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KR100479712B1 - Heat transcription film transcribing gold or silver foil using scratch durability and method of manufacturing it - Google Patents

Heat transcription film transcribing gold or silver foil using scratch durability and method of manufacturing it Download PDF

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Publication number
KR100479712B1
KR100479712B1 KR10-2002-0000266A KR20020000266A KR100479712B1 KR 100479712 B1 KR100479712 B1 KR 100479712B1 KR 20020000266 A KR20020000266 A KR 20020000266A KR 100479712 B1 KR100479712 B1 KR 100479712B1
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resin
solvent
coated
film
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KR20030059864A (en
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정숙희
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코리아케미칼 주식회사
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42Intermediate, backcoat, or covering layers
    • B41M5/426Intermediate, backcoat, or covering layers characterised by inorganic compounds, e.g. metals, metal salts, metal complexes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/36Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using a polymeric layer, which may be particulate and which is deformed or structurally changed with modification of its' properties, e.g. of its' optical hydrophobic-hydrophilic, solubility or permeability properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42Intermediate, backcoat, or covering layers
    • B41M5/44Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14Metallic material, boron or silicon

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Decoration By Transfer Pictures (AREA)

Abstract

본 발명은 목재나 프라스틱 재질에 열전사한 후 금속성 수세미로 원하는 부분을 문지르면 자연스러우면서도 특수한 금은박 문양의 금속성 효과를 갖기 위하여 개발된 내스크래취성을 이용한 금은박 열전사필름 및 그 제조방법에 관한 것으로서, 기재필름층(10); 상기 기재필름층(10)의 면상에 박리성을 갖도록 도포된 이형제층(20); 상기 이형제층(20)의 면상에 입혀진 내스크래취성 인쇄층(30); 상기 내스크래취성 인쇄층(30)의 면상에 입혀진 투명색상 인쇄층(40); 상기 투명색상 인쇄층(40)의 면상에 알루미늄으로 진공증착된 알루미늄 증착층(50); 및 상기 알루미늄 증착층(50)의 면상에 접착제가 도포되는 접착층(60);으로 구성되는 것을 특징으로 한다. 금속성 수세미로 상기와 같은 열전사지로 전사한 후 원하는 부분을 문지를 경우, 내스크래취성 도막이 형성되지 아니한 금은박 도막은 흠집이 나서 벗겨지고 내스크래취성 도막 부분은 금은박의 색상이나 디자인이 그대로 유지된다. 이에 따라 본 발명에서는 자연스러우면서도 새로운 패턴의 디자인과 다양한 문양패턴을 창출할 수 있는 열전사필름이 제공된다. The present invention relates to a gold and silver foil thermal transfer film using a scratch-resistant and developed to have a metallic effect of natural and special gold and silver foil pattern by rubbing a desired portion with a metal scrubber after thermal transfer to wood or plastic material, and a manufacturing method thereof , Base film layer 10; A release agent layer 20 coated on the surface of the base film layer 10 to have peelability; A scratch resistant printed layer 30 coated on the surface of the release agent layer 20; A transparent color printed layer 40 coated on the surface of the scratch resistant printed layer 30; An aluminum deposition layer 50 vacuum-deposited with aluminum on the surface of the transparent color printing layer 40; And an adhesive layer 60 on which an adhesive is applied on the surface of the aluminum deposition layer 50. When the desired part is rubbed after transferring to the thermal transfer paper with a metallic scrubber, the gold-silver foil film which does not have a scratch-resistant coating film is peeled off and the scratch-resistant coating part retains the color or design of the gold-silver foil as it is. . Accordingly, the present invention provides a thermal transfer film that can create a natural and new pattern design and various patterns.

