KR100412330B1 - Membrane Coupled Activated Sludge Method Operating Anoxic/Anaerobic Zone alternatively for Removal of Nitrogen and Phosphorus - Google Patents

Abstract

Oxygen-free and anaerobic process for the simultaneous treatment of nitrogen and phosphorus in accordance with the present invention, the actuated membrane separation activated sludge process, nitrogen and phosphorus is carried out alternately an anaerobic process for the denitrification reaction to remove nitrogen and anaerobic process for the release of phosphorus Sewage and wastewater advanced treatment method for simultaneously treating the wastewater, wherein the anoxic process is introduced into an anaerobic / anaerobic alternating operation reactor in which anoxic and anaerobic processes are successively operated using sewage, sewage, or wastewater as inflow water. (A); (B) operating an internal transfer pump that is operated intermittently to continuously transport the nitrate nitrogen generated in the aeration tank to make the anaerobic / anaerobic shift driving reactor anoxic; (C) converting the nitrate nitrogen supplied through the internal transport of step (b) into nitrogen gas by using the organic material in the continuously introduced inflow water as a carbon source; (D) flowing the denitrification-treated mixture in step (c) and flowing it into the subsequent aeration tank; Under the aerobic conditions of the aeration tank where the continuous aeration by blower, the process of nitrification converting organic nitrogen and ammonia nitrogen supplied from influent by nitrifying microorganism into nitrate nitrogen and oxidizing organic matter decomposing remaining organic matter (e); And (f) continuously discharging the treated water using an immersion type membrane installed in the aeration tank, wherein the anaerobic process is continuously operated in an anaerobic / anaerobic shift operation using sewage, sewage, or wastewater as inflow water. Introducing into the reactor (a '); Stopping the operation of the internal transfer pump that is intermittently operated to stop the internal transfer of nitrate nitrogen generated in the aeration tank to make the anaerobic / anaerobic shift driving reactor anaerobic (b '); (C ') releasing phosphorus to dephosphorized microorganisms by using organic matter in the continuously introduced influent water as a carbon source in an anaerobic state in which denitrification of nitrogen nitrate is depleted due to the stop of internal transport of step (b); (D ') overflowing the microorganisms having released phosphorus in the step (c') to a subsequent aeration tank; Under the aerobic conditions of the aeration tank where continuous aeration is carried out by the blower, the concentration of dissolved phosphorus in the aeration tank is reduced by the phosphorus excess intake of the phosphorus-releasing microorganism of the step (d '), and at the same time, organic nitrogen and (E ') a nitrification process for converting ammonia nitrogen to nitrate nitrogen and an organic matter oxidation process for decomposing the remaining organic matter; Continuously discharging the treated water from which phosphorus has been removed using an immersion membrane installed in the aeration tank (f '); And (g ') discharging the sludge in a state in which the phosphorus in the step (e') is excessively ingested and discharging the phosphorus, wherein the anaerobic and anaerobic processes of the anaerobic / anaerobic alternating reactor are performed. The classification is characterized by the presence or absence of the internal transport of nitrate nitrogen by adjusting the operating time of the internal transport pump.

Description

Membrane Coupled Activated Sludge Method Operating Anoxic / Anaerobic Zone alternatively for Removal of Nitrogen and Phosphorus}

The present invention relates to an advanced treatment method of sewage and wastewater for simultaneously removing nitrogen and phosphorus, which are substances causing eutrophication of rivers and lakes, as well as organic substances contained in sewage or wastewater. Membrane Activated Sludge System composed of two reactors, an anaerobic / anaerobic alternating reactor, in which anoxic and anaerobic processes are operated alternately by intermittent internal transfer, and an aeration tank equipped with an immersion membrane for continuous operation. The present invention relates to an economical and effective method for advanced treatment of sewage and wastewater that simultaneously removes nitrogen and phosphorus together with organic matter in sewage and wastewater.

When nitrogen and phosphorus contained in sewage and wastewater are discharged untreated, it causes eutrophication of rivers and lakes, which adversely affects water resources and aquatic ecosystems, and especially when infants drink large amounts of nitrate nitrogen. May cause cyanosis and require treatment. Therefore, several advanced treatment methods have been devised for the treatment of nitrogen and phosphorus, which are becoming more regulated, and representative processes include Modified Ludzack-Ettinger (MLE), A ₂ O, University of Cape Town (UCT), and Modified University (MUCT). bio-treatment techniques such as of Cape Town and VIP Initiative Plant.

