JPS6348372A - Ink material - Google Patents
Ink materialInfo
- Publication number
- JPS6348372A JPS6348372A JP61193295A JP19329586A JPS6348372A JP S6348372 A JPS6348372 A JP S6348372A JP 61193295 A JP61193295 A JP 61193295A JP 19329586 A JP19329586 A JP 19329586A JP S6348372 A JPS6348372 A JP S6348372A
- Authority
- JP
- Japan
- Prior art keywords
- alkoxide
- binder
- weight
- ink
- ink material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 25
- 239000011230 binding agent Substances 0.000 claims abstract description 23
- 150000004703 alkoxides Chemical class 0.000 claims abstract description 12
- 239000002904 solvent Substances 0.000 claims abstract description 12
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 6
- 229910052788 barium Inorganic materials 0.000 claims abstract description 5
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 5
- 239000011575 calcium Substances 0.000 claims abstract description 5
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 5
- 239000011777 magnesium Substances 0.000 claims abstract description 5
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 5
- 239000010703 silicon Substances 0.000 claims abstract description 5
- 229910052712 strontium Inorganic materials 0.000 claims abstract description 5
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 5
- 239000010936 titanium Substances 0.000 claims abstract description 5
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 5
- -1 silicon alkoxide Chemical class 0.000 claims description 32
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 239000003086 colorant Substances 0.000 claims description 3
- 125000003158 alcohol group Chemical group 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 15
- 238000004040 coloring Methods 0.000 abstract description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 abstract 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 235000019441 ethanol Nutrition 0.000 description 7
- 238000002834 transmittance Methods 0.000 description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 2
- 238000012643 polycondensation polymerization Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium ethoxide Chemical compound [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 description 2
- 229910052724 xenon Inorganic materials 0.000 description 2
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 2
- NLSFWPFWEPGCJJ-UHFFFAOYSA-N 2-methylprop-2-enoyloxysilicon Chemical compound CC(=C)C(=O)O[Si] NLSFWPFWEPGCJJ-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 125000005233 alkylalcohol group Chemical group 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- CPUJSIVIXCTVEI-UHFFFAOYSA-N barium(2+);propan-2-olate Chemical compound [Ba+2].CC(C)[O-].CC(C)[O-] CPUJSIVIXCTVEI-UHFFFAOYSA-N 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- MUJRNJDKBBSXSE-UHFFFAOYSA-N calcium;butan-1-olate Chemical compound [Ca+2].CCCC[O-].CCCC[O-] MUJRNJDKBBSXSE-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- ASBGGHMVAMBCOR-UHFFFAOYSA-N ethanolate;zirconium(4+) Chemical compound [Zr+4].CC[O-].CC[O-].CC[O-].CC[O-] ASBGGHMVAMBCOR-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000001046 green dye Substances 0.000 description 1
- 239000001056 green pigment Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- ORPJQHHQRCLVIC-UHFFFAOYSA-N magnesium;propan-2-olate Chemical compound CC(C)O[Mg]OC(C)C ORPJQHHQRCLVIC-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 238000001782 photodegradation Methods 0.000 description 1
- 239000001044 red dye Substances 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- OHULXNKDWPTSBI-UHFFFAOYSA-N strontium;propan-2-olate Chemical compound [Sr+2].CC(C)[O-].CC(C)[O-] OHULXNKDWPTSBI-UHFFFAOYSA-N 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明はインキ材料に関するものであり、特にカラーフ
ィルタに用いるのに適したインキ材料に関するものであ
る。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to ink materials, and particularly to ink materials suitable for use in color filters.
従来の技術
一般にインキ材料は、色材、バインダー、および溶剤よ
シ構成される。従来、バインダーとしてよく用いられて
きた材料ばＵＶ硬化型樹脂、酸化重合型樹脂などの有機
系文脂であった。また、溶剤には油性と水性とがあシ、
油性には乾性油などが用いられてきた。色材には染料と
顔料とがあり、それぞれに有機系と無機系とがある。BACKGROUND OF THE INVENTION Ink materials generally consist of a colorant, a binder, and a solvent. Conventionally, materials that have been frequently used as binders have been organic resins such as UV-curable resins and oxidation-polymerized resins. In addition, there are both oil-based and water-based solvents.
