KR0179521B1 - Antistatic Agent Composition for Clothing - Google Patents
Antistatic Agent Composition for Clothing Download PDFInfo
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- KR0179521B1 KR0179521B1 KR1019960031833A KR19960031833A KR0179521B1 KR 0179521 B1 KR0179521 B1 KR 0179521B1 KR 1019960031833 A KR1019960031833 A KR 1019960031833A KR 19960031833 A KR19960031833 A KR 19960031833A KR 0179521 B1 KR0179521 B1 KR 0179521B1
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- Prior art keywords
- antistatic
- composition
- weight
- modified silicone
- clothing
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- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 239000002216 antistatic agent Substances 0.000 title claims abstract description 9
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 10
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229960003500 triclosan Drugs 0.000 claims abstract description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 230000000845 anti-microbial effect Effects 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 239000004599 antimicrobial Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 7
- 239000004615 ingredient Substances 0.000 abstract 2
- 238000012360 testing method Methods 0.000 description 14
- 230000000694 effects Effects 0.000 description 8
- 239000004744 fabric Substances 0.000 description 8
- 241000894006 Bacteria Species 0.000 description 7
- 238000001035 drying Methods 0.000 description 6
- 239000000835 fiber Substances 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 230000003068 static effect Effects 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 230000005611 electricity Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- -1 anionic alkyl phosphoric acid ester salts Chemical class 0.000 description 3
- 239000002979 fabric softener Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 241000233866 Fungi Species 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 230000002459 sustained effect Effects 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 206010016322 Feeling abnormal Diseases 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 241000219094 Vitaceae Species 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000021021 grapes Nutrition 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-N methyl sulfate Chemical class COS(O)(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/16—Anti-static materials
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/16—Physical properties antistatic; conductive
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
본 발명은 정전기방지제의 주성분으로서 모노알킬아미노틸베타인을 필수성분으로 함유하고 동시에 술폰산변성 실리콘유도체 및/또는 폴리에테르변성 실리콘유도체를 함유하며 항균성분으로서 트리클로산을 함유하는 것을 특징으로 하는 의류용 정전기방지제 조성물에 관한 것이다.The present invention is an antistatic agent for clothes, which contains monoalkylaminotilbetaine as an essential ingredient as the main component of the antistatic agent, and at the same time contains a sulfonic acid-modified silicone derivative and / or a polyether-modified silicone derivative and contains triclosan as an antibacterial ingredient. It relates to a composition.
Description
[발명의 명칭][Name of invention]
의류용 정전기 방지제 조성물Antistatic Composition For Clothing
[발명의 상세한 설명]Detailed description of the invention
[발명의 목적][Purpose of invention]
본 발명은 항균성분을 함유한 의류용의 액상분무형 정전기 방지제 조성물에 관한 것이다. 더욱 상세하게는 본 발명은 착용중인 각종 천연 또는 화학섬유에서 마찰에 의해 발생되는 정전기 장애를 해소시켜 주기 위하여 항균성분을 함유시킨 의류용 정전기 방지제 조성물에 관한 것이다.The present invention relates to a liquid spray type antistatic composition for clothes containing an antimicrobial component. More particularly, the present invention relates to an antistatic composition for clothes containing antimicrobial components in order to solve the static disturbance caused by friction in various natural or chemical fibers being worn.
