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JPS6172202A - Production of curved surface diffraction grating - Google Patents

Production of curved surface diffraction grating

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Publication number
JPS6172202A
JPS6172202A JP19369984A JP19369984A JPS6172202A JP S6172202 A JPS6172202 A JP S6172202A JP 19369984 A JP19369984 A JP 19369984A JP 19369984 A JP19369984 A JP 19369984A JP S6172202 A JPS6172202 A JP S6172202A
Authority
JP
Japan
Prior art keywords
diffraction grating
curved
curved surface
grating
diffraction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP19369984A
Other languages
Japanese (ja)
Inventor
Masayoshi Ono
大野 正善
Takeshi Yamada
武 山田
Tetsuo Yoshizawa
吉沢 鉄夫
Norio Takato
高戸 範夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Telegraph and Telephone Corp
Original Assignee
Nippon Telegraph and Telephone Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Telegraph and Telephone Corp filed Critical Nippon Telegraph and Telephone Corp
Priority to JP19369984A priority Critical patent/JPS6172202A/en
Publication of JPS6172202A publication Critical patent/JPS6172202A/en
Pending legal-status Critical Current

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  • Diffracting Gratings Or Hologram Optical Elements (AREA)

Abstract

PURPOSE:To obtain a curved surface diffraction grating having the specified blaze angle within the curved surface and high diffraction efficiency by deforming a resilient material formed with a plane diffraction grating to the prescribed curved surface and bringing the curved resilient material into contact with a curved surface diffraction grating material and curing the same. CONSTITUTION:A resilient material 1 is adhered to the curved surface of a base part 2 curved to a prescribed radius of curvature and is deformed. The deformed diffraction grating surface of the material 1 is brought into contact with the curved diffraction grating material 3 in a liquid state and is cured, by which the curved diffraction grating 4 is produced. A metallic alcoholate soln. or plastic such as epoxy resin and ceramics, etc. are usable for such material 3.

Description

【発明の詳細な説明】 〔発明の分野〕 本発明は曲面回折格子の製造方法、さらに詳しくは良好
な性能を有する光部品の曲面格子を容易に製造する方法
に関するものである。
DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a method for manufacturing a curved diffraction grating, and more particularly to a method for easily manufacturing a curved grating for an optical component having good performance.

〔発明の背景〕[Background of the invention]

従来、曲面回折格子においては、凹面回折格子が紫外光
の分光器などに主として用いられてきたが、近年光通信
における光多重伝送方式の進展に伴い、光分波器、合波
器の必要が増しくELECTRONIC5LETTER
S 17 (1981) 934.Applied 0
ptics 19(1980) 3588) 、回折格
子、特に高性能な凹面回折格子の経済的な製造法が望ま
れている。
Conventionally, concave diffraction gratings have been mainly used in ultraviolet light spectrometers, etc., but in recent years, with the development of optical multiplex transmission systems in optical communications, the need for optical demultiplexers and multiplexers has increased. Increasing ELECTRONIC5 LETTER
S 17 (1981) 934. Applied 0
ptics 19 (1980) 3588), an economical method of manufacturing diffraction gratings, particularly high performance concave diffraction gratings, is desired.

従来は、精密加工した凹面に高制度のルーリングマシン
で機械的に溝をきり、これを型としてレプリカを作製す
るという方法が採用されていた。
Conventionally, the method used was to mechanically cut grooves on a precision-machined concave surface using a high-precision ruling machine, and then use this as a mold to create a replica.

この方法においては、機械的に溝を高密度に作製するた
めに、高価な装置を必要とするばかりでなく、第1図(
alに示すように、凹面に対する回折格子の主な回折面
のなす角(以下ブレーズ角と略す)が凹面内の位置によ
って異なるため、回折効率を高くすることができなかっ
た。従来法で作製した回折格子(750l ine/ 
m1)、曲率半径3.8 cm、中心でのブレーズ角1
8.6°)の曲面の位置によるブレーズ角の変化を下記
の第1表に示す。
This method not only requires expensive equipment to mechanically create grooves with high density, but also requires an expensive device (see Fig. 1).
As shown in al, the angle formed by the main diffraction surface of the diffraction grating with respect to the concave surface (hereinafter abbreviated as blaze angle) differs depending on the position within the concave surface, so it was not possible to increase the diffraction efficiency. Diffraction grating (750 l ine/
m1), radius of curvature 3.8 cm, blaze angle at center 1
Table 1 below shows changes in the blaze angle depending on the position of the curved surface (8.6°).

