JPS61277437A - Heat-ray reflecting resin glass - Google Patents
Heat-ray reflecting resin glassInfo
- Publication number
- JPS61277437A JPS61277437A JP12118785A JP12118785A JPS61277437A JP S61277437 A JPS61277437 A JP S61277437A JP 12118785 A JP12118785 A JP 12118785A JP 12118785 A JP12118785 A JP 12118785A JP S61277437 A JPS61277437 A JP S61277437A
- Authority
- JP
- Japan
- Prior art keywords
- heat ray
- resin glass
- ray reflective
- film
- plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Laminated Bodies (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、熱線反射樹脂ガラスに関し、詳しくは、板状
樹脂ガラスとフィルム基体との接着力を強化した熱線反
射樹脂ガラスに関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a heat ray reflective resin glass, and more particularly to a heat ray reflective resin glass in which the adhesive force between a plate-shaped resin glass and a film substrate is strengthened.
本発明の熱線反射樹脂ガラスは、板状樹脂ガラスとフィ
ルム基体との接着力が強固であり、自動車用熱線反射窓
ガラス等として利用できるものである。The heat-reflecting resin glass of the present invention has strong adhesive strength between the plate-shaped resin glass and the film substrate, and can be used as heat-reflecting window glass for automobiles.
［従来の技術］
従来、板状樹脂ガラスの表面に、熱線反射フィルム（フ
ィルム基体と該フィルム基体裏面に形成された熱線反射
膜とから成る）を一体内に融着させた熱線反射樹脂ガラ
スが知られている。[Prior Art] Conventionally, heat ray reflective resin glass has been produced in which a heat ray reflective film (consisting of a film base and a heat ray reflective film formed on the back surface of the film base) is integrally fused to the surface of a plate-shaped resin glass. Are known.
これは、軽量化、加工容易化、あるいは形状の曲面化等
を目的として、無機ガラスに代えて採用されたものであ
る。This was adopted in place of inorganic glass for the purpose of reducing weight, facilitating processing, or making the shape curved.
しかし、上記した従来の熱線反射樹脂ガラスは、板状樹
脂ガラスとフィルム基体との接着力が弱いという欠点を
有する。However, the above-mentioned conventional heat ray reflective resin glass has a drawback that the adhesive force between the plate-shaped resin glass and the film base is weak.
これは、板状樹脂ガラスとフィルム基体との間に配置さ
れる熱線反射膜が、前記板状樹脂ガラ、スと接着しにく
いためである。This is because the heat ray reflective film disposed between the plate-shaped resin glass and the film substrate is difficult to adhere to the plate-shaped resin glass.
［発明が解決しようとする問題点］
本発明は上記した欠点の解消を企図して案出されたもの
であり、板状樹脂ガラスとフィルム基体とを強固に接着
し充分な強度を有する熱線反射樹脂ガラスを提供するも
のである。[Problems to be Solved by the Invention] The present invention has been devised with the intention of eliminating the above-mentioned drawbacks, and is a heat ray reflective material that firmly adheres a plate-shaped resin glass and a film substrate and has sufficient strength. It provides resin glass.
［問題点を解決するための手段及び作用］本発明は、熱
線反射膜をメツシュ状またはスリット状のようにするこ
とによって、板状樹脂ガラスとフィルム基体とを多数部
位において直接的に接触させた熱線反射樹脂ガラスであ
る。[Means and effects for solving the problems] The present invention makes the heat ray reflective film have a mesh shape or a slit shape, so that the plate resin glass and the film base are brought into direct contact at multiple locations. It is a heat ray reflective resin glass.
