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KR100322497B1 - Emulsion Composition for moisturizing skin and Preparation thereof - Google Patents

Emulsion Composition for moisturizing skin and Preparation thereof Download PDF

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Publication number
KR100322497B1
KR100322497B1 KR1019990003075A KR19990003075A KR100322497B1 KR 100322497 B1 KR100322497 B1 KR 100322497B1 KR 1019990003075 A KR1019990003075 A KR 1019990003075A KR 19990003075 A KR19990003075 A KR 19990003075A KR 100322497 B1 KR100322497 B1 KR 100322497B1
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dimethicone
weight
moisturizing
water
emulsion composition
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KR20000052172A (en
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지홍근
서봉석
이윤희
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임충헌
한국화장품주식회사
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/895Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

본 발명은 보습기능을 가지는 에멀젼 조성물 및 그 제조방법에 관한 것으로서, 디메치콘/비닐디메치콘 크로스 폴리머 0.1-2중량%, 싸이크로메치콘/디메치콘 5-10중량%, 세칠 디메치콘 코폴리올 1-5중량% 및 적량의 물을 포함하는 보습기능을 가지는 에멀젼 조성물을 제공하고, 디메치콘/비닐디메치콘 크로스 폴리머와 오일에 용해되는 성분을 유상성분을, 정제수에 용해되는 성분을 수상성분으로하여 상온에서 유상성분에 수상성분을 아주 천천히 첨가하면서 믹서로 균질 혼합하는 유화공정을 거친 후, 탈포공정을 거쳐 제조하는 것을 특징으로 하며, 이와 같이 제조된 에멀젼은 각질세포에 매우 빠르게 침투하여 각질세포간 지질내의 보습, 각질세포내 보습, 수분보유능력의 보습막을 형성하는 것으로 보습능력이 우수하다.The present invention relates to an emulsion composition having a moisturizing function and a method for preparing the same, 0.1-2% by weight of dimethicone / vinyldimethicone cross polymer, 5-10% by weight of cyclomethicone / dimethicone, sechil dimethicone copolyol 1 To provide an emulsion composition having a moisturizing function comprising -5% by weight and an appropriate amount of water, the dimethicone / vinyl dimethicone cross-polymers and components dissolved in oil as an oil phase component, the component dissolved in purified water as an aqueous phase component At room temperature, the aqueous phase component is added to the oil phase component very slowly, followed by an emulsification process of homogeneous mixing with a mixer, followed by a defoaming process. The emulsion prepared thus penetrates keratinocytes very quickly and is interstitial. It is excellent in moisturizing ability by forming a moisturizing membrane of moisturizing in lipids, moisturizing in keratinocytes, and water retention ability.

Description

피부보습용 에멀젼 조성물 및 그 제법{Emulsion Composition for moisturizing skin and Preparation thereof}Emulsion Composition for moisturizing skin and Preparation