これに対し、第1図中)に示すように面内においてブレ
ーズ角を一定にできれば、曲面全体にわたってブレーズ
条件を満足させることができ、回折効率を向上させるこ
とができる。
On the other hand, if the blaze angle can be made constant within the plane as shown in FIG. 1, the blaze condition can be satisfied over the entire curved surface, and the diffraction efficiency can be improved.

ブレーズ角を凹面内で一定とする手法として、イオンビ
ームエツチングが考えられる(腰囲ら、信学論(C1、
J 64−C,10,PP652 (、昭56−6)”
)。
Ion beam etching is considered as a method to make the blaze angle constant within the concave surface (Koshiki et al., IEICE theory (C1,
J 64-C, 10, PP652 (Sho 56-6)”
).

しかし、高価な装置を必要とし、経済性および生産性に
劣るという欠点がある。
However, it has the drawback of requiring expensive equipment and being inferior in economy and productivity.

また数十μmの厚さのシリコンウェハに回折格子お作製
し、ウェハを曲面にそって曲げることにより凹面内でブ
レーズ角が一定な凹面回折格子を作製する手法も報告さ
れている(藤井、Elector。
A method has also been reported in which a diffraction grating is fabricated on a silicon wafer with a thickness of several tens of micrometers, and a concave diffraction grating with a constant blaze angle within the concave surface is fabricated by bending the wafer along a curved surface (Fujii, Electr. .

n1cs  1etters 17 (1981) 9
34 )。しかし、この手法も量産性に乏しいという欠
点がある。
n1cs 1etters 17 (1981) 9
34). However, this method also has the disadvantage of poor mass productivity.

〔発明の概要〕[Summary of the invention]

本発明は上述の点に鑑みなされたものであり、凹面内で
ブレーズ角が一定の凹面回折格子を量産性よく、かつ経
済的に製造できる方法を提供することを目的とするもの
である。
The present invention has been made in view of the above points, and it is an object of the present invention to provide a method for manufacturing a concave diffraction grating having a constant blaze angle within the concave surface with good mass productivity and economically.

したがって、本発明による曲面回折格子の製造方法は、
所定形状の平面回折格子を形成した柔軟な材料を所定曲
面に変形させ、この曲面化した柔軟材料を曲面回折格子
材料に接触させ、硬化せしめることを特徴とするもので
ある。
Therefore, the method for manufacturing a curved diffraction grating according to the present invention is as follows:
The method is characterized in that a flexible material on which a planar diffraction grating of a predetermined shape is formed is deformed into a predetermined curved surface, and the curved flexible material is brought into contact with the curved diffraction grating material and hardened.

本発明による曲面回折格子の製造方法によれば、従来技
術で容易に製造可能な平面回折格子を用い、ブレーズ角
が曲面内で一定な回折効率の高い曲面回折格子を経済的
に製造できるという利点がある。
According to the method for manufacturing a curved diffraction grating according to the present invention, a curved diffraction grating with high diffraction efficiency and a constant blaze angle within the curved surface can be economically manufactured using a flat diffraction grating that can be easily manufactured using conventional techniques. There is.

〔発明の詳細な説明〕[Detailed description of the invention]

第2図は本発明による曲面回折格子の製造方法を模式的
に示した図であり、図中、1は平面回折格子を形成した
柔軟材料、2は基部、3は曲面回折格子材料、4は曲面
回折格子を示す。
FIG. 2 is a diagram schematically showing the method for manufacturing a curved diffraction grating according to the present invention, in which 1 is a flexible material forming a plane diffraction grating, 2 is a base, 3 is a curved diffraction grating material, and 4 is a curved diffraction grating material. A curved diffraction grating is shown.

本発明による曲面回折格子の製造方法によれば、まず、
柔軟な材料に平面的な回折格子を形成する(第1図(a
))。この回折格子を形成する方法は本発明において限
定されるものではなく、従来の方法により作製すること
ができる。
According to the method for manufacturing a curved diffraction grating according to the present invention, first,
Forming a planar diffraction grating in a flexible material (Fig. 1(a)
)). The method of forming this diffraction grating is not limited in the present invention, and can be produced by a conventional method.

このような平面回折格子を形成した柔軟な材料1は曲面
状に湾曲可能な柔軟性を有していれば、本発明において
基本的に限定されるものではない。
The flexible material 1 forming such a plane diffraction grating is not fundamentally limited in the present invention as long as it has flexibility to be curved into a curved shape.

