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JPS6367481A - Diaphragm valve - Google Patents

Diaphragm valve

Info

Publication number
JPS6367481A
JPS6367481A JP21328786A JP21328786A JPS6367481A JP S6367481 A JPS6367481 A JP S6367481A JP 21328786 A JP21328786 A JP 21328786A JP 21328786 A JP21328786 A JP 21328786A JP S6367481 A JPS6367481 A JP S6367481A
Authority
JP
Japan
Prior art keywords
diaphragm
valve
stress
valve body
deflection
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP21328786A
Other languages
Japanese (ja)
Inventor
Takaomi Haniyu
羽生 孝臣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Benkan Corp
Original Assignee
Nippon Benkan Kogyo Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Benkan Kogyo Corp filed Critical Nippon Benkan Kogyo Corp
Priority to JP21328786A priority Critical patent/JPS6367481A/en
Publication of JPS6367481A publication Critical patent/JPS6367481A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To prevent the fatigue breakdown by concentrically providing an annular recess on a diaphragm and mitigating the internal stress of the diaphragm due to deflection with the annular recess. CONSTITUTION:When a pressing force is applied to the center section of a diaphragm 31 by a valve stem 32, the predetermined deflection is generated. The bending stress in the thickness direction and the stress in the radial direction are generated against the predetermined deflection quantity in the thickness direction of the diaphragm 31, but an annular groove 39 is formed on the diaphragm 31, thus the actual diameter length when the diaphragm 31 is extended becomes long. Accordingly, various stress values such as the bending stress in the thickness direction and the stress in the radial direction are mitigated, and fatigue breakdown is prevented.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は、LSI或いは超LSI製)肯装置の配管ライ
ンに使用される超タリンバルブとしてのダイヤフラム弁
の改良に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to an improvement of a diaphragm valve as a super-talin valve used in a piping line of an LSI or super LSI device.

[従来の技術] 従来、この種のダイヤフラム弁としては、第5図に小寸
如き横)聞のものが使用されている。図中1は弁箱で、
本体2と益体3とより成る。本体2は流体人口4及び流
体出口5と弁室6とを連通する流路7及び8を備え、入
口側流路7の内端部に弁座9が形成されている。弁座9
と接離自在に対向して弁室6内に設けられた弁体10は
、ばね部材11により開方向に付勢されている。蓋体3
には軸方向に摺動可能な弁軸12が設けられており、弁
軸12の内端部はスペーサ13を介して上記弁体10と
対向している。弁体10とスペーサ13との間に介在す
るダイヤフラム14は周縁部が本体2と蓋体3との間に
挟持されて弁箱1に支持されている。
[Prior Art] Conventionally, as this type of diaphragm valve, a horizontally sized diaphragm valve as shown in FIG. 5 has been used. 1 in the figure is the valve box,
It consists of a main body 2 and a beneficial body 3. The main body 2 includes channels 7 and 8 that communicate the fluid port 4 and the fluid outlet 5 with a valve chamber 6, and a valve seat 9 is formed at the inner end of the inlet channel 7. Valve seat 9
A valve element 10 is provided in the valve chamber 6 so as to be movable toward and away from the valve element 10, and is biased in the opening direction by a spring member 11. Lid body 3
is provided with a valve shaft 12 that is slidable in the axial direction, and the inner end of the valve shaft 12 faces the valve body 10 with a spacer 13 interposed therebetween. A diaphragm 14 interposed between the valve body 10 and the spacer 13 is supported by the valve body 1 with its peripheral edge being held between the main body 2 and the lid body 3.

