JPS5915569A - Durable hydrophilic anti-stain processing of polyester fiber product - Google Patents
Durable hydrophilic anti-stain processing of polyester fiber productInfo
- Publication number
- JPS5915569A JPS5915569A JP12179782A JP12179782A JPS5915569A JP S5915569 A JPS5915569 A JP S5915569A JP 12179782 A JP12179782 A JP 12179782A JP 12179782 A JP12179782 A JP 12179782A JP S5915569 A JPS5915569 A JP S5915569A
- Authority
- JP
- Japan
- Prior art keywords
- low
- temperature plasma
- polyester fiber
- gas
- torr
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000835 fiber Substances 0.000 title claims description 18
- 229920000728 polyester Polymers 0.000 title claims description 15
- 238000000034 method Methods 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 230000003373 anti-fouling effect Effects 0.000 claims description 8
- 239000004753 textile Substances 0.000 claims description 6
- 238000009832 plasma treatment Methods 0.000 claims description 5
- 239000007789 gas Substances 0.000 description 17
- 238000005406 washing Methods 0.000 description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- -1 polyethylene terephthalate Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
本発明は低温プラズマを利用してポリエステ〃系繊紺製
品の改質をする方法に関するものであり。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for modifying polyester textile products using low temperature plasma.
耐久性のある親水、防汚性能をもつポリエステル系繊維
品を提供することを目的とするものである。The purpose of this invention is to provide a polyester fiber product with durable hydrophilic and antifouling properties.
従来からポリエステル系繊維品は寸法安定性。Polyester fiber products have traditionally been dimensionally stable.
強力、ウォッシュ アンド ウェアー性などの優れた特
性をもつ反面疎水性であるための欠点、すなわち吸汗性
がない、油性汚れがつきやすく脱落し難い、洗濯中に汚
れが再付着しゃずいなどの問題があった。このような問
題を改良するため各種の方法が提案されており例えば親
水性高分子化合物や帯電防止剤をＩＪ＆維表面表面着さ
せる方法、親水性グループを有する重合可能な単量体を
繊維表面にグラフト重合する方法などがある。しかしこ
のような方法では繰り返し洗ｍにより性能が低下してし
まうのが普通であり、風合いの粗硬化、染色堅牢度の低
下などの問題もあって満足できる改良法には到達してい
ないのが晩秋である。さらに最近では高分子物質の表面
改質に低温プラズマを利用する方法が提案され、ポリニ
スブール系ｍ維製品についても酸累な含む気体の低温プ
ラズマによる処理により親水性を与える方法が報告（”
Ｐｏｌｙｍｅｒ”１９７８年８月号ｐ、９０４−９１
２ 、 ”ＡσｒＡ Ｐｏ１ｙ＋ｎａｒ１ｃａ“１９７
９年８月号ｐ、４７０〜４７７など）されている。この
方法は低温プラズマ処理によりボリエスデ／Ｌ’系繊維
表面に親水基を導入し、親水性、防汚性を得るものであ
る。本発明者らはこの新しい提案について詳細な追試を
行った結果、低温プラズマ処理によりポリエステル系繊
維に親水性、防汚性を付与することは確認できたが問題
は経口により性能が低下すること、繰返し洗濯により性
能が急激に低下することであり、従来の方法によるもの
と同様の問題があることが分った・
そこで本発明者らはこのような入点を解決するために鋭
意検討の結果、水蒸気を含む気体の低温プラズマで処理
することにより親水性、防汚性の耐久性が大ｒｊ＋に向
上するという事実を范出し本発明に到達した。Although it has excellent characteristics such as being strong and washable and wearable, it has disadvantages due to its hydrophobic nature, such as lack of sweat absorption, easy attachment of oily stains, difficult to remove, and problems such as stains re-attaching during washing. there were. Various methods have been proposed to improve this problem, including methods of attaching hydrophilic polymer compounds or antistatic agents to the IJ and fiber surfaces, and methods of attaching polymerizable monomers having hydrophilic groups to the fiber surfaces. There are methods such as graft polymerization. However, with these methods, the performance usually deteriorates due to repeated washing, and there are also problems such as rough hardening of the texture and a decrease in color fastness, so a satisfactory improvement method has not been achieved. It is late autumn. Furthermore, recently, a method has been proposed that uses low-temperature plasma to modify the surface of polymeric materials, and a method has been reported for imparting hydrophilic properties to polynisbourg-based fiber products by treating them with low-temperature plasma containing acid-containing gas ("
Polymer” August 1978 issue p. 904-91
2, “AσrA Po1y+nar1ca”197
(August 9th issue, p. 470-477, etc.) In this method, hydrophilic groups are introduced onto the surface of Boriesde/L' fibers by low-temperature plasma treatment to obtain hydrophilicity and antifouling properties. The inventors conducted detailed follow-up tests on this new proposal and were able to confirm that low-temperature plasma treatment imparts hydrophilicity and antifouling properties to polyester fibers, but the problem is that the performance deteriorates when administered orally. It was found that the performance deteriorates rapidly with repeated washing, and there is a problem similar to that with conventional methods.The inventors of the present invention have conducted extensive studies to solve this problem. The present invention was developed based on the fact that the durability of hydrophilicity and antifouling properties is greatly improved by treatment with low-temperature plasma of a gas containing water vapor.