Description

내스크래취성을 이용한 금은박 열전사필름 및 그 제조방법{Heat transcription film transcribing gold or silver foil using scratch durability and method of manufacturing it}Heat transcription film transcribing gold or silver foil using scratch durability and method of manufacturing it}

본 발명은 표면장식용 열전사필름에 관한 것으로서, 보다 상세하게는 목재나 프라스틱 재질에 열전사한 후 금속성 수세미로 원하는 부분을 문지르면 자연스러우면서도 특수한 금은박 문양의 금속성 효과를 갖기 위하여 개발된 내스크래취성을 이용한 금은박 열전사필름 및 그 제조방법에 관한 것이다.The present invention relates to a thermal transfer film for surface decoration, and more specifically, the scratch-resistant developed to have a metallic effect of a natural and special gold and silver foil pattern by rubbing a desired portion with a metal scrubber after thermal transfer to wood or plastic materials. It relates to a gold and silver foil thermal transfer film used and a method of manufacturing the same.

일반적으로 페인트나 전사필름을 이용하여 액자프레임을 제조한 후 다시 특수한 금속무늬의 효과를 발휘하는 제품을 제조할 경우, 그 외표면에 자연스러운 금속효과 도막을 형성하기 위해서는 다음과 같은 작업을 거친다. 즉, 1차 전사가 완료된 피전사체에 자연스러운 무늬로 형성된 금은박 전사지를 2차로 전사하여 원하는 디자인을 형성시키거나, 금속성분의 페인트로 원하는 부분만 덧칠하거나 기타의 방법을 활용하여 자연스러운 색감의 금색 또는 은색의 문양을 구현하고 있다.In general, when manufacturing a frame frame using a paint or a transfer film, and then again to produce a product that exhibits the effect of a special metal pattern, in order to form a natural metal effect coating film on the outer surface is as follows. That is, to transfer the gold and silver foil transfer paper formed with a natural pattern on the transfer target to be transferred to the secondary to form a desired design, or to paint only the desired part with metallic paint or to use the other method of gold or The silver pattern is embodied.

그러나, 금속분의 안료를 혼합한 잉크를 사용하여 실크스크린 인쇄로 만든 제품이나 페인트로 금은색을 칠한 제품은 효과도 미미하면서 제조 공정의 복잡함과 번거로움으로 작업시간이 과다하게 소모되어 제조비용이 높다. 따라서 자연스러운 금속성 효과에 대한 효율성을 위한 방안이 지속적으로 요구되어 왔다.However, products made by silk-screen printing using ink mixed with metal powder or painted with silver and gold with paint have little effect and excessive manufacturing time due to the complexity and hassle of the manufacturing process, resulting in high manufacturing cost. . Therefore, there has been a continuous demand for measures for the effectiveness of natural metallic effects.

본 발명은 상기와 같은 문제점을 해결하기 위하여 창작된 것으로서, 본 발명의 목적은. 특수한 금속층 문양의 형성이 용이하며 작업효율이 향상되고 작업시간이 신속하게 진행되어 다양하면서도 자연스러운 금속효과 문양의 패턴이 창출가능한 내스크래취성을 이용한 금은박 열전사필름 및 그 제조방법을 제공하는 것이다.The present invention has been made to solve the above problems, the object of the present invention. It is to provide a gold and silver foil thermal transfer film using a scratch resistance that can easily form a special metal layer pattern, work efficiency is improved and work time is progressed quickly to create a pattern of a variety of natural metal effect patterns and a manufacturing method thereof.

상기와 같은 본 발명의 목적은, 유ㆍ무광 폴리에스테르필름 또는 상기 폴리에스테르필름에 무광제로 코팅한 무광필름으로 제조한 기재필름층(10); 상기 기재필름층(10)의 면상에 박리성을 갖도록 아크릴계 수지를 베이스 수지로 하여 제조된 이형제가 도포된 이형제층(20); The object of the present invention as described above, the base film layer 10 made of a matte film coated with a matte polyester film or a matte to the polyester film; A release agent layer 20 coated with a release agent manufactured by using an acrylic resin as a base resin to have peelability on a surface of the base film layer 10;