However, these typical processes consist of several reactors and internal circulating pumps, which are difficult to maintain optimum conditions for the removal of nitrogen and phosphorus and are very complicated to operate. It is difficult to keep the concentration of the microorganisms high. In addition, the processes have many problems in efficient treatment due to the inflow of fluctuations of microorganisms due to the impact load, such as fluctuations in inflow load and influx of toxic substances, to reduce the water quality or the loss of active microorganisms. In addition, two or more independent reactors and the end of the sedimentation tank must be installed, so it takes up a large site and is not suitable for small and medium-sized sewage and wastewater treatment.

In order to solve this problem, various sewage and wastewater advanced treatment methods using membrane activated sludge methods using a separator for solid-liquid separation have been tried. However, even in this case, it is necessary to arrange several reactors for the advanced treatment, and there are disadvantages such as difficulty in removing phosphorus.

One such conventional treatment method is a "drainage treatment method (Japanese Patent Laid-Open No. 7-100486). This method consists of a first treatment tank which induces nitrification and denitrification through an intermittent aeration and a second treatment tank which is equipped with an immersion type membrane for solid-liquid separation to remove nitrogen and allow continuous suction filtration. However, this method cannot create an anaerobic condition for the removal of phosphorus, so that phosphorus removal cannot be effectively achieved, and a second treatment tank is separately installed for continuous suction filtration to prevent contamination of the membrane. Since additional aeration is required, the energy cost of the aeration is doubled.

Another conventional method is an apparatus and method for removing biological nitrogen phosphorus using an immersion membrane (Korean Patent Publication No. 2002-44820). This method induces simultaneous removal of nitrogen and phosphorus by installing anaerobic tank, anaerobic tank, aerobic tank and degassing tank sequentially. However, in this case, an anaerobic tank should be additionally used for phosphorus removal, and in the case of sewage with low C / N ratio, which is a characteristic of domestic sewage, most of the carbon source is used for denitrification in an anaerobic tank installed at the front end. There is a disadvantage that there is a limit to the removal of phosphorus due to the lack of a carbon source necessary for the release of phosphorus.

The present invention is to solve the problems of the prior art as described above, an object of the present invention, by alternately repeating the anaerobic / anaerobic process by the intermittent operation of the internal circulation pump, in the anoxic state to remove nitrogen by denitrification In the anaerobic state, by releasing phosphorus, it simultaneously treats nitrogen and phosphorus in sewage and wastewater, and improves the treated water quality, and provides an anoxic and anaerobic process-operated membrane separation activated sludge process and apparatus for simultaneous treatment of nitrogen and phosphorus. It is.

In addition, the present invention can control the maintenance time and the internal circulation flow rate of the anaerobic / anaerobic process, the number of reactors and the number of pumps required by the simple configuration of the process, while the continuous treatment, anoxic for simultaneous treatment of nitrogen and phosphorus And to provide an anaerobic process alternate operation type membrane separation activated sludge process and apparatus.

FIG. 1 (a) schematically shows an anoxic treatment process in an anoxic and anaerobic process-operated membrane separation activated sludge process for simultaneous treatment of nitrogen and phosphorus according to the present invention.

Figure 1 (b) schematically shows the anaerobic treatment process in the anaerobic and anaerobic process alternate operation type membrane separation activated sludge process for the simultaneous treatment of nitrogen and phosphorus according to the present invention.

