05 KR KR10-2002-0006507A patent/KR100513641B1/en not_active IP Right Cessation
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KR20030066178A (en) | 2003-08-09 |
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