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JPS60141887A - Manufacture of electroformed precision parts - Google Patents

Manufacture of electroformed precision parts

Info

Publication number
JPS60141887A
JPS60141887A JP25119783A JP25119783A JPS60141887A JP S60141887 A JPS60141887 A JP S60141887A JP 25119783 A JP25119783 A JP 25119783A JP 25119783 A JP25119783 A JP 25119783A JP S60141887 A JPS60141887 A JP S60141887A
Authority
JP
Japan
Prior art keywords
electroformed
resist pattern
electroforming
resist
photoresist
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP25119783A
Other languages
Japanese (ja)
Inventor
Kaname Miyazawa
宮沢 要
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Seiko Epson Corp
Suwa Seikosha KK
Original Assignee
Seiko Epson Corp
Suwa Seikosha KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Seiko Epson Corp, Suwa Seikosha KK filed Critical Seiko Epson Corp
Priority to JP25119783A priority Critical patent/JPS60141887A/en
Publication of JPS60141887A publication Critical patent/JPS60141887A/en
Pending legal-status Critical Current

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  • Moulds For Moulding Plastics Or The Like (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 〔技術分野〕 本発明は精密電鋳部品の製造方法に関するものであり、
メッキ用フォトレジストをくり返し用いることを特徴と
するものである。
[Detailed Description of the Invention] [Technical Field] The present invention relates to a method for manufacturing precision electroformed parts,
This method is characterized by repeated use of plating photoresist.

〔従来技術〕[Prior art]

最近20μ〜500μ厚の金属板に厚みより小さなパタ
ーン巾を有する部品(メタルエンコーダースリット板、
細胞融合用メツシュ、シャドウマスク、ファインパター
ンコイル等々)が望まれており、しかもその平面の寸法
精度はもとより、断面形状(なるべくストレートに)ま
でが問題となってきている。もとよりこのような薄膜パ
タニングはエツチングフォトレジストを用いたケミカル
エツチングで製造されるのが普通であるが、金属板のよ
うな等方性材料のエツチングでは、アンダーエッチの問
題がありこのような要望に答えられなくなっている。一
方フオドレジストでメッキレシストを形成しておいて電
鋳をすることはよく知られたことであるが、メッキ(電
鋳)レジストのような耐薬品性と、高解像度をもったフ
ォトレジストは現在までのところ得ることができない。
Recently, parts (metal encoder slit plate, metal encoder slit plate,
Meshes for cell fusion, shadow masks, fine pattern coils, etc.) are desired, and not only the dimensional accuracy of the plane but also the cross-sectional shape (as straight as possible) has become a problem. Of course, such thin film patterning is normally produced by chemical etching using an etching photoresist, but when etching isotropic materials such as metal plates, there is a problem of underetching, which makes it difficult to meet such demands. I can't answer it anymore. On the other hand, it is well known that a plating resist is formed using a photoresist and then electroformed. But I can't get it.

現像後の7オトレジスト断面形状ガストレードであるこ
とを考えるとアスペクト比の限界は1:1であり、せい
ぜい30〜50μ厚で30〜50μのパターン巾が限界
である。これでは例えば50〜200μ厚で50〜50
μのパターン巾のようなアスペクト比が1:1以上とな
ると、フォトレジストをメツキレシストとして使えども
電鋳できない。そこで通常はフォトレジストを20〜5
0μ塗布し、マスターマスクを用いて露光、現像し、こ
の工程を2回以上くり返して高アスペクト比のレジスト
パターンを形成する方法がとられているが、2層目以上
のパターンを完全に重ね合わせて露光、現像することは
アライメント技術上非常に問題がある。特に大面積にな
るとアライナ−は手に入れることはできない。そこで本
発明は自らの第1電鋳パターンを用いてマスクとしフォ
トレジストを露光、現像することにより高アスペクト比
テストレート断面形状をもった電鋳部品ができることを
発見し本発明を生むに至った。
Considering that the cross-sectional shape of the 7-otoresist after development is gas traded, the limit of the aspect ratio is 1:1, and the limit is a thickness of 30 to 50 μm and a pattern width of 30 to 50 μm at most. For example, with a thickness of 50 to 200μ, 50 to 50
When the aspect ratio, such as the pattern width of μ, is 1:1 or more, electroforming cannot be performed even though photoresist can be used as a metal resist. Therefore, usually 20 to 5
The method used is to apply 0μ, expose and develop using a master mask, and repeat this process two or more times to form a resist pattern with a high aspect ratio. Exposure and development are extremely problematic in terms of alignment technology. Especially for large areas, aligners are not available. Therefore, the inventor of the present invention discovered that by exposing and developing a photoresist using his first electroformed pattern as a mask, an electroformed part having a cross-sectional shape with a high aspect ratio test rate could be produced, which led to the creation of the present invention. .

