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JPS6389385A - Phosphorescent thermal transfer medium - Google Patents

Phosphorescent thermal transfer medium

Info

Publication number
JPS6389385A
JPS6389385A JP61235555A JP23555586A JPS6389385A JP S6389385 A JPS6389385 A JP S6389385A JP 61235555 A JP61235555 A JP 61235555A JP 23555586 A JP23555586 A JP 23555586A JP S6389385 A JPS6389385 A JP S6389385A
Authority
JP
Japan
Prior art keywords
phosphorescent
layer
transfer
resin
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP61235555A
Other languages
Japanese (ja)
Inventor
Hitoshi Oike
尾池 均
Motonari Yanagimachi
柳町 元成
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oike and Co Ltd
Original Assignee
Oike and Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oike and Co Ltd filed Critical Oike and Co Ltd
Priority to JP61235555A priority Critical patent/JPS6389385A/en
Publication of JPS6389385A publication Critical patent/JPS6389385A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42Intermediate, backcoat, or covering layers
    • B41M5/426Intermediate, backcoat, or covering layers characterised by inorganic compounds, e.g. metals, metal salts, metal complexes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/405Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography characterised by layers cured by radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42Intermediate, backcoat, or covering layers
    • B41M5/423Intermediate, backcoat, or covering layers characterised by non-macromolecular compounds, e.g. waxes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42Intermediate, backcoat, or covering layers
    • B41M5/44Intermediate, backcoat, or covering layers characterised by the macromolecular compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Impression-Transfer Materials And Handling Thereof (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)

Abstract

PURPOSE:To record the transfer image of a character or an illustration having good phosphorescence, by forming a phosphorescent transfer layer to a base film directly or through a release agent layer. CONSTITUTION:A phosphorescent transfer layer is formed to a base film directly or through a release agent layer. As the phosphorescent paint constituting the phosphorescent transfer layer, a composition prepared by mixing a phosphor composed of phosphorescent pigment such as sulfide type phosphorescent pigment, for example, ZnS-Ca or GaAs-Bi or silicate type phosphorescent pigment, for example, (Zn,Be)2SiO4-Na with natural wax such as spermaceti or beeswax, a filler, a plasticizer, an oxidation inhibitor or the like is used. In order to prevent the damage of the phosphorescent transfer layer itself due to friction, a protective resin coating layer 31 is preliminarily provided on the base film through the release agent layer 2. For example, this layer 31 is formed by applying an org. solvent solution or aqueous solution of a thermoplastic resin, a thermosetting resin, an electron beam curable resin or an ultraviolet curable resin and drying the coating layer being formed.

Description

【発明の詳細な説明】 [技術分野] 本発明は、プリンタ、ファクシミリ等の感熱転写装置に
用いられる燐光性感熱転写媒体に関し。
DETAILED DESCRIPTION OF THE INVENTION [Technical Field] The present invention relates to a phosphorescent thermal transfer medium used in thermal transfer devices such as printers and facsimiles.

更に詳しくは、燐光性の文字、イラスト、地図等の画像
を記録できる様にした燐光性感熱転写媒体に関する。
More specifically, the present invention relates to a phosphorescent heat-sensitive transfer medium on which images such as phosphorescent characters, illustrations, and maps can be recorded.

[従来の技術] 従来より、感熱転写媒体には、例えば3〜12gm厚さ
程度のべ一人フィルムの上に所定の温度で熱溶融する熱
溶融性インク層か設けられてできている。この感熱転写
媒体の記録動作を説明すると、ベースフィルムにはサー
マルヘッドが当接していて、サーマルへ・ンドか記録信
号に応じて駆動されその部分が発熱すると、ベースフィ
ルムの該当する部分の熱溶融性インクが溶融して被転写
紙に転写される。この転写インクにより被転写紙に記録
信号に応じた転写像が形成され、普通紙を用いた被転写
紙への記録ができる。
[Prior Art] Conventionally, thermal transfer media have been made by providing a heat-melting ink layer that melts at a predetermined temperature on a flat film having a thickness of, for example, 3 to 12 gm. To explain the recording operation of this thermal transfer medium, a thermal head is in contact with the base film, and when the thermal head is driven according to the recording signal and that part generates heat, the corresponding part of the base film melts. The ink is melted and transferred to the receiving paper. A transfer image corresponding to the recording signal is formed on the transfer paper using this transfer ink, and recording can be performed on the transfer paper using plain paper.

しかしながら、上記のような感熱転写媒体は、熱溶融性
ワックス等にカーボンブラック等の顔料を混合したもの
を熱溶融性インク層に用いているために、被転写紙の表
面に形成される転写像は熱溶融性インク層に用いている
顔料の色に限定され、発光の中でも残光性の大きな性質
、すなわち燐光性を有する転写像等の記録は全く不可能
で有った。
However, since the heat-sensitive transfer medium described above uses a mixture of heat-fusible wax and pigments such as carbon black for the heat-fusible ink layer, the transferred image formed on the surface of the transfer paper is The color is limited to the color of the pigment used in the heat-melting ink layer, and it has been completely impossible to record transferred images that have a long afterglow property, that is, phosphorescence.