たとえば、プラスティックあるいは金属のフィルム状の
ものを用いることができる。特に、弾性があり、曲面回
折格子材料3に対し、耐性を有する材料であるのがよい
。このような柔軟な材料としては、特にシリコーン樹脂
が優れている。
For example, a plastic or metal film can be used. In particular, it is preferable to use a material that is elastic and resistant to the curved diffraction grating material 3. Silicone resin is particularly excellent as such a flexible material.

次ぎにこのような平面回折格子を形成された材料1を曲
面状に変形させるものであるが、この変形方法は基本的
に限定されるものではない。たとえば、第2図に示すよ
うに、所定の曲率半径に湾曲した基部2の前記湾曲面に
柔軟な材料1を貼着することにより変形させることがで
きる。この場合、回折格子が形成されている面を外側に
来るように貼着する(第2図(b))。
Next, the material 1 on which such a plane diffraction grating is formed is deformed into a curved shape, but the method of deformation is not fundamentally limited. For example, as shown in FIG. 2, the curved surface of the base 2 curved to a predetermined radius of curvature can be deformed by attaching a flexible material 1 to the curved surface. In this case, it is pasted so that the surface on which the diffraction grating is formed is on the outside (FIG. 2(b)).

次ぎにこのように変形された柔軟材料1の回折格子面を
液状の曲面回折格子材料3に接触させ(第1図(C))
、硬化せしめる(第1図(d))。これを容器より取り
出すことにより曲面回折格子4を製造できる(第1図(
e))。
Next, the diffraction grating surface of the flexible material 1 thus deformed is brought into contact with the liquid curved diffraction grating material 3 (Fig. 1(C)).
, and harden (FIG. 1(d)). By taking this out of the container, a curved diffraction grating 4 can be manufactured (see Fig. 1 (
e)).

このような曲面格子材料3としては、曲面に変形した柔
軟材料1の回折格子により成形されうるものであればい
かなるものでもよい。たとえば、低粘度の溶液よりガラ
ス成形品を得る、ゾル・ゲル法を用いた微細パターンの
作製方法(特願昭58−129523号)に記載された
金属アルコレート溶液あるいはエポキシ樹脂などのプラ
スティック、さらにはセラミックなどを用いることがで
きる。すなわち、この曲面格子材料3としては、通常の
成形材料を有効に用いることができ、本発明において基
本的に限定されるものではない。
Such curved grating material 3 may be any material as long as it can be formed by a diffraction grating of flexible material 1 deformed into a curved surface. For example, plastics such as metal alcoholate solutions or epoxy resins described in the method for producing fine patterns using the sol-gel method (Japanese Patent Application No. 129523/1982), which obtains glass molded products from low-viscosity solutions, and Ceramic or the like can be used. That is, as this curved lattice material 3, a normal molding material can be effectively used, and is not fundamentally limited in the present invention.

特に上述の金属アルコレートを用いる方法は、温度、湿
度の変化に対し信頼性が高いガラス回折格子をえること
ができる。
In particular, the method using the metal alkoxide described above can provide a glass diffraction grating that is highly reliable against changes in temperature and humidity.

このような金属アルコレートを用いるとき、金属アルコ
レート溶液(曲面回折格子材料3)を用意し、この金属
アルコレート溶液3に回折格子の形成された柔軟材料1
を接触させ、一定時間放置しゲル化させる。このように
ゲル化したのち、前記柔軟材料1を取り除き(第1図(
d))、さらに容器より取り出し、乾燥加熱してガラス
回折格子4(第1図(e))とするものである。
When using such a metal alcoholate, a metal alcoholate solution (curved diffraction grating material 3) is prepared, and a flexible material 1 on which a diffraction grating is formed is added to the metal alcoholate solution 3.
and leave it in contact for a certain period of time to gel. After gelling in this way, the flexible material 1 is removed (see Figure 1 (
d)), and then taken out from the container and dried and heated to form a glass diffraction grating 4 (FIG. 1(e)).

上述の金属アルコレート溶液は少なくとも一種以上の金
属アルコレート、水および必要ならばメタノール、エタ
ノール、プロパツールなどのアルコール系溶媒、酸、塩
基な−どを含む溶液である。
The above-mentioned metal alcoholate solution is a solution containing at least one metal alcoholate, water and, if necessary, an alcoholic solvent such as methanol, ethanol, propatool, etc., an acid, a base, and the like.

このような金属アルコレートとしては、たとえばテトラ
メトキシシラン、テトラエトキシシランなどを例として
挙げることができるが、本発明においてこれに限定され
るものではない。
Examples of such metal alcoholates include tetramethoxysilane and tetraethoxysilane, but the present invention is not limited thereto.