상기 이형제층(20)의 면상에 입혀진, 수지로서 아크릴계 수지, 아크릭우레탄 수지, UV수지 또는 우레탄 수지와, 용제로서 케톤계 용제, 아세테이트계 용제 또는 방향족계 용제와, 염료, 안료 및 경화제로 이루어진 내스크래취성 인쇄층(30); 상기 내스크래취성 인쇄층(30)의 면상에 입혀진, 수지로서 다프수지, 아크릴 수지, 아크릭우레탄 수지 또는 니트로셀룰로스 수지와, 용제로서 케톤계 용제, 아세테이트계 용제 또는 방향족계 용제와, 염료 및 경화제로 이루어진 투명색상 인쇄층(40); An inner resin composed of an acrylic resin, an acrylic urethane resin, a UV resin or a urethane resin coated on the surface of the release agent layer 20, a ketone solvent, an acetate solvent or an aromatic solvent as a solvent, a dye, a pigment, and a curing agent. Scratchable printed layer 30; Dappe resin, acrylic resin, acrylurethane resin or nitrocellulose resin coated on the surface of the scratch-resistant printing layer 30, as a solvent, ketone solvent, acetate solvent or aromatic solvent, dye and hardener A transparent color printed layer 40;

상기 투명색상 인쇄층(40)의 면상에 알루미늄으로 진공증착된 알루미늄 증착층(50); 및 상기 알루미늄 증착층(50)의 면상에 수지로서 아크릴계 수지 또는 폴리에스테르 수지와, 용제로서 케톤계 용제, 아세테이트계 용제 또는 방향족계 용제로 이루어진 접착제가 도포되는 접착층(60);으로 구성되는 것을 특징으로 하는 내스크래취성을 이용한 금은박 열전사필름 및 그 제조방법에 의하여 달성된다.An aluminum deposition layer 50 vacuum-deposited with aluminum on the surface of the transparent color printing layer 40; And an adhesive layer 60 on which an adhesive made of an acrylic resin or a polyester resin as a resin and a ketone solvent, an acetate solvent, or an aromatic solvent is coated on the surface of the aluminum deposition layer 50. It is achieved by a gold and silver foil thermal transfer film using a scratch resistance to the production method.

본 발명은 목재나 프라스틱 재질로 만들어진 액자프레임이나 피전사체와의 직접적인 열전사방식에 의하여 합성고무롤의 열과 압력만으로 열전사필름을 건식접착시키고 금속성 수세미로 원하는 부분을 문지르면 자연스러우면서도 독특한 금은박층이 한 번의 전사공정으로 형성될 수 있음에 착안하여 창작된 것이다.The present invention dry bonds the thermal transfer film only by heat and pressure of synthetic rubber rolls by direct thermal transfer method with a frame frame made of wood or plastic material, and rubs the desired parts with a metallic scrubber to make a natural yet unique gold and silver foil layer. It was created with the idea that it can be formed by one transfer process.

본 발명의 그 밖의 목적, 특정한 장점 및 신규한 특징들은 첨부된 도면들과 연관되어지는 이하의 발명의 상세한 설명과 바람직한 실시예로부터 더욱 분명해질 것이다.Other objects, specific advantages, and novel features of the present invention will become more apparent from the following detailed description of the invention and the preferred embodiments in connection with the accompanying drawings.

이하 본 발명에 따른 내스크래취성을 이용한 금은박 열전사필름 및 그 제조방법의 구성에 대하여 설명하기로 한다.Hereinafter, the configuration of the gold and silver foil thermal transfer film using the scratch resistance according to the present invention and a manufacturing method thereof will be described.

도 1은 본 발명의 일 실시예에 따른 내스크래취성을 이용한 금은박 열전사필름의 단면도이고, 도 2는 본 발명의 다른 실시예에 따른 내스크래취성을 이용한 금은박 열전사필름의 제조방법에 관한 순서도이다. 도 1, 도 2에 도시된 바와 같이, 본 발명에 따른 내스크래취성을 이용한 금은박 열전사필름은 그 단면이 총 6개의 층상구조를 이루고 있다. 1 is a cross-sectional view of a gold and silver foil thermal transfer film using scratch resistance according to an embodiment of the present invention, Figure 2 is a manufacturing method of a gold and silver foil thermal transfer film using scratch resistance according to another embodiment of the present invention Is a flowchart. As shown in Figure 1, Figure 2, the gold and silver foil thermal transfer film using the scratch resistance according to the present invention has a total of six layer structure of the cross section.