[発明の目的] 本発明は上記従来の問題点に鑑み、極めて良好な燐光性
を有した転写像等の記録ができる燐光性感熱転写媒体を
提供することにある。
[Object of the Invention] In view of the above-mentioned conventional problems, an object of the present invention is to provide a phosphorescent heat-sensitive transfer medium capable of recording transferred images and the like having extremely good phosphorescence.

[発明の構成] 即ち本発明は、ベースフィルムの上に直接または離型剤
層を介して、少なくとも燐光性転写層を形成したことを
特徴とする燐光性感熱転写媒体に関するものである。
[Structure of the Invention] That is, the present invention relates to a phosphorescent heat-sensitive transfer medium characterized in that at least a phosphorescent transfer layer is formed on a base film directly or via a release agent layer.

即ち本発明の燐光性感熱転写媒体においては、従来感熱
転写媒体の熱溶融性インク層にかえて少なくとも燐光性
転写層を用いることによって、部間の中でもある一定時
間像を見ることができる、いわゆる燐光性を有した文字
、イラスト、地図等の転写像の記録ができる燐光性感熱
転写媒体を完成したものである。
That is, in the phosphorescent heat-sensitive transfer medium of the present invention, by using at least a phosphorescent transfer layer in place of the heat-melting ink layer of conventional heat-sensitive transfer media, so-called phosphorescence, which allows an image to be seen for a certain period of time even between parts, is achieved. This is a completed phosphorescent heat-sensitive transfer medium that can record transferred images such as characters, illustrations, maps, etc.

即ち本発明は、ベースフィルム(1)の上に直接または
離型剤層(2)を介して、少なくとも燐光性転写層(3
)を形成してたことにより極めて良好な燐光性を有した
文字、イラスト、地図等の転写像の記録ができる燐光性
感熱転写媒体を提供することを可使としたものである。
That is, the present invention provides at least a phosphorescent transfer layer (3) on a base film (1) directly or via a release agent layer (2).
), it is possible to provide a phosphorescent heat-sensitive transfer medium capable of recording transferred images such as characters, illustrations, maps, etc., having extremely good phosphorescence.

本発明の燐光性感熱転写媒体におけるベースフィルム(
1)としては充分な自己保持性を有するものであればい
ずれも用いられるが、たとえばポリエステル、ポリアミ
ド、ポリアミドイミド、ポリエチレン、ポリプロピレン
、セルロースアセテート、ポリカーボネート、ポリ塩化
ビニル、フッ素樹脂などの樹脂類またはセロハン紙、グ
ラシン紙などのフィルム状物またはシート状物や剥離紙
または剥離フィルムなどが適宜用いられる。特にベース
フィルム(1)としては前記樹脂類のフィルム状物で厚
さが2.5〜tZU程度のものを用いるのが、しわや亀
裂などのない燐光性感熱転写媒体の製造が連続的に大量
生産出来る点から好ましい、また先に本出願人が出願し
た発明(特願昭60−260774号)に記載されてい
る様な。
The base film (
As 1), any material can be used as long as it has sufficient self-retention properties, such as resins such as polyester, polyamide, polyamideimide, polyethylene, polypropylene, cellulose acetate, polycarbonate, polyvinyl chloride, fluororesin, or cellophane. A film-like material or sheet-like material such as paper or glassine paper, a release paper or a release film, etc. are used as appropriate. In particular, as the base film (1), a film-like material of the above-mentioned resins with a thickness of about 2.5 to tZU is used to produce phosphorescent heat-sensitive transfer media without wrinkles or cracks. This is preferable from the standpoint of its capability, and is as described in the invention previously filed by the present applicant (Japanese Patent Application No. 60-260774).

プラスチックフィルムの熱転写層を設ける側の反対側に
無機物の薄膜、例えば5iO1Sift、Ti1t、Z
nO,A1.O,等の酸化物、TiN等のチッ化物、T
iC等の炭化物、炭素、A1.Ni、Cr、Ti、Ni
−Cr合金等の金属の6〜loonm程度の6MMを設
けた耐ホツトステイク性加工したものも好ましく用いら
れる。
A thin inorganic film such as 5iO1Sift, Ti1t, Z is placed on the opposite side of the plastic film to the side on which the thermal transfer layer is provided.
nO, A1. Oxides such as O, nitrides such as TiN, T
Carbide such as iC, carbon, A1. Ni, Cr, Ti, Ni
It is also preferable to use a metal such as a -Cr alloy which has been treated with a 6MM layer of about 6 to 1000 mm to resist hotstake.