Drying oils have been used as oils. Coloring materials include dyes and pigments, each of which can be organic or inorganic.
発明が解決しようとする問題点
従来、インキ材料に用いられている有機系樹脂は光照射
により徐々に劣化し、光透過率（光反射率）が低下する
などの欠点があった。したがって、また色材の劣化、す
なわち、退色、変色なども進行するという欠点かった。Problems to be Solved by the Invention Conventionally, organic resins used in ink materials have had drawbacks such as gradual deterioration due to light irradiation and a decrease in light transmittance (light reflectance). Therefore, there is also the disadvantage that deterioration of the coloring material, ie, fading and discoloration, progresses.
すなわち、従来のインキ材料は光劣化を多かれ少なかれ
避けられなかったものである。That is, conventional ink materials cannot more or less avoid photodegradation.
問題点を解決するだめの手段
バインダーとして、シリコンアルコキシド、チタニウム
アルコキシド、ジルコニウムアルコキシド、アルミニウ
ムアルコキシド、マグネシウムアルコキシド、カルシウ
ムアルコキシド、ストロンチウムアルコキシド、および
バリウムアルコキシドからなる金属アルコキシド群から
選ばれた少なくとも１種を含有する。As a means to solve the problem, the binder contains at least one member selected from the metal alkoxide group consisting of silicon alkoxide, titanium alkoxide, zirconium alkoxide, aluminum alkoxide, magnesium alkoxide, calcium alkoxide, strontium alkoxide, and barium alkoxide. .
作 用
金属アルコキシド多液をゆっくりと加水分解さくＭｅ：
金属原子、Ｏ：酸素原子）の結合を含む鎖状または網目
状の重合体（ゲル体）となる。この結合は光に対して極
めて安定である、と同時に、重合体の網目の中に固定さ
れた染料、顔料、又は重合体のミクロポア（直径１ｏ○
〇八以下）内に固定された染料、顔料は化学結合されて
おり、耐光性が向上する。Action: Slowly hydrolyzing metal alkoxide multi-liquid Me:
It becomes a chain or network polymer (gel body) containing bonds of metal atoms and O (oxygen atoms). This bond is extremely stable to light and, at the same time, the dye, pigment, or polymer micropores (100 mm in diameter) immobilized within the polymer network.
The dyes and pigments fixed in the material (under 08) are chemically bonded, improving light resistance.
実施例
本発明で用いた色材は、例えば赤色
（λ！１１１ａ、＝６３０±１０ｎｍ）、緑色（λｍａ
ｘ＝５４０±１Ｑｎｍ）青色（λｍａ工＝４３０±１０
ｎｍ） の三原色をそれぞれ呈する有機系色材である
０色材の材質としては顔料および染料のいずれをも用い
ることができる。Examples The coloring materials used in the present invention are, for example, red (λ!111a, =630±10nm), green (λma
x=540±1Qnm) Blue (λma engineering=430±10
Both pigments and dyes can be used as the material for the coloring material, which is an organic coloring material exhibiting each of the three primary colors (nm).
バインダーとしてはシリコンアルコキシド、チタニウム
アルコキシド、ジルコニウムアルコキシド。Binders include silicon alkoxide, titanium alkoxide, and zirconium alkoxide.
