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JPS6046503A - Diffusion plate - Google Patents

Diffusion plate

Info

Publication number
JPS6046503A
JPS6046503A JP15442483A JP15442483A JPS6046503A JP S6046503 A JPS6046503 A JP S6046503A JP 15442483 A JP15442483 A JP 15442483A JP 15442483 A JP15442483 A JP 15442483A JP S6046503 A JPS6046503 A JP S6046503A
Authority
JP
Japan
Prior art keywords
muscovite
silicon oxide
particle size
see
diffusion plate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP15442483A
Other languages
Japanese (ja)
Inventor
Masao Inoue
井上 雅勇
Shingo Suzuki
信吾 鈴木
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Rayon Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Rayon Co Ltd filed Critical Mitsubishi Rayon Co Ltd
Priority to JP15442483A priority Critical patent/JPS6046503A/en
Publication of JPS6046503A publication Critical patent/JPS6046503A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/02Diffusing elements; Afocal elements
    • G02B5/0205Diffusing elements; Afocal elements characterised by the diffusing properties
    • G02B5/0236Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place within the volume of the element
    • G02B5/0242Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place within the volume of the element by means of dispersed particles
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/02Diffusing elements; Afocal elements
    • G02B5/0273Diffusing elements; Afocal elements characterized by the use
    • G02B5/0278Diffusing elements; Afocal elements characterized by the use used in transmission

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Optical Elements Other Than Lenses (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 (発明の目的) 本発明は、光の透過率が高くかつシースルー(光源の透
視性)の少ない拡散板に関し、透過製スクリーンや照明
カバー等として用いらnるものである。
[Detailed Description of the Invention] (Object of the Invention) The present invention relates to a diffuser plate that has high light transmittance and low see-through (light source transparency), and is used as a transparent screen, lighting cover, etc. be.

(従来技術) 照明カバー、ディスプレイ装置おるいは背面投影スクリ
ーン等として用しられている拡散板は、均一な拡散性を
得るために、表面に微細な凹凸を付与する方法、拡散剤
層を塗布形成する方法るるいは拡散剤を基材に分散させ
る方法等によって製作さtて−る。こ詐らのうち後2者
すなわち拡散剤を用いる方法は、各種の性能を備えた拡
散剤の中から選択できること、−貫して製作でき生産効
率が高いことがめり、広く普及している。
(Prior art) Diffusion plates used as lighting covers, display devices, rear projection screens, etc., have a method of providing fine irregularities on the surface or coating a diffusion agent layer in order to obtain uniform diffusion properties. It can be manufactured by a method of forming a base material, or by a method of dispersing a diffusing agent in a base material. The latter two methods, that is, the method using a diffusing agent, are widely used because they can be selected from among diffusing agents with various performances, can be manufactured consistently, and have high production efficiency.

ところで、このような拡散剤としては、従来エタ酸化ケ
イ素、硫酸バリウムおるいは硝子粒子等各種のものが用
いらnている。例えば、酸化ケイ素を用いるものとして
は、実公昭29−7440号公報、特公昭51−367
79号公報、特公昭52−20857号公報、特開昭5
3−110826号公報、特開昭54−155244号
公報おるいは特開昭57−5742号公報等が知らnて
おり、この種の拡散剤の中におって酸化ケイ素は、高い
拡散性と全光綜透過率を発揮させる物質として多用さn
ている。しかしながら酸化ケイ素は硬度が7と高いため
、酸化ケイ素を添加した拡散板を切断するときに鋸の摩
耗が激しく従って鋸の交換を頻繁に行なわなければなら
ず、また酸化ケイ素を含む成形材料を押出し成形して拡
散板を製作する際にスクリュー等の摩耗を起し易く、あ
るいは酸化ケイ素を含む塗料を塗布するときに用いるド
クターナイフを損耗させる等の特に製造、加工面の問題
点を有していた。
Incidentally, as such a diffusing agent, various materials such as silicon ethyl oxide, barium sulfate, and glass particles have conventionally been used. For example, examples using silicon oxide include Utility Model Publication No. 29-7440 and Japanese Patent Publication No. 51-367.
Publication No. 79, Japanese Patent Publication No. 52-20857, Japanese Unexamined Patent Publication No. 52-2085
3-110826, JP-A-54-155244, JP-A-57-5742, etc. are known, and among this type of diffusing agent, silicon oxide has a high diffusivity. Frequently used as a substance that exhibits total light transmittance.
ing. However, since silicon oxide has a high hardness of 7, the saw is severely worn when cutting the diffuser plate containing silicon oxide, so the saw must be replaced frequently, and the molding material containing silicon oxide must be extruded. There are problems in manufacturing and processing, such as easy wear of screws when molding and manufacturing a diffuser plate, and wear and tear on the doctor knife used when applying paint containing silicon oxide. Ta.