尚、ベースフィルム(1)が燐光性転写層(3)または
保護樹脂塗膜層(31)との」離性がよくない場合には
パラフィンワックス、シリコーン、フッ素樹脂、界面活
性剤などを塗布してgI型剤層(2)を形成しておいて
もよい。
In addition, if the base film (1) does not have good release properties from the phosphorescent transfer layer (3) or the protective resin coating layer (31), apply paraffin wax, silicone, fluororesin, surfactant, etc. The gI type agent layer (2) may be formed in advance.

本発明の燐光性感熱転写媒体の燐光性転写層(3)とし
ては、前記ベースフィルム(1)の上に直接または市記
離型剤層(2)を介して、常法により塗布形成される。
The phosphorescent transfer layer (3) of the phosphorescent heat-sensitive transfer medium of the present invention is formed by coating on the base film (1) directly or via a release agent layer (2) by a conventional method.

前記燐光性転写層を構成する燐光性塗料として例えば、
Zn5−Ca、 Ga5−B1゜Zn5−Cu、Co、
(Zn、fl:d)S−Cu、(Ca、Cr)S−Bi
等の硫化物系燐光顔料や例えば、(Zn、Be)tsi
on−Me等の珪酸塩系燐光顔料等の燐光顔料からなる
燐光体を鯨ロウ、ミツロウ、ラノリン、カルバナワック
ス、キャンデリラワックス、モンタンワックス等の天然
ワックス、パラフィンワックス、マイクロウリンワック
ス、酸化ワックス、エステルワックス、低分子量ポリエ
チレン等の合成ワックス、ラウリン酸、ミリスチン酸、
バルミチン酸、ステアリン酸、フロメン酸、ベヘニン酸
等の高級脂肪酸、ステアリルアルコール、ベヘニルアル
コール等の高級アルコール、ショ糖の脂肪酸エステル、
ソルビタンの脂肪酸エステル等のエステル類、ステアリ
ンアミド、オレインアミド等のアミド類、ポリアミド系
樹脂、ポリエステル系樹脂、エポキシ系樹脂、ポリウレ
タン系樹脂、アクリル系樹脂、塩化ビニル系樹脂、セル
ロース系樹脂、ポリビニール系樹脂、石油系樹脂、エチ
レン−酢酸ビニル共重合体樹脂、フェノール系樹脂、ス
チレン系811I′8、天然ゴム、スチレンブタジェン
ゴム、イソプレンゴム、クロロプレンゴム等のエラスト
マー類、ロジン及びその誘導体、テルペン樹脂、水添石
油樹脂等のタッキファイヤ−1充填剤、可塑剤、酸化防
止剤などの単独又は混合されたものからなる燐光性塗料
が好ましく用いられる。
Examples of the phosphorescent paint constituting the phosphorescent transfer layer include:
Zn5-Ca, Ga5-B1゜Zn5-Cu, Co,
(Zn, fl:d)S-Cu, (Ca,Cr)S-Bi
Sulfide-based phosphorescent pigments such as (Zn, Be) tsi
A phosphor made of a phosphorescent pigment such as a silicate-based phosphorescent pigment such as on-Me can be used as a natural wax such as spermaceti wax, beeswax, lanolin, carbana wax, candelilla wax, or montan wax, paraffin wax, microurethane wax, or oxidized wax. , ester wax, synthetic wax such as low molecular weight polyethylene, lauric acid, myristic acid,
Higher fatty acids such as valmitic acid, stearic acid, fromenic acid and behenic acid, higher alcohols such as stearyl alcohol and behenyl alcohol, fatty acid esters of sucrose,
Esters such as sorbitan fatty acid ester, amides such as stearinamide and oleinamide, polyamide resin, polyester resin, epoxy resin, polyurethane resin, acrylic resin, vinyl chloride resin, cellulose resin, polyvinyl resins, petroleum resins, ethylene-vinyl acetate copolymer resins, phenolic resins, styrene 811I'8, natural rubber, elastomers such as styrene-butadiene rubber, isoprene rubber, chloroprene rubber, rosin and its derivatives, terpenes A phosphorescent paint consisting of a resin, a tackifier-1 filler such as a hydrogenated petroleum resin, a plasticizer, an antioxidant, etc. alone or in combination is preferably used.

燐光性転写層の形成は、前記燐光性転写層を形成するた
めの燐光性塗料の有機溶剤溶液、水溶液などをロールコ
ーティング法、グラビアコーティング法、リバースコー
ティング法、スプレィコーティング法、ホットメルトコ
ーティング法などの通常のコーティング法により塗布し
、乾燥(熱硬化性樹脂、電子線硬化性樹脂、紫外線硬化
性樹脂などの場合は硬化)することによって行われる。
The formation of the phosphorescent transfer layer can be carried out using a roll coating method, a gravure coating method, a reverse coating method, a spray coating method, a hot melt coating method, etc. using an organic solvent solution, aqueous solution, etc. of the phosphorescent paint for forming the phosphorescent transfer layer. This is done by applying the coating using a conventional coating method and drying (curing in the case of thermosetting resin, electron beam curable resin, ultraviolet ray curable resin, etc.).