본 발명에 따른 내스크래취성을 이용한 금은박 열전사필름은 기재필름층(10), 이형제층(20), 내스크래취성 인쇄층(30), 투명색상 인쇄층(40), 알루미늄 증착층(50) 및 접착층(60)으로 구성되어 있다.Gold and silver foil thermal transfer film using scratch resistance according to the present invention is a base film layer 10, release agent layer 20, scratch-resistant printing layer 30, transparent color printing layer 40, aluminum deposition layer 50 ) And an adhesive layer 60.

먼저, S1 단계는 기재필름층(10)을 형성하는 단계이다. 상기 기재필름층(10)은 유ㆍ무광의 열안정성이 우수한 폴리에스테르 필름 또는 상기 폴리에스테르 필름에 무광제로 코팅한 무광필름으로 구성된다.First, step S1 is a step of forming the base film layer 10. The base film layer 10 is composed of a polyester film having excellent thermal stability of matte or matt or a matte film coated with a matte on the polyester film.

이후, S2 단계는 상기 기재필름층(10)의 표면에 이형제층(20)이 도포되는 단계이다. 상기 이형제층(20)은 케톤계, 아세테이트계 혹은 방향족계 용제에 아크릴계 수지가 균일하게 용해되어 있다. 상기 이형제층(20)은 내스크래취성 인쇄층(30) 또는 투명색상 인쇄층(40)과, 기재필름층(10)과의 박리성을 도모하게 된다. 상기 이형제층(20)의 수지중량은 14 ~ 18 중량부가 바람직하다.Thereafter, step S2 is a step in which the release agent layer 20 is applied to the surface of the base film layer 10. In the release agent layer 20, an acrylic resin is uniformly dissolved in a ketone-based, acetate-based or aromatic solvent. The release agent layer 20 achieves peelability between the scratch resistant printing layer 30 or the transparent color printing layer 40 and the base film layer 10. The resin weight of the release agent layer 20 is preferably 14 to 18 parts by weight.

이후, S3 단계는 상기 이형제층(20)상에 내스크래취성을 부여하면서 다양한 색상을 형성하기 위해 내스크래취성 인쇄층(30)을 도포하는 단계이다. 상기 내스크래취성 인쇄층(30)은 수지로서 아크릴계 수지, 아크릭우레탄계 수지, UV 수지 또는 우레탄계 수지와, 용제로서 케톤계, 아세테이트계 또는 방향족계 용제와, 염료와, 안료와, 경화제로 구성된다.Thereafter, step S3 is a step of applying the scratch resistant print layer 30 to form various colors while giving scratch resistance on the release agent layer 20. The scratch resistant printed layer 30 is composed of an acrylic resin, an acrylic urethane resin, a UV resin or a urethane resin as a resin, a ketone, acetate or aromatic solvent, a dye, a pigment, and a curing agent as a solvent.

이후, S4 단계는 상기 내스크래취성 인쇄층(30)상에 투명한 색상의 효과를 부여하기 위해 투명색상 인쇄층(40)을 도포하는 단계이다. 상기 투명색상 인쇄층(40)은 수지로서 내열성이 우수한 다프(DAP) 수지, 아크릴계 수지, 아크릭우레탄계 수지 또는 니트로셀룰로스 수지와, 용제로서 케톤계, 아세테이트계 또는 방향족계 용제와, 염료와, 경화제로 구성된다.Thereafter, step S4 is a step of applying the transparent color printing layer 40 to give the effect of the transparent color on the scratch-resistant printing layer (30). The transparent printed layer 40 is a resin having excellent heat resistance as a DAP resin, an acrylic resin, an acryl urethane resin or a nitrocellulose resin, as a solvent, a ketone-based, acetate-based or aromatic solvent, a dye, and a curing agent. It is composed.

이후, S5 단계는 상기 투명색상 인쇄층(40)상에 알루미늄 성분을 진공증착 가공을 하여 알루미늄 증착층(50)을 형성시키는 단계이다.Subsequently, step S5 is a step of forming an aluminum deposition layer 50 by performing vacuum deposition on the aluminum component on the transparent color printing layer 40.

