JPS63301808A - Hair-conditioning composition and treatment of hair - Google Patents

Abstract

PURPOSE:To obtain the titled composition having a specific melting point and giving flowable hair, by compounding waxes (e.g. Japan wax or beeswax), a higher alcohol and a cationic or anionic surfactant at specific ratios, wherein the sum of the above components accounts for a specific ratio in the whole composition. CONSTITUTION:The titled hair-conditioning composition contains (A) one or more waxes selected from candelilla wax, rice wax, cotton wax, ceresin, hardened castor oil, etc., (B) one or more kinds of higher alcohols and (C) a cationic surfactant or an anionic surfactant. The amounts of the components A, B and C are 20-55wt.%, 10-60wt.% and 5-30wt.%, respectively and the sum of the 3 components is 3-75wt.% based on the whole composition. The melting point of the mixture is 40-90 deg.C. The composition is free from stickiness and is capable of simultaneously imparting the hair with flowability, smoothness and bindability.

Description

DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a hair conditioning composition and a method for heating hair treatment. In particular, we have developed a hair conditioning composition that can provide overall effects such as smoothness, smoothness, ease of combing, ease of combing, and shine without making hair sticky, and this composition. The present invention relates to the hair treatment method used.

[Conventional technology]

Hair conditioning compositions that have the so-called conditioning effect of imparting smoothness and luster to hair and improving combability are generally commercially available under the names of hair rinses, hair treatments, hair conditioners, hair packs, and the like. These hair conditioning compositions contain a quaternary ammonium salt as the t component, and when this is adsorbed to the hair,
The above-mentioned so-called conditioning effect is a well-known fact. Furthermore, it improves the feel after use, such as smoothness, gloss, moistness, ease of bundling, body feel, etc. Oils and fats are added as appropriate. Recently, various natural and synthetic polymer compounds such as collagen polypeptide, keratin polypeptide, cationized cellulose, etc. have been added as appropriate for the purpose of repairing and protecting hair, especially damaged hair, and giving firmness to hair. has been done.

However, although conventional hair conditioning compositions of this type can provide smoothness without making hair sticky when applied and rinsed, they dry the hair when towel-dried after rinsing. "It has a satisfying smoothness after drying," which is especially sought after by young consumers these days.
It was not possible to simultaneously impart the effects of smoothness and ease of organizing.

As an example of research on prior art for imparting smoothness, which has been particularly sought after recently, a hair cosmetic characterized by containing a quaternary ammonium salt and a phosphoric ester
12608), and when this was used, a nearly satisfactory effect was obtained in terms of dryness and smoothness after drying. The results were not satisfactory in terms of slippery feel, smoothness, and ease of gathering after drying. In addition, as an example of research into a rinse conditioner that can better set or maintain a hairstyle, a hair rinse conditioner containing a cationic surfactant and a latex of water-insoluble film-forming polymer particles (Japanese Patent Application Laid-open No. 84211/1983) has been developed. be. Although this was excellent in terms of the effect of making it easy to put together, it was insufficient in terms of the effect of smoothness and smoothness. Further, research examples of prior art for imparting smoothness (Japanese Patent Application Laid-Open Nos. 58-180407, 1987-110611, etc.) were insufficient in both smoothness, smoothness, and ease of gathering.

Currently commercially available hair conditioning compositions do not have the effect of smoothing during and after drying, so they contain a large amount of liquid ester oil, so they can provide moist and smooth hair, but they have excellent dryness, silkiness and smoothness. There are almost no products that simultaneously satisfy the effects of making hair easier to manage.

[Problem that the invention seeks to solve]

Therefore, the object of the present invention is to impart excellent smoothness to the hair without making the hair sticky during application, rinsing, towel drying after rinsing, drying, and after drying, and particularly to provide excellent smoothness during drying and after drying. To provide a new hair conditioning composition and a hair treatment method that can simultaneously impart excellent smoothness, smoothness, and ease of hair combing.

