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KR100205907B1 - Spun yarn with excellent heat resistance - Google Patents

Spun yarn with excellent heat resistance Download PDF

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Publication number
KR100205907B1
KR100205907B1 KR1019940014353A KR19940014353A KR100205907B1 KR 100205907 B1 KR100205907 B1 KR 100205907B1 KR 1019940014353 A KR1019940014353 A KR 1019940014353A KR 19940014353 A KR19940014353 A KR 19940014353A KR 100205907 B1 KR100205907 B1 KR 100205907B1
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South Korea
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fiber
yarn
heat resistance
excellent heat
spun yarn
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KR1019940014353A
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KR960001239A (en
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최상렬
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구광시
주식회사코오롱
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    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • D02G3/047Blended or other yarns or threads containing components made from different materials including aramid fibres
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/12Threads containing metallic filaments or strips
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/16Yarns or threads made from mineral substances
    • D02G3/18Yarns or threads made from mineral substances from glass or the like
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • D02G3/443Heat-resistant, fireproof or flame-retardant yarns or threads

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Abstract

본 발명은 금속섬유 스테이플과 아라미드섬유 스테이플을 일정비율로 혼면한 것을 방적사의 외층으로 하고 무기섬유 필라멘트를 방적사의 내층에 구성시킨 것을 특징으로 하는 내열성이 우수한 방적사에 관한 것으로, 고온하에서 작업되어지는 철강산업이나 유리산업 또는 내열성 및 강도 등이 요구되어지는 마찰재 산업분야에 사용되어질 수 있다.The present invention relates to a spun yarn having excellent heat resistance, characterized in that a blend of metal fiber staples and aramid fiber staples in a certain ratio is formed as the outer layer of the yarn, and an inorganic fiber filament is formed on the inner layer of the yarn. It can be used in the industrial or glass industry or in the friction material industry where heat resistance and strength are required.

Description

내열성이 우수한 방적사Spun yarn with excellent heat resistance

본 발명은 내열성이 우수한 방적사에 관한 것으로서, 더욱 상세하게는 2종류로 구성되는 섬유소재의 스테이플과 필라멘트사에 의해 내열성, 강도, 인체에 대한 안정성을 가지는 내열성이 우수한 방적사의 제조에 관한 것이다. 종래에는 이러한 산업분야의 내열소재를 주로 석면사를 상요한 석면직물이 쓰여서 왔으나, 석면의 인체에 대한 유해성이 알려짐에 따라 점차 법적규제가 심화되고 있는 실정이다.The present invention relates to a spun yarn having excellent heat resistance, and more particularly, to the production of a spun yarn having excellent heat resistance, strength and stability to human body by staple and filament yarn of two kinds of fiber materials. Conventionally, asbestos fabrics mainly used asbestos yarns have been used as heat-resistant materials in these industrial fields, but legal regulations are gradually intensified as the harmfulness of asbestos is known to the human body.