〔目 的〕〔the purpose〕

しかるに本発明の目的は高アスペクト比(1:1以上)
で、しかもストレートな断面形状を有する電鋳部品を安
価に得ることを目的とする。
However, the purpose of the present invention is to achieve a high aspect ratio (1:1 or more).
The object of the present invention is to obtain an electroformed part having a straight cross-sectional shape at a low cost.

〔概 要〕〔overview〕

本発明を第1図を用いて説明する。(A)〜(I()は
本発明のプロセス図である。1は透明基板であり、ガラ
ス、セラミック、プラスチックフィルム(ポリエステル
、ポリカーボネート、ポリエーテルサルフオン、ポリサ
ル7オン、ポリエーテルイミド等)、2はバターニング
されたフォトレジストであり、メツキレシストとなる。
The present invention will be explained using FIG. (A) to (I() are process diagrams of the present invention. 1 is a transparent substrate, made of glass, ceramic, plastic film (polyester, polycarbonate, polyethersulfon, polysulfon, polyetherimide, etc.), 2 is a patterned photoresist, which becomes a metskire resist.

(a)図までは通常のフォトリソグラフィーにより得ら
れる。2はレジスト、解像度にもよるが5μ〜60μで
あり、薄い程、レジスト断面はストレートとなる。この
(A))の工程ではα:bは1:1程度(平行光線を用
い、高解像度レジストを用いても)が最高である。
The images up to (a) are obtained by normal photolithography. 2 is a resist, which has a thickness of 5 μ to 60 μ depending on the resolution, and the thinner the resist, the straighter the cross section of the resist. In this step (A)), the maximum value of α:b is about 1:1 (even if parallel light is used and a high-resolution resist is used).

a/b>1を得ることはむずかしい。(B)は2をレジ
ストとして金属6を電鋳した図であり、6の厚みは2の
厚みbと概同−又は多少薄めに電鋳するのが良い。bよ
り厚くなると断面のストレート性は損なわれキノコ型と
なってくる。乙の金属としては電解又は無電解メッキで
きる金属又は合金であれば何でもかまわないが、よ(N
i、Cu、(3゜等が用いられる。1は透明絶縁体であ
るので少なくとも最初のメッキは無電解メッキでなくて
はならないことは言うまでもない。(0)は(B)の状
態にフォトレジスト4を塗布した工程図である。(D)
は本発明の特徴とする露光工程であり、3をフォトマス
クとして4を1の裏側から露光する。この工程により、
マスクとパターン3の位置的な問題を全く考える必要は
ない0この工程からいっても4に用いるフォトレジスト
はネガ型でなくてはならないことは言うまでもない04
の厚みは前記2と全く同様に考えることができる。(紳
は現像したところであり、(1’)は4をメツキレシス
トとして3の上に5を重ねて電鋳したところの図である
。この方方法により1 > a/b > 1/2で得ら
れることは明らかである。もっと大きな比がほしければ
(0)〜(F)の工程を何回もくり返せば良い0電鋳部
品の使い方によってはレジスト4を永久レジストとして
残しても良いが、通常はハタ離しくG)のようにし、さ
らに基板1からハタ離して電鋳部品(H)を得る。
It is difficult to obtain a/b>1. (B) is a diagram in which a metal 6 is electroformed using 2 as a resist, and it is preferable that the thickness of 6 be electroformed to be approximately the same as the thickness b of 2 or a little thinner. If it becomes thicker than b, the straightness of the cross section will be lost and it will become mushroom-shaped. The metal of Party B may be any metal or alloy that can be plated electrolytically or electrolessly, but
i, Cu, (3°, etc.) are used.Since 1 is a transparent insulator, it goes without saying that at least the first plating must be electroless plating.(0) is a photoresist in the state of (B). It is a process diagram of coating No. 4. (D)
1 is an exposure step that is a feature of the present invention, in which 4 is exposed from the back side of 1 using 3 as a photomask. Through this process,
There is no need to consider the problem of the position of the mask and pattern 3 at all.0 It goes without saying that the photoresist used in step 4 must be negative type even in this process04
The thickness can be considered in exactly the same way as in 2 above. (Figure 1 shows the developed image, and (1') shows the result of electroforming by layering 5 on 3 using 4 as a metskiresist. With this method, 1 > a/b > 1/2 can be obtained. is obvious.If you want a larger ratio, you can repeat steps (0) to (F) many times.Depending on how you use the electroformed parts, you can leave resist 4 as a permanent resist, but usually Separate the parts as shown in G) and further separate them from the substrate 1 to obtain an electroformed part (H).