[Means for solving problems]

1) For each hair conditioning composition such as hair rinse, hair treatment, hair conditioner, hair pack, etc., a small amount of a component such as a wax that is solid at room temperature, such as solid paraffin, is incorporated to improve the treatment after drying. It is known from experience that the texture becomes somewhat lighter and gives smoothness. The present inventors have learned about the effect of adding wax, and have addressed the above-mentioned drawbacks of conventional hair conditioning compositions, and in order to achieve the objects of the present invention, the following three aspects have been achieved, namely: (1) Conditioning hair Interrelationship between the melting point of an oily component mixture containing wax in a conditioning composition and dryness, smoothness, ease of putting together, and sticky feeling.

■ An effective method for adsorbing the wax component in hair conditioning compositions, which is the main component for smoothness, smoothness, and manageability, to hair.

■ In addition to the effects of excellent smoothness, smoothness, and ease of bundling, hair conditioning compositions are used to achieve comprehensive effects of the entire hair treatment process, such as ease of combing, gloss, and body feel. The effective main ingredients in the composition are wax, higher alcohol,
Type and quantitative balance of surfactants.

As a result of intensive research on the following, (a) Wax is an essential ingredient in order to achieve the effects of dryness, smoothness, and ease of gathering, and the melting point of the oily component mixture containing wax is an important point.

([1) By applying a hair conditioning composition containing wax to the hair and then heating it, the effects of dryness, smoothness, and ease of curling are dramatically improved.

(8) In order to achieve the overall effect mentioned in ■, the presence of the three components wax, higher alcohol, and cationic activator or anionic activator is essential, and it is necessary to maintain a certain balance among them. To be.

This discovery led to the completion of the present invention.

That is, the first aspect of the present invention is that as the component (A), candelilla wax, carnauba wax, rice wax, wood wax, jojoba wax,
Beeswax, shellac wax, cotton wax, sugarcane wax, hard lanolin, spermaceti wax, montan wax, ozokerite, ceresin, paraffin wax, microcrystalline wax, veterinarian [J-shita 1%, montan wax derivative, paraffin wax derivative, microcrystalline wax derivative , hydrogenated castor oil, hydrogenated castor oil derivatives,
12-Human [1 xystearic acid, stearamide 1. One or more types of wax selected from the wax group (Ibotaru) (I3) One or more types of higher alcohol (C) as a component
A hair conditioning composition containing a cationic activator or an anionic activator as a component, wherein the ratio of component (A) to the total amount of the three components listed in -1 is 20 to 55% by weight, and the ratio of component (B) is 20 to 55% by weight. is 10 to 60% by weight, and the proportion of component (C) is
In the range of 5 to 30% by weight, and the total amount of the above three components,
A hair conditioning composition characterized in that the content of the composition is 3 to 75% by weight based on the total amount of the composition, and the melting point of the mixture in the composition containing the three components and other oily components is 40 to 90°C. Further, the second invention is characterized in that after the specific hair conditioning composition is applied to the hair, the hair is heated at a temperature in the range of 40 to 180°C, and then cooled. This is a method for treating hair.

Note 2: In the present invention, "melting point" refers to the cosmetic raw material standards (
The temperature specified in Method 2 of the Melting Point Determination Method (Method 2) of the General Test Methods.

[Explanation of constituent components]

As component (A) of the composition of the present invention, among natural and synthetic waxes, those listed in claim (1) can be used. In addition to the above, waxes such as Fischer wax, polyethylene wax, phthalic anhydride, and chlorinated hydrocarbons are also used.
These substances are not suitable as ingredients for the present invention because they do not exhibit sufficient effects in terms of dryness, smoothness, and ease of gathering. Among the above ingredients (A), natural waxes include carnauba wax, candelilla wax,
Rice wax and ceresin give relatively good results, and as synthetic waxes, hydrogenated castor oil and stearic acid amide give relatively good results.

Examples of the higher alcohol which is component (B) of the composition of the present invention include alkyl groups such as lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, hexyldecanol, isostearyl alcohol, ocdyldodecanol, badyl alcohol, and behenyl alcohol. The number of carbon atoms is CI! ~C! Linear or side chain alcohols in the range 4 can be used alone or in mixtures, among which linear alcohols with relatively high melting points, such as myristyl alcohol, cetyl alcohol, stearyl alcohol, and behenyl alcohol, have shown good results. Gave.