따라서 석면을 대체하기 위한 많은 연구개발이 진행되고 있고, 대체소재도 많이 나오고 있다. 이러한 석면에 대한 대체 소재로서 일반적으로 금속섬유 등이 많이 제안되고 있으나 금속섬유는 그 강직성 때문에 스테이플, 합연 또는 제직 등 섬유소재로서 제품화하기 어렵다. 이를 개선하기 위해 금속섬유와 다른 섬유 소재를 혼면하여 제직한 직물로 만들어 사용해 보기도 했으나 화원(火源)에 접근시, 금속섬유 이외의 다른 섬유부분이 인화되어 탄화되거나 취약해져 강도 저하의 원인이 되는 문제점이 발생했다. 따라서 본 발명은 상기와 같은 문제점을 개선할 수 있는 특성을 가진 여러가지 섬유소재를 조합하여 혼면을 만들고, 이러한 혼방사로 제직하여 만든 직물을 사용하면 상기 용도 분야에서 요구하는 성능과 인체에 대해서도 안정성을 확보할 수 있다는 점에 착안하여 우수한 내열성 및 강도와 안정성을 가지는 전방향족 폴리아미드섬유(이하, 아라미드섬유)를 혼면한 방적사를 제조하였다. 이하, 본 발명을 상세하게 설명하면 다음과 같다. 본 발명은 금속섬유 스테이플과 아라미드섬유 스테이플을 일정비율로 혼면한 것을 방적사의 외층으로 하고 무기섬유 필라멘트를 방적사의 내층에 구성시킨 것을 특징으로 하는 내열성이 우수한 방적사에 관한 것이다. 이하 본 발명을 더욱 상세하게 설명하면 다음과 같다. 본 발명은 금속섬유와 아라미드섬유의 스테이플을 외층으로 하고, 무기섬유인 유리섬유 또는 탄소섬유의 필라멘트사를 내층으로 하여 마찰방적기를 이용하여 제조된 다성분으로 구성되는 혼방사이다. 여기서 사용하는 금속섬유는 세라믹섬유나 스텐레스스틸섬유이고 아라미드섬유는 전방향족 폴리아미드의 메타계 또는 파라계 섬유이다. 스테이플로 만들때의 길이는 금속섬유의 경우는 40∼150㎜이고, 아라미드 섬유의 경우는 30∼65㎜인데, 이 길이 범위를 벗어나면 가방성(可紡性)이 불량해지며 특히, 금속섬유는 그 강직성 때문에 길이가 짧아질수록 혼면시 아라미드 스테이플과의 결속력이 떨어질 수 있다. 그리고 금속섬유와 아라미드섬유의 스테이플 혼합비율은 금속섬유 65 ∼ 85 중량%와 아라미드 섬유 15 ∼ 35 중량%로 구성되게 하는데 아라미드 섬유가 고가이기 때문에 가능한 적게 사용하는 것이 좋겠지만 아라미드 섬유가 15중량% 미만일 경우, 방적성이 불량해질 수 있다. 이러한 길이 및 비율로 혼합되는 금속섬유와 아라미드 섬유의 스테이플을 방적하여 혼면으로 만드는 것을 통상의 제조방법에 의한다. 이렇게 제조되어진 혼면은 무기섬유 필라멘트, 즉 유리섬유 또는 탄소섬유의 필라멘트사와 같이 마찰방적기에 투입하여 혼면이 외층으로, 필라멘트사가 내층으로 구성되게한다. 마찰방적기는 페라(fecher)사 제품을 사용했으며, 여기서 내층에 무기섬유 필라멘트사르 넣는 이유는 제품의 강도와 형태 안정성을 추구하기 위한 것인데 유리섬유나 탄소섬유는 그 내열성 및 높은 탄성율을 가지고 있는 섬유소재이기 때문이다. 또한, 혼면을 외층으로 하는 이유는 직물의 촉감 및 염색성을 부여하기 위함이다. 이렇게 제조되어지는 혼방사의 굵기는 제품의 용도에 따라 제조될 수 있다. 또한 상기의 혼방사를 합연사 또는 단사로 하고 용도에 따른 조직설계로 제작하면, 내열성이 우수한 직물을 얻을 수 있게 된다. 본 발명에 의해 제조되는 내열성이 우수한 방적사는 고온하에서 작업 되어지는 철강산업이나 유리산업 또는 내열성 및 강도 등이 요구되어지는 마찰재 산업분야에 사용되어질 수 있다. 이하, 본 발명을 실시예를 통하여 더욱 구체적으로 설명하겠는 바, 실시예에 의하여 본 발명이 한정되는 것은 아니다.Therefore, a lot of research and development is in progress to replace asbestos, and a lot of substitute materials are also coming out. In general, metal fibers and the like have been proposed as alternative materials for such asbestos, but due to its rigidity, metal fibers are difficult to be commercialized as fiber materials such as staples, joints, or weaving. In order to improve this, we have used a combination of woven metal fabric and other textile materials, but when we approach the fire source, other parts of the fiber other than the metal fiber ignite and become carbonized or vulnerable. A problem has occurred. Therefore, the present invention is to make a blended surface by combining a variety of fiber materials having the characteristics that can improve the above problems, using a fabric made by blended yarns such as to ensure the stability and performance for the human body required in the field of use In view of the fact that it can be made, a spun yarn blended with wholly aromatic polyamide fibers (hereinafter, aramid fibers) having excellent heat resistance, strength, and stability was prepared. Hereinafter, the present invention will be described in detail. The present invention relates to a spun yarn having excellent heat resistance, characterized by blending a metal fiber staple and an aramid fiber staple at a predetermined ratio as an outer layer of a yarn of yarn and forming an inorganic fiber filament in an inner layer of a yarn of yarn. Hereinafter, the present invention will be described in more detail. The present invention is a mixed yarn composed of a multicomponent manufactured by using a friction spinning machine using a staple of metal fibers and aramid fibers as an outer layer, and a filament yarn of inorganic fiberglass or carbon fibers as an inner layer. Metallic fibers used herein are ceramic fibers or stainless steel fibers, and aramid fibers are meta-based or para-based fibers of wholly aromatic polyamides. The length of the staples is 40-150 mm for metal fibers and 30-65 mm for aramid fibers. Outside of this length, bagability becomes poor, especially metal fibers. Because of its rigidity, the shorter the length, the lower the binding strength with aramid staples when blending. In addition, the staple mixing ratio of the metal fiber and the aramid fiber is composed of 65 to 85% by weight of the metal fiber and 15 to 35% by weight of the aramid fiber. In this case, the spinning property may be poor. The staples of metal fibers and aramid fibers mixed in such a length and proportion are spun into a mixed surface according to a conventional manufacturing method. The blended cotton thus prepared is fed into a friction spinning machine such as an filament yarn of an inorganic fiber filament, ie, glass fiber or carbon fiber, so that the blended surface is composed of an outer layer and the filament yarn is composed of an inner layer. The friction spinning machine uses a product made by Fercher, and the reason why the inorganic fiber filament yarn is put in the inner layer is to pursue the strength and form stability of the product. Glass fiber or carbon fiber is a fiber material which has heat resistance and high elastic modulus. Because it is. In addition, the reason why the blended surface is the outer layer is to impart the feel and dyeing of the fabric. The thickness of the blended yarn thus produced may be prepared according to the use of the product. In addition, when the blended yarn is made of twisted yarn or single yarn and manufactured by a tissue design according to the use, a fabric having excellent heat resistance can be obtained. The spun yarn having excellent heat resistance according to the present invention may be used in the steel industry, glass industry or the friction material industry where heat resistance and strength are required, which are operated at high temperatures. Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited by Examples.