[발명이 속하는 기술분야 및 그 분야의 종래 기술]TECHNICAL FIELD OF THE INVENTION
일반적으로 각종 천연 또는 화학섬유는 착용 중에 인체와의 마찰이나 섬유간의 마찰, 기타 다른 물체들과의 마찰로 인해 정전기가 발생되고 작업 중에 정전기로 인해 각종장애를 일으키기도 한다. 청정근무환경에 종사하는 경우에는 도전성의 재전복을 입고 근무하도록 권장하고 있는데 이는 상기의 이유 때문인 것으로 볼 수 있다. 또한 우리 생활 주변에는 무수히 많은 미생물이 존재하여 이들 미생물 중에는 의류에 영향을 미치는 세균 및 곰팡이가 있는데, 이들이 의류재질을 파괴하고 착색오염을 일으키기도 하며 의류에서 증식하여 피부자극(1차 자극, 누적 자극, 알러지 등)을 일으키고 악취를 발생시킨다고 알려져 있다(참조 : American Dyestuff Report, Nov., 1937, p48-59, Applied Micorobiology V 25, 1937, p431-435).In general, various natural or chemical fibers are generated by static electricity due to friction with the human body, friction between fibers, and other objects during wearing, and may cause various obstacles due to static electricity during operation. If you work in a clean working environment, it is recommended to wear a conductive overturn, which may be because of the above reasons. In addition, there are countless microorganisms around our lives, and among these microorganisms, there are bacteria and fungi that affect clothing. They destroy clothing material, cause staining of pigment, and proliferate in clothing to stimulate skin (primary and cumulative). , Allergies, etc.) and are known to cause odors (American Dyestuff Report, Nov., 1937, p48-59, Applied Micorobiology V 25, 1937, p431-435).
의류에 정전기방지성을 효과적으로 부여하기 위한 노력은 오랫동안 계속되어 왔으나 실제로 의류에 영구적인 정전기방지가공을 하는 경우는 극히 드물고 일상적으로 착용하는 의류에는 이러한 가공이 되어 있지 않은 것이 대부분이므로 일반 가정에서는 각종 의류를 세탁하는 과정에서 섬유 유연제를 사용하여 정전기방지를 하기도 한다. 그러나 섬유 유연제의 용도로서 주로 사용되는 양이온계면활성제는 착용 중에 마찰에 의해 정전기방지성분이 쉽게 탈착되고 효과가 지속적이지 못한데, 이러한 화합물로는 대개 디장쇄알킬암모늄클로라리드염 또는 메틸설페이트염과 디장쇄알킬이미다 졸리늄염 등의 양이온계면활성제가 가장 많이 사용된다고 알려져 있다 (참조 : 일본 공개특허 제79-160890호, 제 86-207670호, J. of Pediatrics, V 39, 1951, 9730-737).Efforts have been made to effectively provide antistatic properties to clothing, but in practice, permanent antistatic processing of clothing is extremely rare and most of the daily wear of clothing is not processed. In the process of washing the fabric softener may be used to prevent static electricity. However, cationic surfactants, which are mainly used as fabric softeners, are easily desorbed due to friction during wear, and the effect is not sustained. Such compounds are usually di-chain alkylammonium chloride or methyl sulfate salts and di Cationic surfactants such as long-chain alkylimidazolinium salts are known to be most used (see Japanese Patent Laid-Open Nos. 79-160890, 86-207670, J. of Pediatrics, V 39, 1951, 9730-737). .
따라서 의복 착용 중 섬유간 마찰이 심한 부위나 정전기발생이 자주 일어나는 의류에 대해서는 착용 중에 부분적으로 정전기 방지제를 분무하여 정전기장애현상을 해소시켜 주기 위해 물과 에탄올의 혼합물에 전술한 섬유유연제 용도의 양이온계면활성제 이외에 음이온성의 알킬인산에스테르염 및 알킬유산에스테르염, 비이온성의 에톡실화아민과 에톡실화에스테르 및 에톡실화솔비탄지방산 화합물을 함유시킨 제품이 시판되고 있다. 그러나 이러한 성분들은 저습도하에서 정전기방지효과가 부족할 뿐만 아니라 지속적이지 못하며 특히 양이온 성분들은 건조속도가 느리고 끈적거림이 남아 사용감이 좋지 못하다. 또한 최근 우리 생활환경은 각종미생물에 의해 오염되기 쉬운 상태이므로 의류에 잔존함으로써 세균이나 곰팡이의 증식에 의한 의류재질의 파괴와 착색오염을 방지하고 피부자극과 악취발생을 해소시켜줄 수 있는 제품에 대한 필요성이 크게 대두되고 있으나 지금까지 시판되고 있는 제품들은 이러한 욕구를 충족시켜주지 못하고 있는 실정이다.Therefore, in the areas of high friction between fibers during clothing or clothing which frequently generates static electricity, the cationic surface of the above-mentioned fabric softener is used in a mixture of water and ethanol to spray the antistatic agent partially to solve the electrostatic disturbance. In addition to the active agent, products containing anionic alkyl phosphoric acid ester salts and alkyl lactic acid ester salts, nonionic ethoxylated amines, ethoxylated esters and ethoxylated sorbitan fatty acid compounds are commercially available. However, these components not only lack the antistatic effect under low humidity, but are not persistent. Especially, the cationic components have a low drying speed and stickiness, which results in poor usability. In addition, since our living environment is easily contaminated by various microorganisms, there is a need for a product that can remain in clothing to prevent destruction of clothing materials and staining by the growth of bacteria and fungi, and to prevent skin irritation and odors. Although this is a great emergence, the products that have been on the market so far do not satisfy these needs.
