JPS5974506A - Glass fiber for optical transmission and its manufacturing method - Google Patents
Glass fiber for optical transmission and its manufacturing methodInfo
- Publication number
- JPS5974506A JPS5974506A JP57184596A JP18459682A JPS5974506A JP S5974506 A JPS5974506 A JP S5974506A JP 57184596 A JP57184596 A JP 57184596A JP 18459682 A JP18459682 A JP 18459682A JP S5974506 A JPS5974506 A JP S5974506A
- Authority
- JP
- Japan
- Prior art keywords
- glass fiber
- organopolysiloxane
- optical transmission
- manufacturing
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003365 glass fiber Substances 0.000 title claims abstract description 12
- 230000005540 biological transmission Effects 0.000 title claims description 5
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 230000003287 optical effect Effects 0.000 title claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 23
- 239000011248 coating agent Substances 0.000 claims abstract description 11
- 238000000576 coating method Methods 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims description 15
- 239000011247 coating layer Substances 0.000 claims description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract description 3
- 125000005375 organosiloxane group Chemical group 0.000 abstract 2
- 229920002050 silicone resin Polymers 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 9
- 239000011521 glass Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 239000013307 optical fiber Substances 0.000 description 4
- 238000001723 curing Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006757 chemical reactions by type Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 150000003058 platinum compounds Chemical class 0.000 description 1
- -1 polysiloxane Polymers 0.000 description 1
- 210000001747 pupil Anatomy 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920002631 room-temperature vulcanizate silicone Polymers 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/104—Coating to obtain optical fibres
- C03C25/1065—Multiple coatings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Coupling Of Light Guides (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
Abstract
Description
【発明の詳細な説明】
（イ）技術分野
本発明は接続作業性の良い光伝送用ガラスファイバ（以
下光ファイバと称す）およびその製造方法に門するもの
である。DETAILED DESCRIPTION OF THE INVENTION (a) Technical Field The present invention relates to a glass fiber for optical transmission (hereinafter referred to as an optical fiber) with good connection workability and a method for manufacturing the same.
光ファイバの接続法としては、ファイバの被層をすべて
除去し、放電融着する方法が一般的に用いられており、
被覆の除去しやすさく以下皮むき性と称す）は、接続時
の作業性、接続部の機緘強度に大きな影響を与える。す
なわち、被覆の除去が完全でない場合、放電により、燃
焼炭化した被覆材がガラス表面に付貯し、ガラスファイ
バの強度低下の原因である表面欠陥となる。又、接続作
業の単純化のためには、被覆を除去した後、溶剤で洗浄
したり、ガーゼ等でふきとるという作業を省略する必要
がある。The commonly used method for connecting optical fibers is to remove all the fiber coating and perform discharge fusion.
The ease with which the coating can be removed (hereinafter referred to as peelability) has a great effect on the workability during connection and the mechanical strength of the joint. That is, if the coating is not completely removed, the burnt and carbonized coating material accumulates on the glass surface due to the discharge, resulting in surface defects that cause a decrease in the strength of the glass fiber. Furthermore, in order to simplify the connection work, it is necessary to omit the work of cleaning with a solvent or wiping with gauze after removing the coating.
現在、光フアイバ最内層のｖ１２覆利として最も多く用
いられている硬化性オルガノポリシロキサン組成物、特
にフェニルポリシロキサン組成物はガラスに対するぬれ
性が良く、その上、空気中の水分等の作用でガラス表面
との間でシラノール基による水素結合音生じるためガラ
ス表面とのかなり強固な結合力含有している。従って、
ノーニック等の皮むき治具によって最外層のナイロン金
除去する際に最内層のオルガノポリシロキサン組成物層
を同時に完全に除去することはむずかしく、アルコール
を含ませたガーゼ等で再度ガラス表面を拭う必要がある
。この時にガラス表面に傷をつける結果となり、接続部
強度をＹ均５００〜７００ｆ （１２５μｍ 外径ファ
イノ（）まで低下させてしまう−９
（ロ）発明のｖｉ示
本発明はこれらの点に錨みなされ九ものであり、ガラス
ファイバとの剥離性（皮むき性）の良い被覆構造および
その製造方法を提供するものである０
すなわち本発明は線引されたガラスファイバの上に硬化
性オルガノポリシロキサン組成物ｔ−塗布し、その後、
硬化させてなる光伝送用ガラスファイバにおいて、該硬
化性オルガノポリシロキサン組成物に２０重ｉ％以下の
非反応性オルガノポリシロキサンケ添加したことを特徴
とする、光伝送用ガラスファイバくおよびその製造方法
に関するものである０本発明て用いられる硬化性オルガ
ノポリシロキサン組成物（シリコン樹脂）はいわゆる付
カロ反応型のＲＴＶシリコンゴムであり、主に、（６）
一般式
％式％
で表わされる末端ビニルで封鎖されたオルガノポリシロ
キサン（ここでＲは脂肪族不飽和結合を有しない（非）
置換の一価炭化水素基、例えばメチル基などの飽和アル
キル基やフェニル基などのアリール基である）、
（ロ） １分子中にけい素原子に直結した水素原子を６
ケ以上有するオルガツノ・イドロジエンポリシロキサン
、
（ハ）触媒量の白金化合物、
からなり、硬化後、０）成分が（ロ）成分により２次元