斯かる構造のダイヤフラム弁に於いて、弁軸12を下方
へ押し下げると、弁軸12の先端はスペーサ13を介し
てダイヤフラム14を下方へ押し下げ、この押し下げ力
は弁体10をばね部材11のばね力に抗して弁座9の方
向へ押し下げ、ついには弁体10の下面が弁座9に圧着
され、流体入口4I:達する流路7と流体出口に達する
流路8が遮断され、内部流体の流れが止まる。弁軸12
の押し下げ力を解放すると弁体10はばね部材11によ
り押し戻され、これによりダイヤフラム14も押し戻さ
れ、さらにスペーサ13及び弁@12が元位置に押し戻
される。この過程で弁体10の下面は弁座9から離れ、
流路7と流路8が連通し、内部流体が弁中を流れる。
In a diaphragm valve having such a structure, when the valve stem 12 is pushed down, the tip of the valve stem 12 pushes down the diaphragm 14 via the spacer 13, and this pushing down force causes the valve body 10 to be pushed down by the spring of the spring member 11. The lower surface of the valve body 10 is pressed against the valve seat 9 against the force, and the flow path 7 reaching the fluid inlet 4I and the flow path 8 reaching the fluid outlet are blocked, and the internal fluid is The flow stops. Valve stem 12
When the pressing force is released, the valve body 10 is pushed back by the spring member 11, which also pushes back the diaphragm 14, and further pushes the spacer 13 and valve @12 back to their original positions. In this process, the lower surface of the valve body 10 separates from the valve seat 9,
Flow path 7 and flow path 8 communicate with each other, and internal fluid flows through the valve.

上記ダイヤフラム弁の作動の過程で、蓋体3と弁軸12
がこすれて金属粒子が下方に落下し、弁体10の内部に
金属粒子が侵入するのをダイヤフラム14は防止してい
るが、このダイヤフラム14が通常の金属薄板であると
、弁体10に必要とされるに十分な撓み但を与えること
ができない。もし弁体10が必要とするストローク(リ
フト)に相当する撓み量をダイヤフラム14に与えたと
すると、ダイヤフラム14は塑性変形してしまい、撓み
がそのまま残ってしまうことになる。そこでこれを防止
する為にダイヤフラム14の径を大きくすることが考え
られるが、これを実施すると、弁そのものが大きくなり
、LSI或いは超LSI製造装置の配管ラインに使用す
る弁としては不適当である。また塑性変形の無いゴム製
のダイヤフラムを用いることが考えられるが耐久性に劣
り、且つ劣化に伴う微細なゴム片の弁体内への落下等の
問題がある。
In the process of operation of the diaphragm valve, the lid body 3 and the valve stem 12
The diaphragm 14 prevents metal particles from falling downward due to friction and entering the inside of the valve body 10. However, if the diaphragm 14 is a normal thin metal plate, the valve body 10 has It is not possible to provide sufficient deflection to make it possible. If the amount of deflection corresponding to the stroke (lift) required by the valve body 10 is applied to the diaphragm 14, the diaphragm 14 will be plastically deformed and the deflection will remain as it is. In order to prevent this, it may be possible to increase the diameter of the diaphragm 14, but if this is done, the valve itself will become large, making it unsuitable for use in the piping line of LSI or VLSI manufacturing equipment. . It is also possible to use a rubber diaphragm that does not undergo plastic deformation, but it is inferior in durability and has problems such as minute rubber pieces falling into the valve body due to deterioration.

このようなことから、近時、弾性変形の可能な領域が大
きく、大きく変形させてもゴムの如く元に戻る性質を有
する超弾性金属材料で作られたダイヤフラムを備えた弁
が提案され(特開昭80−263793号公報)、これ
により弁体の内面の接ガス部へ超微細粒子(パーティク
ル)が弁外部より侵入したり、或いは弁軸の摺動作用に
よりバッキング材の劣化や金属擦過によるゴム及び金属
粒子が接ガス部へ落ち込んだりするのを防止している。
For this reason, recently, valves have been proposed that have a diaphragm made of a superelastic metal material that has a large area of elastic deformation and has the property of returning to its original state like rubber even if it is greatly deformed. (Japanese Patent Publication No. 80-263793), this may cause ultrafine particles to enter the gas contact part of the inner surface of the valve body from the outside of the valve, or the sliding action of the valve stem may cause deterioration of the backing material or metal abrasion. This prevents rubber and metal particles from falling into gas contact areas.