Next, the cationic activator or anionic activator which is component (C) of the composition of the present invention is a primary to tertiary fatty amine salt l N II yll X quaternary ammonium salt tetraalkylammonium salt Tri Alkylbenzylammonium salt ・2-Alkyl-I-alkyl-I-hydroxyethylimidazolinium salt N,N-dialkylmorpholinium salt Polyethylenebolyamine fatty acid amide salt Acobel type [R,C0N1((C1-ItCII, N1-I) CO
R2]・11 Acid salt alkyl sulfonate (12-S 03) n Mm α-olefin sulfonate dialkyl sulfo succinate α-sulfonated fatty acid salt R-CHC00R 803M Sodium N-methyl-N-oleoyl taurine petroleum sulfonate Alkyl sulfate (ROS O3) nM ts
Sulfated fats and oils (castor oil, beef leg oil, olive oil, etc.) polyoxyethylene alkyl ether sulfate CFLO (CIl
tClltO)nS 0311 m ML Polyoxyethylene alkyl phenyl ether sulfate, polyoxyethylene styrenated phenyl ether sulfate, and the like are exemplified.

Among these, cationic activators are relatively superior in terms of overall effect, and among them, quaternary ammonium salts such as cetyltrimedelammonium chloride, stearyltrimethylammonium chloride, behenyltrimedelammonium chloride, distearyldimethylammonium chloride , cetyltrimethylammonium bromide, stearyltrimethylammonium bromide, and alkylpyridinium salts such as cetylpyridinium chloride, stearylpyridinium chloride, cetylpyridinium bromide, etc. are excellent.

Also, relatively good anion activators are polyoxyethylene alkyl ether sulfates, such as sodium polyoxyethylene alkyl ether sulfate, triethanolamine polyoxyethylene alkyl ether sulfate, sodium polyoxyethylene lauryl ether sulfate, and alkyl sulfates. Salts such as sodium stearyl sulfate, sodium cetyl sulfate, sodium myristyl sulfate, sodium lauryl sulfate, triethanolamine lauryl sulfate, and the like.

In the composition of the present invention, one! - In addition to the three essential ingredients listed above, oily ingredients that play various auxiliary roles in hair conditioning compositions include mink oil, turdle oil,
Animal and vegetable oils such as swan oil, squalane, orange roughy oil, olive oil, camellia oil, sasanqua oil, almond oil, macadamian nut oil, myristic acid, isopropyl phosphate, isopropyl palmitate, butyl stearate, hexyl laurate, myridine Esters such as myristyl acid, oleyl oleate, octyldodecyl myristate, cetyl lactate, diethyl phthalate, and 1 pill adipate, fatty acids such as lauric acid, myristic acid, palmitic acid, and stearic acid are used. The mixture in the composition whose melting point is to be limited for reasons described below is one containing the three components (A), (B), and (C) and these oily components.

[Ratio of each component in the composition]

Wax is an essential ingredient in order to achieve the above-mentioned purpose of the present invention, that is, to exhibit a comprehensive effect that has all the various properties required for a hair conditioning composition.
It is necessary that the higher alcohol, the cationic activator, or the anionic activator be blended in a certain balance. That is, based on the total amount of the three components (A) specific wax, (B) higher alcohol, and (C) cationic activator or anionic activator, component (A) is 20 to 55% by weight (B) component is 10 to 60% by weight Component (C) needs to be blended in a range of 5 to 30% by weight.

(A) The ratio of ingredients is 20 times! If it is less than 4% by weight, the ease of bundling will decrease, and if it exceeds 55% by weight, the smoothness will decrease, so overall favorable results cannot be achieved. Particularly suitable is a range of 30 to 45% by weight.

(If the ratio of the r() component is less than 10% by weight, the stability of the cream, which is the main dosage form of the composition of the present invention, will be significantly reduced over time, and the smoothness will also be reduced. Also, if it exceeds 60% by weight, it will not be easy to put together. This is not preferable because it reduces the ease of combing and the smoothness of the comb.Overall, a particularly suitable range is 30 to 501% R.

When the ratio of component (C) is 5% or less, the combability of the cationic activator decreases, and the combability and smoothness of the anionic activator decrease considerably. On the other hand, if it exceeds 30% by weight, both the cationic and anionic activators will wash away the wax components etc. during washing, and therefore the effects of dryness, smoothness and ease of gathering will decrease. Particularly preferred ranges are 8 to 28% by weight for cationic activators and 8 to 20'l[[nt%] for anionic activators.