燐光性転写層(3)の厚さは被転写紙の表面状態などに
より適宜選択決定されるものであるが通常は1〜IOJ
程度の範囲から選ばれ1通常の被転写紙の表面が比較的
平滑な場合には比較的薄いl〜21程度である。
The thickness of the phosphorescent transfer layer (3) is selected depending on the surface condition of the transfer paper, etc., but is usually 1 to IOJ.
The thickness is selected from a range of 1 to 21, which is relatively thin when the surface of the normal transfer paper is relatively smooth.

末完IJIの燐光性感熱転写媒体において、燐光性転写
層自体は機械的強度か弱く斥擦による損傷などを受けや
すいので、前記ベースフィルム(1)のとに直接または
前記離型剤層(2)を介して予め保護樹脂塗膜層(:1
1)を設けることもある。保護樹脂塗膜の厚さは特に制
限は無いが通常0.5〜2−の範囲から適宜選ばれる。
In the phosphorescent heat-sensitive transfer media of Seikan IJI, the phosphorescent transfer layer itself has weak mechanical strength and is easily damaged by friction, so the release agent layer (2) is applied directly to the base film (1) or Pre-protective resin coating layer (:1
1) may be provided. The thickness of the protective resin coating is not particularly limited, but is usually appropriately selected from the range of 0.5 to 2-2.

かかる保護樹脂塗膜層(コ1)を形成するための樹脂と
しては、たとえば熱可塑性樹脂、熱硬化性樹脂、電子線
硬化性樹脂、lR外線硬化性樹脂のいずれもが用いられ
、たとえばアクリル系樹脂、塩化ビニル−酢酸ビニル共
重合体、ポリビニルブチラール、ポリカーボネート、ニ
トロセルロース。
As the resin for forming the protective resin coating layer (co 1), any of thermoplastic resins, thermosetting resins, electron beam curable resins, and IR external radiation curable resins may be used, such as acrylic resins. Resin, vinyl chloride-vinyl acetate copolymer, polyvinyl butyral, polycarbonate, nitrocellulose.

セルロースアセテート、ウレタン系樹脂、尿素系樹脂、
メラミン系樹脂、尿素−メラミン系樹脂、エポキシ系樹
脂、アルキッド系樹脂、アミノアルキッド系樹脂、ロジ
ン変性マレイン酸樹脂などの単独またはU&物か好まし
く用いられる。
Cellulose acetate, urethane resin, urea resin,
Melamine resins, urea-melamine resins, epoxy resins, alkyd resins, aminoalkyd resins, rosin-modified maleic acid resins, and the like are preferably used alone or in combination with U&.

保護樹脂層の形成は、前記保護樹脂塗膜を形成するため
のs4脂の有機溶剤溶液、水溶液などをロールコーティ
ング法、グラビアコーティング法、リバースコーティン
グ法、スプレィコーティング法などの通常のコーティン
グ法により塗布し、乾燥(熱硬化性樹脂、m:f−線硬
化性樹脂、紫外線硬化性樹脂などの場合は硬化)するこ
とによって行われる。
The protective resin layer is formed by applying an organic solvent solution, aqueous solution, etc. of S4 fat to form the protective resin coating using a normal coating method such as a roll coating method, a gravure coating method, a reverse coating method, or a spray coating method. This is carried out by drying (curing in the case of thermosetting resins, m:f-ray curable resins, ultraviolet curable resins, etc.).

保護樹脂層はそれが透明または半透明である限りにおい
て染料または顔料などの着色材で着色してもよい。
The protective resin layer may be colored with a coloring agent such as a dye or pigment as long as it is transparent or translucent.

本発明の燐光性感熱転写媒体において、燐光性転写層自
体の機械的強度を強<j!1mによる損傷などを受は難
くするためには前記燐光性転写層を形成するための燐光
性塗料の構成成分を樹脂主体にすることにより改善する
こともできるか被転写紙への転写移行率Sよび転写強度
が劣る傾向に有るので、燐光性転写層の面上に接着剤層
(32)を設けることもある。
In the phosphorescent heat-sensitive transfer medium of the present invention, the mechanical strength of the phosphorescent transfer layer itself is increased <j! In order to make the phosphorescent transfer layer less susceptible to damage caused by 1 m, it is possible to improve the transfer rate S to the transfer paper by making the phosphorescent paint for forming the phosphorescent transfer layer mainly composed of resin. In some cases, an adhesive layer (32) is provided on the surface of the phosphorescent transfer layer, since the transfer strength tends to be poor.