본 발명은 보습력이 우수한 에멀젼 조성물에 관한 것으로, 특히 디메치콘/비닐디메치콘 크로스 폴리머를 사용하여 소정의 방법으로 제조한 피부보습용 에멀젼 조성물 및 그 제조방법에 관한 것이다.디메치콘/비닐디메치콘 크로스 폴리머는 메칠폴리실록산으로부터 형성되는 레진 파우더와 디메칠실록산으로 구성된 퍼스널 케어용 메칠폴리실록산 파우더이다. 레진파우더는 고경도를 지닌 분체로서 분체용 화장품에 적용하는 경우 윤활성과 퍼짐성을 부여하는 것이고, 디메치콘/비닐디메치콘 크로스 폴리머는 탄력성을 지닌 분체로, 화장품에 적용시 피부에 매끄러움을 부여하고 제품의 퍼짐성을 향상시키는 기능을 하는 것으로 알려져 있다. 이 디메치콘/비닐디메치콘 크로스 폴리머는 다른 화장품용 흡유물질에 비하여 오일과 물의 흡유성이 매우 뛰어나다.상기 디메치콘/비닐디메치콘 크로스 폴리머의 오일 및 물의 흡유성(단위 : g/100mg)은 다음과 같다.물: 50리퀴드 파라핀 : 72스쿠알렌 : 67이소세틸 알콜 : 35싸이크로메치콘 : 83The present invention relates to an emulsion composition having excellent moisturizing properties, and more particularly to an emulsion composition for moisturizing skin prepared by a predetermined method using dimethicone / vinyl dimethicone cross polymer and a method for producing the same. The polymer is a methylpolysiloxane powder for personal care composed of resin powder and dimethylsiloxane formed from methylpolysiloxane. Resin powder is a powder with high hardness that imparts lubricity and spreadability when applied to cosmetics. Dimethicone / Vinyl Dimethicone Cross Polymer is an elastic powder that gives skin smoothness when applied to cosmetics. It is known to have a function of improving the spreadability. This dimethicone / vinyl dimethicone cross polymer has excellent oil and water absorption properties compared to other cosmetic oil absorbents. The oil and water absorption of the dimethicone / vinyl dimethicone cross polymer (unit: g / 100mg) is as follows. Water: 50 Liquid Paraffin: 72 Squalene: 67 Isocetyl Alcohol: 35 Cymethicone: 83

본 발명은 상기한 디메치콘/비닐디메치콘 크로스 폴리머가 가지는 특유의 성질을 이용하여, 기존의 화장품에 비해 미끌거리는 느낌을 줄이고, 보다 신선하고 상괘한 질감을 가지는 화장품용 에멀젼을 제공하는 것을 목적으로 한다.The present invention, by using the unique properties of the dimethicone / vinyl dimethicone cross polymer described above, to reduce the slippery feeling compared to conventional cosmetics, and to provide a cosmetic emulsion having a fresher and more pleasant texture. do.

도1은 본 발명에 의한 젤 에멀젼이 피부위에서 물방울을 형성하는 사진,도2는 일반 크림과 본 발명의 에멀젼 조성물로 이루어진 젤 크림의 사진,도3은 일반크림과 본 발명의 에멀젼 조성물로 이루어진 젤 크림의 보습력을 비교한 그래프,도4는 본 발명에 의한 젤 크림을 바르기 전과 바른 후에 이미지 분석기(IMAGE ANALYZER)로 피부이미지를 나타낸 사진,도5는 본 발명에 의한 물방울 젤 크림의 입자를 나타낸 사진,도6은 일반 크림과 본 발명에 의한 젤 크림의 피부경피 수분손실도를 나타낸 그래프이다.1 is a photograph of the gel emulsion according to the present invention to form water droplets on the skin, Figure 2 is a photograph of a gel cream consisting of a general cream and an emulsion composition of the present invention, Figure 3 is a gel consisting of a general cream and an emulsion composition of the present invention Figure 4 is a graph comparing the moisturizing power of the cream, Figure 4 before and after applying the gel cream according to the invention the image showing the skin image with the image analyzer (IMAGE ANALYZER), Figure 5 is a photo showing the particles of the water droplet gel cream according to the present invention 6 is a graph showing the dermal transdermal moisture loss of the normal cream and gel cream according to the present invention.