すなわち本発明は、０．１〜２．０Ｔｏｒｒの圧力下の
気体の存在のもとてグロー放電により発生せしめた低温
プラズマでポリエステル系繊維製品を処理するに際し、
該気体の水蒸気分圧を０．０５−１ 、０Ｔｏｒｒに調
節した状態でポリエステル系繊維品を低温プラズマ処理
することを特徴とするポリエステル系繊維品の耐久性親
水、防汚加工方法である。That is, the present invention provides a method for treating polyester fiber products with low-temperature plasma generated by glow discharge in the presence of gas under a pressure of 0.1 to 2.0 Torr.
This is a durable hydrophilic and antifouling processing method for polyester textiles, which is characterized by subjecting the polyester textiles to low-temperature plasma treatment while the water vapor partial pressure of the gas is adjusted to 0.05-1,0 Torr.
以下１本発明の詳細な説明する。本発明でいうポリエス
テル系繊維品とは、ポリエチレンテレフタレート繊維を
主たる対象とするが、テレフタル酸及びエチレングリコ
−ｔｖ ｔｒ−第３成分を含有するポリエステル繊維で
あってもよく、これらの繊維からなる綿、糸、布帛、不
織布などを指す、また本発明でいう低温プラズマとは低
圧下のＡｒ、 Ｎ＋ 。The present invention will be explained in detail below. The polyester fiber products referred to in the present invention mainly refer to polyethylene terephthalate fibers, but may also be polyester fibers containing terephthalic acid and ethylene glyco-TVTR-third component, and cotton made of these fibers. , yarn, fabric, non-woven fabric, etc. Also, the low-temperature plasma referred to in the present invention refers to Ar, N+ under low pressure.
Ｏｌ、 ｃｏ、空気などの気体中でおこるグロー放電に
よって生起される非平衡プラズマのことである。Non-equilibrium plasma is generated by glow discharge that occurs in a gas such as ol, cobalt, or air.
この低温プラズマはデヲズマ重合、プフズマインデュー
スド重合、エツチングなど各種の用途に用いられている
。本発明で使用する気体は上記の気体の低重合系モノマ
ーがス、メタノールなどの有機系ゲス、 Ｈｅなどの不
活性ガスなど特に限定されないがいずれの気体を使用す
る場合においても水蒸気を含有していることが必要不可
欠の条件である。すなわちＯｔや空気など酸化系気体の
低温プラズマでポリエステル系繊維を処理すると繊維表
面に親水基が形成され親水、防汚性が付領さｈるがＡｒ
やＨｅ、隅などの不活性がスや直接親水基を形成しない
気体の場合でもフジカルを形成し、このラジカルが空気
中の酸素と反応して親水基を形成するといわれている。This low-temperature plasma is used for various purposes such as debosma polymerization, pfusma induced polymerization, and etching. The gases used in the present invention include, but are not particularly limited to, the above-mentioned low-polymerized monomers, organic gases such as methanol, and inert gases such as He, but any gases used may contain water vapor. Being present is an essential condition. In other words, when polyester fibers are treated with low-temperature plasma of an oxidizing gas such as Ot or air, hydrophilic groups are formed on the fiber surface, giving it hydrophilicity and antifouling properties.
It is said that even in the case of gases that do not directly form hydrophilic groups, such as inert gases such as helium, helium, etc., radicals are formed, and these radicals react with oxygen in the air to form hydrophilic groups.
。
低温プラズマを発生させる条件のうち気体の圧力は０．
１〜２．０Ｔｏｒｒが好ましい、ＩＯ，Ｉ Ｔｏｒｒ以
下の場合は真空度維持の為の装置の機密性が高精度に要
求されるため、特に布帛等を連続で処理するような場合
装置コストが非常に高くなり不利となる。. Among the conditions for generating low-temperature plasma, the gas pressure is 0.