[発明が解決しようとする問題点] 然し乍ら、斯かる従来のダイヤフラム弁に使用されてい
る超弾性金属材料より成るダイヤフラムも通常の金属と
同様疲労破壊の現象を免れることはできない。従って、
上記ダイヤフラムを備えたダイヤフラム弁でも弁の開閉
を105回も繰り返すと、金属疲労の為に破断してしま
うという欠点かあった。この為ダイヤフラム弁の寿命が
短く、保守が甚だ煩わしかった。
[Problems to be Solved by the Invention] However, diaphragms made of superelastic metal materials used in such conventional diaphragm valves cannot escape the phenomenon of fatigue failure, just like ordinary metals. Therefore,
Even a diaphragm valve equipped with the above-mentioned diaphragm had the disadvantage that if the valve was opened and closed 105 times, it would break due to metal fatigue. For this reason, the life of the diaphragm valve was short and maintenance was extremely troublesome.

[発明の目的] 本発明は、上記問題点を解決すべくなされたものであり
、ダイヤフラムの径を小さいままにとどめ、且つこれが
疲労破壊を起さない応力レベルまでダイヤフラムの撓み
に伴う応力値を低下させて、寿命を増長し、保守の煩わ
しさを除去したダイヤフラム弁を提供することを目的と
するものである。
[Object of the Invention] The present invention has been made to solve the above-mentioned problems, and it is possible to keep the diameter of the diaphragm small and to reduce the stress value associated with the deflection of the diaphragm to a stress level that does not cause fatigue failure. It is an object of the present invention to provide a diaphragm valve which has a long service life and eliminates the trouble of maintenance.

[問題点を解決するための手段1 上記問題点を解決するための本発明のダイヤフラム弁は
、周縁部が弁箱に支持されて弁棒と弁体との間に介在さ
れた超弾性金属材料より成る薄い円板状のダイヤフラム
を有する弁に於いて、前記ダイヤフラムに少くとも一条
の環状凹部を同芯に設けたことを特徴とするものである
[Means for Solving the Problems 1] The diaphragm valve of the present invention for solving the above-mentioned problems includes a superelastic metal material whose peripheral portion is supported by the valve body and which is interposed between the valve stem and the valve body. A valve having a thin disk-shaped diaphragm is characterized in that the diaphragm is provided with at least one annular recess concentrically.

[作 用] 上記の如く構成された本発明のダイヤフラム弁は、弁の
作動によりダイヤフラムに所定の撓みが与えられた時、
撓みに伴うダイヤフラムの内部応力が、少くとも一条の
環状凹部により軽減され、応力値がダイヤフラムを形成
している金属の疲労限以下に低下せしめられるので、疲
労破壊が免れるものである。
[Function] The diaphragm valve of the present invention configured as described above, when a predetermined deflection is applied to the diaphragm by the operation of the valve,
The internal stress of the diaphragm due to deflection is reduced by at least one annular recess, and the stress value is lowered below the fatigue limit of the metal forming the diaphragm, thereby avoiding fatigue failure.