本発明者は、特定粒径の白雲母を拡散剤として用いるこ
とを既に提案しているが、この白雲母に酸化ケイ素と比
べて若干全光線透過率が低いものの明るく拡散性も優れ
た性質を有している。しかもこの白雲母は硬度が2.5
〜3と柔かいため、上記酸化ケイ素と併用してこの添加
量を低く抑えると有利でめり、しかも白雲母は少量であ
ってもシースルーが少ないため、両者を混用することは
、バランスのとnた拡散板を得るためにきわめて有効で
あることが判った。
The present inventor has already proposed the use of muscovite of a specific particle size as a diffusing agent, and although this muscovite has slightly lower total light transmittance than silicon oxide, it has the property of being bright and having excellent diffusivity. have. Moreover, this muscovite has a hardness of 2.5
~3, it is soft, so it is advantageous to use it together with the silicon oxide mentioned above to keep the amount added low.Furthermore, even if a small amount of muscovite is used, there is little see-through, so mixing the two is a good idea because of the balance. It has been found that this method is extremely effective for obtaining a diffuser plate.

(発明の目的) 本発明はこのような検討結果をふまえ、特定粒径の酸化
ケイ素と白雲母との混用によって、シースルーを抑えた
優詐た拡散特性と明るさとを備え、かつ同時に加工性を
高めた拡散板を提供しようとするものでおる。
(Objective of the Invention) Based on the above study results, the present invention has been developed to provide excellent diffusion characteristics and brightness that suppress see-through by using a mixture of silicon oxide and muscovite of a specific particle size, and at the same time improve processability. This is intended to provide an enhanced diffusion plate.

(発明の構成) すなわち本発明の要旨とするところは、平均粒径1〜1
0μの酸化ケイ素と、平均粒径15〜40μの白雲母と
がシースルーを起さない開会で添加されていることを特
徴とする拡散板におる。
(Structure of the Invention) That is, the gist of the present invention is that the average particle size is 1 to 1
The diffusion plate is characterized in that silicon oxide of 0 μm and muscovite of average particle size of 15 to 40 μm are added in an opening that does not cause see-through.

以下、本発明を実施例に従って説明する。Hereinafter, the present invention will be explained according to examples.

平均粒径6μで屈折率1.46の酸化ケイ素(S102
)と、平均粒径15〜35μで屈折率1155〜1.5
9の白雲母(KAlz (AISisOxo)(OH)
z )とを用意し、この酸化ケイ素と白雲母をメタクリ
ル樹脂板を製造する際の部分重会物に添加し、第1図に
示すように基材に均一に添加さnる工うにして板厚5■
のメタクリル樹脂板を作成した。
Silicon oxide (S102) with an average particle size of 6μ and a refractive index of 1.46.
) and a refractive index of 1155 to 1.5 with an average particle size of 15 to 35μ.
9 Muscovite (KAlz (AISisOxo) (OH)
The silicon oxide and muscovite are added to the partially polymerized material used to produce the methacrylic resin plate, and then uniformly added to the base material as shown in Figure 1. Plate thickness 5■
A methacrylic resin board was created.

t′fc比較のため酸化ケイ素単独および白雲母単独の
メタクリル樹脂板も作成した。こ詐らの試料の評価結果
は第1表に示す通りであり几。なお第1図は、この実施
例と同じように基材に酸化ケイ素と白雲母とを均一に添
加して得た拡散板を示しており、(1)が該拡散板であ
る。
For comparison of t'fc, methacrylic resin plates made of silicon oxide alone and muscovite alone were also prepared. The evaluation results of the sample by these authors are shown in Table 1. Note that FIG. 1 shows a diffusion plate obtained by uniformly adding silicon oxide and muscovite to a base material in the same manner as in this example, and (1) is the diffusion plate.