および５次元に架橋した形状となる。Currently, curable organopolysiloxane compositions, particularly phenylpolysiloxane compositions, which are most commonly used as V12 cover for the innermost layer of optical fibers, have good wettability to glass, and are also resistant to the effects of moisture in the air. It has a fairly strong bonding force with the glass surface because hydrogen bonding occurs due to silanol groups between it and the glass surface. Therefore,
When removing the outermost nylon gold layer using a peeling jig such as Nornick, it is difficult to completely remove the innermost organopolysiloxane composition layer at the same time, and it is necessary to wipe the glass surface again with gauze soaked in alcohol. There is. At this time, the glass surface is damaged, and the strength of the connection portion is reduced to Y average 500 to 700 f (125 μm outer diameter phino()). The purpose of the present invention is to provide a coating structure with good peelability (peelability) from glass fibers and a method for manufacturing the same. Composition t-apply, then
A cured glass fiber for light transmission, characterized in that a non-reactive organopolysiloxane of 20% by weight or less is added to the curable organopolysiloxane composition, and its production. The curable organopolysiloxane composition (silicon resin) used in the present invention is a so-called Calo reaction type RTV silicone rubber, and mainly contains (6)
An organopolysiloxane capped with vinyl terminals represented by the general formula % (where R has no aliphatic unsaturated bond)
Substituted monovalent hydrocarbon groups, such as saturated alkyl groups such as methyl groups and aryl groups such as phenyl groups), (b) 6 hydrogen atoms directly bonded to a silicon atom in one molecule.
(c) a catalytic amount of a platinum compound; after curing, component (0) becomes two-dimensionally and five-dimensionally crosslinked by component (b).
また本発明で儒加する非反応性ポリシロキサンは上記硬
化性オルガノポリシロキサン（イ）成分の末端ビニル部
分がメチル基、エチル基などの飽和アルキル基で置き換
えられて末端′ｆＩ：封鎖され九低分子量のものである
。In addition, in the non-reactive polysiloxane to be added in the present invention, the terminal vinyl moiety of the curable organopolysiloxane component (a) is replaced with a saturated alkyl group such as a methyl group or an ethyl group, and the terminal 'fI: is blocked. It is of molecular weight.
本発明の一次被覆層の厚さは特に制限はないが、内部の
ガラスの保瞳の点から２０μｍ以上が望ましく、上限は
２００μｍ程度が適当である。また硬化法も特に制限は
なく、熱、紫外線、電子線のいずれでもよい。The thickness of the primary coating layer of the present invention is not particularly limited, but from the viewpoint of pupil retention of the internal glass, it is preferably 20 μm or more, and the upper limit is preferably about 200 μm. Further, there is no particular restriction on the curing method, and any of heat, ultraviolet rays, and electron beams may be used.
上記非反応性オルガノポリシロキサンを添加することに
より、硬化性オルガノポリシロキサン組成物が硬化した
後、ガラスファイバと硬化したオルガノポリシロキサン
組成物層の界面に、非反応性のオルガノポリシロキサン
かにじみ出して膜が形成されることによって、該オルガ
ノポリシロキサン組成物層の皮むき性が著しく改善され
、最外層のナイロンをノーニックで除去する際に同時に
完全に取力除ぐことがてきる０このようなにじみ出しの
効果全発揮させるためには、非反応性オルガノポリシロ
キサン組成物の平均分子量は１０４ 以下、粘度にして
４００ａｐＯ以下であることが望ましい。添加する非反
応性オルガノポリシロキサンのｉ ｉｊ： 、少なくと
も２０Ｏｐｐｍが必要で、にじみ出しの効果を発揮さぜ
る目的からは多い方が良いが、２０重量−以上でｔよ硬
化後のオルガノポリシロキサン組成物のｑ性を阻害する
。具体的には、機械的強度が小さく、ガラス表面の保護
という本来の目的をはだすこ七ができない。By adding the above non-reactive organopolysiloxane, after the curable organopolysiloxane composition is cured, the non-reactive organopolysiloxane oozes out at the interface between the glass fiber and the cured organopolysiloxane composition layer. By forming a film, the peelability of the organopolysiloxane composition layer is significantly improved, and when the outermost layer of nylon is removed without nicking, the removal force can be completely removed at the same time. In order to fully exhibit the oozing effect, it is desirable that the non-reactive organopolysiloxane composition has an average molecular weight of 104 or less and a viscosity of 400 apO or less. The amount of non-reactive organopolysiloxane to be added is required to be at least 20 Oppm, and for the purpose of exhibiting the oozing effect, more is better, but if it is 20% by weight or more, the organopolysiloxane after curing is Inhibits the q nature of the composition. Specifically, it has low mechanical strength and cannot fulfill its original purpose of protecting the glass surface.