[実施例] 本発明のダイヤフラム弁の一実施例を第1図によって説
明すると、20は逆T形の弁箱で、垂直部20aに弁室
21が形成され、水平部20bに流体入口22及び流体
出口23と弁室21とを連通する流路24及び25が形
成され、入口側流路24の内端側は弁室21と同芯に垂
直となっていて、その周縁は弁座26となっている。弁
座26に密着されるように弁室21内の中心に設けられ
た弁体21は、スプリング28により上方に付勢されて
いる。弁室21の上部内周面には段部29が設けられ、
この段部29上にシールリング30が配され、その上に
超弾性現象を示す金属材料より成るダイヤフラム31の
周縁が支持され、そのダイヤフラム31の周縁上に弁体
32に嵌装した筒状ガイド33が支持され、この筒状ガ
イド33がその外周に嵌装され且つ弁箱20の垂直部2
0aの外周に螺合されたナツト34にて締付固定されて
、前記ダイヤフラム31の周縁も固定されている。前記
弁棒32はエアシリンダ35のピストン36に基端が結
合されており、エアシリンダ35はエアシリンダ蓋37
が前記筒状ガイド33の外周に螺合されて弁箱20に結
合されている。38はエアシリンダ35内のリターンス
プリングである。
[Embodiment] An embodiment of the diaphragm valve of the present invention will be described with reference to FIG. 1. Reference numeral 20 is an inverted T-shaped valve box, in which a valve chamber 21 is formed in a vertical portion 20a, and a fluid inlet 22 and a fluid inlet 22 are formed in a horizontal portion 20b. Flow paths 24 and 25 are formed that communicate the fluid outlet 23 and the valve chamber 21, and the inner end of the inlet flow path 24 is perpendicular to the valve chamber 21, and its periphery is connected to the valve seat 26. It has become. The valve body 21 is provided at the center of the valve chamber 21 so as to be in close contact with the valve seat 26, and is urged upward by a spring 28. A stepped portion 29 is provided on the upper inner peripheral surface of the valve chamber 21,
A seal ring 30 is disposed on the stepped portion 29, on which the periphery of a diaphragm 31 made of a metal material exhibiting a superelastic phenomenon is supported, and a cylindrical guide fitted into the valve body 32 is placed on the periphery of the diaphragm 31. 33 is supported, this cylindrical guide 33 is fitted on the outer periphery, and the vertical part 2 of the valve body 20
It is tightened and fixed by a nut 34 screwed onto the outer periphery of the diaphragm 31, and the periphery of the diaphragm 31 is also fixed. The valve stem 32 has a base end connected to a piston 36 of an air cylinder 35, and the air cylinder 35 is connected to an air cylinder lid 37.
is screwed onto the outer periphery of the cylindrical guide 33 and connected to the valve box 20. 38 is a return spring inside the air cylinder 35.

前記の超弾性現象を示す金属材料より成るダイヤフラム
31は、第2図a、bに示す如く薄い円板形状に作られ
、周方向に同志に断面円弧状の環状溝39が予め塑性加
工により一条形成されて成るものである。
The diaphragm 31 made of a metal material exhibiting the above-mentioned superelastic phenomenon is made into a thin disc shape as shown in FIGS. It is formed by

尚、ダイヤフラム31は、第2図に限るものではなく、
第3図a、bに示す如く環状溝39が同芯二条或いは三
条に形成されたダイヤフラム40でも良く、また第4図
a、bに示す如く半径方向に断面波形状となる複数条の
凹部41と凸部42が交互に同志に形成されたダイヤフ
ラム43でも良い。
Note that the diaphragm 31 is not limited to that shown in FIG.
A diaphragm 40 in which the annular groove 39 is formed in two or three concentric grooves as shown in FIGS. 3a and b, or a plurality of recesses 41 having a wave-shaped cross section in the radial direction as shown in FIGS. 4a and b A diaphragm 43 may be used in which convex portions 42 and convex portions are alternately formed.

上述の如く構成された第1図のダイヤフラム弁に於いて
、エアシリンダ35の上室に作動エアが導入され、これ
によりピストン36が下方へ押し下げられると、弁棒3
2も下方へ下がる。これに伴い弁体27はダイヤフラム
31を介して下方へ押し下げられ、弁体27の下面が弁
室21の底面の弁座26に押付けられて、流路24.2
5が遮断され、内部流体の流れが止まる。
In the diaphragm valve of FIG. 1 configured as described above, when operating air is introduced into the upper chamber of the air cylinder 35 and the piston 36 is pushed downward, the valve stem 3
2 also falls downward. Accordingly, the valve body 27 is pushed down via the diaphragm 31, and the lower surface of the valve body 27 is pressed against the valve seat 26 on the bottom surface of the valve chamber 21, causing the flow path 24.
5 is shut off, stopping the flow of internal fluid.

エアシリンダ35のエア圧が除かれると、リターンスプ
リング38の復帰力によってピストン36が元位置に押
し戻され、これに伴い弁棒32も上方に上がり、弁体2
7及びダイヤフラム31はスプリング28の力で上方へ
持ち上げられ、弁体27の下面が弁室21の底面の弁座
26から離れて、流路24.25が連通され、内部流体
が弁中を流れる。
When the air pressure in the air cylinder 35 is removed, the piston 36 is pushed back to its original position by the return force of the return spring 38, and the valve rod 32 also rises upward, causing the valve body 2 to move upward.
7 and the diaphragm 31 are lifted upward by the force of the spring 28, the lower surface of the valve body 27 is separated from the valve seat 26 on the bottom surface of the valve chamber 21, the flow passages 24 and 25 are communicated, and the internal fluid flows through the valve. .