次ぎに本発明の実施例について説明する。Next, examples of the present invention will be described.

実施例1 市販の平面回折格子をマスクとして厚さ2 mmのシリ
コーン樹脂表面に3001ine/mmのレプリカ回折
格子を形成した。これを曲率半径9.5 cmの凸状の
基部に貼着し、テトラメトキシシラン:メチルアルコー
ル:水(モル比 1  :4  :4)の混合溶液に接
触させ、金属アルコレート溶液がゲル化した後、離型し
た。充分乾燥した後、950 ’Cまで加熱焼結し、第
3図に示すような石英凹面回折格子を得た。
Example 1 A replica diffraction grating of 3001 in/mm was formed on the surface of a silicone resin having a thickness of 2 mm using a commercially available flat diffraction grating as a mask. This was attached to a convex base with a radius of curvature of 9.5 cm and brought into contact with a mixed solution of tetramethoxysilane: methyl alcohol: water (molar ratio 1:4:4), so that the metal alcoholate solution gelled. After that, it was released from the mold. After sufficiently drying, it was heated and sintered to 950'C to obtain a quartz concave diffraction grating as shown in FIG.

得られた回折格子は型として使用したシリコーン樹脂回
折格子に対して、0.45倍に収縮しており、溝数は7
501ine /mm、曲率半径は3.8 cmであっ
た。
The obtained diffraction grating was 0.45 times smaller than the silicone resin diffraction grating used as a mold, and the number of grooves was 7.
The radius of curvature was 3.8 cm.

ブレーズ角の凹面内の位置変化を調べたところ、第2表
の結果が得られた。前述の第1表とともに下記に示す。
When the change in position of the blaze angle within the concave surface was investigated, the results shown in Table 2 were obtained. It is shown below along with the above-mentioned Table 1.

この第1表、第2表に示されるように、ブレーズ角は凹
面内でほぼ一定で、従来のものより著しく優れているこ
とがわかった。
As shown in Tables 1 and 2, the blaze angle was approximately constant within the concave surface, and was found to be significantly superior to the conventional one.

(以下、余白) 第1表 第2表 実施例2 厚さ30μmのシリコーン樹脂表面に3001 ine
/1)H1)のピッチでエシュレット回析格子をイオン
ビームエンヂングで形成した。これを曲率半径20cm
の凹状の基部に貼着し、テトラメトキンシラン:エチル
アルコール:水;塩酸(モル比 t:to:t。
(Hereinafter, blank space) Table 1 Table 2 Example 2 3001 ine on a silicone resin surface with a thickness of 30 μm
/1) An echelette diffraction grating with a pitch of H1) was formed by ion beam engraving. This has a radius of curvature of 20cm
Tetramethquine silane: ethyl alcohol: water; hydrochloric acid (molar ratio t:to:t).

: 0.02)の混合溶液に接触させ、金属アルコレー
ト溶液がゲル化した後、離型した。充分乾燥した後、9
50 ’cまで加熱焼結し、次ぎに薄片状に切り出し、
第4図に示すようなガラス薄片端面に溝数9681in
e /mm、曲率半径は6.2 cmの凸面回折格子面
5を作製した。
:0.02), and after the metal alcoholate solution gelled, the mold was released. After thoroughly drying,
Heat and sinter to 50'c, then cut into thin pieces,
The number of grooves on the end face of the glass thin piece is 9681 inches as shown in Figure 4.
A convex diffraction grating surface 5 with a radius of curvature of 6.2 cm and a radius of curvature of 6.2 cm was fabricated.

実施例3 厚さ2 mmのシリコーン樹脂表面に5001ine 
/mmのエシエレノト回折格子を作製し、これを曲率半
f条4 cmの凸状基部に付着させ、次いで未硬化エポ
キシ樹脂に接触させ、樹脂の硬化後、離型し、第3図に
示すような5001ine /mmのプラスティック凹
面回折格子を作製した。
Example 3 5001ine on a silicone resin surface with a thickness of 2 mm
/ mm was prepared, and it was attached to a convex base with a half-f curvature of 4 cm, and then brought into contact with uncured epoxy resin, and after the resin was cured, the mold was released, and as shown in Figure 3. A plastic concave diffraction grating of 5001 in/mm was fabricated.

この回折格子によってエボキン樹脂層内を導波してきた
光を分光することができる。薄膜型の光分波器を簡便に
装造可能になる。
This diffraction grating allows the light guided within the Evokin resin layer to be separated into spectra. It becomes possible to easily install a thin film type optical demultiplexer.