* Description of the symbols for the main parts of the drawings *

1: source of inflow 2: anaerobic / anaerobic shift reactor

3: stirrer 4: internal return pump

5: Aeration tank 6: Immersion type membrane

7: treated water 8: sludge disposal

9: blower

In order to achieve the object as described above, the anoxic and anaerobic process-type membrane separation activated sludge process for the simultaneous treatment of nitrogen and phosphorus according to the present invention, an anoxic process for denitrification to remove nitrogen and for the release of phosphorus An advanced anaerobic wastewater treatment method for simultaneously treating nitrogen and phosphorus in which anaerobic processes are alternately performed, wherein the anoxic process is operated by alternately operating an anaerobic process and an anaerobic process using sewage, sewage, or wastewater as inflow water. (A) introducing an anaerobic / anaerobic shift driving reactor; (B) operating an internal transfer pump that is operated intermittently to continuously transport the nitrate nitrogen generated in the aeration tank to make the anaerobic / anaerobic shift driving reactor anoxic; (C) converting the nitrate nitrogen supplied through the internal transport of step (b) into nitrogen gas by using the organic material in the continuously introduced inflow water as a carbon source; (D) flowing the denitrification-treated mixture in step (c) and flowing it into the subsequent aeration tank; Under the aerobic conditions of the aeration tank where the continuous aeration by blower, the process of nitrification converting organic nitrogen and ammonia nitrogen supplied from influent by nitrifying microorganism into nitrate nitrogen and oxidizing organic matter decomposing remaining organic matter (e); And (f) continuously discharging the treated water using an immersion type membrane installed in the aeration tank, wherein the anaerobic process is continuously operated in an anaerobic / anaerobic shift operation using sewage, sewage, or wastewater as inflow water. Introducing into the reactor (a '); Stopping the operation of the internal transfer pump that is intermittently operated to stop the internal transfer of nitrate nitrogen generated in the aeration tank to make the anaerobic / anaerobic shift driving reactor anaerobic (b '); (C ') releasing phosphorus to dephosphorized microorganisms by using organic matter in the continuously introduced influent water as a carbon source in an anaerobic state in which denitrification of nitrogen nitrate is depleted due to the stop of internal transport of step (b); (D ') overflowing the microorganisms having released phosphorus in the step (c') to a subsequent aeration tank; Under the aerobic conditions of the aeration tank where continuous aeration is carried out by the blower, the concentration of dissolved phosphorus in the aeration tank is reduced by the phosphorus excess intake of the phosphorus-releasing microorganism of the step (d '), and at the same time, organic nitrogen and (E ') a nitrification process for converting ammonia nitrogen to nitrate nitrogen and an organic matter oxidation process for decomposing the remaining organic matter; Continuously discharging the treated water from which phosphorus has been removed using an immersion membrane installed in the aeration tank (f '); And (g ') discharging the sludge in a state in which the phosphorus in the step (e') is excessively ingested and discharging the phosphorus, wherein the anaerobic and anaerobic processes of the anaerobic / anaerobic alternating reactor are performed. The classification is characterized by the presence or absence of the internal transport of nitrate nitrogen by adjusting the operating time of the internal transport pump.

In the anoxic and anaerobic alternating membrane separation activated sludge process for the simultaneous treatment of nitrogen and phosphorus according to the present invention, the immersion type membrane for obtaining the treated water of step (f) of the anaerobic process and step (f ') of the anaerobic process The silver membrane is characterized in that the microfiltration membrane or ultrafiltration membrane selected from flat membrane type, hollow fiber type, or tubular type.

In the anaerobic and anaerobic process alternating membrane separation activated sludge process for the simultaneous treatment of nitrogen and phosphorus according to the present invention, step (f) of the anaerobic process and step (f ') of the anaerobic process obtain treated water from the immersion type membrane. In the case of membrane filtration, it is characterized by using a suction pump or using a natural suction pressure due to water head difference.

Oxygen-free and anaerobic process alternating operation type membrane separation activated sludge apparatus for the simultaneous treatment of nitrogen and phosphorus according to the present invention, nitrogen and phosphorus, the anaerobic process for the denitrification reaction for nitrogen removal and the anaerobic process for the release of phosphorus alternately, An apparatus for treating sewage and wastewater, comprising: an anoxic / anaerobic alternating reactor equipped with an agitator and an anaerobic process and an anaerobic process operated alternately; An aeration tank equipped with a blow, which causes organic matter oxidation, nitrification reaction, and excessive intake of phosphorus in an aerobic state; An internal conveying pump for conveying nitrate nitrogen generated from the aeration tank to the anoxic / anaerobic alternating operation reactor; And an immersion type separation membrane mounted in the aeration tank for continuously discharging the treated water through membrane filtration, wherein the separation between the anoxic process and the anaerobic process in the anaerobic / anaerobic alternating reactor is performed by an internal transfer pump. It is classified according to the internal transport of nitrogen.

In the anaerobic and anaerobic process-operated membrane separation activated sludge apparatus for the simultaneous treatment of nitrogen and phosphorus according to the present invention, the immersion type membrane is a microfiltration membrane or an ultrafiltration membrane whose membrane is selected from flat membrane, hollow fiber type, or tubular type. .