본 발명에 의한 에멀젼 조성물은 디메치콘/비닐디메치콘 크로스 폴리머 0.1-2중량%, 사이크로메치콘/디메치콘 5-10중량%, 세칠 디메치콘 코폴리올 1-5중량% 및 물을 포함하고 있는 것을 특징으로 한다.상기 디메치콘/비닐디메치콘 크로스 폴리머는 상업적으로 이미 제조판매되고 있는 것을 사용한다. 가능한 입수처로는 제품명 'KSG-21'(SHINETSU 社 제조), 제품명 'Silicone S-1064'(일본 코마 社 제조), 제품명 'E-560C'(다우코닝社 제조)등이다.본 발명에 의한 에멀젼 조성물의 일 형태로서,디메치콘/비닐디메치콘 크로스 폴리머 0.1-2중량%, 사이크로메치콘/디메치콘 5-10중량%, 세칠 디메치콘 코폴리올 1-5중량%, 일반적인 미용성분(예:히아트론산, 사카라이드 이소머레이트 등) 약 1-10중량% 및 적량의 정제수를 혼합하면 젤 타입의 조성물을 얻을 수 있다.상기 물은 일반수돗물, 정제수, 온천수, 샘물, 생수, 약수, 미네랄을 함유한 물, 미용성분을 함유한 물등이 모두 사용될 수 있다.도 1은 상기 조성범위 내에서 젤 형태의 조성물을 제조하고, 이를 피부위에 바른후 문지른 후의 현상을 나타낸 사진이다. 도1에서 사진으로 보는 바와 같이 피부 상에 상당히 많은 미세한 물방울이 형성되는 것을 볼 수 있다.그리고, 도2는 본 발명에 의한 에멀젼 조성물과 일반크림의 미세구조상의 차이점을 보인 것이다. 이 도면에서 보는 바와 같이, 본 발명에 의한 조성물의 경우, 디메치콘/비닐디메치콘 크로스 폴리머는 일반크림에 비해 아주 미세한 다차원의 그물망이 피부를 감싸고 수분증발을 막아줌으로써, 피부 깊숙히 수분을 공급하여 피부가 오랫동안 촉촉해 지게 한다.본 발명에 의한 에멀젼 조성물은 여러가지 제형을 취하여 보습 화장품으로써 응용될 수 있다.예를 들어, 디메치콘/비닐디메치콘 크로스 폴리머(예: SHINETSU 社의 KSG-21 또는 일본코마 社의 Silicone S-1064 등) 0.1-2중량%, 디메치콘 또는 사이크로메치콘/디메치콘 5 - 10중량 %, 선택적으로 세칠 디메치콘 코폴리올 1-5중량%, 미용성분 1~10중량 % 및 적량의 정제수를 혼합하여 젤 타입의 크림을 제조할 수 있다.또한, 디메치콘/비닐디메치콘 크로스 폴리머 0.1-2중량%, 싸이크로메치콘/디메치콘 5-10중량%, 세칠 디메치콘 코폴리올 1-5중량%, 미용성분 1-10중량%에 더하여 , 수용성 이산화티탄 1-5중량%, 안료 0.5-2중량%, 글리세린 1-5중량%에 적량의 정제수를 혼합하면 메이크업 베이스를 얻을 수 있다.또한, 디메치콘/비닐디메치콘 크로스 폴리머 0.1-2중량%, 싸이크로메치콘/디메치콘 5-10중량%, 세칠 디메치콘 코폴리올 1-5중량%, 유기,무기자외선 차단제 1-10중량%, 안료 0.5-2중량%, 미용성분 1-10중량%, 글리세린 1-5중량%에 적량의 정제수를 혼합하여 선크림을 제조할 수 있다.이러한 조성물의 혼합방법은, 디메치콘/비닐디메치콘 크로스 폴리머와 오일에 용해되는 성분(예:사이크로메치콘, 디메치콘, 유기/무기 자외선 차단제 등)인 유상성분에 정제수에 용해되는 성분(예: 글리세린, 미용성분 등)을 상온에서 아주 천천히 첨가하면서 믹서로 균질 혼합하는 유화공정 및 탈포공정(진공압을 거는 등의 방법에 의해 이러한 혼합과정에서 발생되는 기포를 제거하는 공정)에 의한다.도3은 일반크림과 본 발명에 의한 에멀젼 조성물로 이루어진 젤 크림의 보습력을 비교한 그래프이다. 이는 각각의 크림을 바른후, 보습력 측정장치(CORNEOMETER CM820)으로 측정한 결과본 발명에 의한 젤 크림의 보습력이 우수함을 알 수 있다.도4는 본 발명에 의한 에멀젼 조성물로 이루어진 젤 크림을 바르기 전과 바른 후에 이미지 분석기(IMAGE ANALYZER)로 피부이미지 나타낸 사진이다. 이미지 분석기는 SCOPEMAN MS-803를 사용하였다. 본 발명에 의한 에멀젼 조성물로 이루어진 젤 크림을 바르기 전과 바른 1주일후의 사진에서, 본 발명에 의한 에멀젼 조성물로 이루어진 젤 크림을 바르기 전의 각질이 바른 후의 사진에서는 완전히 없어 졌음을 알 수 있다.도5는 본 발명에 의한 에멀젼 조성물로 이루어진 젤 크림의 입자사진을 나타낸 사진이다(OLYMPUS BH2로 400배로 확대).도6은 일반 크림과 본 발명에 의한 에멀젼 조성물로 이루어진 물방울 젤 크림의 피부경피 수분손실도를 나타낸 그래프로서, 각각의 크림을 바른 후, 수분손실 측정장치(TEWAMETER TM210)으로 측정하였다. 도면에 나타낸 바와 같이, 일반 크림에 비해 본 발명에 의한 에멀젼 조성물로 이루어진 물방울 젤 크림이 경피 수분손실도가 적다는 것을 알 수 있다.The emulsion composition according to the present invention contains 0.1-2% by weight of dimethicone / vinyldimethicone cross polymer, 5-10% by weight of cyclomethicone / dimethicone, 1-5% by weight of sechil dimethicone copolyol and water The dimethicone / vinyl dimethicone cross polymer uses a commercially manufactured and sold product. Possible sources include the product name 'KSG-21' (manufactured by Shinnetsu), the product name 'Silicone S-1064' (manufactured by Koma Japan), and the product name 'E-560C' (manufactured by Dow Corning). As one form of the composition, 0.1-2% by weight of dimethicone / vinyldimethicone cross polymer, 5-10% by weight of cyclomethicone / dimethicone, 1-5% by weight of cecil dimethicone copolyol, general cosmetic ingredients (e.g., hya About 1-10% by weight of tronic acid, saccharide isomerate, etc.) and an appropriate amount of purified water can be mixed to obtain a gel-type composition. The water is purified from general tap water, purified water, hot spring water, spring water, bottled water, weak water, and minerals. Water containing, water containing a cosmetic ingredient, etc. can all be used. FIG. 1 is a photograph showing the phenomenon after preparing a gel-like composition within the above composition range, and rubbing it on the skin. As shown in the photograph in Figure 1 it can be seen