[발명이 이루고자 하는 기술적 과제][Technical problem to be achieved]
따라서 본 발명자 등은 상기와 같은 문제점을 해소시키고자 수많은 연구와 실험을 행한 결과 저습도하에서도 우수한 정전기방지 효과와 지속성을 발휘하며 건조속도가 빠르며 끈적거림이 없고 뛰어난 항균 효과를 발휘한 신규한 정전기 방지제 조성물을 개발하였다.Therefore, the present inventors have conducted a number of studies and experiments to solve the above problems, as a result of excellent antistatic effect and persistence even under low humidity, the drying speed is fast, non-sticky and excellent antibacterial effect An inhibitor composition was developed.
[발명의 구성 및 작용][Configuration and Function of Invention]
즉 본 발명은 정전기방지의 주성분으로서 하기일반식(I)의 모노알킬아피노알킬베타인을 필수성분으로 함유하고 동시에 하기일반식(II)의 술폰산변성실리콘유도체 및/또는 하기 일반식(III)의 폴리에테르변성 실리콘유도체를 함유하며 또한 항균성분으로서 하기일반식(Ⅳ)의 트리클로산을 함유하는 것을 특징으로 하는 의류용 정전기방지제 조성물에 관한 것이다.That is, the present invention contains monoalkylaffinoalkylbetaine of the following general formula (I) as an essential component as an antistatic main component and at the same time the sulfonic acid-modified silicone derivative of the following general formula (II) and / or of the general formula (III) The present invention relates to an antistatic composition for clothing, comprising a polyether modified silicone derivative and containing triclosan of the following general formula (IV) as an antibacterial component.
상기 식에서, Rl은 C8내지 C22의 알킬 또는 알케닐기이고, R2는 Cl내지 C4의 알킬기이며, R3은 수소원자, C1내지 C4의 알킬 또는 알케닐기를 나타내고, R4는 페닐기이거나 Cl내지 C4의 알킬로 치환된 페닐렌기 또는 Cl내지 C5의 알킬렌기이고, X는 수소 또는 Na, K, NH4를 나타내며, p, q 및 r은 각각 독립적으로 5 내지 1,500의 정수이고, a는 1 내지 50의 정수이고, b는 0 내지 20의 정수를 나타낸다.Wherein R 1 is a C 8 to C 22 alkyl or alkenyl group, R 2 is a C 1 to C 4 alkyl group, R 3 represents a hydrogen atom, a C 1 to C 4 alkyl or alkenyl group, R 4 is a phenyl group or a phenylene group substituted with C 1 to C 4 alkyl or a C 1 to C 5 alkylene group, X represents hydrogen or Na, K, NH 4 , and p, q and r are each independently 5 It is an integer of 1,500, a is an integer of 1-50, b shows the integer of 0-20.