以上が本発明の概要であるが次に実施例により本発明を
より詳細に説明する。
The above is an overview of the present invention. Next, the present invention will be explained in more detail with reference to Examples.

実施例1 第1図でソーダガラス1上に5n−Pdの触媒処理を施
した後、カーテンコート法でネガ型フォトレジストであ
る日本ソーダ物製タイタロンR9−400を30μコー
トした。次にマスターマスクを用い、露光、現像しくA
)図を得た。α=30μ、b=30μである。次にこの
ようなフォトレジストであるメツキレシスト2を用いて
(B)図のように25〜30μ厚にN1−Pメッキ(3
)を施した。次に同様の方法でネガ型フォトレジスト4
をカーテンコート法で40μコートした(a図)。
Example 1 As shown in FIG. 1, soda glass 1 was subjected to 5n-Pd catalyst treatment, and then coated with 30 μm of Titanon R9-400, a negative type photoresist made by Nippon Soda Mono, by curtain coating. Next, using a master mask, expose and develop the A
) got the figure. α=30μ, b=30μ. Next, using Metsukiresist 2, which is such a photoresist, N1-P plating (3
) was applied. Next, apply negative photoresist 4 in the same manner.
was coated with a thickness of 40μ using the curtain coating method (Figure a).

次に第1次電鋳面3を露光用マスクの様にして使い、(
功!・)図のように基板1の裏側から露光し、現像しく
E)図を得た。次に5なるN1−Pを40μ電鋳した。
Next, use the primary electroformed surface 3 like a mask for exposure, (
Good luck!・) As shown in the figure, the substrate 1 was exposed to light from the back side and developed to obtain the figure E). Next, 40μ of N1-P No. 5 was electroformed.

次にレジストをハク離して(G)図を得た0次に基板か
ら金属部(6及び5)をハク離した。アスペクト比は!
10μニア0μでろニアであった。
Next, the resist was peeled off to obtain Figure (G).The metal parts (6 and 5) were then peeled off from the substrate. The aspect ratio!
It was 10μ near and 0μ near.

又ろ、5の断面は全くストレートであった。従来このよ
うなストレート断面をもちアスペクト比が5ニアに達す
るような部品は製造不可能であった。
Also, the cross section of No. 5 was completely straight. Conventionally, it has been impossible to manufacture parts with such a straight cross section and an aspect ratio of 5 near.

この部品は細胞融合用メツシュとして非常に有用であっ
た。又N i、 −PをCuに変えることにより、非常
に線専積率の良いフラットパターンコイルが得られた。
This part was very useful as a mesh for cell fusion. Moreover, by changing Ni, -P to Cu, a flat pattern coil with a very good line area ratio was obtained.

この場合レジスト(2及び4)は永久レジストとして絶
縁部を成すためにレジスト共々基板1からハク離するこ
とが必要となる。又この工程を3回以上くり返すことに
より30μ:110μ、30μ:150μ等の高アスペ
クト比の電鋳部品が簡単に得られることがわかった。こ
のような基板裏側からの露光方法を用いないと3と5は
完全には重なることがなくストレートな断面は得ること
ができなかった。
In this case, the resists (2 and 4) must be peeled off from the substrate 1 in order to form an insulating part as a permanent resist. It has also been found that by repeating this process three or more times, electroformed parts with high aspect ratios such as 30μ:110μ and 30μ:150μ can be easily obtained. If such an exposure method from the back side of the substrate was not used, 3 and 5 would not overlap completely and a straight cross section could not be obtained.

本発明は、装飾品、機能部品に広く適用される。The present invention is widely applicable to decorative items and functional parts.