アルミニウムアルコキシド、マグネシウムアルコキシド
、カルシウムアルコキシド、ストロンチウムアルコキシ
ド、およびバリウムアルコキシドを用いた。この他、架
橋させるためにバインダーの一部として（バインダー全
体に対して４０重量％未満）不飽和基を有する重合性七
ツマー９開環性重合性モノマーをも用いた。例えば、メ
チルメタクリレート、メタクリロキシシラン、エポキシ
シランなどである。これらのバインダーの含量はインキ
材料全体に対して３０〜８０重量％の範囲が望ましい。Aluminum alkoxide, magnesium alkoxide, calcium alkoxide, strontium alkoxide, and barium alkoxide were used. In addition, a polymerizable heptamer 9 ring-opening polymerizable monomer having an unsaturated group was also used as part of the binder (less than 40% by weight based on the total binder) for crosslinking. Examples include methyl methacrylate, methacryloxysilane, and epoxysilane. The content of these binders is preferably in the range of 30 to 80% by weight based on the total ink material.
さらに上記金属アルコキシドを溶解する溶剤としてはア
ルキルアルコールを用いた。さらに上記金属アルコキシ
ドの加水分解による縮重合をゆっくりと行なわしめるた
めにアンモニア水溶液を上記金属アルコキシド、溶剤の
中に添加混合した。Furthermore, alkyl alcohol was used as a solvent for dissolving the metal alkoxide. Further, an ammonia aqueous solution was added and mixed into the metal alkoxide and the solvent in order to slowly carry out condensation polymerization by hydrolysis of the metal alkoxide.
実施例１
赤色顔料としてブリリアントカーミ７６Ｂの微粉末を６
０ Ｍ量％ ＋バインダーとしてシリコンテトラエトキ
シドを２６重量％、アルミニウムイソプロポキシドを６
重量％、およびインプロビールアルコールを８重量％を
乾燥Ｎ２中で充分に分散。Example 1 Fine powder of Brilliant Carmi 76B was used as a red pigment.
0 M amount% + 26% by weight of silicone tetraethoxide and 6% of aluminum isopropoxide as a binder
% by weight, and 8% by weight of Improv alcohol was well dispersed in dry N2.
混練して赤色インキ材料とした。The mixture was kneaded to obtain a red ink material.
次に、緑色顔料としてフタロシアニングリーンの微粉末
を５０重量係、バインダーとしてシリコンテトラエトキ
シドを３２重量係、アルミニウムインプロポキシドを８
重量％、およびインプロビールアルコールを１０重量％
を乾燥Ｎ２中で充分に分散、混練して緑色インキ材料と
した。Next, 50 parts by weight of fine powder of phthalocyanine green as a green pigment, 32 parts by weight of silicon tetraethoxide as a binder, and 8 parts by weight of aluminum impropoxide.
% by weight, and 10% by weight of Impro beer alcohol.
were sufficiently dispersed and kneaded in dry N2 to obtain a green ink material.
次に青色顔料としてフタロシアニンブルーの微粉末を３
６重量％、バインダーとしてチタニウムテトラエトキシ
ドを３５重量％、アルミニウムイソプロポキシドを１２
重量係、カルシウムブトオキシドを８重量％、およびエ
チルアルコールを５重量係、インプロビールアルコール
を５重量％を乾燥Ｎ２中で充分に分散、混練して青色イ
ンキとした。Next, add 3 fine powders of phthalocyanine blue as a blue pigment.
6% by weight, 35% by weight of titanium tetraethoxide as a binder, and 12% of aluminum isopropoxide.
A blue ink was prepared by thoroughly dispersing and kneading 8% by weight of calcium butoxide, 5% by weight of ethyl alcohol, and 5% by weight of Improv alcohol in dry N2.
以上、調合した赤インキ、緑インキ、および青インキの
それぞれを、清浄なガラス板の上に印刷塗布した後、３
０℃、相対湿度７０％の中でゆっくｐと加水分解させ、
縮重合させて、それぞれのカラーフィルタを作成した。After printing and coating each of the above-prepared red ink, green ink, and blue ink on a clean glass plate,
Slowly hydrolyze with p at 0℃ and 70% relative humidity,
Each color filter was created by condensation polymerization.