Next, (A) component wax and (B) component high alcohol.

Regarding the relationship between the two groups, a suitable blending ratio is set based on experience, although it is not limited. That is, claim No. (1)
When one or more of the component waxes listed in (A) are selected from candelilla wax, carnauba wax, rice wax, jojoba wax, beeswax, shellac wax, cotton wax, sugarcane wax, hard lanolin, and montan wax. The appropriate weight ratio of component (A) to component (I3) is 0.5 to 2.5 times (Claim (2)); , ozokerite, ceresin, paraffin wax, microcrystalline wax, petrolatum, montan wax derivative, paraffin wax derivative, microcrystalline wax derivative, hydrogenated castor oil, hydrogenated castor oil derivative, 12-hydroxystearic acid, stearic acid amide, and privet wax. In this case, it is preferable that the blending ratio with respect to component (13) is 0.75 to 3.0 times by weight. (Claim (3)) Next, in the composition of the present invention, (A) wax, (B)
The blending ratio of the three essential components of higher alcohol, (C) cationic activator, or anionic activator is 3 to 7 in total.
It is necessary to set it within the range of 5 fold ji [%].

If the hair conditioning composition is less than 3% by weight, even if the amount of the hair conditioning composition applied to the hair is increased, the effects of smoothness and ease of combing will be significantly reduced, making it difficult to exert the overall effect, and if the hair conditioning composition exceeds 75% by weight. This makes it extremely difficult to spread the product uniformly over the entire hair, and the effectiveness is also significantly reduced.

The dosage form of the hair conditioning composition of the present invention is mainly an O/W cream or a Wlo cream, but as long as the total amount of the three components is relatively small, it may be in the form of an aerosol type, ie, a spray, a mousse, etc.
It can be applied to f-effects.

As a necessary condition for the physical property E that the composition of the present invention should possess, (
It is important that the melting point of the mixture containing the three components A)(B)(C) and other oily components is 40 to 90°C based on Method 2 of the Melting Point Determination Method of General Tests for Cosmetic Generators. Other oily components herein refer to oily components such as animal and vegetable oils, esters, and higher fatty acids among additives that are auxiliary added to hair conditioning compositions in addition to the above-mentioned three essential components.Specific examples include: is 11η as described above.

If the melting point is below 40° C., the effects of roughness and smoothness will be reduced, and at the same time, the sticky feeling will increase, which is not preferable. Moreover, when the temperature exceeds 90°C, the amount of wax and higher alcohol adsorbed to the hair decreases, resulting in a decrease in the smoothness and ease of bundling.

[Other additives]

The composition of the present invention may contain any ingredients used in ordinary hair cosmetics, such as amphoteric active agents, nonionic active agents, lower alcohols, esters, glycerides, fatty acid amides, amines,
Dyes, pigments, inorganic powders, organic powders, natural polymers, synthetic polymers, sequestering agents, ultraviolet absorbers, humectants, antioxidants, preservatives, fragrances, water, etc. can be blended.

[Preparation method of composition]

Hair conditioning compositions having such characteristics are generally prepared as follows.

(A) wax, (B) higher alcohol, (C) cationic activator or anionic activator, and other oily components are mixed in a predetermined ratio and heated to 85 to 92°C to form a liquid, and then separately prepared. After emulsifying the mixture with purified water at the same temperature, the mixture is cooled to room temperature while stirring, and additives such as fragrances are added and further stirred to form a cream-like composition.

[Method for treating hair] The second aspect of the present invention relates to a method for treating hair using the hair conditioning composition of the first invention. After drying, the hair is heated at a temperature of 40 to 180° C. and then cooled. A concrete explanation of this is as follows.

When using a device that directly touches the hair, such as a hair styling iron, as a method of heating the composition on the hair, it is preferable to heat the device to a temperature of 80 to 180°C and perform ironing operations 2 to 4 times. .

In this method, heating time is relatively short, so 80℃
If the temperature is below, adsorption of wax components, etc. in the composition to the hair will be insufficient, making it difficult to achieve the desired effect. Moreover, if the temperature exceeds 180°C, part of the keratin structure of the hair will decompose, which will increase the rough feel of the finished product, which is not preferable.