、を発明の燐光性感熱転写媒体の接着剤層(32)とし
ては例えば鯨ロウ、ミツロウ、ラノリン、カルバナワッ
クス、キャンデリラワックス、モンタンワックス等の天
然ワックス、パラフィンワックス、マイクロウリンワッ
クス、酸化ワックス、エステルワックス、低分子量ポリ
エチレン等の合成ワックス、ラウリン酸、ミリスチン酸
、バルミチン酸、ステアリン酸、フロメン酸、ベヘニン
酸等の高級脂肪酸、ステアリルアルコール、ベヘニルア
ルコール等の高級アルコール、シミ糖の脂肪酸エステル
、ソルビタンの脂肪酸エステル等のエステル類、ステア
リンアミド、オレインアミド等のアミド類、ポリアミド
系樹脂、ボロエステル系樹脂、エポキシ系樹脂、ポリウ
レタン系樹脂、アクリル系樹脂、塩化ビニル系樹脂、セ
ルロース系樹脂、ポリビニール系樹脂、石油系樹脂、エ
チレン−酢酸ビニル共重合体樹脂、フェノール系樹脂、
スチレン系樹脂、天然ゴム、スチレンブタジェンゴム、
イソプレンゴム、クロロブレンゴム等のエラストマー類
、ロジン及びその誘導体、テルペン樹脂、水添石油樹脂
等のタッキファイヤ−1充填剤、可塑剤、酸化防止剤な
どの単独又は混合されたものか用いられる。接着剤層(
32)の厚さは被転写紙の表面状態などにより適宜選択
決定されるものであるか通常は1〜10u程度の範囲か
ら選ばれ、通常の被転写紙の表面が比較的平滑な場合に
は比較的Bいl〜21程度である。
As the adhesive layer (32) of the phosphorescent heat-sensitive transfer medium of the invention, for example, natural waxes such as spermaceti wax, beeswax, lanolin, carbana wax, candelilla wax, and montan wax, paraffin wax, microurean wax, oxidized wax, Synthetic waxes such as ester wax and low molecular weight polyethylene, higher fatty acids such as lauric acid, myristic acid, balmitic acid, stearic acid, fromenic acid, and behenic acid, higher alcohols such as stearyl alcohol and behenyl alcohol, fatty acid esters of simi sugar, and sorbitan. Esters such as fatty acid esters, amides such as stearinamide and oleinamide, polyamide resins, boroester resins, epoxy resins, polyurethane resins, acrylic resins, vinyl chloride resins, cellulose resins, polyvinyl resins resin, petroleum resin, ethylene-vinyl acetate copolymer resin, phenolic resin,
Styrene resin, natural rubber, styrene butadiene rubber,
Elastomers such as isoprene rubber and chloroprene rubber, rosin and its derivatives, terpene resins, tackifier-1 fillers such as hydrogenated petroleum resins, plasticizers, antioxidants, and the like may be used alone or in combination. Adhesive layer (
The thickness of 32) is selected depending on the surface condition of the transfer paper, etc., and is usually selected from the range of about 1 to 10 μm, and when the surface of the normal transfer paper is relatively smooth, It is relatively B1~21.

つぎに実施例をあげて本発明を説明する。Next, the present invention will be explained with reference to Examples.