1 to 2.0 Torr is preferable; if it is less than IO, I Torr, the device must be highly airtight to maintain the degree of vacuum, so the cost of the device is very high, especially when processing fabrics etc. continuously. becomes disadvantageous.
また２、０Ｔｏｒｒ以上の場合は発生した低温プラズマ
が不安定となり処理の均一性に欠けるという問題がある
。またグロー放電を行わしめるｗｌ、気エネルギーとじ
では直流電圧印加、容量型交流電圧印加。Further, if the temperature is 2.0 Torr or more, the generated low-temperature plasma becomes unstable, resulting in a problem that the processing lacks uniformity. In addition, DC voltage is applied to generate glow discharge, and DC voltage is applied during energy binding, and capacitive AC voltage is applied.
誘導型交流電圧印加など種々の方法があるが一般１こは
＋ ＯＫＨｚ −３０００ＭＨｚの高周波を利用するこ
とが多（電波法上の規制から＋Ｌ５６ ＭＨｚを使用す
ることが多い。またこれらの電源よりの電気出力は０．
１〜Ｉ Ｗ／ｄが適当であり、処理時間は１０秒〜２分
が適当であるが、処理すべ＃繊維品の形態等によってｈ
ｔ ｉ［株］条件を設定すべきである。前述の気体Ｆｉ
ｔ独あるいはこれらの混合気体を用いて低温プラズマな
発生させポリエステル系繊維品を処理すると気体により
効果に差はあるが良好な親水性。There are various methods such as induction type AC voltage application, but in general, high frequencies of +OKHz -3000MHz are often used (+L56MHz is often used due to regulations under the Radio Law. Electrical output is 0.
1 to I W/d is appropriate, and the processing time is appropriate to be 10 seconds to 2 minutes, but the processing time may vary depending on the form of the textile product, etc.
t i [stock] conditions should be set. The aforementioned gas Fi
When polyester fibers are treated by generating low-temperature plasma using gas or a mixture of these gases, good hydrophilic properties can be obtained, although the effect varies depending on the gas.
防汚性を付ずすることがで診る。しかしこれらの効果は
いずれも耐久性が小さく繰り返し洗ＩＩｉすることや長
期間放置することにより性能は大１１に低下する。しか
るＦこ本発明の方法すなわち低温プラズマに使用する気
体に水蒸気をその公庫が０．０５〜１．０Ｔｏｒｒとな
るように混合して低温プラズマとして、ポリエステル系
繊維辣品を処理すると親水性、防汚性の耐久性を大巾に
向上させることかできる。このとき水蒸気を含む気体全
体の圧力は既述のように０．１〜２．０Ｔｏｒｒが適当
であるが水蒸気の分圧はそれぞれの圧力により効果に差
はあるものの０６０５〜１．０Ｔｏｒｒの範囲で良好な
耐久性のある性能が得られる。水蒸気分圧が０．０５Ｔ
ｏｒｒ以下の場合は水蒸気併用の効果が少なく１反対に
１． ＯＴｏｒｒ以上の場合は水蒸気の凝縮などにより
圧力変動要因が増え圧力を一定に保持することが困難と
なる。It can be diagnosed by adding stain resistance. However, all of these effects have low durability, and the performance decreases to 11 when repeatedly washed or left for a long period of time. However, when polyester textiles are treated with the method of the present invention, i.e., by mixing water vapor with the gas used for low-temperature plasma at a temperature of 0.05 to 1.0 Torr, it becomes hydrophilic and waterproof. It can greatly improve stain resistance. At this time, the appropriate pressure of the entire gas including water vapor is 0.1 to 2.0 Torr as mentioned above, but the partial pressure of water vapor is within the range of 0.605 to 1.0 Torr, although the effectiveness varies depending on the pressure. Good durable performance is obtained. Water vapor partial pressure is 0.05T
If it is less than orr, the effect of using water vapor in combination is small, and on the other hand, 1. If the pressure exceeds OTorr, pressure fluctuation factors increase due to water vapor condensation, etc., making it difficult to maintain the pressure constant.
この他の低温プラズマ処理条件すなわち高周波周波数、
出力、処理時間等は従来の水蒸気を含土な第２表 低温
ブッズマ処理品の性能
５級 ： 汚れが全く残らない。Other low temperature plasma processing conditions, i.e. high frequency,
Table 2 shows the output, processing time, etc. of conventional water vapor-containing products. Performance of low-temperature Buzzma treated products: Grade 5: No stains remain.