Particularly good conditions are 2 to 4 cycles of slow operation in the temperature range of 100-120°C.

Next, as a heating method, infrared lamp, far infrared lamp (
A famous example of this heating device is Takara Belmont's ``Schviter''), but when using a device that heats the hair all at once, such as a steamer, hair dryer, or heat cap, it is necessary to heat the area around the hair. A method is adopted in which the ambient temperature is set in the range of 40 to 80° C. and the heating treatment is performed for 5 to 40 minutes.

At temperatures below 40°C, the effects of dryness, smoothness, and ease of gathering are considerably reduced, and at the same time, the sticky feeling increases, which is undesirable.

Moreover, if the temperature exceeds 80° C., even if the heating time is relatively short, the effects of smoothness and ease of gathering will be slightly reduced, and a rough feeling will appear, which is not preferable. On the other hand, heating treatment at 80° C. or higher is painful and impractical.

A suitable heating time is 10 to 30 minutes.

Taking all the above into account, it is desirable that the heating treatment be carried out at 40 to 60° C. for 10 to 30 minutes using a device such as an infrared lamp.

The effect of the method of the present invention is that a specific wax, which is considered to be the main factor in achieving smoothness, smoothness, and ease of bundling through the heating treatment described below, combines with the functions of higher alcohol and activator to coat the hair epidermis. It is presumed that the active ingredient adheres to and penetrates into the hair epidermis, etc. due to the cold part, resulting in a sustained effect. Cooling for 5-10 minutes before rinsing is therefore an important operation for good results.

Next, a standard method for treating hair when using an O/W cream as the dosage form of the composition will be schematically explained.

Shampoo ↓ Rinse ↓ Towel dry ↓ Hair conditioning (apply 20 to 40 coats of the composition cream to too much hair) ↓ Warm * ↓ Cool at room temperature for 5 to 10 minutes ↓ Rinse ↓ Towel dry * ■ Steamer (40-50'C) 10-20 minutes heating ■ Steamer (40-50'C) heating → dryer drying ■ Far-infrared lamp (or infrared lamp) (40-50'C)
°C) 15-20 minutes heating ■ After treatment - ■ Operation ■ Operate 2-4 times with iron (100-120℃) ■ After treatment → ■ Operation ■ Heat cap (40-50℃) 15 ~20 minutes of heating*, ■ to ■ correspond to the heating treatment method of comprehensive evaluation in Examples and Comparative Examples described later.

As an effective embodiment of the hair treatment method of the present invention, it is recommended to add the following pretreatment.

Namely, the first method is to use animal oils such as animal oils for the purpose of imparting an appropriate moisturizing feeling to damaged hair, etc., in addition to the effects of excellent dryness, smoothness, ease of combing, ease of combing, and luster. mink oil, turdle oil, swan oil,
A method in which an appropriate amount of a vegetable oil such as squalane, such as olive oil, camellia oil, sasanqua oil, almond oil, safflower oil, macadamian nut oil, etc., is applied to the hair in advance for pretreatment, and then the hair is heated and treated with the hair conditioning composition of the present invention. It is.

Second, natural polymers such as polypeptide, sodium alginate, etc. are used to provide excellent smoothness, smoothness, ease of combing, ease of combing, and shine, as well as to add suppleness to the hair. , methylcellulose, ethylcellulose, hydroxyethylcellulose, chitosan, etc., synthetic polymers such as polyvinyl alcohol, polyvinylpyrrolidone, 1% sodium polyacrylate, carboxyvinyl polymer, polyethyleneimine, cationized cellulose, etc., are applied in advance to the hair in an appropriate amount. After the treatment, the hair conditioning composition of the present invention is heated and treated.

〔Example〕

Next, the aspects and effects of the present invention will be specifically explained using Examples and Comparative Examples.

Example 1 (A) 7.0 weight ζi parts of carnauba wax, (B)
10.0 parts by weight of cetyl alcohol, 5.0 parts by weight of cetyl trimedelammonium chloride (C), 1.5 parts by weight of glyceryl monostearate, and 1.511 parts by weight of isopropyl myristate were mixed and melted by heating to 90°C. was mixed in 1 part of 74.9 weight Fi of purified water heated to 90°C, and after cooling to 45°C while stirring for about 30 minutes,
0.1 part by weight of perfume was added and stirring was continued to obtain a creamy composition.