[実施例] 実施例1 厚さ6μのポリエチレンテレフタレートフィルム上にパ
ラフィンワックス15部、およびエステルワックス5部
をトルエン60部および石油ナフサ20部からなる混合
溶剤に溶解して成るコーティング溶液を塗布、乾燥して
厚さl−の離型剤層を形成し、次いでその面上にパラフ
ィンワックス20部およびエチレン−酢酸ビニル共重合
樹脂5部および燐光性顔ll4(シンロイヒカラーFM
−14シンロイヒ株式会社製)10部をトルエン50部
、テレピン油15部からなる混合溶剤に溶解してなるコ
ーティング溶液を塗布、乾燥して厚さ2μsの燐光性転
写層を形成して本発明の燐光性感熱転写媒体を得た。(
燐光色ニオレンジ) 実施例2 厚さ6μ烏のポリエチレンテレフタレートフィルムLに
エステルワックス20部をトルエン60部および石油ナ
フサ20部からなる混合溶剤に溶解して成るコーティン
グ溶液を塗布、乾燥して厚さlμの離型剤層を形成し、
アクリル樹脂30部をトルエン30部、メチルイソブチ
ルケトン20部およびシクロへキサノン20部からなる
混合溶剤に溶解して成るコーティング溶液を塗布、乾燥
して厚さ2#L1の保護樹脂塗膜層を形成し、次いでそ
の面上にパラフィンワックス50部、およびカルナバワ
ックス25部、エステルワックス10部、エチレン−酢
酸ビニル共重合樹脂10部および燐光性顔料(シンロイ
ヒカラーFM−12シンロイヒ株式会社製)5部からな
る混合物をホットメルトコーティング法で塗布して厚さ
2−の燐光性転写層を形成して本発明の燐光性感熱転写
媒体を得た。(燐光色ニゲリーン) 実施例3 厚さ9μのポリエチレンテレフタレートフィルム上にパ
ラフィンワックス9部、およびケトン樹脂1部をトルエ
ン70部、テレピン油10部および石油ナフサ10部か
らなる混合溶剤に溶解して成るコーティング溶液を塗布
、乾燥して厚さlμsの離型剤層を形成し、次いでその
面上にスチレンマレイン酸樹脂25部、および燐光性顔
$4(シンロイヒカラーFM−14シンロイヒ株式会社
IM)15部をトルエン30部、メチルイソブチルケト
ン20部およびシクロヘキサノン10部からなる混合溶
剤に溶解して成るコーティング溶液を塗布、乾燥して厚
さ5JJJの燐光性転写層を形成し、その上にパラフィ
ンワックス20部、カルナバワックス5部、およびエチ
レン−酢酸ビニル共重合樹脂5部をトルエン50部、テ
レピン油20部からなる混合溶剤に溶解してなるコーテ
ィング溶液を塗布、乾燥して厚さ2μsの接着剤層を形
成して本発明の燐光性感熱転写媒体を得た。
[Example] Example 1 A coating solution prepared by dissolving 15 parts of paraffin wax and 5 parts of ester wax in a mixed solvent consisting of 60 parts of toluene and 20 parts of petroleum naphtha was applied onto a 6 μm thick polyethylene terephthalate film and dried. to form a release agent layer with a thickness of l-, and then apply 20 parts of paraffin wax, 5 parts of ethylene-vinyl acetate copolymer resin, and a phosphorescent layer (Shinroihi Color FM) on the surface.
A coating solution prepared by dissolving 10 parts of 14 (manufactured by Shinroihi Co., Ltd.) in a mixed solvent consisting of 50 parts of toluene and 15 parts of turpentine oil was applied and dried to form a phosphorescent transfer layer with a thickness of 2 μs. A phosphorescent thermal transfer medium was obtained. (
Example 2 A coating solution prepared by dissolving 20 parts of ester wax in a mixed solvent consisting of 60 parts of toluene and 20 parts of petroleum naphtha is applied to a polyethylene terephthalate film L having a thickness of 6 μm, and dried to give a thickness of Forming a release agent layer of lμ,
A coating solution made by dissolving 30 parts of acrylic resin in a mixed solvent consisting of 30 parts of toluene, 20 parts of methyl isobutyl ketone, and 20 parts of cyclohexanone is applied and dried to form a protective resin coating layer with a thickness of 2#L1. Then, on the surface, 50 parts of paraffin wax, 25 parts of carnauba wax, 10 parts of ester wax, 10 parts of ethylene-vinyl acetate copolymer resin, and 5 parts of phosphorescent pigment (Shinroihi Color FM-12 manufactured by Shinroihi Co., Ltd.) were added. A phosphorescent transfer layer having a thickness of 2 mm was formed by applying a mixture consisting of the following by a hot melt coating method to obtain a phosphorescent thermal transfer medium of the present invention. (Phosphorescent color Nigerene) Example 3 9 parts of paraffin wax and 1 part of ketone resin were dissolved in a mixed solvent consisting of 70 parts of toluene, 10 parts of turpentine oil and 10 parts of petroleum naphtha on a polyethylene terephthalate film with a thickness of 9 μm. A coating solution was applied and dried to form a release agent layer with a thickness of 1 μs, and then 25 parts of styrene maleic acid resin and a phosphorescent face $4 (Shinroihi Color FM-14 Shinroihi Co., Ltd. IM) were applied on the surface. A coating solution consisting of 15 parts dissolved in a mixed solvent consisting of 30 parts of toluene, 20 parts of methyl isobutyl ketone, and 10 parts of cyclohexanone is applied and dried to form a phosphorescent transfer layer with a thickness of 5 JJJ, and on top of that is paraffin wax. A coating solution prepared by dissolving 20 parts of carnauba wax, 5 parts of carnauba wax, and 5 parts of ethylene-vinyl acetate copolymer resin in a mixed solvent consisting of 50 parts of toluene and 20 parts of turpentine oil is applied and dried to form an adhesive with a thickness of 2 μs. A layer was formed to obtain a phosphorescent thermal transfer medium of the present invention.