４＃ ： 汚れがほとんど残らない。4#: Almost no dirt remains.
３り ： 汚れがかなり残る。3rd grade: Quite a lot of dirt remains.
２沙 ： 汚れが多量に残る。2nd Sha: A large amount of dirt remains.
１〃 ： 汚れがほとんど落ちない一
前述のごとく処理条件Ａ、Ｃは水蒸気を含まない従来の
低温プラズマ処理条件であり処理条件Ｂ。1. Almost no dirt is removed.As mentioned above, treatment conditions A and C are conventional low-temperature plasma treatment conditions that do not contain water vapor, and treatment condition B is.
Ｄは水蒸気を含む本発明Ｅこよる処理条件の一例である
。このような条件で処理したボリエスデｕ ｔｆ＆物の
性能は第２表でわかるように処理直後には吸水性も防汚
性も各条件とｔ良好な値を示すが家庭洗濯を１０回繰り
返した後同じ項目についで性能を測定すると、晒埋条件
Ａ、Ｃ（比較例）の試料は吸水性、防汚性とも性能が大
縁く低下しいわゆる耐久性がないことがわかる一方焙理
条件Ｂ、 Ｄ（本発明方法）によれば１０１用Ｏり返
し洗Ｉｖ後も良好な性能を示し本発明の有効性をｌＪ！
ｆｆしている。D is an example of processing conditions according to the present invention E, which includes water vapor. As can be seen in Table 2, the performance of Bories de U TF & products treated under these conditions shows good values for water absorption and stain resistance for each condition immediately after treatment, but after repeated home washing 10 times. When performance was measured for the same items, it was found that the samples under bleaching conditions A and C (comparative examples) had significantly lower performance in both water absorption and antifouling properties, and were not so-called durable. According to D (method of the present invention), good performance was obtained even after repeated washing for 101 O, and the effectiveness of the present invention was confirmed by lJ!
It's ff.
特許出願人 ユニチカ株式会社Patent applicant: Unitika Co., Ltd.
Claims (1)
もとてグロー放電により発生せしめた低温デヲズマＡポ
リエステＡ／系繊維品を処理するに際し。 該気体の水蒸気分圧を０．０５〜１．０Ｔｏｒｒに調節
した状部でポリエステル系繊維品を低温プラズマ処理す
ることを特徴←忰仁り４−μト←郁−組維−品−を一１
低１１ダーワー沖４−処一理−Ｎ逼ベト礒、訃４ト徴と
するポリニスｙ−〜系繊１１ｒ品の耐久性親水。 防汚加工方法。Claims +1) In the treatment of low-temperature DEZMA A polyester A/based textiles generated by glow discharge in the presence of gas under a pressure of 0.1 to 2.0 Torr. The feature is that the polyester fiber product is subjected to low-temperature plasma treatment in a state where the water vapor partial pressure of the gas is adjusted to 0.05 to 1.0 Torr. 1
Durability and hydrophilicity of polyvarnish Y-~ series fiber 11R products with low 11 Dawa Oki 4-Processing 1-N tackiness, and 4-T characteristics. Antifouling method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12179782A JPS5915569A (en) | 1982-07-13 | 1982-07-13 | Durable hydrophilic anti-stain processing of polyester fiber product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12179782A JPS5915569A (en) | 1982-07-13 | 1982-07-13 | Durable hydrophilic anti-stain processing of polyester fiber product |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5915569A true JPS5915569A (en) | 1984-01-26 |
Family
ID=14820149
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12179782A Pending JPS5915569A (en) | 1982-07-13 | 1982-07-13 | Durable hydrophilic anti-stain processing of polyester fiber product |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5915569A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0245140A (en) * | 1988-08-04 | 1990-02-15 | Toray Ind Inc | Laminated structure |
| JP2008012779A (en) * | 2006-07-05 | 2008-01-24 | Daiichi Insatsu:Kk | Filing booklet, assembling kit thereof and manufacturing method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS584808A (en) * | 1981-06-24 | 1983-01-12 | Toray Ind Inc | Coated fiber |
-
1982
- 1982-07-13 JP JP12179782A patent/JPS5915569A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS584808A (en) * | 1981-06-24 | 1983-01-12 | Toray Ind Inc | Coated fiber |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0245140A (en) * | 1988-08-04 | 1990-02-15 | Toray Ind Inc | Laminated structure |
| JP2008012779A (en) * | 2006-07-05 | 2008-01-24 | Daiichi Insatsu:Kk | Filing booklet, assembling kit thereof and manufacturing method thereof |
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