赤、緑、青の各フィルタについて、１ｏｏｍＷ／ｃｒｔ
ｌのキセノン光を１０００Ｈｒ照射した後のλｍａ工で
の光透過率を測定した結果、いずれも透過率に経時変化
は見られなかった。1oomW/crt for each red, green, and blue filter
As a result of measuring the light transmittance of the λma process after irradiation with 1000 hours of xenon light, no change in transmittance over time was observed in any case.
実施例２
赤色染料としてアゾ系のＫａｙａｋｕ Ａｃ１ｄＢｒｉ
ｌｌｉａｎｔ Ｒｅｄ ３ Ｂ Ｌを３５重量％、バイ
ンダーとしてシリコンテトラエトキシドを３０重量％。Example 2 Azo-based Kayaku Ac1dBri as a red dye
35% by weight of lliant Red 3 B L and 30% by weight of silicone tetraethoxide as a binder.
ジルコニウムテトラエトキシドを６重量％、マグネシウ
ムイソプロポキシドを５重量％、溶剤としてメタノール
１５重量％、エタノール１重量係。6% by weight of zirconium tetraethoxide, 5% by weight of magnesium isopropoxide, 15% by weight of methanol and 1% by weight of ethanol as solvents.
およびアンモニア水溶液（ｐＨ＝９）３重ＪＴｈ ％を
充分に混練後、赤インキとして使用した。and ammonia aqueous solution (pH=9) 3x JTh% were thoroughly kneaded and used as a red ink.
緑色染料としてフタロシアニングリーンを３０重量係、
バインダーとしてシリコンテトラエトキシドを３ｏ重量
％、バリウムイソプロポキシドを１０重量％、溶剤とし
てメタノール１５重量％。30 parts by weight of phthalocyanine green as a green dye,
30% by weight of silicon tetraethoxide as a binder, 10% by weight of barium isopropoxide, and 15% by weight of methanol as a solvent.
エタノール１０重量％、およびアンモニア水溶液（ｐＨ
＝９ ）５重量％を充分に混練後、緑インキとして使用
した。10% by weight of ethanol, and aqueous ammonia solution (pH
=9) 5% by weight was sufficiently kneaded and used as a green ink.
次に、青色染料としてフタロシアニンブルーを３０重量
係、バインダーとしてチタニウムテトラエトキシドを３
ｏ重量係、アルミニウムイソプロポキシドを５重量％、
ストロンチウムイソプロポキシドを６Ｍ量チ、溶剤とし
てメタノール１５重量％、エタノール１０重量％、およ
び、アンモニア水溶液（ｐＨ＝９）５重量％を充分に混
線後、青インキとして使用した。Next, 30% by weight of phthalocyanine blue as a blue dye and 30% by weight of titanium tetraethoxide as a binder.
o weight ratio, 5% by weight of aluminum isopropoxide,
After sufficient mixing with 6 M of strontium isopropoxide, 15% by weight of methanol, 10% by weight of ethanol as solvents, and 5% by weight of ammonia aqueous solution (pH=9), it was used as a blue ink.
以上、調合した赤インキ、緑インキ、および青インキの
それぞれを、清浄なガラス板の上に印刷塗布した後、３
０°の温度でゆっくりと加水分解させ、縮重合させて、
それぞれのカラーフィルターを作成した。各フィルター
について、１００ｍＷ／ｃＡのキセノン光を１０００時
間照射した後のλｍａＸでの光透過率をり１１定した結
果、いずれにおいても透過率に経時変化は見られなかっ
た。After printing and coating each of the above-prepared red ink, green ink, and blue ink on a clean glass plate,
Slowly hydrolyzed and polycondensed at a temperature of 0°,
I created a color filter for each. For each filter, the light transmittance at λmax after 1000 hours of irradiation with 100 mW/cA xenon light was determined, and no change in transmittance over time was observed in any of the filters.
