JPS6297692A - Sterilizing cleaning agent having high solubility and lasting property - Google Patents
Sterilizing cleaning agent having high solubility and lasting propertyInfo
- Publication number
- JPS6297692A JPS6297692A JP60238736A JP23873685A JPS6297692A JP S6297692 A JPS6297692 A JP S6297692A JP 60238736 A JP60238736 A JP 60238736A JP 23873685 A JP23873685 A JP 23873685A JP S6297692 A JPS6297692 A JP S6297692A
- Authority
- JP
- Japan
- Prior art keywords
- high solubility
- cleaning agent
- sodium tripolyphosphate
- potassium sulfate
- lasting property
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 5
- 230000001954 sterilising effect Effects 0.000 title claims abstract description 5
- 230000002045 lasting effect Effects 0.000 title abstract 3
- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 claims abstract description 11
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 11
- 229950009390 symclosene Drugs 0.000 claims abstract description 11
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims abstract description 10
- 229910052939 potassium sulfate Inorganic materials 0.000 claims abstract description 10
- 235000011151 potassium sulphates Nutrition 0.000 claims abstract description 10
- 238000000748 compression moulding Methods 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 5
- 239000003206 sterilizing agent Substances 0.000 claims description 4
- 238000009472 formulation Methods 0.000 claims description 3
- 230000005923 long-lasting effect Effects 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 12
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 238000000465 moulding Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 8
- 239000000460 chlorine Substances 0.000 description 8
- 229910052801 chlorine Inorganic materials 0.000 description 8
- 238000007654 immersion Methods 0.000 description 4
- 238000010828 elution Methods 0.000 description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000011978 dissolution method Methods 0.000 description 2
- 238000007922 dissolution test Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
Landscapes
- Apparatus For Disinfection Or Sterilisation (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、浄化槽放流水等の水処理用殺菌清浄剤に関す
るものであり、特にトリクロルイソシアヌル酸を有効成
分とする高溶解性及び持続性を有する殺菌清浄剤に関す
るものである。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a sterilizing agent for treating water such as septic tank effluent, and in particular to a sterilizing agent with high solubility and persistence containing trichloroisocyanuric acid as an active ingredient. It concerns cleaning agents.
従来の技術
従来、トリクロルイソシアヌル酸に相当量の添加剤を配
合し、打錠することによって持続性の良い錠剤を造るこ
とは知られている。（特公昭５７−２５００４号、特公
昭６０−２１９６７号、特開昭５６−１４２２１０号し
かしながらいずれも溶解性が悪く、これを浄化槽放流水
と接触させた場合、活性塩素の溶出量が数ρρｍ／ｈｒ
と少ないため、上記水処理用殺菌清浄剤として満足しう
る状態ではない。BACKGROUND ART Conventionally, it has been known to make tablets with good durability by blending trichloroisocyanuric acid with a considerable amount of additives and then compressing the mixture. (Japanese Patent Publication No. 57-25004, Japanese Patent Publication No. 60-21967, and Japanese Unexamined Patent Publication No. 56-142210) However, all of them have poor solubility, and when they are brought into contact with septic tank discharge water, the amount of active chlorine eluted is several ρρm/ hr
Therefore, it is not in a satisfactory state as a disinfectant for water treatment.
発明が解決しようとする問題点
この種の殺菌清浄剤には、放流水に接触すると速やかに
溶解し、適度な活性塩素を溶出させる高溶解性と安定し
た長期持続性が要求されている。Problems to be Solved by the Invention This type of sterilizing and cleaning agent is required to have high solubility and stable long-term sustainability so that it dissolves quickly when it comes into contact with effluent water and elutes an appropriate amount of active chlorine.
特に１時間当りの流量が約６０！、浸漬深さ２〜３鶴の
接触溶解方式の放流水処理では、平均塩素溶出量として
１０〜１５ｐｐｍ／ｈｒが望まれている。Especially the flow rate per hour is about 60! In effluent water treatment using a contact dissolution method with an immersion depth of 2 to 3, an average chlorine elution amount of 10 to 15 ppm/hr is desired.
問題点を解決するための手段
本発明者らは、このような事情に鑑み、鋭意研究を重ね
た結果、無機酸、有機酸及びその塩類のうち、トリポリ
リン酸ナトリウム、硫酸カリウムがこの種の添加剤とし
て優れていることを見い出した。Means for Solving the Problems In view of the above circumstances, the inventors of the present invention have conducted intensive research and found that among inorganic acids, organic acids, and their salts, sodium tripolyphosphate and potassium sulfate have been added to this type. It was discovered that it is an excellent agent.
