KR100377873B1 - Easily curable yellow soil composition - Google Patents
Easily curable yellow soil composition Download PDFInfo
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- KR100377873B1 KR100377873B1 KR10-2000-0040412A KR20000040412A KR100377873B1 KR 100377873 B1 KR100377873 B1 KR 100377873B1 KR 20000040412 A KR20000040412 A KR 20000040412A KR 100377873 B1 KR100377873 B1 KR 100377873B1
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- weight
- mixture
- ocher
- water
- floor
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- 239000000203 mixture Substances 0.000 title claims abstract description 58
- 239000002689 soil Substances 0.000 title claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000004568 cement Substances 0.000 claims abstract description 11
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 5
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims abstract description 5
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims abstract description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims abstract description 4
- 238000005336 cracking Methods 0.000 abstract description 2
- 238000001704 evaporation Methods 0.000 abstract description 2
- 230000008020 evaporation Effects 0.000 abstract description 2
- 238000010276 construction Methods 0.000 description 9
- 239000011449 brick Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 3
- 239000010902 straw Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 230000007407 health benefit Effects 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/10—Clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/045—Alkali-metal containing silicates, e.g. petalite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
- C04B22/08—Acids or salts thereof
- C04B22/14—Acids or salts thereof containing sulfur in the anion, e.g. sulfides
- C04B22/141—Acids
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/12—Nitrogen containing compounds organic derivatives of hydrazine
- C04B24/129—Compounds containing one or more nitrogen-to-nitrogen double bonds, e.g. azo-compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Floor Finish (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
본 발명은 수분증발로 인한 수축균열을 방지하기 위한 양생이 용이한 황토조성물에 관한 것으로서, 황토 97.6∼99.99 중량부 ; 수화알카리실리케이트와 카오린 1∼3 중량%, 디아조화나프타렌 4∼6 중량%, 설폰산 12∼16 중량%, 물 75∼83 중량%로 이루어진 혼합물 A 2.4∼0.01 중량부 ; 및 상기 혼합물 A의 중량기준으로 10∼1000배의 물과 시멘트 0.1∼100 중량%, 및 고화재 0.1∼10중량%를 혼합하여 이루어진 특징이 있다.The present invention relates to an easy to cure ocher composition for preventing shrinkage cracking due to evaporation of water, 97.6 to 99.99 parts by weight of ocher; 2.4 to 0.01 parts by weight of a mixture A consisting of 1 to 3% by weight of hydrated alkali silicate and kaolin, 4 to 6% by weight of diazotized naphthalene, 12 to 16% by weight of sulfonic acid, and 75 to 83% by weight of water; And 10 to 1000 times water, 0.1 to 100 wt% of cement, and 0.1 to 10 wt% of solidifying material, based on the weight of the mixture A.
Description
본 발명은 양생이 용이한 황토조성물에 관한 것으로 보다 상세하게는 황토의 수분제거로 인한 황토입자끼리의 결속으로 인하여 바닥에 수축균열이 발생하는 것을 없애기 위한 황토조성물에 시멘트와 고화재를 혼합하여 자연적으로 다짐/마감이 이루어지도록 한 양생이 용이한 황토조성물에 관한 것이다.The present invention relates to an ocher composition which is easy to cure. More specifically, it is natural to mix cement and solidified material in an ocher composition to eliminate the occurrence of shrinkage cracks at the bottom due to binding of the ocher particles due to the removal of moisture from the ocher. The present invention relates to an ocher composition that is easy to cure so that compaction / finish is achieved.
일반적으로 황토바닥 시공시에는 황토와 물과 짚을 썰어 넣어 혼합한 후 바닥에 혼합물을 고르게 바른후 미장을 하고 있다.In general, when constructing ocher floor, ocher, water and straw are cut and mixed, and then the mixture is evenly applied to the floor and then plastered.
그런데 상기와 같이 황토와 물과 짚을 썰어 혼합한 후 바닥에 황토미장을 했을 경우 수분증발로 인하여 바닥에 수축균열이 발생하므로서 강도도 약하고 미관상 좋지 않으며 온돌방인 경우 물 및 개스 누출의 위험마져 상존하게 되는 것이다.However, when the ocher and water and straw are cut and mixed as described above, when the ocher plastering is performed on the floor, shrinkage cracks occur on the floor due to evaporation of water, so the strength is weak and not aesthetically good. will be.