本発明の効果が元ファイバの上に硬化性オルガノボリシ
ロキツン組成物ＱＩ￥ｊ層被覆したものにとどまらず、
硬化性オルガノボリシロキザン衛棲数層、あるいＶよ熱
可塑性樹脂層管′ｆＩ：更に被覆した光ファイバにおい
て発現されることは言うまでもない。The effects of the present invention are not limited to coating the original fiber with a layer of the curable organoborisiloxane composition QI\j;
It goes without saying that the effect is expressed in the optical fiber coated with a curable organoborisiloxane trilayer layer or a thermoplastic resin layer tube 'fI.
代理人 内 １） 明 代理人 萩 原 亮 −Agent: 1) Akira Agent Ryo Hagi Hara -
Claims (2)
反応性オルガリボリシロキサン金含有する硬化性オルガ
ノポリシロキチン組成物からなる一次被覆層を有する光
伝送用ガラスファイバ０(1) Glass fiber for optical transmission having a primary coating layer on the glass fiber made of a curable organopolysiloxane composition containing 20% by weight or less of non-reactive orgalibolysiloxane gold.
下の非反応性オルガノポリシロキサンを添加した硬化性
オルガノポリシロキサン組成物を塗布し、その後、硬化
させることからなる、２０重量−以下の非反応性オルガ
ノボリシ四キサンを含有する硬化性オルガノポリシロキ
サン組成物からなる一次被覆層金有する、光伝送用ガラ
スファイバの製造方法。(2) coating a drawn glass fiber with a curable organopolysiloxane composition containing not more than 20% by weight of a non-reactive organopolysiloxane and then curing it; A method for producing a glass fiber for optical transmission, the primary coating layer comprising a curable organopolysiloxane composition containing a non-reactive organopolysiloxane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57184596A JPS5974506A (en) | 1982-10-22 | 1982-10-22 | Glass fiber for optical transmission and its manufacturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57184596A JPS5974506A (en) | 1982-10-22 | 1982-10-22 | Glass fiber for optical transmission and its manufacturing method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5974506A true JPS5974506A (en) | 1984-04-27 |
Family
ID=16155972
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57184596A Pending JPS5974506A (en) | 1982-10-22 | 1982-10-22 | Glass fiber for optical transmission and its manufacturing method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5974506A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62180312A (en) * | 1986-02-04 | 1987-08-07 | Sumitomo Electric Ind Ltd | Fiber for optical transmission |
| WO1998021157A1 (en) * | 1996-11-08 | 1998-05-22 | Dsm N.V. | Radiation-curable optical glass fiber coating compositions, coated optical glass fibers, and optical glass fiber assemblies |
| WO1999059930A1 (en) * | 1998-05-21 | 1999-11-25 | Dsm N.V. | Radiation-curable, optical fiber coating system |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5747761U (en) * | 1980-08-31 | 1982-03-17 |
-
1982
- 1982-10-22 JP JP57184596A patent/JPS5974506A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5747761U (en) * | 1980-08-31 | 1982-03-17 |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62180312A (en) * | 1986-02-04 | 1987-08-07 | Sumitomo Electric Ind Ltd | Fiber for optical transmission |
| WO1998021157A1 (en) * | 1996-11-08 | 1998-05-22 | Dsm N.V. | Radiation-curable optical glass fiber coating compositions, coated optical glass fibers, and optical glass fiber assemblies |
| US6298189B1 (en) | 1996-11-08 | 2001-10-02 | Dsm N.V. | Radiation-curable optical glass fiber coating compositions, coated optical glass fibers, and optical glass fiber assemblies |
| US6339666B2 (en) | 1996-11-08 | 2002-01-15 | Dsm N.V. | Radiation-curable optical glass fiber coating compositions, coated optical glass fibers, and optical glass fiber assemblies |
| US6661959B2 (en) | 1996-11-08 | 2003-12-09 | Dsm N.V. | Radiation-curable optical glass fiber coating compositions, coated optical glass fibers, and optical glass fiber assemblies |
| EP1726574A1 (en) * | 1996-11-08 | 2006-11-29 | DSMIP Assets B.V. | Radiation-curable optical glass fiber coating compositions,coated optical glass fibers, and optical glass fiber assemblies |
| WO1999059930A1 (en) * | 1998-05-21 | 1999-11-25 | Dsm N.V. | Radiation-curable, optical fiber coating system |
| US6110593A (en) * | 1998-05-21 | 2000-08-29 | Dsm N.V. | Radiation-curable optical fiber primary coating system |
| US6169126B1 (en) | 1998-05-21 | 2001-01-02 | Dsm N.V. | Radiation-curable optical fiber primary coating system |
| US6534557B2 (en) | 1998-05-21 | 2003-03-18 | Dsm N.V. | Radiation-curable, optical fiber primary coating system |
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