In the present invention, an anoxic and anaerobic process-operated membrane separation activated sludge apparatus for simultaneous treatment of nitrogen and phosphorus, the apparatus may further include a suction pump for suction filtering the treated water from the immersion membrane.

Hereinafter, an anoxic and anaerobic process-operated membrane separation activated sludge apparatus and method for simultaneous treatment of nitrogen and phosphorus according to the present invention will be described in detail with reference to the drawings.

FIG. 1 (a) schematically shows an anoxic treatment process in an anoxic and anaerobic process-operated membrane separation activated sludge process for simultaneous treatment of nitrogen and phosphorus according to the present invention. Figure 1 (b) schematically shows the anaerobic treatment process in the anaerobic and anaerobic process alternate operation type membrane separation activated sludge process for the simultaneous treatment of nitrogen and phosphorus according to the present invention.

As shown in FIG. 1, the present invention provides an anoxic condition and an anaerobic condition by intermittently controlling the internal conveying pump 4 for returning the activated sludge mixed solution from the aeration tank 5 to the anaerobic / anaerobic alternating operation reactor 2. It consists of an aerobic / anaerobic alternating reaction reactor 2 equipped with an agitator 3 and an aeration tank 5 equipped with an immersion separator 6 in which continuous aeration and membrane filtration are performed.

Looking at the configuration and operation of the present invention in more detail.

Inflow source water 1 of sewage, sewage, wastewater, etc. is continuously introduced into an anaerobic / anaerobic shift driving reactor 2. The anaerobic and anaerobic processes in the anaerobic / anaerobic shift reactor (2) can be classified according to the presence or absence of internal transport. That is, since the nitrate nitrogen is continuously supplied by the internal transfer during the period in which the internal transfer pump 4 which is operated intermittently according to the time interval is operated, it becomes an oxygen-free process, and during the period during which it is stopped, the nitrate nitrogen The supply of is cut off and the nitrate nitrogen is depleted in the tank and becomes an anaerobic process.

In the anoxic / anaerobic alternating reactor (2) during the anoxic process, nitrate nitrogen supplied from the aeration tank (5) to the inner conveyance from the aeration tank (5) is used as nitrogen gas by using organic matter in the continuously introduced inflow water (1) as a carbon source. The denitrification process of conversion and removal proceeds, and the denitrification mixture is moved to the aeration tank 5 which is subsequently passed. In the aeration tank 5 in which the aeration is continuously performed by the blower 9, the nitrification process of converting the organic nitrogen and ammonia nitrogen supplied from the inflow by the nitrifying microorganism into the nitrate nitrogen under aerobic conditions, and the organic matter decomposing the remaining organic matter. The oxidation process proceeds, and at the same time, the treated water 7 is continuously discharged using the immersion type membrane 6 installed in the aeration tank 5.

During the anaerobic process, the internal transfer to the anaerobic / anaerobic alternating reactor (2) stops, and therefore, the nitrate nitrogen remaining in the anaerobic / anaerobic alternating reactor (2) is denitrated and completely removed to become anaerobic. Dephosphorized microorganisms release phosphorus using the carbon source included. Phosphorus-releasing microorganisms lower the concentration of dissolved phosphorus in the aeration tank 5 by overingestion of phosphorus under aerobic conditions in the subsequent aeration tank 5, and at the same time, in the aeration tank, organic nitrogen and ammonia nitrogen supplied from the influent by the nitrifying microorganisms. Nitrification process to convert N to nitrate nitrogen and organic matter oxidation process to decompose the remaining organic matter is carried out. The treated water 7 from which phosphorus is removed is continuously discharged using the immersion type separation membrane 6. At the same time, the phosphorus is finally discharged by disposing the sludge in the state in which phosphorus is excessively ingested.

Although the present invention has been described in detail above with reference to the drawings, it will be apparent to the inventors that various changes and modifications can be made within the scope and spirit of the present invention, and the appended claims It is natural to belong to.

As described above, the oxygen-free and anaerobic process-type membrane separation activated sludge process for the simultaneous treatment of nitrogen and phosphorus according to the present invention, by an intermittent operation of the internal circulation pump alternately repeating the anaerobic / anaerobic process, an anoxic state By removing nitrogen by denitrification and releasing phosphorus in an anaerobic state, nitrogen and phosphorus in sewage and wastewater can be effectively treated simultaneously. In particular, even when the C / N ratio, which is a characteristic of domestic sewage, is low, the limited carbon source contained in sewage can be effectively used for denitrification and phosphorus removal, so that nitrogen and phosphorus removal efficiency can be maintained at the same time. This is an advantageous way. In addition, the treated water quality is also a complete solid-liquid separation through the immersion type membrane, there is an advantage that the treated water can be reused as heavy water immediately without additional treatment to maintain a highly clean water quality.