끝으로, S6 단계는 증착가공이 완료된 증착막의 금속도막과 접착력을 유지하면서 피전사체에 접착효과를 동시에 발휘하기 위하여 상기 알루미늄 증착층(50)의 면상에 접착층(60)을 도포하는 단계이다. 상기 접착층(60)은 수지로서 아크릴계 수지 또는 폴리에스테르 수지와, 용제로서 케톤계 용제, 아세테이트계 용제 또는 방향족계 용제를 혼합하여 제조된다. 이로써 본 발명에 따른 내스크래취성을 이용한 금은박 열전사필름이 완성된다.Finally, step S6 is a step of applying the adhesive layer 60 on the surface of the aluminum deposition layer 50 in order to simultaneously exert the adhesive effect to the transfer object while maintaining the adhesion and the metal coating film of the deposition film is completed. The adhesive layer 60 is prepared by mixing an acrylic resin or a polyester resin as a resin and a ketone solvent, an acetate solvent, or an aromatic solvent as a solvent. This completes the gold and silver foil thermal transfer film using scratch resistance according to the present invention.

상기와 같이 제조된 전사지를 목재나 프라스틱 재질로 만들어진 액자프레임이나 기타 피전사물에 간단하게 열전사시킨 후 금속성 수제미로 문지르면 원하는 자연스러운 금은색 문양의 디자인이 형성된 전사지를 공급받게 된다.The transfer paper prepared as described above is simply thermally transferred to a frame frame or other transfer object made of wood or plastic material and then rubbed with a metallic handmade rice to receive a transfer paper having a desired natural gold or silver pattern design.

이 때, 상기 접착에 있어서 가압로울러는 약 130℃ 전후의 온도와 약 3 ~ 5 m/분의 속도로 전사지를 압편하는 것이 바람직할 것이나, 굳이 이에 한정되지는 아니한다.At this time, it is preferable that the pressure roller squeeze the transfer paper at a temperature of about 130 ° C. and a speed of about 3 to 5 m / min, but is not limited thereto.

이하 본 발명에 따른 내스크래취성을 이용한 금은박 열전사필름 및 그 제조방법의 작용 및 실시예에 대하여 설명하기로 한다.Hereinafter, the operation and examples of the gold and silver foil thermal transfer film using the scratch resistance according to the present invention and a manufacturing method thereof will be described.

상기와 같이 열전사필름상에 특수한 문양이 형성되는 원리에 관하여 설명한다. 상기와 같이 금속성 수세미로 상기 열전사필름의 원하는 부분을 문지를 경우, 내스크래취성 도막이 형성되지 아니한 금은박 도막은 흠집이 나서 벗겨지고, 내스크래취성 도막 부분은 금은박의 색상이나 디자인이 그대로 유지된다. 이에 따라 자연스러우면서도 새로운 패턴의 디자인과 다양한 문양패턴을 창출할 수 있는 열전사필름이 제공된다. The principle of forming a special pattern on the thermal transfer film as described above will be described. When the desired portion of the thermal transfer film is rubbed with a metallic scrubber as described above, the gold and silver foil coating film, in which the scratch resistant film is not formed, is scratched and peeled off, and the portion of the scratch resistant coating film is maintained in the color or design of the gold and silver foil. . As a result, a thermal transfer film that can create a natural and new pattern design and various pattern patterns is provided.

<실시예><Example>

두께 12 ~ 25 미크론의 유ㆍ무광 폴리에스테르필름 또는 폴리에스테르 필름에 무광제를 코팅한 무광필름으로 제조한 기재필름층(10)에 대하여, 이형제층(20)(수지중량 : 14 ~ 18 중량부), 내스크래취성을 부여하기 위한 내스크래취성 인쇄층(30), 내열성이 우수한 수지로 제조한 투명색상 인쇄층(40), 알루미늄 증착층(50), 상기 알루미늄 증착층(50)과 접착을 유지하면서 접착 효과를 발휘하는 접착층(60)을 순차적으로 적층화시켜 본 발명에 따른 금은박 열전사필름을 제조한다.Releasing agent layer 20 (resin weight: 14-18 parts by weight) with respect to base film layer 10 made of matte / coated polyester film having a thickness of 12-25 microns or a matte film coated with a polyester film ), The scratch-resistant printing layer 30 for imparting scratch resistance, the transparent color printing layer 40 made of a resin having excellent heat resistance, the aluminum deposition layer 50, the adhesion with the aluminum deposition layer 50 The gold and silver foil thermal transfer film according to the present invention is prepared by sequentially laminating the adhesive layer 60 exhibiting the adhesive effect while maintaining.