即ち本発明は、
板状樹脂ガラスと、
該板状樹脂ガラス表面に被着されたフィルム基体と、
該フィルム基体裏面に形成され、前記板状樹脂ガラスと
前記フィルム基体との間に配置された熱線反射膜と、
を有する熱線反射樹脂ガラスであって、前記フィルム基
体の前記板状樹脂ガラス表面への被着は、該板状樹脂ガ
ラス表面に前記フィルム基体を直接的に接触させて行な
っている部位と、前記熱線反射膜を介して間接的に行な
っている部位とが混在していることを特徴とする熱線反
射樹脂ガラスである。That is, the present invention comprises: a plate-shaped resin glass; a film substrate adhered to the surface of the plate-shaped resin glass; and a film substrate formed on the back surface of the film substrate and disposed between the plate-shaped resin glass and the film substrate. A heat ray reflective resin glass having a heat ray reflective film, wherein the film base is adhered to the surface of the plate-shaped resin glass by bringing the film base into direct contact with the surface of the plate-shaped resin glass. This heat ray reflective resin glass is characterized in that there are a mixture of areas where the heat rays are exposed and areas where the heat rays are reflected indirectly through the heat ray reflective film.
ここに、板状樹脂ガラスの形状は、最終製品である熱線
反射樹脂ガラスの形状に合致し、これは、押し出し成形
、あるいは注型等の方法によって成形することができる
。Here, the shape of the plate-shaped resin glass matches the shape of the heat ray reflective resin glass that is the final product, and this can be molded by extrusion molding, casting, or other methods.
また、板状樹脂ガラスの材料としては、ＰＣ（ポリカー
ボネート） 、ＭＭＡ （メチルメタクリレート）、Ｍ
ＡＳ（メチルアクリレート−スチレン）、ＰＡ（ポリア
ミド）、ＰＳ（ポリスチレン）、ＡＳ（アクリロニトリ
ル−スチレン）等の透明なく着色されているものも可）
熱可塑性樹脂の単一体及び個々の樹脂を積層した積層体
（例えば、ＭＭＡｌＡＢＳ、ＰＣの三層積層体）を用い
ることができる。In addition, the materials for sheet resin glass include PC (polycarbonate), MMA (methyl methacrylate), M
Non-transparent colored materials such as AS (methyl acrylate-styrene), PA (polyamide), PS (polystyrene), and AS (acrylonitrile-styrene) are also acceptable)
A single thermoplastic resin and a laminate of individual resins (for example, a three-layer laminate of MMAAlABS and PC) can be used.
フィルム基体と、該フィルム基体裏面に形成される熱線
反射膜とから熱線反射フィルムが構成される。その厚さ
は、通常、５０μ〜１００μ程度である。なお熱線反射
膜の形成は、例えば公知の真空成膜法によって行なうこ
とができる。A heat ray reflective film is composed of a film base and a heat ray reflective film formed on the back surface of the film base. Its thickness is usually about 50μ to 100μ. Note that the heat ray reflective film can be formed by, for example, a known vacuum film forming method.
本発明において、板状樹脂ガラスとフィルム基体とには
、両者を直接的に接触させる部位と、熱線反射膜を介し
て間接的に接触させる部位とを設ける。そのためには、
例えば前記熱線反射膜の形成に際して適当なマスクを用
い、該熱線反射膜をメツシュ状（特許請求の範囲第２項
）、または、スリット状（特許請求の範囲第３項）とし
て形成するとよい。なお、熱線反射膜は、メツシュ状、
スリット状に限らず、上記板状樹脂ガラスとフィルム基
体とを、多数部位において直接的に接触させ得るもので
あればよい。In the present invention, the plate-shaped resin glass and the film substrate are provided with a portion where they are brought into direct contact and a portion where they are brought into indirect contact via a heat ray reflective film. for that purpose,
For example, when forming the heat ray reflective film, it is preferable to use a suitable mask and form the heat ray reflective film in a mesh shape (claim 2) or slit shape (claim 3). Note that the heat ray reflective film has a mesh shape,
The shape is not limited to the slit shape, and any shape can be used as long as the plate-shaped resin glass and the film base can be brought into direct contact at multiple locations.