The melting point of this mixture excluding water and the δ material (according to the multiplex measurement method) was 71°C.

Also, the ratio of each component to the total amount of the three components is 32 times the component (A)! n%, (B) component 45% by weight, (C) component 2
3% by weight, and the ratio of the total amount of the three components to the total weight of the composition was 22wt'-+1%.

Next, the hair was treated using this creamy composition according to the method described by 1.

The heating method is 4 using a far infrared lamp, which corresponds to *■.
0~55℃! A heating method of 5 to 20 minutes was adopted. A sensory test was conducted by 100 panelists regarding the treatment results, and evaluations were made regarding dryness, smoothness, and ease of bundling.

In addition, 20 panelists gave a comprehensive evaluation of the results of the treatments using the above-mentioned heating methods *■ to ■.

The results of the following Examples are summarized and listed above in Table 1.

In the table, the meanings of the symbols in the comprehensive evaluation and sensory evaluation are as follows.

◎...Excellent ○...Good △... Acceptable

Hair treatment was performed in the same manner as in Example 1 using this composition.

The results are summarized in (1) to (4) of Table I.

Example 37 In Examples 2.5.11, 20.26.29.35, when hair was treated, hair was treated with mink oil, jojoba oil, olive oil, squalane, polypeptide, sodium polyacrylate, propylene alginate. Pretreatment was performed with glycol ester. The improvement in sensory evaluation by 25 panelists is as follows.

Mink oil: Jojoba oil, which increases smoothness. Olive oil, which increases silkiness. Squalane, which increases smoothness. Polypeptide, which increases smoothness. Sodium polyacrylate, which increases smoothness and suppleness. Propylene glycol ester alginate, which increases smoothness. Smoothness Increased Comparative Examples 1 to 29 Hair treatments similar to those in Examples were performed on compositions that did not meet the conditions of the present invention in terms of the absence of any of the three components, the blending ratio, the melting point of the oily component, etc. They are summarized and listed in (1) to (4) above in Table 2.

〔effect〕

As is clear from the comparison between Tables 1 and 2, the composition of the present invention satisfies all of the various desirable properties after hair treatment that have been strongly demanded by consumers in recent years, compared to the comparative examples. This greatly contributes to the interests of those above.

Procedural amendment (own%') Patent Application No. 137373 of 1988 7J'jlN 2) Title of the invention: hair conditioning composition and hair treatment method 3; Relationship between Patent applicant 4, agent address No. 114-1 Marunouchi 2-chome, Chiyoda-ku, Tokyo Claims column of the specification, detailed description of the invention (1) Claims column of the specification attached Correct as follows.

(2) Second formula from the bottom of page 15 of the specification (3) Second formula r(It,CONIl(CI-1.CIIPNII)C
o}1,)・11 X J to r[Ij. CONII(CIItCH,NH)nCOl
j! )-11 X J Correct.

(4) 5 lines from the bottom of page 17 of the specification [Correct olive oil-1 to [olive oil].

(5) Lines 4 to 3 from directly below No. 24 of the specification "Fatty acid amide," 1-fatty acids, silicone oils, amides,” he corrected.

(6) 8 lines on page 2 and 6 of the specification 1 - Correct "decomposition" to "denaturation".゛ (7) Specification page 27, lines 1-2 [At the same time, the sticky feeling increases] is deleted.

〔Attachment〕

[Hair conditioning (composition cream 20-409% per 100g of hair)
1 Application of hair conditioning composition cream (20 to 409 to 1009 hair) J.

(9) "Glossy effect" in the bottom line of page 29 of the specification and in lines IO to 11 of page 30 are corrected to 1 "Glossy effect".

(10) Specification page 32, line 9 "Easy to organize" is corrected to "easiness to organize."

(ll) Pages 35 to 38 of the specification [Table 1 (1) to Table 1 (4) J is corrected as shown in Attachments 1 to 4.