[실시예 1]Example 1

세라믹섬유를 길이 50㎜되게 스테이플로 하고, 아라미드 섬유를 길이 35㎜되게 스테이플로 하여 그 혼합 중량비율을 80:20으로 하여 혼면으로 만들어, 탄소섬유의 필라멘트사와 같이 마찰방적기에 넣어 혼방사를 만들었다. 또 이 혼방사로 평직으로 제직하여 직물을 만들었고, 혼방사와 직물의 내열성을 측정하여 표1에 나타내었다.The ceramic fiber was stapled to 50 mm in length, the aramid fiber was stapled to 35 mm in length, and the mixed weight ratio thereof was 80:20 to make a blended surface, and the blended yarn was put in a friction spinning machine like filament yarn of carbon fiber. In addition, the blended yarns were woven into plain weave to make a fabric, and the heat resistance of the blended yarn and the fabric was measured and shown in Table 1.

[실시예 2]Example 2

세라믹섬유와 아라미드 섬유의 혼합 중량비율을 65:35로 하였고, 이후 공정은 실시예1과 동일하게 실시하였다.The mixing weight ratio of the ceramic fibers and the aramid fibers was 65:35, and the process was performed in the same manner as in Example 1.

[실시예 3]Example 3

세라믹섬유의 길이를 145㎜로 하고, 아라미드 섬유의 길이를 60㎜로 하였고, 이후 공정은 실시예 1과 동일하게 실시하였다.The length of the ceramic fiber was 145 mm, the length of the aramid fiber was 60 mm, and the process was carried out in the same manner as in Example 1.

[비교예 1]Comparative Example 1

길이 50㎜의 세라믹섬유와 길이 38㎜의 폴리에스테르 섬유를 80:20의 혼합 중량비율로 하여 방적사를 만들고, 이 방적사를 평직으로 제직하였다.A spun yarn was made by mixing a ceramic fiber having a length of 50 mm and a polyester fiber having a length of 38 mm at a mixing weight ratio of 80:20, and the spun yarn was woven into plain weave.

[제조예][Production example]

금속섬유와 아라미드섬유로 혼면된 슬라이버를 한쪽에서 공급하고, 무기섬유 필라멘트를 다른 한쪽에 공급하여 무기섬유 필라멘트가 코어(core)로 형성되고 금속섬유와 아라미드 섬유가 시스(sheath)로 외층에 형성되게 마찰방적기를 이용안하여 방적사를 제조하였다.The sliver blended with metal fiber and aramid fiber is supplied from one side, and the inorganic fiber filament is supplied to the other side, and the inorganic fiber filament is formed into a core, and the metal fiber and aramid fiber are formed into the outer layer with a sheath. The yarn was manufactured using a friction spinning machine.