본 내스크래취성을 이용한 금은박 열전사지를 전사시키고자 하는 액자 프레임 또는 기타의 피전사체에 약 130℃ 정도의 온도조건을 지닌 합성고무롤로 약 3 ~ 5 m/분의 속도로 압편(피전사체의 종류가 다양한 관계로 전사온도와 전사속도는 차이가 있을 수 있다)시키고 금속성 수세미로 문지르면 원하는 제품이 생산된다.This is a synthetic rubber roll having a temperature condition of about 130 ℃ on a frame frame or other transfer target to transfer the gold and silver foil thermal transfer paper using scratch resistance. Due to the variety of types, the transfer temperature and transfer speed may be different) and rubbed with a metal scrubber to produce the desired product.

<비교예 1>Comparative Example 1

기존의 금은박 열전사지로 1차 전사한 후 자연스러운 무늬의 디자인으로 형성된 금은박 전사지로 2차 전사를 시키면 원하는 금은박 디자인이 형성되지만, 1차로 전사된 하층의 전사도막이 압편고무롤의 열에 의하여 광택이 소멸되거나 변형이 생겨서 제품의 가치가 떨어지는 문제점이 있다.When the first transfer to the existing gold and silver foil thermal transfer paper and the second transfer to the gold and silver foil transfer paper formed in a natural pattern design, the desired gold and silver foil design is formed, but the lower transfer film of the first transfer layer is polished by the heat of the squeezed rubber roll. There is a problem that the value of the product is deteriorated due to extinction or deformation.

<비교예 2>Comparative Example 2

기존의 금은박 열전사로 전사한 후 금색 또는 은색의 페인트로 원하는 부분만 덧칠을 하여 이중색감의 금색 또는 은색이 도포된 제품을 특수하게 생산하고 있으나, 가공 공정의 시간이 길고 복잡하기 때문에 제조 원가가 상승되는 문제점이 있다.After the transfer to the existing gold and silver foil thermal transfer, only the desired part is painted with gold or silver paint to produce the product coated with gold or silver with a double color, but the manufacturing cost is long because the processing time is long and complicated. There is a problem that rises.

상기 언급한 바와 같이 본 발명에 따른 내스크래취성을 이용한 금은박 열전사필름에 의하면, 목재 또는 프라스틱 재질의 액자프레임, 가구, 건축내장재 등 여러 분야의 제품에 금속성 수세미나 브러쉬 등의 재료를 사용함으로써 자연스럽고 특수한 금은박의 장식적인 효과를 낼 수 있다.As mentioned above, according to the gold and silver foil thermal transfer film using the scratch resistance according to the present invention, by using a material such as a metal scrubber brush in a product of various fields such as a frame frame, furniture, building interior materials, etc. It can give a decorative effect of natural and special gold and silver foil.

또한, 본 발명에 따른 내스크래취성을 이용한 금은박 열전사필름에 의하면, 장식물을 제작함에 있어서 합성고무롤을 통한 열과 압력만으로 열전사필름을 간단하게 건식접착시키고 금속성 수세미로 문지르면 원하는 자연스러운 효과를 발휘하는 특수한 금은박 문양의 형성이 가능함은 물론이고 우수한 표면문양과 동시에 작업공정의 단순화로 인한 제조비용의 절감에도 효과가 있다.In addition, according to the gold and silver foil thermal transfer film using the scratch resistance according to the present invention, in the production of a decoration simply by dry-bonding the thermal transfer film only by heat and pressure through a synthetic rubber roll and rubbing with a metal scrubber to achieve the desired natural effect It is possible not only to form special gold and silver foil patterns, but also to reduce the manufacturing cost by simplifying the work process as well as excellent surface patterns.