(ll) "Table 2 (1) to Table 2 (4)" on pages 39 to 42 of the specification are corrected as shown in Attachments 5 to 8. Claims (1) (A) Ingredients include candelilla wax, carnauba wax, rice wax, Japanese wax, jojoba wax, beeswax, shellac wax, cotton wax, sugarcane wax, hard lanolin, lacquer wax, Montan wax, ozokerite, ceresin, paraffin wax, microcrystalline wax, petrolatum, montan wax derivatives, paraffin wax derivatives, microcrystalline wax derivatives, hydrogenated castor oil, hydrogenated castor oil derivatives, ll-hydroxystearic acid, stearic acid amide, privet wax group One or more types of wax selected from (B) One or more types of higher alcohol CG')
A hair conditioning composition containing a cationic activator or an anionic activator as an ingredient, in which the ratio of component (A) to the total amount of the three components is 20 to 55%, and the ratio of component (B) is 0. ~60% by weight, the proportion of component (C) is 5
~30% by weight, and the total amount of the three components is in the range of 3 to 75% by weight based on the total weight of the composition, and the mixture in the composition contains the three components and other oily components. A hair conditioning composition having a melting point of 40 to 90°C.

(2) In claim (1), the wax component (A) includes candelilla wax, carnauba wax, rice wax, jojoba wax, beeswax, shellac wax, cotton wax, sugarcane wax, hard lanolin,
A hair conditioning composition comprising montan wax in which the ratio of component (A) to component (B) is 0.5 to 2.5 times by weight.

(3) In claim (1), the wax component (A) includes pyroxene, spermaceti, ozokerite, ceresin, paraffin wax, microcrystalline wax, petrolatum, montan wax derivatives, paraffin wax derivatives, micro Crystalline wax derivatives, hydrogenated castor oil, hydrogenated castor oil derivatives, 12-hydroxystearic acid, stearic acid amide, privet wax, and the ratio of component (A) to component (B) is 0.75 to 3.
．． A hair conditioning composition that is 0x fit.

(4) The composition contains an amphoteric active agent, a nonionic active agent, a lower alcohol, a polyhydric alcohol, an ester, a glyceride,
Fatty acids, -&IJ NEE A47 UAMITO, amines, dyes, pigments, inorganic powders, organic powders, natural polymers, synthetic polymers, total ion sequestrants, ultraviolet absorbers, humectants,
A hair conditioning composition as described in any one of claims 1 to 3 above, containing an antioxidant, a preservative, a drink, and water.

(5) Ingredients (A) include candelilla wax, carnauba wax, rice wax, wood wax, jojoba wax, beeswax, shellac wax, cotton wax, sugarcane wax, hard lanolin, spermaceti, montan wax, ozokerite, ceresin, One of the waxes selected from the group of paraffin wax, microcrystalline wax, petrolatum, montan wax derivative, paraffin wax derivative, microcrystalline wax derivative, hydrogenated castor oil, hydrogenated castor oil derivative, 12-hydroxystearic acid, stearic acid amide, and privet wax. A hair conditioning composition containing a cationic activator or an anionic activator as a component (B) of 11 or more of higher alcohols as a component (C), wherein the ratio of component (A) to the total amount of the above three components is 20-55% by weight, the proportion of the (r3) component is 10-60% by weight, the proportion of the (C) component is
In the range of 5 to 30% by weight, and the total amount of the above three components,
Applying a hair conditioning composition to the hair, the amount of which is in the range of 3 to 75% by weight based on the total amount of the composition, and the melting point of the mixture in the composition containing the three components and other oily components is 40 to 90°C. After applying, the temperature of the hair is 4.
A method for treating hair, which comprises heating the hair in a range of 0 to 180°C and then cooling it.

(6) Claim (5) is characterized in that the heating method involves using an instrument that directly touches the hair, such as a hair styling iron, and heating the instrument to a temperature of 80 to 180°C to treat the hair. hair treatment method.

(7) In claim (5), the heating method uses an infrared lamp, a far-infrared lamp, a steamer, a hair dryer, a heat cap, or other device that heats the hair all at once to control the ambient temperature around the hair. A hair treatment method characterized by heating the hair at a temperature in the range of 40 to 80°C for 5 to 40 minutes.

(8) A method for treating hair according to claim (5), characterized in that hair is pretreated with animal oil or vegetable oil.

(9) A method for treating hair according to claim (5), characterized in that hair is pretreated with a natural polymer solution or a synthetic polymer solution.