本発明は、トリクロルイソシアヌル酸、トリポリリン酸
ナトリウム、硫酸カリウムを重量比で、１００：５〜２
０：５〜２０の割合で含む配合物を圧縮成型した製剤が
、高溶解性及び持続性を有することを見い出し、所期の
目的を達成したものである。The present invention uses trichloroisocyanuric acid, sodium tripolyphosphate, and potassium sulfate in a weight ratio of 100:5 to 2.
It has been found that a formulation obtained by compression molding a formulation containing the compound at a ratio of 0:5 to 20 has high solubility and sustainability, and has achieved the intended purpose.
本発明を実施するに当り、トリポリリン酸ナトリウム、
硫酸カリウムは粉末状のものであっても良いが、結晶状
のものが望ましい。In carrying out the present invention, sodium tripolyphosphate,
Potassium sulfate may be in powder form, but preferably in crystal form.
打錠における成型圧は３００〜１５００ ｋｇ ／ ｃ
ｒＡの範囲であり、打錠に際してはステアリン酸マグネ
シウム、ホウ酸等の滑沢剤を少量加えることによって打
錠を容易にすることができる。Molding pressure in tableting is 300-1500 kg/c
rA range, and tableting can be facilitated by adding a small amount of a lubricant such as magnesium stearate or boric acid.
作用
本発明殺菌清浄剤は放流水に接触すると、速やかにトリ
ポリリン酸ナトリウム、次いで硫酸カリウムの吸水と溶
解が起こり、その結果トリクロルイソシアヌル酸の放流
水との接触面積が大きくなり、錠剤の溶解を促進させる
。さらに、比較的溶解し難いトリクロルイソシアヌル酸
の溶解速度を上げるため、水中でトリポリリン酸ナトリ
ウムと軽い中和反応を起こさせることにより高溶解性と
したものである。Action When the disinfectant of the present invention comes into contact with discharged water, sodium tripolyphosphate and then potassium sulfate rapidly absorb and dissolve, resulting in a larger contact area of trichloroisocyanuric acid with the discharged water, promoting dissolution of the tablets. let Furthermore, in order to increase the dissolution rate of trichloroisocyanuric acid, which is relatively difficult to dissolve, it is made highly soluble by causing a slight neutralization reaction with sodium tripolyphosphate in water.
また、トリクロルイソシアヌル酸、トリポリリン酸ナト
リウム、硫酸カリウムを重量比１００：５〜２０：５〜
２０の割合に配合、圧縮成型したものは、長時間持続し
て所定の活性塩素濃度を保つことができる。In addition, trichloroisocyanuric acid, sodium tripolyphosphate, and potassium sulfate are mixed in a weight ratio of 100:5 to 20:5 to
When the mixture is blended at a ratio of 20% and compression molded, it is possible to maintain a predetermined active chlorine concentration for a long time.
実施例１
トリクロルイソシアヌル酸１１．２５ｇ、トリポリリン
酸ナトリウム１．５ｇ、硫酸カリウム１．５ｇ及び滑沢
剤としてホウ酸０．７５ｇを均一に混合し、打錠機を用
いて面圧５００ｋｇ／ｃｎ（で加圧して、１５ｇの偏平
状錠剤（直径３０酊、厚さ１２．４５ ｗｍ）をつくり
、これを水温２０〜２２℃、流量５Ｑ＃／ｈｒ、浸漬深
さ２〜３龍で溶解試験を実施したときの塩素溶出量は、
次表の通りであった。Example 1 11.25 g of trichloroisocyanuric acid, 1.5 g of sodium tripolyphosphate, 1.5 g of potassium sulfate, and 0.75 g of boric acid as a lubricant were uniformly mixed, and a surface pressure of 500 kg/cn ( Pressure was applied to make 15g flat tablets (diameter 30mm, thickness 12.45wm), which were subjected to a dissolution test at a water temperature of 20~22℃, a flow rate of 5Q#/hr, and an immersion depth of 2~3mm. The amount of chlorine elution when carried out was
The results were as shown in the table below.
表１
実施例２
トリクロルイソシアヌル酸１１．２５ｇ、トリポリリン
酸ナトリウム１．５ｇ、硫酸カリウム２．２５ｇを均一
に混合し、打錠機を用い面圧５００ ｋｇ ／ ｃＩｌ
！で加圧して、１５ｇの偏平状錠剤（直径３０鶴、厚さ
１２．５０酊）をつくり、これを水温２０〜２２℃流量
６０ｊ！／ｈｒ、浸漬深さ２〜３龍で溶解試験を実施し
たときの塩素溶出量は、次表の通りであった。Table 1 Example 2 11.25 g of trichloroisocyanuric acid, 1.5 g of sodium tripolyphosphate, and 2.25 g of potassium sulfate were mixed uniformly, and the surface pressure was 500 kg/cIl using a tablet press.