비록 본 발명이 상기 언급된 바람직한 실시예와 관련하여 설명하였지만, 발명의 요지와 범위로부터 벗어남이 없이 다양한 수정이나 변형을 하는 것이 가능하다. 따라서 첨부된 특허청구범위는 본 발명의 요지에 속하는 이러한 수정이나 변형을 포함한다. Although the present invention has been described in connection with the above-mentioned preferred embodiments, it is possible to make various modifications or variations without departing from the spirit and scope of the invention. Accordingly, the appended claims include such modifications and variations as fall within the spirit of the invention.

도 1은 본 발명의 일 실시예에 따른 내스크래취성을 이용한 금은박 열전사필름의 단면도이다.1 is a cross-sectional view of a gold and silver foil thermal transfer film using scratch resistance according to an embodiment of the present invention.

도 2는 본 발명의 다른 실시예에 따른 내스크래취성을 이용한 금은박 열전사필름의 제조방법에 관한 순서도이다.2 is a flowchart illustrating a method of manufacturing a gold and silver foil thermal transfer film using scratch resistance according to another embodiment of the present invention.

* 도면의 주요 부분에 대한 부호 설명* Explanation of symbols on the main parts of the drawing

10 : 기재필름층10: base film layer

20 : 이형제층20: release agent layer

30 : 내스크래취성 인쇄층30: scratch resistant printed layer

40 : 투명색상 인쇄층40: transparent color printing layer

50 : 알루미늄 증착층50: aluminum deposition layer

60 : 접착층60: adhesive layer

Claims (2)