〔発明の効果〕〔Effect of the invention〕

以上説明したように本発明による曲面回折格子の製造方
法によれば、従来技術で容易に製造可能な平面回折格子
を用いて、ブレーズ角が凸面内で一定な回折効率の高い
凸面回折格子を製造することができるという利点がある
As explained above, according to the method for manufacturing a curved diffraction grating according to the present invention, a convex diffraction grating with high diffraction efficiency and a constant blaze angle within the convex surface is manufactured using a flat diffraction grating that can be easily manufactured using conventional technology. The advantage is that it can be done.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は凹面回折格子におけるブレーズ角の状態を説明
するための説明図、第2図は本発明による製造方法を説
明するための説明図、第3図は実施例1および実施例3
で製造された回折格子の斜視図、第4図は実施例2にお
いて製造された回折格子の斜視図である。 ■ ・・・柔軟材料、2 ・・・基部、3 ・・・曲面
回折格子材料、4 ・・・凹面回折格子、5 ・・・凸
面回折格子。
FIG. 1 is an explanatory diagram for explaining the state of the blaze angle in a concave diffraction grating, FIG. 2 is an explanatory diagram for explaining the manufacturing method according to the present invention, and FIG. 3 is an explanatory diagram for explaining the manufacturing method according to the present invention.
FIG. 4 is a perspective view of the diffraction grating manufactured in Example 2. ■...Flexible material, 2...Base, 3...Curved diffraction grating material, 4...Concave diffraction grating, 5...Convex diffraction grating.

Claims (2)

【特許請求の範囲】[Claims] (1)所定形状の平面回折格子を形成した柔軟な材料を
所定曲面に変形させ、この曲面化した柔軟材料を曲面回
折格子材料に接触させ、この曲面格子材料を硬化せしめ
ることを特徴とする曲面回折格子の製造方法。
(1) A curved surface characterized by deforming a flexible material on which a planar diffraction grating of a predetermined shape is formed into a predetermined curved surface, bringing the curved flexible material into contact with the curved grating material, and hardening the curved grating material. A method of manufacturing a diffraction grating.
(2)前記曲面格子材料は金属アルコレート溶液である
ことを特徴とする特許請求の範囲第1項記載の曲面回折
格子の製造方法。
(2) The method for manufacturing a curved diffraction grating according to claim 1, wherein the curved grating material is a metal alcoholate solution.
JP19369984A 1984-09-14 1984-09-14 Production of curved surface diffraction grating Pending JPS6172202A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP19369984A JPS6172202A (en) 1984-09-14 1984-09-14 Production of curved surface diffraction grating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP19369984A JPS6172202A (en) 1984-09-14 1984-09-14 Production of curved surface diffraction grating

Publications (1)

Publication Number Publication Date
JPS6172202A true JPS6172202A (en) 1986-04-14

Family

ID=16312311

Family Applications (1)

Application Number Title Priority Date Filing Date
JP19369984A Pending JPS6172202A (en) 1984-09-14 1984-09-14 Production of curved surface diffraction grating

Country Status (1)

Country Link
JP (1) JPS6172202A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0750207A2 (en) * 1995-06-19 1996-12-27 Eastman Kodak Company Color separating diffractive optical array and image sensor
CN103018893A (en) * 2012-11-28 2013-04-03 中国海洋大学 Transmission type adjustable liquid diffraction grating
WO2013183601A1 (en) 2012-06-08 2013-12-12 株式会社日立ハイテクノロジーズ Curved face diffraction grating fabrication method, curved face diffraction grating cast, and curved face diffraction grating employing same
WO2014148118A1 (en) 2013-03-19 2014-09-25 株式会社日立ハイテクノロジーズ Curved diffraction grating, production method therefor, and optical device
WO2019130835A1 (en) 2017-12-27 2019-07-04 株式会社日立ハイテクノロジーズ Method for manufacturingconcave diffraction grating, concave diffraction grating, and analysis device using same
WO2024171522A1 (en) * 2023-02-17 2024-08-22 株式会社日立ハイテク Diffraction grating and analysis device using same, and method for manufacturing diffraction grating

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0750207A2 (en) * 1995-06-19 1996-12-27 Eastman Kodak Company Color separating diffractive optical array and image sensor
EP0750207A3 (en) * 1995-06-19 1998-02-25 Eastman Kodak Company Color separating diffractive optical array and image sensor
WO2013183601A1 (en) 2012-06-08 2013-12-12 株式会社日立ハイテクノロジーズ Curved face diffraction grating fabrication method, curved face diffraction grating cast, and curved face diffraction grating employing same
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