본 발명에 따른 정전기방지제 조성물에서 상술한 모노알킬아미노 알킬베타인(I)은 0.05 내지 10중량%를 함유하는 것이 바람직하다. 모노알킬아미노알킬베타인(I)의 함량이 0.05 중량% 미만인 경우에는 충분한 정전기방지효과를 기대할 수 없고, 10중량%를 초과하는 경우에는 정전기방지효과는 좋아지지만 건조속도가 느려져 끈적거림이 남게 되어 사용감이 좋지 않게 되며 의류에 얼룩을 발생시키는 요인이 되기도 하므로 좋지 않다.In the antistatic composition according to the present invention, the above-mentioned monoalkylamino alkylbetaine (I) preferably contains 0.05 to 10% by weight. If the content of monoalkylaminoalkylbetaine (I) is less than 0.05% by weight, sufficient antistatic effect cannot be expected. If it exceeds 10% by weight, the antistatic effect is better but the drying speed is slower, leaving stickiness. It is not good because it feels bad and can also cause stains on clothing.
그리고 술폰산변성 실리콘유도체(11) 및 폴리에테르변성 실리콘 유도체(111)는 단독 또는 병용하여 0.05 내지 5중량% 함유하는 것이 바람직한데, 만약0.05중량% 미만이면 의류의 유연성이 불량해지고 정전기방지효과의 지속성도 급격히 저하되므로 좋지 않고, 5중량% 초과 시에는 건조속도가 느려져 끈적임이 남으므로 좋지 않다.In addition, the sulfonic acid-modified silicone derivative 11 and the polyether-modified silicone derivative 111 may be contained alone or in combination of 0.05 to 5% by weight. If less than 0.05% by weight, the flexibility of the clothing is poor and the antistatic effect is sustained. It is also not good because it is sharply lowered, and when it exceeds 5% by weight, the drying speed is slow and stickiness remains.
또한 본 발명에 따른 정전기방지제 조성물에서 트리클로산(Ⅳ)은 0.01 내지 2중량%를 함유하는 것이 바람직한데, 만약 0.01중량% 미만이면 충분한 항균효과가 나타나지 않고 2중량% 초과의 경우에는 향균 효과는 좋아지나 용해성이 불량해져 분사성이 나빠지므로 좋지 않다.In addition, in the antistatic composition according to the present invention, triclosan (IV) is preferably contained in an amount of 0.01 to 2% by weight. If it is less than 0.01% by weight, sufficient antibacterial effect does not appear. It is not good because it has poor solubility and poor sprayability.
본 발명에 따른 정전기방지제 조성물에서 상기 일반식(I), (Ⅱ), (Ⅲ) 및 (Ⅳ) 성분의 전체함량은 조성물 총량을 기준으로 0.5 내지 15중량%로 제한하는 것이 바람직하다.In the antistatic composition according to the present invention, the total content of the general formulas (I), (II), (III) and (IV) is preferably limited to 0.5 to 15% by weight based on the total amount of the composition.
본 발명에 따른 정전기방지제 조성물은 분사성을 고려하여 용제로서 물과 에탄올을 함유하는데, 분사성 및 물성안정성등에 영향이 없는 범위 내에서 일정비율로 혼합사용이 가능하나 바람직하게는 물과 에탄올의 혼합중량비가 1:1 내지 15 : 1의 범위로서 전제의 50 내지 99중량%를 차지하는 것이 좋다.The antistatic agent composition according to the present invention contains water and ethanol as a solvent in consideration of spraying properties, but can be mixed and used in a predetermined ratio within a range that does not affect spraying properties and physical properties, but preferably mixed with water and ethanol The weight ratio is in the range of 1: 1 to 15: 1 and preferably occupies 50 to 99% by weight of the premise.
그 외에 본 발명에 따른 정전기방지제 조성물은 분사성 및 물성안정성 등에 영향을 미치지 않는 범위 내에서 각종 첨가제로서 향료, 방부제, 점도조절제용의 유기염 또는 무기염의 화합물을 사용목적에 따라 소량 함유할 수 있다. 또한 본 발명의 조성물의 분무형태는 가능한 한 분사각이 크고 미세한 입자로서 균일하게 분사되는 액상분무형 제품이 바람직하다.In addition, the antistatic agent composition according to the present invention may contain a small amount of a compound of a fragrance, preservative, organic salt for the viscosity modifier or an inorganic salt according to the purpose of use as various additives within a range that does not affect the sprayability and physical properties stability. . It is also preferable that the spray form of the composition of the present invention is a liquid spray type product in which the spray angle is as large as possible and uniformly sprayed as fine particles.