上記において、フィルム基体としてはＰＣ（ポリカーボ
ネート）、ＰＡ（ポリアミド）、ＰＭＭＡ（ポリメチル
メタクリレート＞、ＰＥＴ（ボリエヂレンテレフタレー
ト）等を、また熱線反射膜としてはＡＩ（アルミニウム
）、Ｃｒ（クロム）、Ｎｉにッケル）、ＡＵ（金）、Ａ
ｇ（銀）、Ｚｎ（亜鉛）及び個々の金属の酸化膜との組
合せによる多層膜等を用いることができる。In the above, the film base is made of PC (polycarbonate), PA (polyamide), PMMA (polymethyl methacrylate), PET (bolyethylene terephthalate), etc., and the heat ray reflective film is made of AI (aluminum), Cr (chromium), etc. (Nickel), AU (gold), A
A multilayer film made of a combination of g (silver), Zn (zinc), and oxide films of individual metals can be used.
なお、フィルム基体の表面には、３μ〜１０μ程度の厚
さのハードコート膜を、エポキシ樹脂、アクリル樹脂、
アミン樹脂、ポリシロキサン等のハードコート剤を塗布
して形成してもよい。その際、フィルム基体とハードコ
ート膜との密着性を高めるために、必要に応じて該基体
表面にプライマー塗装を施すとよい。Furthermore, on the surface of the film base, a hard coat film with a thickness of about 3 μm to 10 μm is coated with epoxy resin, acrylic resin,
It may also be formed by applying a hard coat agent such as amine resin or polysiloxane. At that time, in order to improve the adhesion between the film base and the hard coat film, it is preferable to apply a primer coating to the surface of the base as necessary.
かかる板状樹脂ガラスと熱線反射フィルムとの接着は、
例えば、板状樹脂ガラスと熱線反射フィルムとを一対の
熱ローラ間に連続的に導き、該熱ローラ間にて加熱、加
圧して一体的に融着することによって行なうことができ
る。ここに、加熱温度、加圧力、及び熱ローラ間での進
行速度は、材料樹脂の種類、及び必要とされる融着の強
度に応じて定める。The adhesion between the sheet resin glass and the heat ray reflective film is as follows:
For example, this can be done by continuously guiding the plate-shaped resin glass and the heat ray reflective film between a pair of heat rollers, and heating and pressurizing the heat rollers to fuse them together. Here, the heating temperature, pressing force, and speed of movement between the heated rollers are determined depending on the type of resin material and the required strength of fusion.
また、成形型内に熱線反射フィルムをセラｌ−Ｌ、、こ
れに樹脂ガラスを注入して上記接着を行なうこともでき
る。Alternatively, the above bonding can be performed by placing a heat ray reflective film in the mold and injecting resin glass into it.
［実施例］ 以下、本発明を具体的な実施例に基づいて説明する。[Example] The present invention will be described below based on specific examples.
第１図は、本発明の実施例の断面模式図であり、第２図
は、該実施例の熱線反射樹脂ガラスの製造方法の説明図
である。FIG. 1 is a schematic cross-sectional view of an example of the present invention, and FIG. 2 is an explanatory diagram of a method for manufacturing heat ray reflective resin glass of this example.
図示のように、本実施例の熱線反射樹脂ガラスは、板状
樹脂ガラス７と、該板状樹脂ガラス７の表面に被着され
た熱線反射フィルム６とから成る。As shown in the figure, the heat-reflecting resin glass of this embodiment is composed of a plate-shaped resin glass 7 and a heat-reflecting film 6 adhered to the surface of the plate-shaped resin glass 7.
ここに、熱線反射フィルム６は、フィルム基体６０と、
該フィルム基体６ｏの一面に形成された熱線反射Ｉ！６
１と、該フィルム基体６０の他面に形成されたハードコ
ート層６２とから成り、前記熱線反射膜６１の形成され
ている側が前記板状樹脂ガラス７に融着されている。Here, the heat ray reflective film 6 includes a film base 60,
Heat ray reflection I formed on one surface of the film base 6o! 6
1 and a hard coat layer 62 formed on the other surface of the film base 60, and the side on which the heat ray reflective film 61 is formed is fused to the plate-shaped resin glass 7.
本実施例の熱線反射樹脂ガラスは、以下の如くして製造
したものである。The heat ray reflective resin glass of this example was manufactured as follows.
（ａ）熱線反射フィルム６
まず、フィルム基体６０に、蒸着またはスパッタリング
によってメツシュ状に熱線反射膜６１を形成し、これを
、熱線反射フィルム送り出し用ローラ５にセットする。(a) Heat ray reflective film 6 First, a mesh-like heat ray reflective film 61 is formed on the film base 60 by vapor deposition or sputtering, and this is set on the heat ray reflective film feeding roller 5.