여기서 바닥이라함은 건축물의 온돌바닥, 비노출바닥, 노출바닥, 침대바닥 등을 말하며 비노출바닥이란 외부로 노출되지 않는 건물내의 바닥을 의미하고 노출바닥은 외부로 노출되는 옥상의 바닥 등을 의미한다.Here, the floor refers to the ondol floor, the non-exposed floor, the exposed floor, the bed floor, etc. of the building, and the non-exposed floor means the floor in the building that is not exposed to the outside, and the exposed floor refers to the rooftop floor that is exposed to the outside.
상기한 문제점을 감안하여 본 출원인의 대한민국특허출원 제97-19944호를 제안한바, 이는 황토에 수화알카리실리케이트와 카오린 1∼3 중량%, 디아조화나프타렌 4∼6 중량%, 설폰산 12∼16 중량%, 물 75∼83 중량의 혼합물(이하 혼합물 A라 한다)을 물과 배합하여 시공하는 황토바닥 시공방법 및 황토조성물이다.In view of the above problems, the applicant has proposed Korean Patent Application No. 97-19944, which is 1 to 3% by weight of hydrated alkali silicate and kaolin, 4 to 6% by weight of diazotized naphthalene, and 12 to 16 sulfonic acid. It is a loess bottom construction method and ocher composition which mix | blend with weight% and 75-83 weight of water (henceforth mixture A), and mix.
상기 본 출원인의 선출원 특허출원 제97-19944호는 바닥에 시공 후 15-20시간 경과후에 다짐마감하는 시공방법에 있어서 일반 주택에서는 적용가능하나 시공상에 많은 시간이 소요되는 문제점이 있고 또한 아파트와 같은 다층으로 이루어진 구조물에 있어서는 다층이라는 구조물의 특성상 시공중인 건물의 아래층에서는 울림이 발생되어 본의 아니게 소음공해를 일으켜 피해끼치는 문제점이 있었다.Applicant's prior application patent application No. 97-19944 is applicable to the general house in the construction method to compact after 15-20 hours after construction on the floor, but there is a problem that takes a lot of time in construction In the structure of the same multi-layer structure due to the nature of the multi-layer structure, the lower floor of the building under construction, the ringing is generated unintentionally causing noise pollution, there was a problem to damage.
본 발명은 상기한 문제점을 감하여 안출한 것으로 이의 목적은 자연적으로 다짐마감이 이루어짐과 짧은 시간에 양생이 이루어지는 양생이 용이한 황토조성물을 제공하는데 있다.The present invention has been made in view of the above problems, and an object thereof is to provide an easy-to-cure ocher composition which is naturally compacted and made in a short time.
상기 본 발명의 목적을 달성하기 위해서는 황토 97.6∼99.99 중량부 ; 수화알카리실리케이트와 카오린 1∼3 중량%, 디아조화나프타렌 4∼6 중량%, 설폰산 12∼16 중량%, 물 75∼83 중량%로 이루어진 혼합물A와; 상기 혼합물A 2.4∼0.01 중량부에 혼합물 A의 중량기준으로 10∼1000배의 물로 이루어진 황토조성물에 있어서, 상기 혼합물 A의 중량기준으로 시멘트 0.1∼100중량%를 혼합하여 이루어진 것을 특징으로 하는 양생이 용이한 황토조성물에 의하여 달성된다.To achieve the above object of the present invention, 97.6 to 99.99 parts by weight of ocher; A mixture A consisting of 1 to 3% by weight of hydrated alkali silicate and kaolin, 4 to 6% by weight of diazotized naphthalene, 12 to 16% by weight of sulfonic acid, and 75 to 83% by weight of water; In the ocher composition consisting of 10 to 1000 times the water by the weight of the mixture A 2.4 to 0.01 parts by weight of the mixture A, 0.1 to 100% by weight cement based on the weight of the mixture A Achieved by an easy ocher composition.
본 발명을 좀더 구체적으로 설명하면, 종래의 황토바닥 시공방법인 황토와 물과 짚을 혼합하여 시공할 경우 수축균열등이 일어나지만 본 발명에서는 황토가 함유하고 있는 수분을 분리시킴으로써 바닥시공시 수축 균열이 발생하는 것을 방지하기 위하여 혼합물 A를 일정비율로 물과 황토와 혼합하여 만든 혼합물에 시멘트를 혼합한 조성물로 바닥을 시공한후 소정시간이 경과되면 자연적으로 다짐/마감이 일어난다.When explaining the present invention in more detail, in the case of construction by mixing the ocher and water and straw, which is a conventional ocher floor construction method, shrinkage cracking occurs, but in the present invention, the shrinkage crack during the floor construction by separating the water contained in the loess In order to prevent the mixture A from being mixed with water and loess at a certain ratio, the cement is mixed with cement.