본 발명은 아래의 실시예를 통하여 구체적으로 설명될 수 있으나 이들 실시예로 본 발명의 기술적 범위가 제한되는 것은 아니다.The present invention can be described in detail through the following examples, but the technical scope of the present invention is not limited to these examples.
[실시예]EXAMPLE
하기 표 1에 나타낸 바와 같은 조성비율로 각 성분들을 혼합하여 실시예 및 비교예의 정전기방지제 조성물을 제조하였다.Each component was mixed at a composition ratio as shown in Table 1 below to prepare an antistatic composition of Examples and Comparative Examples.
각 조성물의 실시예 및 비교예를 토대로 순물질기준으로 환산하여 각 섬유소재별로 일정 사용농도로 처리한 후 일정한 항온 항습 조건하에서 24시간 콘디셔닝시킨 후 정전기방지성시험, 건조성 시험 및 항균시험을 다음과 같이 실시하였다.Based on the examples of the compositions and comparative examples of each composition, treated with a specific use concentration for each fiber material, and then conditioned under constant constant temperature and humidity conditions for 24 hours, followed by an antistatic test, a drying test, and an antibacterial test. It was carried out as follows.
(1) 정전기방지성시험(1) Antistatic test
KS K-0905의 표준백면포, 백폴리에스테르포, 나일론포(한국의류시험연구원 제작)를 일반 세탁세제로 세척한 후 자연 건조시킨 것을 각각 5 × 5cm의 크기로 절단하고 이것을 표1의 실시예 및 비교예의 조성물로 용해한 각각의 헹굼물(순물질 기준 1% 수용액, 20℃)에 넣고 3분간 처리한 후 자연 건조시킨 다음 24치간 동안 스위스 Rothchilds 사제 Static-Voltmeter 기기를 이용하여 KS K-0555c 시험방법으로 초기정전압 150 V를 인가시켰을 때 각 시료포의 정전하의 누설속도로서 반감기를 측정하였다.Standard white cloth, white polyester cloth and nylon cloth (manufactured by Korea Apparel Testing & Research Institute) of KS K-0905 were washed with a general laundry detergent, and then naturally dried and cut into 5 × 5 cm sizes, respectively. And each rinse (1% aqueous solution based on pure substance, 20 ° C) dissolved in the composition of Comparative Example, treated for 3 minutes, dried naturally and then subjected to KS K-0555c test method using a Static-Voltmeter device manufactured by Rothchilds, Switzerland for 24 hours. When the initial constant voltage of 150 V was applied, the half-life was measured as the leakage rate of the electrostatic charge of each sample cloth.
(2) 건조성 시험(2) drying test
KS K-0905의 표준백면포(한국의류시험연구원 제작)를 일반 세탁세제로 세척한 후 자연 건조시킨 것을 직경 l0cm크기로 절단하고 24시간 동안 20 ± 20C, 40 ± 3% RH의 항온 항습 조건하에서 콘디셔닝시킨 후 표1의 실시예 및 비교예의조성물을 순물질기준농도로 하여 각 시료포에 0.5g을 집중 분무한 다음 초기분사직후부터 각 시료포의 중량감소율이 50%와 75%로 될 때의 경과시간을 측정하여 건조성을 판정하였다.After washing the standard white cloth of KS K-0905 (made by Korea Apparel Testing & Research Institute) with a general laundry detergent and cutting it into natural size, it was cut into l0cm in diameter and kept at 20 ± 20C, 40 ± 3% RH under constant temperature and humidity for 24 hours. After conditioning, 0.5g of each sample was concentrated by spraying the composition of Example 1 and Comparative Example of Table 1 to the net material standard concentration, and the weight loss rate of each sample was 50% and 75% immediately after the initial injection. The elapsed time was measured to determine dryness.