유ㆍ무광 폴리에스테르필름 또는 상기 폴리에스테르 필름에 무광제를 코팅한 무광필름으로 제조한 기재필름층(10);A base film layer (10) made of a matte polyester film or a matte film coated with a matting agent on the polyester film; 상기 기재필름층(10)의 면상에 박리성을 갖도록 아크릴계 수지와, 용제로서 케톤계 용제, 아세테이트계 용제 또는 방향족계 용제로 제조된 이형제가 도포된 이형제층(20);A release agent layer 20 coated with an acrylic resin and a release agent made of a ketone solvent, an acetate solvent, or an aromatic solvent so as to have peelability on the surface of the base film layer 10; 상기 이형제층(20)의 면상에 문양을 형성하며 입혀지며, 아크릴계 수지, 아크릭우레탄 수지, UV 수지 또는 우레탄 수지와, 용제로서 케톤계 용제, 아세테이트계 용제 또는 방향족계 용제와, 염료와, 안료와, 경화제로 이루어지는 내스크래취성 인쇄층(30);It is coated while forming a pattern on the surface of the release agent layer 20, acrylic resin, acryl urethane resin, UV resin or urethane resin, ketone solvent, acetate solvent or aromatic solvent, dye, pigment and A scratch resistant printed layer 30 made of a curing agent; 상기 내스크래취성 인쇄층(30)의 면상에 입혀지며, 다프수지, 아크릴 수지, 아크릭우레탄 수지 또는 니트로셀룰로스 수지와, 케톤계 용제, 아세테이트계 용제 또는 방향족계 용제와, 염료와, 경화제로 이루어진 투명색상 인쇄층(40);It is coated on the surface of the scratch-resistant printing layer 30, and made of a dap resin, an acrylic resin, an acryl urethane resin or a nitrocellulose resin, a ketone solvent, an acetate solvent or an aromatic solvent, a dye, and a curing agent. Color print layer 40; 상기 투명색상 인쇄층(40)의 면상에 알루미늄으로 진공증착된 알루미늄 증착층(50); 및An aluminum deposition layer 50 vacuum-deposited with aluminum on the surface of the transparent color printing layer 40; And 상기 알루미늄 증착층(50)의 면상에 입혀지며, 아크릴계 수지 또는 폴리에스테르 수지와, 케톤계 용제, 아세테이트계 용제 또는 방향족계 용제로 이루어진 접착제가 도포되는 접착층(60);으로 구성되는 것을 특징으로 하는 내스크래취성을 이용한 금은박 열전사필름.An adhesive layer 60 coated on a surface of the aluminum deposition layer 50 and coated with an adhesive made of an acrylic resin or a polyester resin and a ketone solvent, an acetate solvent, or an aromatic solvent; Gold and silver foil thermal transfer film using scratch resistance. 유ㆍ무광 폴리에스테르 필름 또는 상기 폴리에스테르 필름에 무광제로 코팅한 무광필름으로 제조한 기재필름층(10)을 형성하는 단계(S1);Forming a base film layer (10) made of a matte polyester film or a matte film coated with a matte on the polyester film (S1); 상기 기재필름층(10)의 면상에 박리성을 갖도록 아크릴계 수지와, 용제로서 케톤계 용제, 아세테이트계 용제 또는 방향족계 용제로 제조된 이형제층(20)을 도포하는 단계(S2);Applying an acrylic resin and a release agent layer 20 made of a ketone solvent, an acetate solvent, or an aromatic solvent to have a peelability on the surface of the base film layer 10 (S2); 상기 이형제층(20)의 면상에 문양을 형성하며 입혀지며, 아크릴계 수지, 아크릭우레탄 수지, UV 수지 또는 우레탄 수지와, 케톤계 용제, 아세테이트계 용제 또는 방향족계 용제와, 염료와, 안료와, 경화제로 제조된 내스크래취성 인쇄층(30)이 인쇄되는 단계(S3);It is coated while forming a pattern on the surface of the release agent layer 20, A step of printing a scratch-resistant printing layer 30 made of an acrylic resin, an acrylic urethane resin, a UV resin or a urethane resin, a ketone solvent, an acetate solvent or an aromatic solvent, a dye, a pigment, and a curing agent ( S3); 상기 내스크래취성 인쇄층(30)의 면상에 입혀지며, 다프 수지, 아크릴수지, 아크릭우레탄 수지 또는 니트로셀룰로스 수지와, 케톤계 용제, 아세테이트계 용제 또는 방향족계 용제와, 염료와, 경화제를 혼합한 투명색상 인쇄층(40)이 인쇄되는 단계(S4);It is coated on the surface of the scratch-resistant printing layer 30, and mixed with a dop resin, an acrylic resin, an acryl urethane resin or a nitrocellulose resin, a ketone solvent, an acetate solvent or an aromatic solvent, a dye, and a curing agent. A step S4 of printing the transparent color printing layer 40; 상기 투명색상 인쇄층(40)의 면상에 알루미늄으로 진공증착된 알루미늄 증착층(50)을 형성하는 단계(S5); 및Forming an aluminum deposition layer (50) vacuum-deposited with aluminum on the surface of the transparent color printing layer (40); And 상기 알루미늄 증착층(50)의 면상에 입혀지며, 아크릴계 수지 또는 폴리에스테르 수지와, 케톤계 용제, 아세테이트계 용제 또는 방향족계 용제로 구성되는 접착층(60)이 도포되는 단계(S6);로 이루어진 것을 특징으로 하는 내스크래취성을 이용한 금은박 열전사필름을 제조하는 방법.Coated on the surface of the aluminum deposition layer 50, a step (S6) of applying an adhesive layer 60 composed of an acrylic resin or a polyester resin and a ketone solvent, an acetate solvent or an aromatic solvent; Method of producing a gold and silver foil thermal transfer film using a scratch resistance.
KR10-2002-0000266A 2002-01-03 2002-01-03 Heat transcription film transcribing gold or silver foil using scratch durability and method of manufacturing it Expired - Fee Related KR100479712B1 (en)

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CN116176150B (en) * 2022-12-15 2023-11-14 江苏学泰印务有限公司 Platinum relief heat transfer film and production process thereof

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JPH05147395A (en) * 1991-11-29 1993-06-15 Yukio Ito Transfer sheet
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KR200211973Y1 (en) * 2000-08-25 2001-02-01 황석화 Transfer paper

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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