斯かるダイヤフラム弁の開閉に於いて、ダイヤフラム3
1は、その中心部に弁棒32による押し力が作用した時
所定の撓みを生じる。ダイヤフラム31は弁の構造上そ
の外周部が固定されている為、板厚方向の所定の撓み量
に対し、板厚方向の曲げ応力、半径方向の応力1周方向
の応力等が生じるが、該ダイヤフラム31には一条の環
状溝39が形成されているので、ダイヤフラム31が引
き延ばされた時の径実長は長くなる。従って、前記の板
厚方向の曲げ応力、半径方向の応力2周方向の応力等の
各種応力値は著しく軽減される。この現象はベローズや
つる巻ばねに見られる物理現象と同等のちのである。こ
のようにして各種応力値がダイヤフラム31の疲労限以
下に低下せしめられ、疲労破壊が免れる。
In opening and closing such a diaphragm valve, the diaphragm 3
1 causes a predetermined deflection when a pushing force from the valve stem 32 is applied to its center. Because the outer circumference of the diaphragm 31 is fixed due to the structure of the valve, bending stress in the thickness direction, stress in the radial direction, stress in the circumferential direction, etc. occur for a predetermined amount of deflection in the thickness direction. Since the single annular groove 39 is formed in the diaphragm 31, the actual diameter length becomes longer when the diaphragm 31 is stretched. Therefore, various stress values such as the bending stress in the plate thickness direction, the radial stress, and the circumferential stress are significantly reduced. This phenomenon is similar to the physical phenomenon seen in bellows and helical springs. In this way, various stress values are reduced below the fatigue limit of the diaphragm 31, and fatigue failure is avoided.

このような応力軽減現象は、第3図及び第4図のダイヤ
フラム40.43を備えたダイヤフラム弁でも同様に環
われることは勿論である。
It goes without saying that such a stress reduction phenomenon also occurs in the diaphragm valve having the diaphragm 40, 43 shown in FIGS. 3 and 4.

[発明の効果] 以上の説明で判るように本発明のダイヤフラム弁は、少
くとも一条の環状凹部を同志に設けた超弾性金属材料よ
り成る薄い円板状のダイヤフラムを弁体と弁棒との間に
設けであるので、ダイヤフラムの径が小さくとも弁作動
時ダイヤフラムに撓みが与えられた際、撓みに伴う内部
応力が環状の凹凸部により軽減され、応力値が超弾性金
属材料の疲労限以下に低下せしめられ、疲労破壊が免れ
る。従って、弁の開閉を107回繰返しても破断するこ
とが無く、ダイヤフラム弁の寿命が著しく増良し、保守
の煩しさが除去されるという優れた効果を奏する。
[Effects of the Invention] As can be seen from the above description, the diaphragm valve of the present invention has a thin disc-shaped diaphragm made of a superelastic metal material and provided with at least one annular recessed part, which is connected to the valve body and the valve stem. Even if the diameter of the diaphragm is small, when the diaphragm is deflected during valve operation, the internal stress associated with the deflection is reduced by the annular unevenness, and the stress value is below the fatigue limit of the superelastic metal material. It is possible to avoid fatigue failure. Therefore, even if the valve is opened and closed 107 times, it will not break, and the life of the diaphragm valve will be significantly extended, and the troublesome maintenance will be eliminated.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明によるダイヤフラム弁の一実施例を示す
縦断面図、第2図a、bはそのダイヤフラム弁に装備さ
れたダイヤフラムの平面図及び断面図、第3図a、bは
ダイヤフラムの変形例を示す平面図及び断面図、第4図
a、bはダイヤフラムのさらに他の変形例を示す平面図
及び断面図、第5図は従来のダイヤフラム弁を示す縦断
面図である。 20・・・弁箱       27・・・弁体31、4
0.43・・・ダイヤフラム 32・・・弁棒       39・・・環状溝41・
・・凹部       41・・・凸部用 願 人  
日本弁管工業株式会社 代 理 人  弁理士 高   雄次部。 第1図 第2図    第3図 第4図 (a) 第5図
Fig. 1 is a longitudinal sectional view showing one embodiment of a diaphragm valve according to the present invention, Figs. 2 a and b are a plan view and a sectional view of a diaphragm installed in the diaphragm valve, and Figs. 3 a and b are views of the diaphragm. FIGS. 4a and 4b are a plan view and a sectional view showing another modification of the diaphragm, and FIG. 5 is a longitudinal sectional view showing a conventional diaphragm valve. 20... Valve box 27... Valve body 31, 4
0.43...Diaphragm 32...Valve stem 39...Annular groove 41.
...Concave portion 41...For convex portion Request person
Nippon Benkan Kogyo Co., Ltd. Representative Patent Attorney Yujibe Taka. Figure 1 Figure 2 Figure 3 Figure 4 (a) Figure 5