In addition, in the present invention, the anaerobic / anaerobic shift type reaction tank is operated alternately according to the time interval, but the inflow of raw water is continuously introduced and at the same time the treated water is continuously produced through the membrane filtration process in the aeration tank to maintain a high total amount of treated water. There is an advantage that it can.

The present invention can easily control the maintenance time and the internal circulation flow rate of the anaerobic / anaerobic process by adjusting the operating time of the internal transfer pump, and furthermore, the process configuration is simple by reducing the number of reactors and required pumps. It is economical because it can be processed continuously.

Claims (7)

As an advanced wastewater and wastewater treatment method for simultaneous treatment of nitrogen and phosphorus, in which an anoxic process for removing nitrogen and an anaerobic process for releasing phosphorus are alternately performed, The anoxic process, (A) introducing into the anaerobic / anaerobic alternating reactor in which anaerobic and anaerobic processes are alternately operated using sewage, sewage, or wastewater as inflow water; (B) operating an internal transfer pump that is operated intermittently to continuously transport the nitrate nitrogen generated in the aeration tank to make the anaerobic / anaerobic shift driving reactor anoxic; (C) converting the nitrate nitrogen supplied through the internal transport of step (b) into nitrogen gas by using the organic material in the continuously introduced inflow water as a carbon source; (D) flowing the denitrification-treated mixture in step (c) and flowing it into the subsequent aeration tank; Under the aerobic conditions of the aeration tank where the continuous aeration by blower, the process of nitrification converting organic nitrogen and ammonia nitrogen supplied from influent by nitrifying microorganism into nitrate nitrogen and oxidizing organic matter decomposing remaining organic matter (e); And It comprises a step (f) for continuously discharging the treated water using the immersion membrane installed in the aeration tank, The anaerobic process, Introducing sewage, sewage, or wastewater into the anoxic / anaerobic alternating reactor with continuous inflow (a '); Stopping the operation of the internal transfer pump that is intermittently operated to stop the internal transfer of nitrate nitrogen generated in the aeration tank to make the anaerobic / anaerobic shift driving reactor anaerobic (b '); (C ') releasing phosphorus to dephosphorized microorganisms by using organic matter in the continuously introduced influent water as a carbon source in an anaerobic state in which denitrification of nitrogen nitrate is depleted due to the stop of internal transport of step (b); (D ') overflowing the microorganisms having released phosphorus in the step (c') to a subsequent aeration tank; Under the aerobic conditions of the aeration tank where continuous aeration is carried out by the blower, the concentration of dissolved phosphorus in the aeration tank is reduced by the phosphorus excess intake of the phosphorus-releasing microorganism of the step (d '), and at the same time, organic nitrogen and (E ') a nitrification process for converting ammonia nitrogen to nitrate nitrogen and an organic matter oxidation process for decomposing the remaining organic matter; Continuously discharging the treated water from which phosphorus has been removed using an immersion membrane installed in the aeration tank (f '); And And a step (g ') of discharging the phosphorus of the over-ingested state of the phosphorus in the step (e'), The anaerobic process and the anaerobic process in the anaerobic / anaerobic shift driving reactor are classified according to the presence or absence of internal transport of nitrate nitrogen by adjusting the operating time of the internal transport pump. And anaerobic process shift driven membrane separation activated sludge process. delete The method of claim 1, The immersion type separation membrane for obtaining the treated water of step (f) of the anaerobic process and step (f ') of the anaerobic process is a microfiltration membrane or ultrafiltration membrane whose membrane is selected from flat membrane type, hollow fiber type or tubular type. And anoxic and anaerobic process alternating membrane separation activated sludge process for simultaneous treatment of phosphorus. The method of claim 1, Step (f) of the anaerobic process and step (f ') of the anaerobic process are characterized by using a suction pump in the membrane filtration to obtain the treated water from the immersion type membrane, or using a natural suction pressure due to water head difference And anoxic and anaerobic process alternating membrane separation activated sludge process for simultaneous treatment of phosphorus. delete delete delete