- 내열성(1) : 혼방사를 화원(火源)으로부터 5㎝거리에서 30초간 방치한후의 섬유 표면상태-Heat resistance (1): Fiber surface state after mixed yarn is left for 30 seconds at 5cm distance from fire source

- 내열성(2) : 혼방사를 400∼1000°C까지 200°C 단위로 30분간 방치후의 원사 인장강도로 단위는 g/d-Heat resistance (2): The tensile strength of the yarn after leaving the mixed yarn for 30 minutes at 400 ° C to 1000 ° C at 200 ° C in units of g / d

- 내열성(3) : 직물을 400∼1000°C까지 200°C단위로 30분간 방치후의 인장강도로 단위는 ㎏/㎝-Heat resistance (3): Tensile strength after leaving the fabric for 30 minutes at 400 ° C to 1000 ° C at 200 ° C

Claims (4)

금속섬유 스테이플과 아라미드섬유 스테이플을 일정비율로 혼면한 것을 방적사의 외층으로 하고 무기섬유 필라멘트를 방적사의 내층에 구성시킨 것을 특징으로 내열성이 우수한 방적사.A spun yarn having excellent heat resistance, characterized by blending metal fiber staples and aramid fiber staples at a constant ratio as the outer layer of the yarn and forming an inorganic fiber filament in the inner layer of the yarn. 제1항에 있어서, 혼면시 금속섬유와 아라미드섬유와의 혼합비율이 금속섬유가 65∼85% 아라미드섬유가 15∼35%임을 특징으로 하는 내열성이 우수한 방적사.The spun yarn having excellent heat resistance according to claim 1, wherein the mixing ratio of the metal fibers and the aramid fibers at the time of blending is 65 to 85% for the metal fibers and 15 to 35% for the aramid fibers. 제1항에 있어서, 금속섬유는 세라믹섬유 또는 스테인레스스틸 섬유로 그 길이가 40∼150㎜의 스테이플이며, 아라미드섬유는 그 길이가 30∼65㎜인 스테이플임을 특징으로 하는 내열성이 우수한 방적사.The spun yarn of claim 1, wherein the metal fiber is a ceramic fiber or a stainless steel fiber and is a staple having a length of 40 to 150 mm, and the aramid fiber is a staple having a length of 30 to 65 mm. 제1항에 있어서, 무기섬유로는 유리섬유 또는 탄소섬유의 필라멘트사 임을 특징으로 하는 내열성이 우수한 방적사.The spun yarn having excellent heat resistance according to claim 1, wherein the inorganic fiber is filament yarn of glass fiber or carbon fiber.
KR1019940014353A 1994-06-22 1994-06-22 Spun yarn with excellent heat resistance Expired - Fee Related KR100205907B1 (en)

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KR1019940014353A KR100205907B1 (en) 1994-06-22 1994-06-22 Spun yarn with excellent heat resistance

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KR960001239A KR960001239A (en) 1996-01-25
KR100205907B1 true KR100205907B1 (en) 1999-07-01

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Cited By (6)

* Cited by examiner, † Cited by third party
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KR100358960B1 (en) * 2000-07-26 2002-10-31 임재경 GLAND PACKING-SEAL NoN-ASBESTOS REPE
KR100918305B1 (en) 2007-04-30 2009-09-18 윤주영 Manufacturing method of buffer fabric and buffer fabric by the method
KR101011911B1 (en) * 2002-07-22 2011-02-01 다이메이카가쿠코교가부시키가이샤 Method for producing brush-type grindstone, brush-type grindstone, and brush for grinder
KR101152492B1 (en) * 2011-04-25 2012-06-01 윤주영 Super heat resisting composition fiber yarn and a using composition adiabatic fiber thereby
CN104611802A (en) * 2015-02-12 2015-05-13 江苏鸿顺合纤科技有限公司 Heat-insulating high temperature blended yarn
CN105624863A (en) * 2014-10-28 2016-06-01 江阴芗菲服饰有限公司 Anti-radiation cool sense-offered semi-worsted yarn and spinning technology thereof

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030071433A (en) * 2002-02-27 2003-09-03 백은기 Actual production method
KR100837764B1 (en) * 2007-03-30 2008-06-16 주식회사 진흥기공 Heat-resistant insulating composite fiber yarn and its manufacturing method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100358960B1 (en) * 2000-07-26 2002-10-31 임재경 GLAND PACKING-SEAL NoN-ASBESTOS REPE
KR101011911B1 (en) * 2002-07-22 2011-02-01 다이메이카가쿠코교가부시키가이샤 Method for producing brush-type grindstone, brush-type grindstone, and brush for grinder
KR100918305B1 (en) 2007-04-30 2009-09-18 윤주영 Manufacturing method of buffer fabric and buffer fabric by the method
KR101152492B1 (en) * 2011-04-25 2012-06-01 윤주영 Super heat resisting composition fiber yarn and a using composition adiabatic fiber thereby
CN105624863A (en) * 2014-10-28 2016-06-01 江阴芗菲服饰有限公司 Anti-radiation cool sense-offered semi-worsted yarn and spinning technology thereof
CN104611802A (en) * 2015-02-12 2015-05-13 江苏鸿顺合纤科技有限公司 Heat-insulating high temperature blended yarn

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