【図面の簡単な説明】[Brief explanation of drawings]

第1図ANH・・・・・・本発明のプロセス図以 上 出願人 株式会社諏訪精工舎 始 < 0 0 凸 W 声 [相] で Figure 1 ANH...Process diagram of the present invention and above Applicant: Suwa Seikosha Co., Ltd. beginning < 0 0 convex W voice [phase]

Claims (1)

【特許請求の範囲】 電鋳部品の製造方法において、 1) 透明基板の片面に7オトレジストによりメツキレ
シストパターンを形成する工程2) 頷レジストパター
ン以外に概メツキレシストの高さと同等まで第1電鋳を
行なう工程3) 第1電鋳終了後、該第1電鋳面にネガ
型の7オトレジストを塗布する工程 4) 該1tトレジストを、第1電鋳バター ?/をマ
スクとして、透明基板の裏側から露光、現像し第2メツ
キレシストパターンを形成する工程 5) 第2メツキレシストパターン以外のS分に第2電
鋳を行なう工程 以上1)〜5)を順次含むことを特徴とする精密電鋳部
品の製造方法0
[Claims] In a method for manufacturing an electroformed part, 1) a step of forming a mesh resist pattern on one side of a transparent substrate using a 7-hole resist; 2) a step of forming a first electroforming resist pattern to approximately the same height as the mesh resist pattern in addition to the nodding resist pattern; Step 3) After the first electroforming is completed, a step of applying a negative type 7 tresist on the first electroformed surface 4) Applying the 1t tresist to the first electroforming butter? Step 5) of forming a second plating resist pattern by exposing and developing from the back side of the transparent substrate using / as a mask Steps 1) to 5) of performing second electroforming on the S portion other than the second plating resist pattern Precision electroformed parts manufacturing method 0 characterized by sequentially including
JP25119783A 1983-12-28 1983-12-28 Manufacture of electroformed precision parts Pending JPS60141887A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP25119783A JPS60141887A (en) 1983-12-28 1983-12-28 Manufacture of electroformed precision parts

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP25119783A JPS60141887A (en) 1983-12-28 1983-12-28 Manufacture of electroformed precision parts

Publications (1)

Publication Number Publication Date
JPS60141887A true JPS60141887A (en) 1985-07-26

Family

ID=17219123

Family Applications (1)

Application Number Title Priority Date Filing Date
JP25119783A Pending JPS60141887A (en) 1983-12-28 1983-12-28 Manufacture of electroformed precision parts

Country Status (1)

Country Link
JP (1) JPS60141887A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62254103A (en) * 1986-04-26 1987-11-05 Kyodo Printing Co Ltd Color filter
WO2002081781A1 (en) * 2001-03-30 2002-10-17 Worlock Co., Ltd. Electrocast article and method for producing the same, electrocast sheet and electrocast product
JP2006016654A (en) * 2004-06-30 2006-01-19 Kuraray Co Ltd Manufacturing method of penetrating metal structure
US7025865B2 (en) * 2000-09-26 2006-04-11 Eastman Kodak Company Method for producing metal mask and metal mask
WO2006064741A1 (en) * 2004-12-13 2006-06-22 Mitsui Mining & Smelting Co., Ltd. Holed electrolytic metallic foil, holed electrolytic metallic foil with carrier base material, and method of manufacturing the same

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62254103A (en) * 1986-04-26 1987-11-05 Kyodo Printing Co Ltd Color filter
US7025865B2 (en) * 2000-09-26 2006-04-11 Eastman Kodak Company Method for producing metal mask and metal mask
WO2002081781A1 (en) * 2001-03-30 2002-10-17 Worlock Co., Ltd. Electrocast article and method for producing the same, electrocast sheet and electrocast product
JP2006016654A (en) * 2004-06-30 2006-01-19 Kuraray Co Ltd Manufacturing method of penetrating metal structure
WO2006064741A1 (en) * 2004-12-13 2006-06-22 Mitsui Mining & Smelting Co., Ltd. Holed electrolytic metallic foil, holed electrolytic metallic foil with carrier base material, and method of manufacturing the same
JP2006193825A (en) * 2004-12-13 2006-07-27 Mitsui Mining & Smelting Co Ltd Perforated electrolytic metal foil, perforated electrolytic metal foil with carrier substrate and their production methods

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