! Pressure is applied to make 15 g flat tablets (diameter: 30 mm, thickness: 12.5 mm), and water temperature: 20-22°C, flow rate: 60 j! The amount of chlorine eluted when a dissolution test was carried out at immersion depth of 2 to 3 hours was as shown in the following table.
表２
発明の効果
本発明によれば、実施例の如く、流量６０β／ｈｒ浸漬
深さ２〜３１ｍの接触溶解方式の放流水処理では、平均
塩素溶出量１０〜１５ｐｐｍ／ｈｒが可能となり、適度
な活性塩素を溶出させる高溶解性と安定した長期持続性
を有する殺菌清浄剤を提供することができ効果は多大で
ある。Table 2 Effects of the Invention According to the present invention, as in the embodiment, in discharge water treatment using the contact dissolution method with a flow rate of 60β/hr and an immersion depth of 2 to 31 m, an average chlorine elution amount of 10 to 15 ppm/hr is possible, which is moderate. It is possible to provide a sterilizing detergent that has high solubility and stable long-term durability that elutes active chlorine, and has great effects.
Claims (1)
、硫酸カリウムを重量比で１００：５〜２０：５〜２０
の割合で含む配合物を圧縮成型したことを特徴とする高
溶解性及び持続性を有する殺菌清浄剤。Trichloroisocyanuric acid, sodium tripolyphosphate, potassium sulfate in a weight ratio of 100:5 to 20:5 to 20
A sterilizing and cleaning agent having high solubility and long-lasting properties, characterized in that it is obtained by compression molding a formulation containing a proportion of .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60238736A JPS6297692A (en) | 1985-10-24 | 1985-10-24 | Sterilizing cleaning agent having high solubility and lasting property |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60238736A JPS6297692A (en) | 1985-10-24 | 1985-10-24 | Sterilizing cleaning agent having high solubility and lasting property |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6297692A true JPS6297692A (en) | 1987-05-07 |
| JPH029878B2 JPH029878B2 (en) | 1990-03-05 |
Family
ID=17034491
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60238736A Granted JPS6297692A (en) | 1985-10-24 | 1985-10-24 | Sterilizing cleaning agent having high solubility and lasting property |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6297692A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63307802A (en) * | 1987-06-08 | 1988-12-15 | Kunimine Kogyo Kk | Production of water-soluble granule |
| JPH0248678U (en) * | 1988-09-30 | 1990-04-04 | ||
| JPH02295564A (en) * | 1989-04-24 | 1990-12-06 | Steris Corp | Antibacterial powder composite |
| JPH0394760A (en) * | 1989-05-09 | 1991-04-19 | Steris Corp | Sterility clarification system and container for holding material wherefor bacteria clarification is done |
| US5723095A (en) * | 1995-12-28 | 1998-03-03 | Steris Corporation | Cleaner concentrate formulation for biological waste fluid handling systems |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3297578A (en) * | 1963-07-26 | 1967-01-10 | Monsanto Co | Bleaching, sterilizing, disinfecting, and deterging compositions |
| JPS5859904A (en) * | 1981-10-06 | 1983-04-09 | Nissan Chem Ind Ltd | Molded composition for water treatment |
-
1985
- 1985-10-24 JP JP60238736A patent/JPS6297692A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3297578A (en) * | 1963-07-26 | 1967-01-10 | Monsanto Co | Bleaching, sterilizing, disinfecting, and deterging compositions |
| JPS5859904A (en) * | 1981-10-06 | 1983-04-09 | Nissan Chem Ind Ltd | Molded composition for water treatment |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63307802A (en) * | 1987-06-08 | 1988-12-15 | Kunimine Kogyo Kk | Production of water-soluble granule |
| JPH0248678U (en) * | 1988-09-30 | 1990-04-04 | ||
| JPH02295564A (en) * | 1989-04-24 | 1990-12-06 | Steris Corp | Antibacterial powder composite |
| JPH0394760A (en) * | 1989-05-09 | 1991-04-19 | Steris Corp | Sterility clarification system and container for holding material wherefor bacteria clarification is done |
| US5723095A (en) * | 1995-12-28 | 1998-03-03 | Steris Corporation | Cleaner concentrate formulation for biological waste fluid handling systems |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH029878B2 (en) | 1990-03-05 |
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