ここに、フィルム基体６０としてはポリカーボネート（
ＰＣ）を、また、熱線反射膜６１としてはＴｉ１ｔとＡ
（ｌとＴｉ ０２の三層構造の膜をそれぞれ用いた。な
お、フィルム基体６０の表面であって前記熱線反ｇ）ｌ
膜６１を形成しない側の面には、あらかじめハードコー
ト処理を施し、ハードコートＷＪ６２を形成しておいた
。Here, the film base 60 is made of polycarbonate (
PC), and Ti1t and A as the heat ray reflective film 61.
A three-layer structure film of (1) and Ti02 was used. Note that the surface of the film base 60 and the above-mentioned heat rays (g)1
The surface on the side on which the film 61 was not formed was previously subjected to hard coat treatment to form a hard coat WJ62.
（ｂ）板状樹脂ガラス７
前記（ａ）の工程と平行的に、押し出し機１のホッパ１
１から原料樹脂（ポリカーボネート）を供給し、ダイ２
から板状樹脂ガラス７を押し出し成形してこれを引き取
り装置３で引き取る。(b) Plate resin glass 7 In parallel to the step (a) above, the hopper 1 of the extruder 1
The raw material resin (polycarbonate) is supplied from die 2.
A plate-shaped resin glass 7 is extruded from the glass and is taken by a taking-off device 3.
（Ｃ）融着
前期熱線反射フィルム送り出し用ローラ５から熱線反射
フィルム６を、また、前記引き取り装置３から板状樹脂
ガラス７を、それぞれ熱ローラ４１．４２間に導き、該
熱Ｏ−ラ４１．４２間で加熱、加圧しつつ進行させ、該
熱線反射フィルム６と該板状樹脂ガラス７とを連続的に
融着させた。(C) The heat ray reflective film 6 is guided from the heat ray reflective film delivery roller 5 in the early stage of fusion bonding, and the plate-shaped resin glass 7 is guided between the heat rollers 41 and 42 from the take-up device 3, respectively. The heat ray reflective film 6 and the plate-shaped resin glass 7 were continuously fused together by heating and pressurizing the heat rays at a temperature of .42 mm.
また、熱線反射フィルム６の融着面は、第２図図示のよ
うに前記熱線反射膜６１を形成した側の面とした。Moreover, the fusion surface of the heat ray reflective film 6 was the surface on which the heat ray reflective film 61 was formed, as shown in FIG.
このようにして製造した本実施例の熱線反射樹脂ガラス
は、以下のごとき利点を有する。The heat ray reflective resin glass of this example manufactured in this manner has the following advantages.
第１に、熱線反射膜６１をメツシュ状としているため、
フィルム基体６０と板状樹脂ガラス７との密着性が良好
である。First, since the heat ray reflective film 61 is mesh-shaped,
Adhesion between the film base 60 and the plate-shaped resin glass 7 is good.
第２に、熱線反射膜６１は、板状樹脂ガラス７とフィル
ム基体６０とにサンドインチされているため、該熱線反
射膜６１が傷ついたり、薬品に侵されることが防止され
る。Second, since the heat ray reflective film 61 is sandwiched between the plate-shaped resin glass 7 and the film base 60, the heat ray reflective film 61 is prevented from being damaged or attacked by chemicals.
第３に、ハードコート膜６２によって、表面の傷つきが
防止される。Thirdly, the hard coat film 62 prevents the surface from being scratched.
第４に、熱線反射フィルム６によって、割れ、破損が防
止される。Fourthly, the heat ray reflective film 6 prevents cracking and damage.
第５に、樹脂製であるため曲面形状とすることが可能で
あり、また、穴加工等の加工も容易である。Fifth, since it is made of resin, it can be formed into a curved shape, and it is also easy to process holes and the like.
第６に、メツシュ状の熱線反射膜によって、意匠効果が
得られる。Sixthly, the mesh-like heat ray reflective film provides a design effect.