예컨대, 시멘트의 특성에 의하여 양생이 자연적으로 시간의 경과로 일어나는 것을 특징으로 한다.For example, due to the characteristics of the cement, the curing occurs naturally over time.
바람직하기로는 황토와 혼합물 A의 97.6∼99.99 : 2.4∼0.01 중량비의 배합물과 상기 혼합물 A의 중량기준으로 10∼1000배의 물을 함유하는 조성물을 골고루 혼합한 후 상기 혼합물을 건축물 바닥에 원하는 두께로 고르게 바르고 나면 시간이 경과됨과 동시에 자연히 양생이 일어나서 다져지는 효과가 발생된다.Preferably the mixture of ocher and a mixture of 97.6 to 99.99: 2.4 to 0.01 weight ratio of mixture A and a composition containing 10 to 1000 times water by weight of the mixture A is mixed, and then the mixture is mixed to the desired thickness on the floor of the building. After evenly applied, curing will occur naturally and the effect will be compacted over time.
혼합물A가 2.4 중량비를 초과할 경우 경제성이 떨어지고 0.01 중량비 미만일 경우에는 그 효과가 현저하게 떨어진다.If the mixture A exceeds 2.4 weight ratio, the economy is inferior, and if the mixture A is less than 0.01 weight ratio, the effect is remarkably decreased.
본 발명에 속하는 황토조성물은 건축물의 바닥뿐만아니라 황토침대,레니탈에도 사용되어 질 수 있다.The ocher composition pertaining to the present invention can be used not only for the floor of a building but also for an ocher bed and a renal.
본 발명의 범위에 속하는 황토와 혼합물 A와 물이 혼합된 황토조성물을 공지의 벽돌이나 블록의 형틀에 넣고 압착하여 벽돌이나 블록을 제조할 경우 잘 깨지지 않거나 부서지지 않는 단단한 벽돌이나 블록을 제조할 수 있다.When the ocher composition mixed with ocher, mixture A, and water falling within the scope of the present invention is put into a mold of a known brick or block and pressed to produce a brick or block, a hard brick or block that is not easily broken or broken can be produced. have.
또한, 본 발명의 황토조성물에 적당량의 모래, 운모, 장석, 맥반석, 청맥반석 등의 세골재를 첨가하면 황토의 건강상의 이점이 상승작용을 한다.In addition, when the appropriate amount of fine aggregates such as sand, mica, feldspar, elvan, and blue lattice are added to the ocher composition of the present invention, the health benefits of ocher are synergistic.
한편, 본 발명의 황토조성물에 경량골재를 혼합하여 상기 벽돌이나 블럭을 제조시 무게를 현저히 가볍게 할 수도 있다.On the other hand, by mixing the lightweight aggregate in the ocher composition of the present invention may be significantly lighter weight when manufacturing the brick or block.
한편 상기 항토와 혼합물A를 섞은 상태에서 여기에 시멘트를 혼합하여 사용할 수도 있지만 상기 혼합물A와 시멘트의 혼합물에 고화재를 혼합하여 사용할 수도 있다.On the other hand, in the state in which the soil mixture and mixture A may be mixed with cement, it may be used by mixing a solid material in the mixture of the mixture A and cement.
상기 고화재의 비율은 혼합물A 2.4∼0.01 중량부에 혼합물 A의 중량기준으로 0.1∼10중량%로혼합하며 이때에는 팽창성에 의한 강도증진, 지질안정 및 엔트린자이드(3CaO·Al2O3·CaSO4·32H2O)를 형성하는 제품이 바람직하다.The ratio of the solidified material is mixed in an amount of 0.1 to 10% by weight based on the weight of the mixture A in 2.4 to 0.01 parts by weight of the mixture A. At this time, the strength is increased due to expandability, lipid stability and entrinzide (3CaO · Al 2 O 3 · Products which form CaSO 4 32H 2 O) are preferred.