that a lot of fine water droplets are formed on the skin. And, Figure 2 shows the difference in the microstructure of the emulsion composition and the general cream according to the present invention. As shown in this figure, in the case of the composition according to the present invention, the dimethicone / vinyl dimethicone cross polymer has a very fine multi-dimensional mesh netting the skin and prevents water evaporation, compared to the general cream, thereby supplying moisture deep into the skin The emulsion composition according to the present invention can be applied as a moisturizing cosmetic by taking various formulations. Silicone S-1064, etc.) 0.1-2% by weight, 5-10% by weight of dimethicone or cyclomethicone / dimethicone, optionally 1-5% by weight of dimethicone copolyol, 1-10% by weight of cosmetic ingredients and the appropriate amount It is also possible to prepare a gel-type cream by mixing purified water of the present invention. In addition, 0.1-2% by weight of dimethicone / vinyldimethicone cross polymer, 5-10% by weight of micromethicone / dimethicone, and fine In addition to 1-5% by weight of methicone copolyol and 1-10% by weight of cosmetic ingredients, 1-5% by weight of water-soluble titanium dioxide, 0.5-2% by weight of pigment, and 1-5% by weight of glycerin make up a suitable amount In addition, 0.1-2% by weight of dimethicone / vinyldimethicone cross polymer, 5-10% by weight of cyclomethicone / dimethicone, 1-5% by weight of sechil dimethicone copolyol, organic and inorganic ultraviolet rays A sunscreen may be prepared by mixing a suitable amount of purified water with 1-10% by weight of a blocking agent, 0.5-2% by weight of a pigment, 1-10% by weight of a cosmetic ingredient, and 1-5% by weight of glycerin. Chicon / vinyldimethicone cross-polymer and oil-soluble components (e.g. cyclomethicone, dimethicone, organic / inorganic sunscreen, etc.) dissolved in purified water (e.g. glycerin, cosmetics, etc.) at room temperature Process and defoaming process for homogeneous mixing in a mixer with very slow addition It depends on (vacuum process to remove air bubbles generated from this mixing process by a method such as placing the air pressure). Fig. 3 is a graph comparing the moisture in the gel cream consisting of an emulsion composition according to the present invention and general cream. After applying each cream, it was found that the moisturizing power of the gel cream according to the present invention is excellent as a result of measuring by a moisturizing power measuring device (CORNEOMETER CM820). After applying it, it shows the skin image with IMAGE ANALYZER. Image analyzer was used SCOPEMAN MS-803. In the photograph before and after 1 week of applying the gel cream of the emulsion composition according to the present invention, it can be seen that in the photograph after applying the keratin before applying the gel cream of the emulsion composition according to the present invention, completely disappeared. Particle photo of the gel cream consisting of the emulsion composition according to the present invention (photo 400 times magnified with OLYMPUS BH2). Figure 6 shows the dermal transdermal moisture loss of the gel cream consisting of a normal cream and the emulsion composition according to the present invention. As the graph shown, after applying each cream, it was measured by a water loss measuring apparatus (TEWAMETER TM210). As shown in the figure, it can be seen that the water droplet gel cream composed of the emulsion composition according to the present invention has a lower percutaneous moisture loss than the general cream.