第1表 なお、平均粒径は、酸化ケイ素の場合一般的に用−られ
ているが、白雲母のように板状結晶の場合、厳密な意味
では正しめとはいえない。
Table 1 Note that the average particle size is generally used in the case of silicon oxide, but in the case of plate-shaped crystals such as muscovite, it cannot be said to be correct in a strict sense.

しかしながら、白雲母の場合も七詐相当の球状をもつも
のとみなして粒径とよぶのが普通なので、こnに従った
。また平均粒径とは、その範囲内に80%の粒子が入っ
ていることを指している。
However, in the case of muscovite as well, it is common to assume that it has a spherical shape equivalent to seven squares and call it the particle size, so this is followed. Furthermore, the average particle size means that 80% of the particles fall within that range.

評価項目のうちシースルーは、10m離した蛍光灯を透
かして見て、その輪郭がはつきり見えるとき×、見えな
いとき○とした。またスクリーンゲインは、試料を一定
の照度で照らし、反対側の輝度を測定して両者の比をと
った。さらに切断性は、拡散板を連続的に切断し、鋸を
交換するまでの切断長さを測った。
Among the evaluation items, see-through was evaluated as × if the outline of the fluorescent lamp was clearly visible when viewed through a fluorescent lamp 10 meters away, and ○ if it was not visible. The screen gain was determined by illuminating the sample with a constant illuminance, measuring the brightness on the opposite side, and calculating the ratio of the two. Furthermore, cutting performance was determined by continuously cutting the diffuser plate and measuring the cutting length until the saw was replaced.

この実施例における試料■〜のは、本発明品でシースル
ーがない混合割合な示している。これに対し試料■〜0
はシースルーが起きてしまう混合割合の例でらり、シー
スルーを起さない限界は、たまたま試料@、 o”c示
す酸化ケイ素。
Samples ① to 1 in this example show the mixing ratio of the products of the present invention with no see-through. In contrast, sample ■~0
is an example of a mixing ratio that causes see-through, and the limit that does not cause see-through happens to be the silicon oxide shown in the sample.

白雲母そnぞnを単独に添加する場合のシースルー限界
を結ぶ線で一致している(第3図参照)。
They coincide with the line connecting the see-through limit when muscovite is added alone (see Figure 3).

また試料■〜■は、全光線透過率がはソ85チ以上うタ
、スクリーンゲインも高いバランスのと7″L友もので
あった。一方、試料■〜0は全光線透過率は高いが、上
述したようにシースルーが起き好ましくなかった。なお
、酸化ケイ累。
In addition, samples ■~■ had a total light transmittance of 85 cm or more and a well-balanced screen gain of 7''L.On the other hand, samples ■~0 had a high total light transmittance, but had a high screen gain. However, as mentioned above, see-through occurred, which was undesirable.

白雲母そn−t″nn単独もの試料@、■は、こ牡も使
用可能であるが、@は切断時の鋸交換が頻繁になり、ま
たのは全光線透過率が若干低くなっている。切断性につ
いて試料■を代表例としたが、試料@と比べて数倍の切
断長さがあり、鋸交換の頻度はきわめて少なくなった。
Muscovite son-t''nn single samples @ and ■ can also be used, but @ requires frequent saw replacement during cutting, and total light transmittance is slightly lower. Regarding cutting performance, sample ① was used as a representative example, but compared to sample @, the cutting length was several times that of sample @, and the frequency of saw replacement was extremely low.