Claims (9)

[Claims] (1) Ingredients (A) include candelilla wax, carnauba wax, rice wax, Japanese wax, jojoba wax, beeswax, shellac wax, cotton wax, sugarcane wax, hard lanolin, spermaceti, montan wax, ozokerite, ceresin, One of the waxes selected from the group of paraffin wax, microcrystalline wax, petrolatum, montan wax derivative, paraffin wax derivative, microcrystalline wax derivative, hydrogenated castor oil, hydrogenated castor oil derivative, 12-hydroxystearic acid, stearic acid amide, and privet wax. A hair conditioning composition containing a cationic activator or an anionic activator as the (C) component of one or more higher alcohols as the (B) component, the ratio of the (A) component to the total amount of the above three components. is in the range of 20 to 55% by weight, the proportion of component (B) is in the range of 10 to 60% by weight, the proportion of component (C) is in the range of 5 to 30% by weight, and the total amount of the above three components is based on the total amount of the composition. 3-75% by weight
A hair conditioning composition characterized in that the melting point of the mixture in the composition containing the three components and other oily components is 40 to 90°C. (2) In claim (1), the wax component (A) includes candelilla wax, carnauba wax, rice wax, jojoba wax, beeswax, shellac wax, cotton wax, sugarcane wax, hard lanolin,
A hair conditioning composition comprising montan wax in which the ratio of component (A) to component (B) is 0.5 to 2.5 times by weight. (3) In claim (1), the wax component (A) includes pyroxene, spermaceti, ozokerite, ceresin, paraffin wax, microcrystalline wax, petrolatum, montan wax derivatives, paraffin wax derivatives, micro Crystalline wax derivatives, hydrogenated castor oil, hydrogenated castor oil derivatives, 12-hydroxystearic acid, stearic acid amide, privet wax, and the ratio of component (A) to component (B) is 0.75 to 3.
．． A hair conditioning composition that is 0 times by weight. (4) The composition contains an amphoteric active agent, a nonionic active agent, a lower alcohol, a polyhydric alcohol, an ester, a glyceride,
Contains fatty acid amides, amines, dyes, pigments, inorganic powders, organic powders, natural polymers, synthetic polymers, sequestering agents, ultraviolet absorbers, humectants, antioxidants, preservatives, fragrances, and water. A hair conditioning composition according to any one of claims (1) to (3). (5) Ingredients (A) include candelilla wax, carnauba wax, rice wax, wood wax, jojoba wax, beeswax, shellac wax, cotton wax, sugarcane wax, hard lanolin, spermaceti, montan wax, ozokerite, ceresin, A wax selected from the group of paraffin wax, microcrystalline wax, petrolatum, montan wax derivatives, paraffin wax derivatives, microcrystalline wax derivatives, hydrogenated castor oil, hydrogenated castor oil derivatives, 12-hydroxystearic acid, stearamide, and privet wax. A hair conditioning composition containing a cationic activator or an anionic activator as one or more of the higher alcohols as the component (B), and one or more of the higher alcohols as the component (C), the component (A) relative to the total amount of the three components above. The proportion of component (B) is in the range of 20 to 55% by weight, the proportion of component (B) is in the range of 10 to 60% by weight, the proportion of component (C) is in the range of 5 to 30% by weight, and the total amount of the three components is 3 to 75% by weight
After applying a hair conditioning composition to the hair, the melting point of the mixture in the composition containing the three components and other oily components is 40 to 90°C.
The hair is heated at a temperature of 40 to 180°C,
A method for treating hair, which comprises cooling the hair. (6) Claim (5) is characterized in that the heating method involves using an instrument that directly touches the hair, such as a hair styling iron, and heating the instrument to a temperature of 80 to 180°C to treat the hair. hair treatment method. (7) In claim (5), the heating method uses a device that heats the hair all at once, such as an infrared lamp, a far-infrared lamp, a steamer, a hair dryer, or a heat cap, and the atmospheric temperature around the hair is raised to 40°C. A hair treatment method characterized by heating the hair at a temperature in the range of ~80°C for 5 to 40 minutes. (8) A method for treating hair according to claim (5), characterized in that hair is pretreated with animal oil or vegetable oil. (9) A method for treating hair according to claim (5), characterized in that hair is pretreated with a natural polymer solution or a synthetic polymer solution.