（評価）
上記実施例の熱線反射樹脂ガラスに
ついて、熱線反射機能の評価を行なった。その結果を第
３図に示す。(Evaluation) The heat ray reflective function of the heat ray reflective resin glasses of the above examples was evaluated. The results are shown in FIG.
第３図かられかるように、本実施例の熱線反射樹脂ガラ
スは、赤外域において良好な反！）１機能を有する。As can be seen from FIG. 3, the heat ray reflective resin glass of this example has good resistance in the infrared region! ) has one function.
［発明の効果］
以上、要するに本発明は、熱線反射膜をメツシュ状また
はスリット状のようにすることによ・って、フィルム基
体と板状樹脂ガラスとの接着力を強化した熱線反射樹脂
ガラスである。[Effects of the Invention] In summary, the present invention provides a heat ray reflective resin glass in which the adhesive force between the film base and the plate resin glass is strengthened by forming the heat ray reflective film into a mesh shape or a slit shape. It is.
実施例に述べたところからも明らかなように、本発明の
熱線反射樹脂ガラスは、フィルム基体と板状樹脂ガラス
とが多数の部位において直接的に接触しているため、両
者の接着力が強固である。As is clear from the examples described, in the heat ray reflective resin glass of the present invention, since the film base and the plate-shaped resin glass are in direct contact with each other at many parts, the adhesive strength between the two is strong. It is.
また、樹脂製であるため曲面形状とすることが可能であ
り、穴加工等の加工も容易である。 。Further, since it is made of resin, it can be formed into a curved shape, and processing such as hole drilling is also easy. .
また、熱線反射膜は、板状樹脂ガラスとフィルム基体と
にサンドインチされているため、該熱線反射膜が傷つい
たり、薬品に侵されることが防止される。Further, since the heat ray reflective film is sandwiched between the plate-shaped resin glass and the film base, the heat ray reflective film is prevented from being damaged or attacked by chemicals.
さらにまた、熱線反射フィルムによって、割れ、及び破
損が防止される。Furthermore, the heat reflective film prevents cracking and damage.
第１図は、本発明の実施例の熱線反射樹脂ガラスの断面
模式図であり、第２図は、該実施例の熱線反射樹脂ガラ
スの製造方法の説明図である。第３図は、実施例の方法
によって製造した熱線反射樹脂ガラスと、熱線反射膜を
有しない樹脂ガラスとの熱線反射機能を比較するグラフ
である。
１・・・押し出し機 ２・・・ダイ３・・・引き取
り装置
４１．４２・・・熱ローラ
６・・・熱線反射フィルム
７・・・板状樹脂ガラスFIG. 1 is a schematic cross-sectional view of a heat ray reflective resin glass according to an example of the present invention, and FIG. 2 is an explanatory diagram of a method for manufacturing the heat ray reflective resin glass according to the example. FIG. 3 is a graph comparing the heat ray reflection function of the heat ray reflection resin glass manufactured by the method of the example and the resin glass without a heat ray reflection film. 1...Extruder 2...Die 3...Take-off device 41.42...Heat roller 6...Heat ray reflective film 7...Plate resin glass
Claims (3)
前記フィルム基体との間に配置された熱線反射膜と、 を有する熱線反射樹脂ガラスであって、 前記フィルム基体の前記板状樹脂ガラス表面への被着は
、該板状樹脂ガラス表面に前記フィルム基体を直接的に
接触させて行なっている部位と、前記熱線反射膜を介し
て間接的に行なっている部位とが混在していることを特
徴とする熱線反射樹脂ガラス。(1) A plate-shaped resin glass, a film substrate adhered to the surface of the plate-shaped resin glass, and a heat ray reflector formed on the back surface of the film substrate and arranged between the plate-shaped resin glass and the film substrate. A heat ray reflective resin glass comprising a film, wherein the adhesion of the film substrate to the surface of the plate-shaped resin glass is performed by bringing the film substrate into direct contact with the surface of the plate-shaped resin glass. 1. A heat ray reflective resin glass characterized in that a heat ray reflective resin glass has a coexistence of a portion where the heat ray reflection is performed indirectly through the heat ray reflective film.