発明の効果
インキ材料の構成成分であるバインダーとして金属アル
コキシドを用いることにより、そのインキを用いて得ら
れるカラーフィルタの耐光性が向上した。Effects of the Invention By using a metal alkoxide as a binder, which is a constituent component of the ink material, the light resistance of a color filter obtained using the ink was improved.
Claims (5)
ンキ材料において、上記バインダーが、シリコンアルコ
キシド、チタニウムアルコキシド、ジルコニウムアルコ
キシド、アルミニウムアルコキシド、マグネシウムアル
コキシド、カルシウムアルコキシド、ストロンチウムア
ルコキシド、およびバリウムアルコキシドからなる金属
アルコキシド群から選ばれた少なくとも１種を含むこと
を特徴とするインキ材料。(1) In an ink material composed of a colorant, a binder, and a solvent, the binder is a metal alkoxide composed of silicon alkoxide, titanium alkoxide, zirconium alkoxide, aluminum alkoxide, magnesium alkoxide, calcium alkoxide, strontium alkoxide, and barium alkoxide. An ink material comprising at least one selected from the group.
ンアルコキシド、チタニウムアルコキシド、ジルコニウ
ムアルコキシド、アルミニウムアルコキシド、マグネシ
ウムアルコキシド、カルシウムアルコキシド、ストロン
チウムアルコキシド、およびバリウムアルコキシドから
なる金属アルコキシド群から選ばれた少なくとも１種か
らなることを特徴とする特許請求の範囲第１項記載のイ
ンキ材料。(2) 60% by weight or more of the binder is made of at least one metal alkoxide selected from the metal alkoxide group consisting of silicon alkoxide, titanium alkoxide, zirconium alkoxide, aluminum alkoxide, magnesium alkoxide, calcium alkoxide, strontium alkoxide, and barium alkoxide. The ink material according to claim 1, characterized in that:
請求の範囲第１項、又は第２項記載のインキ材料。(3) The ink material according to claim 1 or 2, wherein the solvent is an alcohol.
特許請求の範囲第１項、又は第２項記載のインキ材料。(4) The ink material according to claim 1 or 2, wherein the solvent is an alkaline aqueous solution.
ことを特徴とする特許請求の範囲第１項、又は第２項記
載のインキ材料。(5) The ink material according to claim 1 or 2, wherein the amount of the binder is 30 to 60% by weight of the total weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61193295A JPS6348372A (en) | 1986-08-19 | 1986-08-19 | Ink material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61193295A JPS6348372A (en) | 1986-08-19 | 1986-08-19 | Ink material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6348372A true JPS6348372A (en) | 1988-03-01 |
Family
ID=16305537
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61193295A Pending JPS6348372A (en) | 1986-08-19 | 1986-08-19 | Ink material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6348372A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5338350A (en) * | 1992-07-06 | 1994-08-16 | Central Glass Company, Limited | Ink composition for forming thin film |
| US6461419B1 (en) | 1999-11-01 | 2002-10-08 | 3M Innovative Properties Company | Curable inkjet printable ink compositions |
| JP2016206378A (en) * | 2015-04-21 | 2016-12-08 | Jsr株式会社 | Coloring composition, coloring cured film, and solid state imaging element |
-
1986
- 1986-08-19 JP JP61193295A patent/JPS6348372A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5338350A (en) * | 1992-07-06 | 1994-08-16 | Central Glass Company, Limited | Ink composition for forming thin film |
| US6461419B1 (en) | 1999-11-01 | 2002-10-08 | 3M Innovative Properties Company | Curable inkjet printable ink compositions |
| US6582804B2 (en) | 1999-11-01 | 2003-06-24 | 3M Innovative Properties Company | Curable inkjet printable ink compositions |
| US6719422B2 (en) | 1999-11-01 | 2004-04-13 | 3M Innovative Properties Company | Curable inkjet printable ink compositions |
| JP2016206378A (en) * | 2015-04-21 | 2016-12-08 | Jsr株式会社 | Coloring composition, coloring cured film, and solid state imaging element |
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