이제까지 설명한 바와 같이, 본 발명에 의한 에멀젼 조성물은 디메치콘/비닐디메치콘 크로스 폴리머 0.1-2중량%, 싸이크로메치콘/디메치콘 5-10중량%, 세칠 디메치콘 코폴리올 1-5중량% 및 적량의 물을 포함하는 것을 틀징으로 하는 보습기능을 가지는 에멀젼 조성물은 일반 화장품에 비해 보습력, 수분 손실도등이 매우 우수하다는 효과가 있다.As described so far, the emulsion composition according to the present invention comprises 0.1-2% by weight of dimethicone / vinyldimethicone cross polymer, 5-10% by weight of cyclomethicone / dimethicone, 1-5% by weight of sechil dimethicone copolyol and Emulsion composition having a moisturizing function containing the appropriate amount of water has an effect that is very excellent in moisturizing power, moisture loss degree and the like compared to general cosmetics.

Claims (2)

디메치콘/비닐디메치콘 크로스 폴리머 0.1-2중량%, 싸이크로메치콘/디메치콘 5-10중량%, 세칠 디메치콘 코폴리올 1-5중량% 및 적량의 물을 포함하는 것을 틀징으로 하는 보습기능을 가지는 에멀젼 조성물.Moisturizing function of containing 0.1-2 weight% of dimethicone / vinyl dimethicone cross polymer, 5-10 weight% of cyclomethicone / dimethicone, 1-5 weight% of Secyl dimethicone copolyol, and an appropriate amount of water Emulsion composition having a. 디메치콘/비닐디메치콘 크로스 폴리머 0.1-2중량%, 싸이크로메치콘/디메치콘 5-10중량%, 세칠 디메치콘 코폴리올 1-5중량% 등의 유상성분에, 물에 용해되는 성분을 상온에서 천천히 첨가하면서 믹서로 균질 혼합하는 유화공정을 거친 후, 탈포공정을 거쳐 제조하는 것을 특징으로 하는 물방울을 형성하는 에멀젼의 제조방법.Components dissolved in water in oil phase components such as 0.1-2% by weight of dimethicone / vinyl dimethicone cross polymer, 5-10% by weight of cyclomethicone / dimethicone, and 1-5% by weight of Sequil dimethicone copolyol Method for producing an emulsion to form a water droplet, characterized in that after the addition step in the homogeneous mixing in a mixer homogeneously mixed, and then subjected to a defoaming step.
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