(燐光色ニオレンジ) 実施例4 厚さ9μsのポリエチレンテレフタレートフィルム上に
塩化ゴム20部をトルエン40部、メチルイソブチルケ
トン20部およびシクロへキサノン20部からなる混合
溶剤に溶解して成るコーティング溶液を塗布、乾燥して
厚さ2μ曹の保護樹脂塗膜層を形成し、次いでその面上
にスチレンマレイン酸樹脂25部、および燐光性顔料(
シンロイヒカラーFM−12シンロイヒ株式会社製)1
0部をトルエン60部およびメチルイソブチルケトン5
部からなる混合溶剤に溶解して成るコーティング溶液を
塗布、乾燥して厚さ51の燐光性転写層を形成し、その
上にパラフィンワックス50部、エステルワックス30
部、およびエチレン−酢酸ビニル共重合樹脂20部から
なる混合物をホットメルトコーティング法で塗布して厚
さ2−の接着剤層を形成して本発明の燐光性感熱転写媒
体を得た。(燐光色ニゲリーン) [発’J1の効果] 実施例1、実施例2、実施例3および実施例4で得られ
た燐光性感熱転写媒体を用いて普通紙に熱転写プリンタ
 キャノンC−4253(キャノン株式会社製)で印字
した。
(Phosphorescent color: yellow orange) Example 4 A coating solution prepared by dissolving 20 parts of chlorinated rubber in a mixed solvent consisting of 40 parts of toluene, 20 parts of methyl isobutyl ketone, and 20 parts of cyclohexanone was coated on a polyethylene terephthalate film with a thickness of 9 μs. A protective resin coating layer with a thickness of 2μ is formed by coating and drying, and then 25 parts of styrene-maleic acid resin and a phosphorescent pigment (
Shinroihi Color FM-12 (manufactured by Shinroihi Co., Ltd.) 1
0 parts to 60 parts of toluene and 5 parts of methyl isobutyl ketone
A coating solution consisting of 50 parts of paraffin wax and 30 parts of ester wax was applied and dried to form a phosphorescent transfer layer with a thickness of 51 parts.
A phosphorescent heat-sensitive transfer medium of the present invention was obtained by applying a mixture of 1 part and 20 parts of an ethylene-vinyl acetate copolymer resin by a hot-melt coating method to form an adhesive layer with a thickness of 2 mm. (Phosphorescent color Nigeleen) [Effects of 'J1'] Thermal transfer printer Canon C-4253 (Canon stock) was printed on plain paper using the phosphorescent thermal transfer media obtained in Examples 1, 2, 3 and 4 (manufactured by the company).

得られた普通紙上の文字、イラスト、地図等の画像は極
めて芙れいな燐光色を呈していた。
The resulting images of characters, illustrations, maps, etc. on plain paper had an extremely bright phosphorescent color.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本願発明の燐光性感熱転写媒体の基本構成を示
す断面図で第2図は本願発明の燐光性感熱転写媒体の他
の実施態様例を示す断面図である。 (図面の符号) (1)二ベースフィルム (2) : gl型剤層 (31):保護樹脂層 (3):燐光性転写層 (32):接着剤層
FIG. 1 is a sectional view showing the basic structure of the phosphorescent thermal transfer medium of the present invention, and FIG. 2 is a sectional view showing another embodiment of the phosphorescent thermal transfer medium of the present invention. (Symbols in drawings) (1) Two base films (2): GL type agent layer (31): Protective resin layer (3): Phosphorescent transfer layer (32): Adhesive layer

Claims (1)

【特許請求の範囲】 1 ベースフィルムの上に直接または離型剤層を介して
、少なくとも燐光性転写層を形成したことを特徴とする
燐光性感熱転写媒体。 2 前記燐光性転写層がベースフィルムの上に直接また
は離型剤層を介して、少なくとも保護樹脂塗膜層、燐光
性転写層を順次形成してなる特許請求の範囲第1項記載
の燐光性感熱転写媒体。 3 前記燐光性転写層がベースフィルムの上に直接また
は離型剤層を介して、少なくとも燐光性転写層、接着剤
層を順次形成してなる特許請求の範囲第1項記載の燐光
性感熱転写媒体。 4 前記燐光性転写層がベースフィルムの上に直接また
は離型剤層を介して、少なくとも保護樹脂塗膜層、燐光
性転写層、接着剤層を順次形成してなる特許請求の範囲
第1項記載の燐光性感熱転写媒体。
[Scope of Claims] 1. A phosphorescent heat-sensitive transfer medium, characterized in that at least a phosphorescent transfer layer is formed on a base film either directly or via a release agent layer. 2. The phosphorescent sensitive material according to claim 1, wherein the phosphorescent transfer layer is formed by sequentially forming at least a protective resin coating layer and a phosphorescent transfer layer on a base film directly or via a release agent layer. Thermal transfer media. 3. The phosphorescent heat-sensitive transfer medium according to claim 1, wherein the phosphorescent transfer layer comprises at least a phosphorescent transfer layer and an adhesive layer sequentially formed on a base film directly or via a release agent layer. . 4. Claim 1, wherein the phosphorescent transfer layer is formed by sequentially forming at least a protective resin coating layer, a phosphorescent transfer layer, and an adhesive layer on the base film directly or via a release agent layer. The phosphorescent thermal transfer medium described.
JP61235555A 1986-10-03 1986-10-03 Phosphorescent thermal transfer medium Pending JPS6389385A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61235555A JPS6389385A (en) 1986-10-03 1986-10-03 Phosphorescent thermal transfer medium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61235555A JPS6389385A (en) 1986-10-03 1986-10-03 Phosphorescent thermal transfer medium