以上実施例を挙げて説明したが、さらに補足説明すると
、酸化ケイ素の平均粒径は、1p未満になると拡散性が
強すぎて全光線透過率が下ってしまい、逆に10μを超
えるとシースルーが強くなってしまうことから、1〜1
0μの範囲とすることが好ましい。そしてこのときの添
加量としては10〜60 t/rn2 程度でおる。ま
た白雲母の平均粒径が15p未満であるとシースルーに
対する効果がなく、40μを超えると必然的に大きな粒
子が含まれることとなり、拡散板としたときの外観を低
下させる難点があるからである。しかも、拡散板を製造
する際、部分重合物等を濾過することがめるが、粒径が
大き−とf過の目づまりを起す原因ともなり好筐しくな
い。以上のことから本発明においては、平均粒径15〜
40μの範囲の白雲母を用いることが好ましい。また、
このときの白雲母の添加tは10017m”以下、特に
50〜6ot/m2程度が好ましい。さらに、酸化ケイ
累と白雲母とのシースルーを起さない混合割合について
は、上記実施例によって示したが、そ牡ぞn単独系での
全光線透過率とシースルーの限界を測定しておけば、設
定値に対して概ねの割合を決めることができる。
The above explanation has been given with examples, but to provide a further explanation, when the average particle size of silicon oxide is less than 1p, the diffusivity is too strong and the total light transmittance decreases, and on the other hand, when it exceeds 10μ, the see-through is reduced. 1 to 1 because it will become stronger
It is preferable to set it in the range of 0μ. The amount added at this time is about 10 to 60 t/rn2. Furthermore, if the average particle size of muscovite is less than 15p, there is no effect on see-through, and if it exceeds 40μ, large particles will inevitably be included, which has the disadvantage of degrading the appearance when used as a diffuser plate. . Moreover, when manufacturing the diffuser plate, it is possible to filter partially polymerized substances, but if the particle size is large, it may cause clogging of the f-filter, which is not desirable. From the above, in the present invention, the average particle size is 15 to
Preferably, muscovite in the 40μ range is used. Also,
The addition t of muscovite at this time is preferably 10017 m'' or less, particularly about 50 to 6 ot/m2.Furthermore, the mixing ratio of silica oxide and muscovite that does not cause see-through is as shown in the above example. By measuring the total light transmittance and the limit of see-through in a single system, it is possible to determine the approximate ratio to the set value.

以上、メタクリル樹脂に均一に添加させた場合の実施例
について説明したが、木兄8Aはこの例に限定さnず、
塗料中に同じ範囲の平均粒径の酸化ケイ素と白雲母とを
分散させ、透明基板に塗布させて拡散板とすることもで
きる。この例を示したのが第2図でらり、QJ)が透明
基板、(6)が酸化ケイ素と白雲母とを含む塗層、(1
)が得らnた拡散板である。
Above, an example in which it is added uniformly to methacrylic resin has been described, but Kinoe 8A is not limited to this example.
It is also possible to make a diffusion plate by dispersing silicon oxide and muscovite having average particle diameters in the same range in a paint and coating it on a transparent substrate. An example of this is shown in Figure 2, where QJ) is a transparent substrate, (6) is a coating layer containing silicon oxide and muscovite, and (1) is a transparent substrate.
) is the obtained diffuser plate.

また本発明では、各種のレンチキュラーレンズを賦形す
ることも有効でめり;またフレネルレンズを設けて拡散
板を全体的に明るくすることもできる。さらに、加熱プ
レスや鈴込重合時に表面に微細な凹凸を付与することも
有効で、こnによって拡散性金補なうことも可能でおる
In the present invention, it is also effective to form various lenticular lenses; it is also possible to provide a Fresnel lens to brighten the entire diffuser plate. Furthermore, it is also effective to provide fine irregularities on the surface during hot pressing or polymerization, and it is also possible to compensate for the diffusible gold by this process.

勿論、こnらレンチキュラーレンズ、フレネルレンズお
よび微細凹凸は、必要に応じて2以上を組合せることも
可能でるる。
Of course, it is also possible to combine two or more of these lenticular lenses, Fresnel lenses, and fine irregularities as necessary.