Claims (1)

【特許請求の範囲】[Claims] 周縁部が弁箱に支持されて弁棒と弁体との間に介在され
た超弾性金属材料より成る薄い円板状のダイヤフラムを
有する弁に於いて、前記ダイヤフラムに少くとも一条の
環状凹部を同芯に設けたことを特徴とするダイヤフラム
弁。
In a valve having a thin disk-shaped diaphragm made of a superelastic metal material and having a peripheral edge supported by a valve body and interposed between a valve stem and a valve body, at least one annular recess is formed in the diaphragm. A diaphragm valve characterized by being installed concentrically.
JP21328786A 1986-09-10 1986-09-10 Diaphragm valve Pending JPS6367481A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP21328786A JPS6367481A (en) 1986-09-10 1986-09-10 Diaphragm valve

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP21328786A JPS6367481A (en) 1986-09-10 1986-09-10 Diaphragm valve

Publications (1)

Publication Number Publication Date
JPS6367481A true JPS6367481A (en) 1988-03-26

Family

ID=16636614

Family Applications (1)

Application Number Title Priority Date Filing Date
JP21328786A Pending JPS6367481A (en) 1986-09-10 1986-09-10 Diaphragm valve

Country Status (1)

Country Link
JP (1) JPS6367481A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02271168A (en) * 1989-04-11 1990-11-06 Benkan Corp diaphragm valve
JPH0348072A (en) * 1989-06-21 1991-03-01 Benkan Corp Metal-to-metal contact diaphragm valve
JPH0379875A (en) * 1989-08-19 1991-04-04 Benkan Corp Metal-to-metal contact diaphragm valve
JP2004060741A (en) * 2002-07-26 2004-02-26 Motoyama Eng Works Ltd Diaphragm, diaphragm valve, and film forming device
KR100698835B1 (en) 2003-12-10 2007-03-26 엠알엠 주식회사 Valve device
US7384580B2 (en) * 2004-04-02 2008-06-10 Ludwig-Maximilians-Universitat Munchen Method of preparing organomagnesium compounds

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60263793A (en) * 1984-06-13 1985-12-27 Motoyama Seisakusho:Kk Diaphragm valve

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60263793A (en) * 1984-06-13 1985-12-27 Motoyama Seisakusho:Kk Diaphragm valve

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02271168A (en) * 1989-04-11 1990-11-06 Benkan Corp diaphragm valve
JPH0348072A (en) * 1989-06-21 1991-03-01 Benkan Corp Metal-to-metal contact diaphragm valve
JPH0379875A (en) * 1989-08-19 1991-04-04 Benkan Corp Metal-to-metal contact diaphragm valve
JP2004060741A (en) * 2002-07-26 2004-02-26 Motoyama Eng Works Ltd Diaphragm, diaphragm valve, and film forming device
KR100698835B1 (en) 2003-12-10 2007-03-26 엠알엠 주식회사 Valve device
US7384580B2 (en) * 2004-04-02 2008-06-10 Ludwig-Maximilians-Universitat Munchen Method of preparing organomagnesium compounds

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