Publications (1)

Publication Number Publication Date
JPS6389385A true JPS6389385A (en) 1988-04-20

Family

ID=16987718

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61235555A Pending JPS6389385A (en) 1986-10-03 1986-10-03 Phosphorescent thermal transfer medium

Country Status (1)

Country Link
JP (1) JPS6389385A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02155694A (en) * 1988-12-07 1990-06-14 Mitsubishi Kasei Corp Thermal transfer recording medium
WO1998003346A1 (en) * 1996-07-23 1998-01-29 Minnesota Mining And Manufacturing Company Process for preparing high resolution emissive arrays and corresponding articles
US5981136A (en) * 1996-04-15 1999-11-09 3M Innovative Properties Company Laser addressable thermal transfer imaging element with an interlayer
EP1356953A1 (en) * 2002-04-24 2003-10-29 Daicel Chemical Industries, Ltd. Transfer sheets
US7396631B2 (en) 2005-10-07 2008-07-08 3M Innovative Properties Company Radiation curable thermal transfer elements
US7534543B2 (en) 1996-04-15 2009-05-19 3M Innovative Properties Company Texture control of thin film layers prepared via laser induced thermal imaging
US7678526B2 (en) 2005-10-07 2010-03-16 3M Innovative Properties Company Radiation curable thermal transfer elements

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4866152A (en) * 1971-12-14 1973-09-11
JPS5954598A (en) * 1982-09-21 1984-03-29 Fuji Kagakushi Kogyo Co Ltd Heat-sensitive fluorescent transfer medium
JPS61206693A (en) * 1985-03-12 1986-09-12 General Kk Thermal transfer recording medium
JPS61213195A (en) * 1985-03-19 1986-09-22 Ricoh Co Ltd Thermal fluorescent transfer medium

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4866152A (en) * 1971-12-14 1973-09-11
JPS5954598A (en) * 1982-09-21 1984-03-29 Fuji Kagakushi Kogyo Co Ltd Heat-sensitive fluorescent transfer medium
JPS61206693A (en) * 1985-03-12 1986-09-12 General Kk Thermal transfer recording medium
JPS61213195A (en) * 1985-03-19 1986-09-22 Ricoh Co Ltd Thermal fluorescent transfer medium

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02155694A (en) * 1988-12-07 1990-06-14 Mitsubishi Kasei Corp Thermal transfer recording medium
US6866979B2 (en) 1996-04-15 2005-03-15 3M Innovative Properties Company Laser addressable thermal transfer imaging element with an interlayer
US5981136A (en) * 1996-04-15 1999-11-09 3M Innovative Properties Company Laser addressable thermal transfer imaging element with an interlayer
US6099994A (en) * 1996-04-15 2000-08-08 3M Innovative Properties Company Laser addressable thermal transfer imaging element with an interlayer
US6190826B1 (en) 1996-04-15 2001-02-20 3M Innovative Properties Company Laser addressable thermal transfer imaging element with an interlayer
US6582877B2 (en) 1996-04-15 2003-06-24 3M Innovative Properties Company Laser addressable thermal transfer imaging element with an interlayer
US7226716B2 (en) 1996-04-15 2007-06-05 3M Innovative Properties Company Laser addressable thermal transfer imaging element with an interlayer
US7534543B2 (en) 1996-04-15 2009-05-19 3M Innovative Properties Company Texture control of thin film layers prepared via laser induced thermal imaging
US5998085A (en) * 1996-07-23 1999-12-07 3M Innovative Properties Process for preparing high resolution emissive arrays and corresponding articles
EP1028001A1 (en) * 1996-07-23 2000-08-16 Minnesota Mining And Manufacturing Company Organic electroluminescent display panel and method for fabricating the same by thermal transfer
WO1998003346A1 (en) * 1996-07-23 1998-01-29 Minnesota Mining And Manufacturing Company Process for preparing high resolution emissive arrays and corresponding articles
EP1356953A1 (en) * 2002-04-24 2003-10-29 Daicel Chemical Industries, Ltd. Transfer sheets
US7396631B2 (en) 2005-10-07 2008-07-08 3M Innovative Properties Company Radiation curable thermal transfer elements
US7678526B2 (en) 2005-10-07 2010-03-16 3M Innovative Properties Company Radiation curable thermal transfer elements

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