範囲第１項記載の熱線反射樹脂ガラス。(2) The heat ray reflective resin glass according to claim 1, wherein the heat ray reflective film has a mesh shape.
範囲第１項記載の熱線反射樹脂ガラス。(3) The heat ray reflective resin glass according to claim 1, wherein the heat ray reflective film has a slit shape.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12118785A JPS61277437A (en) | 1985-06-04 | 1985-06-04 | Heat-ray reflecting resin glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12118785A JPS61277437A (en) | 1985-06-04 | 1985-06-04 | Heat-ray reflecting resin glass |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS61277437A true JPS61277437A (en) | 1986-12-08 |
Family
ID=14805008
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12118785A Pending JPS61277437A (en) | 1985-06-04 | 1985-06-04 | Heat-ray reflecting resin glass |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61277437A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7238418B2 (en) | 2002-09-25 | 2007-07-03 | Sumitomo Metal Mining Co., Ltd. | Heat radiation shielding component dispersion, process for its preparation and heat radiation shielding film forming coating liquid, heat radiation shielding film and heat radiation shielding resin form which are obtained using the dispersion |
| WO2008136328A1 (en) | 2007-04-26 | 2008-11-13 | Sumitomo Metal Mining Co., Ltd. | Hot radiation shielding polyester film, and hot radiation shielding polyester film laminate |
| WO2009054051A1 (en) | 2007-10-23 | 2009-04-30 | Sumitomo Metal Mining Co., Ltd. | Solar-radiation-shielding material for vehicle window and window for vehicle |
| US7666930B2 (en) | 2002-07-31 | 2010-02-23 | Sumitomo Metal Mining Co., Ltd. | Master batch containing heat radiation shielding component, and heat radiation shielding transparent resin form and heat radiation shielding transparent laminate for which the master batch has been used |
| JP2012530011A (en) * | 2009-06-12 | 2012-11-29 | ピーピージー・インダストリーズ・オハイオ・インコーポレイテッド | Aircraft transparent material with solar control characteristics |
| WO2013125563A1 (en) | 2012-02-22 | 2013-08-29 | 住友金属鉱山株式会社 | Polycarbonate resin composition containing dispersed composite-tungsten-oxide microparticles and radiated-heat-blocking molded body and radiated-heat-blocking laminate using said composition |
| WO2014163119A1 (en) | 2013-04-03 | 2014-10-09 | 住友金属鉱山株式会社 | Heat-ray-shielding film, heat-ray-shielding transparent substrate, heat-ray-shielding resin sheet material, vehicle, and building |
| US9074071B2 (en) | 2002-05-13 | 2015-07-07 | Sumitomo Metal Mining Co., Ltd. | Heat ray shielding sheet material and liquid additive for use in producing the same |
-
1985
- 1985-06-04 JP JP12118785A patent/JPS61277437A/en active Pending
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9074071B2 (en) | 2002-05-13 | 2015-07-07 | Sumitomo Metal Mining Co., Ltd. | Heat ray shielding sheet material and liquid additive for use in producing the same |
| US7666930B2 (en) | 2002-07-31 | 2010-02-23 | Sumitomo Metal Mining Co., Ltd. | Master batch containing heat radiation shielding component, and heat radiation shielding transparent resin form and heat radiation shielding transparent laminate for which the master batch has been used |
| US7238418B2 (en) | 2002-09-25 | 2007-07-03 | Sumitomo Metal Mining Co., Ltd. | Heat radiation shielding component dispersion, process for its preparation and heat radiation shielding film forming coating liquid, heat radiation shielding film and heat radiation shielding resin form which are obtained using the dispersion |
| WO2008136328A1 (en) | 2007-04-26 | 2008-11-13 | Sumitomo Metal Mining Co., Ltd. | Hot radiation shielding polyester film, and hot radiation shielding polyester film laminate |
| WO2009054051A1 (en) | 2007-10-23 | 2009-04-30 | Sumitomo Metal Mining Co., Ltd. | Solar-radiation-shielding material for vehicle window and window for vehicle |