なお、本発明の拡散板の基材としては、ガラスや合成樹
脂の透明材料を用いるのが一般的であるが、このうち、
上述したメタクリル樹脂。
Note that transparent materials such as glass or synthetic resin are generally used as the base material of the diffuser plate of the present invention, but among these,
The methacrylic resin mentioned above.

ポリカーボネート樹脂、塩化ビニル樹脂、スチレン樹脂
等の合成樹脂材料が特に適している。
Synthetic resin materials such as polycarbonate resin, vinyl chloride resin, and styrene resin are particularly suitable.

(発明の効果) 本発明は以上詳述した如き構成からなるものであるから
、光線透過率が高くかつシースルーがきわめて少なくし
かも加工性のよい拡散板を簡便に得らnる利点がおる。
(Effects of the Invention) Since the present invention has the structure as described in detail above, it has the advantage that a diffuser plate having high light transmittance, extremely little see-through, and good workability can be easily obtained.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図および第2図は本発明の拡散板の実施例を示す拡
大断面図、第3図は実施例の評価を示すグラフでめる。 (1)・・・・・拡散板 α■・・・・・透明基板 (2)・・・・・塗 層
1 and 2 are enlarged sectional views showing examples of the diffuser plate of the present invention, and FIG. 3 is a graph showing evaluation of the examples. (1)・・・Diffusion plate α■・・・Transparent substrate (2)・・・Coating layer

Claims (1)

【特許請求の範囲】 1、 平均粒径1〜10μの酸化ケイ素と、平均粒径1
5〜40pの白雲母とがシースルーを起さない開会で添
加されていることを特徴とする拡散板。 2 酸化ケイ素と白雲母とが基材に均一に添加されてi
ることを特徴とする特許請求の範囲第1項記載の拡散板
。 & 酸化ケイ素と白雲母とを含む塗層が形成さnている
ことを特徴とする特許請求の範囲第1項記載の拡散板。 4、 レンチキュラーレンズ、フレネルレンズあるいは
微細な凹凸の少なくとも1′″)が設けらnてめること
を特徴とする特許請求の範囲第1項、第2項または第3
項記載の拡散板。
[Claims] 1. Silicon oxide with an average particle size of 1 to 10μ, and an average particle size of 1
A diffusion plate characterized in that 5 to 40 p of muscovite is added in an opening that does not cause see-through. 2 Silicon oxide and muscovite are uniformly added to the base material
The diffuser plate according to claim 1, characterized in that: & The diffusion plate according to claim 1, wherein a coating layer containing silicon oxide and muscovite is formed. 4. Claims 1, 2, or 3, characterized in that a lenticular lens, a Fresnel lens, or at least 1''' of fine irregularities are provided.
Diffusion plate as described in section.
JP15442483A 1983-08-24 1983-08-24 Diffusion plate Pending JPS6046503A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP15442483A JPS6046503A (en) 1983-08-24 1983-08-24 Diffusion plate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP15442483A JPS6046503A (en) 1983-08-24 1983-08-24 Diffusion plate

Publications (1)

Publication Number Publication Date
JPS6046503A true JPS6046503A (en) 1985-03-13

Family

ID=15583862

Family Applications (1)

Application Number Title Priority Date Filing Date
JP15442483A Pending JPS6046503A (en) 1983-08-24 1983-08-24 Diffusion plate

Country Status (1)

Country Link
JP (1) JPS6046503A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6556347B1 (en) 1998-12-18 2003-04-29 Mitsubisi Rayon Co., Ltd. Rear projection screen
JP2007242546A (en) * 2006-03-10 2007-09-20 Sony Corp Lighting device and video display device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6556347B1 (en) 1998-12-18 2003-04-29 Mitsubisi Rayon Co., Ltd. Rear projection screen
US6760155B2 (en) 1998-12-18 2004-07-06 Mitsubishi Rayon Co., Ltd Rear projection screen
JP2007242546A (en) * 2006-03-10 2007-09-20 Sony Corp Lighting device and video display device

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