(3) 항균시험(3) antibacterial test
KS K-0905의 표준백면포, 모포(한국의류시험연구원 제작)를 직경 4.8cm크기의 원형으로 제단하여 멸균하고 시험균주로는 의류에 가장 큰 영향을 미치는 것으로 알려진 대장균(Escherichia coli)과 황색포도상구균(Staphylococcus aureus)을 선택하여 전배양한다. KS K-0693의 직물의 향균시험방법에 따라 시험시료를 앞서 준비한 시험포에 0, 1, 2회 분사하고 전배양된 시험균을 BHI broth로 희석해서 균현탁액이 104CFU/ml가 되게 하여 시험포에 1mℓ씩 접종한 후 37℃ 항온배양기에서 24시간 배양한 후, 각 시료포의 생균수를 측정하여 균수감소율을 계산함으로써 항균효과를 측정하였다.Standard white cloth and blanket of KS K-0905 (manufactured by Korea Apparel Testing & Research Institute) is sterilized by a round shape of 4.8cm in diameter.Escherichia coli and yellow grapes are known to have the greatest effect on clothing. Staphylococcus aureus is selected and precultured. According to the antimicrobial test method of the fabric of KS K-0693, the test sample was sprayed 0, 1 or 2 times on the prepared test cloth, and the precultured test bacteria were diluted with BHI broth to make the suspension suspension 10 4 CFU / ml. After inoculating 1mℓ into the incubator for 24 hours at 37 ℃ incubator, the antimicrobial effect was measured by measuring the number of viable cells in each sample cell to calculate the number of bacteria.
A : 접종 후 일정 접촉시간을 통하여 배양된 시험편으로부터 재생된 세균수A: Number of bacteria regenerated from the cultured specimen through a constant contact time after inoculation
B : 접종 후 접촉시간0(접촉 후 즉시)의 시험편으로부터 재생된 세균수B: Number of bacteria regenerated from the test piece after contact time 0 (immediately after contact)
상기 시험을 하기 표 2의 평가기준에 따라 평가한 결과는 하기 표3에 나타내었다.The results of evaluating the test according to the evaluation criteria of Table 2 are shown in Table 3 below.
상기 표 3으로부터, 본 발명에 의한 실시예의 조성물은 천연 및 화학섬유에 대해 우수한 정전기방지 효과와 지속성을 발휘하는데 이는 저 습도 조건하에서 현저하게 나타나고 있으며 건조성이 좋아 끈적임이 없으며 의류의 세균 및 곰팡이에 대해서 우수한 항균효과를 발휘함으로써 착용감을 주고 있음을 알 수 있다.From the above Table 3, the composition of the embodiment according to the present invention exhibits excellent antistatic effect and durability against natural and chemical fibers, which are remarkable under low humidity conditions, have good dryness and are non-sticky, and are resistant to bacteria and mold of clothing. It can be seen that giving a feeling of wearing by exhibiting an excellent antibacterial effect.
Claims (6)
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| KR1019960031833A KR0179521B1 (en) | 1996-07-31 | 1996-07-31 | Antistatic Agent Composition for Clothing |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR19990084309A (en) * | 1998-05-04 | 1999-12-06 | 한형수 | Antibacterial and deodorant sanitary agent for textile fabrics and processing method using the same |
| KR20170139937A (en) * | 2016-06-10 | 2017-12-20 | (주)엔바이오 | Fabric treatment composition having anti-bacterial and anti-static function |
| KR20230021489A (en) | 2021-08-05 | 2023-02-14 | 주식회사 그린동화 | Dust blocking composition, dust mask using same, and manufacturing method thereof |
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1996
- 1996-07-31 KR KR1019960031833A patent/KR0179521B1/en not_active IP Right Cessation
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR19990084309A (en) * | 1998-05-04 | 1999-12-06 | 한형수 | Antibacterial and deodorant sanitary agent for textile fabrics and processing method using the same |
| KR20170139937A (en) * | 2016-06-10 | 2017-12-20 | (주)엔바이오 | Fabric treatment composition having anti-bacterial and anti-static function |
| KR20230021489A (en) | 2021-08-05 | 2023-02-14 | 주식회사 그린동화 | Dust blocking composition, dust mask using same, and manufacturing method thereof |
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