이하, 본 발명을 실시예에 의거하여 보다 상세하게 설명하기로하며 본 발명은 실시예에 한정하는 것은 아니다. 아래 실시예의 혼합물A 구성은 수화알카리실 리케이트와 카오린 2%, 디아조화나프타렌 5%, 설폰산 14%, 물 79%로 이루어진 혼합물을 사용하였다.Hereinafter, the present invention will be described in more detail with reference to Examples, and the present invention is not limited to Examples. The mixture A of the examples below used a mixture consisting of hydrated alkali silicate and kaolin 2%, diazonaphtharen 5%, sulfonic acid 14%, and water 79%.
〈실시예 1〉<Example 1>
건축물 바닥을 시공함에 있어서 황토 980kg, 혼합물A 10kg, 물 120kg, 시멘트 2kg의 황토조성물을 충분히 혼합한 후 바닥에 골고루 시공한 후 파괴하중, 압축강도를 측정한바, 아래와 같이 측정됨을 알 수 있었다.When constructing the floor of the building, it was found that the yellow soil composition of 980kg, mixture A 10kg, water 120kg, cement 2kg was mixed well and then evenly installed on the floor, and then the fracture load and compressive strength were measured.
〈실시예 2〉<Example 2>
황토 990kg, 혼합물 A 5kg, 물 80kg, 시멘트2kg의 황토조성물을 충분히 혼합한 후 벽돌 혹은 블록형틀에 넣고 압착하여 벽돌과 블록을 제조한 후 길이변화율, 부착강도, 흡수율, 압착강도를 측정한바, 아래와 같이 측정됨을 알 수 있었다.Ocher 990kg, Mixture A 5kg, Water 80kg, Cement 2kg ocher composition is sufficiently mixed, put into a brick or block mold and pressed to produce a brick and block, and then measured the length change rate, adhesion strength, absorption rate, compressive strength, It can be seen that it is measured together.
이상 설명한 바와 같이 본 발명에 의한 황토조성물 및 황토바닥 시공방법은 혼합물 A를 황토 및 물과 함께 혼합하기 때문에 건조 경과 후에 발생되는 수축으로 인한 균열을 방지하므로써 온돌방인 경우 물 및 가스의 누출을 방지하며 미관상으로도 훌륭한 효과를 발휘한다.As described above, the ocher composition and the ocher bottom construction method according to the present invention mix the mixture A together with the ocher and the water, thereby preventing the leakage of water and gas in the ondol room by preventing cracks caused by shrinkage that occurs after the drying process. Aesthetically good effect.
또한 황토입자의 조밀한 결합으로 인하여 힘을 가해도 잘 깨지지 않는 바닥이나 벽돌 혹은 블록을 제조할 수가 있다.In addition, due to the dense bonding of ocher particles, it is possible to produce floors, bricks, or blocks that are hard to be broken even by applying force.
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| KR10-2000-0040412A KR100377873B1 (en) | 2000-07-14 | 2000-07-14 | Easily curable yellow soil composition |
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| KR10-2000-0040412A KR100377873B1 (en) | 2000-07-14 | 2000-07-14 | Easily curable yellow soil composition |
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| KR100377873B1 true KR100377873B1 (en) | 2003-03-29 |
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| KR101064560B1 (en) * | 2010-02-22 | 2011-09-15 | 경상대학교산학협력단 | Permeable colorless concrete pavement composition using activated kaolin and concrete pavement construction method using the same |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1191207A (en) * | 1996-06-03 | 1998-08-26 | 乔希海 | Method for producing earth for works from flyash and alkali residue |
| KR100209168B1 (en) * | 1997-05-22 | 1999-07-15 | 임병국 | Loess composition and loess floor construction method |
| KR100233157B1 (en) * | 1997-11-21 | 1999-12-01 | 김봉경 | Manufacturing method of brick with yellow clay and polymeric binder |
| KR100239134B1 (en) * | 1997-11-08 | 2000-01-15 | 김성모 | Manufacturing method of ocher board |
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2000
- 2000-07-14 KR KR10-2000-0040412A patent/KR100377873B1/en not_active IP Right Cessation
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1191207A (en) * | 1996-06-03 | 1998-08-26 | 乔希海 | Method for producing earth for works from flyash and alkali residue |
| KR100209168B1 (en) * | 1997-05-22 | 1999-07-15 | 임병국 | Loess composition and loess floor construction method |
| KR100239134B1 (en) * | 1997-11-08 | 2000-01-15 | 김성모 | Manufacturing method of ocher board |
| KR100233157B1 (en) * | 1997-11-21 | 1999-12-01 | 김봉경 | Manufacturing method of brick with yellow clay and polymeric binder |
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