| US10795065B2 (en) | 2007-10-23 | 2020-10-06 | Sumitomo Metal Mining Co., Ltd. | Solar-radiation-shielding material for vehicle window and window for vehicle |
| JP2012530011A (en) * | 2009-06-12 | 2012-11-29 | ピーピージー・インダストリーズ・オハイオ・インコーポレイテッド | Aircraft transparent material with solar control characteristics |
| US9612366B2 (en) | 2012-02-22 | 2017-04-04 | Sumitomo Metal Mining Co., Ltd. | Composite tungsten oxide particle dispersion polycarbonate resin composition and heat-ray shielding sintered compact and heat-ray shielding laminate using the composition |
| WO2013125563A1 (en) | 2012-02-22 | 2013-08-29 | 住友金属鉱山株式会社 | Polycarbonate resin composition containing dispersed composite-tungsten-oxide microparticles and radiated-heat-blocking molded body and radiated-heat-blocking laminate using said composition |
| KR20140129210A (en) | 2012-02-22 | 2014-11-06 | 스미토모 긴조쿠 고잔 가부시키가이샤 | Polycarbonate resin composition containing dispersed composite-tungsten-oxide microparticles and radiated-heat-blocking molded body and radiated-heat-blocking laminate using said composition |
| WO2014163119A1 (en) | 2013-04-03 | 2014-10-09 | 住友金属鉱山株式会社 | Heat-ray-shielding film, heat-ray-shielding transparent substrate, heat-ray-shielding resin sheet material, vehicle, and building |
| EP3034294A1 (en) | 2013-04-03 | 2016-06-22 | Sumitomo Metal Mining Co., Ltd. | Heat-ray-shielding film, heat-ray-shielding transparent substrate, heat-ray-shielding resin sheet material, vehicle, and building |
| US9868665B2 (en) | 2013-04-03 | 2018-01-16 | Sumitomo Metal Mining Co., Ltd. | Heat ray-shielding film, heat ray-shielding laminated transparent base material, heat ray-shielding resin sheet material, automobile and building |
| KR20150138347A (en) | 2013-04-03 | 2015-12-09 | 스미토모 긴조쿠 고잔 가부시키가이샤 | Heat-ray-shielding film, heat-ray-shielding transparent substrate, heat-ray-shielding resin sheet material, vehicle, and building |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2316914C (en) | Metallized sheeting, composites, and methods for their formation | |
| US3839129A (en) | Reflective foil and process | |
| US4403004A (en) | Sandwich metalized resin laminate | |
| US5264063A (en) | Method for making flexible retroreflective sheet material | |
| US4023889A (en) | Retroreflective laminate | |
| JPS61277437A (en) | Heat-ray reflecting resin glass | |
| GB1372237A (en) | Process for the production of an article having an integral mirror surface | |
| CN1165783C (en) | Method of making signs having metalized cube corner sheeting | |
| JPS60250927A (en) | Manufacture of synthetic resin molding excellent in haze prevention performance | |
| US5164032A (en) | Method of forming a decorative article | |
| JPS615910A (en) | Preparation of synthetic resin formed piece excellent in photochromism | |
| JP2545051B2 (en) | Method of manufacturing hologram decorative resin molded product | |
| JPS61277446A (en) | Manufacture of heat-ray reflecting resin glass | |
| JPS62192779A (en) | Manufacture of hologram forming sheet | |
| JPH0490204A (en) | Manufacture of parabolic antenna | |
| JP3130163B2 (en) | New surface hardness modified plate and its manufacturing method. | |
| JPS6110415A (en) | Decorative sheet | |
| JPS6110414A (en) | Decorative sheet | |
| JPS60250926A (en) | Manufacture of synthetic resin molding excellent in antistatic performance | |
| JPH049648B2 (en) | ||
| JPH0663990A (en) | Molded piece with iridescent pattern and manufacture thereof | |
| JPS6226196Y2 (en) | ||
| JP4074558B2 (en) | Molding simultaneous painting sheet and molding simultaneous painting method | |
| JP2001030287A (en) | Manufacture of optical component made of plastic | |
| JP2780946B2 (en) | Method for manufacturing colored resin molded products |